0620 s03 QP 2 PDF
0620 s03 QP 2 PDF
0620 s03 QP 2 PDF
Candidate Number
Name
0620/02
CHEMISTRY
Paper 2
May/June 2003
1 hour
Candidates answer on the Question Paper.
No Additional Materials required
3
4
5
6
TOTAL
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2
1
For
Examiners
Use
II
III
IV
C
Li
Na
K
Fe
Cu
Zn
V
N
VI VII
O
S
F
Cl
Br
0
He
Ne
Ar
Kr
(a) Answer these questions using only the elements shown in the diagram.
Write down the symbol for an element which
(i)
is a transition metal.
(ii)
(iii)
(iv)
(v)
(vi)
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For
Examiners
Use
use
oxygen
in light bulbs
argon
in oxygen tents in
hospitals
chlorine
carbon (graphite)
in balloons
helium
as a lubricant
[4]
Na+
Cl
I
Cl
A
(i)
Cl
Cl Na+
Cl Na+
Na+
Cl
Cl Na+
B
F
F
F
Br
F
C
Explain why compound B does not conduct electricity when solid but does conduct
when molten.
...................................................................................................................................
...............................................................................................................................[4]
0620/02 M/J/03
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4
2
For
Examiners
Use
hydrogen
gas
gas
syringe
small test
tube held by
a piece of
cotton
zinc power
hydrochloric acid
(a) What should the student do to start the reaction?
......................................................................................................................................[1]
(b) The student reads the volume of gas in the syringe every minute.
The results are shown in the table.
(i)
time in minutes
23
35
45
50
53
55
55
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60
50
40
30
20
10
time / min
(ii)
(iii)
Explain why the volume of gas stays the same after six minutes.
...................................................................................................................................
...............................................................................................................................[5]
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For
Examiners
Use
(d) (i) Balance the equation for the reaction between zinc and hydrochloric acid.
Zn
HCl
ZnCl2
H2
[3]
(e) Zinc is an element.
State the meaning of the term element.
......................................................................................................................................
..................................................................................................................................[1]
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7
3
For
Examiners
Use
A ...............................................................................................................................
(ii)
B ...............................................................................................................................
(iii)
C ................................................................................................................................
[3]
(b) Which one of the following best describes the movement of molecules in the liquid
state?
Tick one box.
[1]
(c) Which of the changes A, B or C, is endothermic?
Explain your answer.
..........................................................................................................................................
......................................................................................................................................[2]
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8
(d) Choose from the following list of substances to answer the questions below.
bromine
chlorine
iron
mercury
sodium chloride
sulphur
Name a substance which is
(i)
(ii)
(iii)
rubber bung
The white solid is formed because the molecules of hydrogen chloride gas and
ammonia gas move at random throughout the tube and eventually react with each other.
(i)
(ii)
(iii)
Suggest why the white solid is formed towards one end of the tube and not in the
middle.
...................................................................................................................................
...............................................................................................................................[3]
(f)
What type of chemical reaction takes place when ammonia reacts with hydrochloric
acid?
......................................................................................................................................[1]
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For
Examiners
Use
9
(g) The diagram below shows a simple apparatus that can be used for measuring the
melting point of a solid.
The liquid in the beaker is heated slowly and the temperature at which the solid B melts
is recorded.
For
Examiners
Use
small tube
stirrer
solid B
liquid
heat
(i)
(ii)
(iii)
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4
Catalytic cracking is carried out by oil companies to produce high grade petrol.
The process is carried out using an aluminium oxide catalyst.
The reaction is a type of thermal decomposition.
(a) Explain the meaning of
(i)
thermal decomposition.
...................................................................................................................................
...................................................................................................................................
(ii)
catalyst.
...................................................................................................................................
..............................................................................................................................[2]
C10H22
C8H18
C2H4
(i)
fraction
cracked
hydrogen
methane
ethene
petrol
ethane
10
75
paraffin
15
30
23
diesel
20
17
(ii) Calculate the amount of paraffin fraction needed to make 600g of methane.
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11
(iii) Complete the equation for the cracking of ethane to produce hydrogen and ethene.
C2H6
For
Examiners
Use
[4]
(ii)
Complete the equation below to show the structure of two units in the
poly(ethene) molecule.
H
A precipitate may be formed when two aqueous solutions are mixed. The colour of these
precipitates may be used to identify particular aqueous ions.
(a) Complete the following table.
solution to be added to
test for the ion
colour of precipitate
iron(II)
iodide
chloride
sulphate
[8]
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(b) When a solution of iron(III) chloride is added to a solution of sodium hydroxide, a
precipitate of iron(III) hydroxide is formed and sodium chloride remains in solution.
iron(III) hydroxide
Explain how you would obtain a pure dry sample of sodium chloride from this mixture.
