(4104) DPP 32 50 B PDF

ORG./INO.
CHEMISTRY
TARGET : JEE (Main + Advanced) 2017
Course : VIKAAS (JA) NO. 32 & 33
This DPP is to be discussed in the week (28-09-2015 to 03-10-2015)
1. Course of the week as per plan : Inductive Effect, Resonance.

2. Course covered till previous week : Hydrogen Bonding.
3. Target of the current week : Inductive Effect, Resonance.
4. DPP Syllabus : Inductive Effect, Resonance.
DPP No. # 32 (JEE-ADVANCED)
Total Marks : 79 Max. Time : 48 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.5 (3 marks, 2 min.) [15, 10]
Multiple choice objective ('–1' negative marking) Q.6 to Q.10 (4 marks, 2 min.) [20, 10]
Integer type Questions ('–1' negative marking) Q.11 to Q.14 (4 marks 3 min.) [16, 12]
Match the Following (no negative marking) Q.15 (8 marks, 6 min.) [08, 06]
ChemINFO : 5 Questions ('–1' negative marking) Q.16 to Q.20 (4 marks, 2 min.) [20, 10]
1. In which of the following compounds the direction of Inductive-effect is not correct ?

fuEu ;kSfxdksa esa ls fdlesa izsjf.kd izHkko dh fn'kk lgh ugha gS ?
CH = CH2
COONa
(A) (B) (C*) (D)
OH
C  CH
Sol.
2. –CH2–CH2–O –O –CH2–O

  
Among these groups, which of the following orders is correct for the magnitude of their + effect ?
fuEufyf[kr lewgksa ds + izHkko ds ifjek.k dk lgh Øe dkSulk gS ?
(A) > >  (B) > >  (C) > >  (D*) > > 
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : [email protected]
PAGE NO.- 1
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3. Which of the following statement is CORRECT regarding the inductive effect?
(A) electron-donating inductive effect(+I effect) is generally more powerful than electron-withdrawing inductive
effect(-I effect)
(B) it implies the shifting of  electrons from more electronegative atom to the lesser electronegative atom in
a molecule
(C*) it implies the shifting of  electrons from less electronegative atom to the more electronegative atom in
a molecule
(D) it increases with increase in distance.
izsjf.kd izHkko ls lEcfU/kr dkSulk dFku lR; gS \ [General Organic Chemistry]
(A) bysDVªksu
nsus okyk izsjf.kd izHkko (+ I izHkko) lkekU;r;k vf/kd izHkkoh gksrk gS bysDVªkWu [khpus okys izsjf.kd (–I izHkko ls)
(B) bl ?kVuk esa v.kq esa vf/kd fo|qr_.kh ijek.kq ls de fo|qr_.kh ijek.kq dh vksj  bysDVªkWu dk LFkkukUrj.k gksrk gSA
(C*) bl ?kVuk esa v.kq esa de fo|qr_.kh ijek.kq ls vf/kd fo|qr_.kh ijek.kq dh vksj  bysDVªkWu dk LFkkukUrj.k gksrk gSA
(D) ;g nwjh c<+us ds lkFk c<+rk gSA
4. What is the % s character in hybridisation of carbon when it exerts strongest –I effect ?

tc dkcZu ijek.kq lcls izcy –I izHkko n'kkZrk gS rks blds ladj.k esa % s y{k.k D;k gksxk \
(A) 25% (B*) 50% (C) 75% (D) 100%

5. –OH  SR2 –Br –CN
I II III IV
Among these groups, which of the following orders is correct for the magnitude of their – effect ?
fuEufyf[kr lewgksa ds – izHkko ds ifjek.k dk lgh Øe dkSulk gS ?
(A) V> > I (B) > V> III (C) > > VI (D*) >IV > >I
6. Which order of I effect is/are incorrect. (fuEu esa ls I izHkko dk xyr Øe gS@gSa%)
 
(A*)  NH3 > – S(CH3 )2 [–I] (B*) –NH2 > –NHCH3 [–I]
(C*) –OH > –Cl [–I] (D) –CD3 > –CH3 [+I]
7. Maximum–I effect group than the group –C  C – CH3 are

fuEu esa ls fdldk –I izHkko –C  C – CH3 gS \
(A*) OH (B*) –OCH3 (C*) –NO2 (D) –NH2
8. Which of the following statements is correct about inductive effect ?

(A*) Inductive effect is distance dependent and decreases drastically on increase in distance.
(B*) Inductive effect is transmitted through -bond.
(C) Inductive effect is transmitted through -bond
(D*) Inductive effect is permanent effect
izsjf.kd izHkko ds fo"k; esa fuEu esa ls dkSulk dFku lgha gS \
(A*) izsjf.kd izHkko nwjh ij fuHkZj djrk gS rFkk nwjh c<+us ij blesa vR;f/kd deh vkrh gSA
(B*) izsjf.kd izHkko -ca/k }kjk LFkkukUrfjr gksrk gSA
(C) izsjf.kd izHkko -ca/k }kjk LFkkukUrfjr gksrk gSA (D*) izsjf.kd izHkko LFkk;h izHkko gksrk gSA
9. In which of the following species, correct direction of inductive effect are shown ?
fuEu esa ls dkSulh lajpukvksa esa izsjf.kd izHkko dh fn'kk dks lgh iznf'kZr fd;k x;k gS\
(A*) (B) (C*) (D*)
Sol. Case B has incorrect direction of I effect. (fodYi B esa I izHkko dks xyr fu:fir fd;k x;k gSA½
PAGE NO.- 2
10. Which of the following are + I group
fuEu esa ls dkSulk@dkSulsa + I lewg gS@gSa &
  
(A*)  NH (B) (C*)  CH2 (D)  N  N
3 2 1
11. On which C of CH3 – CH2 – CH2 – Br , the inductive effect is expected to be the maximum.
3 2 1
CH3 – CH2 – CH2 – Br ds dkSuls dkcZu ij izsjf.kd izHkko vkisf{kd :i ls vf/kdre gksrk gsSA
Ans. 1
12. How many groups show – effect? [General Organic Chemistry]

fuEu esa ls fdrus lewg – izHkko n'kkZrs gSa\

–CH3 ,  NH3 , –OH, –O , –N(CH3)2 , –SO3H, –CHO, –Cl, –COO
Ans. 6
13. How many of the following molecules are polar? [Ref. SM Sir] [M]
fuEu esa ls fdrus v.kq /kqzoh; gSa\
(i) CO2 (ii) SO2 (iii) NO2 (iv) SOCl2
(v) COCl2 (vi) BeCl2(g) (vii) TeCl4 (viii) CCl4
(ix) ClO2
Ans. 06
Sol. CO2 O= C=O = 0 ; SO2 SO2 0

sp
NO2 =O  0 ; SOCl2 0
COCl2  0 ; BeCl2 Cl – Be – Cl = 0
TeCl4  0 ; CCl4 0
ClO2 0
14. How many of the following will exhibit Hydrogen bonding in water ? [E] (CBO)
fuEu esa ls fdrus ty esa gkbMªkstu vkca/k n'kkZ;sxsa \
CH3CN, C6H5OH, D2O, H3PO3, SO3, CO2, F2, KF, CH3COOH, CH3OCH3.
Ans. 10
15. Match the column-

Column-I Column-II
(A) HCl < HF (p) Intermolecular forces
(B) PH3 < NH3 (q) Dipole moment
(C) H2 O < D2 O (r) Boiling point
(D) H2 S < H2 O (s) Molar mass
PAGE NO.- 3
feyku dhft,A
dkWye -I dkW ye -II
(A) HCl < HF (p) vUrjkvkf.od cy
(B) PH3 < NH3 (q) f}/kzqo vk?kw.kZ
(C) H2 O < D2 O (r) DoFkukad
(D) H2 S < H2 O (s) eksyj nzO;eku
Ans. (A – p, q, r) ; (B – p, q, r) ; (C – p, q, r, s) ; (D –p,q,r)
Sol. (A) In HF hydrogen bonding takes place so has higher b.p. and dipole moment is more than HCl due to more
polarity of H — F bond.
(B) In NH3 hydrogen bonding takes place so has higher b.p. which is absent in PH3.
(C) In D2O dipole moment, H – bonding and b.p. is more than H2O as D is less electronegative than hydrogen.
(D) In H2O hydrogen bonding is present. So has higher b.p. Also O — H bond is more polar. So H2O has
higher dipole moment.
(A) HF esa gkbMªkstu cU/ku izkIr gksrk gS vr% ;g mPp DoFkukad j[krk gS rFkk bldk HF ca/k dh vf/kd /kqzo.krk ds dkj.k
HCl ls vf/kd f}/kzqo vk?kw.kZ gksrk gSA
(B) NH3 esa gkbMªkstu cU/ku izkIr gksrk gS vr% ;g mPp DoFkukad j[krk gS tksfd PH3 esa vuqifLFkr gSA
(C) gkbMªkstu dh vis{kk D de fo|qr_.kh gksus ds dkj.k D2O esa] H2O dh vis{kk f}/kzqo vk?kw.kZ] H-ca/ku rFkk DoFkukad vf/
kd gksrk gSA
(D) H2O esa gkbMªkstu cU/ku mifLFkr gksrk gSA vr% ;g mPp DoFkukad j[krk gS] H–O ca/k Hkh vf/kd /kqzoh; gksrk gSA vr%
H2O mPp f}/kqzo vk?kw.kZ j[krk gSA
PAGE NO.- 4
ChemINFO-4.2 POSITIVE CHARGE DELOCALISATION
Daily Self-Study Dosage for mastering Chemistry Positive Charge Delocalisation
1. Positive charge is on conjugation or delocalisation when :

(1) Adjacent atom should have negative charge
   
e.g. A  B  A  B NH  CH2  NH  CH2
(2) Adjacent atom should have bond
  
 
e.g. X  Y  Z  X  Y  Z CH2  CH – CH2  CH2 – CH  CH2
(3) Adjacent atom should have lone pair
   ..  
e.g. A  B  A  B H2 N C H2  H2 N  CH2
Note : (i) If positive charge present on IInd period element which have complete octate then it is not delocalised .
; ; ;
(ii) If  bond and positive charge both are present on same atom of IInd period then it is delocalised .
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
16. In which of the following molecule positive charge is not in conjugation ?
(A) (B) (C*) (D*)
17. In which of the following molecule positive charge is delocalised ?
(A) (B) (C) (D*)
18. Which of the following molecule positive charge is not delocalised ?
(A) (B)
(C*) (D)
PAGE NO.- 5
19. In which of the following molecule positive charge is not in conjugation ?
(A) (B*) (C) (D)
20. Which positive charge stabilised by resonance ?


(A) CH2=CH– NH3 (B) (C*) (D)
ChemINFO-4.2 POSITIVE CHARGE DELOCALISATION

Daily Self-Study Dosage for mastering Chemistry Positive Charge Delocalisation
1. la;qXeu ds nkSjku /kukos'k dk foLFkkuhdj.k rc gksrk gS tc :

(1) lehiLFk ijek.kq ij _.kkos'k gksrk gS %
   
e.g. A — B  A  B NH — CH2  NH  CH2
(2) lehiLFk ijek.kq ij  cU/k mifLFkr gksrk gS %

  
 
e.g. X  Y – Z  X – Y  Z CH2  CH – CH2  CH2 – CH  CH2
(3) lehiLFk ijek.kq ij ,dkdh ;qXe mifLFkr gksrk gS %

   ..  
e.g. A — B  A  B H2 N C H2  H2 N  CH2
Note : (i) ;fn /kukRed vkos'k IInd vkoÙkZ RkRo] tks iw.kZ v"Bd j[krk gS ij mifLFkr gksrk gS rks ;g foLFkkuhd`r ugh gksrk gSA
; ; ;
(ii) ;fn  cU/k o /kukRed vkos'k nksuks IInd vkoÙkZ ds leku ijek.kq ij mifLFkr gksrk gS rks ;g foLFkkuhd`r gksrs gSA
PAGE NO.- 6
16. fuEu es ls dkSuls v.kq esa /kukRed vkos'k la;qXeu es ugh gS \
(A) (B) (C*) (D*)
17. fuEu es ls fdl v.kq esa /kukRed vkos'k foLFkkuhd`r gksrk gS \
(A) (B) (C) (D*)
18. fuEu es ls dkSuls v.kq esa /kukRed vkos'k foLFkkuhd`r ugha gksrk gS \
(A) (B)
(C*) (D)
19. fuEu es ls fdl v.kq esa /kukRed vkos'k la;qXeu es ugh gS \

(A) (B*) (C) (D)
20. fuEu es ls dkSulk /kukRed vkos'k vuqukn }kjk LFkk;h gksrk gS \


(A) CH2=CH– NH3 (B) (C) (D)
PAGE NO.- 7
DPP No. # 33 (JEE-MAIN)
1. Which of the following is not acceptable resonating structures of Buta-1, 2, 3-triene.

fuEu esa ls dkSulh vuquknh lajpuk C;wVk-1, 2, 3-VªkbbZu ds fy, ekU; ugh gS \ [General Organic Chemistry]
(A) (B) CH2 = C = C = CH2
(C) (D*)
Sol. (A,B,C,) CH2 = C = C = CH2
2. Which of the following is a conjugated system ?

fuEu esa ls dkSu ,d la;qXeh ra=k gS \
(A) CH2=C=C=CH2 (B) CH2=C=O
(C) CH2=CH–CH=O (D*) All of these mijksDr lHkh
3. Resonance is not possible in :

fuEu esa ls fdl essa vuqukn laHko ugha gS \ [General Organic Chemistry]

(A) CH2 = NH2 (B*) CH3CH = C = CH2 (C) (D)
4. Which of the following does not represent the resonating structure of [GOC - EE]
fuEu esa ls dkSulh lajpuk ;kSfxd] dh vuquknh lajpuk dks iznf'kZr ugha djrh gS \
(A) (B*)
(C) (D)
5. In which case the unshared pair (lone pair) of electrons is not delocalized.
fuEu esa ls dkSulh lajpuk esa vlk¡f>r (unshared) ,dkdh bysDVªkWu ;qXe dk la;qXeh rU=k esa foLFkkuhdj.k(delocalize)
ugh gksrk gS \ [General Organic Chemistry]
(A) (B*) H2C = – CH3 (C) H2C = = (D)
Sol. Lone pair of electrons of H2C = – CH3 is in sp2 hybrid orbital.

H2 C = – CH3 dk ,dkdh bysDVªkWu ;qXe sp2 ladfjr d{kd esa gSA
6. Which of the following statements is true about resonance.

(A) In resonating structure hybridisation of atom will be change.
(B*) Cannonical structures are imaginary
(C) Cannonical structure explains all features of a molecule
(D) In resonating structures position of nuclei change.
PAGE NO.- 8
vuqukn ds fo"k; esa fuEu esa ls dkSulk dFku lgh gS \
(A) vuquknh lajpuk esa] ijek.kq dk ladj.k ifjofrZr gks tkrk gSA
(B*) dSuksfudy lajpuk,sa dkYifud gksrh gSA
(C) dSuksfudy lajpuk fdlh v.kq ds leLr y{k.kksa dh O;k[;k djrh gSA
(D) vuquknh lajpukvksa esa] ukfHkd dh fLFkfr ifjofrZr gksrh gSA
   
7. CH2  CH  CH  CH2 CH2  CH  CH  CH2 CH2  CH  CH  CH2
I II III
Among these which are cannonical structures ?
(A) and  (B) and  (C) and  (D*) all of these
   
CH2  CH  CH  CH2 CH2  CH  CH  CH2 CH2  CH  CH  CH2
I II III
fuEu esa ls dkSulh lajpuk,sa dSuksfudy lajpuk,sa gS \
(A) rFkk  (B) rFkk  (C) rFkk  (D*) mi;qZDr lHkh
8. [General Organic Chemistry]
I II III
The correct statement about the above structures is :
(A) II is the minor contributor to the real hybrid.
(B) III is most stable structure
(C) I contributes more to the real hybrid than that of II.
(D*) I and II are equal contributors and III is a minor contributor.
mijksDr lajpukvksa ds fy, lgh dFku gS %
(A) II lajpuk dk ;ksxnku okLrfod ladfjr esa lcls de gSA
(B) III lcls LFkk;h lajpuk gSA
(C) okLrfod ladfjr lajpuk esa I dk ;ksxnku II ls vf/kd gSA
(D*) I ,oa II dk ;ksxnku cjkcj rFkk III dk ;ksxnku de gSA
9. Which of the following is not correctly orderd for resonance stability. [General Organic Chemistry]
fuEu esa ls dkSuls fodYi vuquknh lajpuk ds LFkkf;Ro ds fy;s lgh ugha n'kkZ;s x;s gSA
(A) (II > I > III)
(B) (I > III > II)
(C*) (I > II)
(D) (II = I)
 
Sol. CH3 — C  O  CH3 – C  O
(I) (II)
Stability II > I due to No. of  bonds.
PAGE NO.- 9
10.
The least stable cannonical structure among these is :

mijksDr lajpukvksa esa ls dkSulh lajpuk U;wure LFkk;h dSuksfudy lajpuk gS %
(A) I (B*) II (C) III (D) IV
11. The most stable resonating structure is : [General Organic Chemistry]

lcls vf/kd LFkk;h vuquknh lajpuk gS %
(A) (B*)
(C) (D)
12. Which of the following compound is not a resonance stablized ?

fuEu esa ls dkSulk ;kSfxd vuqukn }kjk LFkk;h ugha gS \
(A) (B) (C*) (D)
13.
In above carbanion electron is transfered in :

mijksDr dkcZ_.kk;u Lih'kht ds fdl d{kd esa bysDVªkWu dk LFkkukUrj.k gksrk gS \
(A) p-orbital (B*) d-orbital (C) s-orbital (D) f-orbital
(A) p-d{kd (B*) d-d{kd (C) s-d{kd (D) f-d{kd
14. Which of the following molecule donot exhibit resonance ?

fuEu esa ls dkSulk v.kq vuqukn ugha n'kkZrk gS \ (Made by RGP SIR on April2014)(Resonance(O))
(A*) H2C=C=CH2 (B) H2C=C=C=CH2 (C) H2C=C=O (D) NC-HC=CH-CN
Sol. In H2C=C=CH2 multiple bonds are not in conjugation.
H2C=C=CH2 esa cgqy ca/k esa la;qXeu ugha ik;k tkrk gSA
15. Which of the following pairs does not represent resonating structures ?
fuEu esa ls dkSulk ;qXe vuquknh lajpuk ugha n'kkZrk gS \ (Made by RGP SIR on April2014) (Resonance(O))
     O   O
(A) CH3– C  N – O and ¼rFkk½ CH3– C = N – O (B) CH2=N and ¼rFkk½ CH2–N
O O

    O O–H
(C) CH2= N = N and ¼rFkk½ C H2 – N  N (D*) C6H5–C  and ¼rFkk½ C6H5–C
NH3 NH2
Sol. In resonating structures position of atoms should not change.
vuquknh lajpukvksa esa ijek.kqvksa dh fLFkfr ifjofrZr ugha gksrh gSA
PAGE NO.- 10
ChemINFO-4.3 MESOMERIC EFFECT
Daily Self-Study Dosage for mastering Chemistry Mesomeric effect
Mesomeric effect :
Mesomeric effect is defined as permanent effect of  electron shifting from multiple bond to atom or from multiple
bond to single bond or from lone pair to single bond. This effect mainly operates in conjugated system of double
bond. So that this effect is also known as conjugate effect.
Types of Mesomeric effects :

(a) Positive Mesomeric effect (+m effect) :
When the group donates electron to the conjugated system it shows + M effect.
Relative order of +m groups (usually followed) :
– O > –NH2 > –NHR > –NR2 > –OH > –OR > –NHCOR > –OCOR > –Ph > –F > –Cl > –Br > –I > –NO
(b) Negative Mesomeric effect (–m effect) :
When the group withdraws electron from the conjugated system, it shows – M effect
Relative order of –m groups (usually followed) :
Note :
1. Identification of +m & –m groups : If the first atom of the group has lone pair or negative charge shows
+m effect. If the group has vacant p-orbital or vacant d-orbital on first atom and also a multiple bonded group
in which second atom is more electronegative than the first then it shows –m effect.
2. The following group can show both +m & –m : –Cl, –Br, –SR, –NO, –NC
16. Identify which of the following does not show + m effect.

(A) –NHR (B) –OR (C) –F (D*) –COOH
17. Identify which of the following cannot show – m effect.

(A) –NO2 (B) –CONH2 (C*) –OCOR (D) –COO—
18. Decreasing + m effet of given group is :

(I) – NR2 (II) –OCOR (III) –NHCOR (IV) –Ph
(A) I > III > IV > II (B*) I > III > II > IV
(C) III > I > II > IV (D) II > I > IV > III
19. Decreasing – m effet of given group is :

(I) – COOH (II) –NO2 (III) –CHO (IV) –CONH2
(A) I > III > IV > II (B) I > III > II > IV
(C*) II > III > I > IV (D) II > I > IV > III
20. Which of the following can not show both ± m effect.

(A) –Cl (B*) –F (C) –NO (D) –NC
PAGE NO.- 11
ChemINFO-4.3 felksesfjd izHkko
Daily Self-Study Dosage for mastering Chemistry felkse sf jd izH kko
felksesfjd izHkko %
felksesfjd izHkko ,d LFkk;h izHkko gSA ftlesa bysDVªkWuksa dk xeu cgqycU/k ls ijek.kq ij ;k cgqycU/k ls ,dy cU/k ij ;k ,dkdh
;qXe ls ,dy cU/k esa gksrk gSA ;g izHkko eq[;r% f}cU/k ds la;Xq eh rU=k esa mifLFkr gksrk gSA blfy, ;g izHkko la;Xq eh izHkko Hkh dgykrk gSA
felksesfjd izHkko ds izdkj :
(a) /kukRed felksesfjd izHkko (+ m izHkko) :
tc lewg la;qXeh ra=k dks bysDVªkWu nku djrk gS rks ;g + M izHkko n'kkZrk gSA
Relative order of +M groups (usually followed) :
+ m lewgksa dk vkisf{kd Øe %
– O > –NH2 > –NHR > –NR2 > –OH > –OR > –NHCOR > –OCOR > –Ph > –F > –Cl > –Br > –I > –NO
(b) _.kkRed felksesfjd izHkko (– m izHkko) :
os lewg ftudh l;qXeh rU=k ls bysDVªkWu dks viuh vksj [khapus dh izo`fr gksrh gS] – M izHkko n'kkZrs gSA
– m lewgksa dk vkisf{kd Øe %
— –
–NO2 > –CHO > C=O > –C–O–C–R > –C–O–R > –COOH > –CONH2 > –C–O
— || || || ||
O O O O
uksV :
1. +m vkSj –m lewg dh igpku : ;fn lewg ds izFke ijek.kq ij ,dkdh bysDVªkWu ;qXe ;k _.kkRed vkos'k mifLFkr
gks rks og +m izHkko iznf'kZr djrk gSA ;fn lewg ds izFke ijek.kq ij fjDr p-d{kd ;k fjDr d-d{kd mifLFkr gks vkSj
cgqcaf/kr lewg ftlesa f}rh; ijek.kq dh fo|qr_.krk izFke ijek.kq ls vf/kd gks rks og –m izHkko iznf'kZr djrk gSA
2. fuEu lewg +m o –m nksuks izHkko n'kkZrs gS : –Cl, –Br, –SR, –NO, –NC
16. fuEu esa ls dkSulk lewg + m izHkko iznf'kZr ugha djrk gS \

(A) –NHR (B) –OR (C) –F (D*) –COOH
17. fuEu esa ls dkSulk lewg – m izHkko iznf'kZr ugha djrk gS \

(A) –NO2 (B) –CONH2 (C*) –OCOR (D) –COO—
18 uhps fn;s x;s fuEUkfyf[kr lewgksa dh + m izHkko dk ?kVrk gqvk Øe gS %

(I) – NR2 (II) –OCOR (III) –NHCOR (IV) –Ph
(A) I > III > IV > II (B*) I > III > II > IV
(C) III > I > II > IV (D) II > I > IV > III
19. uhps fn;s x;s fuEUkfyf[kr lewgksa dh – m izHkko dk ?kVrk gqvk Øe gS %

(I) – COOH (II) –NO2 (III) –CHO (IV) –CONH2
(A) I > III > IV > II (B) I > III > II > IV
(C*) II > III > I > IV (D) II > I > IV > III
20. fuEu esa ls dkSulk lewg ± m nksuks izHkko ugh n'kkZrk gS \

(A) –Cl (B*) –F (C) –NO (D) –NC
PAGE NO.- 12
ORG./INO. CHEMISTRY
Course : VIKAAS (JA) NO. 34
This DPP is to be discussed in the week (05.10.2015 to 10.10.2015)
1. Course of the week as per plan : Stability of Resonating structure, Mesomeric effect.
2. Course covered till previous week : Inductive Effect, Resonance, Resonance (Drawing Structure).
3. Target of the current week : Stability of Resonating structure, Mesomeric effect.
4. DPP Syllabus :
ANSWER KEY
1. (C) 2. (D) 3. (C) 4. (B) 5. (C) 6.* (ABD) 7*. (ACD)
8*. (ABCD) 9.* (AC) 10.* (ACD) 11. 3 12. 4 13. 6 14. 2
15. (A) – p,q,t ; (B) – p,q,s (C) – p (D) – p,q,r,s 16. (A) 17. (C) 18. (B)
19. (A) 20. (D)
1. + m and + I both effects are shown by :

fuEu esalsd kSulh Lih'kht + m rFkk + I nksuksaizHkko iznf'kZr d jrh gS%
(A) (B) (C*) (D) – C (CH3)3
2. Identify which of the following shows – m effect ?

fuEu esalsd kSulk lewg –m izHkko iznf'kZr d jrk gS\
(A) –NH–CH3 (B) –NH (C) (D*)
3. Decreasing + m power of given group is : [General Organic Chemistry]

uhpsfn;sx;sfuEUkfy f[kr lewgksad h + m {kerk d k ?kVrk gqv k Ø e gS%
(I) –O –CH3 (II) –F (III) –CH2 (IV) –Cl
(A) I > III > IV > II (B) III > II > I > IV (C*) III > I > II > IV (D) II > I > IV > III
4. The correct decreasing order of stability following resonating structure :

uhpsnh x;h vuquknh lajpuk d sLFkkf;Ro d k lgh ?kVrk gqv k Ø e gS%
(A) I > II > III > IV (B*) I > II > IV > III (C) I > IV > III > IV (D) I > IV > II > III
Sol. Non polar > Complete octate > opposite charge > same charge (-ve and lone pair)
v/kqzfo; > v"Vd iw.kZ > foifjr vkos'k > leku vkos'k (–ve rFkk ,d kd h by sDVªkWu ;qXe).
PAGE NO.- 1
5. More stable resonating structure of the given cation is :
uhpsfn;sx;s/kuk;u d h lokZf/kd LFkk;h vuquknh lajpuk gS%
(Made by RGP SIR on April2014) (Resonance(O)

CH2
:OMe
:
 
(A) (B)  (C*) (D)

OMe OMe
OMe OMe 
Sol. Follow the rules for stability of resonating structures (structure with more number of -bonds is more stable)
vuquknhlajpukd sLFkkf;Ro d sfu;e d kvuql j.k d hft , ¼vf/kd re -ca/kj[kusoky hlajpukvf/kd LFkk;hgkrhgSA½
6.* Which of the following carbanions is not resonance stabilized?

fuEu esalsd kSulk d kcZ_ .kk;u vuqukn }kjk LFkk;hd r̀ ugh gksrk gS\ (By RGP Sir, May, 2014)
(A*) O O (B*) H—N N—H (C) S S (D*)
Sol. In S S carbanion present in conjugation with vacant d-orbital of sulpher atom.
S S d kcZ_ .kk;u esalYQ j ijek.kqd sfjDr d-d {kd d h mifLFkfr d sd kj.k la;qXeu ik;k t krk gSA
7*. In which case(s) the second structure is more stable :

d kSulsfod Yiksaesaf}rh; lajpuk vf/kd LFkk;hgS%
(A*) ,
(B) ,
(C*) ,
(D*) ,
PAGE NO.- 2
8*. The correct number of p-electrons have been mentained in :
fd lesalgh p-by sDVªkWuksad k vad u fd ;k x;k gS:
(A*) ; (4) (B*) ; (6)
(C*) ; (3) (D*) ; (6)
9.* Which of the following molecule shows cross conjugation. (Made by RGP SIR on April2014) (Resonance(O)
fuEu esalsd kSulk v.kqØ kWl la;qXeu n'kkZrk gS\
(A*) Ph – C – Ph (B)
||
O
(C*) (D)
Sol. Ph – C – Ph and shows cross conjugation.

||
O
Ph – C – Ph rFkk Ø kWl la;qXeu n'kkZrsgSA

||
O
10.* Identify the correct statements (Made by SHK SIR ) (Resonance(O)
(A*) All C – C bonds in are equal. (B) All C – C bonds in CH2 = CH – CH = CH2 are equal.
(C*) All C – O bonds in are equal. (D*) All C – O bond in are equal.
fuEu esalsd kSulk d Fku lgh gS\
(A*) esalHkh C – C ca/k leku gSA (B) CH2 = CH – CH = CH2 es

alHkh C–C ca/k leku gSA
(C*) esalHkh C–O ca/kleku gSA (D*) esalHkh C–O ca/k leku gSA
Sol. (i), (iii) & (iv) have equal bond length due to equivalent resonating structure.
In (ii) both resonating structure are different.
Sol. (i), (iii) rFkk (iv) d h ca
/k y EckbZ;k¡lerqY; vuquknhlajpuk d sd kj.k leku gSA
(ii) es
anksuksavuquknh lajpuk,safHkUu gSA
PAGE NO.- 3
11. Find the total + m groups attached to the benzene ring in the given compound? (GOC-I)
uhpsfn;sx;s;kSfxd esafd rus+ m izHkko n'kkZusoky slewg csUt hu oy ; lst qM +sgq, gSa\
Ans. 3
Sol. –O–COCH3 , –OCH3, –N(CH3)2
12. In how many compound lone pair of nitrogen is involved in resonance ?

fuEu esalsfd rus;kSfxd ksad sukbVªkst u d k ,d kd h ;qXe vuqukn esaHkkx y srk gS\
(1) (2) (3) (4)
(5) (6) (7)
Ans. 4
13. Number of p electrons in resonance in the following structure is. (Made by SHK SIR ) (Resonance(O)
fuEufy f[kr lajpuk esavuqukn esalfEefy r  by sDVªkWuksad h la[;k fd ruh gksxh\
Ans. 6
Sol. It has only 6 p-electron in conjugation.
blesala;qXeu esad soy 6 -by sDVªkWu mifLFkr gksrsgSA
14. In the given compound how many lone pair of e– are delocalised ?
mijksDr ;kSfxd esafd rus,d kd h e– ;qXe d k foLFkkuhd j.k gksrk gS\
Ans. 2
PAGE NO.- 4
15. Match the column :
Column-I Column-II
(A) (p) Resonance possible

(B) H2N–CH=CH2 (q) Even number of p-electrons
(C) (r) localized lone pair of e–.
(D) (s) Delocalized lone pair of e–.
(t) 2 e– in p orbitals
l gh fey ku d hft ,&
d kWy e-I d kWy e-II
(A) (p) vuq
ukn lEHko
(B) H2N–CH=CH2 (q) p-by s

DVªkWuks
ad hlela[;k
(C) (r) by sDVªkWu d k LFkkuhd r̀ ,d kd h by sDVªkWu ;qXe
(D) (s) by sDVªkWu d k foLFkkuhd r̀ ,d kd h by sDVªkWu ;qXe
(t) p d {kd esa2 by sDVªkWu

Ans. (A) – p,q,t ; (B) – p,q,s (C) – p (D) – p,q,r,s
Sol. (A) (B)
(C) (D)
Lecutre Sub-topic(s) Nam e Hom e Work Hom e Work NCERT Chem . Hand
W.S.
No. (No. of Lectures) Sheet Pg.N INFO out
Ex.1 (S) Sec : C XI
Th.
Ex.1 (O) Sec : C XII
Stability of 346 Type of
L60 Ex.2 (O) 6 to 11 XI
Resonating structure 362 reagent
Prob.
Ex.2 (I) 8, 9
Ex.2 (M) 13 to 15 XII
346
Ex.1 (S) Sec : D XI
Th. 394 to 395
Ex.1 (O) Sec : D XII
Mesomeric effect
L61 Ex.2 (O) 12 to 14 XI
(Nature & strength)
Ex.2 (I) 10 to 14
Prob.
16 to 18, 20 to
Ex.2 (M) XII
22
PAGE NO.- 5
ChemINFO-5.1 HYDROCARBON
Daily Self-Study Dosage for mastering Chemistry Type of Reagent
An organic reaction can be represented as
solvent
Reactant (substrate) + Reagent 
 Product
Types of Bond dissociation :

All reactions are initiated with bond dissociation. There are two types of bond dissociation.
(a) Homolytic bond dissociation : A bond dissociation in which a bond pair electron is equally distributed to
the bonding atoms.
e.g. A–B  A• + B•
a homolytic bond dissociation generates radicals.
(b) Hetrolytic bond dissociation : A bond dissociation in which a bond pair electron is shifted to one atom
only.
e.g. A–B  A + B
A hetrolytic bond dissociation always generate a cation and an anion.
Types of Reagents :
A reagent generates three type of attacking species. Which are nucleophile, electrophile and radical.
(a) Electrophiles : Electrophiles are electron deficient species.
    
e.g. H Cl , Br , NO2 , CH3 (positively charged species), PCl5, SO2, SO3, BF3(species with vacant orbital
at central atom, carbenes) etc.
(b) Nucleophiles : It is the electron rich species having atleast one unshared pair of electron. It can be neutral
or negativetely charged it is always a lewis base.
e.g. CN–, OH–, Br – , I – , NH3 , H2O etc.
(c) Free radicals : It is electron deficient species with seven electrons around an atom.
e.g. C2H5, C2H5O, CH3COO, X etc.
16. Electrophiles are :

(A*) Electron deficent species (B) having atleast one pair of electron
(C) Electron rich species (D) negatively charged species
17. Which of the following is an electrophilic reagent ?

