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The Reagent For The Following Conversions Is: (For Questions 1 To 5) (Only One Answer Correct) 1
The Reagent For The Following Conversions Is: (For Questions 1 To 5) (Only One Answer Correct) 1
1.
(A) CH3OH / H+ (B) CH3CH2OH / H+ (C) H2O / H+ (D) HOCl / H+
3.
4.
5.
H H H
| | |
(A) Ph C CH2 CH3 (B) Ph C C CH3
| | |
OH H OH
H H
| |
(C) Ph C C CH3 (D) Ph – CH2 – OH
| |
OH H
2
dil. H SO
4
7.
21
2
dil. H SO
4
8.
2
9. dil. H SO
4
(A) (B)
(C) (D)
2
10. dil. H SO
4
2
11. dil. H SO
4
(A) (B)
(C) (D)
22
12.
OH H OH
| | |
(A) CH3 C CH2 CH3 (B) CH3 C C CH3
| | |
CH3 CH3H
H H H
| | |
(C) CH3 C CH2 CH2 OH (D) HOCH2 C C CH3
| | |
CH3 CH3H
13. HBr
2
14. HBr / R O
2
15. HCl
16.
(A) (B)
(C) (D)
23
17.
(A) (B)
(C) (D)
H Cl
| |
(C) CH3 O C CH3 (D) CH3 O C CH3
| |
Cl Cl
21. Give the major product obtained from the reaction of the following with HBr.
24
22. The product of following reaction can be :
HBr
A B
(1) HBr ( 2moles ) (2) Zn
24.
R 2O 2 Ether
25. HBr
CH3 C CH
2
26. Bayer's reagent
|
CH3
OH OH OH
| | |
(A) CH3 C CH2 (B) CH3 C CH3 (C) CH3OH (D) none of the above
| |
CH3 CH3
25
27.
(A) (B)
(C) (D)
Bayer 's reagent
28. dil (cold KMnO 4 )
29.
30.
OH H OH
| | |
(A) CH3 C CH2 CH3 (B) CH3 C C CH3
| | |
CH3 CH3H
H H H
| | |
(C) CH3 C CH2 CH2 OH (D) HOCH2 C C CH3
| | |
CH3 CH3H
31.
26
32. 2 2 CH N
BH
(1)
3
33.
( 2 ) H2O 2 , OH ¯
3BH , THF
H2O 2 , OH ¯
34.
(A) (B)
(C) (D)
35.
OH H OH
| | |
(A) CH3 C CH2 CH3 (B) CH3 C C CH3
| | |
CH3 CH3H
H H H
| | |
(C) CH3 C CH2 CH2 OH (D) HOCH2 C C CH3
| | |
CH3 CH3H
27
2 32 2
(1) Hg (O CCH ) ,H O
37.
( 2 ) NaBH4 NaOH
(A’) (B)
(C) (D)
CH N
2 2
38.
CH3 H
| |
HC C CH3
(A) (B) | |
CH3 H
(C) (D)
39.
(A) (B)
(C) (D)
40.
(A) (B)
(C) (D)
28
(CH3)3CCl
A 3 B
alc. KOH 3 CF CO H
41.
The product ‘B’ is
42.
43.
CH2 CH CH2
(A) (B) CH3 C(Br ) 2 CH2
| | | |
Br Br OH OH
45. Which alkene you will choose to prepare (2R, 3S)-2, 3-Dibromobutane, by the reaction with
Br2 / CCl4
Ph – CH = CH2
(A)
(B)
BrCl / CCl aq. NaOH (1eq.)
46. 4
H H
| |
(A) A is Ph C CH2 Br (B) B is Ph C CH2 Br
| |
Cl OH
H H
| |
(C) A is Ph C CH2 Br (D) B is Ph C CH2 Br
| |
OH Cl
29
47. + Br2
(stereoisom er )
2Br
48.
CCl 4 ( )
CHBr
3
50.
t BuO ¯ K
trans-2-pentene
2 Cl / CCl
4
51.
30
cis-2-Butene2
Br / H O
2
52.
53.
(A) CH2 = CH – O – CH = CH2 (B) RO – CH2 – CH2 – – CH2 – CH2 – OR
(C) ClCH2CH2 – OH (D) CH3 – CH2 – Cl
54. Give the structure of the alcohol that is formed from the acid-catalysed hydration of the following
alkene.
