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Nsec Solved Past Paper 2007
Nsec Solved Past Paper 2007
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CH3 Q.12 Arange the following compounds in order of
(A)
CH3 decreasing reactivity in the elimination
H 3C (bimolecular) reaction with C2H5ONa
CH3
(B)
CH3
Br I Cl F
H 3C
CH3 I II III IV
(A) II > I > III > IV (B) IV > III > I > II
(C)
(C) III > I > II > IV (D) I > III > IV > II
H 3C CH3
CH3 Q.13 Indicate the order of reactivity of the
(D) CH3 following compounds in nucleophilic
H 2C substitution (unimolecular) reaction.
Q.11 Indiacate the correct order of acidity (first Q.15 Repeating isoprene units are present in
ionization) in the following dicarboxylic (A) alkaloids (B) peptides
acids : (C) nucleic acids (D) terpenoids
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Q.18 The carbocation (CH3)3C+ is stabilized HO
primarily by Cl
(A) hyperconjugation (B) tautomerism (A)
(C) resonance (D) conjugation
OH
(B)
Q.19 Predict the product formed in the following
reaction HO
(C)
Product
AlCl3
OH
OH
(D)
(A) (B)
Q.23 Fullerenes are generated on a very repid scale
typically in milliseconds. In all techniques.
Cl Cl C60 is produced in much greater quantites
than C180 though latter is more stable. Which
(C) (D) of the following graph represents the
following two processes ?
Reaction coordinate
(C) (D) (B)
X o Y
NaOH ( aq ) Reaction coordinate
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Q.24 Consider the following reactions Q.27 The correct order of acidicty of the C–H
Cl proton is -
(A) acetylene > ethylene > ethane
CH 3 I
M m L m
LDA
NaH
o (B) ethylene > acetylene > ethane
273 K 298 K (C) ethane > ethylene > acetylene
(D) acetylene > ethane > ethylene
X CH3I
o Y
(LDA = lithiumdiisopropyl amide) Q.28 In the petroleum industry, crude oil is
The products M and Y respectively are separated into different fractions by
O (A) differential extraction
O
(B) fractional distillation
(C) chromatography
(A) and (D) leaching
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Q.34 In which of the following compounds is the Q.42 According to molecular orbital theory, the
oxidation number of the transition metal zero ? oxygen molecule is -
(A) [Ni(CO)4] (A) Diamagnetic (B) Paramagnetic
(C) Ferromagnetic (D) Non magnetic
(B) [Pt(C2H4)Cl3]
(C) [Co(NH3)6]Cl2
(D) [Fe(H2O)3](OH)2 Q.43 Which of the following has zero dipole
Q.35 As the number of electrons in d orbitals of moment ?
trasnsition elements increases, the screening (A) NH3 (B) NF3 (C) BF3 (D) CHCl3
effect on the valence electrons -
Q.44 Thallium forms stable chloride, TICl, unlike
(A) increases Aluminum which forms chloride AlCl3. This
(B) decreases greatly is because :
(C) is not observed (A) Insert pair effect makes TI+ more stable
(D) decreases slightly than Tl3+
(B) TI is not a group 13 element
Q.36 [NiCl4]2 is paramagnetic and therefore its (C) TI-X bond is covalent while Al-Cl bond
is ionic.
geometry is
(D) TI-X bond is ionic while Al-Cl bond is
(A) pyramidal (B) bi-pyramidal covalent
(C) tetrahedral (D) square planar
Q.45 Which two of the following reactions are
possible ?
