Fiitjee: Mid Phase Test-2

FIITJEE MID PHASE TEST-2
BATCHES: CRP 1820 A LOT (CLASS- XI)

M PT – 2 Q.P. Code
CONDUCTION DATE: 26/09/2018 113908
ANSWER KEY
SECTION – I (PHYSICS)
PART – A
1. D 2. D 3. D 4. B
5. D 6. C 7. C 8. C
9. B 10. A
PART - C
1. 5 2. 9 3. 2 4. 3
5. 8 6. 2 7. 9 8. 3
9. 3 10. 1
SECTION – II (CHEMISTRY)
PART - A
1. B 2. A 3. B 4. A
5. B 6. A 7. C 8. D
9. A 10. D
PART - C
1. 5 2. 8 3. 9 4. 2
5. 3 6. 2 7. 1 8. 5
9. 1 10. 9
SECTION – III (MATHEMATICS)

PART – A
1. C 2. B 3. C 4. C
5. D 6. C 7. B 8. C
9. B 10. B
PART - C
1. 7 2. 8 3. 2 4. 2
5. 1 6. 0 7. 5 8. 0
9. 0 10. 4
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CRP 1820 A LOT –MPT-2 – (PCM) - IITJEE/20
2
HINTS & SOLUTIONS

SECTION– I (PHYSICS)
PART – A
1. D
 dp
Sol. F  A   sin kt  iˆ   cos kt  ˆj 
dt  
   
F  p  0 Hence F  p
2. D
   
Sol. For collision, r1  v1 t  r2  v2 t
 3iˆ  5 ˆj  2 4 iˆ  3 ˆj  5iˆ  3 ˆj  2 aiˆ  7 ˆj
       
 11iˆ  11 ˆj   29  5  iˆ  11 ˆj
a8
3. D
   
m a  m2 a2 
Sol. acm  g  1 1 g
m1  m2
 

 a2 
 m1  m2  g  m1 a1
m2
4. B
Sol. Let displacement of plank is x.
M 3
xcm  0  M  x  L   x0x L
3 4
3 L
Distance moved by man  x  L  LL 
4 4
5. D
L
2
 x dm  x dm  kx dx 2L
0
Sol. xcm    L

 dm  dm 3
 kxdx
0
6. C
Sol. Impulse, J   Fdt  area of F  t graph
 T 
 F0   F0T
2 2 4
J F T
J  mu  u   0
m 4m
7. C
2 2
m x  m2 x 2 a   0   b   c  b 2 c
Sol. xcm  1 1  2 2
 2 .
m1  m 2 a   b  a  b2
8. C
m x  m2 x 2
Sol. xcm  1 1
m1  m2
xcm  0  m1 x1  m2 x 2  0
L L3 13
 R 2    R   L2     0  R 3   L   2  R
2 2
9. B
  
Sol. Impulse, J  m  v2  v1 
 5iˆ  2 ˆj
Since impulse is perpendicular to wall. Hence unit vector perpendicular to wall,
1
nˆ 
29

5iˆ  2 ˆj 
3
10. A
 
 m v  m2 v2 1 ˆ
Sol. v 1 1
m1  m2
 4i  3 ˆj
2
 
1 1 1
k  m1 v12  m2 v22   m1  m2  v 2
2 2 2
1 1 1 25
  40  4 2   40  3 2   80 
2 2 2 4
 320  180  250
= 250 J
PART - C
1. 5
Sol. 2h 2  80 150 g 50 g
t  4
g 10 v 3v
5
3v  v  5  v  m/s 80 m
4
5
x  vt  4  5m
4
2. 9
Sol. 3 u v 1 v
v   u/2
2 2 u 3 v/2
3v
v2 1 v 1
e   2 u
3u 2 3u 3
3u
2
60°
3. 2
Sol. By COM m2 v   m1  m2  v1
2
 m2 v  1
By COE  kx 2
2  m1  m2  2
1  10
x m = 20 cm
5  500
4. 3
   
Sol. J  m v f  vi  3miˆ  m  v f  2iˆ  3 ˆj 
   
 

v f   iˆ  3 ˆj
5. 8
Sol. Height after nth rebound,
n
2n h  1 4
h   e h     h
4 2
n
 1 4 1
  
2 4
n
2
 1 4  1 
   
2 2
n
 2n8
4
4
6. 2
Sol. Applying momentum conservation,
v
u
mu  2  mv cos 30   v 
3
u
v 2 v 2 1 2
Coefficient of restitution, e      
u cos 30 u
3  3 3 3
v
7. 9
Sol. 1
ki  mu2 u sin 60°
2
1 2
u cos 60° 60°
kf  m  u sin 60 
2 u sin 60°
kf 2 3
  sin 60  
ki 4
3 3
kf   ki   12  9 J
4 4
8. 3
 dn  dn F 144
Sol. F  mv      3
 dt  dt mv 40
 1200
1000
9. 3
Sol. Velocity before hitting  2 gh  9.8 m/s
3
Velocity after hitting   9.8 m/s
4
2v 2 3 
T    9.8   1.5 seconds
g 9.8  4 
10. 1
Sol.    
u1
u1  u2  10 u2 1
u1
gt  u1  t   1 second
g  
gt gt
 
v2 v1
SECTION – II (CHEMISTRY)
PART-A
1. B
Sol. For indicator dissociation equilibrium; being an acid
HIn H   In 
Colour A Colour B
 
