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Chapter 17 Notes 2
Chapter 17 Notes 2
Physics of Solids
Physics of Solids
Q # 4. Define following:
i)
Unit Cell
ii)
Crystal Lattice
Ans.
Unit Cell
A crystalline solid consists of three dimensional pattern that repeat itself over and over again.
This smallest three dimensional basic structure is called unit cell.
Crystal Lattice
The whole structure obtained by the repetition of unit cell is known as crystal lattice.
Q # 5. What do you know about deformation? Also describe the phenomenon of deformation in
crystalline solids.
Ans. Deformation
Any change in shape, volume and length of an object when it is subjected to some external
force is called deformation.
Deformation in Crystalline Solids
In crystalline solids atoms are arranged in a certain order. When external force is applied on
such a body, a distortion results because of displacement of the atoms from their equilibrium position
and the body is said to be in state of deformation.
In deformed crystalline solid, the atoms return to their equilibrium position after the removal
of external force. This ability of the body to return to its original shape is called elasticity.
Q # 6. What do you know about mechanical properties of solids?
Ans. The properties shown by the solid material under the action of external force are called
mechanical properties. Physical quantities such as stress, strain and modulus of elasticity are used to
describe the mechanical properties of solids.
Q # 7. Define the term Stress. Also describe its different types.
The force applied on unit area to produce any change in the shape, volume or length of a body
is called stress. Mathematically, it is described as:
Stress ( ) =
Force ( F )
Area ( A)
The SI unit of stress is newton per square meter, which is given the name pascal (Pa).
Types of Stress
Tensile Stress: A stress that causes the change in length of an object is called tensile stress.
Shear Stress: A stress that causes the change in shape of an object is called shear stress.
Volume Stress: A stress that causes the change in volume of an object is called volume stress.
Q # 8. Define the term Strain. Also describe its different types.
Ans. Strain is the measure of deformation of a solid when stress is applied to it. For the case of one
dimensional deformation, strain is defined as the fractional change in length.
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Written and composed by: Prof. Muhammad Ali Malik, Govt. Degree College, Naushera, 03016775811
Physics of Solids
If l is the change in length and l is the original length, then the strain is given by:
Strain ( ) =
l
l
Since strain is the ration of lengths, it is dimensionless, and therefore, has no units.
Types of Strain
Tensile Strain: If the strain is due to tensile stress, it is called tensile strain.
Shear Strain: A strain produced in the object when it is subjected to shear stress is called shear strain.
When the opposite faces of a rigid body are subjected to shear stress, the shear strain produced is
given by:
Shear Strain =
a
= tan
a
Volumetric Strain: When the applied stress changes the volume, then the change in volume per unit
volume is called volumetric strain. Thus
Volumetric Strain =
V
V
Q # 9. What do you know about Modulus of Elasticity? Describe its different types.
Ans. Modulus of Elasticity The ratio of stress to strain is a constant for a given material, provided
the external applied force is not too great, called modulus of elasticity. Mathematically, it is described
as:
Modulus of Elasticity =
Stress
Strain
Since the strain is a dimensionless quantity, the units of modulus of elasticity are the same as that of
stress, i.e., Nm-2 or Pa.
Types of Elastic Constants
Young Modulus: For the case of linear deformation, the ration of tensile stress to tensile strain is
called Young Modulus (Y):
Y =
F/A
l / l
Shear Modulus: When the shear stress =(F/A) and shear strain ( = tan) are involved, then their
ratio is called shear modulus (G):
G=
F/A
tan
Bulk Modulus: For three dimensional deformations, when volume is involved, then the ratio of
applied stress to volumetric strain is called bulk modulus (K):
K=
F/A
V / V
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Written and composed by: Prof. Muhammad Ali Malik, Govt. Degree College, Naushera, 03016775811
Physics of Solids
Q # 10. How the mechanical properties of a wire are determine in Tensile Test.