(A) H2O (B) OH– (C*) NO2+ (D) None
18. Which of the following is a nucleophile ?

(A) BF3 (B*) SH– (C) CH3+ (D) AlCl3
19. Which one of the following has maximum nucleophilicity ?

– –
(A*) CH3 (B) NH2– (C) OH– (D) F
20. Which of the followings are free radicals ?
  
(A) CH3 – CH2 (B) Cl (C) CH3O (D*) All of these
PAGE NO.- 6
Daily Self-Study Dosage for mastering Chemistry v fHkd eZd ksa d s izd kj
,d d kcZfud vfHkfØ ;k d ksfuEukuql kj iznf'kZr fd ;k t k ld rk gS%
foy k;d
vfHkd kjd (inkFkZ) + vfHkd eZd  mRikn
caèk fo[k.Mu d s izd kj %
lHkh vfHkfØ ;k caèk fo[k.Mu gksusij gh izkjEHk gksrh gSA nksizd kj d scaèk fo[k.Mu gksrsgS%
(a) l eka'k caèk fo[k.Mu : bl izd kj d scaèk fo[k.Mu esacaèk ;qXe by sDVªkWu caèk fo[k.Mu d si'pkr~cafèkr ijek.kqv ksa ij
cjkcj : i lsforfjr gkst krsgSA
mnk- A–B  A• + B•
leka'k caèk fo[k.Mu d s d kj.k ewy d cursgSA
(b)fo"keka'k caèk fo[k.Mu : bl izd kj d scaèk fo[k.Mu esacaèk ;qXe by sDVªkWu caèk fo[k.Mu d si'pkr~d soy ,d ijek.kq
ij gh forfjr gksrsgSA
mnk- A–B  A + B
fo"keka'k caèk fo[k.Mu d sd kj.k lnSo èkuk;u rFkk _ .kk;u cursgSA
v fHkd eZd ksa d s izd kj %
vfHkd eZd rhu izd kj d h vkØ e.kd kjh Lih'kht cukrsgS] t ksukfHkd Lusgh] by sDVªkWuLusgh rFkk ewy d gSA
DVªkWuLusgh : by sDVªkWuLusgh by sDVªkWu
(a) by s U;wu Lih'kht gksrh gSA
    
mnk- H Cl , Br , NO2 , CH3 (èkukos
f'kr Lih'kht ), PCl5, SO2, SO3, BF3(d s
fUæ; ijek.kqij fjDr d {kd j[kusokyh
Lih'kht ]d kchZ
u) bR;kfnA
(b)ukfHkd Lusgh : ;g ,d by sDVªkWu èkuh Lih'kht gSft uesad e lsd e ,d vlgHkkft r by sDVªkWu ;qXe ik;k t krk gSA ;g
mnklhu vFkok +_ .kkosf'kr gksld rsgSA ;g lnSo ,d y wbZl {kkj Hkh gksrsgSA
mnk- CN–, OH–, Br – , I – , NH3 , H2O bR;kfnA
(c) eqDr ewy d : ;g ,d by sDVªkWu U;wu Lih'kht gS ft ud s ijek.kq esa lkr by sDVªkWu gksrs gSA
mnk- CH3 C2H5, C2H5O, CH3COO, X bR;kfnA
16. by sDVªkuLusgh gSa%

(A*) by sDVªkWu U;wu Lih'kht (B) d e lsd e ,d ,d kd h by sDVªkWu ;qXe mifLFkr gksa
(C) by sDVªkWu /kuhLih'kht (D) _ .kkRed vkos
f'kr Lih'kht
17. fuEu esalsd kSulk ,d by sDVªkWuLusgh vfHkd eZd gS?

(A) H2O (B) OH– (C*) NO2+ (D) d ks
bZugha
18. fuEu esalsd kSulk ,d ukfHkd Lusgh gS\

(A) BF3 (B*) SH– (C) CH3+ (D) AlCl3
19. fuEu esad kSulklokZf/kd ukfHkd Lusfgrkj[krkgS\

– –
(A*) CH3 (B) NH2– (C) OH– (D) F
20. fuEu esalsd kSu eqDr ewy d gS\

  
(A) CH3 – CH2 (B) Cl (C) CH3O (D*) mijks
Dr lHkh
PAGE NO.- 7
ORG./INO. CHEMISTRY
1. Course of the week as per plan : Mesomeric effect and SIR, Hyperconjugation, Application of I.R.,M HC
effects (Bond Length & Electron density on benzene ring)
2. Course covered till previous week : Stability of Resonating structure, Mesomeric effect.
3. Target of the current week : Mesomeric effect and SIR, Hyperconjugation, Application of I.R.,M HC effects
(Bond Length & Electron density on benzene ring)
4. DPP Syllabus : Mesomeric effect and SIR, Hyperconjugation, Application of I.R.,M HC effects (Bond Length &
Electron density on benzene ring)
ANSWER KEY
1. (D) 2. (B) 3. (C) 4. (A) 5. (C) 6. (D) 7. (D)
8. (B) 9. (B) 10. (A) 11. (C) 12. (A) 13. (D) 14. (C)
15. (C) 16. (A) 17. (C) 18. (C) 19. (C) 20. (B)
1. Hyperconjugation phenomenon is possible in :

fuEu esalsfd l v.kqesavfrla;qXeu lEHko gS\
(A) (B) CH2 = CH2
(C) C6H5 – CH = CH2 (D*) CH3 – CH2 – CH = CH2

Sol. CH3 – CH2 – CH = CH2 has two -hydrogen for hyperconjugation.
Sol. CH3 – CH2 – CH = CH2 vfrla;qXeu d sfy , nks-gkbMªkst u ijek.kqmifLFkr gSA
2. Hyperconjugation is possible in which of the following species ?

fuEu izt kfr;ksaesalsfd lesavfrla;qXeu lEHko gSa\
CH3
| 
(A) (B*) C6H5—CH3 (C) CH2=CH2 (D) CH3 — C — C H2
|
CH3
3. Number of  electrons in conjugation for these compounds
, , and will be respectively :
v|ksfy f[kr ;kSfxd ksad sla;qXeu esaHkkx y susoky sby sDVªkWuksad h la[;k Ø e'k%gSa\
, , rFkk
(A) 8, 6, 6, 6 (B) 6, 4, 6, 6 (C*) 6, 6, 6, 6 (D) 6, 6, 8, 6
4. Which of the following alkenes will show maximum number of hyperconjugation forms ?
fuEu ,Yd huksaesad kSu lokZf/kd vfrla;qXeu : i n'kkZ;sxk \
(A*) (B) CH3–CH=CH–CH3 (C) (D)
5. Hyperconjugation is not present in : [SHK Sir 2012]

fuEu esalsfd lesavfrla;qXeu lEHko ughagS%
(A) (B) (C*) (D)
Sol. C has no sp3 carbon and H for hyperconjugation.

fod Yi C esa];kSfxd esavfrla;qXeu d sfy , H rFkk sp3 d kcZu mifLFkr ughagSA
6. Which of the following species will not show hyperconjugation : [General Organic Chemistry]
fuEu esalsd kSulh lajpuk vfrla;qXeu çnf'kZr ughad jsxh %
(A) C6H5—CH3 (B) (C) (D*)
7. The correct stability order of following is :

fuEu d sLFkkf;Ro d k lgh Ø e gS%
(I) (II) (III) (IV)
(A) I > II > III > IV (B) III > IV > II > I (C) II > IV > III > I (D*) IV > III > II > I
Sol. Stability  resonance
 Hyperconjugation
length of conjugation is equal in all I, II, III & IV.
gy - LFkkf;Ro  vuqukn
 vfrla ;qXeu
lHkh I, II, III o IV esala;qXeu d h y EckbZleku gSA
PAGE NO.- 2
8.
Among these compounds, the correct order of resonance energy is :

fuEu ;kSfxd ksd h vuquknh Å t kZd k lgh Ø e d kSulk gS%
(A) > >  (B*) > >  (C) > >  (D) > > 
9. The correct decreasing order of electron density in aromatic ring of following compounds is :
fuEufy f[kr ;kSfxd kasesa,jkseSfVd oy ; ij by sDVªkWu ?kuRo d k lgh ?kVrk gqv k Ø e gksxk %
(I) (II) (III) (IV)
(A) (II) > (III) > (IV) > (I) (B*) (III) > (II) > (IV) > (I) (C) (IV) > (I) > (III) > (II) (D) (III) > (II) > (I) > (IV)
Sol. + m group increases electron density and – m group decreases electron density in aromatic ring.
,sjkseSfVd oy ; esa+ m lewg by sDVªkWu ?kuRo c<+k nsrk gSrFkk – m lewg by sDVªkWu ?kuRo esad eh d j nsrk gSA
10. Which of the following molecule has longest C=C bond length ? [General Organic Chemistry]
fuEu esalsfd l v.kqesaC=C ca/k y EckbZlokZf/kd gS\
(A*) CH3–CH=CH–CH=CH–CH3 (B) CH2=CH–CH=CH2
(C) CH3–CH=CH–CH3 (D) CH2=CH2
Sol. CH3 — CH = CH — CH = CH — CH3
(A) reso + H.C.
bond order as, bond lenght 
Sol. CH3 — CH = CH — CH = CH — CH3
(A) v uq
ukn + v frl a;qXeu
ca/k Ø e , ca/k y EckbZ
NH2 NH2 NH2
CH2=NH
11.
CHO II III IV
I
Among these compounds the correct order of C–N bond length is :
mijksDr ;kSfxd kasd slUnHkZesaC–N ca/k d h y EckbZd k lgh Ø e d kSulk gS%
(A) IV > I > II > III (B) III > I > II > IV (C*) III > II > I > IV (D) III > I > IV > II
12. The most stable cannonical structure of this molecule is :

uhpsfn;sx;sv.kqd h lokZf/kd LFkk;h d Suksfud y lajpuk d kSulh gS\
O
`

O O  O

(A*) 
(B) (C)
single bond
(D) All structures are equal contribution ¼mijks

Dr lajpuk,sacjkcj ;ksxnku iznku d jrh gS½
PAGE NO.- 3
O O
Sol.  Both ring are aromatic. ¼nks
uksaoy ; ,sjkseSfVd gSa½
13. Which of the following has shortest C-Cl bond ?

fuEu esalsfd l v.kqesaC-Cl ca/k lclsNksVk gS\
(A) CH3–Cl (B) CH2=CH–l
Cl
(C) CH2=CH–CH=CH–Cl (D*)
Sol. As conjugation in the molecule increases partial double bond character between C-Cl increases and bond
length decreases.
t Sl sgh fd lh v.kqesala;qXeu c<+rk gS]rksC-Cl ca/k d se/; vkaf'kd f}ca/k vfHky {k.k c<+rk gSrFkk ca/k y EckbZ?kVrh gSA
14. Total number of hyperconjugative hydrogen atom in the given compound is: (By RGP Sir, May, 2014)
uhpsfn;sx;s;kSfxd esad qy fd rusvfrla;qXeh gkbMªkst u ijek.kqmifLFkr gS\
(A*) 6 (B) 5 (C) 7 (D) 8
15. How many alkenes, from followings are more stable than (By RGP Sir, May, 2014)
fuEu esalsfd ruh ,Yd husa d h vis{kk vf/kd LFkk;h gS
(A) 2 (B) 3 (C*) 4 (D) 5
Lecutre Sub-topic(s) Nam e Hom e Work Hom e Work NCERT Chem .

W.S.
No. (No. of Lectures) Sheet Pg.N INFO
Ex.1 (S) Sec : F XI 347
Th.
Ex.1 (O) Sec : F XII
L62 Hyperconjugation Ex.2 (O) 15 to 21, 23 XI 348
Ex.2 (I) 15 to 18 Prob.
Ex.2 (M) 23, 24 XII
Ex.1 (S) Sec : E, G XI 391
Th.
Ex.1 (O) Sec : E, G XII
L63 SIR + Aromaticity Ex.2 (O) 27, 30 XI Hydrocarbon
Ex.2 (I) 19 to 21 Prob.
Ex.2 (M) 25 to 27 XII
Ex.1 (S) Sec : H XI
Th.
Ex.1 (O) Sec : H XII
Application of I.R.,M HC 348
effects (Bond Length & 22, 24 to 26, 264
L64 Ex.2 (O) XI
Electron density on 31 to 34 363
Prob.
benzene ring) 397
Ex.2 (I) 22, 23
Ex.2 (M) 29 to 31 XII
PAGE NO.- 4
Generally an organic reaction is basically of three types
(a) Substitution reaction : In a substitution reaction a group is replaced by other group.
R–Y + Z  R–Z + Y
(b) Addition reaction : In addition reaction one bond is broken and two new  bonds are formed.
YZ
| |
  C  C 
| |
Y Z
(c) Elimination reaction : In an elimination reaction two atoms or groups (YZ) are removed from the substrate
and generally resulting into formation of  bond.
| |
Elimination
CC 

 YZ
| |
Y Z
16. Substitution reactions involve :
(A*) Cleavage of a –bond and formation of a new –bond
(B) Cleavage of two –bond and formation of a new –bond
(C) Cleavage of a –bond and formation of two new –bond
(D) None of these
17. Which of the following reaction is a substitution reaction ?

Ni / H2 CH 2– CH2
(A) CH2 = CH2    CH3–CH3 (B) Zn
 CH2 = CH2 + ZnBr2

Br Br
H
  KCN
(C*) CH3 – I + OH  CH3 OH  I (D) CH3 – CHO  
 CH3 – C –OH
H
CN
18. Addition reactions involve
(A) Cleavage of a -bond and formation of a new -bond
(B) Cleavage of two -bond and formation of a new -bond
(C*) Cleavage of a -bond and formation of two new -bond
(D) None of these
19. Which of the following reaction is an elimination reaction ?

PCl 5
(A) CH3 – CH2 – CH2 – OH   CH3 – CH2 – CH2 – Cl
HCl
(B) CH3 – CH = CH2  
Alc . KOH
(C*)   CH3 – CH = CH2
CH OH
(D) 3
  
20. The given reaction is an example of CH3–CH2–CHO + HCN 
(A) Elimination reaction (B*) Addition reaction

(C) Substitution reaction (D) None of these
PAGE NO.- 5
lkekU;r;k,d d kcZfud vfHkfØ ;krhu izd kj d hgksrhgSA
frLFkkiu v fHkfØ ;k: izfrLFkkiu vfHkfØ ;k esa],d lewg d k nwl jslewg }kjk izfrLFkkiu gksrk gSaA
(a) iz
R–Y + Z  R–Z + Y
xkRed v fHkfØ ;k : ;ksxkRed vfHkfØ ;k esa,d caèk VwVrk gSrFkk nksu;s caèk cursgSA
(b) ;ks
YZ
| |
  C  C 
| |
Y Z
iu v fHkfØ ;k: foy ksiu vfHkfØ ;k esa]vfHkd kjd lsnksijek.kq;k lewg (YZ) fu"d kflr gksrsgSA ft ld s
(c) foy ks
ifj.kkeLo: i lkekU;r;k caèkcurkgSA
| |
E lim ination
CC    
| |  YZ
Y Z
16. izfrLFkkiu vfHkfØ ;kesagksrkgS:
(A*) –ca /k d k fo[k.Mu ¼fony u½ rFkk u;s–ca/k d k fuekZ.k
(B) nks–ca /k d k fo[k.Mu ¼fony u½ rFkk ,d u;s–ca/k d k fuekZ.k
(C) ,d –ca /k d k fo[k.Mu¼fony u½ rFkk nksu;s–ca/k d k fuekZ.k
(D) bues alsd ksbZugha
17. fuEu esalsd kSulhvfHkfØ ;kizfrLFkkiu vfHkfØ ;kgS?

Ni / H2 CH 2– CH2
(A) CH2 = CH2    CH3–CH3 (B) Zn
 CH2 = CH2 + ZnBr2

Br Br
H
  KCN
(C*) CH3 – I + OH  CH3 OH  I (D) CH3 – CHO  
 CH3 – C –OH
H
CN
18. ;ksxkRed vfHkfØ ;kesagksrkgS%
(A) -ca/k d k fo[k.Mu ¼fony u½ rFkk u;s-ca/k d k fuekZ.k
(B) nks-ca /k d k fo[k.Mu ¼fony u½ rFkk u;s-ca/k d k fuekZ.k
(C*) -ca/k d k fo[k.Mu ¼fony u½ rFkk nksu;s-ca/k d k fuekZ.k
(D) bues alsd ksbZughaA
19. fuEu esalsd kSulhvfHkfØ ;kfoy ksiu vfHkfØ ;kgS\

PCl 5 HCl
(A) CH3–CH2–CH2–OH   CH3–CH2–CH2–Cl (B) CH3–CH=CH2 
Alc . KOH CH OH
(C*)   CH3–CH=CH2 (D) 3
  
20. v|kfsyf[kr vfHkfØ ;kfuEu es

alsfd l vfHkfØ ;kd kmnkgj.kgS%CH3–CH2–CHO + HCN 
(A) foyksiu vfHkfØ ;k (B*) ;ks

xkRed vfHkfØ ;k
(C) izfrLFkkiu vfHkfØ ;k (D) buesalsd ksbZugha
PAGE NO.- 6
ORG./INO. CHEMISTRY

1. Course of the week as per plan : Application of I.R.,M HC effects (Bond Length & Electron density on
benzene ring), Aromaticity, Carbanion and It’s Stability.
2. Course covered till previous week : Mesomeric effect and SIR, Hyperconjugation, Application of I.R.,M HC
effects (Bond Length & Electron density on benzene ring)
3. Target of the current week : Application of I.R.,M HC effects (Bond Length & Electron density on benzene
ring), Aromaticity, Carbanion and It’s Stability.
4. DPP Syllabus :
ANSWER KEY
1. (C) 2. (A) 3. (C) 4. (D) 5. (C) 6.* (BCD) 7.* (AC)
8.* (ACD) 9.* (ACD) 10.* (AB) 11. 3 12. 5 13. 8 14. 8
15. (A - p,s) ; (B - p,s) ; (C - p,s) ; (D - r) 16. (C) 17. (C) 18. (B) 19. (D)
20. (D)
1. The least stable resonating strucutre is

lclsd e LFkk;h vuquknh lajpuk gS%
(A) (B)
(C*) (D)
2. The correct decreasing order of electron density on pyridine nucleus :

fifjMhu ukfHkd ij by sDVªkWu ?kuRo d k ?kVrk gqv k Ø e gS%
(A*) II > III > I > IV (B) II > I > III > IV (C) II > IV > III > I (D) II > IV > I > III
PAGE NO.- 1
3.
The most stable canonical structure of this molecule is
bl v.kqd h lclsvfèkd LFkk;h vuquknh lajpuk gS%
(A) (B) (C*) (D) All are equally stable
lHkhleku : i lsLFkk;hgSA
4. Which of the following compounds is aromatic ?
fuEu esalsd kSulk ;kSfxd ,sjkseSfVd gS\
(A) (B) (C) (D*) all of these mijks

Dr lHkh
5. Lone-pair of electrons on nitrogen atom of pyridine is not delocalized with  – electrons because
(A) it is in p orbital (B) it is in sp3 orbital
2
(C*) it in sp orbital which cannot over lap with p orbitals on adjacent carbon atoms.
(D) it is in sp orbital
fijhfMu d sukbVªkst u ijek.kqij by sDVªkWu ;qXe -by sDVªkWu d slkFkfoLFkkuhd r̀ ughagksrk gSD;ksafd
(A) ;g p d {kd gS (B) ;g sp3 d {kd gS
(C*) ;g sp2 d {kd gSt kslehiLFk d kcZ
u ijek.kqv ksaij p d {kd ksad slkFkvfrO;kfir ughagksrk gSA
(D) ;g sp d {kd gSA
6.* Which of the following are Aromatic in nature.
fuEu esalsd kSuls,jksesfVd gSA [General Organic Chemistry]
(A) (B*) (C*) (D*)
7.* Which of the following are Aromatic compound. [Ref_RSS Sir_2013]

fuEu esalsd kSuls,jksesfVd ;kSfxd gS% [General Organic Chemistry]
(A*) (B) (C*) (D)
8.* What is/are correct about Guanidine base [Ref. DRM Mam]
(A*) Resonance possible (B) Odd number of p-electrons

(C*) localized lone pair of e–. (D*) Delocalized lone pair of e–.
PAGE NO.- 2
XokfuMhu {kkj d sfy , lgh d Fku gS@ gSa& [Ref. DRM Mam]
(A*) vuq
ukn laHko (B) p by s
DVªkWu
d h fo"ke la[;k
(C*) e d sLFkkuhd r̀ ,d kd h;q
–
Xe (D*) e d sfoLFkkuhd r̀ ,d kd h;q
–
Xe
9.* Identify the correct statement
(A*) All C–O bond length in carbonate ion is equal (B) All C–C bond length in naphthalene is similar.
(C*) All N–O bond length in is similar (D*) All C–O bond length in is equal.
lghd Fku d ksigpkfu;saA

(A*) d kcks
ZusV vk;u esalHkhC–O caèky EckbZcjkcj gSA (B) uS¶Fksfy u esalHkh C–C caèk y EckbZleku gSA
(C*) esalHkh N–O caèk y EckbZleku gSA (D*) esalHkhC–O caèky EckbZcjkcj gSA
10.* Hyperconjugation is possible in

fuEu esalsfd lesavfrl;qXeu lEHko gSA
(A*) (B*) (C) (D)
11. How many species out of the following are aromatic ? [General Organic Chemistry]
fuEu esafd ruh Lih'kht ,sjksesfVd gS
no cyclic resonance
, , , , ,
Ans. 3
Sol. , , are Aromatic species. ¼,s

jksesfVd Lih'kht gSA½
12. At how many carbons the negative charge of the following anion can reach through resonance (including the
carbon at which – ve charge is present in the given structure).
fuEu _ .kk;u Lih'kht d svuqukn d sQ y Lo: i fd rusd kcZu ijek.kqij _ .kkos'k vkrk gSA ¼nh xbZlajpuk esa_ .kkRed
vkosf'kr d kcZu ijek.kqlfgr½
Ans. 5
PAGE NO.- 3
13. How many p-electrons are involved in resonacne in the given structure? [Ref. DRM Mam]
nh xbZlajpuk esavuqukn esaHkkx y susoky sp-by sDVªkWUkksad h la[;k fd ruh gS\
Ans. 8
14. How many hyperconjugable H atoms are in
esavfrla;qXeh H ijek.kqv ksad h la[;k fd ruh gS\
Ans. 8
15. Match the following

Column – I Column – II
(A) (p) Aromatic
(B) (q) Non aromatic
(C) (r) Anti aromatic
(D) (s) Heterocyclic
PAGE NO.- 4
fuEu d kslqesfy r d hft ;s
d kWy e– I d kWy e– II
(A) (p) ,s
jks
eS
fVd
(B) (q) ukW

u ,s
jks
eSfVd
(C) (r) ,UVh,s

jkseSfVd
(D) (s) fo"kepØ h;
Ans. (A - p,s) ; (B - p,s) ; (C - p,s) ; (D - r)
Lecutre Sub-topic(s) Nam e (No. of Hom e Work Hom e Work NCERT Chem .
W.S.
No. Lectures) Sheet Pg.N INFO
Application of I.R.,M HC effects
L65 (Bond Length & Electron
density on benzene ring)
Ex.1 (S) Sec : J XI

Th.
Ex.1 (O) Sec : J XII
Chemical reactions of
L66 Carbanion & its stability Ex.2 (O) 47 to 49 XI
alkane
Ex.2 (I) 27, 28 Prob.
Ex.2 (M) 35, 36 XII
Ex.1 (S) I1 to I3, Sec : K XI
Th.
Ex.1 (O) I1 to I7, Sec : K XII Cation & radical
L67 Carbocation Stability Ex.2 (O) 35 to 43, 45, 50 XI 364 stability order (20
Ex.2 (I) 24, 26, 29 to 32 Prob. Ques.)
Ex.2 (M) 33, 34, 37, 38 XII
PAGE NO.- 5
ChemINFO-5.3 Hydrocarbon
Daily Self-Study Dosage for mastering Chemistry Alkane :- Chemical Reaction of Alkane
Chemical Reaction of Alkane
Halogenation of Alkane :- It is example of free radical substitution reaction
CH3 –CH3 + Cl2 CH3 –CH2 Cl + HCl
It is found that the rate of reaction of alkanes with halogens is F2 > Cl2 > Br2 > I2
Alkane which give more stable free radical will be more reactive towards halogenation
> CH3CH2CH3 > CH3CH3 > CH4
Fluorination is too violent to be controlled.Iodination is very slow and a reversible reaction. It can be carried out in
the presence of oxidising agents like HIO3 or HNO3
Mechanism  Three Step
1. Chain Initiation Step
Cl –Cl Homolysis 2
2. Chain Propagation Step :
(a) CH4 +  + HCl (b) +Cl2  CH3–Cl +

3. Chain Termination Step :
(a) +  Cl2 (b) +  CH3 – CH3
(c) +  CH3 –Cl
16. Which of the following step is chain propagation step of ethane.
(A) CH3 – + CH3 – CH2  (B) CH3 –CH3  CH3 – CH2 + H
(C*) CH3 –CH3+  CH3– CH2 + HCl (D) CH3 – CH2 +  CH3–CH2–Cl
17. Chlorination of an alkane involves
(A) Cl (B) Cl (C*) (D)
18. The reactivity of hydrogen atom in an alkane towards substitution by bromine atom is :
(A) 1°H > 2°H > 3°H (B*) 3°H > 2°H > 1°H (C) 3°H > 1°H > 2°H (D) 2°H > 3°H > 1°H
19. Reactivity order of halogens towards free radical substitution reaction is

(A) Br2 > F2 > Cl2 > I2 (B) F2 > I2 > Br2 > Cl2
(C) I2 > Br2 > Cl2 > F2 (D*) F2 > Cl2 > Br2 > I2
20. CH3 –CH2 –CH2 –CH3  major product, major product is :
(A) CH3 –CH2 –CH2 –Cl (B)
Cl
(C) (D*)
Cl Cl
PAGE NO.- 6
ChemINFO-5.3 Hydrocarbon
Daily Self-Study Dosage for mastering Chemistry Alkane :- Chemical Reaction of Alkane
,Yd suksad k gSy kst uhd j.k %;g eqDr ewy d çfrLFkkiu vfHkfØ ;k d k mnkgj.k gSA
CH3 –CH3 + Cl2 CH3 –CH2 Cl + HCl
;g ik;k x;k gSfd gSy kst uksad slkFk ,Yd suksad h vfHkfØ ;k d h nj F2 > Cl2 > Br2 > I2 gksrh gSA
,Yd su t ksvf/kd LFkk;h eqDr ewy d nsrk gS]og gSy kst uhd j.k vfHkfØ ;k d sçfr T;knk fØ ;k'khy gksrk gSA
> CH3CH2CH3 > CH3CH3 > CH4
¶yksjhuhd j.kfu;a f=kr ifjfLFkfr;ks

ad svUrxZ
r Hkhcgq
r d fBukbZiw
oZ
d gks
rkgS
A vk;kMshuhd j.k,d cgq
r /khehrFkkmRØ e.kh; vfHkfØ ;k
gSA ;g vkWDlhd kjd inkFkZt Sl sHIO3 ;kHNO3 d hmifLFkfr esalEiUu gksrkgSA
fØ ;kfof/k rhu in
1. Jà[ky k çkjEHkd in
Cl –Cl 2
2. Jà[ky k l ap j.k in :
(a) CH4 +  + HCl (b) +Cl2  CH3–Cl +
3. Jà[ky k l ekiu in :
(a) +  Cl2 (b) +  CH3 – CH3
(c) +  CH3 –Cl
16. fuEu esalsd kSulk in ,Fksu d k Jà[ky k lap j.k in gS\

