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Syllabus For Chemistry (XL: Section H) : Atomic Structure and Periodicity
Syllabus For Chemistry (XL: Section H) : Atomic Structure and Periodicity
Chemical Equilibria:
Colligative properties of solutions, ionic equilibria in solution, solubility product, common ion effect, hydrolysis of salts, pH, buffer and their applications in chemical analysis, equilibrium constants (Kc, Kp and Kx) for homogeneous reactions,
Electrochemistry:
Conductance, Kohlrausch law, Half Cell potentials, emf, Nernst equation, galvanic cells, thermodynamic aspects and their applications.
Reaction Kinetics:
Rate constant, order of reaction, molecularity, activation energy, zero, first and second order kinetics, catalysis and elementary enzyme reactions.
Thermodynamics:
First law, reversible and irreversible processes, internal energy, enthalpy, Kirchoff's equation, heat of reaction, Hess law, heat of formation, Second law, entropy, free energy, and work function. Gibbs-Helmholtz equation, Clausius-Clapeyron equation, free energy change and equilibrium constant, Troutons rule, Third law of thermodynamics.
Structure-Reactivity Correlations:
Acids and bases, electronic and steric effects, optical and geometrical isomerism, tautomerism, conformers, concept of aromaticity