Diameter (m) 0.

05
Area(m )
2
0.0019634954
Time (min) 10
Time (hr) 0.1666666667
Working pressure (bar) 1

M0.0 M0.125
Time Permeate volume (mL) Flux (L/m .hr)
2
Permeate volume (mL)
10 112 342.2467896248 136
20 96 293.354391107 128
30 450 82 250.5735424039 116
40 80 244.4619925892 108
50 400 80 244.4619925892 102
60 78 238.3504427744 100
70 Pure water flux76
(L/m/h)
232.2388929597 90
80 350 72 226
90 74 226.127343145
100 74 226.127343145
300
110 74 226.127343145
120 68 207.7926937008
130 250 0
230.19

200

HFO 0% 150 229.50 48.7

HFO 1.5% 0 10 20305.6030 40 50 54.1
60 70 80
HFO 2.91% 310.00 58.1
HFO 5.66% 397.30 Time (min) 72.4

10 20.00 30
20
30
M0.125 M0.25 M0.5
Flux (L/m .hr)
2
Permeate volume (mL) Flux (L/m .hr)
2
Permeate volume (mL)
415.585387402 250 763.943726841 165
391.139188143 140 427.808487031 145
354.469889254 120Fh366.692988884
PSf/ 0% 135
330.023689995 90 354 130
PSf/ 1.5% Fh
311.689040551 90 311 130
PSf/ 2.9% Fh
305.577490736 90 275.019741663 130
275.019741663 PSf/5.7% Fh
90 275.019741663 130
275 90 275.019741663
275 275
275 275
275 275
275 275
0 0

305.58 326.37

60 70 80 90 100

n)

40 50 60 70
M0.5 M1.0 M1.5
Flux (L/m .hr)
2
Permeate vFlux (L/m .hr)
2
Permeate vFlux (L/m2.hr)
504.202859715 465 1420.935 638 1949.584
443.087361568 370 1130.637 370 1130.637
412.529612494 280 855.617 298 910.6209
397.250737957 235 718.1071 252 770.0553
397.250737957 205 626.4339 222 678.382
397.250737957 160 488.924 198 605.0434
397.250737957 0 180 550.0395
397 0 0
397 0 0
397 0 0
397 0 0
397 0 0
0 0 0
702.83
397.25 611.15

80 90
 MO M0.125 M0.25 M0.5 M1.0
Wet weight(g) 0.0927 0.1077 0.0925 0.0979 0.135
Dry weight (g) 0.019 0.0263 0.028 0.031 0.0408
Thickness (cm) 0.01 0.014 0.013 0.011 0.012
Area (cm2) 10.179 10.752 10.179 10.463 10.752

POROSITY (g/g) 0.72404 0.540763 0.487429 0.581269 0.730097

Porosity (%) 72.4 54.07 48.74 58.12 73
Wettability () 70.53 62.45 52.98 43 16.94
M1.5 0
1 2 3 4 5 6
0.1376 -0.1
0.0436 -0.2
0.011
-0.3
9.621
-0.4
Porosity (%)
0.888209 -0.5
Wettability ()
88.8 -0.6
8.02
-0.7
-0.8
-0.9
-1
Porosity (%)
Wettability ()
BET: 233.49 m2/g

CONTACT ANGLE
READING M0 M0.125 M0.25 M0.5
1 68.8 59 50.17 43
2 67.2 63.8 53.61 43
3 73.5 62 54.14
4 73.3 65 52.02
5 71 53.48
6 52.11
7 52.12
8 56.22
9
AVERAGE 70.53 62.45 52.98 43
M1.0 M1.5
28 13
29 10
8 8.6
9.4 13
10.3 7.1
3.7
5.7
3.1

16.94 8.02
 Volume
Diameter (m) 0.05
Area(m2) 0.001963
Time (min) 10
Time (hr) 0.166667
Working pressure (bar) 0.5

M1.5
Time Permeate volume (mL) Time
10 10
20 20
30 180 30
60 94 60
90 45 90
120 49 120
150 61 150
180 180
210 210
240 240
270 270
300 300
330 330
360 360
390 390
420 420
COMPACTION 1.5BAR 30 MINUTES, DATA TAKEN EVERY 30 MINUTES, 0.3 BAR

M1.5
Permeate volume (mL)
Adsorpstion for M 1.5

after Capacity
Before adsorption Volume
adsorption Mass (g) adsorption
(C0) (mg/L) (L)
(Ce) mg/L (mg/g)
0.4 0.192 0.05 0.05 0.208
5 0.3 0.05 0.05 4.7
10 0.59 0.05 0.05 9.41
15 2.8 0.05 0.05 12.2
optimum concentra
35 21.8 0.05 0.05 13.2
45 37 0.05 0.05 8

