Memristors: Definition and Construction
Memristors: Definition and Construction
The memristor (/mmrstr/; a portmanteau of memory resistor) was originally envisioned in 1971 by circuit
theorist Leon Chua as a missing non-linear passive twoterminal electrical component relating electric charge and
magnetic ux linkage.[1] According to the characterizing mathematical relations, the memristor would hypothetically operate in the following way: The memristors
electrical resistance is not constant but depends on the
history of current that had previously owed through the
device, i.e., its present resistance depends on how much
electric charge has owed in what direction through it in
the past. The device remembers its history - the so-called
non-volatility property:[2] When the electric power supply
is turned o, the memristor remembers its most recent
resistance until it is turned on again.[3][4]
Leon Chua has more recently argued that the denition
could be generalized to cover all forms of two-terminal
non-volatile memory devices based on resistance switching eects[2] although some experimental evidence contradicts this claim, since a non-passive nanobattery eect
is observable in resistance switching memory.[5] Chua
also argued that the memristor is the oldest known circuit
element, with its eects predating the resistor, capacitor
and inductor.[6]
voltage
v
charge
q
Capacitor
dq = Cdv
Resistor
dv = Rdi
Memristor
d = Mdq
dq
id
current
i
Inductor
d = Ldi
vd
flux
Background
Chua suggested experimental tests to determine if a device may properly be categorized as a memristor:[27]
M (q(t)) =
dm /dt V (t)
=
dq/dt
I(t)
It can be inferred from this that memristance is chargedependent resistance. If M(q(t)) is a constant, then we
obtain Ohms Law R(t) = V(t)/ I(t). If M(q(t)) is nontrivial, however, the equation is not equivalent because q(t)
and M(q(t)) can vary with time. Solving for voltage as a
According to Chua[28][29] all resistive switching memo- function of time produces
ries including ReRAM, MRAM and phase change memory meet these criteria and are memristors. However, the
lack of data for the Lissajous curves over a range of iniV (t) = M (q(t))I(t)
tial conditions or over a range of frequencies, complicates
assessments of this claim.
This equation reveals that memristance denes a linear
Experimental evidence shows that redox-based resistance relationship between current and voltage, as long as M
memory (ReRAM) includes a nanobattery eect that is does not vary with charge. Nonzero current implies time
contrary to Chuas memristor model. This indicates that varying charge. Alternating current, however, may rethe memristor theory needs to be extended or corrected veal the linear dependence in circuit operation by inducto enable accurate ReRAM modeling.[5]
ing a measurable voltage without net charge movement
as long as the maximum change in q does not cause much
change in M.
Theory
Furthermore, the memristor is static if no current is applied. If I(t) = 0, we nd V(t) = 0 and M(t) is constant.
The memristor was originally dened in terms of a non- This is the essence of the memory eect.
linear functional relationship between magnetic ux linkThe power consumption characteristic recalls that of a reage (t) and the amount of electric charge that has
sistor, I 2 R.
owed, q(t):[1]
f(
m (t), q(t))
=0
M (q) =
dm
dq
)
(
v RON
q(t)
M (q(t)) = ROFF 1
D2
THEORY
4.2
Memristive systems
One of the resulting properties of memristors and memristive systems is the existence of a pinched hysteresis
eect.[31] For a current-controlled memristive system, the
input u(t) is the current i(t), the output y(t) is the voltage
v(t), and the slope of the curve represents the electrical
resistance. The change in slope of the pinched hysteresis curves demonstrates switching between dierent resistance states which is a phenomenon central to ReRAM
and other forms of two-terminal resistance memory. At
high frequencies, memristive theory predicts the pinched
hysteresis eect will degenerate, resulting in a straight
line representative of a linear resistor. It has been proven
that some types of non-crossing pinched hysteresis curves
(denoted Type-II) cannot be described by memristors.[32]
5.2
4.4
Polymeric memristor
5
an electric eld is applied, the oxygen vacancies drift
(see Fast ion conductor), changing the boundary between
the high-resistance and low-resistance layers. Thus the
resistance of the lm as a whole is dependent on how
much charge has been passed through it in a particular direction, which is reversible by changing the direction of
current.[3] Since the HP device displays fast ion conduction at nanoscale, it is considered a nanoionic device.[38]
One example[33] attempts to extend the memristive systems framework by including dynamic systems incorporating higher-order derivatives of the input signal u(t) as Memristance is displayed only when both the doped layer
a series expansion
and depleted layer contribute to resistance. When enough
charge has passed through the memristor that the ions can
no longer move, the device enters hysteresis. It ceases to
integrate
q=Idt,
but rather keeps q at an upper bound and
d2 u
d4 u
d2m
u
y(t) = g0 (x, u)u(t)+g1 (x, u) 2 +g2 (x, u) 4 +...+gmM
(x,xed,
u) thus
,acting as a constant resistor until current is
2m
dt
dt
dt
reversed.
