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ECN Balzers 20april10 AC Falen Presteren
ECN Balzers 20april10 AC Falen Presteren
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Advanced
Technologies
Page 2
2009
Discontinued operations
Page 3
2009
40 Centres
24 Centres
America
Argentina
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USA
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Czech Rep.
Finland
France
Germany
Great Britain
Hungary
Asia
China
India
Indonesia
Japan
Korea
Singapore
Thailand
Page 4
2009
Italy
Poland
Portugal
Romania
Spain
Sweden
Switzerland
Turkey
As of June 2009
Pick-up service
available on request
Page 6
2009
Pick up
Job ordering
Cleaning
Batch loading
Coating
Packaging / dispatch
Page 7
2009
Carbon-based coatings
BALINIT DLC
Hard coatings
BALINIT TRITON
BALINIT DIAMOND
BALINIT ALDURA
BALINIT HELICA
BALINIT ALCRONA
BALINIT CROVEGA
BALINIT C
BALINIT LUMENA
BALINIT X.CEED
BALINIT FUTURA NANO
BALINIT HARDLUBE
BALINIT FUTURA
BALINIT G
BALINIT CAST
BALINIT B
BALINIT D
BALINIT A
TiN
1980
TiCN
TiAlN
1990
WC/C
AlTiN
AlCr
2000
P3eTM
2007
2000
4000
6000
8000
10000
Hardness (HV)
Cutting
Tool life
Productivity
Punching/
forming
Plastics processing
Tool life
Dry running
Mould protection
Shorter cycle times
Die casting
Wear resistance
Gears
Engine components
Hydraulic
Compressor parts
Rocker arm
Injection system
Page 13
2009
Human hair
0.05 mm
Page 15
2009
1
1000
mm
50 - 100 m
coating: 3 4m
Only 0,003 mm
thickness.
Harder then
steel.
Ceramic
properties
Follows surface
structure
exactly.
Ionplating-process
Hot filament cathode
Argon
Reactive gas
Substrates
Substrat
e
< 500C
Low voltage
arc discharge
Vacuum pump
Crucible (Anode)
C.B6.04 (0204) e
Coating material
RCS
BAI1200
Arc evaporation-process
Argon
Reactive gas
< 500C
Substrates
Arc sources
Vacuum pump
C.B6.05 (0204) e
Sputter process
BAI830C
Enhanced Sputter-process
Hot filament cathode
Argon
Reactive gas
< 250C
Substrates
Vacuum pump
Auxiliary anode
C.B6.02 (0304) e
1 m
PVD-coated (BALINIT A)
1 m
CVD-coated
CVD
Procestemperatuur
<500C
850 -1100C
Diffusie
Fijnkorrelig
Grofkorrelig
Onbeduidend
Hoge drukbelasting
Spanningsbelasting
Snijkant hardmetaal
Verzwakt ( fase)
Ja
Neen
Dikte
1 - 4 m
5 - 10 m
Rz>2m
Coatbaarheid cermets
Ja
Neen
Milieuvervuiling
Onbestaande
Verwijdering metaalchloriden
Leap into
a new Dimension
Page 28
2009
ab l e
l
i
a
v
ent a 2/2008
m
p
i
E q u s in c e 1
l
i n Ti e
16
Multilayer
oxide coating
TiAlN base
Thermal stability
Inserts heated at 1000C, 30 minutes, on air
uncoated
TiCN
P3eTM
(Al,Cr)2O3
(Al,Cr)2O3 protects
carbide substrate at
high temperatures
from oxidation
Properties
Deposition temperature
Residual stress of coating
Toughness
Thermal cracks
Maximum coating thickness
-Al2O3
PVD
CVD
P3eTM
500 C
1000 C
500 - 600 C
compressive
tensile
adjustable
high
low
high
no
yes
no
6 m
> 20 m
> 10 m
no
yes
(Al,Cr)2O3
Corundum
X3turn
12
Tool
Insert, CNMG120408
Coating thickness 13 m
10
Workpiece
Steel DIN 1.1221 (~AISI 1060)
Cutting data
f = 0.25 mm/rev
ap = 2 mm
VBmax = 0.3 mm
dry
6
4
CVD Benchmark
Tool manufacturer
X3turn
vc = 175 m/min
vc = 200 m/min
BALINIT DIAMOND
CH4
H2
C
8-10000
Result
0,1
Composition
Microhardness
(HV 0,05)
Coefficient of friction
against aluminium
(dry)
6 - 20
Thickness (m)*
600
Max. temperature of
use (C)
grey
Colour
800
Coatingtemp. (C)
BALINIT DIAMOND
Organic compounds:
2.
