Lesson - 21
Lesson - 21
Lesson - 21
8$riecirr--orfijg& crgl gporp* rrt$eost (b') Cted:S;uGeund (a) o,tGqns (c) tando3erc {d) gg6;Gar* [dor- : dl (Jun 06) 2. gO&qrn eri*eorrcrufr CE,ri'iOg,@. (6) Oodlgrcarn* (a) o,&Gqn* (d) 6gGsr* (c) oiuumide !a9wlr* : d! 3. {}$rrianeiruoerpgch er4pt *&Gyr*39 &rn1g$p*nrpdlo :
(a) @FL-erl,L eri&aag (b) g@d;er eriSaooq
{c) $qrrfiu$u6l6o 6gGanar+ toL@rb Gle,r@*6ryr. (d) $qtrfitt5u uat-$gt gqgGarrau &bgttb fu*vtGurglgg. 6an@Ahpg* hncttr- : cl
4.
c&GrrGdt lgqg&Gan*6, &riy&Gr-n*rb rlsrrr&cri ur:qqqtuglr (a)C,-C, (b)C;az (c)C,-Co {4C,4.o lelenr- : lll 5. 19qgriGeneiu crprn* 1gq5*G*ned* .,atIrDorsrc
rorf ptlut-n5lr
(o)Br/HrO
(c') unor,aw {b) ""Gr-n9urg (d) a*-rt aagada
fldnoru : dl {Mar{16)
{derr- :
e!
gilGGorn stldordr 8. Oriortou.rpp anrtuerrs* Gereirqrnp (b) acdfrc$etr (a) ilraoerilerr [cseor-- : cl @) o,p3lrrfietr (c) q}qn6r5i66t 9. qrprfo aerfld'r aL@ronc glcl&a-glcch (a\ c,.aagttyqntfl 4Lfianb (6) o - sltfrGarrr 4dlouth
Dl
(a)
6)Cqcp6ot
ctr 4t1uccfl
(b)
alrl,u0ev ry,'inffi
(c)
11.
Sdvan
dl
[dorr- :
[dorr12.
dl
[doru
al
13.
qrprfoocir erpendr un$&eriuun5tr (a) err,dlalb (b) atvth (c) a-a:iOtatuufiaa (d) 6'i
[oleort--
cl
14.
pdn Surr$oru OpppO erdrugl crgl cldreir (o) qrpp4grctror a,pr4;rggar fia',erutl 1?flatat P6o (b) qrpp@dw e-uqflu'iv Gcwfi$pefrr $gpsa @) graart-nrh flalcu s466'tr,uLl Qgpsa [e8orr(O g4,pa:nb flo,ou s4eli,u,uq @gPorit
bl
15. erdroerircerflcfo
gfur:$*
Oeure>npgqttn
Fpdt
srpsr ncbr
(a) gr,fiGclr
n c4tficuwo,r;fierr arfloe
al
($
Grr,fiGi,e.rcrrtr;lrG/,adoao'r.th
lctroru
7 '
qrpriuserfldt FilD;gt:.1* $gpgurno ollormorgt (Oct 06) (b) es$|"%ungd elr,dlourb (a) -ctaln66',66t (c) qdlGqrn clrfrcuh (S alGqnGrctyd; eyfilc,urjo[ollorr- : cl (Mar 06) qrprbeeh ereiruorot 17. (a) urc$lOuucrl,e@aen (b) uetury elt6lariaaotr al (c) uouurg .o,tlatrn,io (d) uro0 orcivt-ftsen [ollsor-18. {S${ie6udrr-orpgoir FrF)6b oslt$O. o-ehmglr (b) eerflrl orcirr,dewruL (a) aiutrrihe, cl (c) g,nouq erciwGewfu (t) 6uuau@ [orlorr-19. er$eb +6drr GerfirorrO -qr-rlu6tuloirenglt (b) eeanu,k eraiw?owrw (a) G'rcq96 hl (c) erg qaturdowtu (d) 4doqL0atr [oioor20, er$lei: 6F+- eri,1Glo$ ereiur-ri c-cirmgtr (b) eearlu:do orciviao ut (a) 6n1ry9 (c) udlGi,ucncll._dr EraivGiow,it (A G+oilg2rGalnerb [oloru rl 21. conrourcb eroftr6aoru9oSlqgF5t Gupuu@rir Oonqguq anSla:rilr (b) aiurywrfli; sldtwb (a) e$tryd; e.rflcuth (c) GuevenuSl& erfioudo (d) 4d;eno6ld qt$outh [olorr-- -: 0l 22. * gt florpopirm Gonqgriq -eldlorir glcbor (b) aiuryuLrfl& 4ldlourh (a) un,kttlryd. 4dab (d) Befiefit lqdlwnth [crtcurr- : dl (c) ga5luge gd/o.l,tb 23. ceur rou.r eb er edr Gmr or u-r* cntr rb Q cncilr @ fi rn pu g$ptre[: Glorr--riugl (b) Befieqffd) (a) Genutl (c) 6an1ryuq el6tcr,b (A @) rcfigth (b) [olorr-- : dl 24. perir ro$grn (p+t:96b rchmgtr (b) darlgutq (a) ?e,iog13cl,rciv (d) ottdl@ (c) Flrnu+asr [crieorr-- : cl 25. 6csbeorrf,eto gliiGlu-r Gor$)uGunr-geir (d) e6lttLficu"r [olorr-- : Dl (a) a9i9@ (b) Oec;irgJGcuneiv (c) '4rptb qnfiucheuru 26. pnorqfuoerfldr g,flu.r gerfluicil 45terrcru@dr, FqUr.n gcrflrlGcririore 46rrt-Fgt pq5otgt (b) anriGunagtt-GqL (a) qrsb (d) darqgutl (c) caatttdletraotr [oiorr-- : 6l
16.