x = f (x, u)
Memory applications of thin-lm oxides had been an area
where m is a positive integer, u(t) is an input signal, y(t) of active investigation for some time. IBM published an
is an output signal, the vector x represents a set of n state article in 2000 regarding structures similar to that devariables describing the device, and the functions g and scribed by Williams.[39] Samsung has a U.S. patent for
f are continuous functions. This equation produces the oxide-vacancy based switches similar to that described by
same zero-crossing hysteresis curves as memristive sys- Williams.[40] Williams also has a U.S. patent application
tems but with a dierent frequency response than that related to the memristor construction.[41]
predicted by memristive systems.
In April 2010, HP labs announced that they had practical
Another example suggests including an oset value a to memristors working at 1 ns (~1 GHz) switching times and
account for an observed nanobattery eect which violates 3 nm by 3 nm sizes,[42] which bodes well for the future of
the predicted zero-crossing pinched hysteresis eect.[5]
the technology.[43] At these densities it could easily rival
the current sub-25 nm ash memory technology.
y(t) = g0 (x, u)(u(t) a),
x = f (x, u)
5
5.1
Implementations
Titanium dioxide memristor
using organic ion-based memristors.[46] The synapse circuit demonstrated long-term potentiation for learning as
well as inactivity based forgetting. Using a grid of circuits, a pattern of light was stored and later recalled. This
mimics the behavior of the V1 neurons in the primary visual cortex that act as spatiotemporal lters that process
visual signals such as edges and moving lines.
5.3
6 APPLICATIONS
Layered memristor
5.4
Ferroelectric memristor
The ferroelectric memristor[48] is based on a thin ferroelectric barrier sandwiched between two metallic electrodes. Switching the polarization of the ferroelectric
material by applying a positive or negative voltage across
the junction can lead to a two order of magnitude resistance variation: ROFF RON (an eect called Tunnel
Electro-Resistance). In general, the polarization does not
switch abruptly. The reversal occurs gradually through
the nucleation and growth of ferroelectric domains with
opposite polarization. During this process, the resistance
is neither RON or ROFF, but in between. When the
voltage is cycled, the ferroelectric domain conguration
evolves, allowing a ne tuning of the resistance value.
The ferroelectric memristors main advantages are that
ferroelectric domain dynamics can be tuned, oering a
way to engineer the memristor response, and that the resistance variations are due to purely electronic phenomena, aiding device reliability, as no deep change to the
material structure is involved.
5.5
5.5.1
6 Applications
Williams solid-state memristors can be combined into
devices called crossbar latches, which could replace transistors in future computers, given their much higher circuit density.
