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Vlad and Orlandea 2004 - Metallogeny of The GQ
Vlad and Orlandea 2004 - Metallogeny of The GQ
INTRODUCTION
The Gold Quadrilateral (GQ) of the Metaliferi Mts., South Apuseni Mts.,
Romania, was considered at the beginning of the 20th century as an European
Eldorado. Due to its richness, the area has been known for centuries. Early mining
*
th
Lecture partly presented at the XVI Congress of the Carpathian Balkan Geological Association, Vienna,
Austria, 1998.
1
Babe-Bolyai University, Department of Mineralogy, Kogalniceanu 1, 400084 Cluj Napoca, Romania.
works are related to Roman Times. Remnants can be seen nowadays at Roia
Montan, Barza, Stnija and Vlcoi-Bucium. The main commodity has been gold,
exploited from high-grade deposits. During the Middle Ages other deposits were
discovered, such as Scrmb ore deposit, the type locality of five tellurides:
nagyagite, krennerite, petzite, stuetzite, and munthmanite. At the same time, other
metals activated the mining industry, i.e. silver, lead, zinc, copper and mercury.
There is no geological significance concerning the borders of the GQ. They
simply link the extreme North-South and West-East gold mines. Anyway Tertiary
volcanic rocks prevail over the sedimentary molasse and basement rocks inside
tectonically controlled basins of the GQ. The corners of the GQ are located not so
far from small, but famous mining sites such as Brad, Baia de Arie, Zlatna and
Deva (Tschermack, 1868).
The present paper is an attempt at a regional scale reinterpretation of the
Tertiary volcanic related metallogeny of the GQ in terms of sulfur content of the
epithermal systems, redox potential of mineralising fluids and, last but not least, the
connection and deeper passage the through subvolcanic-porphyry environment
associated with the major tectonic setting of ore deposition.
Recent intensive studies of the above mentioned topics belong to Borco
(1994), Vlad (1995), Vlad & Borco (1996, 1998), Udubaa et al. (2001).
New concepts in gold modelling
A modern approach involving epithermal gold deposition might start with
the case of the Wild Dog system in Papua New Guinea. It became famous recently
after the interpretation of the Au-Ag epithermal environment in terms of sulfidation
degree (Ashley, 1982; Sillitoe, 1993). This deposit comprises massive wall rock
silification that contains tellurides and high-sulfidation copper dominated sulfides
associated with sericitic rather than the expected advanced argillic alteration.
The Au-Ag metallogeny of the GQ is not so far from such an unconformable occurrence. In fact, epithermal deposits showing a combination of characteristics from high-sulfidation and low-sulfidation types, suggest generation of fluids
intermediate in composition between those two above mentioned models.
It is widely believed and generally accepted by economic geologists that
high-sulfidation epithermal deposits form in part by interaction of magmatic volatiles
with cooler ground water (Hayba et al., 1985; Hedenquist, 1987; Berger & Henley,
1989; Gammons & Williams-Jones, 1997). As a consequence and in addition to
specific structural-geochemical arguments, the high-sulfidation systems are
proximal to subvolcanic porphyry intrusions (Bonham, 1986; Sillitoe, 1989; White &
Hedenquist, 1995). Rather in a distal position, the low sulfidation systems it have
been divided from the beginning in several subtypes, e.g. alkalic model (Bonham,
1988), hot spring model (Nelson, 1989) and more recently rich sulfide/poor sulfide
models (Silitoe, 1993) or even a kind of transitional term, i.e., intermediate sufidation
(Hedenquist et al., 2000). The last three models refer especially to andesitic terrains
(Silitoe, 1989, 1993, Noble, 1990, Hedenquist et al., 1996, Silitoe & Hedenquist, 2003).
16
Fig. 1. Geological map of the Metaliferi Mountains (South Apuseni Mountains) with the
distribution of the Neogene ore deposits. 1- The famous Golden Quadrilateral of Metaliferi Mts.,
2- Estimated gold production from all the times, since Roman Epoch (millions of ounces).