Capacity ad
15
LANGMUIR ISOTERM

after adsorption 10
q (mg/g) Ce/q
(Ce)
1/ce 1/qecapacity adsorption (mg/g)
0 0.4 0 5.2 4.8 5
0.3 4.7 0.06383 3.3 0.2
0.59 9.41 0.062699 1.7 0.12 0
2.8 12.2 0.229508 0.4 0.08 0 5
21.8 13.2 1.651515 0.05 0.07 in
37 8 4.625 0.03 0.13

Langmuir
5

4
f(x) = 0.1154618643x - 0.0971099186
3 R = 0.9509216207
Column C
Ce/q Linear (Column C)
2

0
0 5 10 15 20 25 30 35 40

q (mg/g)
Conclusion :

Compared their regresion (R^2) : the best is Langmuir with regresion 0.896, this indicated that your
chemisorption is when your heavy metal adsorpted only 1 layer in your membrane surface, so if y
Search mechanism chemiso
Compared their regresion (R^2) : the best is Langmuir with regresion 0.896, this indicated that your
chemisorption is when your heavy metal adsorpted only 1 layer in your membrane surface, so if y
Search mechanism chemiso
 optimum concentration for capacity adsortion for your membrane is 35 mg/L, ,if u increased your initial conce
capacity adsorption again and again

Capacity adsorption
15
FREUNDLICH ISOTERM
after
10 adsorption q (mg/g) Log Ce Log q
ption (mg/g) (Ce)
5 0.192 0.208 -0.716699 -0.681937
0.3 4.7 -0.522879 0.672098
0 0.59 9.41 -0.229148 0.97359
0 5 10 2.8 15 20 25 30 12.2
35 40 45 50
0.447158 1.08636
initial21.8
concentration13.2
(mg/L) 1.338456 1.120574
37 8 1.568202 0.90309

Freundlich
1.5

f(x) = 0.4334111665x
1 + 0.5427925311
mn C R = 0.375508983
ar (Column C) 0.5 Column K
Log q Linear (Column K)
0
-1 -0.5 0 0.5 1 1.5 2
-0.5

-1

Log Ce

is indicated that your heavy metal adsorpted in your membrane with chemisorption mechanism. Mechanism of
brane surface, so if you increase your heavy metal concentration, it will decresed your capacity adsorption. ---
h mechanism chemisorption in internet
 u increased your initial concentration it will be decreased your
and again

TEMPKIN ISOTERM
after
adsorption In Ce q (mg/g)
(Ce)
0.192 -1.65026 0.208
0.3 -1.203973 4.7
0.59 -0.527633 9.41
2.8 1.029619 12.2
21.8 3.08191 13.2
37 3.610918 8

Tempkin
14
12
f(x) = 1.4710938585x + 6.8887661173
10
R = 0.455811204
8 Column R
q 6 Linear (Column R)
olumn K 4
near (Column K) 2
0
-2 -1 0 1 2 3 4

In Ce

n mechanism. Mechanism of
your capacity adsorption. ---
mn R
ar (Column R)
 1.EFFECT OF Ph
WEIGHT MEMBRANE:0.05G
VOL:50ML IC: 60 PPM
MEMBRANE:M1.5
HFO HNT
Ph FC (mg/L) RE (%) FC (mg/L) RE (%)
2 37.3 37.8 36.87 38.5
4 33 45 32.46 45.8
6 24.8 58.7 24.05 59.9
7 3.08 94.9
8 4.2 93 2.4 96
10 0.1 99.8 0.3 94

3.KINETIC STUDIES
WEIGHT MEMBRANE:0.05G
VOL:50ML IC: 15 PPM
MEMBRANE:M1.5
TIME INTERVAL (MIN) FC (mg/L) RE (%) qt
0.08 14.3 4.7 0.7
0.166 12.35 17.7 2.65
0.5 12.29 18.1 2.7
1 11.07 26.2 3.9
2 10.42 30.5 4.6
4 10.2 32 4.8
6 9.3 38 5.7
8 8.7 42 6.3
10 8.8 41.3 6.2
12 8.6 43 6.4
18 2.9 81 10.8
24 2.9 81 12.1
36 2.2 85 13
48 2.2 85 13
 3.KINETIC STUDIES
WEIGHT MEMBRANE:0.05G
VOL:50ML IC: 15 PPM
MEMBRANE:M1.5
TIME INTERVAL (MIN) FC (mg/L) RE (%) qt
0.08 14.3 4.7 0.7
0.166 12.35 17.7 2.65
0.5 8.1 18.1 6.9
1 5.5 26.2 9.5
2 4.73 30.5 10.27
4 3.54 32 11.46
6 3.57 38 11.43
8 3.42 42 11.58
10 2.84 41.3 12.16
12 2.8 43 12.2
18 2.85 81 12.15
24 2.82 81 12.18
36 2.83 85 12.17
48 2.9 85 12.1
M0.125 29.3
35 M0.5 28.5
M1.5 21.8
M0.125 39
45 M0.5 38
M1.5 37
 2.EFFECT OF DIFFERENT INITIAL CONCENTRATION/ADSORPTION ISOTHERM
MASS M 0.05
VOL 0.05
Ph:6.5