(A) (B)
(C) (D)
MnO ¯ / H O, OH ¯
4
A 4 2
(1) OsO / Pyridine
57. A is
( 2) NaHCO3 , H2O Cold
31
58. Products
CH2 CH COOH
59. Zn dust
| |
Br Br
(A) II > IV > III > I (B) IV > II > III > I (C) IV > II > I > III (D) IV > I > II > III
(A) IV < III < I > II (B) IV > III > I > II (C) IV > I > III > II (D) IV > I > II > III
(A) I > II > III > IV (B) I < II < III < IV (C) I > IV > III > II (D) I > IV > II > III
(A) I > III > II > IV (B) II > I > III > IV
(C) II > I > IV > III (D) I > II > IV > III
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64. Rate of addition of Cl2 / H2O of the following alkenes is
(A) IV > III > I > II (B) IV > III > II > I (C) I > II > III > IV (D) I > II > IV > III
CH3 CH3
| |
CH3 CH2 C CH3 CH3 CH2H C CH3 CH3 CHCH2 C H2
I II III
(A) I < II < III (B) II < I < III (C) II < I < III (D) I > II > III
CH3 CHCH2 C H2 CH3 CH2CH2 C H2 CH3 CH2CH C H2
|
|
Cl II Cl
I
III
(A) II > III > I (B) I > III > II (C) II > I > III (D) I > II > III
67. Match the relative reactivity of the following alkenes towards bromine in methanol solution.
Compound Re lative Ra te
I II III
(A) a b c
(B) b a c
(C) c b a
(D) b c a
68.
I2
X
Na CO
2 3
33
70. An unknown compound decolorizes bromine in carbon tetrachloride, and it undergoes catalytic
reduction to give deccalin. When treated with warm, connected potassium permangate, this com-
pound give cis–cyclohexane–1,2–dicaboxylic acid and oxalic acid. Propose a structure for the
unknown.
Answers
EXERCISE - 1
1. A 2. B 3. D 4. B
5. A 6. C 7. A 8. C
9. A 10. D 11. C 12. A
13. B 14. A 15. C 16. A
17. B 18. B 19. D 20. C
21. B 22. D 23. D 24. A
25. D 26. A 27. D 28. A
29. C 30. C 31. A 32. D
33. B 34. C 35. B 36. A
37. A 38. C 39. B 40. A
41. B 42. C 43. C 44. A
45. D 46. B 47. B 48. C
49. B 50. A 51. B 52. B
53. A 54. A 55. C 56. D
57. A 58. C 59. B 60. A
61. B 62. C 63. D 64. B
65. D 66. C 67. C 68. A
69. A 70. D 71. C
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Assertion Reason type Question
(A) If both assertion and Reason is correct explanation of A
(B) If both assertion and Reason are correct but Reason is not correct explanation of A
(C) If assertion is correct, reason is wrong
(D) If assertion is wrong, reason is correct
H
3. Assertion :
and
4. Assertion : The addition of CBrCl3 in the presence of peroxides takes place faster to 2-ethyl-1-
hexene than to 1-octene.
Reason : Due to formation of 1° free radical in case of 2 ethyl-1-hexene
gives
Reason : The syn addition of BH3 across the double bond of norbornane takes place mostly from
the more accesible outside face of the double bond.
35
7. Assertion : A peroxyacid epoxidizes an alkene by a concerted electrophillic reaction where sev-
eral bonds are broken are formed at the same time.
Reason : The reaction between an alkene and the peroxy acid is a one step reaction which gives
the epoxide and the acid directly without any intermediates.
Answers
EXERCISE - 2
1. D 2. A 3. A 4. C
5. A 6. C 7. A 8. D
9. C 10. C
36
One or more than one answer can be correct.
1. (A)
Br2
(B)
KCN
CH3 OH
(A) A is (B) B is
(C) A is (D) B is
2.
trans-2-Butene2
D / Ni
4.
CH3
|
(A) (B) (C) (D) CH3 CH C HCH3
37
6. Select the correct statements
(A) Additon of chlorine water to Cis-2-Butene gives the racemic threo chlorohydrin
(B) Addition of chlorine water to Cis–2–Butene gives the racemic erythreo chlorohydrin
(C) Addition of chlorine water to trans–2–Butene gives the racemic erythreo chlorohydrin
(D) Addition of chlorine water to trans–2–Butene gives the racemic threo chlorohydrin
7. Alkenes (A) & (B) yield the same alcohol (C) on hydration. On vigorous oxidation with KMnO4 (A)
gives a carbonyl compound (D) and an acid (E), each containing four carbon atoms. On the other
hand (B) gives an acid (F) and a carbonyl compound (G). In (G) no two identical groups are
attached to the same carbon atom.Identify the correct structure.
(A) A is (B) C is
Answers
EXERCISE - 3
1. C, D 2. A, B, C 3. A, D 4. B, C
5. A, B, D 6. A, C 7. A, B, C, D
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