In tensile test, metal wire is extended at a specified deformation rate. The stresses generated in the
wire during deformation are continuously measured by a
suitable electronic device fitted in the mechanical testing
machine. Stress-strain curve is plotted automatically on
XY chart recorder. A typical stress strain curve for a
ductile material is shown in the figure:
In the initial stages of deformation, stress is
increased linearly with strain till point A on stress-strain
curve. This is called proportional limit.
Proportional Limit (Definition):
Proportional limit is the greatest stress that a material can endure without losing straight line
proportionality between stress and strain.
From A to B, the stress and strain are not proportional, but nevertheless, if the load is
removed at any point between O and B, the curve will be retraced and the material will return to its
original length. The point B is called yield point and the value of stress at this point is known as yield
stress or elastic limit.
Yield Stress or Elastic Limit (Definition):
Elastic limit is the greatest stress that a material can endure without any permanent deformation.
If the stress is increased beyond elastic limit, the specimen becomes permanently deformed.
This kind of behavior is called plasticity. The region of plasticity is represented by the portion of the
curve from B to C. The point C represents ultimate tensile strength (UTS).
Ultimate Tensile Stress (UTS), (Definition):
Ultimate tensile stress is the maximum stress that a material can withstand.
Once point C corresponding to UTS is crossed, the material breaks at point D, responding to fracture
stress.
Q # 11. Describe the classification of solids on the basis of plastic deformation of solids.
Ductile Substances
Substances that undergo plastic deformation until they break are called ductile substances.
Lead, copper and wrought iron are ductile.
Brittle Substance
The substances which break just after the elastic limit is reached, are known as brittle
substances. Glass and high carbon steel are brittle.
Q # 12. Define the term Strain Energy. Also derive its expression of strain energy by considering
force-elongation graph obtained during the tensile test of a wire.
Ans. Strain Energy. The amount of P.E stored in a material due to displacement of its molecule from
its equilibrium position, under the action of stress, is called strain energy.
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Written and composed by: Prof. Muhammad Ali Malik, Govt. Degree College, Naushera, 03016775811
Physics of Solids
Work Done =
Work Done =
1
2
( l1 )( F1 )
Strain Energy =
1
2
( l1 )( F1 )
---------- (1)
Modulus of Elasticity =
E=
F1 / A
l1 / L
E=
F1 L
EAl1
F1 =
Al1
L
Stress
Strain
Strain Energy =
1
2
Strain Energy =
( l1 )
EAl1
1 EAl12
2 L
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Written and composed by: Prof. Muhammad Ali Malik, Govt. Degree College, Naushera, 03016775811
Physics of Solids
Q # 12. What do you mean by electrical properties of solids? Also write a short note on energy
band theory of solids.
Ans. The electrical properties of solids determine its ability to conduct electric current. The
conventional free electron theory based on Bohr Model failed to explain completely the vast diversity
in the electrical behavior of solids. On the other hand, the energy based on wave mechanical model
has been found successful in resolving this problem.
Q # 13. Define following:
i.
ii.
iii.
iv.
Energy Band
Forbidden Band
Valance Band
Conduction Band
Ans.
Energy Band
When the numbers of atoms are brought together, as in a crystal, they interact with one
another. As the result, each energy level splits up into several sub-levels. A group of such energy sublevels are called an energy band.
Forbidden Bands
The energy bands are separated by gaps in which there is no energy level. Such energy gaps are called
forbidden bands.
Valence Bands
The electrons in the outermost shell of an atom are called valance electrons. Therefore, the
energy band occupied by valance electrons is called the valance band. The valance band may be either
completely filled or partially filled with the electrons but can never be empty.
Conduction Band
The energy band next to the valance band is called the conduction band. The valance and
conduction bands are separated by forbidden energy gaps. The conduction band may be empty or
partially filled. The electrons in the conduction band can drift freely in the materials and are called
free or conduction electrons.
Q # 14. Differentiate among conductors, insulators and semiconductors on the basis of band
theory of solids.
Ans. The width of forbidden energy gap between valance and conduction band
decide whether a material is a conductor, insulator or a semiconductor.