(A) CH3 – CH2 + CH3 – CH2  (B) CH3 –CH3  CH3 – CH2 + H
(C) CH3 –CH3+  CH3– CH2 + HCl (D) CH3 – CH2 +  CH3–CH2–Cl
17. ,Yd su d sDy ksjhuhd j.k esafuEu esalsd kSulh Lih'kht ç;qDr gksrh gS\
(A) Cl (B) Cl (C) (D)
18. czksehu ijek.kq}kjk çfrLFkkiu d sçfr ,Yd su esamifLFkr gkbMªkst u ijek.kqv ksad h fØ ;k'khy rk d k lgh Ø e fuEu gS%
(A) 1°H > 2°H > 3°H (B) 3°H > 2°H > 1°H (C) 3°H > 1°H > 2°H (D) 2°H > 3°H > 1°H
19. eqDr ewy d çfrLFkkiu vfHkfØ ;k d sçfr gSy kst uksad h fØ ;k'khy rk d k lgh Ø e d kSulk gS\
(A) Br2 > F2 > Cl2 > I2 (B) F2 > I2 > Br2 > Cl2
(C) I2 > Br2 > Cl2 > F2 (D) F2 > Cl2 > Br2 > I2
20. CH3 –CH2 –CH2 –CH3  eq[; mRikn]eq[; mRikn gS%
(A) CH3 –CH2 –CH2 –Cl (B)
Cl
(C) (D)
Cl Cl
PAGE NO.- 7
ORG./INO. CHEMISTRY
1. Course of the week as per plan : Carbocation and It’s Stability, Carbocation Rearrangement, Discusion.
2. Course covered till previous week : Application of I.R.,M HC effects (Bond Length & Electron density on
benzene ring), Aromaticity, Carbanion and It’s Stability.
3. Target of the current week : Carbocation and It’s Stability, Carbocation Rearrangement, Discusion.
4. DPP Syllabus :
ANSWER KEY
1. (C) 2. (A) 3. (A) 4. (B) 5. (B) 6. (A) 7. (D)
8. (B) 9. (B) 10. (B) 11. (C) 12. (C) 13. (D) 14. (C)
15. (A) 16. (B) 17. (D) 18. (C) 19. (B) 20. (A)
1. Select the correct stability order of the following carbanions.

fuEu d kcZ_ .kk;uksad sLFkkf;Ro d k lgh Ø e D;k gS\
-
(i) CH2 = CH – (ii) CH3 – C – CH2 (iii) CH3 – C – – C –CH3
O O O
(A) (i) > (ii) > (iii) (B) (ii) > (iii) > (i) (C*) (iii) > (ii) > (i) (D) (ii) > (i) > (iii)

(i) CH  C .. (ii) (iii)
(A*) (i) > (ii) > (iii) (B) (ii) > (iii) > (i) (C) (iii) > (ii) > (i) (D) (ii) > (i) > (iii)

.. .. ..
CH2
(i) (ii) (iii) (iv)
(A*) (i) > (ii) > (iii) > (iv) (B) (ii) > (iii) > (i)> (iv) (C) (iii) > (iv) > (ii) > (i) (D) (iv)> (ii) > (i) > (iii)
PAGE NO.- 1
.. .. ..
CH CH CH
– 2 – – –
–
(i) (ii) (iii)
– –
NO2 CHO
(A) (i) > (ii) > (iii) (B*) (ii) > (iii) > (i) (C) (iii) > (ii) > (i) (D) (ii) > (i) > (iii)
5. The correct stability order of following carbocations is

fuEu d kcZ/kuk;uksad sLFkkf;Ro d k lgh Ø e gS%
(A) I > II > III > IV (B*) IV > II > III > I (C) IV > III > II > I (D) IV > I > III > II
Sol. The correct stability order of the following carbocations is IV > II > III > I
fuEu d kcZ/kuk;uksad sLFkkf;Ro d k lgh Ø e IV > II > III > I gS
> > >
Stability of carbocation depend upon conjugation > Hyperconjugation

d kcZ/kuk;uksad k LFkkf;Ro fuHkZj d jrk gS% la;qXeu > vfrla;qXeu
6. Which of the following is the most stable carbocation intermediate.

fuEu esalslclsvf/kd LFkk;h e/;orhZd kcZ/kuk;u d kSulk gS\
(A*) (B) (C) (D)
Sol. Carbocation stablized by + m effect.
+ m iz
Hkko d sd kj.kd kcZ/kuk;u LFkk;hgksrkgSA
7. In which of the following Ist is more stable than IInd :
fuEu esalsfd lesaIst , IInd lsvf/kd LFkk;h gS\
(A) , (B) ,
 
(C) CH3– C H –CH3, CH3–CH2– C H2 (D*) All of these mijks
Dr lHkh
PAGE NO.- 2
8. Which of the following is correct order of stability of carbocation? [Ref_RGP Sir]
bu d kcZ/kuk;u d sLFkkf;Ro d k lgh Ø e d kSulk gS\
(A) I > II > III (B*) III > I > II (C) I > III > II (D) III > II > I
9. Which of the following carbocation is most stable :

fuEu esalsd kSulkd kcZ/kuk;u lokZf/kd LFkk;hgS\
CH2 CH2 CH2 CH2
(A) (B*) (C) (D)
CH3 OH Cl NO2
10. Which of the following carbocation is most unstable :

fuEu esalsd kSulkd kcZ/kuk;u lokZf/kd vLFkk;hgS\
(A) (B*) (C) C6H5–CH2 (D) CH –CH–CH

3 3
11. Which of the following carbocation is most unstable ?

fuEu esalsd kSulkd kcZ/kuk;u lokZf/kd vLFkk;hgS\
(A) (B) (C*) (D)
12. Maximum number of atoms in same plane in benzene are : [Made by DRM Mam]
(A) 6 (B) 10 (C*) 12 (D) None of these
csat hu easvfèkd re fd rusijek.kqleku ry esagksrsgS\
(A) 6 (B) 10 (C*) 12 (D) bues
alsd ksbZugha
13. In which of the following maximum SIR. [Made by DRM Mam]

fuEu esalsfd lesavfèkd re SIR gksxk \
(A) (B) (C) (D*)
PAGE NO.- 3
14. In which of the following positive charge of carbocation is not in conjugation with –OH group.
fuEu esalsfd lesad kcZèkuk;u d k èkukos'k –OH d slkFk la;qXeu esaugh gksrk gS\ [Made by DRM Mam]
(A) (B) (C*) (D) None of these bues

alsd ksbZugha
15. Which of the following is most stable cation. [Made by DRM Mam]
fuEu esalsd kSulklokZfèkd LFkk;h èkuk;u gS\
(A) (B*) (C) (D)
Lecutre Sub-topic(s) Nam e Hom e Work Hom e Work NCERT Chem . Hand
W.S.
No. (No. of Lectures) Sheet Pg.N INFO out
Ex.1 (S) I4 XI
Th.
Ex.1 (O) I8 to I12 XII
Carbocation Chemical reaction
L68 Ex.2 (O) 44 XI Carbene
Rearrangement of alkane
Ex.2 (I) 25 Prob.
Ex.2 (M) 32 XII
L69 Discussions
Discussion of DPP's
L70
of Hydrocarbon
PAGE NO.- 4
Daily Self-Study Dosage for mastering Chemistry Chemical reaction of Alkane :- Nitration and sulphonation
Nitration and sulphonation of alkane
Nitration :- Replacement of H-atom of alkane by nitro group is known as nitration. When nitration is carried out in
vapour phase between 420 K and 720 K, a mixture of all possible mononitro derivatives is obtained (directly or after
chain fission) Reactivity order = 30 > 20 > 10
For example : R–H R–NO2 ; CH3–CH3 CH3–CH2–NO2
Sulphonation :- When alkane is treated with oleum (H2S2O7) or fuming sulphuric acid, H-atom is replaced by –
SO3H group . Reactivity order = 30 > 20 > 10
For example : CH3–CH2–CH3
16. CH3–CH2–CH3 major product is
(A) (B*) (C) CH3–CH2–NO2 (D) CH3–NO2
17. major product is
(A) (B) (C) CH3–CH2–NO2 (D*)
(A) (B) (C*) (D)
CH3
CH2–SO3H CH3 SO3H CH3
SO3H
(A) (B*) (C) (D)
SO3H
20. CH3–CH2–CH3 major product is.

(A*) (B) (C) CH3–CH2–SO3H (D) CH3–SO3H
PAGE NO.- 5
Daily Self-Study Dosage for mastering Chemistry Chemical reaction of Alkane :- Nitration and sulphonation
,Yd su d k ukbVªhd j.k rFkk l YQ ksuhd j.k
ukbVªhd j.k: ukbVªkslewg }kjk ,Yd su d sH-ijek.kqd sfoLFkkiu d ksukbVªhd j.k d grsgSA t c ukbVªhd j.k420 K rFkk720 K rki
d se/; ok"i voLFkkes agkrskgS
]rkslHkhlEHkkfor ekuskuskbVª
ksO;q
RiUukasd sfeJ.k¼çR;{k: i ls;kJà
[kykfo[k.Mu d si'pkr~
½çkIr gkrssgS
A
fØ ;k'khy rk d k Ø e = 30 > 20 > 10
mnkgj.k d sfy , : R–H R–NO2 ; CH3–CH3 CH3–CH2–NO2
l YQ ksuhd j.k: t c ,Yd su d h vfHkfØ ;k vksfy ;e (H2S2O7) vFkok la/kwezlY¶;wfjd vEy d slkFk d jkrsgS]rksSO3H lewg }kjk
H-ijek.kqd kfoLFkkiu gks rkgSA fØ ;k'khy rk d k Ø e = 30 > 20 > 10
mnkgj.k d sfy , : CH3–CH2–CH3 H2SO4 + SO3
16. CH3–CH2–CH3 eq[; mRikn gS%

(A) (B*) (C) CH3–CH2–NO2 (D) CH3–NO2
17. eq[; mRikn gS%
(A) (B) (C) CH3–CH2–NO2 (D*)
18. eq[; mRikn gS%
(A) (B) (C*) (D)
19. eq[; mRikn gS%
CH3
CH2–SO3H CH3 SO3H CH3
SO3H
(A) (B*) (C) (D)
SO3H
20. CH3–CH2–CH3 eq[; mRikn gS%

(A*) (B) (C) CH3–CH2–SO3H (D) CH3–SO3H
PAGE NO.- 6
ORG./INO. CHEMISTRY

Important Note : The Chapter of hydrocarbon will be coursed in study-XI from Board point of view only.
Read the theory and momerise it, then answer the question given below that portion of theory. This is to be
done during PSA holiday as Self-study.
1. Course of the week as per plan : Discusion, Discusion of DPPs of hydrocarbon
2. Course covered till previous week : Carbocation and It’s Stability, Carbocation Rearrangement, Discusion.
3. Target of the current week : Discusion, Discusion of DPPs of hydrocarbon
4. DPP Syllabus : Discusion of DPPs of hydrocarbon
ChemINFO Questions ('–1' negative marking) Q.1 to Q.17 (4 marks, 2 min.) [68, 34]
ANSWER KEY
1. (C) 2. (B) 3. (A) 4. (C) 5. (D) 6. (C) 7. (B)
8. (B) 9. (A) 10. (C) 11. (D) 12. (B) 13. (C) 14. (B)
15. (B) 16. (D) 17. (B)

1. (C) 2. (C) 3. (B) 4. (B) 5. (A) 6. (A) 7. (B)
8. (B) 9. (A) 10. (B) 11. (B) 12. (C) 13. (D) 14. (B)
15. (C) 16. (A) 17. (C) 18. (D) 19. (C) 20. (C)

1. (B) 2. (A) 3. (D) 4. (C) 5. (A) 6. (C) 7. (D)
8. (D) 9. (D) 10. (D) 11. (B) 14. (A) 12. (C) 13. (D)
15. (C) 16. (A) 17. (C) 18. (D) 19. (B) 20. (A)

1. (C) 2. (D) 3. (A) 4. (B) 5. (C) 6. (D) 7. (D)
8. (C) 9. (A) 10. (B) 11. (B) 12. (A) 13. (A) 14. (D)
15. (B) 16. (A) 17. (C) 18. (D) 19. (C) 20. (D)
Isomerism in Alkane & Alkene

,Yd su rFkk ,Yd hu esal eko;ork %
(1) Geometrical Isomerism :
Two compounds having same structural formula but different orientation of atoms or groups in space due
to restricted rotation of bonds are known as geometrical isomers.
e.g.
PAGE NO.- 1
(1) T;kferh; l eko;ork :
,sl s;kSfxd ft ud slajpukRed lw=k leku gksrsgSay sfd u ca/kksad sizfrcaf/kr ?kw.kZu d sd kj.k f=kfoe esaijek.kqv ksavFkok
lewgksad k vfHkfoU;kl fHkUu&fHkUu ik;k t krk gS] mUgsaT;kferh; leko;oh d grsgSrFkk bl leko;ork d ksT;kferh;
leko;ork d grsgSaA
mnk-
Nomenclature of Geometrical isomers :

Cis-Trans naming : If similar group present at once side of double bond/ring known as cis isomer and
if present at opposite side of double bond/ring known as trans isomer.
Cis and trans are G.I. of each other.
e.g.
T;kferh; l eko;oh;ksa d k uked j.k %

l ei{k&foi{k uked j.k % ;fn f}ca/k@oy ; d s,d rjQ leku lewg ik;st krsgS] rksblslei{k leko;oh d grs
gSrFkk ;fn f}ca/k@oy ; d h foijhr lrgksaij leku lewg ik;st krsgS] rksblsfoi{k le;ko;oh d grs
gS
A
lei{k rFkk foi{k leko;oh ,d &nwl jsd sT;kferh; leko;oh gksrsgSA
mnk-
1. Among the given compounds identify the pair of geometrical isomers :-

fn;sx;s;kSfxd ksesT;kferh; leko;oh;ksad s;qXe d ksigpkfu;s%
(A) I & II (B) I & III (C*) II & IV (D) III & IV
(A) I rFkkII (B) I rFkkIII (C*) II rFkkIV (D) III rFkkIV
PAGE NO.- 2
2. Which of the following is cis-isomer \
fuEu esalsd kSu lk lei{k& leko;oh gS\
(A) (B*)
(C) (D)
3. Which of the following is trans-isomer \

fuEu esalsd kSu lk foi{k& leko;oh gS\
(A*) (B) (C) (D)
Preparation of Alkene
(1) from partially hydrogenation of alkyne
The hydrogenation with poisoned Pd + H2 + BaSO4 + S or quinoline (Lindlar's catalyst) reduces triple bond to
double bond stereo specifically via syn addition (addition of both H atom from the same side) where as the
reduction with alkali metal in liquid NH3 (Birch reduction) reduces triple bond to double bond stereo specifically
via anti addition. (addition of H-atom from two different sides, above and below the plane)
R R
Poisoned Na / liq NH
R  C  C  R  H2    C=C ; R  C  C  R  H2 
3

Pd
H H
(cis alkene)
R H
C=C
H R
(Trans alkene)
,Yd hu d k fojpu %
(1) ,Yd kbZu d sv kaf'kd gkbMªkst uhd j.k }kjk %
fo"kkDr Pd + H2 + BaSO4 + S ;kfDouksy hu ¼fy .My kj mRizsjd ½ d hmifLFkfr esagkbMªkst uhd j.kij f=kca/kf=kfoe fof'k"V
: i lsflu ;ksx }kjkf}ca/kesavipf;r gkst krkgS¼flu ;ksx %leku lrg ij nksuks aH ijek.kqv ks
ad k;ksx gksrkgSA½ t cfd
SCl NH3 es a{kkj /kkrq¼cpZvip;u½d hmifLFkfr esaf=kca
/kf=kfoe fof'k"V : i ls,s
.Vh&;ksx }kjkf}ca/kes avipf;r gkst krk
gSA ¼nksfofHkUu lrgksa]Å ij ,oeauhpsd h lrg ij H-aijek.kqd k ;ksx gksrk gSA½
Poisoned nzo NH3
R  C  C  R  H2    ; R  C  C  R  H2  
Pd
Poisoned
4. CH3  C  C CH3  H2  Product is
Pd
fo"kkDr
CH3  C  C CH3  H2 
 mRikn gS%
Pd
(A) CH3  CH2  CH2  CH3 (B) CH3  CH2  CH  CH2
CH3 CH3 CH3 H

(C*) (D)
C C C C
H H H CH3
PAGE NO.- 3
Na / liq NH
5. CH3 — C  C — CH3 
3
 Product is.
Na / nz
o NH
CH3 — C  C — CH3 
3
 mRikn gS%
(A) CH3  CH2  CH2  CH3 (B) CH3  CH2  CH  CH2
CH3 CH3 CH3 H

(C) (D*)
C C C C
H H H CH3
6. Poisoned Pd
CH3 — CH2 — C  C — CH3  H2  Product is.
fo"kkDr Pd
CH3 — CH2 — C  C — CH3  H2  mRikn gS%
CH3 -CH2 H
(A) CH3 — CH2 — CH2 — CH2 — CH3 (B)
C C
H CH3
CH3-CH2 CH3
(C*) (D) CH3 — CH2 — CH2 — CH  CH2
C C
H H
Na / liq.NH3
7. CH3 — CH2 — C  C — CH3   Product is.
Na / nz
o NH
CH3 — CH2 — C  C — CH3 
3
 mRikn gS%
CH3 -CH2 H
(A) CH3 — CH2 — CH2 — CH2 — CH3 (B*)
C C
H CH3
CH3-CH2 CH3
(C) (D) CH3 — CH2 — CH2 — CH  CH2
C C
H H
(2) Dehydrohalogenation of alkyl halide

Alkyl halide on heating with alcoholic potash ( Potassiam hydroxide dissolved in alcohol) eliminate one
molecule of halogen acid to form alkene. This reaction is known as dehydrohalogenation.
This is example of  - elimination reaction since  -hydrogen atom is eliminated from the  - carbon atom.
H H
H C C alc.KOH
H  H H
 C C
 H H
H X
( X = Cl, Br, I )
Note-
(1) Order of ease of dehydrohalogenation of R – X : 3o > 2o > 1o
(2) Reactivity order of R–X : R–I > R – Br > R– Cl
(3) More stable alkene is formed as major product.
(2) ,fYd y gSy kbM d sfogkbMªksgSy kst uhd j.k }kjk %
t c ,fYd y gSy kbM d ks,Yd ksgkWfy d ikSVk'k¼,Yd ksgkWy esa?kqfy r iks
VSf'k;e gkbMªksDlkbM½ d slkFkxeZd jrsgS]rksgSy kst u
vEy d k,d v.kqfoy ksfir gksusij ,Yd hu curhgSA bl vfHkfØ ;kd ksfogkbMªksgSy kst uhd j.kd grsgSA
;g  - foy ksiu vfHkfØ ;k d k mnkgj.k gSD;ksafd  - d kcZu ijek.kqls - gkbMªkst u ijek.kqd kfoy ksiu gksrk gSA
PAGE NO.- 4
H H
,Yd k-sKOH H H
H C C H 
 C C
 H H
H X
( X = Cl, Br, I )
uksV&
(1) R – X d sfogkbMªksgSy kst uhd j.k d k ljy rk lsgksusd k Ø e : 3o > 2o > 1o
(2) R–X d h fØ ;k'khy rk d k Ø e : R–I > R – Br > R– Cl
(3) vfèkd LFkk;h ,fYd u eq [; mRikn d s: i esaizkIr gksrh gSA
alc.KOH ,sYd k-s KOH

8. CH3 —CH2 —CH2 —CH2 —CH2 

 Product is.
 mRikn gS%

Cl
(A) CH3—CH2—CH2—CH2—CH3 (B*) CH3—CH2—CH2—CH=CH2
(C) CH3— C CH CH3 (D) CH3— C CH CH3

CH3 CH3

9. CH3—CH2—CH2—CH—CH3 

 Product is.
 mRikn gS%

Cl
(A*) CH3—CH2—CH = CH—CH3 (B) CH3—CH2—CH2—CH=CH2
(C) CH3— C CH CH3 (D) CH3— C CH CH3

CH3 CH3
10. CH—
3 CH—CH—CH3   Major Product is.
 eq[; mRikn gS%
 
CH3 Cl
(A) CH3—CH2—CH = CH—CH3 (B) CH3—CH2—CH2—CH=CH2
(C*) CH3— C CH CH3 (D) CH3— C CH CH3
CH3 CH3
,sYd k-s KOHalc.KOH
11. CH3—CH—CH2—CH2—Cl    Product is.mRikn gS%
 
CH3
(A) CH3—CH2—CH = CH—CH3 (B) CH3—CH2—CH2—CH=CH2
(C) CH3— C CH CH3 (D*) CH—
3 CH—CH=CH2
CH3 CH3
(3) From vicinal dihalide
Dihalide in which two halogen atoms are attached to two adjacent carbon atoms are known as vicinal
dihalides. Vicinal dihalide on treatment with Zinc metal lose a molecule of ZnX2 to form an alkene. This
reaction is known as dehalogenation.
Br Br
(3) fofl uy MkbgSy kbM }kjk %
MkbgSy kbM ft uesanksgSy kst u ijek.kqnksfud VorhZd kcZu ijek.kqv ksalst qM +sgksrsgS]mUgsafofluy MkbgSy kbM d grsgSA
fofluy MkbgS y kbM d hvfHkfØ ;kZn /kkrqd slkFkd jkusij ZnX2 d sfu"d kflr gks usij ,Yd hu curhgSA bl vfHkfØ ;kd ks
fogSy kst uhd j.kd grsgSA
Br Br
PAGE NO.- 5
12. – Product is mRikn gS%
(A) CH2 = C = CH2 (B*) CH3— CH = CH2 (C) CH2 = CH2 (D)CH3—CH2— CH = CH2
13. Zn dust
  product is
Zn pw
.kZ
  mRikn gS%
(A) Ph — C  CH (B) (C*) Ph — CH  CH2 (D) Ph — CH3
Zn dust
14.  Product is

Zn pw
.kZ
(A) CH2  CH — CH2 — CH3 (B*) CH3 — CH  CH — CH3

(C) CH2  CH — CH  CH2 (D)
(4) From alcohol by acidic dehydration

Alcohols on heating with concentrated sulphuric acid form alkene with the elimination of one water
molecule. Since a water molecule is eliminated from the alcohol molecule in the presence of an acid ,this
reaction is known as acidic dehydration of alcohols.
This reaction is example of  - elimination reaction since –OH group takes out hydrogen atom from the  -
carbon atom.
Conc.H SO
2 4
 CH –CH=CH–CH
 3 3
(1) Ease.of dehydration of alcohol  3o > 2o > 1o

(2) More stable alkene is formed as major product
(4) ,Yd ksgkWy ksad sv Ey h; fut Zy hd j.k }kjk %
,Yd ksgkWy ksad kslkUnzlY¶;wfjd vEy d slkFkxeZd jusij t y d s,d v.kqd kfoyks iu gksusij ,Yd hu curhgSA pwfd vEy
¡
d hmifLFkfr es a,Yd ks
gkW
y v.kqlst y v.kqd kfoyks
iu gks
rkgS
]blfy, bl vfHkfØ ;kd ks,Yd ks gkW
y ks
ad kvEyh; fut Z
y hd j.k
d grsgSA ;g vfHkfØ ;k  - foy ksiu vfHkfØ ;kd kmnkgj.kgSpw¡fd  – d kcZ
u ijek.kqls–OH lewg gkbMª ks
t u ijek.kqxzg.k
d jrkgS A
l kUn-zH2SO4
  CH –CH=CH–CH
 3 3
(1) ,Yd ks
gkWy d sfut Zy hd j.k d h ljy rk lsgksusd k Ø e  3o > 2o > 1o
(2) vfèkd LFkk;h ,fYd u eq [; mRikn d s: i esaizkIr gksrh gSA
PAGE NO.- 6
Conc.H2SO 4
15.  

 Major product is
OH
lkUn-zH2SO4
  eq
[; mRikn gS%

OH
(A) CH3 — CH2 — CH  CH2 (B*) CH3 — CH  CH — CH3
(C) CH3 — CH2 — CH2 — CH3 (D)
Conc.H2SO 4
16.  

 product is
OH
l kUn-zH2SO4


 mRikn gS%
OH
(A) CH3 — CH2 — CH  CH2 (B) CH3 — CH  CH — CH3
(C) CH3 — CH2 — CH2 — CH3 (D*)
Conc.H SO
17. 2
   
4
 Major product is

OH
l kUn-zH2SO4


 eq[; mRikn gS%
OH
(A) Ph — CH2 — CH  CH2 (B*) Ph — CH  CH — CH3
(C) Ph (D)

Chemical reactions of alkene

,Yd hu d h jkl k;fud v fHkfØ ;k
(1) Addition of halogens :
Halogens like bromine or chlorine add up to alkene to form vicinal dihalides.Addition of halogen to alkene is
an example of electrophilic addition reaction. This reaction is used as a test for unsaturation.
CCl4
CH2  CH2  Br2  
gSy kst uksad k ;ksx %

gSy kst u t Sl sfd czksehu ;kDy ksjhu],Yd hu lst qM +usij fofluy MkbgSy kbM cukrhgSA ,Yd hu ij gSy kst uksad k;ksx ,d
by sDVª kW
uLusgh;ksxkRed vfHkfØ ;kd kmnkgj.kgSA bl vfHkfØ ;kd kmi;ksx vla rÌrrkd kijh{k.kd jusd sfy, fd ;kt krk
gS
A
PAGE NO.- 7
CCl4
CH2  CH2  Br2  
CCl
1. CH3 — CH  CH2  Br2 
4
 Product is. mRikn gS%
(A) (B)
(C*) (D)
 Product is. mRikn gS%

2. CCl4
CH3 — CH  CH — CH2 — CH3  Br2 
(A) (B)
(C*) (D)
3. Br2 / CCl4
  Product is. mRikn gS%
(A) (B*)
(C) (D)
(2) Addition of Hydrogen halides :

Addition of HX to unsymmetrical alkene place according to Markovinikov rule.
Markovnikov rule : The rule states that the negative part of the attacking species add on the carbon atom
containing less number of hydrogen atom.
(2) gkbMªkst u gSy kbMksad k ;ksx %

vlefer ,Yd hu ij HX d k;ksx ekjd ksuhd kWQ fu;e d svuql kj gksrkgSA
eksjd ksuhd kWQ fu;e %
vfHkd kjd d k _ .kkRed Hkkx ml d kcZu ijek.kqlst qM +rkgS]ft l ij gkbMªkst u ijek.kqv ksad h la[;kd e gksrhgSA
PAGE NO.- 8
d e LFkk;h d kcZ
/kuk;u
¼vYi mRikn½
vf/kd LFkk;h d kcZ/kuk;u

eq[; mRikn
4. Major Product. eq
[; mRikn gS%
(A) (B*)
(C) (D)
5. + HBr Major Product. eq

[; mRikn gS%
(A*) (B) (C) (D)
6. Ph — CH  CH2  HBr Product is. mRikn gS%

(A*) (B)
(C) (D) Ph — C  CH
(3) Addition of HBr in Presence of peroxide or Kharash effect or Anti Markovnikov effect :
In the presence of peroxide such as benzoyl peroxide [ ] and light, the addition of
HBr to unsymmetrical alkene occurs contrary to Markovnikov’s rule.