Semi-organic compounds:
3.
Graphite
Composites (carbon fibers+epoxy, glass
fibers+polyesters, )
Reinforced plastics, honeycomb, foam,
Sandwich (Glare, carbon-epoxy + Al alloys and/or
Ti, )
MMC (Al bases, Duralcan)
Metallic compounds
PA-CVD- Plasma
Activated Chemical
Vapour Deposition
Chamber
Specially designed
and developed
coatings for the
trimming and forming
of Aluminium parts.
Aluminium parts used
to reduce the weight of
the vehicle and
improve fuel efficiency
bring there own varied
set of production
problems which can
be eliminated with
Balzers VST's a-C:H
coatings.
Metallurgic Laboratory
Extensive testing of
coatings and metals, with
100% quality control of all
treatments and processes
Punching / Forming
Plastics processing
General engineering
68
Hardness [HRC]
Tempering diagram
for steel:
K107
(1.2436)
64
60
Standard coating
temperature
56
ARCTIC coating
temperature
52
48
44
40
0
100
200
300
400
500
600
700
Tempering temperature [C]
120
100
Standard coating
temperature
80
ARCTIC coating
temperature
60
40
0
100
200
300
400
500
600
700
Tempering temperature [C]
Prevention of distortion
0.15
0.1
Standard coating
temperature
0.05
0
ARCTIC coating
temperature
-0.05
-0.1
-0.15
0
100
200
300
400
500
600
700
Tempering temperature [C]
BALINIT D ARCTIC
(CrN)
Hardness 2300 HV
- abrasive wear resistance
- adhesive wear resistance
Hardness 1750 HV
- adhesive wear resistance
- corrosion resistance
- oxidation resistance
BALINIT
FUTURA NANO ARCTIC
(TiAlN)
Hardness 3300 HV
abrasive wear resistance
high thermal stability
high oxidation resistance
high chemical stability
Substrate size/weight:
Coatable material:
Metals like high speed steel, cold and hot working steel, stainless steel, carbide, cermet.
Requirements for hardened steels: tempering temperature > coating temperature
Copper and Aluminium type: please contact us
Coating zone:
Coatable materials
Pre-hardened
steel
Hotwork-
Coldwork
steel
steel
1.2323
1.2083
1.1151
1.2343
1.2316
1.2344
Bronze
1.4002
1.3202
Ampco 8
1.1181
1.4006
1.3207
Ampco 18
1.2362
1.1191
1.4021
1.3243
Ampco 45
1.2360
1.2363
1.1221
1.4028
1.3245
Ampco 83 (300C)
1.2365
1.2369
1.2307
1.4034
1.3247
Ampco 88 (450C)
1.2367
1.2376
1.2311
1.4057
1.3255
Ampco 95 (450C)
1.2567
1.2378
1.2312
1.4110
1.3333
Ampco M4
1.2581
1.2379
1.2738
1.4112
1.3341
1.2603
1.2380
1.6582
1.4116
1.3342
1.2606
1.2436
1.7225
1.4120
1.3343
1.2662
1.2601
1.4122
1.3344
1.2678
1.2609
1.4125
1.3348
1.2709
1.2631
1.4528
1.3355
1.2744
1.2851
1.4542
1.2777
1.3551
1.2799
Stainless
steel
Elmax
Moldmax LH (375C)
M 390 PM
Moldmax HH (315C)
1.2885
CPM 9V
1.2889
CPM 10V
S 390 PM
1.6358
T440V
S 690 PM
Vanadis 4
K190 PM
SMV 5
Miscelannous
Ferro Titanit
Durotherm 600
Hastelloy
TiAl6V4
Hardmetalen
Some examples.
4000
4100 pc.
BALINIT ALCRONA
Tool:
PM-HSS hob
3600
+ 80 %
3200
Workpiece:
Steel, DIN 1.7131 (~ AISI 5115)
2800
2400
2300 pc.