IC(mg/L) MEMBRANE FC (mg/L) RE (%)

M0.125 -0.144 100
0.4 M0.5 -0.178 100
M1.5 -0.192 100
M0.125 0.49 90.2
5 M0.5 0.4 92
M1.5 0.3 94
M0.125 2.9 71
10 M0.5 1.008 89.9
M1.5 0.59 94.1
M0.125 9.3 38
15 M0.5 8.6 43
M1.5 2.8 81.3
M0.125 29.3 16.3
35 M0.5 28.5 18.6
M1.5 21.8 37.7
M0.125 39 13.3
45 M0.5 38 15.6
M1.5 37 17.7

ADSORPTION STUDY: qe=(Co-Ce)V/

0.08 A
2.65 2.65 0.166 2.65
2.7 2.7 0.33 2.7
3.9 3.9 1 3.9
4.6 4.6 2 4.6
4.8 4.8 4 4.8
5.7 5.7 6 5.7
6.3 6.3 8 6.3
6.2 6.2 10 6.2
6.4 6.4 12 6.4
8.3 8.3 16 8.3
10.8 12.1 18 10.8
12.1 13.5 24 12.1
13.5 13.9 28 13.5
 13.7 14.5 32 13.7
13.9 36 13.9
14.5 48 14.5

RE (%) Qe=mg/g ce/qe

100 0.4 0
100 0.4 0
100 0.4 0
100 4.51 0.11
92 4.6 0.09
94 4.7 0.06
71 7.1 0.27
89.9 8.992 0.11
94.1 9.41 0.06
38 5.7 1.63
43 6.4 1.34
81.3 12.2 0.23
16.3 5.7 5.14
18.6 6.5 4.38
37.7 13.2 1.65
13.3 6 6.5
15.6 7 5.42
17.7 8 4.63
ATION/ADSORPTION ISOTHERM

BARU EDIT
Pb (II) concentratio PSf/HFO-M0PSf/HFO-M0.25
mg/L
Qe=mg/g 5 4.51 4.55
0.4 10 7.1 8
0.4 15 6.5 7
0.4 35 6.2 6.7
4.51 45 6 6.5
4.6
4.7
7.1
8.992
9.41
5.7
6.4
12.2
5.7
6.5
13.2
6
7 14
8
12

10

Qt (mg/g)
6

0
0 5 10 15 20
Tim
0
0 5 10 15 20
Tim
 PSf/HFO-M0PSf/HFO-M1PSf/HFO-M1.5

4.6 4.65 4.7

8.9 9.15 9.4
8 9.3 12.2
7.3 9.85 13.2
7 7.5 8

15 20 25 30 35 40 45 50
Time (h)
15 20 25 30 35 40 45 50
Time (h)
M0.125
Before after
Capacity
adsorptio adsorptio Volume
Mass (g) adsorptio
n (C0) n (Ce) (L)
n (mg/g)
(mg/L) mg/L LANGMUIR ISOTERM
after
0.4 0.05 0.05 0.4 adsorptio q (mg/g)
0 n (Ce)
5 0.49 0.05 0.05 4.51 0 0.4
15 9.3 0.05 0.05 5.7 0.49 4.51
35 29.3 0.05 0.05 5.7 9.3 5.7
45 39 0.05 0.05 6 29.3 5.7
39 6

M0.25

Before after
Capacity
adsorptio adsorptio Volume
Mass (g) adsorptio
n (C0) n (Ce) (L)
n (mg/g)
(mg/L) mg/L LANGMUIR ISOTERM
after
0.4 0.05 0.05 0.4 adsorptio q (mg/g)
0 n (Ce)
5 0.45 0.05 0.05 4.55 0 0.4
15 8 0.05 0.05 7 0.45 4.55
35 28.3 0.05 0.05 6.7 8 7
45 38.5 0.05 0.05 6.5 28.3 6.7
38.5 6.7
38.5 6.7

