Subject - Chemistry B.sc. Part-I (Semester I & II)
Subject - Chemistry B.sc. Part-I (Semester I & II)
Title
I
II
III
I
INORGANIC CHEMISTRY
ORGANIC CHEMISTRY
PHYSICAL CHEMISTRY
PRACTICAL CHEMISTRY
Max.
Sem. Paper Int. Asstt.
Marks
35
26
09
35
26
09
35
26
09
45
16 (Pass Marks)
SEMESTER II
Paper
Title
I
II
III
II
INORGANIC CHEMISTRY
ORGANIC CHEMISTRY
PHYSICAL CHEMISTRY
PRACTICAL CHEMISTRY
Max.
Sem. Paper Int. Asstt.
Marks
35
26
09
35
26
09
35
26
09
45
16 (Pass Marks)
30 hours
Time allowed - 3 hrs
3 period/week
30 hours
Time allowed - 3 hrs
3 period/week
Section - A
I. Structure and Bonding
5 Hrs.
Hybridization, bond lengths and bond angles, bond energy, localized and
delocalized chemical bond, Van der Walls interactions, resonance, hyperconjugation,
aromaticity, inductive and field effects, hydrogen bonding.
II . Mechanism of Organic Reactions
7 Hrs
Curved arrow notation, drawing electron movements with half- headed and
double headed arrows, homolytic and heterolytic bond breaking. Types of reagents of
organic reaction. Energy considerations. Reactive intermediates-bocations,
carbanions, free radicals, carbenes, arynes and nitrenes (with examples). Assigning
formal charges on intermediates and other ionic species.
Methods of determination of reaction mechanism (product analysis,
intermediates, isotope effect, kinetic and stereo-chemical studies).
III. Alkanes
4 Hrs.
Isomerism in alkanes, sources, methods offormation (with special reference to
Wurtz reaction, Kolbe reaction, Corey-House reaction and decarboxylation of
carboxylic acids), physical properties and Mechanism of free radical halogenation of
alkanes: orientation, reactivity and selectivity.
Section B
4. Cyclo alkanes
3 Hrs.
Cycloalkanes--nomenclature, chemical reactions, Baeyer's strain theory and its
limitations. Ring strain in small rings (cyclopropane and cyclobutane), theory of strain
less rings. The case of cyclopropane ring: banana bonds.
5. Stereochemistry of Organic Compounds
12 Hrs.
SEMESTER I
PAPER-III
PHYSICAL CHEMISTRY
Max Marks : 35
Semester Paper : 26
Internal Assessment: 9
Pass Marks : 35%
30 hours
Time allowed - 3 hrs
3 period/week
number, mean free path and collision diameter, Liquifacation of gases (based on
Joule-Thomson effect).
5. Physical Properties and Molecular Structure
4 Hrs.
Optical activity, polarization-(Clausius-Mossotti equation), orientation of
dipoles in an electric field, dipole moment. Induced dipole moment, measurement of
dipole moment temperature method and refractivity method. Dipole moment and
structure of molecules, magnetic properties-paramagnetism, diamagnetism and
ferromagnetism.
PRACTICAL CHEMISTRY - I
SEMESTER I
Max Marks : 45
Passing Marks : 35%
6 Periods / week
10 Marks
Copy
5 Marks
SEMESTER II
PAPER-I
INORGANIC CHEMISTRY
Max Marks : 35
Semester Paper : 26
Internal Assessment: 9
Pass Marks : 35%
30 hours
Time allowed - 3 hrs
3 period/week
SEMESTER II
PAPER-II
ORGANIC CHEMISTRY
Max Marks : 35
Semester Paper : 26
Internal Assessment: 9
Pass Marks : 35%
30 hours
Time allowed - 3 hrs
3 period/week
8 Hrs.
6 Her.
Section B
3. Dienes And Alkynes
7 Hrs.
SEMESTER II
PAPER-III
PHYSICAL CHEMISTRY
Max Marks : 35
Semester Paper : 26
Internal Assessment: 9
Pass Marks : 35%
30 hours
Time allowed - 3 hrs
3 period/week
8 Hrs.
6 Periods / week
10 marks
Laboratory Techniques
Determination of melting points:
Naphthalene, 80-820. Benzoic acid, 121.5-1220
Urea, 132.5-1330, Succinic acid, 184.5-1850.
Cinnamic acid, 132.5-1330, Salicylic acid, 157.5-1580.
Acetanilide, 113.5-1140, m-Dinitrobenzene, 900.
-Dichlorobenzene, 520, Asprin, 1350.
Determination of boiling points
Ethanol, 780, Cyclohexane, 81.40. Tolune, 110.60, Benzene, 800.
Crystallization
concept of induction of crystallization
Phthalic acid from hot water (using fluted filter paper and seamless funnel)
Acetanilide from boiling water
Naphthalene from ethanol
Benzoic acid from water
Physical Chemistry Experiment
20 Marks
Chemical Kinetics
1.
To determine the specific reaction rate of the hydrolysis of methyl
acetate/ethyl acetate catalyzed by hydrogen ions at room temperature.
2.
To study the effect of acid strength on the hydrolysis of an ester.
3.
Viscosity & Surface Tension of pure liquids.
To determine the viscosity and surface tension of C2H5oH and glycerin
solution in water
4.
Molecular weight determined by Part method.
Viva Voce
Copy
10 Marks
5 Marks
10
11