Q.37 The magnetic moment of MnSO4.4H2O is :
(i) 2FeCl3 + SnCl2 o2FeCl2 + SnCl4
(A) 1.73 BM (B) 3.87 BM
(ii) 2FeCl2 + SnCl4 o2FeCl3 + SnCl2
(C) 4.90 BM (D) 5.92 BM (iii) PbCl2 + SnCl4 oSnCl2 + PbCl4
(iv) SnCl2 + PbCl4 oPbCl2 + SnCl4
Q.38 dsp2 hybridization represnts (A) i and ii (B) i and iii
(A) octahedral geometry (C) i and iv (D) ii and iv
(B) square-planar geometry
Q.46 Silicones are water repelling in nature
(C) trigonal-bipyramidal geometry because -
(D) square-pyramidal geometry (A) they have highly covalent Si-O-Si
linkages
Q.39 Which type of bond exists between the two (B) they have organic groups forming
boron atoms in a diborane molecule ? hydrophobic exterior.
(A) 2-center-2-electron (C) they are polymeric in nature.
(D) they have Si-H bonds as in hydrocarbons
(B) 2-center-3-electron
(C) 3-center-3-electron Q.47 Which of the following compounds is most
(D) 4-center-4-electron basic in nature ?
(A) Si(OH)4 (B) Al(OH)3
(C) Mg(OH)2 (D) P(OH)3
Q.40 Which isomerism is exhiliated by
[Co(NH3)6][Cr(CN)6] and [Cr(NH3)6][Co(CN)6] ? Q.48 Aqueous solutions having equimolar
(A) Ionization (B) Linkage quantities of Pb(NO3)2, AgNO3,AgSO4,
(C) Coordination (D) Polymerization BaCl2 and K2CrO4 are allows react and the
reaction mixture is then altered. Which ions
will be present in the filtrate in appreciable
Q.41 The complex pentaamincarbonatocobalt (III)
quantity
chloride is (A) Pb2+,Ag+,Ba2+,K+,NO3 ,SO42 CrO42 Cl
(A) [Co(NH3)5CO3]Cl (B) Ba2+,K+,NO3 ,CrO42
(B) [Co(NH2)5CO3]Cl (C) Pb2+,Ba2+,K+,NO3 ,CrO42
(C) [Co(NH2)5CO2]Cl (D) K+, NO3
(D) [Co(NH3)5CO2]Cl
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Q.49 Concentrated sulphuric acid on reaction with Q.54 What is the correct order of stability of the
NaCl, NaBr and Nal produces HCl, bromine complexes,
and iodine, respectively. What order of [Ni(NH3)6]2+, [Ni(en)3]2+, [Ni(DET)2]2+ ?
oxidizing of halogens with reference of [en = 1,2 diaminoethane, H2NCH2CH2 NH2
sulphuric acid can be established on the basis DET = Diethylenetriamine,
H2NCH2CH2NHCH2NH2]
of this reaction
(A) Ni(NH3)6]2+ |[Ni(en)3]2 |[Ni(DET)2]2+
(A) H2SO4 > I2 > Br2 > Cl2
(B) Ni(NH3)6]2+ <[Ni(en)3]2+ |[Ni(DET)2]2+
(B) Cl2 > H2SO4 > Br2 > I2
(C) Ni(NH3)6]2+ <[Ni(en)3]2+ <[Ni(DET)2]2+
(C) H2SO4 > Cl2 > Br2 > I2
(D) Ni(NH3)6]2+ >[Ni(en)3]2+ >[Ni(DET)2]2+
(D) Cl2 > Br2 > I2 > H2SO4
Q.55 How many isomers are possible for a
Q.50 According to the Crystal field theory, the compound with formula, [Rh(en)Cl(NO2)] ?