2?. firn$ugpp"Slair
6E5ti;Gcneiu, topS6
(b)
r9g,*GL-n6tr+$
aitturrii
[orieou cl
(d) okt*nrtn
[oSorr--
cl
31.
(dS etsn6;Gt-neiu [sriorr-* a,e.?yneiv SLGr-n,l'ri6 e(b e-Sirryewrril (b) 3"8Yd;& neiv (a) E5gyflSa,naio (d) ami;Gt-neiu [olaru @\ s,AGqnch ornririrun$ 6unglcunar risr)Lr+ ori&e ortre ofidr
"%r-9.reGr--neru
ul
bl
(C6Hr,,oi)n
[olorrr-
d1
$rnLoreri eriseeor .erorriu$eu5l (b) 5qdGat<it @) *AGqffaiD (d) lr,ndoGunaiu {c) "%Eq&Gtne.iv ei ortu$orgl 33. ad*eiriaortr (b) ad;Gqtr6it) neit td,""Ard;Gt (d) u,n'6o3tnehs (c) qgi;Ga'naiu 34. uroSlcntaorrOGQDIB(5 eq5 e-Bnvorrrit (b) e.d;Gqn* (a) cioL-rft& (d) f"Eq&;GL-ns, {c\ gqd;G.sr* 35. or*rei: enfiustrot-& Genedrqrnp g{LSlGcn-n (b) erueacmfrr (a) ilawrfic-,w (c\ t-da4Gwncrreqtr (d) u3qtrcrl,ou,66r
lo9orr-
bl
[oleou
b1
[o9orr-gDtdl6Ddt
al
(Jan 06)
[o9orr-
al
[3 o$frGuoiraeirl
[un.gn.a9.,1-5]
1.
u
cn>och pqqc.
u1
narSl eo W
t-
gn&
W@s
dtsu 14 uL
et q
i a s crfleo eu ea a u9@ e n riG u nrri,qll, ryG yL@ aw erear L u@ th. g) -* g'reu q rh aafi 6o grfl a: @ fia s 8 cio 6 eot-t6 rh a rfl a t 6 u n1g6trs6tr. gofiu9afu e.nduecr-eut--geoootr@rb, 6Arb gofii'Geri4;c,aa 14at-fu1
G
ri;t
uL
sniGu n er;pqGqL-.@ a'arr,er.$ pgAteo petr. er@$gttant-@ : efthsan aiutrrii 2. *rhGrner8eh =qrDot6)u crqg$t.
glorror]rl
H_
cHroH
H-
C-------r
HO-C-H
?
I
HO-C-H
tl
I
n-J-oH
H*C-OH
lo
"-J cHroH
I
rl
cH2oH
C-l 6
&*r&;Gt--nfl66r C-Z
094
gq&Ga-nc;rfila,o
Glorr--tugr flgt?
u
nc$l
e n& sar@ aofi ,60 t8 a 1y:th w @ rratrg 6iut-n rtti'. or$gi r.r,c,wlyttb, Qunohgt Gcrtath. Gsngau, *cll,allu-1th @<iacurg Gtatati$aa 6lp
Gsner6, unic0, elfi|Gl, o-qgaont 6W,iug ugtd;Gle-nLcri-L-aai,I 4A w ag $l do et6 s th e-.etrc,rgt. $ qfffu u gu Eeiv @gfi w na& Aon--tLug1
gq&Gena,iu.
(Cr2H22Or), +
(C6Hr,,Oj)"
(Cr2H22O1)n
iurygLaadr L6at-wgt. 4. qgg*Genauch str-i HI 6fo oiccro ojrgt? Aauq unehtuyeht gtetrefio,cuugci; HI 4udleurn gqgdGa rors 1gfiflgrnra A@liA n-Gtoyr,&Geeurns nnfugQtpgr CH3CHTCHTCHTCHTCHT n-Gtpt*Geatr gEgdGeneiu C.H,rOo -*
u,ndo3tneiu I C6Hr2Oo ggd;Gsmio I 6rt$g HCt I fuSt eloatrcGouneiu, elcrloGoun du&ryefrr erevgtth
ilui,eivryrtlair
@Cg
5. Gcnuun&s6b
eretrprneb
5r@r66r?
s-uLi 6an1gurl
46tourwa
e-1ryatn6i,pg1. S)alcrgcoa"r
CH,.OOCR
I
cH,oH
I
CHOOCR + 3NaOH
I
CHOH + 3R.COONa
I
cHr.0H
6tefileYndo
Ganutl
cH|oocR
6. Bpdtp cri'6corIlncir eroruorol u.lrr6Dol? u6r) GLoggrr-b erafruL eid;saqsetns $qnfuugtis(g+urnfi ea q e ft &a p ea g endo b aogt ti; r-yq rr/i;cn9 -gourgeo w@ sl d061)gl E tG oralriu u@ rh. Gr. a n. ) 6E5gGs reiu, ""'E ttG t-.neiv' 7. goSGen cri6eeoFeeir erordlu$uenor u-trrstr6u'l e ri I e ea q a ea ot $ fiq rr p ut g g gcrlou S) reurr @ ta, st fi p (5 ^G rc fi u t e qaon o et u u @ th' p i n riGu na pn ryGy r@ a 6n gorl Gen e i &aa g@A 66r 8. rndrrilGorneiu erorugt u-rngl? Jlolp firnOuqg$pn6i)
Glorru-tluorot
ltlrrdD6rl?