You may use diagrams to help with your explanation.
[3]
(c) Sodium chloride and iron(III) hydroxide are both compounds.
Explain the meaning of the term compound.
..........................................................................................................................................
..................................................................................................................................... [2]
(d) Molten sodium chloride can be electrolysed using graphite electrodes.
Predict the products of this electrolysis
(i)
(ii)
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13
6
For
Examiners
Use
more reactive
less reactive
(a) From this list, choose a metal which is extracted using electrolysis.
......................................................................................................................................[1]
(b) Two thousand years ago, people were able to extract iron and copper from their ores.
They were not able to extract aluminium.
Suggest why they were not able to extract aluminium from its ore.
..........................................................................................................................................
......................................................................................................................................[1]
(c) Uranium is between magnesium and zinc in the reactivity series.
Equal sized strips of magnesium, uranium and zinc were placed in hydrochloric acid.
The hydrochloric acid was the same concentration.
The results are shown in the table.
(i)
uranium
zinc
(ii)
(iii)
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(d) Metals high in the reactivity series react readily with oxygen.
Name the compound formed when magnesium reacts with oxygen.
......................................................................................................................................[1]
(e) Copper is alloyed with tin to make bronze.
(i)
(ii)
(f)
Zn
CO
N2
2NH3
mean?
...................................................................................................................................
(ii)
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15
For
Examiners
Use
(ii)
Explain what happens to the magnesium atom when it reacts and forms a
magnesium ion.
...............................................................................................................................[3]
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Magnesium
Sodium
Calcium
0620/02 M/J/03
Strontium
Rubidium
88
45
89
Actinium
Ac
227
Key
X = atomic symbol
72
Hafnium
Lanthanum
57
178
Hf
40
Zirconium
Zr
91
Titanium
139
Yttrium
89
22
48
Ti
La
39
21
Scandium
Sc
87
Ra
Radium
226
Fr
56
Barium
Caesium
Francium
55
137
Ba
133
Cs
38
Sr
Rb
37
88
85
20
Potassium
19
40
Ca
39
12
24
Mg
23
Na
Beryllium
Lithium
11
Be
II
Li
51
Ta
181
Niobium
Nb
93
90
58
73
52
Mo
96
184
Protactinium
Thorium
55
Tc
186
Re
144
Nd
92
60
Uranium
238
Neodymium
75
Rhenium
43
Technetium
25
Manganese
Mn
27
59
28
59
29
64
30
65
Ru
101
Iron
190
Pm
Osmium
Os
Np
93
Neptunium
61
Promethium
76
44
Ruthenium
26
56
Fe
Sm
150
Iridium
Pu
94
Plutonium
62
152
Eu
Am
95
Americium
63
Europium
78
Platinum
195
Pt
Ir
46
Palladium
Pd
106
Nickel
Ni
192
Samarium
77
45
Rhodium
Rh
103
Cobalt
Co
Gd
157
Gold
Au
197
Silver
96
64
Curium
Cm
Gadolinium
79
47
Ag
108
Copper
Cu
201
Bk
Terbium
Tb
159
Mercury
Hg
97
Berkelium
65
80
48
Cadmium
Cd
112
Zinc
Zn
Dy
162
Thallium
Tl
204
Cf
98
Californium
66
Es
Holmium
Ho
165
Lead
Pb
207
Tin
99
Einsteinium
67
82
50
Sn
Indium
119
115
32
Germanium
Ge
73
Silicon
In
Gallium
Dysprosium
81
49
31
70
Ga
14
28
Si
Carbon
27
Aluminium
13
12
Al
Boron
11
75
Sb
122
Arsenic
As
Bi
209
Fermium
Fm
Erbium
Er
167
Bismuth
100
68
83
51
Antimony
33
15
Phosphorus
31
Nitrogen
14
Se
79
Sulphur
Po
169
Md
Thulium
Tm
101
Mendelevium
69
84
Polonium
52
Tellurium
Te
128
Selenium
34
16
32
Oxygen
16
Yb
173
Astatine
At
Iodine
127
Bromine
Br
80
Chlorine
No
102
Nobelium
70
Ytterbium
85
53
35
17
Cl
35.5
Fluorine
19
Lr
Lutetium
Lu
175
Radon
Rn
Xenon
Xe
131
Krypton
Kr
84
Argon
Ar
40
Neon
103
Lawrencium
71
86
54
36
18
10
Ne
20
Helium
VII
Hydrogen
VI
He
IV
III
1
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).
91
Pa
Th
232
Praseodymium
Cerium
59
141
Pr
140
74
Tungsten
42
Molybdenum
24
Chromium
Cr
Ce
Tantalum
41
23
Vanadium
Group
DATA SHEET
The Periodic Table of the Elements
16
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