CET Org Chem Halogen Derivs
CET Org Chem Halogen Derivs
1. Introduction of alkyl or aryl group in chlorobenzene by reacting it with methyl chloride in the presence of [1]
anhydrous aluminum chloride is known as ________.
a) zero b) 2nd
c) 3rd d) 1st
4. Treatment of sec-butyl bromide with alcoholic KOH form ________ as the major product. [1]
a) but-2-ene b) but-1-ene
c) butan-1-ol d) butan-2-ol
5. Chlorobenzene when heated with a mixture of concentrated H2SO4 and concentrated HNO3 yeilds ________ as [1]
a major product.
a) b)
c) d)
6. Aryl halides are less reactive towards nucleophilic substitution reaction as compared to alkyl halides due to [1]
________.
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c) weaker carbon halogen bond d) resonance stabilisation
7. Which of the following is a primary alkyl halide? [1]
a) (CH3)3CCl b) (CH3)2CHCH2Cl
c) C6H5CHClCH3 d) CH3CHClCH2CH3
8. Which of the following acid adds to propene in the presence of peroxide to give anti-Markovnikov’s product? [1]
a) HF b) HCl
c) HBr d) HI
9. Identify the INCORRECT statement. [1]
A. The major product of dehydrohalogenation reaction of 2 -bromobutane is but-2 -ene.
B. The mixture of concentrated HCl and anhydrous ZnCl2 is called the Lucas reagent.
I. OH-
∙∙
II. NH 3
III. R - NH2
a) 2-Bromopropane b) 1-Chloropropane
c) 1-Bromopropane d) 2-Chloropropane
13. Arenes on treatment with chlorine in presence of ferric chloride as a catalyst undergo what type of reaction? [1]
a) CH3F > CH3Cl > CH3Br > CH3I b) CH3Cl > CH3Br > CH3F > CH3I
c) CH3F < CH3Cl < CH3Br < CH3I d) CH3I > CH3F > CH3Cl > CH3Br
15. Which of the following statements is TRUE in case of alkyl halides? [1]
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c) They are highly soluble in water. d) They undergo addition reactions.
16. The reaction of C6H5CH = CHCH3 with HBr produces ________. [1]
a) C6 H5 CH2 C HCH3 b)
|
Br
Br
18. Which of the following forms a poisonous compound phosgene when exposed to air and light? [1]
a) CCl4 b) CHCl3
c) CHl3 d) CH2Cl2
19. The compound which contains all the four 1o, 2o, 3o, and 4o carbon atoms is ________. [1]
a) 2,3-dimethylpentane b) 3-chloro-2,3-dimethylpentane
c) 1-chloro-2,3,3-trimethylpentane d) 3,3-dimethylpentane
20. Which of the following is a halogen derivative of aromatic hydrocarbon? [1]
a) Hexachlorobenzene b) Hexachlorocyclohexane
a) arene b) alkane
c) alkene d) alkyne
23. The SN1 mechanism for the hydrolysis of an alkyl halide to alcohol involves the formation of ________. [1]
24. C3H8 + Cl2 −−→ C3H7Cl + HCl is an example of which of the following types of reactions? [1]
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a) Rearrangement b) Elimination
c) Addition d) Substitution
25. Identify the CORRECT statements from the following. [1]
I. Aryl halides are insoluble in water but soluble in organic solvents.
II. The isomeric dihalobenzenes have nearly the same boiling points.
III. Para isomer of dihalobenzenes has symmetrical structure which closely packs in the crystal lattice.
IV. The isomeric dihalobenzenes have nearly the same melting points.
ii. RCH 2
− CH − OH
|
C H3
iii. CH 3 CH2 − C − OH
|
a) (i) > (ii) > (iii) b) (i) > (iii) > (ii)
c) (ii) > (i) > (iii) d) (iii) > (ii) > (i)
28. Which of the following has the lowest boiling point? [1]
a) CH3F b) CH3l
c) CH3Cl d) CH3Br
29. The product (X) formed in the following reaction is ________. [1]
H2 O2
Major
a) Ph(CH2)2-Br: b) Ph-CH(Br)CH3:
Markovnikov’s product
30. CH3CH = CHC(Cl)(CH3)2 is which type of halide is based on the position of -Cl? [1]
a) Allylic b) Secondary
c) Vinylic d) Aryl
31. About a racemic mixture, some statements are given below: [1]
i. It is a mixture of (d) and (/) isomers in equimolar proportion.
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ii. It is optically inactive.
iii. It may be laevo-rotatory or dextrorotatory.
iv. It rotates the plane of polarized light towards the left.
The FALSE statements are ________.