gb6ap
8;g rh.
dor erur uqoeh ercirr u cor 6n utr dt! 6il ? lr6ur.rr.$ ertgsarysaf)ev, uoo gplopi eitsayaeir 4ti;aen@ t 6 ew peo' @ $ 5 u n at rits en ndo g etr3pt nG t- n atrg @ coewrd; s u u t-t4 1ry u u @ rh' 6nGa n @ ry&; 3 a owr u q a'etr orctr @ la,owru q a otr 6 a 10. gqgriGanorsldr 4trri;erslgGorpp er9ororotu-t 6rQ95l'
9.
Glorr
n CIrg
ri
ygd;Ganal,e tqGryn6latr
4tetEgGetrfig"-b
Gsnoiw@
a"if,a
ggdGarch
Br"/HrO
:ryeri
(cHoH)4
$V)Aa,r,6fi8 gtdartb
CH2OH
tl tl
(cHoH)4
COOH
sn&erfli
sryrda-rrir
lJHoHl.
I
12.
*r*al
6pn!$ CIebecreu srdr9t qgaD$Gencrflsb sdlop ereirorng cl$arnrirt pg6pgt' ygd;Ganeiu $rfldo aeaybgt pAflcrl,euth seaqeaas etat rg:q'etnfipgt' G'sogi $)cucoou ggtGa;no$tcio
Gl pngF 13. qgg{tiGsnenleb 4b6bt+66}gnDO eretruorp pq9tll{ilgd olleooreou-l tr$Sl'
"916tau$
o-ehorgt
sev$5 ?a;latrclfl gg&Gli;neiu eno;a,rraiu anqe'nflal,uL GuGnnefiutn ea y e a et * g"aft, _ * t ) e,G c,rsn o 6 ett 61f arf) uJ n s a1 th, f" Gt t eE rfu rg s (anrtil @urcit) 4&al,atst-naqrh (@arut1 6p u"9gu+u\) g@hgtpgl 6png@ z-atrGngt erenugl Ag*"bt 6q5"ec*oonncu 4ourgcow@ 6grfl6pgt. OH GpntgF o-eirorGprdrg 14. qSaD.iGencr6lcb EFSt
fi ryw g:etrcfi aa ull'do e1@ t-ryt std6u $ rll oE tetr A**qrfl6,g,t Gtueirun elAGtt-o e$ Sugpgt' @ciuaffeoasr G,pr6@ae;t @:ryuua\& gd'i6pSL 1EggG*;nafiao gpst -OH
gg&G a
neiu E
ua
ereirorn
gl
$lqSrllri;onuGGlP
glt
15.
nnnrirrfiGr--neiu
ernonor
f"urytGtneiv stL-ri HNo3 elt6let:$pn6o e\fipnat$g't d; tfl a$66.,P t4 Ib 5OA pgL 6 affit s n66li; ey6t a$ag u1 tb, L--nri t-n rfl c1
,""ayg;Gt-reiv+ 4 (O)
HNo'>
qrflGlpglt
cooH + cooH
(CHOH)4 COOH 6'ooor,i'e,na$& st6tath
I
ll
8r-Gr-n Gpnq$ a-ehmoorp o-g$u@ggrrb u.rrStl Na/Hg/HrO 6anaiw@ fo0rySGtnaoau u6@ g@dcrn }eutprcio erriEr_tno':, rlnerfit-ndv orcogttb @fA orAniaefiatr {Ea)6a6u heat-tdpgl @ciuoflcn,ovd- gCf qSuL Enean$gonanuLfip earcuLtb C - 2 e-7gann&auu@Apgt. $1g Gt--Gtrf 6Sng9 e-arerap e-Et@uu@ggt6pgt. cH,oH cH,oH
16. &r5lrriGr--ner6lcb
Gcnporo
o%uq&Gene,*
2(HfdH/tort - J-
clogtryrflev
cH'oH 17. nnnrir6Gr--nClci: Br-Grn 6pntgF OgclinLndr onrtuor 4@t6fir$ C - 2 olcb ueirm$t 6r6il erciorng etflornfir p-t-ovr e$laeotlrfl$gtl e-aiwtn86n euLG66rt "o"EyiGrn6iu HCN
.tl
cH2oH
$qnfrugteuut@
-t
eflaeor?unTqan
Aatutl
unoivuq6iu Hl
6)naiutnth sniudrr
-grarorei9ci-r
cHroH
otuqtGen,
(cHoH)3
I
l\oH
J-
t*
cHroH
CH'
I /cooH
(cH,)l
I
l-o"
CH,
6ile.u u
18.
*tG g naed
9@66r
rrdl
Erfirie$l$gnoil Oorerfiri a@eer flpt a,oiwewrnty Gunargt Gtungetr 6)oot86)pg1. 6lg/Go, unrie$ eidseary oreouu@b.
Q*g
rh.
t9.