7
They can potentially be fashioned into non-volatile solidstate memory, which would allow greater data density
than hard drives with access times similar to DRAM,
replacing both components.[13] HP prototyped a crossbar latch memory that can t 100 gigabits in a square
centimeter,[7] and proposed a scalable 3D design (consisting of up to 1000 layers or 1 petabit per cm3 ).[59] In
May 2008 HP reported that its device reaches currently
about one-tenth the speed of DRAM.[60] The devices resistance would be read with alternating current so that
the stored value would not be aected.[61] In May 2012
it was reported that access time had been improved to
90 nanoseconds if not faster, approximately one hundred
times faster than contemporaneous ash memory, while
using one percent as much energy.[62]
Memristor patents include applications in programmable
logic,[63] signal processing,[64] neural networks,[65]
control systems,[66] recongurable computing,[67]
brain-computer interfaces[68] and RFID.[69] Memristive
devices are potentially used for stateful logic implication, allowing a replacement for CMOS-based logic
computation. Several early works in this direction are
reported.[70] [71]
In 2009, a simple electronic circuit[72] consisting of an LC
network and a memristor was used to model experiments
on adaptive behavior of unicellular organisms.[73] It was
shown that subjected to a train of periodic pulses, the circuit learns and anticipates the next pulse similar to the
behavior of slime molds Physarum polycephalum where
the viscosity of channels in the cytoplasm responds to periodic environment changes.[73] Applications of such circuits may include, e.g., pattern recognition. The DARPA
SyNAPSE project funded HP Labs, in collaboration with
the Boston University Neuromorphics Lab, has been developing neuromorphic architectures which may be based
on memristive systems. In 2010, Versace and Chandler described the MoNETA (Modular Neural Exploring Traveling Agent) model.[74] MoNETA is the rst
large-scale neural network model to implement wholebrain circuits to power a virtual and robotic agent using
memristive hardware.[75] Application of the memristor
crossbar structure in the construction of an analog soft
computing system was demonstrated by Merrikh-Bayat
and Shouraki.[76] In 2011 they showed[77] how memristor crossbars can be combined with fuzzy logic to create an analog memristive neuro-fuzzy computing system
with fuzzy input and output terminals. Learning is based
on the creation of fuzzy relations inspired from Hebbian
learning rule.
9 Timeline
9.1 1808
Sir Humphry Davy is claimed by Leon Chua to have
performed the rst experiments showing the eects of a
memristor.[6][81]
9.2 1960
Bernard Widrow coins the term memistor (i.e. memory
resistor) to describe components of an early articial neural network called ADALINE.
9.3 1968
Argall publishes an article showing the resistance switching eects of TiO2 which was later claimed in 2008 to
be evidence of a memristor by researchers from Hewlett
Packard.[37]
9.4 1971
9 TIMELINE
9.7
2009
On May 1 Kim, et al. described a newly discovered memristor material based on magnetite nanoparticles and proOn July 31, Meuels and Soni[20] questioned the appliposed an extended memristor model including both timecability of the concept of a solely current-controlled, nondependent resistance and time-dependent capacitance.[84]
volatile memristor to any physically realizable device.
On July 13 Mouttet described a memristor-based pattern recognition circuit performing an analog variation of
the exclusive nor function. The circuit architecture was 9.11 2013
proposed as a way to circumvent Von Neumann architecture#Von Neumann bottleneck for processors used in On February 27 Thomas et al., demonstrated that a memrobotic control systems.[85]
ristor can be used to mimic a synapse more readily than
On August 4 Choi et al. described the physical realization traditional CMOS technology and be used as the founof an electrically modiable array of memristive neural dation for building physical circuits capable of learning.
