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XtraedgeFebruary 2012
XtraedgeFebruary 2012
Editor :
Editorial
Dear Students,
Pramod Maheshwari
[B.Tech. IIT-Delhi]
All of us live and work within fixed patterns. These patterns and habits
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aware of how much we influence others, how productive we are and
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Owned & Published by Pramod
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Maheshwari, Published & Printed at 112,
Pramod Maheshwari,
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B.Tech., IIT Delhi
Editor : Pramod Maheshwari
AIEEE & BIT-SAT Mock Test Paper with Solution IITian ON THE PATH OF SUCCESS 5
Dr. Amitabha Ghosh
KNOW IIT-JEE 6
Previous IIT-JEE Question
Study Time........
DYNAMIC PHYSICS 14
S
8-Challenging Problems [Set # 10]
Students’ Forum
Success Tips for the Months Physics Fundamentals
• If one asks for success and prepares for Matter Waves, Photo-electric Effect
Thermal Expansion, Thermodynamics
failure, he will get the situation he has
prepared for.
CATALYSE CHEMISTRY 29
• Loser's visualize the penalties of failure.
Key Concept
Winner's visualize the rewards of success. Carbonyl Compound
Co-ordination Compound &
• Treat others as if they were what they
Metallurgy
ought to be and you help them to become Understanding : Physical Chemistry
what they are capable of being.
DICEY MATHS 36
• You never achieve real success unless you
Mathematical Challenges
like what you are doing
Students’ Forum
• The first step toward success is taken when Key Concept
you refuse to be a captive of the Integration
environment in which you first find Trigonometrical Equation
yourself.
Test Time ..........
• Believe in yourself ! Have faith in your
abilities ! without a humble but reasonable XTRAEDGE TEST SERIES 47
confidence in your own powers you can not Class XII – IIT-JEE 2012 Paper
be successful or happy. Class XI – IIT-JEE 2013 Paper
Mock Test-3 (CBSE Board Pattern) [Class # XII] 68
Solution of Mock Test-2 & 3 (CBSE Pattern)
equilibrate. Calculate the pressure of each gas at 5H2O + CuSO 4 → CuSO 4 .5H 2 O
800 K. [IIT- 1989] White Blue
Sol. Since to start with SO2 is not present, it is expected ZnSO4 + 2NaOH → Zn(OH)2 + Na2SO4
that some of SO3 will decompose to give SO2 and
O2 at equilibrium. If 2x is the partial pressure of Zn(OH)2 + 2NaOH → Na2ZnO2 (soluble) + 2H2O
SO3 that is decreased at equilibrium, we would Also in excess of NH4OH it forms soluble
have complex [Zn(NH3)4](OH)2.
2SO2(g) + O2(g) 2SO3(g)
t=0 0
teq 2x
2 atm
2 atm + x
1 atm
1 atm – 2x
MATHEMATICS
(p SO3 ) 2 (1 atm − 2 x ) 2 11. If f (x) is twice differentiable function such that
Hence, Kp = 2
= 2 f (a) = 0, f (b) = 2, f (c) = 1, f (d) = 2, f (e) = 0,
(p SO 2 ) (p O 2 ) (2x ) (2 atm + x )
where a < b < c < d < e, then the minimum number
= 900 atm–1 of zero's of g(x) = {f ' (x)}2 + f '' (x). f (x) in the
Assuming x << 2 atm, we get interval [a, e] is? [IIT-2006]
(1 atm − 2x ) 2 d
2
= 900 atm–1 Sol. Let, g(x) = [f (x) . f '(x)]
(2x ) (2 atm) dx
to get the zero of g(x) we take function
(1 atm − 2x ) 2
or = 1800 h(x) = f (x). f ' (x)
(2x ) 2
between any two roots of h(x) there lies at least
1 atm one root of h' (x) = 0
or – 1 = 42.43
2x ⇒ g(x) = 0 ⇒ h(x) = 0 ⇒ f (x) = 0 or f ' (x) = 0
1 If f (x) = 0 has 4 minimum solutions.
or x = atm = 0.0115 atm
2 × 43.43 f ' (x) = 0 has 3 minimum solutions.
Hence, p(SO2) = 2x = 0.023 atm; h(x) = 0 has 7 minimum solutions.
p(O2) = 2atm + x = 2.0115 atm and ⇒ h' (x) = g(x) = 0 has 6 minimum solutions
p(SO3) = 1 atm – 2x = 0.977 atm 12. The position vectors of the vertices A, B and C of a
10. A white substance (A) reacts with dil. H2SO4 to ^ ^ ^ ^ ^
tetrahedron ABCD are i + j + k , i and 3 i ,
produce a colourless gas (B) and a colourless
solution (C). The reaction between (B) and respectively. The altitude from vertex D to the
acidified K2Cr2O7 solution produces a green opposite face ABC meets the median line through
solution and a slightly coloured precipitate (D). The A of the triangle ABC at a point E. If the length of
substance (D) burns in air to produce a gas (E) the side AD is 4 and the volume of the tetrahedron
which reacts with (B) to yield (D) and a colourless
2 2
liquid. Anhydrous copper sulphate is turned blue on is , find the position vector of the point E for
addition of this colourless liquid. Addition of 3
aqueous NH3 or NaOH to (C) produces first a all its possible positions. [IIT-1996]
1 / 3 1 + 3u 2
2du
=
4π
3
. { 3 tan −1
3u 1 / } 3
3
1 – 3 tan 2 x
tan x(1 – 3 tan 2 x)
4π 4π 1 =
= (tan–1 3 – tan–11) = tan–1 3 tan x – tan 3 x
3 3 2
1 – 3 tan 2 x
π/3 π + 4x3 4π 1 = [Q tan 3x ≠ 0 ⇒ 3x ≠ 0]
∴ ∫
−π / 3 π
dx =
3
tan–1 .
2
3 – tan 2 x
2 − cos | x | + ⇒ x≠0
3
⇒ tan x ≠ 0
14. An unbiased die, with faces numbered 1, 2, 3, 4, 5,
0 ∞
6, is thrown n times and the list on n numbers
showing up is noted. What is the probability that + – +
among the numbers 1, 2, 3, 4, 5, 6 only three
numbers appear in this list ? [IIT-2001] 1/3 3
Sol. Let us define at onto function F from A : [r1, r2 ...
rn] to B : [1, 2, 3] where r1r2 .... rn are the readings Let tan x = t
of n throws and 1, 2, 3 are the numbers that appear
1 – 3t 2
in the n throws. ⇒ y=
Number of such functions, 3– t2
M = N – [n(1) – n(2) + n(3)] ⇒ 3y – t2y = 1 – 3t2
where N = total number of functions and ⇒ 3y – 1 = t2y – 3t2
n(t) = number of function having exactly t elements ⇒ 3y – 1 = t2 (y – 3)
in the range.
3y –1
Now, N = 3n, n(1) = 3.2n, n(2) = 3, n(3) = 0 ⇒ = t2
y –3
⇒ M = 3n – 3.2n + 3
Hence the total number of favourable cases 3y –1
⇒ ≥ 0, t2 ≥ 0 ∀ t ∈ R
= (3n – 3.2n + 3). 6C3 y –3
(3 n − 3.2 n + 3) × 6 C3 ⇒ y ∈ (– ∞, 1/3) ∪ (3, ∞)
⇒ Required probability = n
6 Therefore, y is not defined in between (1/3, 3).
Physics Facts
Nuclear Physics
1. Alpha particles are the same as helium nuclei and have the symbol .
1. The atomic number is equal to the number of protons (2 for alpha)
2. Deuterium ( ) is an isotope of hydrogen ( )
3. The number of nucleons is equal to protons + neutrons (4 for alpha)
4. Only charged particles can be accelerated in a particle accelerator such as a cyclotron or Van Der Graaf
generator.
5. Natural radiation is alpha ( ), beta ( ) and gamma (high energy x-rays)
6. A loss of a beta particle results in an increase in atomic number.
7. All nuclei weigh less than their parts. This mass defect is converted into binding energy. (E=mc2)
8. Isotopes have different neutron numbers and atomic masses but the same number of protons (atomic
numbers).
9. Geiger counters, photographic plates, cloud and bubble chambers are all used to detect or observe radiation.
This section is designed to give IIT JEE aspirants a thorough grinding & exposure to variety
of possible twists and turns of problems in physics, that would be very helpful in facing IIT
JEE. Each and every problem is well thought of in order to strengthen the concepts and we
hope that this section would prove a rich resource for practicing challenging problems and
enhancing the preparation level of IIT JEE aspirants.
By : Dev Sharma
So lutions will b e p ub lished in nex t issue Director Academics, Jodhpur Branch
1. A particle of charge Q and of negligible initial speed (A) zero if both wires slide towards left
is accelerated through a potential difference of U. (B) zero if both wires slide in opposite direction
The particle reaches a region of uniform magnetic (C) 0.2mA if both wires move towards left
field of induction B, where it undergoes circular
(D) 0.2mA if both wires move in opposite direction
motion. If potential difference is doubled & B is also
doubled then magnetic moment of the circular 4. A circular current loop is shown in the adjacent
current due to circular motion of charge Q will figure. The magnetic field in the region is along x-
become axis and its magnitude in the space is increasing
(A) double (B) half with increasing y-coordinate. The net magnetic
(C) four times (D) remain same force on the loop is
2. Three long rod AA, AB, CC are moving with a y
speed v in a uniform magnetic field B perpendicular B
to the plane of paper as shown in figure. The
triangle formed between the three wires is always an
equilateral triangle. If resistance per unit length of x
wire is λ , then the induced current in the triangle is
A B (A) along + z-axis (B) along –z-axis
× × × × × × × (C) along +y-axis (D) None of these
B0
× × × × × v× ×
v
× × × × × × × 5. A point charge q moves from A to B along a
× × × × × × × parabolic path (AB is latus rectum). Electric field is
C × × × × C
× along x-axis. The work done by the field is
B B0 A
v y
B0 v 2B 0 v
(A) (B) A B
3λ 3λ 2
y = 4ax
B0 v B0 v
(C) (D)
3λ λ x
E
3. In the diagram shown, the wires P1Q1 and P2Q2 are
made to slide on the rails with same speed of 5m/s.
In this region a magnetic field of 1T exists. The (A) – qEa (B) –2qEa
electric current in 9Ω resistor is (C) +qeA (D) 2qEa
× × P1× × P2 × × × × →
6. In a cylindrical zone of radius R, magnetic field B is
× × × × × × × × × present perpendicular to the plane of the paper into it.