The general formula of the organic compound obtained in the above reaction is ________.
a) R - ONa b) R - R
c) R - I d) R - H
33. The reactivity of various types of alkyl halides towards SN1 reaction is ________. [1]
a) secondary > primary > tertiary b) secondary > tertiary > primary
c) primary > secondary > tertiary d) tertiary > secondary > primary
34. Which of the following is formed when alkyl halide is treated with sodium alkoxide? [1]
a) R-CN b) R-O-R'
c) R-O-Na d) R-NC
35. If starting compound is laevo rotatory, after the SN1 reaction, the product is ________ [1]
According to the representation, which bond lies below the plane of the paper?
a) C - Br b) C - H
c) C - Cl d) C - F
37. Chlorination of ethane is carried out in presence of ________. [1]
38. The optically active product obtained from SN2 reaction of a Dextro rotatory compound will be: [1]
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O
||
[1]
Δ
a) Ketone b) Ester
c) Ether d) Alcohol
40. The order of reactivity of HX in the following reaction is ________. [1]
Alkene + HX ⟶ RX
a) HBr > HCl > HI > HF b) HF > HBr > HCl > HI
c) HCl > HBr > HI > HF d) HI > HBr > HCl > HF
41. Which of the following CANNOT be prepared by direct halogenation of benzene? [1]
a) Iodobenzene b) Chlorobenzene
c) Bromobenzene d) Fluorobenzene
42. The CORRECT order of increasing reactivity of C - X bond towards nucleophile in the following compounds is [1]
________.
I.
II.
a) PhCH2Cl b) PhCH(Ph)Cl
c) PhCH(CH3)Cl d) PhC(CH3)(Ph)Cl
a) HCl b) SOCl2
c) Cl2 d) NaCl
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is ________.
a) b)
c) d)
46. The isomer of C4H9I which is capable of producing but-2-ene with ale. KOH solution is ________. [1]
a) 1-iodo-2-methylpropane b) 2-iodo-2-methylpropane
c) 1-iodobutane d) 2-iodobutane
47. Acetonitrile is prepared by treating methyl iodide with an alcoholic solution of ________. [1]
a) iodo b) fluoro
c) chloro d) bromo
50. In SN2 reactions, the CORRECT order of reactivity for the following compounds; CH3Cl, CH3CH2Cl, [1]
(CH3)2CHCl and (CH3)3CCl is ________.
a) (CH3)2CHCl > CH3CH2Cl > CH3Cl > b) CH3CH2Cl > CH3Cl > (CH3)2CHCl >
(CH3)3CCl (CH3)3CCl
c) CH3Cl > CH3CH2Cl > (CH3)2CHCl > d) CH3Cl > (CH3)2CHCl > CH3CH2Cl >
(CH3)3CCl (CH3)3CCl
a) CH3CH2CH(Br)CH3 b) CH3CH(Br)CH2CH3
52. In the dehydrohalogenation reaction, the conversion that takes place is ________. [1]
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a) alkene to haloalkane b) alkene to alcohol
CH3
I. RX + ale. KCN −
→ RNC
III. RX + KNO2 ⟶ R - 0 - N = 0
c) I, IV d) I, II
55. Which compound among the following on reaction with ethyl magnesium bromide gives ethane? [1]
c) H2O d) CH3CHO
56. Iodination of CH4 to CH3I is carried out in the presence of HIO3 which ________. [1]
c) 1-Chlorobutane d) 1-Bromo-1-phenylethane
58. Which of the following statements is INCORRECT? [1]
A. Optical activity of a substance is expressed numerically in terms of optical rotation.
B. A compound which rotates the plane of plane polarized light towards right is laevorotatory in nature.
C. The optical isomers which are nonsuperimposable mirror image of each other are called enantiomorphs.
D. Enantiomers have identical chemical properties except towards optically active reagents.
c) d)
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a 1o bromoalkane a 2o bromoalkane
60. Best method of preparing alkyl chloride is ________. [1]
anhydrousZnC l2
a) ROH + HCl −−−−−−−−−→ b) ROH + PCl3 ⟶
61. Which of the following statements is FALSE about SN1 mechanism? [1]
a) zero b) second
c) pseudo d) first
63. C2H5Br gives C2H5CN on reaction with alcoholic KCN, while with alcoholic AgCN the major product is [1]
C2H5NC. The reason is ________.
X is ________.
65. Alkyl halides can be converted into Grignard reagent by ________. [1]
C2 H5
a) 2-ethyl-3-bromopentane b) 3-bromo-3-methylhexane
c) 2-bromo-3-ethylpentane d) 3-bromo-2-ethylpentane
67. Identify optically inactive compound from the following. [1]
a) 3-Bromohexane b) 2-Bromopentane
c) 2-Bromo-3-methylbutane d) 2-Bromo-2-methylbutane
68. ________ is obtained when benzenediazonium salt reacts with Cucl/HCl. [1]
a) 1,2-Dichlorobenzene b) Benzene
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c) Aniline d) Chlorobenzene
69. Which of the following halide undergoes hydrolysis on warming with water/aqueous NaOH? [1]
a) b)
c) d)
70. In haloalkanes, a halogen atom is bonded to ________ hybridized carbon atom. [1]
a) sp3d b) sp3
c) sp2 d) sp
boil
a) C3H7OH b) C4H9OH
c) C3H7Br d) C4H9Cl
c) n-butane d) isobutene
74. An alkyl iodide (X) reacts with sodium in ether to form 4,5-diethyloctane, the compound (X) is ________. [1]
a) CH3(CH2)5I b) CH3(CH2)2CH(I)CH2CH3
c) CH3(CH2)3CH(I)CH3 d) CH3(CH2)3I
75. Amongst the following, which is/are TRUE for SN2 reaction? [1]
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a) Option (A) b) Option (D)
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