*&Gqn*200" C }wuuflal,eud;gn 6@u@$gtbGungt 6*r @p@ u(g,uLl fip u+*p .oevmnuLfip GunTryon 6icr'.t_'8;6pg' CIgGr.qn-r,r;l oeutuu@tb"
tfro a4fiaana* 6aL-uugt' ggl 6eou &6raaq 6a u) u Ll e n i $ g u 6fi a erfl91 b e-1g at n g g g eE gt rc, p n ov q rits aft eor rcfuyt 4r!
aefiGa.:Gvt
?0. 6leei:guGerrneiu upd{i t5dfiq 6ilorlF{6' ton6r!5' a'niGu nc,ttovl+Grr--G) Qlgt aruioour$ pneu ryr,l,a,efigtrh
uwatru@ilpgt $tS/ 6,frgtu, arfirc aeaquunotraetflgtb 66atrul$g!' u6uuari,t-$gy D gg*Gsna' $rigg H'SO, p-t_dtr Galn6i,&a ol,at$ryndo 6eat-&6pg' nCuHttOo gq&Gsn* (C6I{r5Oj)" (fi,edogt}asnc,,) + nHrO #>
6uoDtr{5'
o, o o o r;,
gtata-gt erat6
etr tp
etr'
4fgrasefiegtopSeireanqetroteoaltltrgrilaetrrrrt}uLeioqg-erretetlan. ctt9lert e-gtueauult-b, 6ntr e-Etuauultb g6nGa clilcrrefido 0-Gpn (;,a,naivt--eaat, aal,yeofietr pH 8u GtunTryogil 9-et
w
ofi u n a G ottn
or6i,
6 e uL'io u @ rh'
LJrpfigadr e1wofia6n tflewqou$@dt Gpftt$letr 1g:cr,coari.uLGan' o@ri pH 'i0 qrlg dlotrlgoanaocowGwn Gryftht 6eoi-rglrb' @a5 @du0r-rqy:a&e',Eu 6rpg 8A dlea1g:crr,eocouLulrh Ggrn86 parnadv flaq tb' u 6l etrs ea to uillds ot:n p fl a ertea uL epo 16 pgt. e n t6t etr q en efl erct u @ a9 g u ryatrgdo g eaet uSlc;u Ll r p ti ot9$ u r4arri6i, pgt' Slciu ang q r fi th @ fi atc'filw gt^p 6etuua' 7g,etr @uduo,u @goaou' arctruu@ep9l. anqb, auairu eryrr6lau b Seogth uet-' a,rlJewfla,arndu t1fiu@5# (g+qtb'
24. gtr6lGern tNr.Sln:riroclr erchuenor u.rlrenor? oniu n&Gldo 6p n6$a w uqrn, (- COOH) at-E3cor Gpng@ea ut th ggaGs danaiv@etrer @yt-me e$lcriew$}gnqfi Geriu,rilaon e1 6lGet n a1 6l a aewr6 k, s1 at fi Sl ar Gt u ngl an natr at n ut u u n@
u.1 ri;t
HO
R-C_C_OH
I
til
a 6ffiu6tr
NH,
aat$lfun 46la&a;eir c,-a;miugtt-oir @aunavforctrm R - 6lgrrg@ug6ir Geugu@Etetrpso. @c'oorGu-r qqphlaralnlfi uaiwqaam finewugtd;fuovryo.
25. cr$$u-rnor6u-r .gr.SlGcrn g4dlofircch, glS$lu-rnorOlrri Qeboln grtr-5lGffr glr6lolfuach _ $-perrp ordnturgt. e- t-gt ti; g $ G p da an ut n et A ert a1 6l G w n g4 6l as rn sch e_ Lat6ir e, aiw t- n d; s u u @ eu S 6oeo a. 44 g ev n dts 6) -- e_ ew dn (g 6t) rr e Gtan@8auue Galain@6. 44pevndu *ll6trb6rlp s4$SuLnatflut
c-,fl LD
a4 tfl e1
et
t6l G ev
n n
a4
t6l et ril
s otr a
eir&i- G gt
th.
u.t
e1 tA
ao rfu a
6n
aa
$fi
uL
n aA
ercouu@th,
26. gtdlGern :xr0al6 6rs OqCA-* 4u.red$pehoro 6upgcirmglr a4 6t Gew n ep6l a:ri;t+,aft et d a, cnq 69 ftg$a,crl,eru 6 u fiE11g ti ug neio eg @[email protected] 41uLetfl eraingltb eluLerfl$peolou,nou; a4eathpgl. - COOH ,io zeiatr H' s4utetfi NH, 6)gn(t@i;g anfrgdpgl
R
lt CH
NH, COOH
NH,
----t
CH
COO-
[5
o$h:rGueineeir]
[un.gr.ot.' 1-Sl
1.
enriGunoorggqGyL@ocom
oreoctu@$gtFdD6DF
ato,auu@$pu
I. ei&aaqaetr, 2. erid,aaq
si&seaqsar.
@ducungal,ett etdlcr)gt
u@ u+
@coar
l.alnat 6i,e,naiwt- ut4stfuseit'
(ii) gfiearpri cri&oorueeir : Slcoreu Goglrb cr,otfruL sritsaart'drrrcB ai,gn+qn6;6 gcu+oopal@ slcila.u9;l $ynfi ug&auuL (A)+urn7 ul,
E t-G tnevroar.