4cm × × ×
2Ω ×2Ω× × × × ×
9Ω
→
Magnitude of B is varying with time as B0(p + qt)
× × × × × × × × ×
where p & q are positive constant. Consider a static
× × × × × × × × × triangle loop OAM. Emf induced in the triangular loop
Q1 Q2
1. AB and CD are two ideal springs having force constant (F1 + K1y1) + (F2 + K2y2) = F + mg ...(ii)
K1 and K2 respectively. Lower ends of these springs are Taking moments about B, (figure)
attached to the ground so that the springs remain F
vertical. A light rod or length 3a is attached with upper
ends B and C of springs. A particle of mass m is fixed C
B a 2a
with the rod at a distance a from end B and in
equilibrium, the rod is horizontal. Calculate period of
small vertical oscillations of the system. (F1 + K1y1) mg (F2 + K2y2)
m
B a C (F + mg) × a = (F2 + K2y2) × 3a ...(iii)
2a
Solving above equations,
2F F
K1y1 = and K2y2 = .
3 3
K1 K2 2F F
or y1 = and y2 =
3K1 3K 2
Since, distance of the particle from left spring is 'a'
and that from right spring is '2a', therefore,
A D downward displacement of the particle from
equilibrium position will be
Sol. Let, in equilibrium, compressive forces in left and
right springs be F1 and F2, respectively. 2 y1 y 4F F ( K 1 + 4K 2 ) F
y= + 2 = + =
Considering free body diagram of rod BC, (figure) 3 3 9K l 9K 2 9 K 1K 2
B a C 9 K 1K 2
2a or F= ...(iv)
( K 1 + 4K 2 )
F1 mg F2 Now, if the particle be released, it starts accelerating
F1 + F2 = mg ...(i) upwards due to excess compressive force in springs.
Hence, the restoring force is (K1y1 + K2y2), which is
Taking moments about B,
numerically equal to F.
mg × a = F2 × 3a
9 K 1K 2
1 or Restoring force = F = .y
or F2 = mg ( K 1 + 4K 2 )
3
Substituting this value in equation (i), F 9K 1 K 2
or Restoring acceleration, a = = .y
m m( K 1 + 4K 2 )
2
F1 = mg Since, acceleration is restoring and is directly
3
proportional to displacement y, therefore, the
Let the particle be pressed from its equilibrium
particle performs SHM. Its period of oscillations is
position by applying a force 'F'. Let left and right
springs be further compressed through y1 and y2, y
T = 2π
respectively. Increase in compressive forces in the a
spring will be K1y1 and K2y2 respectively. In other
words, total compressive forces in two springs will 2π m(K 1 + 4K 2 )
or T= Ans.
be (F1 + K1y1) and (F2 + K2y2) respectively. 3 K 1K 2
Now considering new free body diagram (figure) of
the rod BC,
emitted electron,
1
= mv2 = h(ν – ν0) = hν – W
2
Explanation of laws of photoelectric effect :
(a) The KE of the emitted electron increases with the ν0
increase of frequency of incident radiation since Frequency of incident light
W (work function) is constant for a given emitter. Millikan measured the slope of the straight line
KE is directly proportional to (ν – ν0) (=h/e) and calculated the value of Planck's constant.
(b) Keeping the frequency of incident radiation I
constant if the intensity of incident light is
increased, more photons collide with more atoms Full intensity
and more photoelectrons are emitted. The KE of 75% intensity
the emitted electron remains constant since the 50% intensity
same photon collides with the same atom (i.e., the 25% intensity
nature of the collision does not change). With the – V0 +
increase in the intensity of incident light
Potential difference
photoelectric current increases.
ν0
of strength 10–4 tesla is parallel to the metal surface,
find the radius of the largest circular path followed by
A1 A2 A3 Frequency the emitted photoelectrons.
B1
hc 6.6 × 10 −34 × 3 × 108
B2 Sol. Energy of one photon = =
λ 4.8 × 10 −7
B3
= 4.125 × 10–19 J
(c) Stopping potential versus frequency graphs for Number of photons emitted per second
different metals : These graphs indicate that the
stops is same for all metal, since they are parallel 1.0
= = 2.424 × 1018
−19
straight lines. The slope is a universal constant 4.125 × 10
(=h/e). Further, the threshold frequency varies Number of photons striking the plate per square
with emitter since the intercepts on frequency axis
metre per second
are different for different metals.
2.424 × 1018
= = 4.82 × 1016
4 × 3.14 × (2) 2
Solved Examples Maximum kinetic energy of photoelectrons emitted
from the plate
1. (i) A stopping potential of 0.82 V is required to stop
the emission of photoelectrons from the surface hc
Emax = –W
of a metal by light of wavelength 4000 Å. For λ
light of wavelength 3000 Å, the stopping = 4.125 × 10–19 – 1.17 × 1.6 × 10–19
potential is 1.85 V. Find the value of Planck's
constant. = 2.253 × 10–19 J
emitters also.
volume change and the equation of state of the
Problem solving Strategy : Thermal Expansion material that makes up the thermodynamic system
Step 1: Identify the relevant concepts: Decide (for an ideal gas, pV = nRT).
whether the problem involves changes in length Step 3: Execute the solution as follows :
(linear thermal expansion) or in volume (volume
thermal expansion) You shouldn't be surprised to be told that
Step 2: Set up the problem using the following steps: consistent units are essential. If p is a Pa and V in
m3, then W is in joules. Otherwise, you may want
Eq. ∆L = αL0∆T for linear expansion and to convert the pressure and volume units into
Eq. ∆V = βV0∆T for volume expansion. units of Pa and m3. If a heat capacity is given in
Identify which quantities in Eq. ∆L = αL0∆T or terms of calories, usually the simplest procedure
∆V = βV0∆T are known and which are the is to convert it to joules. Be especially careful
unknown target variables. with moles. When you use n = mtot/M to convert
PA1 m1g
As piston is moved slowly therefore, change in From equilibrium consideration of upper piston
kinetic energy is zero. By work-energy theorem, we we get, P0A1 + T + m1g = PA1
can write Similarly, consider FBD of lower piston
ext
Wgas in right chamber + Wgas in left chamber + WAgent = ∆KE T
ext PA2
WAgent = (Wgas(R) + Wgas(L))
We know that in isothermal process, work done is
given by
Vf P0 A2 m2g
W = nRT ln
∴ P0A2 + T = m2g + PA2
Vi Eliminating T, we get
∴ Work done by gas in left chamber (WL) (m1 + m2 ) g
P = P0 +
V + ∆V 2η A1 − A2
= P0V0 ln 0 = P0V0 ln
V0 η +1 According to problem
Similarly, work done by gas in right chamber (WR) m = m1 + m2
V − ∆V and ∆S = A1 – A2
2η
= P0V0 ln 0 = P0V0 ln mg
V η +1 ∴ P = P0 +
0
∆S
ext 2η 2η Now, PV = RT
WAgent = –P0V0 ln – P0V0 ln
η +1 η +1 P∆V
or P∆V = R∆T or ∆T =
2 R
η +1 But ∆V = (A1 – A2)l = ∆S. l
= P0V0 ln
4η mg
∴ ∆T = P0 + ∆S.l
∆S
5. A smooth vertical tube having two different sections
is open from both ends equipped with two pistons of
different areas figure. Each piston slides within a l l
respective tube section. One mole of ideal gas is
enclosed between the pistons tied with a non-
stretchable thread. The cross-sectional area of the
upper piston is ∆S greater than that of the lower one.
The combined mass of the two pistons is equal to m. l
The outside air pressure is P0. By how many kelvins
must the gas between the pistons be heated to shift
the pistons through l.
Organic
Chemistry CARBONYL COMPOUND
Fundamentals
R + .. R´´
Reduction of Aldehydes and Ketones by Hydride C = O + (C6H5)3P – C
Transfer : R R´´´
Aldehyde or Phosphorus ylide
ketone or phosphorane
R R
R δ+ δ– R R´´
– H – OH
H 3B – H + C=O H–C–O H–C–O–H C=C + O =P(C6H5)3
R´ R´ R´´´
R´ R´
Alkene Triphenyl phosphine
Hydride transfer Alkoxide ion Alcohol [(E) and(Z) isomers] oxide
This reaction, known as the Wittig reaction, has
These steps are repeated until all hydrogen atoms proved to be a valuable method for synthesizing
attached to boron have been transferred. alkenes. The Wittig reaction is applicable to a wide
Sodium borohydride is a less powerful reducing variety of compounds, and although a mixture of (E)
agent than lithium aluminum hydride. Lithium and (Z) isomers may result, the Wittig reaction offers
aluminum hydride reduces acids, aldehydes, and a great advantage over most other alkene syntheses in
ketones but sodium borohydride reduces only that no ambiguity exists as to the location of the
aldehydes and ketones : double bond in the product. (This is in contrast to E1
eliminations, which may yield multiple alkene
Reduced by LiAlH4 products by rearrangement to more stable carbocation
intermediates, and both E1 and E2 elimination
reactions, which may produce multiple products
Reduced by NaBH4 when different β hydrogens are available for
removal.)
O O O O Phosphorus ylides are easily prepared from
triphenylphosphine and primary or secondary alkyl
C < C < C < C halides. Their preparation involves two reactions :
R O– R OR´ R R´ R H
General Reaction
Reaction 1
Ease of reduction R´´ R´´
+
(C6H5)3P : + CH – X → (C6H5)3P – CH X–
Lithium aluminum hydride reacts violently with
R´´´ R´´´
water, and therefore reductions with lithium
Triphenylphosphine An alkyltriphenylphosphonium
aluminum hydride must be carried out in anhydrous halide
solutions, usually in anhydrous ether. (Ethyl acetate
is added cautiously after the reaction is over to Reaction 2
decompose excess LiAlH4; then water is added to R´´ R´´
+ +
decompose the aluminum complex.) Sodium – –
(C6H5)3P – C – H : B → (C6H5)3P – C : + H:B
borohydride reductions, by contrast, can be carried R´´´ R´´´
out in water or alcohol solutions.
A phosphorus ylide
The Addition of Ylides : The Wittig reaction : Specific Example
Aldehydes and ketones react with phosphorus ylides Reaction 1
to yield alkenes and triphenylphosphine oxide. (An +
ylide is a neutral molecule having a negative carbon (C6H5)3P : + CH3Br C→
6H6
(C6H5)3P – CH3Br –
adjacent to a positive heteroatom.) Phosphorus ylides
Methyltriphenylphosphonium
are also called phosphoranes : bromide (89%)
Reaction 2
Tetragonal distortion of octahedral complexes (Jahn- orbitals are no longer equal in energy. If the d z 2
Teller distortion) :
orbital contains one.