Peroxide
CH3 — CH  CH2  HBr  
PAGE NO.- 9
(3) ijkWDlkbM d h mifLFkfr esaHBr d k ;ksx ;k [kjk'k izHkko ;k ,s.Vh&eksjd ksuhd kWQ izHkko
iz
d k'krFkkijkW
DlkbM d hmifLFkfr es
at Sl scs
Ut kW
;y ijkW
DlkbM [ ] vlefer ,Yd hu ij HBr
d k;ksx ekjd ksuhd kWQ fu;e d sfoijhr gksrkgSA

ijkWDl kbM
CH3  CH  CH2  HBr   
Peroxide
7. Ph — CH  CH2  HBr   Product is
ijkWDlkbM
Ph — CH  CH2  HBr   mRikn gS%
(A) (B*)
(C) (D) Ph — C  CH
8. Peroxide
  Product is
ijkWDlkbM
(A) (B*) CH3
(C) (D)
peroxide
9. + HBr   Major product
ijkWDlkbM
+ HBr   eq[;’mRikn gS%
(A*) (B) (C) (D)
(4) Addition of sulphuric acid :

Cold concentrated sulphuric acid add to alkene in accordance with Markovnikov rule to form alkyl hydrogen
sulphate.
PAGE NO.- 10
(4) lY¶;wfjd v Ey d k ;ksx %
,Yd hu ij B.MslkUnzlY¶;w
fjd vEy d k;ksx eksjd ksuhd kWQ fu;e d svuq
l kj gksusij ,fYd y gkbMª
ks
t u lYQ sV curkgSA
10. Ph–CH=CH–CH3 + Conc.H2SO4  Major Product is : eq[; mRikn gS%

(A) Ph–CH 2–CH–CH 3 (B*) Ph–CH–CH 2–CH 3
O–SO 2OH O–SO 2OH
(C) Ph–CH 2–CH 2–CH 2 (D) None of these bues
alsd ksbZugha
O–SO 2OH
11. + Conc.H2SO4 Major product is : eq[; mRikn gS%
(A) (B*)
(C) (D)
(5) Addition of water :

Alkene react with water to form alcohols, in accordance with the markovinikov rule.
(5) t y d k ;ksx %
ekjd ksuhd kWQ fu;e d svuql kj ,Yd hu]t y d slkFkvfHkfØ ;kd jd s,Yd ksgkWy cukrhgSA
12. Ph–CH=CH–CH3+H2O 
H


Major product is : eq[; mRikn gS%
(A) Ph–CH 2–CH2–CH2 (B) Ph–CH 2–CH–CH 3
OH OH
(C*) Ph–CH–CH 2–CH 3 (D) None of these buesalsd ksbZugha
OH
13. + H2O 
H 
 Major product is : eq[; mRikn gS%
OH OH
(A) (B) (C) (D*)
OH OH
(6) Oxidation of alkene :
Acidic potassium premanganate or acidic potassium dichromate oxidise alkene to ketone and/or acids
depending upon the nature of the alkene.
PAGE NO.- 11
CH3–CH=CH–CH3 2CH3COOH
Alkene having = CH2 will give CO2 as one of the oxidation product by oxidising agent KMnO4 and K2Cr2O7.
(6) ,Yd hu d k v kWDlhd j.k :

vEy h; iksVs
f'k;e ijeSaXusV ;kvEyh; iksVS
f'k;e MkbØ ks
es
V],Yd hu d ksbld hiz
d f̀r d svk/kkj ij d hVksu rFkk@;kvEyksaesa
vkWDlhd r̀ d j nsrkgSA
CH3–CH=CH–CH3 2CH3COOH
,Yd hu t ks= CH2 j[krsgSt ksvkW
Dlhd kjhvfHkd eZd KMnO4 rFkkK2Cr2O7 d s}kjkCO2 d s: i es
a,d vkW
Dlhd kjhmRikn
ns
rsgSA
14. mRikn gS
(A) CH3–COOH and CH3–CHO (B*) CH3–C–CH3 and CH3COOH

O
(C) CH 3–C–CH 3 and CH 3CHO (D) CH3–CHO and CH3–C–COOH
O O
(A) CH3–COOH rFkkCH3–CHO (B*)
(C) (D)
15. CH3–CH=CH–CH2–CH3 Products is : mRikn gS

(A) CH3–C–CH3 and CH3COOH (B) CH3–CH2–CHO and CH3–COOH
O
(C*) CH3–CH2–COOH and CH3COOH (D) CH 3–C–CH 3 and CH 3CHO
O
(A) CH3–C–CH3 and CH3COOH (B) CH3–CH2–CHO rFkkCH3–COOH
O
(C*) CH3–CH2–COOH rFkkCH3COOH (D) CH 3–C–CH 3 and CH 3CHO
O
KMnO4 /H
16. CH3–CH2–CH=C–CH2–CH3 Products is-
CH
O 3
(A*) CH 3–CH 2–COOH and CH 3–C–CH 2–CH 3 (B) CH3COOH and CH3–C–CH2–CH3
O O
(C) CH3–C–CH3 and CH3CH2COOH (D) CH 3–CH 2COOH and CH 3–C–COOH
O O
KMnO4 /H
CH3–CH2–CH=C–CH2–CH3 mRikn gS
CH
O 3
(A*) CH3–CH2–COOH rFkk CH3–C–CH2–CH3 (B) CH3COOH rFkk CH3–C–CH2–CH3
O O
(C) CH3–C–CH3 rFkk CH3CH2COOH (D) CH3–CH2COOH rFkk CH3–C–COOH
O O
PAGE NO.- 12
(7) Oxidation of alkene with dil. KMnO4 (Bayer’s reagent) :
H.A.

H.A. = Hydroxylating agent. It may be any one of these :

(a) Bayer’s reagent: cold dilute 1% alkaline KMnO4 (pink color) or
(b) (i) OsO4 (ii) NaHSO3
Note :
Double bond of Aromatic ring cannot react with these reagents.
It is syn addition. Both OH groups add on the same side of pi-bond.
Ex. H.A.

(7) ruqKMnO4 ¼cs;j v fHkd eZd ½ }kjk ,Yd hu d k v kWDlhd j.k %
H.A.

H.A. = gkbMª ksfDly hd j.kvfHkd eZd A buesalsd ksbZHkhgksld rkgSA

(a) cs;j v fHkd eZd % B.Mk ruq1% {kkjh; KMnO4 ¼xqy kch jax½ ;k
uksV :
,sjkseSfVd oy ; d sf}ca/kbu vfHkd eZd ksad slkFkvfHkfØ ;kughad jrsgSA
;g flu;ksx gksrk gSA nksuksaOH lewg ikbZca/k d sleku lrg ij t qM +rsgSA
H
OH
Ex. H.A.

OH
lkbDyksgs
Dl hu H
lei{k&lkbDyks
gs
Dls
u-1,2-MkbvkWy
Baeyer's reagent
17.  Product ; Product will be :
     
cs;j vfHkd eZd

  mRikn ; mRikn gksxk %
OH
HO OH
(A) (B) (C*) (D)
HO OH OH
18.
Reagent x will be :
(A) 1% alkaline KMnO4 (Bayer’s reagent) (B) OsO4 /NaHSO3
(C) Peracid/H3O+ (D*) A and B both
PAGE NO.- 13
vfHkd eZd x gksxk :
(A) 1% {kkjh; KMnO4 (cs
;j vfHkd eZd ) (B) OsO4 /NaHSO3
(C) ij&vEy /H3O +
(D*) A rFkk B nks
uksa
Baeyer 's Re agent

19. CH3 – CH=CH – CH3 or
      Product ; Product will be :
OsO / NaHSO 4 3
cs;j vfHkd eZd

CH3 – C  C – CH3   mRikn ; mRikn gksxk %
;k OsO4 / NaHSO3
(A) (B)
(C*) (D)
20. Which one of the following can not undergo in hydroxylation.

fuEu esalsfd l ;kSfxd d k gkbMªksfDly hd j.k ughagksld rk gS\
(A) (B) (C*) (D)

Preparation of Alkyne
1. Dehydrohalogenation of gem and vic dihalide :
Dihalide in which two halogen atoms are attached to two adjacent carbon atoms are known as vicinal
dihalides.
Dihalide in which two halogen atoms are attached to same carbon atoms are known as geminal dihalides.
H H
| |
2 NaNH
2  R  C  C  R  2NaBr
R  C C R   
| |
Br Br
A vic  dibromide
,Yd kbZu d k fojpu

1. t Se ,oafol MkbgSy kbMksad sfogkbMªksgSy kst uhd j.k }kjk %
MkbgSy kbM ft uesanksgSy kst u ijek.kqnksfud VorhZd kcZu ijek.kqv ksalst qM +sgksrsgS]mUgsafofluy MkbgSy kbM d grsgSA
MkbgSy kbM ft uesanksgSy kst u ijek.kq,d d kcZu ijek.kqv ksalst qM +sgksrsgS]mUgsat Sfeuy MkbgSy kbM d grsgSA
H H
| |
2 NaNH
2  R  C  C  R  2NaBr
R  C C R   
| |
Br Br
A vic  dibromide
NaNH
1.  Product is.mRikn
2
CH3–CH2–CH2–CHCl2    gS%
Ä
(A) CH3–C  C–CH3 (B*) CH3–CH2–C  CH

(C) CH2=CH–CH=CH2 (D) CH3–CH2–CH = CH2
NaNH
2.  Product is. mRikn
2
Ph–CCl2–CH3    gS%
Ä
(A*) Ph–C  CH (B) CH3–C  CH (C) Ph–CH = CH2 (D) Ph–CH = CHCl
PAGE NO.- 14
NaNH
3.  Major product is eq
2
CH3–CHCl–CH2Cl    [; mRikn gS%
Ä
(A) CH2=C = CH2 (B) CH3–C = CH2 (C) CH3–CH = CCl2 (D*) CH3–C  CH
2. Dehalogenation of tetrahaloalkane :
2. VsVªkgSy k,Yd su d sfogSy kst uhd j.k }kjk %
R – C  C – R + 2Zn X2
Zn
4.  Product is mRikn
CH3–CBr2–CHBr2 Ä gS%
(A) CH2 = C = CH2 (B) CH3— CH = CH2 (C*) CH3–C  CH (D) CH3–CBr = CBr2
Zn
5.  

 Product is mRikn gS%
(A*) Ph–C  C–CH3 (B) Ph–CH2–C  CH (C) Ph–C=C=CH2 (D) Ph–CBr2–C  CH
3. Kolbe's electrolytic synthesis :

3. d ksYcsoS| qrv i?kVu la'y s"k.k }kjk:
Electrolysis o|
S qr viV?kVu
+ H2O Current
    R – C  C – R + 2CO2 + 2KOH + H2
fo| qr /kkjk
If R = H, product will be CH  CH ; If R = CH3, product will be CH3 – C  C – CH3.

;fn R = H gksxk rksmRikn CH  CH gksxk; ;fn R = CH3 gksxk]mRikn CH3 – C  C – CH3 gksxkA
6. Electrolys
  is
 product is
fo| qr vi?kVu mRikn gS%

 
(A) Ph–CC–CH3 (B) Ph–CH=CH–Ph (C*) Ph–CC–Ph (D) Ph–CH2–CH2–Ph
7. Electrolys
  is
 product is :
fo| qr vi?kVu mRikn gS%

 
(A) CHCH (B) CH3–CH=CH2 (C) CH3–CH2–CH3 (D*) CH3–CCH
4. Hydrolysis of carbides :
4. d kckZbMksd st y v i?kVu }kjk %
CaC2 + 2HOH  C2H2 + Ca(OH)2 ; Mg2C3 + 4HOH  CH3 – C  CH + 2Mg(OH)2
8. The caribide which gives propyne on hydrolysis is
fd l d kckZbZM +d st y vi?kVu lsizksikbZu izkIr gksxhA
(A) Al4C3 (B) CaC2 (C) Fe3C (D*) Mg2C3
PAGE NO.- 15
Chemical reactions of alkyne
(1) Addition of halogens :
Halogens like bromine or chlorine add up to alkyne to form trans dihalides and further addition of halogen give
tetrahalo alkane. It is an example of electrophilic addition reaction. This reaction is used as
a test for unsaturation.
Br Br Br
– –
– –
–
Br2 (1eq.)
R – C  C – R  Br2 (1eq.)
  R – C = C – R      R – C – C – R
–
Br Br Br
(Trans-dihalide) (Tetrahalide)
,Yd kbZu d h jklk;fud v fHkfØ ;k
(1) gSy kst uksad k ;ksx %
gS
y ks
tu tS l sfd czks
ehu ;kDykjshu],Yd kbZ
u lst q
Mu+sij Vª
ka
l MkbgS
y kbM cukrhgS
A t ksiq
u%gS
y ks
t u d s;ks
x lsVs
VkªgS
y ks
,Yd s
u
cukrkgSA ;g ,d bysDVªkWuLusgh;ks xkRed vfHkfØ ;kd kmnkgj.kgSA bl vfHkfØ ;kd kmi;ksx vlarÌrrkd kijh{k.kd jus
d sfy , fd ;k t krk gSA
Br2 (1eq.)
R – C  C – R  Br (1eq.)
  2  
CCl4
9. CH3–C  CH + Br2   Product is.mRikn gS%
(A) (B)
(C) (D*) CH3–CBr2–CHBr2
CCl
10. CH3–C  C–CH2–CH3 + Cl2  4 Product is.mRikn gS%
(A) (B)
(C) (D*) CH3–CH2–CCl2–CCl2–CH3
CCl
11. CH3–C  C–CH3 + Cl2 (1 eq.)  4 Product is. mRikn gS%
(A) (B*)
(C) (D)
(2) Addition of Hydrogen halides :

Addition of HX to unsymmetrical alkyne place according to Markovinikov rule.
Markovnikov rule : The rule states that the negative part of the attacking species add on the carbon atom
containing less number of hydrogen atom.
Br
– –
HBr ( dark ) HBr

R – C  C – H     R–CBr=CH2   R – C – CH 3
Br
PAGE NO.- 16
(2) gkbMªkst u gSy kbMksad k ;ksx %
vlefer ,Yd kbZu ij HX d k;ksx ekjd ksuhd kWQ fu;e d svuql kj gksrkgSA
eks
jd ksuhd kW
Q fu;e %vfHkd kjd d k_ .kkRed Hkkx ml d kcZu ijek.kqlst qM+rkgS]ft l ij gkbMªkst u ijek.kqv ksad hla[;k
d e gksrh gSA
Br Br
–
HBr ( va/ksjsesa
)
– –
HBr
R – C  C – H  R – C = C – H   R – C – CH 3
–
H Br
(MK)
14. CH3–C C – CH3 + HBr  Product is. mRikn gS%
(A*) (B)
(C) (D)
(3) Addition of HBr in Presence of peroxide or Kharash effect or Anti Markovnikov effect :
In the presence of peroxide such as benzoyl peroxide [Ph–CO–O–O–CO–Ph] and light, the addition of HBr
to unsymmetrical alkyne occurs contrary to Markovnikov’s rule.
Peroxide
CH3 – C  CH + HBr    CH3– CH2– CHBr2
(3) ijkWDlkbM d h mifLFkfr esaHBr d k ;ksx ;k [kjk'k izHkko ;k ,s.Vh&eksjd ksuhd kWQ izHkko
izd k'krFkkijkWDlkbM d hmifLFkfr es at S
l scsUt kW;y ijkWDlkbM [Ph–CO–O–O–CO–Ph] vlefer ,Yd kbZ
u ij HBr d k
;ksx ekjd ksuhd kWQ fu;e d sfoijhr gksrkgSA
Peroxide
CH3 – C  CH + HBr    CH3– CH2– CHBr2
12. Ph–C  CH + HBr  Product is. mRikn gS%

(A) (B)
(C*) Ph–CBr2–CH3 (D) Ph–CH2–CHBr2
13.   Product is. mRikn

Ph–C  CH + HBr Peroxide gS%
(A) (B)
(C) Ph–CBr2–CH3 (D*) Ph–CH2–CHBr2
(4) Addition of water :

Alkyne react with water to form carbonyl compounds, in accordance with the markovinikov rule.
H
|
R  C  C  H  H2 O R CCH
|| |
( Markoniko ff rule) O H
ketone
( stable )
PAGE NO.- 17
(4) t y d k ;ksx %
ekjd ksuhd kWQ fu;e d svuql kj ,Yd kbZu]t y d slkFkvfHkfØ ;kd jd sd kcksZfuy ;kSfxd cukrhgSA
15. CH3– C  CH Major Product is : eq

[; mRikn gS%
(A) (B) CH3–CH2–CHO
(C*) (D)
16. Ph–CC–CH3+H2O Major product is : eq[; mRikn gS%

(A*) (B) Ph–CH 2–CH–CH 3
OH
(C) Ph–CH–CH 2–CH 3 (D)
OH
(5) Oxidation of alkyne :

Acidic potassium premanganate or acidic potassium dichromate oxidise alkyne to acids .
O.A. O.A.
 2RCOOH  + CO2
Alkyne having  C–H will give CO2 as one of the oxidation product by oxidising agent KMnO4 and K2Cr2O7.
O.A. O.A.
 2CH COOH  + CO2
3
(5) ,Yd kbZu d k v kWDlhd j.k :

vEy h; iksVsf'k;e ijeSaXusV ;k vEy h; iksVSf'k;e MkbØ ksesV],Yd kbZu d ksvEy ksaesavkWDlhd r̀ d j nsrk gSA
O.A. O.A.
 2RCOOH  + CO2
,Yd kbZ
u t ks CH j[krsgSt ksvkW
Dlhd kjhvfHkd eZ
d KMnO4 rFkkK2Cr2O7 d s}kjkCO2 d s: i esa,d vkW
Dlhd kjhmRikn
ns
rsgSA
O.A. O.A.
 2CH COOH  + CO2
3
17. CH3–C  C – CH2–CH3 Products is :

(A) CH3–C–CH3 and CH3COOH (B) CH3–CH2–CHO and CH3–COOH
O
(C*) CH3–CH2–COOH and CH3COOH (D) CH 3–C–CH 3 and CH 3CHO
O
CH3–C  C – CH2–CH3 mRikn gS%
(A) (B) CH3–CH2–CHO rFkkCH3–COOH
(C*) CH3–CH2–COOH rFkkCH3COOH (D)
PAGE NO.- 18
18. CH3–CH2–C  CH Products is : mRikn gS%
(A) CH3–CH2–COOH & HCOOH (B) CH3–COOH & CH3–COOH

(C) & CO2 (D*) CH3–CH2–COOH & CO2
CH3–CH2–C  CH mRikn gS%

(A) CH3–CH2–COOH o HCOOH (B) CH3–COOH o CH3–COOH
(C) o CO2 (D*) CH3–CH2–COOH o CO2
(6) Oxidation of alkyne with dil. KMnO4 (Bayer’s reagent) :
H.A.
—CC— 
H.A. = Hydroxylating agent. It may be any one of these :
(a) Bayer’s reagent: cold dilute 1% alkaline KMnO4 (pink color) or
(6) ruqKMnO4 ¼cs;j v fHkd eZd ½ }kjk ,Yd kbZu d k v kWDlhd j.k %
H.A.
—CC— 
H.A. = gkbMª ksfDly hd j.kvfHkd eZd A buesalsd ksbZHkhgksld rkgSA
(a) cs;j v fHkd eZd % B.Mk ruq1% {kkjh; KMnO4 ¼xqy kch jax½ ;k
Baeyer 's Re agent
19. Ph–C  C–CH3       Product is :
or OsO4 / NaHSO3
cs; j vfHkd eZd

Ph–C  C–CH3  mRikn gS%
;kOsO4 / NaHSO3
(A) (B*)
(C) (D)
Baeyer 's Re agent cs; j vfHkd eZd

20. CH3–C  CH        Product is : mRikn gS%
or OsO4 / NaHSO3 ;kOsO4 / NaHSO3
(A*) (B)
(C) (D)
PAGE NO.- 19
Preparation of Benzene
csUt hu d k fuekZ.k
1. By polymerisation of Acetylene :
Re d hot iron tube

3HC  CH     
,flfVy hu d scgqy hd j.k }kjk :

jDr rIr y kSg ufy d k
3HC  CH       
1. On heating a mixture of sodium benzoate and sodalime, the following is obtained

(A) Toluene (B) Phenol (C*) Benzene (D) Benzoic acid
lksfM;e csUt ks,V rFkk lksM k y kbZe d sfeJ.k d ksxeZd jusij]fuEu esalsd kSulk d kcZfud ;kSfxd izkIr gksrk gSA
(A) VkW
y wbZu (B) fQ ukW
y (C*) cs
Ut hu (D) cs
Ut ksbd vEy
Re d hot iron tube jDr rIr y kSg ufy d k product is mRikn

2. 3CH3–C  CH             gS:
(A) (B) (C) (D*)
2. By decarboxylation of Benzoic acid :

csUt ksbd v Ey d sfod kcksZfDlfy d j.k }kjk :
NaOH
NaOH   + Na2CO3
  ( CaO )
NaOH / CaO
3.    product is mRikn gS:

(A*) (B) (C) (D)
3. By catalytic reforming of n-Hexane :
Pt, 873 K Pt, 873 K

CH3 – (CH2)4 – CH3      
 H2  3H2
PAGE NO.- 20
n-gs
Dlsu d h mRizsjd h; v fHkfØ ;k }kjk :
Pt, 873 K Pt, 873 K

CH3 – (CH2)4 – CH3      
 H2  3H2
Pt
4.  product is mRikn
CH3 – (CH2)5 – CH3 873 gS:
K
(A) (B*) (C) (D)
4. By reduction of Phenol :
fQ ukWy d sv ip;u }kjk:
Zn


Zn
5. 

product is mRikn gS:
(A) (B) (C*) (D)
Zn
6. 

product is mRikn gS:
(A) (B) (C) (D*)
Chemical reactions of Benzene

csUt hu d h jkl k;fud v fHkfØ ;k
Benzene has clouds of pi electrons above and below its sigma bond framework. Although benzene’s pi
electrons are in a stable aromatic system still they are available to attack a strong electrophile to give a
carbocation. This resonance-stabilized carbocation is called a sigma complex because the electrophile is
joined to the benzene ring by a new sigma bond.
The sigma complex (also called an arenium ion) is not aromatic because the sp3 hybrid carbon atom interrupts
the ring of p orbitals. This loss of aromaticity contributes to the highly endothermic nature of thus first step.
The sigma complex regains aromaticity either by a reversal of the first step (returning to the reactants) or by
loss of the proton on the tetrahedral carbon atom, leading to the substitution product.
PAGE NO.- 21
 
The overall reaction is the substitution of an electrophile (E ) for a proton (H) on the aromatic ring: electrophilic
aromatic substitution.
csUt hu d sflXekca/kd sÅ ij rFkkuhpsd hvksj ikbZbysDVª kWu vHkzik;kt krkgS A ;|fi csUt hu d sikbZby sDVªkW
u ,d LFkk;h
,s
jkseSfVd ra=kesaik;kt krkgSfQ j Hkh;g izcy bysDVªkWuLus ghd svkØ e.kij miyC/kgksrsgSarFkkft llsd kcZ/kuk;u curk
gSA bl vuqukn LFkk;hd r̀ d kcZ/kuk;u d ksflXekl ad q y d grsgSaD;ksa
fd by sDVªkWuLus
gh,d u;sflXekca/k}kjkcsUt hu oy ;
lst qM +rkgSA
flXeklad q y (ft ls,fjfu;e vk;u Hkhd grsgSa A) ,jkseSfVd ughagksrkgSD;ka sfd sp3 la
d fjr d kcZu ijek.kqp d {kd ksad hbl
oy ; d ksvo: ) d j nsrk gSA ,sjkseSfVd rk d k gklzgksusij izFke in vR;ar Å "ek'kks"kh izd f̀r d k in gksrk gSA flXek ca/k
,s
jkseSfVd rkiqu%rc iz kIr d j ysrkgSt c izFke in foijhr fn'kkes a(vfHkd kjd fuekZ.kd hrjQ ) gksrkgS;kfQ j prq "Q yd h;
d kcZu ijek.kqlsizksVkWu d k fu"d klu gksrk gSft ld sQ y Lo: i izfrLFkkiu mRikn curk gSA
 
lEiw.kZvfHkfØ ;kesa,sjkseSfVd oy ; ij izksVkWu (H) d sfy , by sDVªkWuLusgh(E ) d kizfrLFkkiu gksrkgS
]blfy , bl vfHkfØ ;k
d ksby sDVªkWuLusgh ,sjkseSfVd izfrLFkkiu v fHkfØ ;k d grsgSA
Step 1 : Attack of an electrophile on benzene ring forms the sigma complex
H E H E
Resonance hybrid
[  – complex]
Arenium Ion
in 1 : csUt hu oy ; ij by sDVªkWuLusgh d sv kØ e.k }kjk fl Xek l ad qy curk gSA
H E H E
vuqukn lad fjr

[  – lad qy ]
,sjsfu;e vk;u
Step 2 : Loss of a proton gives the substitution product.
in 2 : izksVkWu d sfu"d kl u }kjk izfrLFkkiu mRikn curk gSA
H E E

Nu : + Nu – H
 
7. Electrophilic substitution reaction is characterstics reaction of :

(A) Alkane (B) Alkyl halide (C) Alkene (D*) Aromatic compound
by sDVªksuLusghizfrLFkkiu vfHkfØ ;kfuEu esalsfd ld hvfHky k{kf.kd vfHkfØ ;kgS\
(A) ,Yd s u (B) ,fYd y gSy kbM (C) ,Yd hu (D*) ,jkS
es
fVd ;kS
fxd
(1) Halogenation AlCl3

+ Cl2  Electrophile is Cl

(1) gS
y kst uhd j.k AlCl3
+ Cl2  by sDVªkWuLusghClgSA

PAGE NO.- 22
8. The following reaction is :
FeBr
C 6H6  Br2   3
 C 6H5Br  HBr
(A) An electrophilic addition reaction (B) A nucleophilic substitution reaction
(C*) An electrophilic substitution reaction (D) A free radical substitution reaction
fuEu vfHkfØ ;k gS:
FeBr
C 6H6  Br2  
3
 C 6H5Br  HBr
(A) ,d by s
DVªkWuLusgh;ksXkkRed vfHkfØ ;k (B) ,d ukfHkd Lus
ghizfrLFkkiu vfHkfØ ;k
(C*) ,d by s
DVªkW
uLusghizfrLFkkiu vfHkfØ ;k (D) ,d eqDrewy d izfrLFkkiu vfHkfØ ;k
9. Electrophile in the case of chlorination of benzene in the presence of FeCI3 :

FeCI3 d h mifLFkfr es acsUt hu d sDy ksjhuhd j.k d k by sDVªkWuLusgh fuEu gS%
(A*) Cl+ (B) Cl– (C) Cl (D) FeCl3
(2) Nitration conc. HNO3  H2 SO 4

      Electrophile is NO2
(2) ukbVª
hd j.k lkUnzHNO3  H2SO4 bysDVª
kWuLusghNO2gSA
     
10. Which of the following reactions takes place when a mixture of concentrated HNO3 and H2SO4 reacts on
benzene at 350 K
(A) Sulphonation (B*) Nitration (C) Hydrogenation (D) Dehydration
t c 350 K rki ij cs
Ut hu d hvfHkfØ ;klkUnz HNO3 rFkkH2SO4 d sfeJ.kd slkFkd jkrsgS
]rksfuEu es
alsd kS
ulhvfHkfØ ;k
gks
rhgSA
(A) lYQ ku
shd j.k (B*) ukbVª
hd j.k (C) gkbMª
ks
t uhd j.k (D) fut Z
y hd j.k
conc. H SO
(3) Sulphonation 2
   
4
 Electrophile is SO3
or H2 S 2O 7
lkUnzH2SO4
(3) l YQ ks
uhd j.k     by sDVªkWuLusghSO3 gSA
; k H2S2O7
11. Which of the following reactions is not an electrophilic substitution ?
fuEu esalsd kSulhvfHkfØ ;k,d by sDVªkuLusghizfrLFkkiu vfHkfØ ;kughagS?
Cl OH

+ OH
(A) (B*)
NO2 NO2
(C) (D) + NO2
3 AlCl
(4) Friedel–crafts alkylation + R–Cl  
 Electrophile is R
3 AlCl
(4) fÝ My -Ø k¶V ,Yd y hd j.k + R–Cl  
 by sDVªkWuLusghRgSA
PAGE NO.- 23
12. Benzene reacts with CH3CI in the presence of anhydrous AlCl3 to form
(A*) Toluene (B) Chlorobenzene (C) Benzylchloride (D) Xylene
fut Zy AlCl3 d h mifLFkfr esacsUt hu d h vfHkfØ ;k CH3Cl d slkFk d jkusij fuEu esalsd kSulk ;kSfxd izkIr gksrk gS%
(A*) VkW
y wbZu (B) Dy ks
jkscs
Ut hu (C) cs
fUt y Dyks
jkbM (D) t kbyhu
anhydrous
13. C6H6 + CH3 Cl    C6H5CH3 +HCI is an example of :
AlCI 3
(A*) Friedel-Craft's reaction (B) Kolbe's synthesis
(C) Wurtz reaction (D) Grignard reaction
fut Zy
C6H6 + CH3 Cl  fuEu vfHkfØ ;kd kmnkgj.kgS%
 C6H5CH3 +HCI

A lCI 3
(A*) fÝ My&Ø k¶V vfHkfØ ;k (B) d ks
Ycsla'y s
"k.k
(C) oqVZ
t vfHkfØ ;k (D) fxz
U;kj vfHkfØ ;k
14. + CH3–CH2–Cl AlCl

 3
 product is mRikn gS:
(A) (B) (C) (D*)
y wbZl vEy
+ CH3–CH–CH3 Lewis   product is mRikn gS:
15. acid
  
Cl
CH2–CH2–CH3 CH2–CH=CH2
(A) (B*) (C) (D)
CH3
16. + CH3–C–Cl AlCl
 3
CH3
CH3
CH3–C–CH3 CH3
CH—CH CH2–CH=CH2
CH3
(A*) (B) (C) (D)
PAGE NO.- 24
Cl
17. + AlCl
 3
CH2–CH2–CH3
(A) (B) (C*) (D)
CH2–CH2–CH3
(5) Friedel–crafts acylation AlCl3

+ CH 3 COCl  Electrophile is

(5) fÝ My –Ø k¶V ,fl y hd j.k AlCl3

+ CH3COCl by sDVªkWuLusgh gSA

18. + CH3–C–Cl AlCl

 3
O
O CH3 O CH3
(A) (B) (C) (D*)

Cl
AlCl 3
19. + Ph–C–Cl   product is mRikn gS:
O
O Ph
O Ph O Ph
(A) (B) (C*) (D)

Cl
Cl
PAGE NO.- 25
20. AlCl
 3
O
(A) (B) (C) (D*)
Lecutre Sub-topic(s) Nam e Hom e Work Hom e Work NCERT Hand

No. (No. of Lectures) Sheet Pg.N out
Discussion of DPP's
L70
of Hydrocarbon
Ex.1 (S) XI 370

Th.
Ex.1 (O) XII
Discussion of DPP's
L71 Ex.2 (O) XI 397
of Hydrocarbon
Ex.2 (I) Prob.
Ex.2 (M) XII
PAGE NO.- 26
ORG./INO. CHEMISTRY

1. Course of the week as per plan : Discusion of DPPs of hydrocarbon
2. Course covered till previous week : Revision of GOC-I
3. Target of the current week : Discusion of DPPs of hydrocarbon
4. DPP Syllabus : Revision of GOC-I

ANSWER KEY
1. (A) 2. (D) 3. (B) 4. (D) 5. (D) 6.* (BC) 7.* (ACD)
8.* (BCD) 9.* (AD) 10.* (ABD) 11. 6 12. 8 13. 5 14. 5
15. (A) - (p,r) ; (B) - (p,s) ; (C) - (p,q,r) ; (D) - (p,q,r)
1. Which of the following species have all equally contributing resonating structures ? (Electronic effect(O))
fuEu esalsd kSulh Lih'kht +esalHkh leku : i lslg;ksx iznku d jusoky h vuquknh lajpuk,sagS\
(A*) (B) CH2=CH–CH=CH2 – + –