energy of dxy orbital is lower than d x 2 y 2 in (A) 2 (B) 4 (C) 6 (D) 8
an octahedral complex because Q.56 Metal carbonyls have the metal ions in zero
(A) the dxy orbital is near the ligands. or unusually lower oxidation states. This is
(B) the repulsion between the dxy electrons because
and ligand electrons is less than that (A) carbonyl ligand is reducing in nature
(B) carbonyl is a highly electron rich ligand
between d x 2 y 2 and ligand electrons
(C) carbonyl is a strongly V-bonding ligand
(C) the repulsion between the dxy electrons (D) carbonyl is a strongly S-acidic ligand
and ligand electrons is more than that
between d x 2 y 2 and ligand electrons. Q.57 Europium forms stable Eu2+ ions because
(A) Europium is a lanthanide
(D) the d x 2 y 2 orbital is away from the ligands (B) 2+ is the common oxidation state of
lanthanides
Q.51 The orbitals of iron involved in the (C) Eu2+ has f7 valence electronic
hybridization in Fe(CO)5 are configuration
(D) All of the above reasons
(A) s, px, px, pz and d x 2 .y 2
(B) s, px, px, d z 2 and d x 2 .y 2 Q.58 Which of the following molecules contains
the maximum% of sulphur by mass ?
(C) s, px, py, pz and d z 2 (A) Na2SO4 (B) H2SO4 (C) Li2SO4 (D) PbSO4
(D) s, px, pz, dxy and d x 2 y 2 Q.59 17.1 grams of aluminum sulfate, Al2(SO4)3 is
dissolved in enough water to prepare 1.00 L
Q.52 The crystal filed stabilization energy (CFSE) of solution. What the molarity of the sulfate
in [Co(SCN)6]3 is ion in this solution ? (Neglect any hydrolysis)
(A) 1.67 × 10 2 M (B) 5.00 × 10 2 M
(A) –24 Dq (B) –18 Dq
(C) 1.50 × 10 1 M (D) 2.50 × 10 1 M
(C) –4 Dq (D) 0 Dq
Q.60 Calculate the pH of a solution made by
Q.53 Element having (4,0,0, + 1/2) as a set of four mixing 150 cm3 of 0.10 M CH3COONa and
quantum numbers for its valence electron is - 250 cm3 of 0.10 CH3COOH
(A) Na (B) Ca [Ka of CH3COOH = 1.8 × 10 5]
(C) K (D) Br (A) 2.37 (B) 4.52
(C) 4.74 (D) 4.97
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Q.61 The solubility product constant, Ksp, of Q.67 Assuming a lawis structure for SO2 in which
Ag3PO4 is 1.8 × 10 18. What is the molar all the atoms obey the octet rule, the formal
solubility of Ag3PO4 in water (neglect any charge on S is :
hydrolysis) (A) + 1 (B) 0 (C) +2 (D) –2
(A) 1.6 × 10 5 (B) 8.4 × 10 7
Q.68 Which of the following will have the slowest
(C) 1.3 × 10 9 (D) 4.5 × 10 19
rate of reactin with HCl ?
(A) Marble chips at 40°C
Q.62 Chlorine can be prepared by reacting HCl
(B) Powdered marble at 25°C
with MnO2. The reaction is represented by the (C) Marble chips at 25°C
equation (D) Powdered marble at 40°C
MnO2(s) + 4HCl(aq) oCl2(g) + MnCl2(aq) +
2H2O(l) Q.69 How many moles of Na+ ions are there in
Assuming the reaction goes to completion. 20mL of 0.40 M solution of Na3PO4 ?
What mass of concentrated HCl solution (A) 0.008 (B) 0.020 (C) 0.024 (D) 0.008
(36.0% HCl by mass) needed to produce 2.50 g
of Cl2 Q.70 The solubility of a gas in a liquid is directly
proportional to the partial pressure of the gas
(A) 5.15 g (B) 14.3 g
over the solution. This statement is known as :
(C) 19.4 g (D) 26.4 g
(A) Raoult's law
Q.63 In the unit cell of the crystal formed by the (B) Henry's law
(C) Boyle's law
ionic compound of X and Y, the corners are
(D) Charales and Gay lussac's law
occupied by X and Y centers of the faces by
Y. The empirical formula of the compound is : Q.71 How many sigma bons and pi bonds are
(A) XY (B) X2Y present in CH2=C=CH2 ?