The shape of transition metal complexes are affected
by whether the d orbitals are symmetrically or Asymmetrical electronic arrangements :
asymmetrically filled.
Repulsion by six ligands in an octahedral complex Electronic t2g eg
configurati
splits the d orbitals on the central metal into t2g and eg on
levels. It follows that there is a corresponding
repulsion between the d electrons and the ligands. If d4
the d electrons are symmetrically arranged, they will
d7
repel all six ligands equally. Thus the structure will
be a completely regular octahedron. The symmetrical
d9
arrangements of d electrons are shown in Table.
Symmetrical electronic arrangements :
more electron than the d x 2 − y 2 orbital then the ligands
Electronic t2g eg
configurat approaching along +z and –z will encounter greater
ion repulsion than the other four ligands. The repulsion
d5 and distortion result in elongation of the octahedron
along the z axis. This is called tetragonal distortion.
d6 Strictly it should be called tetragonal elongation. This
form of distortion is commonly obsered.
d8 If the d x 2 − y 2 orbital contains the extra electron, then
d10 elongation will occur along the x and y axes. This
means that the ligands approach more closely along
the z-axis. Thus there will be four long bonds and
All other arrangements have an asymmetrical two short bonds. This is equivalent to compressing
arrangement of d electrons. If the d electrons are the octahedron along the z axis, and is called
asymmetrically arranged, they will repel some tetragonal compression, and it is not possible to
ligands in the complex more than others. Thus the predict which will occur.
structure is distorted because some ligands are For example, the crystal structure of CrF2 is a
prevented from approaching the metal. distorted rutile (TiO2) structure. Cr2+ is octahedrally
as closely as others. The eg orbitals point directly at surrounded by six F–, and there are four Cr–F bonds
the ligands. Thus asymmetric filling of the eg orbitals of length 1.98 – 2.01 Å, and two longer bonds of
in some ligands being repelled more than others. This length 2.43 Å. The octahedron is said to be
causes a significant distortion of the octahedral tetragonally distorted. The electronic arrangement in
shape. In contrast the t2g orbitals do not point directly Cr2+ is d4. F– is a weak field ligand, and so the t2g
at the ligands, but point in between the ligand level contains three electrons and the eg level contains
directions. Thus asymmetric filling of the t2g orbitals one electron. The d x 2 − y 2 orbital has four lobes whilst
has only a very small effect on the stereochemistry.
Distortion caused by asymmetric filling of the t2g the d z 2 orbital has only two lobes pointing at the
orbitals is usually too small to measure. The ligands. To minimize repulsion with the ligands, the
electronic arrangements which will produce a large single eg electron will occupy the d z 2 orbital. This is
distortion are shown in Table.
equivalent to splitting the degeneracy of the eg level
The two eg orbitals d x 2 − y 2 and d z 2 are normally so that d z 2 is of lower energy, i.e. more stable, and
degenerate. However, if they are asymmetrically d x 2 − y 2 is of higher energy, i.e. less stable. Thus the
filled then this degeneracy is destroyed, and the two
273.15 K 0.17 V
= (75.312 J K–1mol–1) × ln
263.15 K E 2º
= 2.809 J K–1 mol–1
(b) H2O(1, 0ºC) → H2O(s, 0ºC) ...(2) Sol. The reaction corresponding to the potential Eº1 is
∆rH2 = – 6.008 kJ mol–1
1
BrO3– + 3H2O + 5e– = Br2 + 6OH– ...(1)
(6008 J mol –1 ) 2
∆rS2 = – = – 21.995 J K–1 mol–1
(273.15 K ) This reaction can be obtained by adding the
(c) H2O(s, 0ºC) → H2O(s, –10ºC) ...(3) following two reduction reactions:
263.15 K BrO3– + 2H2O + 4e– = BrO– + 4OH– ...(2)
∆rH3 = ∫C
273.15 K
p , m (s) dT 1
BrO– + H2O + e– = Br2 + 2OH–
2
...(3)
= (36.400 J K–1 mol–1)(–10 K) Hence the free energy change of reaction (1) will be
= – 364.0 J mol–1 º
∆G reaction º º
(1) = ∆G reaction ( 2 ) + ∆G reaction (3)
263.15 K
C p, m (s) Replacing ∆Gºs in terms of potentials, we get
∆rS3 = ∫
273.15 K
T
dT
– 5FE1º = – 4F(0.54 V) – 1F (0.45 V)
= (–2.61 V) F
`tà{xÅtà|vtÄ V{tÄÄxÇzxá 10
This section is designed to give IIT JEE aspirants a thorough grinding & exposure to variety
of possible twists and turns of problems in mathematics that would be very helpful in facing
IIT JEE. Each and every problem is well thought of in order to strengthen the concepts and
we hope that this section would prove a rich resource for practicing challenging problems and
enhancing the preparation level of IIT JEE aspirants.
By : Shailendra Maheshwari
So lu t ion s wi l l b e p ub lished in nex t issue Joint Director Academics, Career Point, Kota
∆ s ( s − a)( s − b)( s − c)
1. as φ (a) = φ (b) = φ (c) so r = k = =
s s
so by Rolle’s theorem there must exist at least a point
x = α & x = β each of intervals (a, c) & (c, b) such s ( s − a)( s − b)( s − c)
r=k=
that φ′(α) = 0 & φ′(β) = 0. Again by Rolle’s theorem, s
there must exist at least a point x = µ such that 2sk = s ( s − a)(a − b + c)(a + b − c)
α < µ < β where φ′(µ) = 0
2 f (a) 2 f (b) = s ( s − a)(a − 2 x)(a + 2 x)
so +
( a − b) ( a − c ) (b − c) (b − a)
2sk = s ( s − a )(a 2 − 4h 2 )
2 f (c )
+ – f ′′ (µ) = 0 required locus is
(c − a ) (c − b ) 4s2y2 = A(a2 – 4x2)
f (a) f (b) Aa 2
so + ⇒ s2y2 + Ax2 =
( a − b) ( a − c ) (b − c) (b − a) 4
f (c ) 1 where A is = s (s – a)
+ = f ′′ (µ) here h2 < as so it is an ellipse
(c − a ) (c − b ) 2
where a < µ < b. 4. f (0) = c
f (1) = a + b + c & f (−1) = a − b + c
2. Required probability solving these,
r −2 1
5 5 5 5 1 5 1 a = [f (1) + f (−1) − 2 f (0)] ,
1. . . ........ . = . (r – 2) times
6 6 6 6 6 6 6 2
Note : any number in 1st loss 1
b = [f (1) − f (−1)] & c = f (0)
same no. does not in 2nd (any other comes). 2
Now 3rd is also diff. (and in same r − 2 times) x( x + 1) x( x − 1)
so f (x) = f (1) + (1− x2) f (0) + f(−1)
Now (r − 1)th & r th must be same. 2 2
2
2 | f (x) | < | x | | x + 1 | + 2| 1 − x | + | x | | x − 1| ;
3. 2s = a + b + c as | f (1) | , | f (0) |, | f (−1) | ≤ 1.
ON = − BN + BO 2 | f (x) | ≤ | x | (x + 1) + 2 (1 − x2) + | x | (1 − x) as
Let BN = x x ∈ [−1, 1]
2BN + 2CN + 2AR = 2s 5 5
x + (a − x) + (b − a + x) = s so 2 | f (x) | ≤ 2 (|x| + 1 − x2) ≤ 2 . so | f (x) | ≤
4 4
x=s−b
2 1
A Now as g (x) = x f (1/x) = (1 + x) f (1)
2
1
+ (x2 − 1) f (0) + (1 − x) f (−1)
2
M R so 2 | g (x) | ≤ | x + 1 | + 2 | 1 − x2 | + | 1 − x|
I (h,k)
⇒ 2 | g (x) | ≤ x + 1 + 2 (1 − x2) | + 1 − x ;
as x ∈ [−1, 1]
r ⇒ 2 | g (x) | < − 2x2 + 4 ≤ 4.
B C ⇒ |g (x) | ≤ 2.
N O
5. Oil bed is being shown by the plane A′ PQ. θ be the
a
so h = ON = − (s − b ) angle between the planes A′ PQ & A′ B′ C′. Let A′ B′
2
C′ be the x − y plane with x-axis along A′ C′ and
−2 s + a + 2b b−c
= = & r = k. origin at A′. The P.V.s of the various points are
2 2 defined as follows
B´
= ∫ (cos 3x − cos 2 x) dx
sin 3 x sin 2 x
= − +C
3 2
A´ C´
P x
d2y
Q 7.
dx 2
=2 ∫ f (t ) dt
0
point C′ : b î , point B′ : cos A î + c sin A ĵ ,
integrate using by parts method
point Q : b î – z k̂ , point P : cos A î + c sin A ĵ – y k̂ x x
dy
normal vector to the plane A′ B′ C′
r dx
∫ 0
∫
= 2 x f (t ) dt − x . f ( x) dx
0
= n1 = bc sin A k̂
r x
normal vector to the plane A'PQ = n2
= cz sin A î + (by – cz cos A) ĵ + bc sin A k̂
∫
= 2 ( x − t ) f (t ) dt
0
r r
n1.n2 again integrating,
so cos θ = r r
| n1 || n1 | x x x
y = 2 x ( x − t ) f (t ) dt − x f (t ) dt − 0 dx
∫ ∫ ∫
bc sin A
= 0 0 0
[c z sin A + (by − cz cos A) 2 + b 2 c 2 sin 2 A]1 / 2
2 2 2
b c sin A x x2
x x 2
x
cos θ = 2 2 2
[b c sin A + (c 2 z 2 + b 2 y 2 − 2bycz cos A)]1 / 2 0
∫
=2 x ( x − t ) f (t ) dt −
2
0
f (t ) dt +∫0
2
f ( x) dx
∫
[c 2 z 2 + b 2 y 2 − 2bycz cos A]1 / 2 x x x
so tan θ =
∫ 2 (x ∫x ∫t
2 2 2
bc sin A = − xt ) f (t ) dt − f (t ) dt + f (t ) dt
0 0 0
z 2 y 2 2 yz x x
so tan θ . sin A = + − cos A
b2 c2 ∫ (x ∫ (x − t)
2 2 2
bc y= − 2 xt + t ) f (t ) dt = f (t ) dt
0 0
cos 8 x − cos 7 x 2 sin 5 x
6. ∫ 1 + 2 cos 5 x
.