@
* b A gletret
agal,ow$
r4u u anu9a'r
6l--
G.:,glttb arcoa,}u@$5uu@6etrpeo'
o
il
theaa,crl u 6 u n q5$91' fi$tg 6tr6n s n ri ul;n gt g,ut aefi etr orcio etr//tdgtd;Geneiu ercoEtrh G,t-LGqrdw, }uatrGtndn' +#rA-*n, d-gr.i, at a a u u @ $5 u u@ 6 etrPar' 8g&daiwr- Gtunglatnet 4,ioGt-r'e, LDbgltb GLGt-nc's,atr etr pno' at nfu u n@ aait ndo a n Ltl) u @6
uL
gLGens,a;rtr
(-C- )
il
orowglth elrri.gti,auu@6lctrpetr'
@w
t-a
=o
I
cHroH
(cHoH)"
I
c=o
I
cHroH
4doGcn*adr
(cHoH)"
I
CH"OH
ar4aaly 19et&a'gtae#lan @iuattrEt e-aiwt-ngth gbo,pti at .,,,u u 6 etr pet' @ $5 u u @ TrAr^A,;,^"a w u G u rgt $gt th. @',at g3q arcaauLnaw 44etsetg1 (a) $rr:eo'--& cfiiio6or[ocir : 9-s aer q 6 atdtGatryt 6tt 66',6 u tr66t S ranG- g bcli,'pt e i&aa l9aha-Et
fiq o bu glPsofldo 6 a n@ 8; 6 t-b' C6Hr2O(, + C,rHrrO,, + H"O
ol*G7n6iv glgGanon
CoH,rOo
goglGorr eri&rnoltroeh z $gnfrugppuEo;0, 6)*- @,ldav+ a,oi,or ti 6 s t@ &6 atr ptet' oill<ry bryt u Fgt g p--tpg e riga,al,r Epata'g1
&uqfGLnctr)
(b)
oarheanE s ri ti s
or d; 6 a n@ 6
eirp ow.
C6FI,2O6 + CuH,re + C6Hro6 sneudGr_rs 6<cl7,Gar6fu &uyiGt_neio -t (ii) uolurg cri.6eoogeeir : .gdao4r@ urr6,)rttts6nn6a gefuGpn Gt endrEt @ cloow&a u u L L_ u 6il f? p66,p e it aeap V:at:i;a^]t affiffd) -g qt*s t' u L r_Gp u euu rg ari&sa ytu ng,b. @$go,al, ^u*ru t1 *^* Gt oo or G s rr Gl tg& E a ewr u t1 s ewtrcir Et G p tr b. r6t* rA u y eu a n a q it ^1 elsannsc'1th E-aro,r u', u+ ,.rits.,q,,arflefu Aungtarretr attnduun@ (CuH,,,Or)" q@tb. 6)-- $gnfiuguuoat_fut gbal,p efigaaqaaarg pg6airpav.
+ 2rIrO qtu9Gannefu
C,rHrrO,n
GatS'dSlweacuu }unrg$peueli,yog,do
si&soo4a,afiov Glpryw
ohstnii
s,ndGunern ryGye@a,en
eft&aaq
@docri.nprrl.at
2. g@riqrn,
Golgur$e eh !utr6)6]r? Glungtwna @rt_rrl.ee eiga,ol,qa,efioio gapppst gn gfiolp+ :nfuyq tnfiGtpnaiirgt otr ariGunavfl,io snriuatr kggA;Garil* C, * &uydGtnAtair C2 Lb) atgfrutne $leaovta,uu(;rilry: @raiv@ gbqrpt eri&aaysgth e,ni3urefidv e,nriua,ar} u w w u @ $fi Q clo,ew ie u u e i. qg5g nd: (ag9y nildo e_arengtG u na ) g@iCSrb pabaLawfip ei&aayundpg. @St q.;o+6a4f; Gt pn6S a u 6 u frfl q rg. (er. s n. ) x6Ggn6iu, *iCiuieiv "",A
:
uL
r
gn g.p^pt eft&aaq sniGunefido sntiudvr eltgilaaatuld afiGtpretrgt GoGgtnlry e niuoir .gg[6aatu]'-b @66rdl66r Cr a fi6 pneo flci.r Co etcircudil C ) u ew u @ $@ @cri,ow&su u t-t4;1g $p n'6o (contG tnr'o,afi ,it e-eirercri,p b G u n a) g6)dg6 e rifio,arl. qw nOt pgl ggt @oflutqti r66raru-!alrt-w, urgs$patraa 6snaivt- 4do+aW@
uL
Gorgu@$gtt.
(Oct 06)
ggtGaneio CrH,rOu
EfiGt-nqiu C6H,2O6
"a.ro
I
94on
I
CHOH
I
CHOH
I
CHOH
I
CHOH
I
CHOH
I
CHOH
I
cHroH lgqgriGanciu
crlOH
&dr$Guneiu
3.
Dff66tg ?fiaawfip atiuqreen e-oireteo. M g@ 4rio3tn GlEod;endu ggrt an@o$$ goiran u1 a uuLg. @gil pffi (ry66r66r6! 6ubp gefiar-w ataLqptb 6cUuq6pgt.
994
CI$)ri, (g@rg
a n ft u dw a
GiarcwfuP
ul66rt-ugt. @gt
gt6tt(g6t6616r!
4.
5.