(C) N (D)
=N=N
2. The species which is stable at room temperature is : [Topic-GOC-II(O)]

fuEUk esalsd kSulh Lih'khT+k d ejsd srki ij LFkk;h gS%
(A) (B) (C) (D*)
3. Consider the following carbocation, [Electronic Effects / Carbocation/T(O))]
If we assume that all possible rearrangements are taking place by various shifts, then which of the following
rearranged carbocation cannot be formed?
fuEufyf[kr d kcZèkuk;u ij fopkj d hft ,%
PAGE NO.- 1
;fn ,sl keku fy ;kt k;s]fd fofHkUu foLFkkiuksad s}kjkmijks
Dr d kcZ/kuk;u esalHkhlEHko iqufoZU;kl (rearrangements)
d jk;sx,]rksfuEu esalsd kSulkiquZfoU;kflr (rearranged) d kcZèkuk;u ughacusxk\
(A) (B*) (C) (D)
Sol. The +ve charge of carbocation is not possible at bridge-head (B.H.) position in bicyclic systems.
Sol. f}pØ h; ;kSfxd ksa(Bicyclo compounds) d sd kcZ/kuk;u esalsrqcU/k (bridge-head) (B.H.) ij /kukos'klEHko ughagSaA
4. Which is correct for carbocation stability? [Electronic Effects / Carbocation/M(O)]

fuEu esalsd kSulk d kcZ/kuk;u d sLFkkf;Ro d k lgh Ø e gS\
+
(A) < CH2 (B) <
(C) < (D*) <
5. The correct order of electron density in aromatic ring of following compounds is : [Topic-GOC-II(O)]
fuEufy f[kr ;kSfxd kasesacsUt hu oy ; ij by sDVªkWu ?kuRo d k lgh Ø e gksxk %
I II III IV
(A) IV > III > II > I (B) I > II > III > IV (C) IV > II > I > III (D*) IV > II > III > I
Sol. On the basis of electronic effect. ¼by s
DVªkWfud izHkko d svk/kkj ij½
6.* Which of the following carbocation would not likely rearrange to a more stable carbocation ?
fuEUkesalsd kSulkvf/kd LFkk;hd kcZ/kuk;u esaiqufoZU;kfLkr ughagksxk\
(A) (B*) (C*) (D)
7.* Which of the following carbocations is/are expected to undergo rearrangement. (Carbocation(O))
fuEu esalsd kSulk@d kSulsd kcZ/kuk;u esaiquZfoU;kl lEHko gS\
H CH2 – CH3
| CH3 |
CH2
CH3–CH2–C–C HO – C – C – CH3
(A*) (B) CH3 (C*) (D*)
| | |
O
CH2–CH2–CH3 CH3 CH3
CH2 CH3
Sol. (A)
(B) No rearrangement iq
uZ
foU;kl ughagksrkgS
A
PAGE NO.- 2
(C) O
O Complete Octet
v"Vd iw
.kZ
Et CH3
Et | |
| HO – C – C – CH3
HO – C – C – CH3 |
(D) | | CH3
CH3 CH3 Complete Octet
v"Vd iw.kZ
8.* In which of the following first carbocation is more stable than second one ?
fuEu esalsd kSulsfod Yiksaesaigy k d kcZ/kuk;u nwl jslsvf/kd LFkk;h gS\ [General Organic Chemistry]
(A) , (B*) ,
(C*) , (D*) ,
Sol. (B) has extended conjugation. ¼foLrkfjr la;qXeu gSA½
(C) has +M effect of –OCH3. (–OCH3 lew

g d k +M izHkko gSA½
(D) after delocalisation gets +M effect of –OMe.
¼foLFkkuhd j.k d jd s–OMe d k +M izHkko fey t krk gSA½
9.* Observe each pair of cations. In which case (s) first is more stable than the second :
fuEu /kuk;u d s;qXeksad k izs{k.k d hft ,A buesalsfd l ;qXe esaigy k /kuk;u nwl jsd h vis{kk vf/kd LFkk;h gS:
(A*) , (B) ,
(C) , (D*) ,
PAGE NO.- 3
Sol. In (W) since C–H bond is weaker than C–D bond so hyperconjugation stability is more in I.
In (X) only +I effect is present which is more for –C(CD3).
In (Y) only +I which is more for –CD3
In (Z) –I effect of –CCl3 group will make II cation highly unstable.
(W) es aC–H ca/kC–D ca/k lsnqcZy gksrk gS]blfy , vfrla;qXeu LFkkf;Ro I esavf/kd gksxkA
(X) es
ad soy +I izHkko mifLFkr gS]blfy , –C(CD3) d kizHkko vf/kd gksxkA
(Y) es
ad soy +I izHkko mifLFkr gS]blfy , –CD3 d kizHkko vf/kd gksxkA
(Z) es
a–CCl3 d k–I izHkko gS]blfy , II /kuk;u vR;f/kd vLFkkbZgksxkA
10.* Which of the given following stability order is correct. [Ref. RGP sir]
fuEu esalsd kSulk LFkkf;Ro d k lgh Ø e gSA
O < O
(A*)
H 2C
(B*) <
O
(C) > H2N CH2
CH2 > CH2

(D*) F
Cl
11. How many carbocations given below are more stable than sec. butyl carbocation
t-butyl carbocation Benzyl carbocation Allyl carbocation Cyclopropenyl cation
Tropylium cation n- butyl carbocation cyclopropylmethyl carbocation
fuEu esalsfd rusd kcZ/kuk;u f}rh;d C;wfVy d kcZ/kuk;u lsvf/kd LFkk;hgSA
t-C;wfVy d kcZ/kuk;u csfUt y d kcZ/kuk;u ,fyy d kcZ/kuk;u lkbDyksçks
is
fuy d kcZ
/kuk;u
Vªksikbfy;e d kcZ/kuk;u n- C;wfVy d kcZ/kuk;u lkbDyks
çks
ikbyes fFky d kcZ
/kuk;u
Ans. 6
Sol.
12. The total number of hyperconjugable hydrogen atoms in the given two species are : [Topic-GOC-II(O)]
uhpsnh xbZnksuksaLih’kht ksaesavfrla;qXeh gkbMªkst u ijek.kqv ksad h d qy la[;k fuEu gksxh %
(i) (ii)
Ans. 8
PAGE NO.- 4
13. How many groups (each attached with benzene ring) show + M (Mesomeric) effect? (Electronic effect(O))
fuEu esalsfd ruslewg (t kscsUt hu oy ; lst qM +sgSa) + M (esl ksesfjd ) izHkko n’’'kkZrsgSa\
O O
|| ||
N(CH3)2 SH C — OCH3 O — C — CH3
Ans. 5
Sol.
have + M group.
;slHkh + M lewg j[krsgSaA
14. How many species out of the following are aromatic ? [Topic-GOC-II(O)]
fuEu esalsfd ruh Lih’'kht ,sjksesfVd gS\
Ans. 5
Sol. Aromatic species are
fuEu ,sjksesfVd Lih’'kht gS%
PAGE NO.- 5
15. Match the characteristics of Column-II with the compounds given in Column-I.
Column-I Column-II (Electronic effects(O))
(A) (p) Resonance possible
(B) (q) Rearrangement possible
(C) (r) Hyperconjugation possible
(D) (s) Steric inhibition of resonance possible (SIR)
d kWy e-II d sy {k.kksad ksd kWy e-I d s;kSfxd kslsfey ku d hft ,A

d kWy e-I d kWy e-II
(A) (p) vuq

ukn laHko
(B) (q) iq
ufoZ
U;kl la
Hko [Rearrangement]
(C) (r) vfrla

;qXeu laHko
(D) (s) vuq

ukn d kf=kfoe ckèkk (SIR) lEHko
Sol. (A) - (p,r) ; (B) - (p,s) ; (C) - (p,q,r) ; (D) - (p,q,r)
Lecutre Sub-topic(s) Nam e Hom e Work Hom e Work NCERT

Handout
No. (No. of Lectures) Sheet Pg.N
379
Ex.1 (S) XI to
Th.
388
L72 Revision of GOC Ex.1 (O) XII
Ex.2 (O) XI 397
Ex.2 (I) Prob.
Ex.2 (M) XII
PAGE NO.- 6
ORG./INO. CHEMISTRY

1. Course of the week as per plan : Introduction of s-block elements, Physical Properties of s-block elements,
Chemical Properties of s-block elements.
2. Course covered till previous week : Revision of GOC-I
3. Target of the current week : Introduction of s-block elements, Physical Properties of s-block elements,
Chemical Properties of s-block elements.
4. DPP Syllabus : Introduction of s-block elements, Physical Properties of s-block elements, Chemical Properties
of s-block elements.
ANSWER KEY
1. (B) 2. (D) 3. (D) 4. (D) 5. (A) 6. (A) 7. (C)
8. (B) 9. (C) 10. (C) 11. (C) 12. (C) 13. (D) 14. (B)
15. (D) 16. (D) 17. (B) 18. (B) 19. (A)
1. Which of the following gives propyne on hydrolysis ? [s-block Elements]

fuEu esalsd kSu]t y vi?kVu }kjk izksikbu cukrk gS\
(A) Al4C3 (B*) Mg2C3 (C) B4C (D) La4C3
2. Which of the following compounds on thermal decomposition yields a basic as well as an acidic oxide ?
fuEu esalsfd l ;kSfxd d srkih; vi?kV~u ij ,d {kkjh; vkWDlkbM d slkFk&lkFk,d vEy h; vkWDlkbM HkhizkIr gks
rkgS\
[s-block Elements]
(A) KClO3 (B) NaNO3 (C) K2CO3 (D*) MgCO3
Hint : MgCO3  MgO + CO2

(Basic) (Acidic)
3. Which of the following statements is incorrrect ? [s-block Elements]
(A) The superoxide ion (i.e. O2–) is stable only in presence of larger cations such as K+, Rb+, Cs+.
(B) Alkali metals are normally kept in kerosene oil.
(C) All the alkali metal hydrides are ionic solids with high melting points.
(D*) The concentrated solution of alkali metals in liquid ammonia is paramagnetic in nature.
fuEu esalsd kSulk d Fku vlR; gS%
(A) lqijvkWDlkbM vk;u (O2–), cM+s/kuk;uksat Sl sK+, Rb+, Cs+ d slkFkgh LFkk;hgksrk gSA
(B) {kkjh; /kkrq
v ksad kslkekU;r%d Sjksl hu esaj[kkt krkgSA
(C) lHkh{kkjh; /kkrq v ksad sgkbMªkbM]vk;fud Bksl gksrsgSrFkkmPp xy ukad j[krsgSaA
(D*) {kkjh; /kkrq
v ksad k nzo veksfu;kesalkUnzfoy ;u]çd f̀r esavuqp qEcd h; gksrkgSA
Sol. (A) Bigger anion is stabilised by bigger cation through lattice energy effect.
(B) Because of their high reactivity towards air and water.
(C) True Statement
PAGE NO.- 1
(D) In concentrated solution, unpaired electrons with opposite spins paired up – forming the solution diamagnetic.
(A) cM+ s_ .kk;u t ky d Å t kZizHkko lscM+s/kuk;u }kjk LFkk;hd r̀ jgrk gSA
(B) D;ks afd bud h ok;qo t y d sizfr mPpfØ ;k'khy rk gksrh gSA
(C) lR; d Fku
(D) lkfUnz r foy ;u esafopfjr pØ .k ;qDr v;qfXer by sDVªkWu ;qfXer gksd j fopy u d ksizfrpqEcd h; cukrsgSA
4. Identify the correct statement : [s-block Elements]

(A) Sodium metal can be prepared by the electrolysis of an aqueous solution of NaCl.
(B) Sodium metal can be kept under ethyl alcohol.
(C) Sodium metal is insoluble in liquid NH3 at low temperature.
(D*) Elemental sodium is easily oxidised.
lgh d Fku d h igpku d hft , %
(A) NaCl d st y h; foy ;u d sfo|q r vi?kV~u d s}kjk lksfM;e /kkrqcuk;h t k ld rh gSA
(B) lks
fM;e /kkrqd ks,fFky ,Yd ksgkWy esaj[kkt k ld rkgSA
(C) fuEu rkieku ij lks fM;e /kkrq]nzo NH3 esavfoy s; gSA
(D*) rkfRod lksfM;e]vklkuhlsvkWDlhd r̀ gkst krkgSA
5. The pair of compounds which cannot exist together in solution is : [s-block Elements][JEE-1986, 1 M]
(A*) NaHCO3 and NaOH (B) Na2CO3 and NaHCO3
(C) Na2CO3 and NaOH (D) NaHCO3 and NaCI
;kSfxd ksd k d kSulk ;qXe]foy ;u esa,d lkFk ughajg ld rk gS% [JEE-1986, 1 M]
(A*) NaHCO3 o NaOH (B) Na2CO3 o NaHCO3
(C) Na2CO3 o NaOH (D) NaHCO3 o NaCI
Sol. Since NaHCO3 is an acid salt of H2CO3. it reacts with NaOH to form Na2CO3 and H2O.
NaHCO3 + NaOH  Na2CO3 + H2O.
gy - pwafd NaHCO3, H2CO3 d k,d vEy y o.kgSA ;g NaOH d slkFkvfHkfØ ;kd j Na2CO3 o H2O cukrkgSA
NaHCO3+ NaOH  Na2CO3 + H2O.
6. Calcium is obtained by : [s-block Elements] [JEE-1980]

(A*) electrolysis of molten CaCl2 (B) electrolysis of solution of CaCl2 in water
(C) chemical reduction of CaCl2 (D) roasting of lime stone.
d SfY'k;e fuEu d s}kjk çkIr gksrk gS% [JEE-1980]
(A*) xfy r CaCl2 d sfo?kq
rvi?kVu }kjk (B) t y esaCaCl2 foy ;u d sfo?kqrvi?kVu }kjk
(C) CaCl2 d sjklk;fud vip;u }kjk (D) y kbe LVks
u d sHkt Zu }kjk
Sol. Ca is obtained by electrolysis of molten mixture of CaCl2 mixed with CaF2.
gy - Ca, CaF2 d slkFk fefJr CaCl2 d sxfy r feJ.kd sfo?kqrvi?kVu }kjk çkIr gksrk gSA
7. Which of the following statements is true for all the alkali metals ? [s-block Elements]
(A) Their nitrates decompose on heating to give the corresponding nitrites and oxygen.
(B) Their chlorides are deliquescent and crystallise as hydrates.
(C*) They react with water to form hydroxide and hydrogen.
(D) They readily react with halogens to form ionic halides, M+X–.
lHkh {kkjh; /kkrqv ksad sfy , fuEu esalsd kSulk d Fku lR; gS\
(A) bud sukbVª sV]xeZd jusij fo?kfVr gksd j lacaf/kr ukbVªkbV rFkk vkWDlht u nsrsgSA
(B) bud sDy ks jkbM]izLosn~d ¼deliquescent½ gksrsgaSrFkk t y ;ksft r : i esafØ LVy hd r̀ gksrsgSaA
(C*) ;st y d slkFkfØ ;kd jd sgkbMª ksDlkbM rFkkgkbMªkst u cukrsgaSA
(D) ;sgS y kst u d slkFkrqjUr fØ ;kd jd svk;fud gSy kbM , M+X– cukrsgaSA
Sol. (A) 4 LiNO3  2Li2O + 4NO2 + O2
2NaNO3  2NaNO2 + O2 (similar decomposition with the nitrates of K, Rb and Cs)
(B) Only LiCl is deliquescent and crystallises as a hydrate LiCl.2H2O
(C) 2M + 2H2O  2M+ + 2OH– + H2 (M = an alkali metal)
(D) Halides of Li are covalent in nature.
PAGE NO.- 2
(A) 4 LiNO3  2Li2O + 4NO2 + O2
2NaNO3  2NaNO2 + O2 (ukbVª kbV K, Rb rFkk Cs d slkFklkeu fo?kVu)
(B) d os
y LiCl izLos| ; gSrFkk gkbVªsV LiCl.2H2O d s: i esafØ LVy hd r̀ jgrk gSA
(C) 2M + 2H2O  2M+ + 2OH– + H2 (M = ,d {kkj /kkrq )
(D) Li d sgS
y kbM lgla;kst hizd f̀r d sgksrsgSA
8. Which of the following reactions of potassium superoxide supply oxygen gas in the breathing equipments
used in space and submarines ? [s-block Elements]
(1) reaction of superoxide with nitrogen in the exhaled air
(2) reaction of superoxide with moisture in the exhaled air
(3) reaction of superoxide with carbon dioxide in the exhaled air
(A) (1), (2) and (3) (B*) (2) and (3) only (C) (2) only (D) (1) and (2) only
varfj{krFkkiaM qfCc;ksaesafuEu esalsiksVsf'k;e lqij vkWDlkbM d hd kSulhvfHkfØ ;k]'olu ;a=kesavkWDlht u xSl d sçokg
d sfy , iz;qDr d h t krh gS\ [s-block Elements]
(1) fu"d kflr ok;qes aukbVªkst u d hlqij vkWDlkbM d slkFkvfHkfØ ;kA
(2) fu"d kflr ok;qes auehd hlqij vkWDlkbM d slkFkvfHkfØ ;kA
(3) fu"d kflr ok;qes ad kcZuMkbZv kWDlkbM d hlqij vkWDlkbM d slkFkvfHkfØ ;kA
(A) (1), (2) rFkk(3) (B*) d s
oy (2) rFkk(3) (C) d s
oy (2) (D) d s
oy (1) rFkk(2)
Sol. (2) KO2 + 2H2O  KOH + H2O2 + 1/2O2
(3) 4KO2 + 2CO2  2K2CO3 + 3O2
9. STATEMENT-1 : Lithium is the most powerful reducing agent and sodium is the least powerful reducing
agent amongst the alkali metals in aqueous solutions. [s-block Elements]
STATEMENT-2 : Lithium has the highest hydration enthalpy and the sodium the least value.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
(C*) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True
d Fku-1 : t yh; foy;u es ]{kkjh; /kkrq
a v ks
aes
ayhfFk;e lclsçcy vipk;d d kjd gSrFkklks fM;e lclsnq cZ
y vipk;d gS
A
d Fku-2 : y hfFk;e mPpre foy k;d u ,UFkSYih j[krk gSrFkk lksfM;e]lclsd eA
(A) d Fku& 1 lR; gS ]d Fku& 2 lR; gS; d Fku& 2, d Fku& 1 d k lgh Li"Vhd j.k gSA
(B) d Fku& 1 lR; gS ]d Fku& 2 lR; gS; d Fku& 2, d Fku& 1 d k lgh Li"Vhd j.k ughagSA
(C*) d Fku& 1 lR; gS ]d Fku& 2 vlR; gSA
(D) d Fku& 1 vlR; gS ]d Fku& 2 lR; gSA
Sol. (i) E Li /Li = –3.04 ; Na+ / Na = – 2.71 which is least among the alkali metals.
 +
(ii) Hydration enthalpy / KJ mol–1

Li = – 506 ; Na = – 406 ; Cs has the least Hhyd = – 276
(i) E Li+/Li = –3.04 ; Na+ / Na = – 2.71 t ks{kkjh; /kkrq
v ksaesalclsd e gSA
(ii) foy k;d u Å t kZ/ KJ mol –1
Li = – 506 ; Na = – 406 ; Cs , Hfoy k;d u = – 276 d k eku d e j[krk gS A
10. Which of the following is correct order regarding properties mentioned. (Electronic effect(O))

(A) CH3–CH2+ > CH3 – CH– CH3 (Stability order)
–
(B) CH3– CH2 < CH3 – CH– CH3 (Stability order)
(C*) HCOOH > CH3CH2COOH (Acidic strength)
(D) CH3–CH2–F > CH3–CH2–NO2 (Dipole moment)
uhpsn'kkZ;sx;sxq.kksad slUnHkZesad kSulk fod Yi lgh Ø e iznf'kZr d jrk gS\

(A) CH3–CH2+ > CH3 – CH– CH3 (LFkkf;Ro d kØ e)
–
(B) CH3– CH2 < CH3 – CH– CH3 (LFkkf;Ro d kØ e)
(C*) HCOOH > CH3CH2COOH (vEy h;rkd kØ e)
(D) CH3–CH2–F > CH3–CH2–NO2 (f}/kq
o vk?kw
z .kZd kØ e)
PAGE NO.- 3
11. Which of the following statements is not true about the dilute solutions of alkali metals in liquid ammonia ?
(A) They are deep blue coloured solutions. [s-block Elements]
(B) They are highly conducting in nature.
(C*) They are diamagnetic in nature.
(D) Ammoniated cation and solvated electron are formed in the solution.
nzo veksfu;k esa{kkjh; /kkrqv ksad sruqfoy ;u d sfy , fuEu esalsd kSulk d Fku lR; ughagS\
(A) ;g xgjsuhy sja x d k foy ;u gSA
(B) ;g iz d f̀r esavR;f/kd pky d gksrk gSA
(C*) ;g iz d f̀r esaizfrpqEcd h; gksrkgSA
(D) foy ;u es aveksfud r̀ /kuk;u rFkk foy ;hd r̀ by sDVªkWu curk gSA
Sol. M + (x + y)NH3  [M(NH3)x]+ + [e(NH3)y]–
It is paramagnetic due to the presence of the unpaired electrons
v;qfXer by sDVªkWu d h mifLFkfr d sd kj.k ;g izfrpqEcd h; gksrk gSA
12. Which of the following has the highest solubility in water ? [s-block Elements]
fuEu esalsfd ld h]t y esafoy s;rk lokZfèkd gksrh gS\
(A) LiOH (B) KOH (C*) CsOH (D) RbOH
13. Which is correct order of ionic mobility in aqueous medium – [E] (SBC (I))
(A) Li(aq )  Na(aq )  Rb(aq ) (B) Al(3aq

)  Mg(2aq

)  Na(aq )
(C) Li(aq )  Na(aq )  K (aq ) (D*) Both (A) & (B)

Tky h; ek/;e esvk;fud xfr'khy rk d k lgh Ø e gS%
(A) Li(aq )  Na(aq )  Rb(aq ) (B) Al(3aq
 2 
)  Mg( aq )  Na( aq )
(C) Li(aq )  Na(aq )  K (aq ) (D*) (A) o (B) nks

uksa
Sol. Smaller the ion, higher the hydration, lower the mobility.
vk;u ft ruk NksVk gksrk gS]mruk gh t y &vi?kVu mPp gksrk gS]xfr'khy rk mruh gh d e gksrh gSA
14. The following compounds have been arranged in order of their increasing thermal stabilities. Identify the
correct order. K2CO3 (), MgCO3 (), CaCO3 (), BeCO3(V) [s-block Elements]
fuEufy f[kr ;kSfxd ksad ksmud srkih; LFkkf;Ro d sc<+rsgq, Ø e esaO;ofLFkr fd ;k x;k gSA lgh Ø e d ksigpkfu,A
K2CO3 (), MgCO3 (), CaCO3 (), BeCO3(V)
(A)  <  <  < V (B*) V <  <  <  (C) V <  <  <  (D)  < V <  < .
Sol. As the size of cation decreases, the extent of polarisation increases so covalent character  and stability 
gy & t Sl s& t Sl s/kuk;u d kvkd kj ?kVrk gS]/kzqo.k d sc<+uslslgla;kst h y {k.k c<+rsgSrFkkLFkkf;Ro ?kVrk gSA
15. Which of the following statement is incorrect about the alkali metals ? [s-block Elements]
(A) All alkali-metal salts impart a characteristic colour to the Bunsen flame.
(B) The correct order of increasing thermal stability of the carbonates of alkali metals is Li2CO3 < Na2CO3 <
K2CO3 < Rb2CO3 < Cs2CO3 .
(C) Among the alkali metals, cesium is the most reactive.
(D*) All are incorrect.
{kkjh; /kkrqv ksad sfy , fuEu esslsd kSulk d Fku vlR; gS\
(A) lHkh {kkjh; /kkrq v ksad sy o.k]cqUlsu Toky k d ks,d y kf{.kd jax iznku d jrsgaSA
(B) {kkjh; /kkrqv kasd sd kckuZsVs d srkih; LFkkf;Ro d klghc<+rkgq v kØ e Li2CO3 < Na2CO3 < K2CO3 < Rb2CO3 < Cs2CO3 gS
A
(C) lHkh{kkjh; /kkrq v ksaesalslhft +;e lokZfèkd fØ ;k'khy gSA
(D*) lHkhxy r gS aA
PAGE NO.- 4
ChemINFO-6.1 s-BLOCK ELEMENT
Daily Self-Study Dosage for mastering Chemistry Calcium oxide & Hydroxide
Reactions Charts (Quick Revision) :
Cl2 CaOCl2
(Bleaching powder)
Na2CO3 NaOH
(Castic-soda)
+ H2O Ca(OH)2
(slaked lime) 1 part slaked lime + 3 or 4 parts silica + water
SiO2
(mortar)
used as a building material
CaO
Quicklime Absorbs CO2 gas
+ Slaking with NaOH + Ca(OH)2

NaOH solution (Soda lime)
CaCN2 + C
+ Coke N2 H2O
CaC2 (Nitrolium) NH3
Heated in electric use as a fertilizer
0
furnace at 2000 C
H2O
C2H2
(Acetylene)
16. Which hydrocarbon obtained by the hydrolysis of calcium carbide?

(A) Methane (B) Ethane (C) Ethene (D*) Ethyne
17. The formula of slaked lime is :

(A) CaO (B*) Ca(OH)2 (C) Ca2O2 (D) None of these
18. What will obtained when slaked lime react with Na2CO3 ?
(A) Na2O2 (B*) NaOH (C) NaNH2 (D) NaNO3
19. Which product will obtain when CaC2 react with N2 ?

(A*) CaCN2 + C (B) Ca(CN)2 (C) Ca(OH)2 (D) CaO
PAGE NO.- 5
ChemINFO-5.1 s-BLOCK ELEMENT
Daily Self-Study Dosage for mastering Chemistry Calcium oxide & Hydroxide
v fHkfØ ;k pkVZ ¼'kh?kz iquZjkoy ksd u½ :
Cl2 CaOCl2
(fojatd pw.kZ)
Na2CO3 NaOH
(dkWfLVd&lksMk)
+ HO
2 Ca(OH)2
(cw>k pwuk) 1 Hkkx cw>k pwuk + 3 ;k 4 Hkkx flfydk + ty
SiO2
(eksVkZV)
bldk mi;ksx Hkou fuekZ.k djus okys
inkFkksZ esa fd;k tkrk gSA
CaO
(fcuk cw>k CO2 xSl dk vo’kks"k.k
gqvk pwuk)
NaOH foy;u NaOH + Ca(OH)2

ds lkFk cw>kuk (lksMkykbZe)
CaCN 2+ C
+ dksd N2 HO
2
CaC2 (ukbZVªksfy;e) NH3
2000ºC rki ij oS|qr moZjd dh rjg iz;qDRk
HkV~Vh esa xeZ djuk
HO
2
C2H2
¼,sflfVyhu½
16. d SfY'k;e d kckZbM d st y vi?kVu ij fuEu esalsd kSulkgkbMªksd kcZu IkzkIr gksrkgS?
(A) eS Fksu (B) ,s
Fks
u (C) ,s
Fkhu (D*) ,s
FkkbZ
u
17. cw> sgq,spwusd k lw=k gS:

(A) CaO (B*) Ca(OH)2 (C) Ca2O2 (D) bues
alsd ksbZugha
18. fuEu esalsd kSulk mRikn izkIr gksrk gSt c cw> sgq,spwusd h vfHkfØ ;k Na2CO3 d slkFk d jkrsgS?
(A) Na2O2 (B*) NaOH (C) NaNH2 (D) NaNO3
19. fuEu esalsd kSulk mRikn izkIr gksrkgSt c CaC2 d hvfHkfØ ;kN2 d slkFk d jkrsgS?
(A*) CaCN2 + C (B) Ca(CN)2 (C) Ca(OH)2 (D) CaO
PAGE NO.- 6
Lecutre Sub-topic(s) Name Home Work Home Work NCERT
Handout
291 to
292
Ex.1 (S) A-1 to A-4 XI
Th.
298
Introduction of to 299
L73
s-block elements
Ex.1 (O) A-1 to A-7 XII
Ex.2 (O) 1 XI 305
Ex.2 (I) Prob.
Ex.2 (M) 1 XII
292 to 293
Ex.1 (S) XI
Th.
Physical Properties 299 to 300
of Ex.1 (O) XII
L74
s-block elements 302, 305
Ex.2 (O) XI
306
Prob.
Ex.2 (I)
Ex.2 (M) XII
293 to 296
Ex.1 (S) XI
Th.
Chemical Properties 300 to 302
of Ex.1 (O) XII
L75
s-block elements 305, 294
Ex.2 (O) XI
295
Prob.
Ex.2 (I)
Ex.2 (M) XII
PAGE NO.- 7
ORG./INO. CHEMISTRY

1. Course of the week as per plan : Important compounds of s-block elements, Discussion.
2. Course covered till previous week : Introduction of s-block elements, Physical Properties of s-block
elements, Chemical Properties of s-block elements.
3. Target of the current week : Important compounds of s-block elements, Discussion.
4. DPP Syllabus : Important compounds of s-block elements, Discussion.
Comprehension ('–1' negative marking) Q.10 to Q.12 (3 marks, 2 min.) [09, 06]
Integer type Questions ('–1' negative marking) Q.13 (4 marks 3 min.) [04, 03]
ANSWER KEY
1. (A) 2. (C) 3. (C) 4. (C) 5. (D) 6. (D) 7. (ABCD)
8. (ABCD) 9. (AD) 10. (A) 11. (A) 12. (A)
13. (i) Na2S + 4Na2O2  Na2SO4 + 4Na2O. (ii) MnSO4+ 2Na2O2  Na2MnO4+ Na2SO4
(iii) 2NaOH + 2NO2  NaNO2 + NaNO3 + H2O (iv) 6NaOH+3Br2  5NaBr + NaBrO3 + 3H2O
(v) 6NaOH + 4S  2Na2S + Na2S2O3 + 3H2O. (vi) 4NaOH + 2F2  4NaF + O2 + 2H2O.
(vii) PbO + 2NaOH  Na2PbO2 + H2O
(viii) Form insoluble hydroxides CrCl3 + 3NaOH  Cr(OH)3  (Green) + 3NaCl.
(ix) HgCl2 + 2NaOH  Hg(OH)2  + 2NaCl ; Hg(OH)2  HgO  (yellow or brown) + H2O.
150  200 º C
(x) NaOH + CO    HCOONa.
5 10 atm
14. (A – p) ; (B – q, s, t) ; (C – t) ; (D – q, r) 15. (C) 16. (C) 17. (B) 18. (C)