The approach utilizes memristors as key components in
synapses.[86]
a blueprint for an articial brain.[94]
On April 23 Valov, et al., argued that the current memristive theory must be extended to a whole new theory
9.8 2010
to properly describe redox-based resistively switching elements (ReRAM). The main reason is the existence of
On April 8 Borghetti, et al. described an array of nanobatteries in redox-based resistive switches which vimemristors demonstrated the ability to perform logical olates the memristor theorys requirement for a pinched
operations.[87]
hysteresis.[5]
On April 20 Memristor-based content addressable memory (MCAM) was introduced.[88]
9.12 2014
demonstrated a
9
new type of exible memristors comprising solution- [9] HP to replace ash and SSD in 2013, 7 October 2011
processed MoO/MoS2 heterostructures stacked with
[10] HP 100TB Memristor drives by 2018 if you're lucky, adprinted silver electrodes on a plastic foil.[47]
mits tech titan, 1 November 2013
9.13 2015
[11] Articial synapses could lead to advanced computer memory and machines that mimic biological brains, HRL Laboratories, March 23, 2012, retrieved March 30, 2012
10
See also
Memistor
Electrical element
List of emerging technologies
Physical neural network
RRAM
11
References
10
11
REFERENCES
[27] Chua, L. O.; Kang, S. M. (1 January 1976), Memristive devices and systems, Proceedings of the IEEE 64 (2):
209223, doi:10.1109/PROC.1976.10092
11
[57] Pershin, Y. V.; Di Ventra, M. (2008), Spin memristive systems: Spin memory eects in semiconductor
spintronics, Physical Review B 78 (11): 113309,
arXiv:0806.2151,
Bibcode:2008PhRvB..78k3309P,
doi:10.1103/PhysRevB.78.113309
[58] Pershin,
Y. V.;
Di Ventra,
M. (2008),
Current-voltage characteristics of semiconductor/ferromagnet junctions in the spin-blockade
regime, Physical Review B 77 (7):
073301,
arXiv:0707.4475,
Bibcode:2008PhRvB..77g3301P,
doi:10.1103/PhysRevB.77.073301
[59] Finding the Missing Memristor - R. Stanley Williams
[60] Marko, J. (1 May 2008), H.P. Reports Big Advance in
Memory Chip Design, New York Times, retrieved 200805-01
[61] Gutmann, E. (1 May 2008), Maintaining Moores law
with new memristor circuits, Ars Technica, retrieved
2008-05-01
[62] Palmer, J. (18 May 2012), Memristors in silicon promising
for dense, fast memory, BBC News, retrieved 2012-05-18
[63] U.S. Patent 7,203,789
[64] U.S. Patent 7,302,513
[65] U.S. Patent 7,359,888
[66] U.S. Patent 7,609,086
[67] U.S. Patent 7,902,857
[68] U.S. Patent 7,902,867
[69] U.S. Patent 8,113,437
[70] Lehtonen, E. (2010), Two memristors suce to compute
all Boolean functions, Electronics Letters 46 (3): 239
240, doi:10.1049/el.2010.3407
[71] Chattopadhyay, A.; Rakosi, Z. (2011), 2011
IEEE/IFIP 19th International Conference on
VLSI and System-on-Chip,
VLSI-SoC: 200,
doi:10.1109/VLSISoC.2011.6081665, ISBN 978-14577-0170-2 |chapter= ignored (help)
[72] Pershin, Y. V.; La Fontaine, S.; Di Ventra, M. (2009), Memristive model of amoeba
021926,
learning, Physical Review E 80 (2):
arXiv:0810.4179,
Bibcode:2009PhRvE..80b1926P,
doi:10.1103/PhysRevE.80.021926
[73] Saigusa, T.; Tero, A.; Nakagaki, T.; Kuramoto, Y. (2008), Amoebae Anticipate PePhysical Review Letters 100
riodic Events,
(1):
018101,
Bibcode:2008PhRvL.100a8101S,
doi:10.1103/PhysRevLett.100.018101, PMID 18232821
[74] Versace, M.; Chandler, B. (2010), MoNETA: A Mind
Made from Memristors, IEEE Spectrum 12 (12): 3037,
doi:10.1109/MSPEC.2010.5644776
[75] Snider, G.; et al. (2011), From Synapses to Circuitry: Using Memristive Memory to Explore the
Electronic Brain, IEEE Computer 44 (2): 2128,
doi:10.1109/MC.2011.48
12
13
12
Further reading
Ronald Tetzla, ed. (2013). Memristors and Memristive Systems. Springer. ISBN 978-1-4614-90685.
Andrew Adamatzky and Leon Chua, ed. (2013).
Memristor Networks. Springer. ISBN 978-3-31902630-5.
Keith Atkin (2013), An introduction to the memristor, Phys. Educ. 48 317 doi:10.1088/00319120/48/3/317. One of the relatively simple experiments described in this paper has been reproduced
by Chris Winstead.
Muthuswamy,
B
et
al.,
"Memristor
Modelling",
IEEE
ISCAS
2014,
doi:10.1109/ISCAS.2014.6865179;
see also
accompanying video/
13
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