 H   In 
 K HIn 
 HIn
 H    80  100
1  10 5   
100  20
  H   0.25  105  pH = 5.6020

5
2. A
MT  M O
Sol. 
 n  1 M O
92  M O
 0.2 
MO
 M O  76.66
PM mixture 1  76.66
d mixture  =  3.11 g/litre
RT 0.821  300
3. B
Sol. Let x is partial pressure of A and y is partial pressure of C when both equilibrium simultaneously
established in a vessel
X  s A  g  2 B  g 
x 2x2 y
2
K P1  PA .P B  total 
Y s C  g  2 B  g 
y 2 y2x
2
K P2  PC .P B  total 
K P1 x
  x  2y
K P2 y
2
K P1  x  2 x  2 y 
 x  0.1 atm  y  0.05 atm
Total pressure of gases = PA  PB  PC  3  x  y   0.45 atm
4. A
Sol. NaOCN  H 2O NaOH  HOCN
Kh Kw 1014
 h    104
C K a .C 3.33  104  0.003
 % hydrolysis = 10 2 %
5. B
Sol. 3Se  g 
2 Se6  g 
moles at eqm a 1  a
3
Observed number of moles at equilibrium M T


Initial number of moles of reactant MO
a
a 1    
 3  M T    0.315
a MO
Where molar mass of Se2
 M T   79  2  158
And molar mass of mixture
wRT 0.02  24.63
 MO     200
PV 1  2.463 103
6. A
Sol. NaCN + HCl is not a buffer but if HCl is in less amount then, it gives a buffer as it produces HCN.
NaCN  HCl 
 NaCl  HCN
Mole addd reaction 0.01 a 0 0
Mole after reaction (0.01 - a) 0 a a
6
This is buffer of HCN + NaCN

Let a mole of HCl be used for this pupose.
0.01  a
 pH   log K a  log
a
0.01  a
8.5   log 4.1 1010  log
a
3
 a  8.85  10 mole of HCl.
7. C
Sol. Let the mixture contains V mL of 0.1 M HCOONa and 50 mL of 0.05 M HCOOH.
1 V  milli-mole 
 HCOONa    conc.  
V  50  VmL 
50  0.05
 HCOOH  
V  50
According to Handerson equation
pH   log K a  log
Salt 
 Acid 
 0.1  V  / V  50 
4.0  3.80  log
2.5 / V  50 
V  39.62 mL
8. D
 1 2 
LiCl. NH 3  s   2 NH 3  g  LiCl.3 NH 3 s   K p1  9  atm  
Sol.
Initial mole 0.1 a
Final mole 0 (a - 0.2) 0.1
1
At eqm, K P1  2
P' NH 3
 P 'NH3  3 atm
PV  nRT
3 × 5 = n × 0.0821 × 313  n  0.5837
i.e.  a  0.2   0.5837
 Initial mole of NH3 = a  0.5837  0.2 = 0.7837 mole
9. A
N 2O4 2NO2
Sol.
Concentration at t = 0 5 5
GNO2O4   100kJmol-1 ; GNO

o

2  298 k
 50 kJ mol-1
298 K
o
G° for reaction = 2 × G NO2
 G No 2O4  2  50  100  0
Now G  G  2.303RT log Q  3.99 kJ
10. D
3 3 2
Sol. K sp   3a   3a   2a   2916a 8
PART- C
1. 5
Sol. NH 4  H 2O NH 4 OH  H 
Weak base Strong acid
Kw 10 14
At equilibrium, K h    5.6  10 10
K b 1.8  10 5
7
Kh 5.6  1010
Degree of hydrolysis, h    3.74  10 5
C 0.4
Kh
And,  H    C.h  C  K h .C  1.5  105
C
Or,  log  H   pH   log1.5  105  4.8239  5