19. (D)
1. Which of the following statements are true about the alkali metals ? [s-block Elements]
(1) All alkali-metal salts impart a characteristic colour to the Bunsen flame.
(2) The correct order of increasing thermal stability of the carbonates of alkali metals is Li2CO3 < Na2CO3 <
K2CO3 < Rb2CO3 < Cs2CO3 .
(3) Among the alkali metals, cesium is the most reactive.
(4) The reducing character of the alkali metal hydrides follow the order : LiH > NaH > KH > RbH > CsH.
(A*) (1), (2) and (3) (B) (1), (3) and (4) (C) (2), (3) and (4) (D) (1), (2), (3) and (4)
{kkjh; /kkrqv ksad sfy , fuEu esslsd kSulsd Fku lR; gS\
(1) lHkh {kkjh; /kkrq v ksad sy o.k]cqUlsu Toky k d ks,d y kf{.kd jax iznku d jrsgaSA
(2) {kkjh; /kkrqv kasd sd kckuZsVs d srkih; LFkkf;Ro d klghc<+
rkgqv kØ e Li2CO3 < Na2CO3 < K2CO3 < Rb2CO3 < Cs2CO3 gS
A
(3) lHkh{kkjh; /kkrq v ks
aesalslhft +;e lokZfèkd fØ ;k'khy gSA
(4) {kkjh; /kkrqgkbMª kbM d svipk;d xq.k d k Ø e LiH > NaH > KH > RbH > CsH gSA
PAGE NO.- 1
(A*) (1), (2) rFkk(3) (B) (1), (3) rFkk(4) (C) (2), (3) rFkk(4) (D) (1), (2), (3) rFkk(4)
Hint : (4) Reducing nature increases down the group as their stability decreases down the group
CsH > RbH > KH > NaH > LiH
(4) oxZes auhpst kusij vipk;d izd f̀r c<+rh gSD;ksafd oxZesauhpst kusij bud k LFkkf;Ro ?kVrk gSA
CsH > RbH > KH > NaH > LiH
2. HCl is added to following oxides. Which one would give H2O2? [s-block Elements] [JEE-1980]
(A) MnO2 (B) PbO2 (C*) BaO2.8H2O (D) NO2
HCl d ksfuEu es
alsd kSulsvkWDlkbM esafey kusij H2O2 izkIr gksrk gS? [JEE-1980]
(A) MnO2 (B) PbO2 (C*) BaO2.8H2O (D) NO2
Sol. BaO2.8H2O + 2HCl  BaCl2 + H2O2 + 8H2O
3. S1 : Plaster of paris is a hemihydrate of calcium sulphate obtained by heating the gypsum above 393 K.
S2 : Sodium carbonate is used in water softening.
S3 : The order of mobilities of the alkali metal ions in aqueous solutions is Li+ > Na+ > K+ > Rb+ > Cs+.
S1 : ft Ile d ks393 K d sÅ ij xeZd jusij d SfYl;e lYQ sV d kgsehgkbMªsM izkIr gksrkgS]mlsIy kLVj vkWQ isfjl d grs
ga
AS
S2 : lks
fM;e d kcksZusV d k mi;ksx]t y d kseǹwcukusesafd ;k t krk gSA
S3 : t y h; foy ;u es a{kkjh; /kkrqvk;u d hxfr'khy rkd kØ e Li+ > Na+ > K+ > Rb+ > Cs+ gSA [s-block Elements]
(A) T T F (B) T T T (C*) F T F (D) F F F
393K
Sol. S1 : (2 CaSO4.2H2O)   2 (CaSO4). H2O + 3H2O ; above 393 K dead burnt plaster is obtained.
S2 : Ca2+ + Na2CO3  CaCO3 + 2Na+

S3 : Li+ < Na+ < K+ < Kb+ < Cs+
Bigger hydrated ion moves slower in aqueous solution.
393K
S1 : (2 CaSO4.2H2O)   2 (CaSO4). H2O + 3H2O ; 393 K d sÅ ij er̀ t fy r Iy kLVj izkIr gksrk gSA
S2 : Ca2+ + Na2CO3  CaCO3 + 2Na+
S3 : Li+ < Na+ < K+ < Kb+ < Cs+
t y h; foy ;u esacM+k t y k;ksft r vk;u /khjslsxfr d jrk gSA
4. STATEMENT-1 : Lithium is the most powerful reducing agent and sodium is the least powerful reducing
agent amongst the alkali metals in aqueous solutions. [s-block Elements]
STATEMENT-2 : Lithium has the highest hydration enthalpy and the sodium the least value.
d Fku-1 : t y h; foy ;u esa]{kkjh; /kkrqv ksaesay hfFk;e lclsçcy vipk;d d kjd gSrFkklksfM;e lclsnqcZy vipk;d
gS
A
d Fku-2 : y hfFk;e mPpre foy k;d u ,UFkSYih j[krk gSrFkk lksfM;e]lclsd eA
(A) d Fku& 1 lR; gS ]d Fku& 2 lR; gS; d Fku& 2, d Fku& 1 d k lgh Li"Vhd j.k gSA
(B) d Fku& 1 lR; gS ]d Fku& 2 lR; gS; d Fku& 2, d Fku& 1 d k lgh Li"Vhd j.k ughagSA
(C*) d Fku& 1 lR; gS ]d Fku& 2 vlR; gSA
(D) d Fku& 1 vlR; gS ]d Fku& 2 lR; gSA
Sol. (i) E Li+/Li = –3.04 ; Na+ / Na = – 2.71 which is least among the alkali metals.
(ii) Hydration enthalpy / KJ mol–1
Li = – 506 ; Na = – 406 ; Cs has the least Hhyd = – 276
(i) E Li+/Li = –3.04 ; Na+ / Na = – 2.71 t ks{kkjh; /kkrq
v ksaesalclsd e gSA
(ii) foy k;d u Å t kZ/ KJ mol –1
Li = – 506 ; Na = – 406 ; Cs , Hfoy k;d u = – 276 d k eku d e j[krk gS A
PAGE NO.- 2
5. Which of the following compounds on thermal decomposition yields a basic as well as an acidic oxide ?
fuEu esalsfd l ;kSfxd d srkih; vi?kV~u ij ,d {kkjh; vkWDlkbM d slkFk&lkFk,d vEy h; vkWDlkbM HkhizkIr gks
rkgS\
(SBC-CPM (I))
(A) KClO3 (B) KNO3 (C) Na2CO3 (D*) CaCO3

Hint : CaCO3  CaO + CO2
(Basic) (Acidic)
({kkjh;) (vEy h;)
6. An inorganic compound (X) which produces brick red coloration as flame when (X) dissolves in water
produces alkaline solution and a combustible gas (Y). (X) and (Y) are respectively.
,d d kcZfud ;kSfxd (X) Toky kesabZV t S
l ky ky jax mRiUu d jrkgS
A t c (X) d kst y esafoys; fd ;kt krkgSrksnks{kkjh;
foy ;u rFkk ,d ngu’khy xSl (Y) curh gSA (X) rFkk(Y) Ø e'k%gSA [SBC-CAM]
(Made by SCS SIR ON Nov.2014) (SBC-CAM-(I))
(A) CaO, O2 (B) Ca3N2, NH3 (C) CaCO3, CO2 (D*) CaH2, H2
Sol. CaH2 + H2O  Ca(OH)2 + H2
7. Select correct matching. [SBC-CAEM]

(A*) Hydrolith = CaH2 (B*) Bleaching powder = CaCl2. Ca(OCl)2
1
(C*) Epsom salt = MgSO4. 7H2O (D*) Plaster of Paris = CaSO4. HO
2 2
lgh fey ku pqfu, &
(A*) gkbMª
ks
fyFk= CaH2 (B*) fojt a
d pw
.kZ= CaCl2. Ca(OCl)2
1
(C*) ,ile y o.k = MgSO4. 7H2O (D*) Iy kLVj vkW
Q isfjl = CaSO4. H2O
2
8. Which of the following is/are correct? [SBC-PP]

(A*) Ionization energy = Ca > K (B*) Melting point = Ca > K
(C*) Stability = MgCO3 < CaCO3 (D*) Hydration energy = Ca2+ > K+
fuEu esalsd kSulk@d kSulslgh gS@ gSa\
(A*) vk;uu Å t kZ= Ca > K (B*) xy uka
d = Ca > K
(C*) LFkkf;Ro = MgCO3 < CaCO3 (D*) t y ;ks
t u Å t kZ= Ca2+ > K+
9. Which s-block element shows crimson red coloration in flame ? [SBC-PP]

(A*) Lithium salt (B) Rubidium salt (C) Barium salt (D*) Strontium salt
fuEu esalsd kSulk s-Cy kWd rRo Toky k esafØ elu y ky jax n'kkZrk gS\
(A*) fy fFk;e y o.k (B) : fcfM;e y o.k (C) cs
fj;e y o.k (D*) LVª
kWfU'k;e yo.k
Comprehension
Alkali metals burns vigorously in oxygen forming various oxides like monoxide, peroxide and superoxide.
The basic character of various oxides of alkali metals increases with increasing metallic character .The
increasing stability of the peroxide or super oxide, as the size of the metal ion increases, is due to stabilisation
of larger anions by larger cation through lattice energy effects.
v uqPN sn
{kkj /kkrq,Wok;qes arhoz: i lst y d j fofHkUu izd kj d svkDlkWbM t Sl seks
uksv kWDlkbM]ijkDlkWbM o lqijkDlkWbM cukrhgSA
{kkj /kkrqv ksad sfofHkUu vkDlkbMksad s{kkjh; xq.k/kkfRod vfHky {k.kc<+usd slkFkc<+rsgSA
t kyd Å t kZiz Hkko d sd kj.kcM+
s/kuk;u }kjkcM+ s_ .kk;u d sLFkk;hd j.kd sd kj.kijkDWlkbM vFkoklqijkDWlkbM d kLFkkf;Ro
c<+t krk gS]D;ksafd /kkrqvk;u d k vkd kj c<+t krk gSA
10. Principal ( i.e main) compound formed upon combustion of sodium metal in excess air is :
ok;qd svkf/kD; esalksfM;e /kkrqd sngu lseq[; ;kSfxd curk gS]og gS%
(A*) Na2O2 (B) NaO2 (C) NaO3 (D) NaN3
PAGE NO.- 3
1
Sol. 4Na + O2  2Na2O ; Na2O + O 2  Na2O2
2
11. Among the following, which one of the superoxide is thermally most stable ?
fuEu esalsd kSulklqijkWDlkbM rkih; : i lslokZf/kd LFkk;h gS\
(A*) CsO2 (B) NaO2 (C) KO2 (D) RbO2
12. Which of the following is most basic oxide of alkali metal ?

fuEu esalsd kSulk{kkj /kkrqd klokZf/kd {kkjh; vkDlkbM gS\
(A*) Rb2O (B) K2O (C) Li2O (D) Na2O
Sol. Basic strength of oxides increases in the order Li2O < Na2O < K2O < Rb2O. This is due to the increase in
metallic character down the group.
vkWDlkbMksad h{kkjh; lkeF;ZLi2O < Na2O < K2O < Rb2O Ø e esac<+
rhgSA oxZesuhpst kusij /kkfRod vfHky {k.keaof̀)
d sd kj.k,sl kgksrkgSA
13. COMPLETE THE FOLLOWING REACTIONS : [s-block Elements]
fuEu v fHkfØ ;v ksad ksiw.kZd hft , %
(i) Na2S + Na2O2 
Ans. Na2S + 4Na2O2  Na2SO4 + 4Na2O.
(ii) MnSO4 + Na2O2 
Ans. MnSO4 + 2Na2O2  Na2MnO4 + Na2SO4 .
(iii) NaOH + NO2 

Ans. 2NaOH + 2NO2  NaNO2 + NaNO3 + H2O
(iv) NaOH (hot & conc.) (xeZrFkk lkUnz
) + Br2 
Ans. 6NaOH + 3Br2  5NaBr + NaBrO3 + 3H2O.
(v) NaOH + S 
Ans. 6NaOH + 4S  2Na2S + Na2S2O3 + 3H2O.
(vi) NaOH (hot & conc.) (xeZrFkk lkUnz
) + F2 
Ans. 4NaOH + 2F2  4NaF + O2 + 2H2O.
(vii) PbO + NaOH 

Ans. PbO + 2NaOH  Na2PbO2 + H2O
(viii) CrCl3 + NaOH 
Ans. Form insoluble hydroxides. v?kq
y u'khy gkbMª
kWDlkbM curkgSaA
CrCl3 + 3NaOH  Cr(OH)3  (Green) + 3NaCl.
(ix) HgCl2 + NaOH 

Ans. HgCl2 + 2NaOH  Hg(OH)2  + 2NaCl ; Hg(OH)2  HgO  (yellow or brown) + H2O.
150  200 º C
(x) NaOH + CO   
5 10 atm
150  200 º C
Ans. NaOH + CO    HCOONa.
5 10 atm
14. Match the compounds listed in column-I with the characteristic(s) listed in column-II.
Column-I Column-II
(A) BeO (s) (p) Amphoteric in nature
(B) NaHCO3 (crystalline) (q) Imparts characteristic colour to Bunsen flame.
(C) BeCl2(s) (r) Produce H2O2 and O2 on reaction with water.
(D) CsO2(s) (s) Show hydrogen bonding
(t) Has a chain structure
PAGE NO.- 4
LrEHk -I esafn;sx;s;kSfxd ksad ksLrEHk -II esafn;sx;svfHky {k.kksad slkFklqesfy r fd ft ,A
LrEHk -I LrEHk -II
(A) BeO (s) (p) mHk;/kehZiz of̀r
(B) NaHCO3 (fØ LVyh;) (q) cq ulsu Toky k esavfHky k{k.khd jax n'kkZrsgSA
(C) BeCl2(s) (r) t y d slkFk vfHkfØ ;k d j H2O2 o O2 ns rsgSA
(D) CsO2(s) (s) gkbMª kst u ca/kn'kkZrsgSA
(t) Jà[ky k ljap uk j[krk gSA
Ans. (A – p) ; (B – q, s, t) ; (C – t) ; (D – q, r)
Sol. (A) BeO is amphoteric in nature becuase it reacts with acid as well as base.
(B) Hydrogen bonding ; HCO3– ions are linked into an infinite chain through H-bonding.
(C)
(D) 2CsO2 + 2H2O  2Cs+ + 2OH– + H2O2 + O2
(A) BeO mHk;/kehZiz d f̀r d kgksrkgSD;ksafd ;g vEy lkFk ghlkFk{kkj d slkFkvfHkfØ ;kd jrkgSA
(B) gkbMª
kst u ca/k ; HCO3– vk;u H-ca/k }kjk vUur%J`[kay kesat qM +sgksrsgSA
(C)
(D) 2CsO2 + 2H2O  2Cs+ + 2OH– + H2O2 + O2
ChemINFO-7.1 HYDROGEN
Daily Self-Study Dosage for mastering Chemistry Preparation of H2
There are three main sources from which hydrogen may be prepared.
These are (i) Water (ii) Acids (C) Alkalines
(i) Hydrogen from water :
(a) Cold water react with alkali and alkaline earth matals to evolve hydrogen
2Na – (Hg) + 2H2O  2NaOH + H2 
Sodium amalgam
Note : The reaction are vigorous to minimum the rate of reaction, alkali metals are used in the form of amalgam.
(b) Hot water or steam, when passed over metals like Zn, Fe, Mn, Co, Cr, Sn etc is decompose to librate hydrogen.
Zn + H2O  ZnO + H2 
Note: When steam, when passed over hot coke, hydrogen is produced in the form of water gas.
C + H2O  H2 + CO
Steam water gas
(II) Hydrogen from Acid :

Many reactive metals such as alkali metals, alkaline earth metals, Zn, Mg, Fe etc. react with dil HCl or dil H2SO4 to evolve
hydrogen.
Mg + 2HCl  MgCl2 + H2
Note : Mn and Mg react with dil HNO3 to evolve hydrogen.
(III) Hydrogen from alkali :
Zn, Al, Sn, Pb, Si (Amphoteric metals) reacts with boiling NaOH or KOH to evolve hydrogen.
Zn + 2NaOH  Na2ZnO2 + H2 
Sodium Zincate
Sn + 2NaOH + H2O  Na2SnO3 + 2H2 
Sodium stannate
PAGE NO.- 5
15. Which of the following metal give H2 after reac- 18. Which of the following metal gives H2 gas after
tion with cold water. reaction with acid as well as alkali.
(A) Cu (B) Ag (A) Cu (B) Na
(C*) K (D) Pt (C*) Zn (D) Fe
16. Metals on reaction with water or dilute mineral
acids can give 19. Which of the following metal does not give H2
(A) Monohydrogen (B) O2 after reaction with dil H2SO4
(C*) Dihydrogen (D) Tritium (A) Mg (B) Fe
(C) Zn (D*) Cu
17. Water gas is
(A) CO + N2 (B*) CO + H2
(C) CO2 + H2 (D) CO2 + N2
Daily Self-Study Dosage for mastering Chemistry Preparation of H2
;gk¡rhu eq[; L=kksr gSft ulsgkbMªkst u cuk;h t k ld rh gS&
;g gS% (i) t y (ii) vEy (C) {kkj
(i) t y l sgkbMª
kst u izkIr d juk :
(a) B.Mkt y ]{kkj rFkk{kkjh; eǹk/kkrq v ksad slkFkfØ ;kd jd sgkbMªkst u fu"d kflr d jrkgSA”
2Na – (Hg) + 2H2O  2NaOH + H2 
lksfM;e vey xe
uksV : vfHkfØ ;k rhozgksrh gS]vkSj vfHkfØ ;k d h nj d ksd e d jusd sfy , {kkjh; /kkrq,¡vey xe d s: i esaiz;qDr gksrh gSA
(b) xeZt y ;kHkki d kst c /kkrqt Sl sZn, Fe, Mn, Co, Cr, Sn bR;kfn ij izokfgr d jrsgS ]rks;g fo?kfVr gkds j gkbMª
ks
t u fu"d kflr
d jrkgSA Zn + H2O  ZnO + H2 
uksV : t c Hkki d ksxeZd ksd ij izokfgr d jrsgS]rksgkbMªkst u t y xSl d s: i esamRiUUk gksrh gSA
C + H2O  H2 + CO
Hkki t y xSl
(II) v Ey l sgkbMªkst u izkIr d juk :
{kkjh; /kkrq,¡]{kkjh; e`ǹk/kkrq,¡]Zn, Mg, Fe bR;kfn d sleku vf/kd fØ ;k'khy /kkrq,¡ruqHCl ;kruqH2 SO4 d slkFkfØ ;kd jd s
gkbMª kst u fu"d kflr d jrhgS aA Mg + 2HCl  MgCl2 + H2
uksV : Mn rFkk Mg ruqHNO3 d slkFk fØ ;k d jd sgkbMªkst u fu"d kflr d jrh gSA
(III) {kkjkslsgkbMª
kst uiz
kIr d juk:
Zn, Al, Sn, Pb, Si (mHk;/kehZ/kkrq
,¡) mCky rsgq, NaOH ;kKOH d slkFkfØ ;k d jd sgkbMªkst u fu"d kflr d jrsgSaA
Zn + 2NaOH  Na2ZnO2 + H2 
lks
fM;e ft ad sV
Sn + 2NaOH + H2O  Na2SnO3 + 2H2 
lksfM;e LVsusV
15. fuEu esalsd kSulh/kkrqB.Mst y d slkFkvfHkfØ ;kd s 17. t y xSl gS&

i'pkRk~H2 nsrh gS\ (A) CO + N2 (B*) CO + H2
(A) Cu (B) Ag (C) CO2 + H2 (D) CO2 + N2
(C*) K (D) Pt
18. fuEu esalsd kSulh/kkrqvEy d slkFk&lkFk{kkj d slkFk
16. /kkrq,¡]t y ;k ruq[kfut vEy d h fØ ;k ij nsrh gS& vfHkfØ ;k d si'pkRk~H2 nsrh gS\
(A) eks uks
gkbMª
kstu (B) O2 (A) Cu (B) Na (C*) Zn (D) Fe
(C*) MkbZ gkbMª
kts u (D) Vª
kbZfV;e 19. fuEu esalsd kSulh /kkrqruqH2SO4 d slkFk vfHkfØ ;k
d si'pkRk~H2 ugh nsrh gS\
(A) Mg (B) Fe (C) Zn (D*) Cu
PAGE NO.- 6
ORG./INO. CHEMISTRY

1. Course of the week as per plan : Boron Family, Compound of Boron (B2O3, H3BO3, Borax), Compounds
Al2O3, AlCl3, Alum
2. Course covered till previous week : Important compounds of s-block elements, Discussion.
3. Target of the current week : Boron Family, Compound of Boron (B2O3, H3BO3, Borax), Compounds Al2O3,
AlCl3, Alum
4. DPP Syllabus : Boron Family, Compound of Boron (B2O3, H3BO3, Borax), Compounds Al2O3, AlCl3, Alum

ANSWER KEY
1. (B) 2. (D) 3. (A) 4. (D) 5. (D 6. (C) 7. (C)
8. (C) 9. (B) 10. (C) 11. (C) 12. (D) 13. (A) 14. (D)
15. (C) 16. (B) 17. (C) 18. (A)
1. Moderate electrical conductivity is shown by : [JEE-1982, 1 M]
(A) silica (B*) graphite (C) diamond (D) (BN)X
fuEu esalsfd ld s}kjk e/;e fo|qrpky d rk n'kk;h t krh gS% [JEE-1982, 1 M]
(A) flfyd k (B*) xz
sQ kbV (C) ghjk(diamond) (D) (BN)X
2. Which of the following halides is least stable and has doubtful existence? [JEE 1996]
(A) C4 (B) Ge4 (C) Sn4 (D*) Pb4
fuEu esalsd kSulk gSy kbM lclsd e LFkk;h rFkk langsiw.kZvfLrRo j[krk gS\ [JEE 1996]
(A) C4 (B) Ge4 (C) Sn4 (D*) Pb4
3. Which one of the following oxides is neutral ? [JEE 1996, 1 M]
fuEu esalsd kSulk mnklhu vkWDlkbM gSA
(A*) CO (B) SnO2 (C) ZnO (D) SiO2
4. Which of the following is bauxite?
fuEu esalsd kSulk ckWDlkbV gS\
(A) Al(NO3)3 (B) AlCl3 (C) Al2(SO4)3. xH2O (D*) Al2O3. xH2O
5. Name the type of the structure of silicate in which one oxygen atom of [SiO4]4– is shared ?
(A) Three – dimensional (B) Linear chain silicate
(C) Sheet silicate (D*) Pyrosilicate
flfy d sV d h lajpuk d sizd kj d k uke D;k gSft lesa[SiO4]4– d s,d vkWDlht u ijek.kqlslkf>r gksrk gS?
(A) f=kfofe; (B) js
[kh; Jà[ky kflfy d sV
(C) 'khV flfy d sV (D*) ik;jkf
slfyd sV
6. When orthoboric acid (H3BO3) is heated, the residue left could be
(A) metaboric acid (B) Boron (C*) Boric anhydride (D) Borax
PAGE NO.- 1
t c vkFkksZcksfjd vEy (H3BO3) d ksxeZfd ;k t krk gS]rks'ks"k cpk vof'k"V fuEu gksxk %
(A) es
Vkcks fjd vEy (B) cks
jks
u (C*) cksfjd ,ugkbMª kbM (D) cks
jDsl
7. Boron carbide , B4C, is widely used for
(A) making acetylene (B) making plaster of paris
(C*) as a hardest substance after diamond (D) making boric acid
cksjksu d kckZbM B4C, d k mi;ksx eq[; : i lsfd l gsrqfd ;k t krk gSA
(A) ,s
l Vhy hu d sfuekZ.k esa (B) Iy kLVj vkWQ isfjl d sfuekZ.k esa
(C*) ghjsd sckn lclsd Bks j inkFkZd s: i esa (D) cks
fjd vEy d sfuekZ.k esa
8. An aqueous solution of borax is
(A) Neutral (B) Amphoteric (C*) Basic (D) Acidic
cksjsDl d k ,d t y h; foy ;u gS%
(A) mnklhu (B) mHk;/kehZ (C*) {kkjh; (D) vEyh;
9. Boric acid is polymeric due to

(A) its acidic nature (B*) the presence of hydrogen bonds
(C) its monobasic nature (D) its geometry.
cksfjd vEy fuEu d sd kj.k cgqy d h; gS-
(A) bld hvEy h; izd f̀r d sd kj.k (B*) gkbMª
kst u
cU/kd hmifLFkfr d sd kj.k
(C) bld h,d y {kkjh; iz d f̀r d sd kj.k (D) bld hT;kferh; d sd kj.k
10. The type of hybridization of boron in diborane is

Mkbcksjsu esacksjksu d slad j.k d k izd kj gS%
(A) sp (B) sp2 (C*) sp3 (D) dsp2
11. Which of the following is formed when aluminium oxide and carbon is strongly heated in dry chlorine gas ?
(A) Aliminium chloride (B) Hydrated aluminium chloride
(C*) Anhydrous aluminium chloride (D) None of these
fuEu esalsD;kfufeZ
r gkxskt c ,Y;q
fefu;e vkDWlkbM rFkkd kcZ
u d ks'k"qd Dykfsju xS
l es
siz
cyrj : i lsxeZfd ;kt krkgS
?
(A) ,Y;q
fefu;e Dy ksjkbM (B) gkbMª
sV
,Y;qfefu;e Dy ksjkbM
(C*) fut Z
y ,Y;qfefu;e Dy ksjkbM (D) bues
alsd ksbZugha
12. Which of the following statements about H3BO3 is not correct ?
(A) It is prepared by acidifying an aqueous solution of borax.
(B) It has a layered structure in which planar B(OH)3 units are joined by hydrogen bonds.
(C) It does not act as proton donor but acts as well as Lewis acid by accepting hydroxyl ion.
(D*) It is a strong acid.
fuEu esalsd kSulk d Fku H3BO3 d sckjsesavlR; gS?
(A) blscks
jsDl d svEy hd r̀ t y h; foy ;u }kjk cuk;k t krk gSA
(B) ;g ,d ijrh; la jpuk j[krkgSft lesalery h; B(OH)3 bd kb;k¡gkbMªkst u cU/kksa}kjk t ksM +st krsgSaA
(C) ;g izksVkWu nkrk d h rjg gh d k;Zughad jrk gSy sfd u gkbMªksfDly vk;u d ksxzg.k d j y qbZl vEy d h rjg Hkh d k;Z
d jrkgSA
(D*) ;g ,d iz cy vEy gSA
13. Which gas is liberated when Al4C3 is hydrolyzed ?
d kSulh xSl eqDr gksxh t c Al4C3 t y vi?kfVr gksrk gS?
(A*) CH4 (B) C2H2 (C) C2H6 (D) CO2
PAGE NO.- 2
Daily Self-Study Dosage for mastering Chemistry Properties of Hydrogen
Properties of Hydrogen
(1) It is colourless, odourless and taste less gas.
(2) It is only slightly soluble in water.
(3) It is lightest of all elements.
(4) certain metals like palladium, platinum etc can adsorb large quantities of hydrogen. The adsorbed hydrogen is
called occluded hydrogen and is more active than ordinary hydrogen.
Combustion : Hydrogen is flammable or combustible gas it burn with blue flame in oxygen atmosphere.
2H2 + O2  2H2O
Combination reaction :
Due to very high bond dissociation energy (436 KJ mol–1) hydrogen is not a very active.
(A) Except Beryllium all alkali and alkaline earth metal directly combine with hydrogen and ionic hydride is formed.
2Li + H2  2LiH Ca + H2  CaH2

2Na + H2  2NaH Ba + H2  BaH2
(B) Halogens directly combine with Hydrogen to form covalent compounds.
H2 + X2  2HX X  F , Cl , Br , I
The reactivity of Halogen : F2 > Cl2 > Br2 > I2
(C) Synthesis of methyl alcohol : In presence of ZnO and CrO3 catalyst at 200 atmosphere CO and H2 combine
to form CH3OH.
catalyst
CO + 2H2   CH3OH
300 C
(D) Unsaturated fats are changed to saturated fats in presence of nickel .
Ni
Unsaturated fat + H2  Saturated Fat

catalyst
(Oil) (vanaspati ghee)
(E) Synthesis of Ammonia (Haber's Process) : A mixture of N2 and H2 in ratio of 1 : 3 at 200 atm, 500°C in presence
of Fe catalyst NH3 is formed.
N2 + 3H2 2NH3 H = –22.4 Kcal mol–1
14. The colour of hydrogen is :
(A) Yellow (B) Orange (C) Red (D*) None
15. Which of the following is the lightest gas ?

(A) Nitrogen (B) Helium (C*) Hydrogen (D) Oxygen
16. Which of the following metal adsorb hydrogen ?