2 sin 5 x
dx
a α
1/ α
a β
1/ β
(t – 1)
P A
θ
Regents Physics
O C B (t, 1)
You Should Know
rθ = t ; so θ = t
Modern Physics :
PB θ
from ∆PAB : = PA sin • The particle behavior of light is proven by the
2 2
photoelectric effect.
t
⇒ PB = 2 sin ........(1) • A photon is a particle of light {wave packet}.
2
θ t • Large objects have very short wavelengths when
Now ∠ PBC = = ; moving and thus can not be observed behaving
2 2
as a wave. (DeBroglie Waves)
θ t
so from ∠ PCB ; = • All electromagnetic waves originate from
2 2
accelerating charged particles.
1/ 2 t
so from ∆ PCB ; = sin ........(2) • The frequency of a light wave determines its
PB 2
energy (E = hf).
from (1) & (2) PB = 1 ; so θ = t = π/3
• The lowest energy state of a atom is called the
1
thus | PB |2 = (t − x)2 + = 1. ground state.
4
• Increasing light frequency increases the kinetic
3 3 energy of the emitted photo-electrons.
|t−x|= ; t−x= ; as t > x
2 2
• As the threshold frequency increase for a photo-
π 3 cell (photo emissive material) the work function
so x = −
3 2 also increases.
• Increasing light intensity increases the number of
10. Let xn = n − 1 + n + 1 be rational, then emitted photo-electrons but not their KE.
1
=
1
is also rational Mechanics :
xn n −1 + n +1
• Centripetal force and centripetal acceleration
1 n +1 − n −1 vectors are toward the center of the circle- while
= is also rational
xn 2 the velocity vector is tangent to the circle.
• An unbalanced force (object not in equilibrium)
n +1 − n − 1 is also rational
must produce acceleration.
as n +1 + n −1 & n +1 − n − 1 are rational • The slope of the distance-tine graph is velocity.
so n +1 + n − 1 must be rational • The equilibrant force is equal in magnitude but
i.e. (n + 1) & (n – 1) are perfect squares. opposite in direction to the resultant vector.
This is not possible as any two perfect squares differe • Momentum is conserved in all collision systems.
at least by 3. Hence there is not positive integer n for
• Magnitude is a term use to state how large a
which n −1 + n + 1 is a rational. vector quantity is.
sin 4 α cos 4 α 1 Sol. The greatest integer [x3 + 1] takes jump from 2 to 3 at
1. If + = , show that 3
a b a+b 2 and again from 3 to 4 at 3 3 in [1, 1.5] and
therefore it is discontinuous at these two points. As a
sin 8 α cos 8 α 1
3
+ 3
= . result the given function is discontinuous at 3 2 and
a b ( a + b) 3
hence not differentiable.
a+b a+b To find the derivative at other points we write :
Sol. Here sin4α + cos4α = 1
a b 2
+ sin x
in (1, 3
2 ), f(x) = ( x + 2) x
b 4 a
or sin4α + cos4α + sin α + cos4α = 1 2
+sin x −1
a b ⇒ f ´(x) = ( x + 2) x
or (sin2α + cos2α)2 – 2 sin2α . cos2α {x2 + sin x + (x + 2) (2x + cos x) log (x + 2)}
2
b a in ( 3 2 , 3 3 ), f(x) = ( x + 3) x +sin x
,
+ sin4α + cos4α = 1
a b 2
+sin x −1
2 f ´(x) = ( x + 3) x {x2 + sin x
b b a
or sin 2 α – 2 . sin2α . cos2α + (2x + cos x) (x + 3) × loge (x + 3)}
a a b
2
+ sin x
in ( 3 5 , 1.5), f(x) = ( x + 4) x ,
2
a 2
+ cos 2 α = 0 f ´(x) = ( x + 4) x +sin x −1
, {x2 + sin x + (2x + cos x)
b
(x + 4) × loge(x + 4)}
2
b a
or sin 2 α – cos 2 α = 0 3. The decimal parts of the logarithms of two numbers
a b taken at random are found to six places of decimal.
What is the chance that the second can be subtracted
b a from the first without "borrowing"?
∴ sin2α = cos2α
a b Sol. For each column of the two numbers,
a n(S) = number of ways to fill the two places by the
or sin2α = cos2α digits 0, 1, 2, ... , 9
b
= 10 × 10 = 100.
sin 2 α cos 2 α sin 2 α + cos 2 α
∴ = = x
a b a+b × × × × × ×
y
a b × × × × × ×
∴ sin2α = , cos2α =
a+b a+b Let E be the event of subtracting in a column without
sin 8 α cos8 α 1 a4 1 b4 borrowing. If the pair of digits be (x, y) in the column
∴ + = . + . where x is in the first number and y is in the second
a3 b3 a3 ( a + b) 4 b3 ( a + b) 4 number then
a b a+b 1 E = {(0, 0), (1, 0), (2, 0), .. ,(9, 0),
= + = =
( a + b) 4
( a + b) 4
( a + b) 4
( a + b) 3 (1, 1), (2, 1), ..., (9, 1),
(2, 2), (3, 2), ..., (9, 2),
2. Let [x] stands for the greatest integer function find (3, 3), (4, 3), ..., (9, 3),
2
the derivative of f(x) = ( x + [ x 3 + 1]) x +sin x , where it ......
(8, 8), (9, 8),
exists in (1, 1.5). Indicate the point(s) where it does
not exist. Give reason(s) for your conclusion. (9, 9)}
Integration : 1 1 x−a
d
18. ∫x 2
−a 2
=
2a
log
x+a
, when x > a
If
dx ∫
f(x) = F(x), then F ( x ) dx = f(x) + c, where c
1 1 a+x
is an arbitrary constant called constant of integration. 19. ∫a 2
−x 2
dx =
2a
log
a−x
, when x < a
x n +1
1. ∫ x n dx =
n +1
(n ≠ –1)
20. ∫
dx x
= log x + x 2 − a 2 = cos h–1
2
x −a 2 a
1
2. ∫ x
dx = log x
dx x
21. ∫ = log x + x 2 + a 2 = sin h–1
∫e a
2 2
3. x
dx = ex x +a
1 1 x
4. ∫ a x dx =
ax
log e a
22. ∫ a 2 − x 2 dx =
2
x a 2 − x 2 + a2 sin–1
2 a
1
5. ∫ sin x dx = – cos x 23. ∫ x 2 − a 2 dx =
2
x x2 − a2
6. ∫ cos x dx = sin x –
1 2
2
a log x + x 2 − a 2
∫ sec x dx = tan x
2
7. 1
24. ∫ x 2 + a 2 dx =
2
x x2 + a2
∫ cos ec x dx = – cot x
2
8.
1 2
+ a log x + x 2 + a 2
9. ∫ sec x tan x dx = sec x 2
f ´(x )
10. ∫ cosec x cot x dx = – cosec x
25. ∫ f ( x) dx = log f(x)
x π f ´(x)
11. ∫ sec x dx = log(sec x + tan x) = log tan 2 + 4 26. ∫ f ( x)
dx = 2 f ( x)
This can be reduced to one of the forms of the above Some Important Integrals :
formulae (15), (20) or (21).
dx x−α
(iii) ∫ ax 2 + bx + c dx 1. To evaluate ∫ ( x − α)( x − β)
, ∫ dx,
β− x
This can be reduced to one of the forms of the above
formulae (22), (23) or (24). ∫ ( x − α)(β − x) dx. Put x = α cos2θ + β sin2θ
( px + q)dx ( px + q )dx
(iv) ∫ 2
ax + bx + c
, ∫
ax 2 + bx + c
2. To evaluate
dx
∫ a + b cos x , ∫ a + b sin x ,
dx
∫e
ax
3. cos(bx + c) dx 2 a−b x
= tan–1 tan + c
2
a −b 2
a + b 2
e ax
= [a cos (bx + c) + b sin(bx + c)]
a 2 + b2 dx
2. (When a < b) ∫ a + b cos x
e ax b
= cos bx + c − tan −1 x
2
a +b 2 a b − a tan − a+b
1 a
=– log
x
4. ∫ ekx{kf(x) + f '(x)} dx = ekxf(x) b2 − a 2 b − a tan + a + b
a
x dx 1 x
5. ∫ log e x = x(logex – 1) = x loge
e
3. (when a = b) ∫ a + b cos x = a tan 2 +c
Functions with their Periods : checked whether they satisfy the original equation
or not. e.g. Let x = 3. Squaring, we get x2 = 9,
Function Period ∴ x = 3 and – 3 but x = – 3 does not satisfy the
sin (ax + b), cos (ax + b), sec (ax + b), 2π/a original equation x = 3.
cosec (ax + b)
2. Any value of x which makes both R.H.S. and
tan(ax + b), cot (ax + b) π/a L.H.S. equal will be a root but the value of x for
|sin (ax + b)|, |cos (ax + b)|, |sec (ax + b)|, π/a which ∞ = ∞ will not be a solution as it is an
|cosec (ax + b)| indeterminate form.
|tan (ax + b)|, |cot (ax + b)| π/2a 3. If xy = xz, then x(y – z) = 0 ⇒ either x = 0 or
y z
Trigonometrical Equations with their General y = z or both. But = ⇒ y = z only and not
Solution: x x
x = 0, as it will make ∞ = ∞. Similarly, if ay = az,
Trgonometrical equation General Solution then it will also imply y = z only as a ≠ 0 being a
sin θ = 0 θ = nπ constant.
cos θ = 0 θ = nπ + π/2 Similarly, x + y = x + z ⇒ y = z and x – y = x – z
tan θ = 0 θ = nπ
⇒ y = z. Here we do not take x = 0 as in the
above because x is an additive factor and not
sin θ = 1 θ = 2nπ + π/2 multiplicative factor.
cos θ = 1 θ = 2nπ
4. When cos θ = 0, then sin θ = 1 or –1. We have to
sin θ = sin α θ = nπ + (–1) αn verify which value of sin θ is to be chosen which
1
cos θ = cos α θ = 2nπ ± α satisfies the equation cos θ = 0 ⇒ θ = n + π
2
tan θ = tan α θ = nπ + α
If sin θ = 1, then obviously n = even. But if
sin2θ = sin2α θ = nπ ± α sin θ = –1, then n = odd.
tan2θ = tan2α θ = nπ ± α Similarly, when sin θ = 0, then θ = nπ and cos θ = 1
or –1.
cos2θ = cos2α θ = nπ ± α
If cos θ = 1, then n is even and if cos θ = –1, then
sin θ = sin α θ = 2nπ + α n is odd.