M0.5

Before after
Capacity
adsorptio adsorptio Volume
Mass (g) adsorptio
n (C0) n (Ce) (L)
n (mg/g)
(mg/L) mg/L LANGMUIR ISOTERM
after
0.4 0.05 0.05 0.4 adsorptio q (mg/g)
0 n (Ce)
5 0.4 0.05 0.05 4.6 0 0.4
10 1.01 0.05 0.05 8.99 0.4 4.6
15 8.6 0.05 0.05 6.4 1.01 8.99
35 28.5 0.05 0.05 6.5 8.6 6.4
45 38 0.05 0.05 7 28.5 6.5
38 7
M1.0
Before after
Capacity
adsorptio adsorptio Volume
Mass (g) adsorptio
n (C0) n (Ce) (L)
n (mg/g)
(mg/L) mg/L LANGMUIR ISOTERM
after
0.4 0.05 0.05 0.4 adsorptio q (mg/g)
0 n (Ce)
5 0.35 0.05 0.05 4.65 0 0.4
10 0.85 0.05 0.05 9.15 0.35 4.65
15 5.7 0.05 0.05 9.3 0.85 9.15
35 25.15 0.05 0.05 9.85 5.7 9.3
45 37.5 0.05 0.05 7.5 25.15 9.85
37.5 7.5

Adsorpstion for M 1.5

Before after
Capacity
adsorptio adsorptio Volume
Mass (g) adsorptio
n (C0) n (Ce) (L)
n (mg/g)
(mg/L) mg/L LANGMUIR ISOTERM
after
0.4 0.192 0.05 0.05 0.208 adsorptio q (mg/g)
n (Ce)
5 0.3 0.05 0.05 4.7 0.19 0.208
10 0.59 0.05 0.05 9.41 0.3 4.7
15 2.8 0.05 0.05 12.2 0.59 9.41
35 21.8 0.05 0.05 13.2 2.8 12.2
45 37 0.05 0.05 8 21.8 13.2
37 8
 M0.125
7

6 f(x) = 0.1685687738x + 0.027292891

R = 0.9991812788
5
Ce/q M0.125
4 Linear (M0.125)
0 3
0.1
2
1.6
5.1 1
6.5 0
0 5 10 15 20 25 30 35 40 45

M0.25
6
f(x) = 0.1482921863x - 0.0113726986
5
Ce/q R = 0.9997835022
M0.25
4
Linear (M0.25)
0
3 Linear (M0.25)
0.1
1.1 2
4.2
1
5.7
5.7 0
0 5 10 15 20 25 30 35 40 45

M0.5
6

5 f(x) = 0.145829452x + 0.0254314379

Ce/q R = 0.9972038114
M0.5
4
Linear (M0.5)
0
3 Linear (M0.5)
0.1
0.11 2
1.3
1
4.4
5.4 0
0 5 10 15 20 25 30 35 40
 2

0
0 5 10 15 20 25 30 35 40

M1
6

Ce/q 5
f(x) = 0.1259154421x - 0.0645698325 M1
4
0 R = 0.9810264653 Linear (M1)
0.07 3 Linear (M1)
0.1
2
0.6
2.6 1
5
0
0 5 10 15 20 25 30 35 40

5
4.5
4 f(x) = 0.118574873x - 0.0837121735
R = 0.9788492974
3.5
3
Ce/q Column I
2.5
1/qmKL qmax Linear (Column I)
0 2
0.1335 -1.423221 Linear (Column I)
0.06 1.5-4.081633
0.1335
0.07 0.13351-9.291339
0.2 0.1335
0.5 42.10526
2 0.1335 11.67961
0
4.6 0.1335 8.283891
0 5 10 15 20 25 30 35 40
 14

12

10

8
M0.125
Linear (M0.125) 6

0
0 5 10 15 20 25 30 35 40 45

M0.25
Linear (M0.25)
Linear (M0.25)

M0.5
Linear (M0.5)
Linear (M0.5)

40
40

M1
Linear (M1)
Linear (M1)

40

Column I
Linear (Column I)
Linear (Column I)
 M0.125
M0.25
M0.5
M1.0
M1.5

35 40 45 50
M0.125 f(x) = 0.0621649888x + 0.6782616489
M0 R = 0.9447812069 0.
after
adsorptio q (mg/g) 0.80
n (Ce) LOG CE LOG Q
0 0.4 0.75
0.49 4.51 -0.31 0.65
0.70
9.3 5.7 0.97 0.76
29.3 5.7 1.47 0.76
0.65
39 6 1.59 0.78
0.60