(A) Zn (B*) Pd (C) Al (D) K
17. Which of the following react with Hydrogen very fast :

(A) Br2 (B) Cl2 (C*) F2 (D) I2
18. H2 cannot combine directly with which metal :

(A*) Be (B) Ca (C) Ba (D) Na
PAGE NO.- 3
Daily Self-Study Dosage for mastering Chemistry gkbMªkst u d sxq.k/keZ
gkbMªkst u d sxq.k/keZ
(1) ;g ja xghu]xa/kghu rFkk Loknghu xSl gSA (2) ;g d soy t y esad e ?kqy u'khy gksrh gSA
(3) ;g lHkhrRoks alsgYd hgksrhgSA
(4) fuf'pr /kkrq ,sat S
l sisy sfM;e]IysfVue bR;kfn gkbMªkst u d ksvf/kd re la[;kesavf/k'kks
f"kr d j ld rhgSA vf/k'kksf"kr gkbMª
ks
tu
vo: ) gkbMªkst u (occluded hydrogen) d gy krhgSrFkk;g lkekU; gkbMªkst u d hvis{kkvf/kd fØ ;k'khy gksrhgSaA
ngu : gkbMªkst u Toy u'khy ;k ngu'khy xSl gS;g vkWDlht u;qDr ok;qe.My esauhy h Toky k d slkFk t y rh gSA
2H2 + O2  2H2O
l a;kst u v fHkfØ ;k :
cgqr vf/kd cU/kfo;kst u Å t kZ(436 KJ mol–1) d sd kj.kgkbMªkst u vf/kd lfØ ; ughgksrhgSA
(A) cs jhfy;e d ksNks Md+ j lHkh{kkj rFkk{kkjh; eǹk/kkrq
,s
agkbMªks
t u d slkFkiz
R;{k: i lst qMrhgSrFkkvk;fud gkbMª kbM cukrhgS A
2Li + H2  2LiH Ca + H2  CaH2
2Na + H2  2NaH Ba + H2  BaH2
(B) gs y kst u gkbMªkst u d slkFkizR;{k: i lst qM d j lgla;kst d ;kSfxd cukrsgSA
H2 + X2  2HX X  F , Cl , Br , I
gsy kst u d h fØ ;k'khy rk : F2 > Cl2 > Br2 > I2

(C) esfFky ,Yd ksgy d kla 'ys"k.k: ZnO rFkkCrO3 mRiz
jd d hmifLFkfr es
s a200 ok;q
e.Myh; nkc ij CO rFkkH2 t Mq+
d j CH3OH
cukrsgSA
mRizsjd
CO + 2H2 
300 C
CH3OH
(D) vlarÌr olk fud y d h mifLFkfr esalarÌr olk esacny rh gSA
Ni
vlarÌr olk + H2  mRizsjd
 la rÌr olk
(rs
y) (ouLifr ?kh)
(E) veksfu;kd kla 'ys
"k.k(gs
cj iz Ø e) : N2 rFkkH2 d kfeJ.k200 atm rFkk500°C ij Fe mRis
jd d hmifLFkfr es
z a1 : 3 d svuq
ikr
esafØ ;k d jd sNH3 cukrkgSA
N2 + 3H2 2NH3 H = –22.4 Kcal mol–1
14. gkbMªkst u d kjax gksrkgS& 17. gkbMªkst u fuEu eslsfd l d slkFklokZf/kd fØ ;k'khy gS&
(A) ihyk (B) ukjaxh (C) y ky (D*) d ks
bZugh (A) Br2 (B) Cl2
(C*) F2 (D) I2
15. fuEu esalsd kSu gYd h xSl gS?
(A) ukbVª
kst u (B) ghfy;e 18. fuEu esalsfd l /kkrqd slkFk gkbMªkst u izR;{k : i lsugh
(C*) gkbMªks
tu (D) vkDWlht u t qM +rhgS&
(A*) Be (B) Ca
16. fuEu eslsd kSulh/kkrqgkbMªkst u d ksvf/k'kksf"kr d jrhgS? (C) Ba (D) Na
(A) Zn (B*) Pd (C) Al (D) K
Lecutre Sub-topic(s) Nam e Hom e Work Hom e Work NCERT
Chem INFO Handout
Ex.1 (S) XI 307 to 312
Th.
Ex.1 (O) XII
Chemical
L78 Boron Family Ex.2 (O) XI 323, 311
reaction of D2O
Ex.2 (I) Prob.
Ex.2 (M) XII
Ex.1 (S) XI 312 to 314
Th.
Ex.1 (O) XII
Compound of Boron
L79 Ex.2 (O) XI 323, 324, 325
(B2O3, H3BO3, Borax)
Ex.2 (I) Prob.
Ex.2 (M) XII
Ex.1 (S) XI 314
Th.
Ex.1 (O) XII
Compounds -Al2O3,
L80 Ex.2 (O) XI 323, 324, 325
AlCl3, Alum
Ex.2 (I) Prob.
Ex.2 (M) XII
PAGE NO.- 4
ORG./INO. CHEMISTRY

1. Course of the week as per plan : Carbon family, Compounds-CO,CO2,C3O2, SiO2 Silicate & Silicone, Discurssion
of p-block and Basic Strength.
2. Course covered till previous week : Boron Family, Compound of Boron (B2O3, H3BO3, Borax), Compounds
Al2O3, AlCl3, Alum
3. Target of the current week : Carbon family, Compounds-CO,CO2,C3O2, SiO2 Silicate & Silicone, Discurssion
of p-block and Basic Strength.
4. DPP Syllabus : Carbon family, Compounds-CO,CO2,C3O2, SiO2 Silicate & Silicone, Discurssion of p-block and
Basic Strength.

ANSWER KEY
1. (AB) 2. (ACD) 3. (AB) 4. (ABC) 5. (C) 6. 5 7. 4
8. 4 9. 1 10. (D) 11. (D) 12. (A) 13. (D) 14. (A)
1. Which of the following are correct [M] (PBC(INO))

(A*) B2H6 reacts with excess of ammonia at low temperature to form an ionic compound.
(B*) Borax, when heated with oxides of certain transition metals, forms coloured beads.
(C) One mole borax in aqueous solution will require one mole HCl for titration
(D) B2H6 can be methylated completely to give B2(CH3)6
fuEu esad kSulsd Fku lR; gSa\
(A*) B2H6 fuEu rki ij veks fu;k d svkf/kD; lsfØ ;k d jd s,d vk;fud ;kSfxd cukrk gSA
(B*) t c cksjsDl d ksd qN laØ e.k /kkrqvkWDlkbMksad slkFk xeZfd ;k t krk gSrksjaxhu eud k curk gSA
(C) t y h; foy ;u es a,d eksy cksjsDl d svuqekiu d sfy , 1 eksy HCl d h vko';d rk gksxhA
(D) B2H6 d ksiw .kZr%esfFky hd r̀ d jd sB2(CH3)6 mRiUu fd ;kt kld rkgSA
Sol. (C) One mole borax will require two moles of HCl for complete reaction.
(D) The bridging hydrogens can not be methylated in B2H6.
gy (C) iw
.kZvfHkfØ ;kd sfy , ,d eksy cksjsDl d ks2 eksy HCl d hvko';d rk gksxhA
(D) B2H6 esalsrqgkbMªkst uksad ksesfFky hÑ r ughad j ld rsgSaA
2. Which of the following can produce B2O3 ? (p-Block) [By SM Sir, Oct 2013] [M]
(A*) Heating borax with conc. H2SO4 (B) Passing CO2 through aq. NaBO2
(C*) Combustion of diborane, B2H6. (D*) Warming H3BO3 crystals till red hot.
fuEu esalsd kSu B2O3 d ksmRikfnr d j ld rk gS\
(A*) lkUnzH2SO4 d slkFkcks jsDl d ksxeZd j (B) t y h; NaBO2 es
als CO2 izokfgr d j
(C*) Mkbcks
jsu, B2H6 d kngu d j (D*) H3BO3 fØ LVy d ksy ky rIr rd xeZd jd s
PAGE NO.- 1
3. Which of the following are correct about B2H6 ? [M]
(A*) each ‘B’ atom is sp3 hybridised
(B*) It consists of two-”3 centre 2 electron bonds”
(C) The two bridging H-atoms are in the plane of the molecules
(D) All of these
B2H6 d sckjses afuEu esalslgh gS\
(A*) izR;sd ‘B’ ijek.kqsp3 lad fjr voLFkk esagSA (B*) blesanks]rhu d sUnz-nks-by sDVªkWu cU/k gksrsgSaA
(C) nksls rqH-ijek.kqv.kqd sry esagh gksrsgSaA (D) mijks
Dr lHkh
Sol. ‘A’ and ‘B’ are correct on the basis of structure of B2H6.
B2H6 d h la jpuk d svk/kkj ij ‘A’ o ‘B’ lgh gSaA
4. Which of the following hydrides react with water ? [M]
fuEu esalsd kSulsgkbMªkbM t y d slkFk vfHkfØ ;k d jrsgS\ (Inorganic)
(A*) B2H6 (B*) NH3 (C*) NaH (D) C2H6
Sol. B2H6 + H2O  H3BO3 + H2
NH3 + H2O  NH4OH
NaH + H2O  NaOH + H2
C2H6 + H2O  no reaction. vfHkfØ ;kughagks

rhA
5. Which of the following oxides are acidic :
fuEu esalsd kSulsvkWDlkbM vEy h; gSa%
(A) CaO (B) Na2O (C*) B2O3 (D*) CO2
6. In borax ion how many B–O–B bonds present : [Made by DRM Mam]
cksjsDl vk;u esafd rusaB–O–B caèk gS%
Ans. 5
7. In diborane maximum how many 2c – 2e bonds present : [Made by DRM Mam]
MkbZcksjsu esavf/kd re fd rus2c – 2e caèk gS%
Ans. 4
8. How many oxides in the following are basic in water: [Made by DRM Mam]
fuEu esalsfd rusvkWDlkbM t y esa{kkjh; gksrsgS%+
B2O3, Al2O3, CO2, SO2, NO2 CaO, Na2O, K2O, Cs2O, CaO
Ans. 4
9. Basicity of H3BO3 is :
H3BO3 d h {kkjd rk gS% [Made by DRM Mam]
Ans. 1
Lecutre Sub-topic(s) Nam e (No. Hom e Work Hom e Work NCERT Chem
Handout
No. of Lectures) Sheet Pg.N INFO
Ex.1 (S) XI 314 to 319
Th.
Ex.1 (O) XII
L81 Carbon family Ex.2 (O) XI 324
Ex.2 (I) Prob.
Ex.2 (M) XII
Ex.1 (S) XI 319 to 320
Th.
Ex.1 (O) XII
Compounds-CO, CO2,
L82 Ex.2 (O) XI 324, 325
C3O2
Ex.2 (I) Prob.
Ex.2 (M) XII
Ex.1 (S) XI 320 to 322
Th.
Ex.1 (O) XII
L83 SiO2 Silicate , Discussion Ex.2 (O) XI 325 Alums
Ex.2 (I) Prob.
Ex.2 (M) XII
PAGE NO.- 2
ChemINFO-8.1 p-BLOCK ELEMENT
Daily Self-Study Dosage for mastering Chemistry Group 13 & 14 Elements
ALUMS ; M2SO4. M2 (SO4)3. 24H2O or MM (SO4)2. 12H2O

Alums are transparent crystalline solids having the above general formula where M is almost any univalent positive
cation (except Li+ because this ion is too small to meet the structural requirements of the crystal) and M’ is a
trivalent positive cation (Al3+, Ti3+, V3+, Cr3+, Fe3+, Mn3+, Co3+, Ga3+ etc.). Alums contain the ions [M(H2O)6]+, [M’(H2O)6]3+
and SO42– in the ratio 1 : 1 : 2. Some important alums are :
(i) Potash alum K2SO4 . Al2(SO4)3 . 24H2O (ii) Chrome alum K2SO4 . Cr2(SO4)3 . 24H2O
(iii) Ferric alum K2SO4 . Fe2(SO4)3. 24H2O (iv) Ammonium alum (NH4)2SO4 . Al2(SO4)3 . 24H2O
Alums are double salts which when dissolved in water produce metal ions (or ammonium ions) and the sulphate
ions.
Preparation :
A mixture containing solutions of M2SO4 and M’2(SO4)3 in 1 : 1 molar ratio is fused & then the resulting mass is
dissolved into water. From the solution thus obtained, alums are crystallised.
Uses : It is used
1. As a mordant in dye industry. The fabric which is to be dyed is dipped in a solution of the alum and heated
with steam. Al(OH)3 obtained as hydrolysis product of [Al(H2O)6]3+ deposits into the fibres and then the dye
is absorbed on Al(OH)3.
2. as a germicide for water purification.
3. As a coagulating agent for precipitating colloidal impurities from water.
10. Which mixed sulphate is not an alum:

(A) K2SO4.Al2(SO4)3.24H2O (B) K2SO4.Cr2(SO4)3.24H2O
(C) Na2SO4.Fe2(SO4)3.24H2O (D*) CuSO4.Al2(SO4)3.24H2O
Sol. M is divalent, it should be monovalent according to the formula of alum.
11. Alum is used by dyer for :
(A) for fire-proofing fabrics (B) as first aid for cuts
(C) for softening hard water (D*) as mordant
Sol. As a mordant in dye industry. The fabric which is to be dyed is dipped in a solution of the alum and heated
with steam. Al(OH)3 obtained as hydrolysis product of [Al(H2O)6]3+ deposits into the fibres and then the dye
is absorbed on Al(OH)3.
12. Alums contain the ion [M(H2O)6]+, [M'(H2O)6]+3 and SO4–2 in the ratio :
(A*) 1 : 1 : 2 (B) 1 : 1 : 1 (C) 2 : 1 : 1 (D) 1 : 2 : 1
13. In question no. 12, M ion can not be :
(A) Li+ (B) K+ (C) NH4+ (D*) Al+3
14. Alums are :
(A*) double salt (B) single salt (C) Triple salt (D) none of these
PAGE NO.- 3
ChemINFO-8.1 p-BLOCK ELEMENT
Daily Self-Study Dosage for mastering Chemistry Group 13 & 14 Elements
,sy e~(M2SO4. M2 (SO4)3. 24H2O v Fkok MM (SO4)2. 12H2O) :

,y e~] ikjn'khZfØ LVy h; Bksl gS] ft ld k mijksDr lkekU; lw=k gSrFkk ;gk¡M ,d la;kst h /kkrqvFkok /kukRed ewy d gS(Li+ d s
vfrfjDr D;ksafd ;g vk;u]fØ LVy lajpukd hvko';d rklscgqr NksVsvkd kj d kgS) rFkkM f=kla;kst h/kkrqgS(Al3+, Ti3+, V3+,
Cr3+, Fe3+, Mn3+, Co3+, Ga3+ etc.). ,y e~[M(H2O)6]+, [M’(H2O)6]3+ rFkkSO42– vk;uks ad ks1 : 1 : 2. vuqikr esaj[krk gSA d qN
izeq[k ,sy e~fuEu gS&
(i) iks
Vk'k,y e~K2SO4 . Al2(SO4)3 . 24H2O (ii) Ø ks
e
,y e~K2SO4 . Cr2(SO4)3 . 24H2O
(iii) Q S
fjd ,y e~K2SO4 . Fe2(SO4)3. 24H2O (iv) veks
fu;e ,sy e~(NH4)2SO4 . Al2(SO4)3 . 24H2O
,sy e~f}d ~yo.kgS A t c bud kst y es
afoys
; fd ;kt krkgSrks/kkrqvk;u (vFkokvekfsu;e vk;u) rFkklYQ Vs vk;u cukrsgS Aa
fojpu %
,sy e~d k 1 : 1 eksy vuqikr esaM2SO4, M’2(SO4)3 d ksxfy r d jd sçkIr ifj.kkeh nzO;eku d kst y esafoy ; fd ;k t krk gSrFkk
bl çd kj çkIr foy ;u ls,sy e~d ksfØ LVy hd r̀ fd ;k t krk gSA
mi;ksx :
1. jat d m|ks x es
aca/kd d s: i esa]Q S
fcz
d (d iM+s
@ /kkxs
a) ft ud ksja
ft r fd ;kt kukgSd ks
],sy e~d sfoy;u esafoy; fd ;kt krk
gSrFkkHkki d slkFkxeZfd ;kt krkgSA /kkxks aij [Al(H2O)6]3+ d st y vi?kVu lsiz kIr Al(OH)3 fu{ks
fir gkst krkgSrFkk
fQ j jat d Al(OH)3 ij vo'kksf"kr gkst krkgSA
2. t y 'kqf) d j.k d sfy , d hVk.kquk'kd d s: i esa
3. t y lsd ksy kbMy v'kqf) ;ksad ksvo{ksfir d jusd sfy , Ld Und kjd d s: i esa
10. fuEu esalsd kSulk fefJr lYQ sV],sy e~ughagS%

(A) K2SO4.Al2(SO4)3.24H2O (B) K2SO4.Cr2(SO4)3.24H2O
(C) Na2SO4.Fe2(SO4)3.24H2O (D*) CuSO4.Al2(SO4)3.24H2O
Sol. M f}la;kst hgS];g fQ Vd jhd slw=kd svuql kj ,d y la;kst hgksukpkfg,A
11. oL=kkasd ksjaxusoky sO;fDr (dyer) ,sy e~d ksfd l mís'; lsiz;qDr d jrsgSa%
(A) oL=kksad ksvfXuizfrjks/khcukusd sfy , (B) d Vusij iz kFkfed mipkj d sfy ,
(C) d Bks j t y d kseǹqd jusd sfy , (D*) ca /kd d s: i esa
Sol. jat d m|ksx esac/kad d s: i esa]Q sfczd ¼d iM+s;k /kkxsa½ ft Ugsajaft r fd ;k t krkgSd ks],sy e~d sfoy ;u esafHkxks;k t krkgS
rFkk Hkki d slkFkxeZfd ;k t krkgSA /kkxksaij [Al(H2O)6]3+ d st y vi?kVu lsizkIr mRikn Al(OH)3 fu{ksfir gkst krkgS
rFkkfQ j jat d Al(OH)3 ij vo'kksf"kr gkst krkgSA
12. ,y e esavk;u [M(H2O)6]+, [M'(H2O)6]+3 rFkkSO4–2 fuEu vuqikr esagksrsgS%

(A*) 1 : 1 : 2 (B) 1 : 1 : 1 (C) 2 : 1 : 1 (D) 1 : 2 : 1
13. iz'u la- esa12 esaM vk;u ughagksld rk gS&

(A) Li+ (B) K+ (C) NH4+ (D*) Al+3
14. ,y e gksrsgS&
(A*) f}d y o.k (B) ,d y y o.k (C) f=kd yo.k (D) bues
alsd ksbZugha
PAGE NO.- 4
ORG./INO. CHEMISTRY

1. Course of the week as per plan : Basic Strength, Basic Strangth and Acidic Strength
2. Course covered till previous week : Carbon family, Compounds-CO,CO2,C3O2, SiO2 Silicate & Silicone,
Discurssion of p-block and Basic Strength.
3. Target of the current week : Basic Strength, Basic Strangth and Acidic Strength
4. DPP Syllabus : Basic Strength, Basic Strangth and Acidic Strength
ANSWER KEY
1. (B) 2. (D) 3. (B) 4. (B) 5. (C) 6. (B) 7. (D)
8. (A) 9. (B) 10. (D) 11. (A) 12. (B) 13. (C)
1. The following structures represent various silicate anions. Their formulas are respectively [M] (PBC(INO))
fuEu lajpuk,¡fofHkUu flfy d sV _ .kk;uksad ksiznf'kZr d jrh gSA mud slw=k Ø e'k%fuEu gSa&
O = Oxygen
= Silicon
O O
(A) SiO44– & Si3O88– (B*) SiO44– & Si3O108– (C) SiO42– & Si3O92– (D) SiO34– & Si3O108–
(A) SiO44– o Si3O88– (B*) SiO44– o Si3O108– (C) SiO42– o Si3O92– (D) SiO34– o Si3O108–
2. Select the correct statements [E] (PBC(I))

(A) Oxides of boron (B2O3) and silicon (SiO2) are acidic in nature.
(B) Oxides of aluminium (Al2O3) and gallium (Ga2O3) are amphoteric in nature.
(C) Oxides of germanium (GeO2) and tin (SnO2) are acidic in nature.
(D*) both (1) and (2)
lghd Fkuksad kp;u d hft ;sA
(A) cks
jksu (B2O3) rFkkflfy d kWu (SiO2) d svkWDlkbM vEy h; izd f̀r d sgksrsgSA
(B) ,y q
ehfu;e (Al2O3) rFkk xsfy ;e (Ga2O3) d svkWDlkbM mHk;/kehZizd f̀r d sgksrsgSA
(C) t esZfu;e (GeO2) rFkkfVu (SnO2) d svkWDlkbM vEy h; izd f̀r d sgksrsgSA
(D*) (1) rFkk(2) nks
uks
a
Sol. S1 and S2 are correct statements.
S3 : GeO2 is acidic while SnO2 is amphoteric in nature.
gy % S1 o S2 lgh d Fku gSaA
S3 : GeO2 vEy h; gSt cfd SnO2 mHk;/kehZiz
d f̀r d k gSA
PAGE NO.- 1
3. BC3 is more stable than TC3 because : [p-Block] [SA Mam_Jan_2013] [M]
(A) The difference between electronegativity of B and C is larger than that of T and C.
(B*) The higher oxidation state of T (+ 3) is less stable than that of B (+ 3).
(C) Thallium being larger in size is able to accomodate more C atoms around it.
(D) B3+ is more easily formed than T3+.
BC3, TC3 d hvis {kkvf/kd LFkk;hgksrkgS]D;kasfd : [p-Block] [SA Mam_Jan_2013]
(A) B rFkkC d h fo|q
r_ .krk d se/; vUrj T rFkkC d h vis{kk vf/kd gksrk gSA
(B*) T (+ 3) d h mPpre vkW DLkhd j.k voLFkkB (+ 3) d h vis{kk d e LFkk;h gksrh gSA
(C) FkS
fy ;e vkd kj esacM+kgksrk gS]rFkk bld spkjksvksj vf/kd C ijek.kqfLFkr gksrsgSA
(D) B3+, T3+ d h vis{kk vf/kd ljy rk lscurk gSA
Sol. Refer notes (uks V~l ns[ksa)
4. The straight chain polymer is formed by : [M] (PBC(INO))

(A) hydrolysis of (CH3)3 SiCl followed by condensation polymerization.
(B*) hydrolysis of (CH3)2 SiCl2 followed by condensation polymerization.
(C) hydrolysis of (CH3) SiCl3 followed by condensation polymerization.
(D) hydrolysis of (CH3)4 Si followed by condensation polymerization.
lh/kh Jà[ky h; cgqy d d k fuekZ.k fd ;k t k ld rk gS%
(A) (CH3)3 SiCl d kt y &vi?kVu rRi'pkr~la ?kuu cgqy d hd j.k}kjk
(B*) (CH3)2 SiCl2 d kt y &vi?kVu rRi'pkr~la ?kuu cgqy d hd j.k}kjk
(C) (CH3) SiCl3 d kt y &vi?kVu rRi'pkr~la ?kuu cgqy d hd j.k}kjk
(D) (CH3)4 Si d kt y &vi?kVu rRi'pkr~la ?kuu cgqy d hd j.k}kjk
5. Which gas is formed when CaC2 is allowed to react with dilute HCl ? [Change by CJ Sir] [E]
(A) Ethane (B) Ethene (C*) Ethyne (D) Methane
t c CaC2 d ksruqHCl d slkFk vfHkd r̀ fd ;k t krk gS]rksd kSulh xSl curh gS\
(A) ,s
Fks
u (B) ,Fkhu (C*) ,Fkkbu (D) es
Fks
u
Sol. CaC2 + 2HCl  CaCl2 + HCCH
Ethyne
,Fkkbu
6. The function of fluorspar in the electrolytic reduction of alumina dissolved is fused cryolite (Na3AlF6) is
(A) as a catalyst
(B*) to lower the temperature of the melt and to make the fused mixture very conducting
(C) to decrease the rate of oxidation of carbon at the anode
(D) none of these above
laxfy r Ø k;ksy kbV (Na3AlF6) esa?kqfy r ,sY;qfeuk d soS| qr vi?kVuh; viPk;u esa¶y ksjLikj d k d k;Zgksrk gSA
(A) mRiz
sjd d s: i esagSA
(B*) xfy r d k rki d e d juk rFkk la
xfy r feJ.k d ksvfrpky d cukuk
(C) ,uks
M +ij d kcZu d hvkWDlhd j.kd hnj d ks?kVkuk
(D) buesalsd ksbZugha
7. Which of the following is bauxite?

fuEu esalsd kSulk ckWDlkbV gS\
(A) Al(NO3)3 (B) AlCl3 (C) Al2(SO4)3. xH2O (D*) Al2O3. xH2O
8. Which of the following oxidation states are the most characterstics for lead and tin, respectively ?
y SM o fVu d sfy , fuEu esalsd kSulh vkWDlhd j.k voLFkk Ø e'k%lokZf/kd : i lsvfHky k{kf.kd gSa\
(A*) + 2 , + 4 (B) + 4 , + 4 (C) + 2 , + 2 (D) + 4 , + 2
PAGE NO.- 2
9. Which of the following anions is present in the chain structure of silicates ?
flfy d sV d h Jà[ky k lajpuk esafuEu esalsd kSulk _ .kk;u mifLFkr gksrk gS\
(A) (Si2O 52– )n (B*) (SiO 23 – )n (C) SiO 44 – (D) Si2O76 –
10. Glass reacts with HF to produce

Xy kl]HF d slkFk fØ ;k d j fuEu mRikn curk gSA
(A) H2SIO3 (B) SiF4 (C) Na3AlF6 (D*) H2SiF6
11. The oxide which is not a reducing agent is : [p-Block Element (Boron & Carbon Family)]
og vkWDlkbM t ksfd vipk;d ughagS]fuEu gS%
(A*) CO2 (B) CO (C) SO2 (D) Both (A) & (C) nks
uks(A) rFkk
(C)
Sol. CO2 can not act as reducing agent because carbon is in its highest oxidation state, i.e., +4.
gy - CO2 vipk;d d s: i esad k;Zughad jrk gSD;ksafd d kcZu bld h mPpre vkWDlhd j.k voLFkk +4 esagSaA
12. Aqueous solution of potash alum is : [p-Block Element (Boron & Carbon Family)]
(A) alkalline (B*) acidic (C) neutral (D) soapy
iksVk'k ,sy e~d k t y h; foy ;u fuEu gksrk gS%
(A) {kkjh; (B*) vEyh; (C) mnklhu (D) lkcquhd r̀
Sol. It is acidic because of the hydrolysis of Al2(SO4)3 according to the following reaction.
Al2 (SO4)3 + 6H2O 
 2Al(OH)3 + 3H2SO4.
gy - fuEufy f[kr vfHkfØ ;kd svuql kj Al2(SO4)3 d st y vi?kVu d sd kj.k;g vEy h; gSA
Al2 (SO4)3 + 6H2O   2Al(OH)3 + 3H2SO4.
13. From B2H6, all the following can be prepared except : [p-Block Element (Boron & Carbon Family)]
B2H6 lsfuEu esalsfd l ,d d svfrfjDr lHkh d kscuk;k t k ld rk gS%
(A) H3BO3 (B) [BH2(NH3)2]+ [BH4]– (C*) B2(CH3)6 (D) NaBH4
Sol. (C) CH3 group being larger can not form a bridge between two small sized boron atoms.
gy - (C) CH3 lewg d k cM+k vkd kj gksusd sd kj.k ;g nksNksVsvkd kj d scksjkWu ijek.kqv ksad se/; lsrqughacuk ld rk gSA z
Lecutre Sub-topic(s) Nam e (No. Hom e Work Hom e Work NCERT

Handout
No. of Lectures) Sheet Pg.N
L84 Basic Strength
Ex.1 (S) XI
Th.
Ex.1 (O) XII 388 to 391
Ex.2 (O) XI
L85 Basic Strength
Ex.2 (I)
Prob.
401, 392,
Ex.2 (M) XII
396, 400
PAGE NO.- 3
ORG./INO. CHEMISTRY

1. Course of the week as per plan : Acidic Strength, Acidic Strength and Tautomerism.
2. Course covered till previous week : Basic Strength, Basic Strangth and Acidic Strength
3. Target of the current week : Acidic Strength, Acidic Strength and Tautomerism.
4. DPP Syllabus : Acidic Strength, Acidic Strength and Tautomerism.
ANSWER KEY
1. (A) 2. (A) 3. (D) 4. (B) 5. (C) 6. (C) 7. (A)
8. (A) 9. (D) 10. (C) 11. (A) 12. (B) 13. (C) 14. (C)
15. (D) 16. (C) 17. (B) 18. (C)
1. (B) 2. (D) 3. (A) 4. (D) 5. (C) 6. (D) 7. (B)
8. (B) 9. (B) 10. (C) 11. (C) 12. (C) 13. (D)
14. 2 (II & IV) 15. (A  p) ; (B  r) ; (C  q) ; (D  s)
1. Which molecule have more tendency to accept H?

d kSulk v.kqH xzg.k d jusd h izof̀Ùk vf/kd j[krk gS\
(A*) (B) (C) (D)
2. Which N atom can donate its electron pair more easily?

d kSulk N ijek.kqby sDVªkWu ;qXe vf/kd vklkuh lsnsld rk gS\
O
||
NH—C—CH3
(A*) (B) (C) (D)
3. Choose the strongest base among the following :

fuEu esaizcy re {kkj d k p;u d hft ;sA
(A) (B) (C) (D*)
Sol. Only in (D) the .p of N atom is not involved in resonance with benzene ring.
d soy (D) esaN ijek.kqd k .p csat hu oy ; d slkFk vuqukn esaughagSA
PAGE NO.- 1
4. Which nitrogen in LSD (Lysergic acid diethylamide) is most basic ?
LSD (y kblft Z
d vEy Mkb,fFky ,ekbM ) esad kSulkukbVªkst u lclsvf/kd {kkjh; gSA
(1) O
H–N || (3)
(2) C – N(C2H5)2
N
|
CH3
(A) 1 (B*) 2 (C) 3 (D) all are equally basic
(A) 1 (B*) 2 (C) 3 (D) lHkhleku {kkjh; gSA
5. Increasing order of their basic strength follows for :
Aniline p-nitroaniline p-toluidine
I II III
fuEufy f[kr d sfy , {kkjh; lkeF;Zd k c<+rk gqv k Ø e gS%
,fuyhu p-ukbVª k,ss
uhfyu p-Vkys bwfMu
I II III
(A) III < I < II (B) III < II < I (C*) II < I < III (D) I < III < II
6. Consider the set of three compounds, one set of three compound being
(1) MeNH2 (2) Me2NH and (3) Me3N and another set of three compounds being
(4) EtNH2 (5) Et2NH and (6) Et3N
Which is true about basicity of these compounds in water ?
(A) 2 > 1 > 3 and 5 > 4 > 6 (B) 2 > 3 > 1 and 5 > 4 > 6
(C*) 2 > 1 > 3 and 5 > 6 > 4 (D) 3 > 2 > 1 and 6 > 5 > 4
fuEu ;kSfxd ksad sleqPp; ij fopkj d hft ;sA rhu ;kSfxd ksad k ,d leqPp; gS
(1) MeNH2 (2) Me2NH rFkk (3) Me3N vkSj vU; rhu ;kSfxd ksad k leqPp; gS
(4) EtNH2 (5) Et2NH rFkk (6) Et3N
bu ;kSfxd ksad h t y esa{kkjh;rk d k lgh Ø e gS?
(A) 2 > 1 > 3 rFkk 5 > 4 > 6 (B) 2 > 3 > 1 rFkk 5 > 4 > 6
(C*) 2 > 1 > 3 rFkk 5 > 6 > 4 (D) 3 > 2 > 1 rFkk 6 > 5 > 4
Sol. In RNH2, R2NH, R3N; the order of base strength is 2º > 1º > 3º when R = Me and the order is 2º > 3º > 1º
when R  Me.
RNH2, R2NH, R3N; es a{kkjh; lkeF;Zd k Ø e gS2º > 1º > 3º t c R = Me rFkk ;g Ø e gksxk 2º > 3º > 1º ;fn R 
Me
7. Identify the most basic nitrogen atom. (vf/kd {kkjh; ukbVª
kst u ijek.kqd ksigpkfu;s\)
(A*)  (B) (C)  (D)V
NH2 NH2 NH2 NH2