9SI
q?qnLilatr 6rna qGqffL6l66r 6rra 4,iffi9 0g/ 4ie$tgGewfipb elolu$gt Getfipa epotat9,6ooa.i";u. @gi ggianetff.* eltflou$ap$ & E rd;G enc$1,60 qrio +ap@ fi@AW. @g gWeGonor$ou 6Sog6 @ciroro erdouaSS ,q6do+aW@ 6prg@ ane@hpgt.
e-anerclnp& ant-@6t ptgt.
(g eDAG6n6iu
o%rirrfi
G r-_
neiu
Glprgg
$gcr,auL otgo;rv
S)oi_rc.ocu,.
Na/HglHrO Gta,naiv@ u@g g@dab Aewgncio sni9 eL_-n<io, tonotfluncu ereurp @frnT &6D6o6r
6Jan,to6pg.
orr o_ edo
r__
4. Glurieougl
ollcn ri qg.
t9 oo eurr
drq
cu
e ro
c&r
u n r__ 6t
r__
a4
H gpogageawultb, :;'-';:r -*r, ar}[g^.r^ etnaevqrnwsndo l{r1W#*:uy Aw u a,e,r * ^;T;ur"W* -r*, '6 a t@ Ea,,ewu nfl,:Tfl ^pS_ A f6:J!; u: Affiir*. -C-OH +H_ N C_N_+HrO il I [i O H
--COO
uu
ea
gn elalGawn c16tatgg6r,
OH
6soa8
Gsoag
@{,6
sJ@th. Giuueae@aev @rLaot, gD,b^,;, c,t_Lsrr, G,;;,; -CI, [email protected]'' Gtuu',-.ry" ;_:y"*53i,,:s: aaivomfl d a s ea w g 6 fl d6tuw pgt. 6uuar@ e-aivungbGungt *' G*Et elt,Geon *,,)ouwsen @A eueaaaatfleio e$to,alrq
;;;-J
rft.ou |o.
cHr
(i)
NH,
q-
.l#;ry-ffi
qoutottbat arleaaficw
cooH
(ii) 4N -
I
CH _ COOH +
-.**r]tl.*,
a4ar:ofidtr
4N
_ CH, _
gleoerilstr
_>
4N{H _ CO_NH{4{00H
6uueoe6)
I-dllrtG QD{rnr'FJFD -3nYr D-u9ft g6DnrlqscrRci: dh9@oerfidr Gcurebun@oeir I Srrarqth abEtb Erncwfla,ofido, 6an1gutl abgb otaiv?owrfu 46waat Ernc,rllfle'ofilcio' 4[pa,old Gedt$gt eoettdau uuLanu@ileopet' & s u u @ 6 pgt' eoau e t6l G $gt dt o 1g,i 11, gl u fl oaets rr,'60 $ a'&; a,efi 6a 6an1gur1 (g@tb, a,nriGunori,oyr,+Grc@, Llrqtb GunewEt 2t/a atlil5
e$;
erooeoauLu 4fipol,oui Getfl$gt ooa;de (g+u1tb' uGp 6t ae4 th eaau Getft $gt 6 u ng$pat alltr, cJpp6a61)& Gt engu u nsi A&oinnm at$' }anguq Gtatuu 4fi9(;0 6Lgg' Ggngl&+ryu9lcio e.-eiror 6anqgutl e-ce9cfl1g$g,t C)atuur-b 6atefiGuLfiEtdrGagP
p@d;6pgt.
6-(9<9, Eynolrtta,llr rcbgth Snatqasetflecr Grocu uqueau uog,tiag,g,' $rip9i,ato,c')un{t @g'q elfiu@ata\$ 5@8sa1tb' abEtrh ut&r4ff1u:no$ecndo un@u4 eJputnadu g@^*e tr*i* Zigt*n,i,*^t b, 6 alggu u t-rxtb u wewu@6 pgt' aon e-u9l qa au t1 6 e"'" u no$latr, G, etilfi,etr G u nctrp u noiuG u ne:fjl E6l 6coi't aefi,io t6lo g:&;6w ung at6i,&5iotrpotr' nqa$'il' 6ad@ov' 6t919@)' s-erer e4orrc-:,eou ati;6pgt' G'cfoune$letr qy:cri.,erusl'io a6tdpgt' u&6 ilcfounofloirr,iotr @r$Ak e-agtge9rio 19t6w
a;nc.r,cGt-n cil9@aen <q,6a6n IDbgtLb erdsot,n DIItbLl @s'haefigtth ea or G a n eE E @ a efi gt etr en a n ewru u @ th 6 et aivu t-as$@ cio ton et eo' h
Ga,o.r,thtno- g(D un'io eri&aayuLnqtb' (ryraaclr nbgttb DrbLl n6veupn atffiiii@ 44eatu1th u@d$@gtdry6tr 5|Fea7sUti;g e-ornoflo un,io efttao,r @1ryia Ga:r,liwrywgt dlg,ayh eptflwb' ropgri uoirqaeir upd 5r(95t' 6. gqgirGen0dr
Bu-rnrffuq
(Jun 06)
gl ar-e*t-Gqneiv arcwalth elagtuitu@dpgt' alGi'otrofido $1gl eiiseaq fiLp^",na atct@*gfiStwnaGan e-enetgl @g flrffL-eae Gunetrp }*gu,:, c4o,gda,uu@,6p51' $lauflt e,ai,cttuloirer $ryntax u grit.aefilg2lt-b, Ggr,tflgt rh t^t @gt e-etrorgt' purnrfl$pei> t agqrhtli eida,ai,yc,aw 4tioagr'60 1y:eoefior'eufil'io eneoeuulldo puL nrfl&s etL6t^) ilrttbuAs^do g:eopusldo Gengaett
@+ulLb.