(C) XY3 (D) X5Y6 (A) 6 sigma and 1 pi
(B) 8 sigma and 0 pi
Q.64 Which of the following pairs is a lewis acid &
(C) 4 sigma and 4 pi
lewis base ? (D) 6 sigma and 2 pi
(A) Cl & Ag+ (B) NH3 & BF3
2
(C) SO4 & HSO4 (D) H+ & OH Q.72 A first-order reaction has a rate constant of
0.003 s 1. The time required for completion of
Q.65 In which of the following reactions will an 75% reaction is
incease system favor the formation of the (A) 231 s (B) 201 s (C) 41.7 s (D) 462 s
products ?
(A) C(s) + H2O(g) CO(g) + H2(g) Q.73 The activaton energy of a reaction is given by
(B) H2(g) + I2 (g) 2HI(g) (A) –R/(slope of a plot of ln k vs. 1/T)
(C) 4NH3(g) + 5O2(g) 4NO(g) + 6H2O(g) (B) – (slope of a plot of ln k vs. 1/T) R
(C) – (slope of a plot of ln k vs. 1/T) × R
(D) 3O2(g) 2O3(g)
(D) + (slope of a plot of ln k vs. 1/T) × R
Q.66 What is the total pressure inside 2L vessel Q.74 The activation energy
containing 1g of He, 14g of CO and 10g of (A) decreases with increasing temperature
NO at 27°C ? (B) increases with increasing temperature
(A) 0.25 atm (B) 13.2 atm (C) remains constant with temperature
(C) 1.24 atm (D) 21.6 atm (D) shows linear relation (with positive slope)
with temperature
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Q.75 Which of the following is not a colligative Q.81 The pH of a 0.01 M solution of ammonium
property ? acetate can be changed by changing
(A) solubility (A) the temperature
(B) vapor pressure lowering (B) the volume of solution
(C) boiling point elevation (C) the concentration
(D) osmotic pressure
(D) the pressure on solution
Q.76 Which of the following has the lowest
freezing point and the highest bolling point ? Q.82 Which of the following represents the true
(A) 1.5 m magnesium phosphate order of dissociation energy of the indicated
(B) 1.0 m sodium chloride C–H bond of the following molecules ?
(C) 1.5 m aluminum nitrate
(D) 1.5 m calcium chloride
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Q.86 For the reaction shown below, wich statement Q.94 Presence of higher number of GC pairs in a
is true ? DNA molecule makes it more stable at
2Fe + 3 CdCl2 2FeCl3 + 3Cd (A) high temperature
(A) Fe is the oxidizing agnet (B) low temperature
(B) Cd undergoes oxidation (C) high pH
(C) Cd is the reducing agent (D) high salt concentration
(D) Fe undergoes oxidation
Q.95 A polypeptide chain with 60 amino aicds
Q.87 The voltage for the cell : Fe/Fe2+ (0.001M) // residue will have …….. number of
Cu2+ (0.10 M)/ Cu2+ (0.10 M)/ Cu is 0.807 V nucleotides in its DNA ?
at 25° C. What is the value of E° ? (A) 60 (B) 120 (C) 180 (D) 360
(A) 0.629 V (B) 0.689 V
(C) 0.748 V (D) 0.866 V Q.96 Electrophoretic mobility (without change in
Q.88 A current of 2.0 A is used to plate Ni(s) from primary structure) of a multi-subunit protein
500mL of a 1.0 M Ni2+ aqueous solution. sample with interchain disulfide bond will be
What is the [Ni2+] after 3.0 hours ? affected if it is treated with
(A) 0.39 M (B) 0.46 M (A) performic acid (B) typsin
(C) 0.78 (D) 0.89 V (C) NaCl (D) CNBr
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ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25
Ans. A B B D C D B C B B C A B C D C D A B B C C A C C
Que. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
Ans. B A B D A B C B A A C D B B C A B C A D B C D B B
Que. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
Ans. C A C C C D C B C B A B C D A B A C C B D D C A A
Que. 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100
Ans. A D A C D A A B D D D C C C B B D D A D A B D A B
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