0.55
-0.50 0.00 0.50 1.00

M0.25 M0.125
after
adsorptio q (mg/g)
n (Ce) LOG CE LOG Q
0 0.4 0.00 -0.40 1.00
0.45 4.55 -0.35 0.66 f(x) = 0.7891003288x - 0.26644
0.80
R = 0.8632426785
8 7 0.90 0.85
0.60
28.3 6.7 1.45 0.83
38.5 6.7 1.59 0.83 0.40
38.5 6.7 1.59 0.83 0.20
0.00
0.00 0.20 0.40 0.60 0.80 1
-0.20

M0.5 M0.25 -0.40

after -0.60
adsorptio q (mg/g)
n (Ce) LOG CE LOG Q
0 0.4 0.00 -0.40
f(x) = 0.1291055038x + 0.7704189634
R = 0.6424781179
8.6 6.4 0.93 0.81
28.5 6.5 1.45 0.81 1.20
38 7 1.58 0.85
1.00

0.80

0.60
M1.0 M1.0
after 0.40
adsorptio q (mg/g)
n (Ce) LOG CE LOG Q 0.20

0.00
-1.00 -0.50 0.00 0.50
 0.40

0.20
0 0.4 0.00
0.35 4.65 -0.46 0.67 -1.00 -0.50 0.00 0.50
0.85 9.15
5.7 9.3 0.76 0.97
25.15 9.85 1.40 0.99
37.5 7.5 1.57 0.88

M1.5 M1.5
after
adsorptio q (mg/g)
n (Ce) LOG CE LOG Q
0.19 0.208
0.3 4.7 -0.52 0.67
0.59 9.41
2.8 12.2 0.45 1.09
21.8 13.2 1.34 1.12
37 8
49888x + 0.6782616489
2069 0.125 M0.
0.90
0.80
f(x) = 0.0849220798x + 0.7083043021
R0.70
= 0.8077241589
0.125
0.60
Linear (0.125)
0.50
Linear (0.125)
0.40
0.30
0.20
0.10
0.00
.00 0.50 1.00 1.50 2.00 -0.50 0.00 0.50 1.00

0.5
) = 0.7891003288x - 0.2664469965
= 0.8632426785
0.5
Linear (0.5)
Linear (0.5)

0.20 0.40 0.60 0.80 1.00 1.20 1.40 1.60 1.80

f(x) = 0.2436769336x + 0.857110679

55038x + 0.7704189634 R = 0.8257643173
1179 1 1.20
1.20
1.00
1.00
0.80
1
0.80
Linear (1) 0.60
0.60 Linear (1)
0.40
0.40
0.20
0.20

0.00 0.00
50 0.00 0.50 1.00 1.50 2.00 -1.00 -0.50 0.00 0
 Linear (1)
0.40
0.40
0.20
0.20

0.00 0.00
50 0.00 0.50 1.00 1.50 2.00 -1.00 -0.50 0.00 0
 M0.25

849220798x + 0.7083043021
77241589
M0.25
Linear (M0.25)
Linear (M0.25)

0.50 1.00 1.50 2.00

6769336x + 0.857110679
643173 1.5
1.20

1.00
1.5
0.80 Linear (1.5)
Linear (1.5)
0.60 Linear (1.5)
Linear (1.5)
0.40

0.20

0.00
-0.50 0.00 0.50 1.00 1.50
 Linear (1.5)
0.40

0.20

0.00
-0.50 0.00 0.50 1.00 1.50
 EFFECT OF INITIAL CONCENTRATION 14
M0 M0.125 M0.25 M0.5 M1.0 M1.5
ADSORPTION CAPACIT 0.4 0.4 0.4 0.4 120.4 0.4
5 4.51 4.55 4.6 4.65 4.7
15 6.8 7.5 8.3 109.3 12.2
35 6.2 6.7 7.3 9.85 13.2
45 6 6.5 7 87.5 11.5
80
Adsorption capacity (mg/g)
6
Initial concentration M0 M0.125 M0.25 M0.5 M1.0 M1.5
0.4 100 100 100 100
4
100
5 90.2 91 92 93 94
10 45
2
15
35
0
45 0 5 10 15 20 25 3
Initial concentration (

3.KINETIC STUDIES
WEIGHT MEMBRANE:0.05G
VOL:50ML IC: 15 PPM
MEMBRANE:M1.5 TIME
TIME INTERVAL (MIN) FC (mg/L) RE (%) qt 0.08
0.08 14.3 4.7 0.7 0.166
0.166 12.35 17.7 2.65 0.33
0.33 12.29 18.1 2.7 1
1 11.07 26.2 3.9 2
2 10.42 30.5 4.6 4
4 10.2 32 4.8 6
6 9.3 38 5.7 8
8 8.7 42 6.3 10
10 8.8 41.3 6.2 12
12 8.6 43 6.4 24
24 2.9 81 12.1 48
48 2.2 85 13