*
cos θ = cos α 5. The equations a cos θ ± b sin θ = c are solved as
follows :
sin θ = sin α θ = 2nπ + α
*
tan θ = tan α Put a = r cos α, b = r sin α so that r = a2 + b2
and α = tan–1 b/a.
tan θ = tan α θ = 2nπ + α
* The given equation becomes
cos θ = cos α
r[cos θ cos α ± sin θ sin α] = c ;
* If α be the least positive value of θ which satisfy c c
cos (θ ± α) = provided ≤ 1.
two given trigonometrical equations, then the general r r
value of θ will be 2nπ + α.
Relation between the sides and the angle of a triangle:
Note :
1. Sine formula :
1. If while solving an equation we have to square it,
then the roots found after squaring must be
A ( s − b)( s − c) (i) a, b a a
(c) tan = , tanA = , B = 90º – A, c =
2 s( s − a) b sin A
(ii) a, c a
B ( s − a)( s − c) C ( s − a)( s − b) sinA = , b = c cos A, B = 90º – A
tan = , tan c
2 s ( s − b) 2 s( s − c)
Napier's Analogy : Case II. When a side and an acute angle are given –
B −C b−c A C−A c−a B In this case, we can determine
tan = cot , tan = cot
2 b+c 2 2 c+a 2
Given Required
A− B a −b C
tan = cot (i) a, A
2 a+b 2 a
B = 90º – A, b = a cot A, c =
Area of Triangle : sin A
1 1 1 (ii) c, A B = 90º – A, a = c sin A, b = c cos A
∆ = bc sin A= ca sin B = ab sin C
2 2 2
2 2 2
∆ = 1 a sin B sin C = 1 b sin C sin A = 1 c sin A sin B
2 sin( B + C ) 2 sin(C + A) 2 sin( A + B)
2 2∆
sin A = s ( s − a)( s − b)( s − c ) =
bc bc
2∆ 2∆
Similarly sin B = & sin C =
ca ab
IIT-JEE 2012
XtraEdge Test Series # 10
Time : 3 Hours
Syllabus :
Physics : Full Syllabus, Chemistry : Full Syllabus, Mathematics : Full syllabus
Instructions :
Section - I
• Question 1 to 9 are multiple choice questions with only one correct answer. +3 marks will be awarded for
correct answer and -1 mark for wrong answer.
• Question 10 to 13 are Reason and Assertion type question with one correct answer. +3 marks will be awarded for
correct answer and –1 mark for wrong answer.
• Question 14 to 19 are passage based questions. +4 marks will be awarded for correct answer and –1 mark for wrong
answer.
• Question 20 to 22 are Column Matching type questions. +6 marks will be awarded for the complete correctly
matched answer (i.e. +1 marks for each correct row) and No Negative marks for wrong answer.
60º V=0
A B
(0,5,12)
y
(A) M (B) M en O
B B B (D) N
A B 4
en H
A
B
(C) en (D) 5. In the Cannizzaro's reaction given below :
M en M –
2Ph – CHO OH → Ph–CH2OH + PhCOO–-
B
A en the slowest step is -
2. Titration curve of Na2CO3 and HCl is as given below. (A) the attack of OH– at the carbonyl group
The indicators In1 and In2 respectively, must be – (B) the transfer of hydride to the carbonyl group
(C) the abstraction of proton from the carboxylic acid
(D) the deprotonation of Ph–CH2OH
12
6. The relative rates of solvolysis in 80% EtOH of the
10 In1 following bromides is in the order –
pH 6
Br Br Br
In2
4 I II III
(A) I > II > III (B) III > II > I
2
(C) II > III > I (D) II > I > III
10 20 30 40 50 60
Volume of HCl (ml)
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22. Match the Column : 7. The number of different words of three letters which
Column-I Column-II can be formed from the word "PROPOSAL", if a
(A) Soluble in dil HCl (P) SrS2O3 vowel is always in the middle are-
(B) Yields SO2 with dil (Q) SrSO3 (A) 53 (B) 52
HCl on bonding (C) 63 (D) 32
(C) Soluble in aqueous (R) SrSO4 8. Let a1, a2, a3, ...... be terms of an A.P. If
solution a1 + a 2 + .... + a p p2 a
= 2 , p ≠ q, then 6 equals-
(D) Insoluble in aqueous (S) CdS a1 + a 2 + ..... + a q q a 21
solution
(A) 41/11 (B) 7/2
(C) 2/7 (D) 11/41
MATHEMATICS 9. The curve y = ax3 + bx2 + cx is inclined by 45º to
Questions 1 to 9 are multiple choice questions. Each x-axis at origin and it touches x-axis at (1,0). Then-
question has four choices (A), (B), (C) and (D), out of (A) a = –2, b = 1, c = 1 (B) a = 1, b = 1, c = –2
which ONLY ONE is correct. Mark your response in (C) a = 1, b = –2, c = 1 (D) a = –1, b = 2, c = 1
OMR sheet against the question number of that
question. + 3 marks will be given for each correct This section contains 4 questions numbered 10 to 13,
answer and – 1 mark for each wrong answer. (Reason and Assertion type question). Each question
1. The area enclosed by | y | – | x | = 1 and x2 + y2 =1 is contains Assertion (A) and Reason (R). Each question
has 4 choices (A), (B), (C) and (D) out of which ONLY
(A) 2 units2 (B) zero units2
2 ONE is correct. Mark your response in OMR sheet
(C) infinite units (D) none of these against the question number of that question. +3 marks
2. Least value of the expression 9sec2θ + 4cosec2θ, is- will be given for each correct answer and – 1 mark for
(A) 6 (B) 1 (C) 36 (D) 25 each wrong answer.
The following questions given below consist of an
x
"Assertion" (A) and "Reason" (R) Type questions. Use
3. ∫
Let f (x) = (2( x − 1)( x − 2) 3 + 3( x − 1) 2 ( x − 2) 2 ) dx ,
1
the following Key to choose the appropriate answer.
(A) If both (A) and (R) are true, and (R) is the correct
then- explanation of (A).
(A) f has exactly 4 critical points (B) If both (A) and (R) are true but (R) is not the
(B) f has maximum at x = 2 correct explanation of (A).
(C) If (A) is true but (R) is false.
(C) x = 7/5 is minima & x = 1 is maxima
(D) If (A) is false but (R) is true.
(D) none of these
10. Assertion (A) : Let z be a complex number satisfying
4. The locus of the middle points of chords of a |z – 3| ≤ |z – 1|, |z – 3| ≤ |z – 5|, |z – i| ≤ |z + i|
parabola which subtend a right angle at the vertex of and |z – i| ≤ |z – 5i|. Then the area of region in which
the parabola is- z lies is 12 sq. units.
(A) Circle (B) Parabola 1
(C) Ellipse (D) Straight line Reason (R) : Area of trapezium = (sum of parallel
2
5. The probability that a particular day in the month of sides) (Distance between parallel sides)
july is a rainy day is 3/4. Two person whose
credibility are 4/5 and 2/3 respectively claim that 15th 11. Let f (x) = | 1 – x | and g(x) = sin–1(f | x |)
july was a rainy day. The probability that it was real Assertion (A) : Number of values of x, where g(x) is
a rainy day. non differentiable is 3.
(A) 3/4 (B) 24/25 (C) 8/9 (D) none Reason (R) : Domain of g(x) is [–1, 1]
k is equal to
x x
Chemistry Facts
(C) If three successive terms of a G.P. (R) 2 • At 0 degress Celsius and 1 atmospheric pressure,
with common ratio r, (r > 1) forms one mole of any gas occupies approximately
the sides of a triangle then [r] + [–r] 22.4 liters.
is equal to (where [.] denotes
greatest integer function) • Atomic weight is the mass of an atom relative to
(D) Let f(x) = (x2 – 3x + 2)(x2+3x+2) (S) 3 the mass of an atom of carbon-12 which has an
and α, β, γ are the roots of atomic weight of exactly 12.00000 amu.
f '(x) = 0, then [α]+[β] + [γ] is • If the atom were the size of a pixel (or the size
equal to (where [.] denotes greatest of a period), humans would be a thousand miles
integer function) tall.
IIT-JEE 2013
XtraEdge Test Series # 10
Time : 3 Hours
Syllabus :
Physics : Full Syllabus, Chemistry : Full Syllabus, Mathematics : Full syllabus
Instructions :
• Question 1 to 9 are multiple choice questions with only one correct answer. +3 marks will be awarded for
correct answer and -1 mark for wrong answer.
• Question 10 to 13 are Reason and Assertion type question with one correct answer. +3 marks will be awarded for
correct answer and –1 mark for wrong answer.
• Question 14 to 19 are passage based questions. +4 marks will be awarded for correct answer and –1 mark for wrong
answer.
• Question 20 to 22 are Column Matching type questions. +6 marks will be awarded for the complete correctly
matched answer (i.e. +1 marks for each correct row) and No Negative marks for wrong answer.
(A) x = 40 cm (B) x = 60 cm
PHYSICS (C) x < 60 cm (D) x > 60 cm
Questions 1 to 9 are multiple choice questions. Each 5. Figure shows a toy-whistle. It a disk made of plastic
question has four choices (A), (B), (C) and (D), out of having two conical grooves at diametrically opposite
which ONLY ONE is correct. Mark your response in point. When it is rotated about its centre with
OMR sheet against the question number of that sufficiently high speed air intercepted by groove
question. + 3 marks will be given for each correct produce whistling sound. An observer is at a distance
answer and – 1 mark for each wrong answer. 10 m from the centre of toy. Radius of toy is 15 cm.
1. Ice point on a particular scale measure 22º. The scale Frequency of sound emitted by toy when it is rotating
agrees with Fahrenheit scale at 72ºF. The 1800
with ω = rpm is 10 kHz. If velocity of sound
temperature in Fahrenheit scale when new scale π
reads 27º is - in air 300 m/s, beat frequency heard by observer is –
(A) 40ºF (B) 38ºF (C) 36ºF (D) 34ºF
2. A hot body is kept in a chamber maintained at fixed
lower temperature. Time taken by body in loosing O
half the maximum heat it can lose is
5 min. Time taken by body in loosing the maximum
heat it can lose is -
(A) 10 Hz (B) 15 Hz (C) 20 Hz (D) None
(A) 10 min (B) 12 min (C) 20 min (D) Infinite
6. An ice cube is fixed at the bottom of container
3. A point source of power 4 W is placed at the centre
containing water. Water in the container will be
of spherical shell. The shell is kept in a vacuum
cooled majorly by -
chamber maintained at 27ºC. If shell attains a
constant temperature 37ºC, emissivity of surface of (A) Convection (B) Conduction
shell is nearly - (C) Radiation (D) Convection and conduction
1 1 2 4 7. In a region of space a constant force F newton acts
(A) (B) (C) (D)
2 3 3 5 on a particle of mass m, which is released from rest
at point A. When the particle reaches B its –
4. In a resonance–column experiment, a long tube, open
→
at top, is clamped vertically. Water level inside tube F
can be moved up or down. First resonance is
occuring when water level is at depth 20 cm below m
open end. Let second resonance occurs when water A B
level is at a distance ‘x’ below opening, then -
S 1680 3380
(A) P (P) Temperature
A
17. Which of the above element is likely to be alkali is increasing
metal ?