Sedimentary deposits
Igneous rocks
Quaternary
Quaternary (?) basalts
Neogene
o o
Neogene volcanites
Paleogene
Laramian magmatism (Banatites)
Cretaceous
Eocretaceous magmatites
Permian-Jurassic
Mesozoic ophiolites
CRYSTALLINE BASEMENT
Hydrothermal
Porphyry copper type
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Deposit
Izvorul Ampoiului
Caraci
Cinel
Bia
Bucureci-Rovina
Roia Montan
Barza
Bucium
Scrmb
Hane-Faa Bii-Breaza
Baia de Arie
Alma-Stnija
Troia-Trestia
Hondol
Prul lui Avram
Roia-Poieni
Deva
Host rock
volcano-sediments
andesites
andesites
rhyodacites
andesites
dacites
andesites
andesites
andesites
andesites
andesites, limestones
andesites
andesites
andesites
andesites
andesites
andesites
Metallogenicformations
Hg
Au-Ag
Au-Ag
Au-Ag
Au-Ag;Cu
Au-Ag
Au-Ag(Pb-Zn);Cu-Au
Au-Ag (Pb-Zn);Cu-Au
Au-Ag-Te
Au-Ag-Te;Au-Ag-Pb-Zn
Au-Ag-Te;Pb-Zn
Au-Ag;Au-Ag-Pb-Zn
Pb-Zn;Au-Ag;Cu-Mo
Au-Ag-Pb-Zn
Cu-As
Cu-Mo-As
Cu-Mo
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Table1
Main features of calc-alkaline - andesitic (CAM) and sub-alkalic - rhyodacitic (SRM)
types in the Gold Quadrilateral, South Apuseni Mts.
TYPES
TYPE DEPOSITS
STYLE OF SULFIDES
ABUNDANCE IN
EPITHERMAL SUITE
FORM OF DEPOSITS
KEY PROXIMAL
ALTERATION
MINERALS
MAIN METALS
PRESENT IN
EPITHERMAL SUITE
(MAJOR ELEMENTS)
CAM
SRM
ROIA MONTAN, RODU,
MGURA, CORANDA, PRUL LUI
FRASIN, CONTU, BAIA DE
AVRAM, VOIA, BOLCANA, BUCIUM,
ARIE, MGURA EBII,
ROIA POIENI, MUNCCEASCASCRMB, FAA BII,
POPA, HANE, BARZA.
BIA CRCIUNETI
LOW-SULPHIDATION-RICH
LOW-SULPHIDATION-POOR
SULPHIDE (7-15% S) SYSTEMS SULPHIDE (2-7% S) SYSTEMS
ARE DOMINANT
ARE DOMINANT
BRECCIA PIPE/STOCKWORKS;
SUBORDINATE VEIN SYSTEMS;
OPEN SPACE VEINS /
MASSIVE SULPHIDE VEINS
STOCKWORKS ARE COMMON
AND REPLACEMENT BODIES
MINOR
SERICITE -SMECTITE
SERICITE ADULARIA;
QUARTZ- SERICITE
Au, Ag, Te
HYDROTHERMAL
CONDUIT
BASEMENT TYPE
OPHIOLITE BASEMENT
MINERALIZED
SUBVOLCANIC
ENVIRONMENT
LOCALLY DEVELOPED
BOILING PHENOMENA; NONRESTRICTIVE HYPOGENE
FLUID CIRCULATION
MESOZOIC / CRYSTALLIN
ROCKS
NON- PORPHYRY
ENVIRONMENT, MAGMATICHYDROTHERMAL BRECCIA,
MESOTHERMAL MASSIVE
SULPHIDE VEINS AND
REPLACEMENT BODIES
DIAGNOSTICS OF
ACID MINERAL
ALTERATION
KAOLINITE- ALUNITE
ASSEMBLAGE AS A RESULT OF
SUPERGENE ALTERATION
DOMINANT; LOCALLY
DEVELOPED IN HIGH
SULPHIDATION SYSTEMS OR
SHALLOW ACID ZONE
GOLD SILVER
BETWEEN
RATIO FOR
1:
1 1: 20
EPITHERMAL SYSTEM
MINOR AND
TRACE
As, Te, Se, Ge, Mo, Hg, Bi, Sb, Sn.
ELEMENTS
22
BETWEEN
1: 10 1: 150
Pb, Zn, Cu, Sb, As.
The gold/silver ratio of the epithermal vein suite of this type commonly ranges
between 1:1 and 1:20, showing an important hypogene component of mixed fluids or a
lower rate of erosion (still in the upper part of the epithermal system). The geochemical
signature of the CAM type is featured by As, Te, Se, Ge, Mo, Hg, Bi, Sb, Sn.
Numerous ore deposits of the GQ are to be included in CAM, e.g. Barza, Mgura
Ferag, Coranda, Prul lui Avram-Voia, Troia-Bolcana, Bucium Complex, Roia
Poieni, Muncceasca, Popa Stnija, Hane, etc.
