Safety Data Sheet

Revision Number: 001.0 Issue date: 11/03/2014

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: ARMSTRONG A-2 RESIN IDH number: 2007998
Product type: Epoxy resin Item number: 2008000_1960697
Restriction of Use: None identified Region: United States
Company address: Contact information:
Henkel Corporation Telephone: (860) 571-5100
One Henkel Way MEDICAL EMERGENCY Phone: Poison Control Center
Rocky Hill, Connecticut 06067 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING: CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.

HAZARD CLASS HAZARD CATEGORY

SKIN IRRITATION 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1

PICTOGRAM(S)

Precautionary Statements

Prevention: Avoid breathing vapors, mist, or spray. Wash thoroughly after handling. Contaminated work
clothing should not be allowed out of the workplace. Wear eye and face protection. Wear
protective gloves.
Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. If
skin irritation or rash occurs: Get medical attention. If eye irritation persists: Get medical
attention. Take off contaminated clothing.
Storage: Not prescribed
Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local
governmental regulations.

Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous Component(s) CAS Number Percentage*

IDH number: 2007998 Product name: ARMSTRONG A-2 RESIN

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Aluminum oxide, fibrous 1344-28-1 30 - 60
Epoxy resin Proprietary 30 - 60
Epoxy resin Proprietary 5 - 10
Aluminium hydroxide 21645-51-2 5 - 10
Epoxy resin Proprietary 1-5
1,6-Hexanediol diacrylate 13048-33-4 1-5
Titanium dioxide 13463-67-7 0.1 - 1

* Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections.

4. FIRST AID MEASURES

Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. If symptoms develop and persist, get medical attention.

Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove
contaminated clothing and footwear. If symptoms develop and persist, get
medical attention. Wash clothing before reuse. Thoroughly clean shoes before
reuse.

Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get
medical attention.

Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel.

Never give anything by mouth to an unconscious person. Get medical
attention.

Symptoms: See Section 11.

5. FIRE FIGHTING MEASURES

Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.

Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as
turn-out gear.

Unusual fire or explosion hazards: Closed containers may rupture (due to build up of pressure) when exposed to
extreme heat. In case of fire, keep containers cool with water spray.

Hazardous combustion products: Oxides of carbon. Phenolics. Toxic fumes. Irritating vapors.

6. ACCIDENTAL RELEASE MEASURES

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.

Environmental precautions: Do not allow product to enter sewer or waterways.

Clean-up methods: Ensure adequate ventilation. Wear appropriate personal protective equipment.
Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up.
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder,
universal binder, sawdust). Scrape up spilled material and place in a closed
container for disposal.

IDH number: 2007998 Product name: ARMSTRONG A-2 RESIN

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 7. HANDLING AND STORAGE
Handling: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist.
Wash thoroughly after handling. Use only with adequate ventilation. Keep
container closed.

Storage: Keep container tightly closed and in a cool, well-ventilated place away from
incompatible materials. Keep away from heat, spark and flame. Protect from
direct sunlight.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER

5 mg/m3 PEL
1 mg/m3 TWA Respirable fraction.
Aluminum oxide, fibrous None None
Respirable fraction. 15 mg/m3 PEL Total
dust.
Epoxy resin None None None None
Epoxy resin None None None None
10 mg/m3 TWA (as 15 mg/m3 TWA (as
Al) Total dust. Al) Total dust.
Aluminium hydroxide None None
1 mg/m3 TWA 5 mg/m3 TWA (as Al)
Respirable fraction. Respirable fraction.
Epoxy resin None None None None
0.11 ppm (1 mg/m3)
1,6-Hexanediol diacrylate None None None
TWA (Skin sensitizer)
15 mg/m3 PEL Total
Titanium dioxide 10 mg/m3 TWA None None
dust.

Engineering controls: Use local ventilation if general ventilation is insufficient to maintain vapor
concentration below established exposure limits.

Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure
limit(s).

Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should
be used if the potential for splashing or spraying of product exists. Safety
showers and eye wash stations should be available.