Insulators
Insulators are those materials in which valance electrons are bound very
tightly to their atoms and are not free. In terms of energy bands, it means that an
insulator has:
a) An empty conduction band (no free electron)
b) A full valence band
c) A large energy gap (several eV) between them.
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Written and composed by: Prof. Muhammad Ali Malik, Govt. Degree College, Naushera, 03016775811
Physics of Solids
Conductor
Conductors are those which have plenty of free electrons for
electrical conduction. In terms of energy bands, conductors are those
materials in which valence and conduction band largely overlap each
other. There is no physical distinction between the two band which
ensures the availability of free electrons. That is why, the conductions
are good conductors of electricity.
Semiconductors
In terms of energy bands, semiconductors are those materials which at
room temperature have
i)
ii)
iii)
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Written and composed by: Prof. Muhammad Ali Malik, Govt. Degree College, Naushera, 03016775811
Physics of Solids
four equidistant neighbors. Each atom with its four valence electrons, shares an electrons from its
neighbors. This effectively allocates eight electrons in the outermost shell of each atom, which is a
stable state.
Q # 19. Describe the different types of extrinsic semi-conducting materials.
The conductivity of silicon and germanium can be drastically increased by the controlled addition of
impurities to the intrinsic (pure) semiconductive material.
N-Type Semi-conductors
When a silicon crystal is doped with a pentavalent
element, e.g., arsenic, antimony or phosphorous etc., four
valance electrons of impurity atom form covalent bond with
the four neighboring Si atoms, while the fifth valence electron
provides a free electron in the crystal. This extra electron
becomes a conduction electron because it is not attached to
any atom. Such a doped extrinsic semi-conductor is N-type
semi-conductor.
P-Type Semi-conductors
When a silicon crystal is doped with the trivalent
element, e.g., aluminum, boron, gallium or indium etc., three
valence electrons of the impurity atom form covalent bond with
three neighboring Si atoms, while the one missing electron in the
covalent bond with the forth neighboring Si atom, is called a
hole which in fact is vacancy where an electron is
accommodated. Such a semi-conductor is called P-Type Semiconductor.
Q # 20. What is effect of battery on the motion of charge carrier in a semi-conductor crystal?
Ans. When a battery is connected to a semi-conductor, it establishes an electric field across it due to
which a directed flow of electrons and holes takes place. The electrons drift towards the positive end
whereas the holes drift towards the negative end of the semi conductor. The current flowing through
the semi-conductor is carried by both electrons and holes. It may be noted that the electronic current
and charge the hole current add up together to give the current I.
Q # 21. Define following:
i. Superconductors
ii. Critical Temperature
iii. High Temperature Superconductors
Superconductors
The materials whose resistivity becomes zero below a certain temperature are called superconductors.
Critical Temperature
The temperature at which the resistivity of a material falls to zero is called critical temperature.
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Written and composed by: Prof. Muhammad Ali Malik, Govt. Degree College, Naushera, 03016775811
Physics of Solids
Electron orbiting the nucleus behaves like an atom sized loop of current that generate
small magnetic field.
ii)
The net magnetic field generated by the electrons within an atom is due to combined field created by
their orbital and spin motion.
Q # 24. Differentiate among the paramagnetic and diamagnetic substances.
Paramagnetic Substances
The solids in which the orbital and spin axes of the electrons in an atom are so oriented that
their fields support each other are called paramagnetic substances. In these solids, each atom behaves
like a tiny magnet.
Diamagnetic Substance
In diamagnetic substance, there is no resultant field as the magnetic field produced by both
orbital and spin motions of the electron might add up to zero. For example, the atoms of water copper,
bismuth and antimony are diamagnetic.
Q # 25. Write a note on Ferromagnetic Substances. Also describe its different types.
In ferromagnetic substances, e.g., Fe, Co, Ni, Chromium dioxide and Alnico, the atoms
cooperate with each other in such a way so as to exhibit a strong magnetic effect. In ferromagnetic
substance, there exist small regions called domains (contain 1012 to 1016 atoms). Within each domain,
the magnetic fields of all spinning electrons are
parallel to one another, i.e., each domain is
magnetized to saturation. Each domain behaves as a
small magnet with its own north and south poles.