6)St/
c,rHrro,, + HrO
a;1ryrltt1e
c,,H,ro. +
coH,ro,,
eita,al,r1 H.
qlg?,a,neiv &ug&Genciv
lgqgGonenidr clootnuq
e! + u u 60 t-
i SgAangtn e-c,i$rri u,scln6it I <;o 69 8G a rA eh cq 6a u Ll gqg& 6e u u @ Et p9t. L. Fefirc quJ6rt, qytate^gt crolt_utfryio 4hwcur!fiar
LD
gg,Geneae <gbdgnne g@e6) n-GtpilGearna arfrg16pgt. @96tCAfg ggd;Gan@,k p-eiran 4Et a,niue,ir g1tg1i,nqy.,th Oo'enu9lq;oarp 6pryw efiitde$t 14aa*-,t ?anaiw@'iretgt erctr
c4fluLanth.
a1.1flcu.Jo
HVp gqGaneiu
3. gqGaraiD
CHr
n-GtptGe<frr
CH2
CH,
CH,
CH2
CHI
6,rfldu orefignai e,6af6g;t p@'firlr.,oug; e,cri,yoor,w$ p@gtpgt. elpavnds 6gGan66o O Gtpog@ S)cirano: r;,66r
etfiuLamh.
ll
(-c_oH)
4. ggGaraiv
NH2OH s_L_d6r u,nerr:ndcrl,etb
euL0evneal,gl4rflan,evuqrh
oll ll
(C
p(Adtpgl
@g66rffcdu
(-c-H)
e-energt erdv e4Stwanth.
- )CS"g@
HC:N_OH gqd;Ganeiv
NHrOH
I I
(CHOH)4
5. gqGcrae qGqntfrdw e'eri.qe'io (tfrprcnar 6Jbil Ganaiw@ 6tbpb deuLgncio gqGanatflti; a4dicutb Etrrlt-,t6pg. eyt ggGanflio sJ,6o+arW@ 6p"qg e-rlnero,pt snt@hpE1. elGleoaafleio olfipnat-$gg qcg orainewfltaaa.larm aniuair et guit a,6a cllr,ti Gt a naiv u ey6l a$ a g e_aiv t_ni5atgt q,.o;o +o,@l@. ggGe ra, Frrl,arufil'ioounp eri,tflta9l$ Ggnt_ri g21^^u*uu Glufiflguuprrio, 4ciotgclnry@ 6prgg 5gGana Utou&e^flaer g1g
1y:elnelrtlfildo
e@ag@@te
Ganiw@rh.
cntsrfi&
crlpt--,fi4; s16la:$fimncir Groglrb e1fiprceat$g1 e1r1jat$aoq, SAhpg. @St ggGunfido gGr gA grflaowru 4,6oa,pnio 6pogg e-eir61'611,p& att@5;,p1g1.
BrrlFlrO
6. lgqgGoneiu
5qtGsnon
@sOpaJdral
HNOI
COOH
|
4ta6gGa@pb
(cHoHxssdsc*pp,i (CHOH)4
cH2oH
tt
cooH
7. ggGenoiu t-naxtraiu a,yelrifleout (gbGanetflwn e,o.:'$p Gtarcnefi p a LG q L-@ ) e-G et ns 6 arcnefi uL ns ayh, f"6 u eE ril 6 aa q ea a (a n y th )
gur6iu q&r;a'et-rre,c,4th (Glauq Ap ,Bgu+q) g@litg6pgl. @^*, 6gGerfl,6o q,lio+ap@ 6Srg@ e-en6nag8 snt@fletrpatr.
8. ggGsneiu Arflrye,in g:enetflatteuu9l,io. el6ltryd; J/Ldl6u $rflcflultctr eflaarqfisg duentn elflGttettt-$ p@gtpgt. @d&aw ggGsnA6o EFg caeul,+qnd;A Gtpng$a,etr e-etrerrri,pt
ant@6gtgt.
Gafuaaiwu 6latqiite'6rfl66r ettryLuaeuflldo gqGaneiv g(D Gtueirt-noa +gnd;A 6gat&;eGov,6o (gri 4arGr- ndgotGcna) eren e1$luLuu@6W. @ol,pt tlp&saivt euaauildo a,nLt-ounrb'
H.O
I
\CV
CHOH
r'
*
cHoH
I
CHOH
I
CHOH
I
* C
l",sF-rvl
[10 o$r:6uewredr]
Si$g
H,so,
C6Hr2O6 + ggGanciu
C6Hr2O(
&uytGt-neiu
+n44ere$ldo D (+) grgGsna,t| D (-) ooouqgGL-nsth s_6ir6rr 66au{r6rla) orfin& s,pbgl ari&aay cretrqrh @iGeuLcio (q,6rrp eitaeaqu9arr ofi ri& agtfiFtuLngdo aanayh epopddGgtnb.
cgeootq 1. fiadtrc .gJutat, lgoud*gt aro,tuLStpcu 4Et uLerfifieSg4gt &ury&Gtnoru CrHr2O6 erowp annwuunt_o.or_s }snaivtgl a;166r
:
e1$t8Gpnh. 2. Aeut:t1 unaiuuqoiu, lttqgr)+trut+8 eltflwrh 4&i-tuLatfipndu (g)@6a rruJ n6 g@ d6 c,urndo n- ApdGeetr 6laot_66 pg.