TIME QT LN(QT) 1/QT T/QT LN (QE-QT)

0.08 0.7 -0.4 1.429 0.1 2.51
0.166 2.65 1.0 0.377 0.1 2.34
0.33 2.7 1.0 0.370 0.1 2.33
1 3.9 1.4 0.256 0.3 2.21
2 4.6 1.5 0.217 0.4 2.13
4 4.8 1.6 0.208 0.8 2.10
6 5.7 1.7 0.175 1.1 1.99
8 6.3 1.8 0.159 1.3 1.90
10 6.2 1.8 0.161 1.4 1.80
12 6.4 1.9 0.156 1.5 1.70
24 12.1 2.5 0.083 2.0 -0.11
48 13 2.6 0.077 3.8 0.00

TIME QT LN(QT) 1/QT T/QT LN (QE-QT)

0.08 0.7 -0.4 1.429 0.1 2.51
0.166 2.65 1.0 0.377 0.1 2.34
0.33 2.7 1.0 0.370 0.1 2.33
1 3.9 1.4 0.256 0.3 2.21
2 4.6 1.5 0.217 0.4 2.13
4 4.8 1.6 0.208 0.8 2.10
6 5.7 1.7 0.175 1.1 1.99
8 6.3 1.8 0.159 1.3 1.90
10 6.2 1.8 0.161 1.4 1.80
12 6.4 1.9 0.156 1.5 1.70
24 12.1 2.5 0.083 2.0 0.00
48 13 2.6 0.077 3.8 0.00

PSEUDO FIRST :LN (QE-QT)

3.00

2.50

2.00 f(x) = - 0.0565501098x + 2.2954322764

LN (QE-QT)
R = 0.8577483578
Linear (LN (QE-QT))
1.50

1.00

0.50

0.00
0 10 20 30 40 50 60
5 10 15 20 25 30 35 40 45 50
Initial concentration (mg/L)

TIME QT T/QT QE-QT

QT LN(QT) 1/QT 0.08 0.7 0.11 13.8
0.7 -0.4 1.429 0.166 2.65 0.06 11.85
2.65 1.0 0.377 0.33 2.7 0.12 11.8
2.7 1.0 0.370 1 3.9 0.26 10.6
3.9 1.4 0.256 2 4.6 0.43 9.9
4.6 1.5 0.217 4 4.8 0.83 9.7
4.8 1.6 0.208 6 5.7 1.05 8.8
5.7 1.7 0.175 8 6.3 1.27 8.2
6.3 1.8 0.159 10 6.2 1.61 8.3
6.2 1.8 0.161 12 6.4 1.88 8.1
6.4 1.9 0.156 16 8.3 1.93 6.2
12.1 2.5 0.083 14.5
13 2.6 0.077 24 12.1 1.98 2.4
28 13.5 2.07 1
32 13.7 2.34 0.8
36 13.9 2.59 0.6
N (QE-QT)

PSEUDO SECOND ORDER

E-QT)
4.0
f(x) = 0.0747801472x + 0.3489024391
3.0 R = 0.9485256124

T/QT
LN (QE-QT) 2.0
Linear (T/QT
Linear (LN (QE-QT))
1.0

0.0
0 10 20 30 40 50 60

t (h)

0
LN (QE-QT)LN QT
2.624669 -0.4
2.472328 1.0
2.4681 1.0
2.360854 1.4
2.292535 1.5
2.272126 1.6
2.174752 1.7
2.104134 1.8
2.116256 1.8
2.091864 1.9
1.824549 2.1
2.674149
0.875469 2.5
0 2.6
-0.223144 2.6
-0.510826 2.6
DER

T/QT
Linear (T/QT)

60
REGENERATION STUDY

DIAMETER=25 CM2 COMPACTION= 30 MINS AT 1.0 BAR

SOLUTION = LEAD (II) PRESSURE= 0.5 BAR
PH=6.5-7 FLOW= 1ML/MIN
SOAKING IN NAOH=2 HOURS VOLUME=*4LITER
MEMBRANE USED= M1.5 INITIAL CONC=0.1PPM/100PPB