Types of Ferromagnetic Substances
Soft Ferromagnetic Substances
In soft ferromagnetic substances, the domains
are easily oriented on applying an external field and
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Written and composed by: Prof. Muhammad Ali Malik, Govt. Degree College, Naushera, 03016775811
Physics of Solids
also readily return to random positions when the field is removed. This is desirable in an
electromagnet and also in transformers. Iron is a soft magnetic material.
Hard Ferromagnetic Substances
In hard ferromagnetic materials, domains are no so easily oriented to order. They required
very strong external fields, but once oriented, retain the alignment. These solids are used to make
permanent magnet. Steel is an example of hard ferromagnetic material.
Q # 26. What do you know about the Curie temperature in Ferromagnetic Substances?
The thermal vibrations in ferromagnetic solids tends to disturb the orderliness of domains.
Ferromagnetic materials preserve the orderliness at ordinary temperatures. When heated, they begin to
lose their orderliness due to increased thermal motion. This process begins to occur at a particular
temperature called Curie temperature. Above the Curie temperature iron is paramagnetic but not
ferromagnetic. The curie temperature of iron is about 7500C.
Q # 27. How the Hysteresis Loop of a magnetic material is obtained?
To investigate a ferromagnetic material, a bar of that material such
as iron is placed in an alternating current solenoid. When the
alternating current is at the positive peak value, it fully magnetizes
the specimen in one direction and when the current is at its
negative peak, it fully magnetized it in opposite direction. Thus an
alternating current changes from its positive peak value to its
negative peak value and then back to its positive peak value, the
specimen undergoes a complete cycle of magnetization, called
hysteresis loop.
Q # 28. Define the following properties of Hysteresis Loop:
i.
Hysteresis
ii.
Saturation
iii.
Remanence or Retaintivity
iv.
Coercivity
v.
Hysteresis
The value of flux density for any value of current is always greater when the current is
decreasing, then when it is increasing, i.e., magnetism lags behind the magnetizing current. This
phenomenon is known as hysteresis.
Saturation
The alignment of all domains of magnetic materials under the influence of external magnetic
field is called saturation. The magnetic flux density increases from zero and reaches a maximum
value. At this stage, the material is said to be magnetically saturated.
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Written and composed by: Prof. Muhammad Ali Malik, Govt. Degree College, Naushera, 03016775811
Physics of Solids
Remanence or Retaintivity
When the current is reduced to zero, the material still
remain strongly magnetized represented by point R on the curve. It
is due to the tendency of domains to stay partially in line, once
they have been aligned.
Coercivity
To demagnetize the material, the magnetizing current is
reversed and increased to reduce the magnetization to zero. This is
known as coercive current, represented by C on curve. The
Coercivity of steel is more than that of iron, as more current is
needed to demagnetize it.
Area of the loop (Measure of Hysteresis Loss)
The area of the loop is the measure of the energy needed to
magnetize and demagnetize the specimen during each cycle of the
magnetizing current. This is the energy required to do work against
internal friction of the domains. This work is dissipated as heat. It is
called hysteresis loss.
Hard magnetic material like steel cannot be easily
magnetized and demagnetized, so they have large loop area as
compared to soft magnetic materials such as iron which can easily
be magnetized. The energy dissipated per cycle, thus, for iron is less
than for steel.
Q # 29. Describe the advantages of Hysteresis Loop.
Suitability of magnetic material for different purposes can be
studied by taking the specimen through a complete cycle and drawing the hysteresis loop.
A material with high Retaintivity and large coercive force would be most suitable to make a
permanent magnet.
The cores of electromagnets used for alternating current where the specimen repeatedly
undergoes magnetization and demagnetization should have narrow hysteresis curve of small
area to minimize the waste of energy.
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Written and composed by: Prof. Muhammad Ali Malik, Govt. Degree College, Naushera, 03016775811