HVP
'""uq{i;GL-n6i1)
CHj
CH2
CH,
CH2
CH2
CH,
n-6pdGeoo -) 3, fouqi;Gtne $rfldo orefrgnat 66agpgt p@flag;,61,d a61;.gre6,a61,t Gtsr@ t6 pg1. M gWCsnil do - CO-OH 6p og@ S)etuooou erovru ol,pd snt@6gtgt.
Gtprrg$aen z-on6tapd; ant-@6 pg1 5. fouq&Gtn+ NH,OH p-t-etr gp6ap une,trntic,aein S@6pg. etgrtGunooGet HCN yt_dtr euGetn pW+fiarnc,w$ #OApg.
$pcCIeoeu're en &uqaiGL-n66o
a. ArflLyow, e1fltry*; +l .1iou $ficfl, f"Dqg1r-neoe, 6udtrt-n elQlt-Gt-ttra rcnfiEtdpg. @A;Steaotr fouq&Gun6:tdv g4gt -OH
: O g2@Dc,)gt gtGt-rctr
g@tab
(cHoH)l
I
CHrOH
&uq&GL-.n6iD
4daae-i
"o"uq&GLn6b, BrrlHrO etnio eTfiprooor__ol$)oucoa;. @Sl &uqdGL-n@(il cJcio+ap@ 6qoq9 $)arcoo erctrueap&
ant-@Gtpg1.
6.
4evndv, s.lt-i.HNO, - earndo e1fipn6aL-Ugr fleaeranefld ettfrcurh tDbgtth unit-nrfli s16la& a-6u6ac,r 6ioiL__t6tpgt. 4&AgGetfip eflcli,amfilciu C - C Ean,eavuq rg:fiatatdpgt. clgevn,ia gL3tnov 6Sog9 a-etrevgt e-E1@ uL 16 pg.
.
"%$tyd;GL_nafi
HNO,
+ 4 (O)
COOH + CH2OH
-) (cHoH),
i
COOH
tt
cooH
+ 3H,O
A-ar&a,ne$& grdleurb
unirnft& elrfleaj:
en
ri"
6tallt-&;frpg, asGteoetficfu Sarafleoerrageu g@ tlgu., Gieau,$ patreanuLfip oaauLti: C - 2 do e_i6atnSauu@6tgg1. @gt GuGLn Gpog@ e-eirerag, o Er$tu uG,pSthpg.
ctlroH
Na/Hg/HrO
I
7. Nar/Hg/HrO Oeneun@ rgEyiGsnaeu u6$ g@aeib Gt+tupnoio r9 t-. : n do, ro,.rcofi L- rro-i, 6r gJ Lit I f rn A er LS] n i s ofi ,ar 66u6D 6u
cHrOH
I
SouqdGr-n* + 2(H)
-+
H*C_OH + HO_C-H
(cHoH)3
I
lr
(cHoH)l
I
cHroH enri9et--na
I
CH,OH
rr,nr,tffLtncu
8. "%uy*;Grna HCN E-eotr erflc,aerir1rflbgy e_aiwundgLb cuGain agtryrflav $qnfi u gta u u L@, et?reaarr? u nlgon Aeu u q u ndiuu qeiu Hl e.-tevr gt@d;auuLendo . 2-Gtn$eio-Gtpseatrnuglt etdtouth @aao d;6tpgt. @86t<SFSt """uqaiGL-nA6il, SLGt_n Gpogg anriudtr e-etrargt eret$ 6gfi@pg. /guoga-l @fafurertb
iuTi3et*
I
I
----) ti o"
I
(cHoH)3
i(CHOH)
I
rlc,tuk 1lo"
)cooH
(CH,).
I
-o,
a
I
t
cHroH
cH,oH
2 -Gt
CH,
e1 6r
atr
a@eiu?g4,tG en ugt d
u q tG t_n
n
n
I
I
l
a fi 6
e nev
ev
a$l
at
ry n
rfl
urst
pgt
o",
@(D 6 u
CH,OII
I
CO * *
CHOH
I
CHOH
I
* CHOH
I
* C : Gianfigt aniudtr
eagaryrynd;Ft
2
c4@1
CH,OH f"ur&GLnalu
0,
3, 4, 5,
6 }udtrLn
-?gtdeGew
nev
(eb) Ge niq rDpSri 6.(gtg purnrfluooruu updl tgduq (5) oJ dr, t .F r araivaactw rcbgttn 6snqguqsaor snqu: Gsroiw@ 6r,rb
u rg u u pettr go 6ut.b
Ge n
t1
aar
6) u qq
nerct1 er: g
r ft &'s tt u @ B
etr pen.
CH._O.OC_R
ll
CH,_OH
CH
-O-OC-
R + 3Na
OH
---+
ors
3RCOONa+CH
-OH
cH,-oH 6l t--G tb qg -. u naio utt t-tya G petr 6 n1g6 aotr ugt 6l rfl a e eio u n et/ia,sn nbgrb dlrflaeeio 4eiosgtndu et1leoowuu@$fi
S) LbGtrog:Gt
cH"-o-oc-R