–
–
–
CCl3
–
8.
–
CCl3
–
CCl3
(o) (m) (p) Aniline
(A*) Aniline > p > m > o (B) Aniline > m > p > o
(C) p > o > Aniline > m (D) p > o > m > Aniline
(A*) ,fuy hu > p > m > o (B) ,fuy hu> m > p > o
(C) p > o > ,fuy hu > m (D) p > o > m > ,fuy hu
Sol. –CCl3 group shows –I effect so the greatest base weakening effect will be at ortho position than at meta
positive and then at para position. Unsubstituted aniline will be strongest in the above list.
–CCl3 , –I iz
Hkko n'kkZ
rkgSvr%{kkjh; {kerkd ks?kVkusokyklewg esVkrFkkiSjkd hrqy ukes avkFkks
Zij gSA vr%viz
frLFkkih
PAGE NO.- 2
,fuy hu vU; d h rqy uk esavf/kd {kkjh; gSA
9. Which of the following statement is wrong about basic strength.
(A) Generally electron donating group increases basic strength & electron withdrawing group decreases basic
strength.
(B) As we move down the group basic character decreases.
(C) As we move across the period basic character decreases.
(D*) Ortho effect in aniline increases basic strength.
{kkjh; lkeF;Zd slanHkZesad kSulk d Fku xy r gS\
(A) lkekU;r;k by s DVªkWu nkrk lewg {kkjh; lkeF;Zc<+krsgSarFkk by sDVªkWu vkd "khZlewg {kkfj; lkEkF;Z?kVkrsgSaA
(B) ,d oxZes aÅ ij lsuhpst kusij {kkjh; xq.k ?kVrsgSaA
(C) ,d vkorZd sla xr t kusij {kkjh; xq.k ?kVrsgSaA
(D*) ,sfuy hu esavkWFkksZizHkko {kkjh; xq.k c<+krkgSA
10. Which of the following acid has highest tendency to ionise in aqueous solution ?
t y h; foy ;u esad kSulsvEy d h vf/kd vk;fur gksusd h izof̀r gksrh gSA
(A) HCOOH (B) CH3COOH (C*) FCH2COOH (D) BrCH2COOH
Sol. Acidity  - I effect
– F show – I effect, Acidity  as
Sol. vEy h;rk - I izHkko
– F, – I iz
Hkko n'kkZrk gS]blfy , vEy h;rk c<+rh gSA
11. Among -nitro acetic acid (1), -fluoroacetic acid (2) -bromoacetic acid (3), -cyanoacetic acid (4), the
correct order of increasing acid strength is :
ukbVªks
,lhfVd vEy (1), ¶yks jks
,lhfVd vEy (2), czks
eks
,lhfVd vEy (3), lk;uks ,lhfVd vEy (4) d s e/;
vEy h; lkeF;Zd k lgh c<rk Ø e gksxkA
(A*) 3 < 2 < 4 < 1 (B) 1 < 2 < 3 < 4 (C) 2 < 1 < 3 < 4 (D) 4 < 1 < 2 < 3
Sol. due to – I effect – No2 > – CN > – F > – Br
Sol. – I iz
Hkko d sd kj.k– NO2 > – CN > – F > – Br
12. Ease of hydrogen release in decreasing order follows
gkbMªkst u d sfud y us(Ease of hydrogen release) d h nj d k ?kVrk gqv k Ø e gksxkA
(A) a > c > e > d > b (B*) a > e > c > b > d (C) a > d > c > b > e (D) a > c > b > d > e
Sol. Due to stability of conjugate base
Sol. le;qXeh {kkj d sLFkkf;Ro d sd kj.k
13. Which of the following phenols has the largest pKa value ?
fuEufy f[kr fQ ukWy esalspKa d k eku fd lesalclsvf/kd gksxk \
(A) (B)
(C*) (D)
Sol. is lowest Ka value so this compound has largest pKa value.
Sol. d k fuEure Ka eku blfy , ;g ;kSfxd vf/kd re pKa eku j[krk gSA
PAGE NO.- 3
14. What is the acidity order of the following compounds.
fn;s x;s ;kSfxd ksa d s vEy h; lkeF;Z d k Ø e crkb;sA
COOH
COOH COOH COOH COOH
CH3 CH 3
I II III IV V CH3
CH3
CH3
(A) I > II > III > IV > V (B) II > III > IV > V > I
(C*) V > III > I > II > IV (D) V > III > II > I > IV
Sol. (C) Due to ortho effect of benzoic acid, acidity as
Sol. (C) csUt ksbd vEy d svkFkhZizHkko d sd kj.k vEy h;rk c<+rh gSA
15. The feasible reaction is [VPM Madam]

lql axr vfHkfØ ;k gSA
(A) CH3COOH + NaCl  (B) C6H5COOH + KBr 
(C) + KHSO4  (D*) + 
Sol. Salicylic acid is more acidic than p-hydroxy benzoic acid.

lsy hflfyd vEy ] p-gkbMªkWDlhcSUt ksbd vEy d hvis
{kkvf/kd vEy h; gSA
16. Select the incorrect statement order :

xy r d Fku@Ø e d k p;u d hft , %
(A) > .......... (Stability) (LFkkf;Ro)
(B) > .......... (Acidic-strength) (vEyh; lkeF;Z

)
(C*) > .......... (Acid-strength) (vEyh; lkeF;Z

)
(D) < .......... (Acid-strength) (vEyh; lkeF;Z

)
Sol. (A)  Intramolecular H-bending

(B)  due to ortho effect
(D)  Due to ortho effect, ka as
Sol. (A) vUrvkf.od H-cU/ku

(B)  vkFkhZiz
Hkko d sd kj.kA
(D)  vkFkhZiz
Hkko d sd kj.k, Ka c<+rk gSA
PAGE NO.- 4
17. If statement is True mark T and for False mark F
(i) Imidazole is more basic than pyridine because conjugate acid of imidazole have
equal distribution of charge between both nitrogen.
(ii) Ethylamine is stronger base than aniline.

– –
(iii) NH2 is stronger base than C H3
(iv) (CH3)2NH is less basic than (CH3)3N
;fn d Fku lgh gSrksT rFkk vlR; gksusij F fy f[k,A
(i) behMst kW
y , fifjfMu lsvf/kd {kkjh; gSD;ksa
fd behMst kW
y d sla;qXehvEy esanks
uksaukbVª
ks
tu
ij vkos'kd k leku forj.k

(ii) ,fFky ,ehu],uhy hu lsizcy {kkj gSA
– –
(iii) NH2 , C H3 lsiz
cy {kkj gSA
(iv) (CH3)2NH, (CH3)3N lsd e {kkjh; gSA
(A) T T F T (B*) T T F F (C) F T F T (D) T F T F
Sol.
Sol.
18. STATEMENT -1 : is stronger base than
STATEMENT -2 : The –:NH2 group of (I) is better electron pair donor to H+ ion than the –:NH2 group of (II)
PAGE NO.- 5
d Fku-1 : d k {kkjh; lkeF;Z lsvf/kd gksrk gSA
d Fku-2 : ;kSfxd (I) d k –:NH2 lewg ;kSfxd (II) d s–:NH2 lewg lsH+ vk;u d sfy ;svPNk by sDVªkWu ;qXe nkrk gSA
(A) d Fku& 1 lR; gS ] d Fku& 2 lR; gS; d Fku& 2, d Fku& 1 d k lgh Li"Vhd j.k gSA
(B) d Fku& 1 lR; gS ] d Fku& 2 lR; gS; d Fku& 2, d Fku& 1 d k lgh Li"Vhd j.k ughagSA
(C*) d Fku& 1 lR; gS ] d Fku& 2 vlR; gSA (D) d Fku& 1 vlR; gS] d Fku& 2 lR; gSA

H
Sol. 

Conjugate base stabilise by resonance

la;qXeh {kkj vuqukn }kjk LFkk;hd r̀ gksrsgSA

Total Marks : 51 Max. Time : 35 Amin.
Comprehension ('–1' negative marking) Q.11 to Q.13 (3 marks, 2 min.) [09, 06]
Integer type Questions ('–1' negative marking) Q.14 (4 marks 3 min.) [04, 03]
1. Which of the following will not show tautomerism ? [Tautomerism]

fuEu esalsd kSu py ko;ork ughan'kkZrk gS\
(A) (B*) (C) (D)
2. Which one of the following compound does not exist in enol form ? [Tautomerism]
fuEu ;kSfxd ksaesalsd kSu bZuksy : i iznf'kZr ughad jrk gS?
O O
(A) || || (B)
CH3  C  CH2  C  C 2H5
(C) (D*)
Sol. (D) All carbon atoms are sp2 hybridized.

(D) lHkh C ijek.kqsp2 la
d fjr gSA
3. Which of the following compound will not show tautomerism.

fuEufy f[kr esalsd kSulk ;kSfxd py ko;ork iznf'kZr ughad jrsgSA
(A*) Ph — C — Ph (B) CH3 – CH – NO2 (C) (D) CH3  C  CH2  C  CH3

|| || ||
O CH 3 O O
PAGE NO.- 6
Sol. For tautomerism -H must be present.
py ko;ork d sfy , -H mifLFkr gksuk pkfg,A
4. Tautomerism will be exhibited by :

fuEu esalsfd ld s}kjk py ko;ork iznf'kZr d h t krh gSA
(A) (CH3)2NH (B) (CH3)3CNO (C) (CH3)3C – CN (D*) RCH2NO2
Sol.
5. In which of the following compound. D–exchange will take palce in OD/D2O solution ?
fuEu esad kSulk;kSfxd OD/D2O foy ;u esaD-fofue;(D–exchange ) d jrkgS\
(A) (B) (C*) (D)
6.
Stability order among these tautomers is :

mijksDr py ko;oh;ksad sLFkkf;Ro d k lgh Ø e d kSulk gS%
(A) I > II > III (B) III > II > I (C) II > I > III (D*) II > III > I
7.
Which of these tautomers is more stable ?

(A) I (B*) II (C) I = II (D) Can not predict
fuEu esalsd kSulk py ko;oh : i vf/kd LFkk;h gS\
(A) I (B*) II (C) I = II (D) crk;k ugh t k ld rk
8.
Which of these tautomers is more stable ?

(A) I (B*) II (C) I = II (D) Can not predict
fuEu esalsd kSulk py ko;oh : i vf/kd LFkk;h gS\
(A) I (B*) II (C) I = II (D) crk;k ugh t k ld rk
PAGE NO.- 7
9. The correct acidity order is :
vEy h;rk d k lgh Ø e D;k gS\
O O
|| ||
CH3 – C – OH H – C – OH
(Y) (Z)
(A) X > Z > Y (B*) Z > X > Y (C) Y > Z > X (D) X > Y > Z
10. The compound in which the CH3 –group causing increase in acid strength and decrease in basic strength are
respectively :
;kSfxd ft lesaCH3 –lewg vEy h; lkeF;Zd ksc<+krk gSrFkk {kkjh; lkeF;Zd ks?kVkrk gSØ e'k%gS:
(1) CH3–COOH (2) (3)
(4) (5) (6)
(A) 3 and rFkk 5 (B) 1 and rFkk 6 (C*) 3 and rFkk 4 (D) 2 and rFkk 5
Sol. Due to ortho effect –CH3 group in ‘3’ is increasing acidic strength & in ‘4’ is decreasing basic strength.
Sol. vkFkhZizHkko d sd kj.k ‘3’ esa–CH3 lewg vEy h; lkeF;Zc<+rk gSrFkk ‘4’ esavEy h; lkeF;Z?kVkrk gSA
Write up : (Q.11 to Q.13)

Observe the following sequence of reactions
vfHkfØ ;k vuqØ e d k izs{k.k d hft ;sA
 H  H  H
  
1 2 3
11. The correct stability order is

LFkkf;Ro d k l gh Ø e gSA
(A) III > II (B) IV > II (C*) III > IV (D) > IV
Sol. III is more stable becose –OH group show – I effect but in compound IV – O  show + I effect
Sol. III vf/kd LFkk;h gSD;ks
afd –OH lewg – I izHkko n'kkZrk gSy sfd u ;kSfxd IV – O  lewg + I izHkko n'kkZrk gSA
12. In compound II which of the following electronic effect is absent
(A) Inductive effect (B) Delocalisation of  electrons.
(C*) Hyperconjugative (D) Negative mesomeric effect
fn;sx;s;kSfxd II esafuEu esalsd kSulk by sDVªkWfud izHkko vuqifLFkr gSA
(A) iz
sjf.kd iz
Hkko (B)  bysDVª
kWuksad kfoLFkkuhd j.k
(C*) vfrla ;q
Xeu (D) +
_ .kkRed esl ksesfjd izHkko
Sol. (C) sp3 Hydrogen is absent
Sol. (C) sp3 gkbMª
kst u ijek.kqvuqifLFkr gSA
PAGE NO.- 8
13. Which of the following is not an acid
fuEu esalsd kSulk vEy ughagSA
(A) I (B) II (C) III (D*) IV
Sol. (D) Due to absence of acidic Hydrogen
Sol. (D) v Ey h; gkbMª
kst u d h v uqifLFkfr d sd kj.kA
14. How many of the following will show tautomerism ?

fuEu esalsfd rus;kSfxd py ko;ork iznf'kZr d jsxs\
O
NH
Ans. 2 (II & IV)
Some important order of decreasing acidic strength (based on Ka values )

d qN egRoiw.kZ v Ey h; l keF;Z d k ?kVrk gqv k Ø e (Ka d s ekuksa ij v k/kkfjr)
CF3COOH > CCl3COOH > CHCl2COOH > NO2CH2COOH > NC–CH2COOH > FCH2COOH > ClCH2COOH >
BrCH2COOH > HCOOH > ClCH2CH2COOH > C6H5COH > C6H5CH2COOH > CH3COOH > CH3CH2COOH
15. Match the column :

fey ku fd ft , &
Column I Column II [Ref. MM Sir]
Compounds Kb
d kWy e-I d kWy e-II [Ref. MM Sir]
;kSfxd Kb
(A) (p) 5.6 × 10–7
(B) (q) 4 × 10– 4
(C) NH3 (r) 4.6 × 10– 9
(D) CH3 –CH2 – NH –CH3 (s) 10 × 10– 4
Ans. (A  p) ; (B  r) ; (C  q) ; (D  s)
Lecutre Sub-topic(s) Nam e Hom e Work Hom e Work NCERT Chem
Handout
No. (No. of Lectures) Sheet Pg.N INFO
Ex.1 (S) XI
Th.
Ex.1 (O) XII
Ex.2 (O) XI
L89 Acidic Strength
Ex.2 (I)
Prob.
345, 378, 379
Ex.2 (M) XII
402, 376
Ex.1 (S) Sec : B, C XI
Th.
Ex.1 (O) Sec : B, C XII
L90 Tautomerism Ex.2 (O) 6 to 23 XI Deutarium Exchange
Ex.2 (I) 5 to 11 Prob.
Ex.2 (M) 5 to 15 XII
Ex.1 (S) XI
Th.
Ex.1 (O) XII
fesibility of acid -base
L91 Tautomerism Ex.2 (O) XI
reaction
Ex.2 (I) Prob.
Ex.2 (M) XII
PAGE NO.- 9
ORG./INO. CHEMISTRY
This DPP is to be discussed in the week (04-01-2016 to 09-01-2016)
1. Course of the week as per plan : Acidic Strength, Acidic Strength and Tautomerism.
2. Course covered till previous week : Basic Strength, Basic Strangth and Acidic Strength
3. Target of the current week : Acidic Strength, Acidic Strength and Tautomerism.
4. DPP Syllabus : Acidic Strength, Acidic Strength and Tautomerism.
DPP No. # 50 (JEE-MAIN) (Revision DPPS)
ANSWER KEY
DPP No. # 50 (JEE-MAIN) (Revision DPPS)
1. (C) 2. (B) 3. (C) 4. (B) 5. (D) 6. (D) 7. (D)
8. (C) 9. (D) 10. (C) 11. (B) 12. (A) 13. (D) 14. (C)
15. (B) 16. (B) 17. (A) 18. (C) 19. (B) 20. (C)
1. is named as :
(A) 2, 3-Dimethylenebutanal (B) 3-Methyl-2-methylenebut-3-enone

(C*) 3-Methyl-2-methylenebut-3-enal (D) 2, 3-Dimethylenebutanone
d k uke gS%
(A) 2, 3-Mkbes
fFky huC;w
VsuSy (B) 3-es
fFky -2-es
fFkyhuC;w
V-3-bZ
uks
u
(C*) 3-es
fFky -2-es
fFkyhuC;w
V-3-bZ
uS
y (D) 2, 3-Mkbes
fFkyhuC;wVs
uks
u
O 4
Sol. 2 3-Methyl-2-methylenebut-3-enal
H 1 3
O 4
Sol. 2 3-es
fFky -2-es
fFkyhuC;w
V-3-bZ
uS
y
H 1 3
PAGE NO.- 1
2. How many structural isomers could be obtained from the alkane C6H14 ?
,Yd su C6H14 d sfd ruslajpukRed leko;oh lEHko gS\
(A) 4 (B*) 5 (C) 6 (D) 7
3. Reductive ozonolysis
An alkene (A)  A is

vip;kRed vkst ksuhvi?kVu

,d ,Yd hu (A)  A gS%
(A) (B) (C*) (D)
Sol.
4. Acetaldehyde and Propyne can be distinguish by

,s
l hVS
fYMgkbM vkSj izksikbu d ksfoHksfnr fd ;kt kld rkgSA
(A) NaHCO3 (B*) I2/NaOH (C) Lucas reagent D) neutral FeCl3
(A) NaHCO3 (B*) I2/NaOH (C) Y;q
d kl vfHkd eZ
d (D) mnklhu FeCl3
Sol. Acetaldehyde and Propyne can be distinguish by Iodoform test.
,s
l hVSfYMgkbM vkSj izksikbu d ksvk;ksMksQ keZijh{k.k}kjkfoHksfnr fd ;kt kld rkgSA
5. Arrange following compounds in decreasing order of their dipole moment.

fn;sx, ;kSfxd ksad sf}/kqzo vk?kw.kZd k ?kVrk gqv k Ø e gS%
CH3—CH2—NO2 CH3—CH2—NH2 CH3—CH2—F CH3—CH2—CN
I II III IV
(A) IV > III >I > II (B) IV > I > III > II (C) I > III > IV > II (D*) I > IV > III > II
Ans. Decreasing order of dipole moment for given compounds
;kSfxd ksad sf}/kqzo vk?kw.kZd k ?kVrk gqv k Ø e fuEu gS%
I > IV > III > III
PAGE NO.- 2
6. Identify which of the following does not show + m effect ?
fuEu esalsd kSulk lewg + m izHkko iznf'kZr ughad jrk gS\
O O
|| ||
(A) –NH2 (B) –O 
(C)  NH  C  CH (D*)  C  NH  CH
3 3
O
||
Sol.  C  NH  CH3 do not contain lone pair or negative charge on first atom.
O
||
Sol.  C  NH  CH3 es
aizFke ijek.kqij ,d kd h by sDVªkWu ;qXe ;k _ .kkRed vkos'k mifLFkr ughagSA
7. The correct stability order of following is :

fuEu d sLFkkf;Ro d k lgh Ø e gS%
(I) (II) (III) (IV)

(A) I > II > III > IV (B) III > IV > II > I (C) II > IV > III > I (D*) IV > III > II > I
Sol. Stability  resonance
 Hyperconjugation
length of conjugation is equal in all I, II, III & IV.
gy - LFkkf;Ro  vuqukn
 vfrla ;qXeu
lHkh I, II, III o IV esala;qXeu d h y EckbZleku gSA
8. Correct order of stability of given carbocation is :

fuEu d kcZ/kuk;uksad sLFkkf;Ro d k lgh Ø e gS%
+ + +
I II III
(A) I > III > II (B) I > II > III (C*) II > III > I (D) II > I > III
9. Which molecule have lowest pKb value?

d kSulk v.kqU;wure pKb eku j[krk gS\
(A) (B) (C) (D*)
PAGE NO.- 3
10. Using anhydrous AlCl3 as catalyst, which one of the following reaction produce ethylbenzene (PhEt)?
mRizsjd fut Zy h; AlCl3 d h mifLFkfr esafuEu esalsfd ld h fØ ;k }kjk ,fFky csUt hu (PhEt) curk gS? [AIPMT 2004]
(A) H3C – CH2OH + C6H6 (B) CH3 – CH == CH2 + C6H6
(C*) C2H5Cl + C6H6 (D) H3C – CH3 + C6H6
11. A particular form of tribromobenzene forms three possible mononitro Bromo-benzenes the structure of
compound is :
(A) (B*) (C) (D) Both B and C
,d VªkbZczksekscsat hu]rhu lEHko eksuksukbVªksczksekscsat hu cukrhgSrks;kSfxd d hlajpukgksxhA [Ref. DRM mam]
(A) (B*) (C) (D) B rFkk C nks

uksa
Sol. conc. HNO  conc. H SO

3 2 4

12_. Which is more stable :

fuEu esalsd kSulk vf/kd LFkk;h gS%&
(I) (II)
(A*) I > II (B) II > I (C) II = I (D) stability can’t be predicted

(A*) I > II (B) II > I (C) II = I (D) LFkkf;Ro d kvuq eku ughayxk;kt kld rk
13_. In HCOO–, the two carbon-oxygen bonds are found to be of equal length. What is the reason for this ?
(A) The anion is obtained by the removal of a proton from the acid molecule.
(B) Electronic orbitals of carbon atoms are hybridised.
(C) The C=O bond is weaker than C–O bond.
(D*) The anion HCOO– has two equally stable resonating structures.
PAGE NO.- 4
HCOO– esanksuksd kcZu vkWDlht u ca/k leku y EckbZd sgksrsgSA bld k lgh d kj.k D;k gS\
(A) vEy v.kqlsizksVksu fu"d klu d si'pkr _ .kk;u izkIr gksrk gSA
(B) d kcZ
u v.kqd sby sDVªkfud d {kd lad fjr gksrsgSA
(C) C=O ca /k C–O ca/k lsnqcZy gksrk gSA
(D*) _ .kk;u HCOO– d hnksleku LFkkf;Ro oky hvuq uknhlajpuk,sagksrhgSA
Sol.
In HCOO– , the two carbon oxygen bonds are of equal length because the anion HCOO– has two equally
stable resonating structures.
HCOO– es
anks
uksd kcZ
u vkW
Dlht u ca
/kleku yEckbZd sgks
rsgSD;ks
fd a_ .kk;u HCOO– d hnksleku LFkkf;Ro okyhvuq
uknh
lajpuk,sagksrhgSA
14_. Which of the following benzene ring has greater electron density than
fuEu esalsd kSulh csUt hu oy ; d k by sDVªkWu ?kuRo lsvf/kd gSA
(A) (B) (C*) (D)
15._ Which is most basic in aqueous solution ?

fuEu esalsd kSulk t y h; foy ;u esavf/kd {kkjh; gS&
(A) CH3NH2 (B*) (CH3)2NH (C) (CH3)3N (D) Ph–NH2
Sol. Secondary amine is most basic in aqueous solution among aliphatic amines.
,fy Q sfVd ,ehuksaesalsf}rh;d ,ehu t y h; foy ;u esalokZf/kd {kkjh; gksrk gSA
16._ Decreasing order of enol content of the following compound in aqueous phase.
fuEu ;kSfxd ksd k t y h; voLFkk esabZukWy ?kVd d k ?kVrk gqv k Ø e gS&
(a) (b)
(c) (d)
(A) (a) > (b) > (c) > (d) (B*) (c) > (b) > (a) > (d) (C) (c) > (b) > (d) > (a) (D) (b) > (c) > (a) > (d)
PAGE NO.- 5
17._ The correct order of decreasing acid strength of trichloroacetic acid (A), trifluoroacetic acid (B), acetic acid
(C) and formic acid (D) is : [AIPMT 2012 (Pre.)]
Vª
kbZDy ksjks
,s
l hfVd ,flM (A), VªkbZ
¶yqv ks
jks,sflfVd ,flM (B), ,s
l hfVd ,flM (C) vkSj Q kfeZ
d ,flM (D) d s?kVrsgq
, vEy
lkeF;Zd k lgh Ø e gS%
(1*) B > A > D > C (2) B > D > C > A (3) A > B > C > D (4) A > C > B > D
Sol. CF3–COOH > CCl3–COOH > HCOOH > CH3COOH (Ka order) (Ka d kØ e)
18. Which is most basic among the followings ? (GOC-II)

fuEu easlsd kSulk lclsvf/kd {kkjh; gS\ (MG Sir April 2015)
(1) Ph-NH2 (2) NH3 (3*) CH3–NH2 (4) C2H5–CN
19._ Arrange the following compounds in order of decreasing acidity.

fuEu ;kSfxd ksd k vEy h;rk d k ?kVrk gqv k lgh Ø e gS&
(i) (ii) (iii) (iv)

(1) (i) > (ii) > (iii) > (iv) (2*) (iii) > (i) > (ii) > (iv) (3) (iv) > (iii) > (i) > (ii) (4) (ii) > (iv) > (i) > (iii)
Sol. Electron withdrawing group increase acidic strength and electron relasing group decrease acidic strength.
by sDVªkWu vkd "khZlewg vEy h; lkeF;Zd ksc<+krsgSrFkk by sDVªkWu fu””"d f"kZlewg vEy h; lkeF;Zd ks?kVkrsgSA
20. In which pairs first compound is stronger acid than the second ?
(A) Adipic acid, succinic acid (B) Fumaric acid, maleic acid
(C*) Pthalic acid, terepthalic acid (D) Picric acid, o-toluic acid
fd l ;qXe esaizFke ;kSfxd ]f}rh; d h rqy uk esavf/kd izcy vEy gS\
(A) ,Mhfid vEy ]lfDlfud vEy (B) ¶;wesfjd vEy ] eSy sbd vEy
(C*) FkS
fy d vEy ]VjFkSfy d vEy (D) fifØ d vEy , o-VkWyw bd vEy
Sol. (C) Phthalic acid is stronger acid due to intramolecular hydrogen bonding.
gy % (C) FkS
fy d vEy vUr%vkf.od gkbMªkst u ca/ku d sd kj.kizcy vEy gSA
PAGE NO.- 6

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ORG./INO.

TARGET : JEE (Main + Advanced) 2017

Course : VIKAAS (JA) NO. 32 & 33

This DPP is to be discussed in the week (28-09-2015 to 03-10-2015)

1. Course of the week as per plan : Inductive Effect, Resonance.

1. In which of the following compounds the direction of Inductive-effect is not correct ?

2. –CH2–CH2–O –O –CH2–O

4. What is the % s character in hybridisation of carbon when it exerts strongest –I effect ?

7. Maximum–I effect group than the group –C  C – CH3 are

8. Which of the following statements is correct about inductive effect ?

(A*) (B) (C*) (D*)

12. How many groups show – effect? [General Organic Chemistry]

Sol. CO2 O= C=O = 0 ; SO2 SO2 0

NO2 =O  0 ; SOCl2 0

COCl2  0 ; BeCl2 Cl – Be – Cl = 0

TeCl4  0 ; CCl4 0

15. Match the column-

1. Positive charge is on conjugation or delocalisation when :

(A) (B) (C*) (D*)

17. In which of the following molecule positive charge is delocalised ?

(A) (B) (C) (D*)

18. Which of the following molecule positive charge is not delocalised ?

(A) (B*) (C) (D)

20. Which positive charge stabilised by resonance ?

ChemINFO-4.2 POSITIVE CHARGE DELOCALISATION

1. la;qXeu ds nkSjku /kukos'k dk foLFkkuhdj.k rc gksrk gS tc :

(2) lehiLFk ijek.kq ij  cU/k mifLFkr gksrk gS %

(3) lehiLFk ijek.kq ij ,dkdh ;qXe mifLFkr gksrk gS %

(A) (B) (C*) (D*)

17. fuEu es ls fdl v.kq esa /kukRed vkos'k foLFkkuhd`r gksrk gS \

(A) (B) (C) (D*)

19. fuEu es ls fdl v.kq esa /kukRed vkos'k la;qXeu es ugh gS \

20. fuEu es ls dkSulk /kukRed vkos'k vuqukn }kjk LFkk;h gksrk gS \

1. Which of the following is not acceptable resonating structures of Buta-1, 2, 3-triene.

(A) (B) CH2 = C = C = CH2

Sol. (A,B,C,) CH2 = C = C = CH2

2. Which of the following is a conjugated system ?

3. Resonance is not possible in :

(A) (B*) H2C = – CH3 (C) H2C = = (D)

Sol. Lone pair of electrons of H2C = – CH3 is in sp2 hybrid orbital.

6. Which of the following statements is true about resonance.

8. [General Organic Chemistry]

(A) (II > I > III)

(B) (I > III > II)

(C*) (I > II)

The least stable cannonical structure among these is :

11. The most stable resonating structure is : [General Organic Chemistry]

12. Which of the following compound is not a resonance stablized ?

(A) (B) (C*) (D)

In above carbanion electron is transfered in :

14. Which of the following molecule donot exhibit resonance ?

Types of Mesomeric effects :

16. Identify which of the following does not show + m effect.

17. Identify which of the following cannot show – m effect.

18. Decreasing + m effet of given group is :

19. Decreasing – m effet of given group is :

20. Which of the following can not show both ± m effect.

16. fuEu esa ls dkSulk lewg + m izHkko iznf'kZr ugha djrk gS \

17. fuEu esa ls dkSulk lewg – m izHkko iznf'kZr ugha djrk gS \

18 uhps fn;s x;s fuEUkfyf[kr lewgksa dh + m izHkko dk ?kVrk gqvk Øe gS %

19. uhps fn;s x;s fuEUkfyf[kr lewgksa dh – m izHkko dk ?kVrk gqvk Øe gS %

20. fuEu esa ls dkSulk lewg ± m nksuks izHkko ugh n'kkZrk gS \

(A) (B) (C) (D*)

(A) (B) (C) (D)

(A) (B) (C) (D)

(A) O O (B) H—N N—H (C) S S (D*)

(A) ; (4) (B) ; (6)

(C) ; (3) (D) ; (6)