(A) P (B) Q (C) R (D) S V
18. Which of the above element is likely to be alkaline
earth metal ?
(A) P (B) Q (C) R (D) S A B
P
(B) (Q) Isotherm
19. Which of the above element is likely to be noble gas?
(A) P (B) Q (C) R (D) S
T
This section contains 3 questions (Questions 20 to 22). A
Each question contains statements given in two columns
which have to be matched. Statements (A, B, C, D) in
Column I have to be matched with statements (P, Q, R, S) P
in Column II. The answers to these questions have to be (C) (R) Isochoric
appropriately bubbled as illustrated in the following B
example. If the correct matches are A-P, A-S, B-Q, B-R,
C-P, C-Q and D-S, then the correctly bubbled 4 × 4 T
matrix should be as follows :
16. Two parallel wires of infinite length have linear 25. A 0.5 m long metal rod PQ completes the circuit as
shown. The area of the circuit is perpendicular to the
charge densities λ1 and λ2 coulomb/metre. Derive an
magnetic field of flux density 0.15 T. If the
expression for force per unit length acting between
them. resistance of the total circuit is 3 Ω. Calculate the
force needed to move the rod in the direction as
17. A 10 µF capacitor is charged by a 30 V d.c. supply indicated with speed 2 ms–1.
and then connected across an uncharged 50 µF
capacitor. Calculate (i) the final potential difference × × × × × ×Q× × × ×
across the combination and (ii) the initial and final × × × × × × × × ××
× × × × × × × × ×v ×
energies. How will you account for the difference in × × × × × × × × ××
energy ? × × × × × ×P× × × ×
18. Amplitude of electric field in an electromagnetic wave 26. Explain the principle and working of cyclotron with
is 3×106 V/m. Find amplitude of magnetic field. the help of a labelled diagram.
19. Explain it 27. Using Gauss' theorem, deduce an expression for the
(i) work function electric field intensity at any point due to a thin,
(ii) Threshold frequency infinitely long wire of charge/length λ C/m.
(iii) Threshold wave length
28. What is diffraction ? write down its difference with
(iv) Stopping potential
interference ? If single slit diffraction is obtained by
20. Show that the energy of the first excited state of He+ using light of wavelength 5000Å and slit width 0.5
atom is equal to the energy of the ground state of mm. Then calculate angular width of central
hydrogen atom maxima.
OR
21. In a young's double slit experiment, the slits are What is dispersion ? How the angular dispersion is
separated by 0.56 mm and the screen is placed 2.8 m defined ? Which colours is deviated maximum by a
away. The distance between the central bright fringe prism ? Calculate dispersive power of crown glass if
and the fifth bright fringe is measured to be 1.5 cm. refractive indices for red, yellow and violet colours
Determine the wavelength of light used in the are 1.5140, 1.5170 and 1.5318 respectively.
experiment.
22. A communication system having operating wavelength • 29. What is spectrum ? write down types of spectrum
?
λ in m can use only x% of its source frequency as its
channel bandwidth. The system is to be used for • OR
transmitting TV signals requiring bandwidth of F Hz, • If electrons trans it from first excited state of
How many channels can this system transmit H-atom to ground state and emitted radiations
simultaneously incidents over a metallic surface of threshold
wavelength 4000 Å, then what is the value of
10. For the following conversion reactions write the 23. What is adsorption ? How does adsorption of a gas
chemical equations : on a solid surface vary with
dx
14. Evaluate : ∫ (sin x – 2 cos x)(2 sin x + cos x) . Section C
23. One bag contains five white and four black ball.
15. The position vectors of two points A and B are Another bag contains seven white and nine black
balls. A ball is transferred from the first bag to the
3iˆ + ˆj + 2 kˆ and iˆ – 2 ˆj – 4 kˆ respectively. Find the
second and then a ball is drawn from the second.
vector equation of the plane passing through B and Find the probability that the ball drawn is white.
perpendicular to the vector AB.
24. Find the area of the region bounded by x2 + y2 = 1 and
→ → (x – 1)2 + y2 = 1.
16. If a = iˆ – 3 ˆj + kˆ , b = iˆ – ˆj + kˆ and
π
→ → → → e cos x
c = 2iˆ – ˆj + kˆ , verify that a × ( b × c ) = 25. Evaluate : ∫e cos x
+ e – cos x
dx .
→ → → → → → 0
(a .c ) b –(a .b )c . Or
π/ 4
x + π/4
17. Find the equation of tangent to curve y = 3x – 2 . Evaluate : ∫ 2 – cos 2 x
dx .
Which is parallel to line 4x – 2y + 5 = 0. –π/ 4
h
20. λ=
2mqV
i A
for proton →
→
h dl r
λ= …(i)
2meV
→ →
For α-particle → µ i (dl× r )
h dB = 0
λ= …(ii) 4π r 3
2 × 4m × 2eV'
µ 0 idl sin θ
By (i) and (ii) or dB =
4π r 2
2meV = 2 × 4m × 2eV'
where µ0 ⇒ Permeability of free space,
V' = V / 8 → →
θ ⇒ between dl and r .
21.
27. (i) On increasing distance between the coils, flux
linked decreases, hence mutual inductance decreases
Fe 56
e µ 0 N1N 2 A
d (ii) Q M =
c a → 2He4 l
BE/A b b → 4Be8 ∴ on increasing no. of turns, M increases
a (iii) when iron sheet (µr) is inserted
c → 6C12
d → 8O16 µ µNN A
Then M = 0 r 1 2
e → 10Ne20 l
A ∴ M increased, because for iron µr > > 1
= V(r) – V(R)
R1 = + 20; R2 → ∞ ; q 1 1
= –
1 1 1 4πε0 r R
= (µ2 – 1) −
f + 20 ∞ In this way, the potential of the outer shell increases
1 1 1 considerably.
= (2 –1) − (ii) Sharp pointed surfaces have larger charge
f 20 ∞
densities, so these can be used to set up discharging
∴ f = +20 cm action.
Conducting
OR S Shell
i
M C2
r
α β γ
P C I Grounded
O u R
v
Steal Insulating
Tank Column
µ1
µ2
By snell's law C1 , C2
metal
m1 sin i = µ2 sin r Comb H
But for small aperture MP; vR
µ1i = µ2r …(i)
In ∆OCM; i = α + β
Target
and In ∆ICM; β = r + γ ⇒ r = β – γ.
Working :Let spray comb C1 be charged to a high +ve
∴ By (i) potential which spray +ve charge to the belt which in
turn becomes positively charged. Since belt is
µ1 (α + β) = µ2 (β – γ)
moving up, so it carries this positive charge upward.
MP MP MP MP Opposite charge appears on the teeth of collecting
µ1 + = µ2 PC − PI comb C2 by induction from the belt. As a result of
OP PC
this, positive charge appears on the outer surface of
1 1 1 1 shell S. As the belt is
µ1 + = µ2 + R − + v moving continuously, so the charge on the shell S
− u + R
increase continuously. Consequently, the potential
µ1 µ1 µ 2 µ 2 of the shell (S) rises, to a very high value.
– + = − Now the charged particles at the top of the tub (T)
u R R v
are very high potential with respect to the lower end
µ 2 µ1 µ 2 − µ1 of the tube which is earthed. Thus these particles get
− =
v u R accelerated downward and hit the target emerging
from the tube.
Or 1 q
(i) Intensity of the Electric field at a point on the (in the direction BP) and E2 =
4πε0 K (r + l 2 )
2
Axis of a Diople :
l l (in the direction PA)
A B E2 P E1
The magnitude of E1 and E2 are equal (but directions
are different). On resolving E1 and E2 into two
–q O +q
r
components parallel and perpendicular to AB, the
components perpendicular to AB
The intensities E1 and E2 are along the same line in (E1 sin θ and E2 sin θ) cancel each other (because
opposite directions. Therefore, the resultant intensity they are equal and opposite) while the components
E at the point P will be equal to their difference and parallel to AB (E1 cos θ and E2 cos θ), being in the
in the direction BP (since E1 > E2). That is, same direction ,add up. Hence the resultant intensity
E = E1 – E2 of electric field at the point P is
1 q 1 q E = E1 cos θ + E2 cos θ
= –
4πε0 K (r – l) 2
4πε0 K (r + l) 2 1 q 1 q
= cos θ + cos θ
q 1 1 4πε0 K (r 2 + l 2 ) 4πε0 K (r 2 + l 2 )
= –
4πε0 K (r – l) 2 (r + l) 2 1 q
= 2 cos θ
4πε0 K (r + l 2 )
2
q ( r + l ) 2 – ( r – l) 2
= OB OB
4πε0 K (r 2 – l 2 ) 2 But from fig. cos θ = =
PB (OP + OB 2 )1/ 2
2
q 4lr l
= 2 2 2 = .
4πε0 K (r – l ) (r 2 + l 2 )1/ 2
1 2 (2 q l) r 1 q 2l
= ∴ E=
4πε 0 K (r 2 – l 2 ) 2 4πε0 K (r 2 + l 2 ) (r 2 + l 2 )1/ 2
But 2ql = p (electric dipole moment). 1 2ql
= .
1 2pr 4πε0 K (r + l 2 )3 / 2
2
∴ E=
4πε0 K (r – l 2 ) 2
2
But 2ql = p (moment of electric dipole).
If l is very small compared to r (l << r), then l may 2 1 p
E= .
be neglected in comparison to r2. Then the electric 4πε0 K (r 2 + l 2 )3 / 2
intensity at the point P due to the dipole is given by
If l is very small as compared to r ( l < < r), then l2
1 2pr 1 2p can be neglected in comparison to r2. Then the
E= = N/C.
4πε 0 K r 4 4πε 0 K r 3 electric intensity at the point P due to the dipole is
For vacuum (or air) K = 1. 1 p 1 p
E= = N/C.