Skin protection: Use chemical resistant, impermeable clothing including gloves and either an
apron or body suit to prevent skin contact.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Viscous, Liquid
Color: Off white
Odor: Mild
Odor threshold: Not available.
pH: Not available.
Vapor pressure: Not determined
Boiling point/range: Not determined
Melting point/ range: Not available.
Specific gravity: 1.8
Vapor density: Not available.
Flash point: > 93.33 °C (> 199.99 °F) ASTM D3278 Setaflash Closed Cup
Flammable/Explosive limits - lower: Not available.
Flammable/Explosive limits - upper: Not available.
Autoignition temperature: Not available.
Evaporation rate: Not available.
Solubility in water: Slightly soluble
Partition coefficient (n-octanol/water): Not available.

IDH number: 2007998 Product name: ARMSTRONG A-2 RESIN

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 VOC content: Not available.
Viscosity: Not available.
Decomposition temperature: Not available.

10. STABILITY AND REACTIVITY

Stability: Stable under normal conditions of storage and use.

Hazardous reactions: None under normal processing.

Hazardous decomposition Oxides of carbon. Phenolics. Toxic fumes. Irritating vapors.

products:

Incompatible materials: Oxidizing agents. Acids. Bases. Amines. Ethylene oxide. Chlorine trifluoride.

Reactivity: Not available.

Conditions to avoid: Keep away from heat, ignition sources and incompatible materials. Protect from direct sunlight.

11. TOXICOLOGICAL INFORMATION

Relevant routes of exposure: Skin, Inhalation, Eyes

Potential Health Effects/Symptoms

Inhalation: Inhalation of vapors or mists of the product may be irritating to the respiratory system.
Skin contact: Causes skin irritation. May cause allergic skin reaction.
Eye contact: Causes serious eye irritation.
Ingestion: Not expected under normal conditions of use. May cause gastrointestinal tract irritation if
swallowed.

Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects
Aluminum oxide, fibrous None Irritant, Nuisance dust, Corrosive
Epoxy resin None Irritant, Allergen
Epoxy resin None Allergen, Irritant
Aluminium hydroxide Oral LD50 (RAT) = > 5,000 mg/kg Irritant, Lung, Respiratory
Epoxy resin None Allergen, Irritant
Oral LD50 (RAT) = 5 g/kg
1,6-Hexanediol diacrylate Irritant, Allergen
Dermal LD50 (RABBIT) = 3,600 mg/kg
Irritant, Respiratory, Some evidence of
Titanium dioxide None
carcinogenicity

OSHA Carcinogen
Hazardous Component(s) NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
Aluminum oxide, fibrous No No No
Epoxy resin No No No
Epoxy resin No No No
Aluminium hydroxide No No No
Epoxy resin No No No
1,6-Hexanediol diacrylate No No No
Titanium dioxide No Group 2B No

12. ECOLOGICAL INFORMATION

Ecological information: Not available.

IDH number: 2007998 Product name: ARMSTRONG A-2 RESIN

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 13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.

Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.

Hazardous waste number: Not a RCRA hazardous waste.

14. TRANSPORT INFORMATION

The transport information provided in this section only applies to the material/formulation itself, and is not specific to any
package/configuration.

U.S. Department of Transportation Ground (49 CFR)

Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

International Air Transportation (ICAO/IATA)

Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

Water Transportation (IMO/IMDG)

Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

15. REGULATORY INFORMATION

United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12 (b) Export Notification: None above reporting de minimis

CERCLA/SARA Section 302 EHS: None above reporting de minimis

CERCLA/SARA Section 311/312: Immediate Health, Delayed Health
CERCLA/SARA Section 313: This product contains the following toxic chemicals subject to the reporting requirements of
section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40
CFR 372). Aluminum oxide, fibrous (CAS# 1344-28-1).

California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This
product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.

Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.

16. OTHER INFORMATION

This safety data sheet contains changes from the previous version in sections: First issue.

Prepared by: Rebecca Pasco, Regulatory Affairs Specialist

Issue date: 11/03/2014

IDH number: 2007998 Product name: ARMSTRONG A-2 RESIN

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 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.

IDH number: 2007998 Product name: ARMSTRONG A-2 RESIN

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