MINUTE VOLUME (ML) CE (mg/L) 1

30 0 0 2
60 82 3
10090 53 4
120 60 5
150
80 61 6
180 59 7
210 62 8
60
240 59 9
270 65 10
300
40 55 11
330 45 12
360 60 13
20
390 14
420 15
0
450 155 16
4800 500 1000 75 1500 2000 2500 3000 3500 4000
17 4500
510 35 18
540 19
570 20
600
S AT 1.0 BAR

volume ug/L volume ug/L

200 0.5 20 1 200 0.5
100
400 0.5 40 2 400 0.5
600 0.5 60 3 600 1
800 2.4
80 80 4 800 0.7
1000 0.6 100 5 1000 0.7
1200 0.6 6 1200 0.6
60
1400 2.4 7 1400 1
1600 2.2 8 1600
1800 40 9 1800 5.8
2000 3.8 10 2000 5.8
2200 0.5
20 11 2200 6
2400 0.6 12 2400 1.2
2600 4.6 13 2600 4.3
0
2800 14 2800 6.8
0 500 1000 1500 2000 2500 3000 3500 4000 4500
3000 1 15 3000 6.8
3200 2.8 16 3200 4.3
500 4000 4500
3400 0.5 17 3400 0.5
3600 1.8 18 3600 14.5
3800 0.5 19 3800 14.7
4000 3.9 20 4000 16.1
3500 4000 4500
2.EFFECT OF DIFFERENT INITIAL CONCENTRATION/ADSORPTION ISOTHERM
MASS M 0.05
VOL 0.05
Ph:6.5

IC(mg/L) MEMBRANE FC (mg/L) RE (%) Qe=mg/g

M0.125 -0.144 100 0.4
0.4 M0.5 -0.178 100 0.4
M1.5 -0.192 100 0.4
M0.125 0.49 90.2 4.51
5 M0.5 0.4 92 4.6
M1.5 0.3 94 4.7
M0.125 2.9 71 7.1
10 M0.5 1.008 89.9 8.992
M1.5 0.59 94.1 9.41
M0.125 9.3 38 5.7
15 M0.5 8.6 43 6.4
M1.5 2.8 81.3 12.2
M0.125 29.3 16.3 5.7
35 M0.5 28.5 18.6 6.5
M1.5 21.8 37.7 13.2 14
M0.125 39 13.3 6
12
45 M0.5 38 15.6 7
M1.5 37 17.7 8 10

0
0 5 10 15 20
 m0.125 m0.5 m1.5
0 0.4 0 0.4 0 0.4
0.49 4.51 0.4 4.6 0.3 4.7
2.9 7.1 1 8.99 0.59 9.41
9.3 5.7 8.6 6.4 2.8 12.2
29.3 5.7 28.5 6.5 21.8 13.2
39 6 38 7 37 8

M0.125
M0.5
m1.5

5 10 15 20 25 30 35 40 45
 3.KINETIC STUDIES TIME INTERVAL (MIN)
QT
WEIGHT MEMBRANE:0.05G 0.08 0.70
VOL:50ML IC: 15 PPM 0.166 2.60
MEMBRANE:M1.5 0.33 6.90
TIME INTERVAL (MIN)
FC (mg/L) RE (%) qt 1 9.50
0.08 14.3 4.7 0.7 2 10.30
0.166 12.4 17.7 2.65 4 11.46
0.33 8.1 46 6.9 6 11.43
1 5.5 63 9.5 8 11.60
2 4.73 68.5 10.27 10 12.16
4 3.54 76.4 11.46 12 12.18
6 3.57 76.2 11.43 18 12.15
8 3.4 77.3 11.6 24 12.18
10 2.84 81 12.16 36 12.18
12 2.8 43 12.2 48 12.17
18 2.85 81 12.15
24 2.82 81 12.18
36 2.82 81 12.18
48 2.83 81.1 12.17

14

12 4.5000
4.0000
10 R ==0.9995862343
f(x) 0.081011154x + 0.0364844979
3.5000

8 3.0000
2.5000
Column D
6 t/qt 2.0000
1.5000
4
1.0000
2 0.5000
0.0000
0
0 10 20 30 40
0 10 20 30 40 50 60
t (h)
 LOG (QE-QT) 1/QT T/QT LN (QE-QT)
1.0599 1.429 0.1143 2.51
0.9814 0.385 0.0638 2.34
0.7226 0.145 0.0478 1.81
0.4281 0.105 0.1053 1.25
0.2742 0.097 0.1942 0.99
-0.1427 0.087 0.3490 0.43
-0.1249 0.087 0.5249 0.45
-0.2366 0.086 0.6897 0.34
-1.6990 0.082 0.8224 -0.17
Err:502 0.082 0.9852 -0.20
-1.5229 0.082 1.4815 -0.16
1.00
Err:502 0.082 1.9704 -0.20
Err:502 0.082 2.9557 -0.20
0.50
-2.0000 0.082 3.9441 -0.19R = 0.7889766284
0.00