1 2p 4πε0 K (r )2 3/ 2
4πε0 K r 3
∴ E= NC –1 …..(i)
4πε0 r 3 For vacuum (or air) K = 1
Intensity of the Electric Field at a point on the 1 p
NC –1 . …..(ii)
Equatorial Line of a Dipole. 4πε 0 r 3
E1
E2 The direction of the electric field E is parallel to the
θ E1 sin θ axis of the dipole from the positive charge towards
E P
the negative charge.
E2 Comparing eq. (i) and (ii) we see that for a short
θ dipole the intensity of the electric field on an axial
r P
E1 cos θ + point is twice the intensity at the same distance on
→ E2 cos θ the equatorial line.
P θ
A B (ii) W = Uf – Ui =PE (1 – cos θ) = PE (1 – cos 180°)
–q +q E2 sin θ
O
E2
= PE (1 + 1) = 2 PE
l l
t
2. 3-Amino-2-chloro butanamide
3. These are partly produced in body.
Ex. Histidine and arginine
4. yes, because O2 is paramagnetic
Or
5. In B.C.C no. of effective atoms are = 2
Let a source of alternating e.m.f. be connected to a
circuit containing a pure inductance only, Fig. In F.C.C no. of effective atoms are = 4
Suppose the alternating e.m.f. supplied is 6. In lyophillic colloids affinity is present between
represented by dispersed phase and dispersion medium and
E = E 0 sin ωt therefore it is more stable.
7. r = k [NO]2 [H2]
L
8. 6-Amino 3-chloro 4-hydroxy hexanamide
9. (i) Aldol condensation : Two molecules of an
aldehyde or a ketone having at least one α-hydrogen
atom, condense in the presence of a dilute alkali to
give β-hydroxy aldehyde or β-hydroxy ketone.
O OH
If dI/dt is the rate of change of current through L at
any instant, then induced e.m.f. in the inductor at the Dil. NaOH
CH3–C + HCH2CHO CH3–C–CH2CHO
same instant is = – L dI/dt . The negative sign
indicated that induced e.m.f. opposes the change of H H
current. To maintain the flow of current, the applied Ethanal Ethanal Aldol
voltage must be equal and opposite to the induced (ii) Gabriel phthalimide synthesis : Phthalimide on
voltage treatment with ethanoic KOH gives potassium
dI phthalimide which on heating with a suitable alkyl halide
i.e. E = – – L = Eo sin ωt
dt gives N-substituted phthalimides. These upon hydrolysis
with dil HCl under pressure give primary amines.
E0
or dI = sin ω t dt CO
L
NH + KOH (alc)
Integrating both sides, we get –H2O
CO
E
L ∫
I = 0 sin ωt dt Phthalimide
E 0 cos ωt E C2H5I, ∆
CO
= – = – 0 cos ωt
L ω ωL N–H+
–KI
E0 π CO
=– sin – ωt Pot. Phthalimide
ωL 2
E CO
or I = 0 sin (ωt – π/2) …(i) H+ / –H2O
ωL N–C2H5
The current will be maximum i.e. I = I0, when sin CO
(ωt– π/2) = maximum = 1. N-Ethylphthalimide
E0 COOH
From (i), I0 = ×1 …(ii)
ωL C2H5NH2 +
Putting in (i), we get COOH
I = I 0 sin(ωt – π / 2) Ethylamide Phthalic acid
This is the form of alternating current developed.
sin( x − a + a )
14. ∫ sin( x − a)
dx
dt x 2 + y 2 = 2( x + yy ' ) x
∫ (t − 1) 2 − 22 OR
Let P(x, y) be any point on the curve. The equation of
log | (t − 1) + (t − 1) 2 − 2 2 | +c replace t the normal at P (x, y) to the given curve is
1
Y–y=– (X –x) … (i)
16. take log dy / dx
m log x + n log y = (m + n) log (x + y) It is given that the normal at each point passes through
m n dy (m + n) dy (2, 0). Therefore, (i) also passes through (2, 0). Putting
diff. + = 1 + Y = 0 and x = 2 in (i), we get
x y dx x + y dx
1
nx − my dy nx − my dy 0–y=– (2 –x)
⇒ = ⇒ = y/x dy / dx
y ( x + y ) dx ( x + y ) x dx
dy
⇒y =2–x
17. C1 → C1 + C2 + C3 dx
1 −a+b −a+c ⇒ ydy = (2 – x) dx [On integrating both sides]
(a + b + c) 1 3b −b+c y 2
(2 − x) 2
⇒ =– +C
1 −c+b 3c 2 2
R2 → R2 – R1, R3 – R1 ⇒ y2 = – (2 – x)2 + 2C … (ii)
1 −a+b −a+c This passes through (2, 3). Therefore,
(a + b + c) 1 2b + a − b + a 9
9 = 0 + 2C ⇒ C =
2
1 − c + a 2c + a
9
(a + b + c) [(2b + a) (2c + a) – (a – b) (a – c)] Putting C = in (ii), we get
2
put x = tan θ
→
–1 2 tan θ ⇒ r = 2iˆ − 3 ˆj − 5kˆ + t (6iˆ − 3 ˆj + 5kˆ) ….(ii)
y = sin 2
1 + tan θ Now line (2) meets the plane (1), when
i.e. when 50
6 (2 + 6t) + 3 (3 + 3t) + 5 (5t – 5) = –2
(0, 40) 40 C
1
i.e. when t =
35
Substituting this value of t in (2), we get 30
→ 1 ˆ
r = 2iˆ − 3 ˆj − 5kˆ + (6i − 3 ˆj + 5kˆ) A (0, 20)
35 20
50 40
P ,
1
= (76iˆ − 108 ˆj − 170kˆ) 3 3
35 10
∴ The required point of intersection is D(25,0) B
X
O 10 20 30 40 50
76 − 108 − 170 I
35 , 35 , 35
II
25. Let the distance covered at the speed 25 km/hour = x km The coordinates of feasible region is A (0, 20)
and the distance covered at the speed 40 km hour 50 40
P , , D (25, 0)
= y km 3 3
maximum distance z = x + y Corner points z=x+5
subject to constraints
A (0, 20) z = 0 + 20 = 20
2x + 5y ≤ 100
50 40 50 40
x y P , z= + = 30
+ ≤1 3 3 3 3
25 40
D (25, 0) z = 25 + 0 = 25
x, y ≥ 0
∴ Max. distance covered = 30 km 50/3 km at the
Table for 2x + 5y = 100 …(i)
speed of 25 km/hour and 40/3 km at the speed of
40 km/hour
x 0 50
3
y 20 0 26. Ist part : Area = ∫ 0
[(2 x − x 2 ) − (− x)] dx
x y
Table for + =1 3x 2 x 3
3
25 40 = −
x 0 25 2 3
0
y 40 0 area = 9/2
x y
Plot lines 2x + 5y = 100 and + = 1 on a graph
25 40
paper. The shaded region satisfy the given
inequalities.
(2, 0)
(0, 0)
(3, –3)
2nd part :
Both curve intersect at
(2 3 ,2), (−2 3 ,2)
By property x 1
π/ 2 ⇒ X = y = − 1
I= ∫ 0
log cos x dx …(2)
z 1
x = –1, y = –1, z = 1
π/ 2 sin 2 x
2I = ∫ 0
log
2
dx
29. Let length, width → x
π/2 π/2 height → y
2I = ∫ 0
log sin 2 xdx − (log 2) ∫0
dx
volume v = x2y …(1)
π are s = x2 + 4xy …(2)
2I = I1 – log2 …(3)
2 4v
s = x2 + (from (1), (2))
Now In I1 2x = t x
dx = 1/2 dt ds 4v d 2 s 8v
= 2x – 2 , = 2+ 3 > 0
1 π 2
I1 =
2 ∫ 0
log sin t dt dx x
ds
dx x
4v
1 π/ 2 Now = 0 ⇒ 2x – 2 = 0
= .2
2 ∫ 0
log sin t dt
⇒ x = 2y
dx x
(Q v = x2y)
I1 = I
…(4)
From (3), (4), 2I = I – π/2 log 2
I = – π/2 log 2
C1V1 + C 2 V2 R1 R 3
17. (i) Vcom = 23. =
C1 + C 2 R2 R4
Torsion Head OR
Consider two infinitely long thin conductors
Phosphor carrying currents in opposite directions.
Bronze Magnetic field B1 due to I1 at P on conductor CD is
given by
µ I
B1 = 0 1
Mirror 2πr
Copper coil B I1 D
Frame
Q P
N S
F1B2 B1F2
r
I2
Core A C
T2
Spring The magnetic field B1 is perpendicular to plane of
paper and directed inward. This field will produce a
Working : When a current is passed through the force/length F2 on conductor given CD by
coil, the two vertical limbs experience a force normal
H H
Ethanal Ethanal Aldol
Manganous
CH 3CHO + [O] → CH 3COOH CH 3 COO − + Cu 2 O+ H 2 O
Acetate red ppt .
Acetaldehyde Acetic acid
(ii) The boiling points of aldehydes and ketones are 30. (i) Cl2 > Br2 > F2 > I2 (due to exceptionally small size
lower than corresponding acids and alcohols due to of F, F2 has lower bond energy than expected)
absence of intermolecular hydrogen bonding . (ii) HF < HCl < HBr < HI (according to bond length)
(iii) Aldehydes and ketones undergo a number of (iii) NH3 > PH3 > AsH3 > SbH3
addition reactions as both possess the carbonyl (according to density of lonepair on central atom)
functional group which reacts a number of (iv) H2O > H2Te > H2Se > H2S
nucleophiles such as HNC, NaHSO3, alcohols, (according to strength of intermolecular bonding)
ammonia derivatives and Grignard reagents. (v) HOCl < HClO2 <HClO3 < HClO4
(according to no. of O atoms attached to Cl)
= – 6 î + 10 ĵ – 6 k̂
Section A AD = ( 2 î + 5ˆj + 10 k̂ ) – ( 6 î – 7 ĵ )
= – 4 î + 12 ĵ + 10 k̂
1. y = A cos (x + B)
dy 10 – 22 – 4
= – A sin (x + B)
dx Now ∆ = – 6 10 – 6
d2y – 4 12 10
= – A cos (x + B)
dx 2 Operate R1 → R1 + R2 + R3
2 2
d y d y 0 0 0
2
=–y⇒ 2
+y=0
dx dx = – 6 10 – 6 = 0
– 4 12 10
∫ cos x / 4 + sin x / 4 + 2 sin x / 4 cos x / 4 dx
2 2
2.