Sub-alkaline rhyodacitic metallogenetical type (SMR)
The SMR type of the GQ is a non-porphyry environment related to rhyolite
rhyodacite-dacite or even andesite rocks with a slightly subalkaline tendency.
This trend is pointed out both in chemistry and the mineralogical-petrographical
pattern of some andesite host rocks, i.e. occurrence of trachyandesite latite,
apparently not related to the mineralizing event (Scrmb, Mgura ebii), or the
presence of Na rich types of ferrous hornblende ferohastingsite (Baia de Arie).
The main feature of SRM is expressed by the low sulfide amount of the
epithermal ore bodies (2-7%) and a reduced to neutral pH of the mineralizing fluids
that suggest a low-sulfidation-poor sulfide type (Fig. 2B).
The main metals of the epithermal suite are Au, Ag and Te. The ore bodies
are breccia pipe structures, stockworks, and subordinately vein systems. Minor
sulfide mesothermal veins and replacement bodies occur at deeper levels, spatially
or genetically associated with subvolcanic to volcanic intrusions. The peripherial
parts of the intrusive are often controlled by phreato-magmatic, hydrothermal or
tectonic brecciation.
The key alteration consists of a typical sericite-adularia assemblage,
developed in a rich silica halo. The circulation of reduced hypogene fluids is not
restricted to sub-alkaline intrusive boundaries and boiling may occur too. However,
shallow (surficial) acid leached zones with alunite, kaolinite, and chlorite are found
in a few deposits (Roia Montan, Mgura ebii). The advanced argillic alteration is
caused this time by the absorption of boiled-off volatiles and subsequent oxidation
of H2S in the vadose zone, near the water table. Advanced argillic alteration caps
develop in the vicinity of low-sulfidation-poor sulfide gold-silver epithermal environment,
related to the SRM type.
In contrast with the CAM type, the gold/silver ratio varies through an extended
interval, i.e. between 1:10 and 1:150 suggesting both a deeper epithermal
environment and an intense rock leaching. The basement is represented by preBaikalian to Hercynian crystalline schists or Mesozoic sedimentary rocks. Minor
elements such as Pb, Zn, Cu, As, and Sb are frequently registered in the SRM
metallogenetical type of the GQ.
The type deposit is the Roia Montan gold bearing breccia pipe and veins.
This is the largest Romanian gold deposit, known and mined since Roman times.
Other deposits such as Bucium Rodu, Frasin, Conu, Mgura ebii, Bia
Crciuneti, Baia de Arie, Scrmb, and Faa Bii may be included in the SRM
type: the last three occurrences are gold-silver tellurides rich.
23
24
Fig. 3. Schematic cross section in calcalkaline andesitic structures (CAM) of the Gold
Quadrilateral: Valea Morii (A), Musariu (B), Muncceasca Podul Ioanului (C) adapted from
Borco et al. (1985), and Mgura Ferag (D) after Orlandea (1992). 1) Intrusion of andesite,
quartz andesite + diorite (Sarm. Pan.); 2) Andesite, quartz andesite (Sarm. Pan.); 3) Miocene
sdimentary and volcanic rocks; 4) Mesosoic sedimentary rocks; 5) Mesozoic island arc volcanites
(Jur. Cret.); 6) argillic alteration; 7) propylitic alteration; 8) potasic alteration; 9) Au Ag and
polymetallic vein mineralization; 10) Fault.
Fig. 4. Geological cross section through non porphyry SRM structures of Gold Quadrilateral:
A- Baia de Arie, B- Roia Montan. 1) Hornblende + quartz + pyroxene andesite (Afini, Ambru,
Colul Lazrului type); 2) Miocene volcano sedimentary formation; 3) Dacite rhyodacite;
4) Phreato magmatic and/or hydrothermal breccia; 5) Cretaceous sediment-tary rocks;
6) Hercynian crystalline limestone; 7) Pre-Alpine metamorphic rocks; 8) Au Ag + Te, As
mineralized stock bodies with sericite adularia halo; 9) Faults, Fractures; 10) Veins;
11) Replacement bodies (Au Ag Pb Zn); 12) Overthrust plane; 13) Drill hole.
28
rhodochrosite, and barite. Native gold is deposited from As rich fluids, i.e. intimately
associated with arsenopyrite. A constant Au/As ratio of 1:2.500 is worth to be
mentioning at Baia de Arie.
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