AlTiN / Competitor
Cutting parameters:
vc = 200 m/min
VB ~ 0.3 mm
Dry
2000
Source:
Automotive manufacturer
Page 52
2009
100
Oxidation resistance
Hot hardness
TiCN
Parameters
- End milling
- Finishing
- Coated carbide
- Wet
- VBmax = 0.12 mm
TiAlN
10
200
300
400
Alcrona
TiN
Explanation:
Wear comparison TiN with
Alcrona after 970.000
strokes
tool:
Contour punch
ASP23 (1.3344 HRC 64)
workpiece:
steel sheet C22
thickness 1,25 mm
16
14
12
Process parameter
Frequency: 125 spm
Punch
displacement/stroke: 4mm
10
8
6
4
2
0
TiN
ALCRONA
Ophangbeugel Ford Ka
Materiaal : HLE (High Level Elasticity Steel) 4mm
Gereedschap : 1.2379
Machine : 1600 T - 14 Slag / min
Smering : Pure olie
Bron : Benteler Spanje
Zonder coating
Koudlas van de stempels na 300 000
Balint X-Cell
Na 1 200 000 slagen nog geen slijtage
Nog Steeds in gebruik
Uncoated
BALINIT C
3445
50000
4065
89600
0.07
0.05
28
3.84
38
3.84
0.14
0.10
0.03
0.04
0.07
0.00
0.28
0.15
Savings
46 %
BALINIT A / nitriding
5.000.000
5.000.000
(meanvalues)
number of parts
4.000.000
3.000.000
2.000.000
1.000.000
1.000.000
TIN
TIN / Nitriding
tool:
Knife (dividing)
mat. 1.3344 (62 64 HRC) / Nitriding
polished
workpiece:
1,00 mm sheet - thickness
Mat. KBB S320GD+Z
application:
profiles cutting
source: BFL
Page 58
2009
Valve piston
Poppet valve
Control
piston
Injection
needle
Image source:
Siemens VDO
Page 59
2009
> 250
Temperature: 30 C
Coefficient of friction: 0.004
Roller wear: 5 mg
1.5
1,5
Rings and rollers
BALINIT C coated
uncoated
Bearing 81206
Load: 33 kN
Cage material: PA 66
Speed: 15 rpm
Dry running
Suspension parts
Wrist pins
Con rods
Valves
Camshafts
Pistons
Gear wheels
Page 61
2009
Crank shaft
Breaking out
Plastic deformation
Breakage
Needed
property
Location
Solution
Type of steel +
Heat treatment
Type of steel +
Heat treatment
Abrasive
wear
Resistance against
wear
Surface
Type of steel +
Heat treatment +
coating
Adhesive wear
(Coldwelding)
Lowering friction
+ surface tension
Surface
Surfaceproperties +
coating
Brittle crack
Breaking out
Chipping
pretreatment
necessary
not good
grinded
Turned/milled
Topography
blasted
polished
eroded
Steam temper
nitrided
plasmanitrided
Hartchrom plated
Chem. Nickel
photoetched
Interface
Substrate
- Geometry (e.g. cutting tool edge, topography)
- Substrate (Strength, ductility, roughness)
gasnitrided
bathnitrided
Friction Coefficient
20 m
Rz
optimal
Coating Topography
Rz (m )
0
0,14
0,18
0,2
Ra [m]
0,26
0,34
Ra= 0.04 m
Not acceptable
Ra= 0.1 m
Ra= 0.3 m
Ra= 0.5 m
Ra= 1m
Roughness table
EDM surfaces
EDM surfaces can only be coated when they have had the
right pretreatment (blasting or grinding).
Total removal of the white layer is crucial for tools / parts
that are suffering under high loads .
Microcrack
Pore
White layer
Thermal influenced area
Undamaged microstructure
Microbasting
Surface after
microblasting
Three common processes are usable for steel treatment (salt, gas, plasma).
Plasma nitriding gives the best result to increase hardness.
Its a stable proces which produces clean surfaces (no compound layer)
Meanwhile we are able to combine plasmanitriding and PVD coating in one
process; Balinit Alcrona Advanced.
www.coating-guide.balzers.com
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