⇒ The points A, B, C and D are coplanar.
∫ (cos x / 4 + sin x / 4) dx = 4 sin (x/4) – 4 cos (x/4) + c 6. Put x = a sin θ
→ →
3. a = iˆ – 2 ˆj + 3kˆ ; b = iˆ – 3kˆ , a sin θ
= tan–1
→ a cos θ
⇒ 2 a = 2iˆ – 4 ˆj + 6kˆ
= tan–1 (tan θ) = θ
iˆ ˆj kˆ x
→ →
∴ b ×2 a = 1 0 –3 = sin–1
a
2 –4 6
7. g (f(x)) = |5 f(x) – 2|
= – 12iˆ – 12 ˆj – 4 kˆ
| 5x – 2 |, x ≥ 0
= – 4(3iˆ + 3 ˆj + kˆ) = | 5 | x | – 2| =
→ →
| –5x – 2 |, x < 0
⇒ | b × 2 a | = | – 4(3iˆ + 3 ˆj + kˆ) |
8. (A3×4 ⋅ B4×2 ) . C2×3
= 4 3 2 + 3 2 + 12 = 4 19 = (X)3×2 . C2×3
→ → = (Y)3×3 ∴ final order = 3 × 3
4. a = iˆ + 2 ˆj – 3kˆ , b = 3iˆ – ˆj + 2 kˆ
→ →
⇒ a + b = 4iˆ + ˆj – kˆ , 9. x + 2 = – (2 × –3) ⇒ 3x = 1 ⇒ x = 1/3
→ →
a – b = 2iˆ + 3 ˆj – 5kˆ
→ → → → 10. 2 – 20 = 2x2 – 24 ⇒ 2x2 = 6 ⇒ x=± 3
( a + b ) . ( a – b ) = ( 4iˆ + ˆj – kˆ ).( 2iˆ + 3 ˆj – 5kˆ )
= 4 × (– 2) + 1 × 3 – 1 × (– 5)
=–8+3+5=0 Section B
→ → → →
⇒ a + b is perpendicular to a – b .
11. Let A and B denote the two events respectively
5. Let the position vectors of A, B, C, D be 6 î – 7 ĵ , 5 5 6 6
P( A ) = = , P(B) = =
5+2 7 6 + 5 11
16 î – 29 ĵ – 4 k̂ , 3 ĵ – 6 k̂ and 2 î + 5ˆj + 10 k̂ 5 2 6 5
P(A) = 1 – = , P( B ) = 1 – =
respectively. Then 7 7 11 11
AB = OB – OA P(At least one of A and B happens)
= 1 – P(none of A and B happens)
= ( 16 î – 29 ĵ – 4 k̂ ) – ( 6 î – 7 ĵ ) = 1 – P (A ∩B)
= 10 î – 22 ĵ – 4 k̂ 5 5 52
=1– × =
7 11 77
∫
2x
dx
Let tan x = t
2
I.F. = e 1+ x 2 = e ln (1+ x )
= 1 + x2 sec2x dx = dt
4x 2 dt
Solution is : y (1 + x2) = ∫ 1+ x 2
(1 + x2) dx + c
∫ (t – 2)(2t + 1)
4x 3 1 dt
y(1+x2) =
3
+c ∫
2 ( t – 2)( t + 1 / 2)
x (2 + x ) – 1 1 2 1 1
13. ∫e 2
(2 + x )
dx . ∫–
2 5 t – 2 t + 1 / 2
dt
1 – 1 1 ( t – 2)
∫e + dx log +c
x
2 5 ( t + 1 / 2)
2 + x (2 + x )
↓ ↓
15. Position vector of A is
f(x) f ′(x)
1 3î + ĵ + 2 k̂ ⇒ A (3, 1, 2)
= ex . +c
2+ x Position vector of B is
OR î – 2 ĵ − 4 k̂ ⇒ B(1, –2, – 4)
2x d.r.s of the line AB are 3, –1, 1 – (– 2), 2 – (– 4)
∫ 2
1 − x − (x ) 2 2
dx
i.e. 2, 3, 6
∴ Eq. of the required plane through B and
dt
Let x2 = t. Then, d(x2) = dt ⇒ 2x dx = dt ⇒ dx = perpendicular line AB is
2x
2 (x – 1) + 3 (y + 2) + 6 (z + 4) = 0
dt dt
∴I= ∫ 1− t − t 2
= ∫ 2
− {t + t − 1}
⇒ 2x + 3y + 6z + 28 = 0
→ → →
dt a = î – 3 ĵ + k̂ , b = î – ˆj + k̂ and c = 2 î – ˆj – k̂
= ∫ 1 1
16.
− {t 2 + t + − − 1} î ĵ k̂
4 4 → →
dt dt b × c = 1 – 1 1 = 2 î + 3 ĵ + k̂
⇒Ι= ∫ 1 2 5
= ∫ 5 1
2 2 –1 –1
− t + − − t +
4 2 → → →
2 4
∴ L.H.S = a × ( b × c )
0 1 x+ y 1/ 2 1
= (x – y) (y – z) 0 1 y + z
A = 2
∫ 0
1 – ( x – 1) 2 dx + ∫1/ 2
1 – x 2 dx
1 z z2
1 1
1/ 2
1 x+ y A = 2 ( x – 1) 1 – ( x – 1) 2 + sin –1 ( x – 1)
= (x – y) (y – z) 2 2 0
1 y+z
= (x – y) (y – z) [(y + z) – (x + y)]
1
1 1 2π 3
= (x – y) (y – z) (z – x) + x 1 – x 2 + sin –1 x = –
2 2 1/ 2 3 2
5
= . π π
9
Now, second bag contains 8 white and 9 black balls. 0
∫ 0
∫
By property f ( x ) dx = f (π – x ) dx
The probability of drawing a white ball from the
8 8 eqn (1) + (2)
second bag = = .
8+9 17 π
ecos x + e – cos x
∴ The probability of both these events taking place
5 18 40
2I= ∫
0
e cos x
+ e – cos x
dx ⇒ I = π/2
together is = × =
9 17 153 2nd Part
Case II : When a black ball is transferred from the Ist
π/ 4 π/ 4
bag to the second probability of getting black ball dx dx
from Ist bag =
4 4
= .
I= ∫
–π / 4
2 – cos 2 x
dx + π / 4 ∫ 2 – cos 2x
–π / 4
5+4 9
π/ 4
Draw the lines
sec 2 x
= 2π / 4 ∫1
0
2
+ ( 3 tan x ) 2
[Q f(x) is even function] 2x + y = 140
3x + 5y = 350
..... (1)
..... (2)
The shaded unbounded region is the feasible region.
dt
Let 3 tan x = t ⇒ sec2x dx = These line meet at P(50, 40)
3
Now value of c = 5x + 8y
3 350 1750 1
=
π
2 ∫
dt / 3
1+ t2
= π / 2 3 tan –1 t ( )0
3
=
π2
6 3
at C
3
,0 , is
3
= 583
3
0 at P(50, 40) is 570
at B(0, 140) is 1120
26. The given lines are
→
∴ The cost is minimum at P(50, 40)
r = ( î – 2 ĵ + 3k̂ ) + t ( – î + ˆj – 2 k̂ ) This occurs when 50 kg of type & fertilizer and 40
→ kg of type B fertilizer are mixed to the meet the
and r = ( î – ˆj – k̂ ) + s ( î + 2 ĵ – 2 k̂ ) requirement.
→ →
Part 2nd
Here a1 = î – 2 ĵ + 3k̂ ; b1 = – î + ˆj – 2 k̂
→ → Let x and y represent the number of tables and chairs
a 2 = î – ˆj – k̂ ; b 2 = î + 2 ĵ – 2 k̂ respectively that the dealer sells and P be the profit
of the dealer. Then the required LPP is .
î ĵ k̂
→ → Maximize: P = 50x + 15y
∴ b1 × b 2 = – 1 1 – 2 = 2 î – 4 ĵ – 3k̂
Subject to the constraints
1 2 –2
500x + 200 y ≤ 10,000 ⇔ 5x + 2y ≤ 100
The S.D. between the gives lines x + y = 60 ....(1)
5x + 2y = 100 .... (2)
→ → → →
(b1× b 2 ).(a 1 – a 2 ) (2 î – 4 ĵ – 3k̂).( ĵ – 4 k̂) y
= =
| b1 × b 2 | | 2 î – 4 ĵ – 3k̂ | B(0, 60)
D
(0, 50)
4 + 12 8
= =
2
2 +4 +3 2 2 29 A(60, 0)
x
O C (20, 0) (1)
27. Part Ist (2)
Let x kg and y kg. of fertilizer A and B be mixed by A shaded region OCD is the feasible region.
the farmer. Then LPP is Now P = 50x + 15y
Minimize : C = 5x + 8y At O, value of P is O
subject to the constraints
At C, value of P is 50 × 20 = 1,000
10 5
x + y ≥ 7 ⇔ 2x + y ≥ 140 At D, value of P is 15 × 50 = 750
100 100
∴ Profit is maximum at C (20, 0)
6 10
x + y≥ 7 ⇔ 3x + 5y ≥ 350
100 100
C HE M ISTR Y
Ques 1 2 3 4 5 6 7 8 9 10
Ans B A A C B B C A A B
Ques 11 12 13 14 15 16 17 18 19
Ans C A D B D A C C C
20 A → P,S B→S C→Q D →RP
Column
21 A→S B→P C→Q D→R
Matching
22 A → P,Q B→P C → P,Q,R D→S
MATHEMATICS
Ques 1 2 3 4 5 6 7 8 9 10
Ans B D C B B C A D C D
Ques 11 12 13 14 15 16 17 18 19
Ans C D A A C B B C A
20 A→S B→Q C→P D→R
Column
21 A→S B→R C→P D→P
Matching
22 A→R B→S C→Q D→P
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"XtraEdge for IIT JEE" magazine makes sure you're updated & at the forefront.
Every month get the XtraEdge Advantage at your door step.
✓ Magazine content is prepared by highly experienced faculty members on the latest trend of the IIT JEE.
✓ Predict future paper trends with XtraEdge Test Series every month to give students practice, practice & more practice.
✓ Take advantage of experts' articles on concepts development and problem solving skills
✓ Stay informed about latest exam dates, syllabus, new study techniques, time management skills and much more XtraFunda.
✓ Confidence building exercises with Self Tests and success stories of IITians
✓ Elevate you to the international arena with international Olympiad/ Contests problems and Challenging Questions.
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