-0.50
log (qe-qt)
0.08 1.06
0.166 0.98
0.33 0.72 -1.00
1 0.43
2 0.27 -1.50
64844979 4 -0.14
6 -0.12 -2.00
8 -0.24 0 10 20 30 40
Time (h)
18 -1.52
48 -2.00

30 40 50 60

t (h)
 30 40 50 60
Time (h)
 M0.125
after
IC (Co) adsorptio q (mg/g) Log Ce Log q Ce/q Ln qe Ln Ce
n (Ce)

5.00 0.49 4.51 -0.31 0.65 0.11 1.5062972 -0.7133499

10.00 2.90 7.10 0.46 0.85 0.41 1.7 1.06471074
15.00 9.30 5.70 0.97 0.76 1.63 1.7404662 2.2300144
35.00 29.30 5.70 1.47 0.76 5.14 1.7404662 3.37758752
45.00 39.00 6.00 1.59 0.78 6.50 1.7917595 3.66356165

M0.25
IC (Co) after
adsorptio q (mg/g) Log Ce Log q Ce/q Ln qe Ln Ce
n (Ce)
0.40 0.00 0.40 0.00
5.00 0.45 4.55 -0.35 0.66 0.10 1.515 -0.799
10.00 2.00 8.00 0.30 0.90 0.25 1.700 0.693
15.00 9.00 6.00 0.95 0.78 1.50 1.792 2.197
35.00 29.00 6.00 1.46 0.78 4.83 1.792 3.367
45.00 29.50 15.50 1.47 1.19 1.900 3.384
4.5
M0.5
IC (Co) after
adsorptio q (mg/g) Log Ce Log q Ce/q Ln qe Ln Ce
n (Ce)
0.40 0.00 0.40 0.00
5.00 0.40 4.60 -0.40 0.66 0.09 1.5260563 -0.9162907
10.00 1.00 9.00 0.00 0.95 0.11 1.7 0
15.00 8.60 6.40 0.93 0.81 1.34 1.856298 2.1517622
35.00 28.50 6.50 1.45 0.81 4.38 1.8718022 3.34990409
45.00 38.00 7.00 1.58 0.85 5.43 1.9459101 3.63758616

M1.0
IC (Co) after
adsorptio q (mg/g) Log Ce Log q Ce/q Ln qe Ln Ce
n (Ce)
0.40 0.00 0.40 0.00
5.00 0.35 4.65 -0.46 0.67 0.08 1.54 -1.05
10.00 0.77 9.23 -0.11 0.97 0.08 1.80 -0.26
15.00 4.30 10.70 0.63 1.03 0.40 2.10 1.46
35.00 25.10 9.90 1.40 1.00 2.54 2.29 3.22
45.00 38.50 6.50 1.59 0.81 4.00 2.30 3.65

M1.5
IC (Co) after
adsorptio q (mg/g) Log Ce Log q Ce/q Ln qe Ln Ce
n (Ce)
0.40 0.00 0.40 0.00
5.00 0.30 4.70 -0.52 0.67 0.06 1.55 -1.20
10.00 0.59 9.41 -0.23 0.97 0.06 1.90 -0.53
15.00 2.80 12.20 0.45 1.09 0.23 2.40 1.03
35.00 21.80 13.20 1.34 1.12 2.00 2.58 3.08
45.00 37.00 8.00 1.57 0.90 3.50 2.50 3.61
 7

ce/qe
3
M-
0.125
2
Linear
1 (M-
0.125)

0
0 5 10 15 20 25 30 35 40 45

Ce (mg/L)

2.5

1.5
ln qe

0.5
 1.5
ln qe

0.5

0
-2 -1 0 1
ln ce 2 3
 M-
0.125

Linear
(M-
0.125)

35 40 45

M-
0.125

Linear
 M-
0.125

Linear
(M-
0.125)

2 3 4
calibration
1.4
conc Abs
200 0.284 1.2
f(x) = 0.00112
400 0.539
1
600 0.782
800 1 0.8
1000 1.175
0.6

M0 0.4

0.2

0
100 200 300 400 5
1.4

1.2
f(x) = 0.0011215x + 0.0831
1

0.8 Column B
Linear (Column B)
0.6
Linear (Column B)
0.4

0.2

0
100 200 300 400 500 600 700 800 900 1000 1100
NMOs size SSA pH dosage adsorption capacity
HMO 2.1 359
TiO2 3.8 185.5
HAl2O3 1.9 411 401.14
ZnO2 20-May 147 6.7
CeO2 260 72 9.2
Nanoscale z 30-Oct 24.4 5.25-6.05 1
dsorption capacity