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The Carbonyl Compound-3
The Carbonyl Compound-3
H3O+
OCH3 A, A is
2.
3.
Br
1. Mg/ ether II: CH3CHCH2CH III: CH3CHCH2CH
Product (s) I:
2. CH3CH(OH)CH2CHO
3. H3O+ OH O OH OH
(a) III (b) I, III (c) I, II (d) II, III
4. Maximum hydration takes place of:
(a) CF3COCF3 (b) CH3COCH3 (c) CH3CHClCOCH3 (d) C6H5COC6H5
5.CH3COCH2CH2COOCH2CH3 (i)CH 3MgBr ( onemol ), (ii )H3O +
→A, A formed in this reaction is:
OH O O O CH3 CH3
H3C O
(a) CH3CCH2CH2COCH2CH3 (b) CH3CCH2CH2CCH3 (c) O (d) CH3CCH2CH2CCH3
H3C
CH3 OH OH
OH
O
(A) CH3CH2CH=CHCH2OH → CH3CH2CH=CHCHO (B)
(a) MnO2 in A and CrO3 (in glacial acetic acid) in B (b) CrO3 in A and MnO2 in B (c) both correct (d) none is
correct
15. Aldehyde group can be protected:
(a) by acetal formation against attack by alkaline oxidising agents (c) both statements are correct
(b) by mercaptal formation against attack by acidic oxidising agents (d) none is correct
16. Mixture of CH3CH2OH and CH3CHO can be separated by using:
(a) NaHSO3 (b) NH2OH (c) HCN (c) LiAlH4
17. End product of the following sequence of reactions is:
COCH3 CN COOH
COCH3
NBS Mg/ether CH3CN (a) (b) (c) (d)
H3O+
O
HgSO4/H2SO4
C CH A, A is:
18.
O O O OH
O
O
1
2 O
3
19. Following is hydrated maximum at the position O (a) 1 (b) 2 (c) 3 (d) equal
2CH3M gBr
20. C2H5O-CO-OC2H5 → A. Product A formed can:
(a) give iodoform test (b) further react with CH3MgBr / H3O+ to give t-butyl alcohol
(c) be obtained by the ozonolysis of 2,3-dimethyl-2-butene (d) all correct
O
1. KBrO, ∆
COCH3 A, A is:
CH3 2. H+
21. 3. ∆
O O
1.O3/H2O
2. ∆ A, A is:
22. (a) CH3COOH (b) CH2(COOH)2 (c) both (d) none
Answers:-
1. C 2. B 3. (c) 4.(a) 5. C 6. A 7. B 8. A 9. C 10. A 11. B 12. (d) 13. (c) 14. (a) 15.
(c) 16. (a) 17. B 18. B 19. (b) 20. (d) 21. B 22. (a)