2. 8
dy
8B  g  8 A g   C  s 
dx
4V 2V
Initial number of moles
RT RT
Sol.
4V 2V
No. of moles at eq. x x
RT RT
2V
 x
RT
8 8
 4V   2V 
 Kc    /  8
 RT   RT 
3. 9
Sol. Let V mL of 0.1 M NaOH and 0.1 M HA reacts to give NaA.
NaOH  HA NaA  H 2O
Meq. before reaction 0.1×V + 0.1 × V 0 + 0
Meq. at end point 0 + 0 0.1 × V
0.1  V
 NaA   0.05M (Total volume become 2V mL).
2V
Now 0.05 M NaA solution undergoes hydrolysis.
A  H 2 O OH   HA
1 0 0
1 H H H
  OH    C .h  9.45  106
 pOH   log OH    5.025

pH  14  pOH  8.975  9
4. 2
Sol. XA D C
a 1  a a
x x
2 2
a
KC  x
2  1
2 
V x a  
  V 
Since  is independent of A
2 x 0
x2
5. 3
Sol.
N2  3H 2 2NH 3
Initial mole 1 3 0
At equilibrium 1  x   3  3x   2x 
 Out of 4 mole of mixture, q mole have reacted and hence 2 mole are left
 1  x  3  3x  2
8
x  0.5
Total mole at equilibrium = 1  x  3  3 x  2 x  3
Number of mole of NH3 at equilibrium = 2x = 1
1 p
 pNH3  p  y3
3 3
6. 2
Sol. The two conditions when colour of indicator will be visible are derived by
 In 
pH  pK a  log
 HIn
pH  5  log10  6 ...(i)
pH  5  log 0.1  4 ...(ii)
Thus, minimum change in pH = 2
7. 1
Sol. Sb2 S3 s   3H 2 g  2Sb s   3H 2 S g 
0.01 x 0.013 x 2x 3x
Where 3x  0.005
H 2 S  Pb 2  
 PbS  2 H 
1.19
Number of moles of PbS formed = = 0.005 mole
238
 0.005 
At equilibrium,  H 2 S    
 250 
 0.005 
Kc    1
 0.005 
8. 5
Sol. Anilium acetate + H2O Aniline + Acetic acid
1 0 0
(1–x) x x
Let concentration of salt be C mol/litre.
 [Acetic acid] = Cx
x Kw 1014
 Kh    1.054
1 x K a  Kb 5  1010  1.8  105
 x  0.513
1
pH  log Kb  log Ka  log K w 
2
1
pH   9.3010  4.7447  14  4.7219  5
2
9. 1
n g
Sol. KP  Kx  P
 KP  K x  P
Thus, K P  K x , when P = 1 atm
10. 9
 NH 4 
Sol. pOH  pK b  log
 Base 
 pK b   log K b   log K NH 4OH 
9
K NH   10 9  K NH   K NH 4OH  K w
4 4
14
10
K NH 4 OH  9
 105
10
Given,   NH 4 2 SO4   0.2M   NH 4   0.2  2  0.4 M
And  NH 4 OH   0.40 M
0.4
pOH   log105  log 5
0.4
pH  14  pOH  14  5  9
SECTION – III (MATHEMATICS)

PART – A
1. C
Sol. y  b  m1  x  a  ... (i)
y  b  m2  x  a  ... (ii)
 1   2   x  a  0 directrix  m1  m2  1
2. B
Sol. It passes through the focus (2, 0)
3. C
1
Sol. y  mx  passes through (1, 4) m  2  3.
m

tan   3 
3
4. C
4 y 16 x 57
Sol. y2   
3 9 9
2
 2
 9  y    16 x  61
 3
5. D
Sol. Given exp    2  3  4  2  3  4 
 4  6  4   2   2   6  18  12  16  44.
6. C
2
Sol. f  x    x  b   2 c 2  b 2  f min  2 c 2  b 2
2
g  x     x  c   c 2  b 2  g max  c 2  b 2
7. B
2
2 2  3  11
Sol.  2   2        2    p  2   p  1   p   
 2 4
8. C
x 2  2x  c
Sol. Let y  2
x  4 x  3c
  y  1  x 2   4y  2  x   3y  1 c  0
 D  0   4  3c  y 2  4  1  c  y  1  c  0y
 4  3c  0, D  0
2
4  3c  0, 4  1  c    4  3c  1  c   0
 c   0, 1
9. B
10
z1 3 z1 6
Sol. x ,y
2 5
13
z z1 6 1
if xy  z 3 2 ;   z3 2  z  .
2 5 10
10. B
Sol. Case I
2x  3  1
3x  4  1
5
x x2
3
Case II
0  2x  3  1
0x41
5 3 5
x  x
3 2 3
PART - C
1. 7
Sol. Let P  t1  , Q  t 2  2 t12  2 t 22  17,  2t 12  2t 22   11
ST 2  SP  SQ  2  1  t12  2  1  t 22   34  4  11  49.
2. 8
Sol. family of line passes then (2, 0)
chord is x = 2 and point are (2,  4)
3. 2
Sol. Let the normal at ‘t’ must curve again t1
2
t 1  t  but t1  t  4
t
4 2
  t   t 2  2
t t
4. 2
Sol. If A is t1 and B is t2
2
t 2   t1  , t1 t 2   4
t
Eliminate t 2 t 12  2
Slope = t1  Slope  m 2  2
5. 1
6 x 2  18  21
Sol. Let y  2
6 x  18  17
6  y  1 x 2  18  y  1  x  17 y  21  0
D0
15
1 y  .
7
6. 0
Sol. x  1  x  1  4x  1
Square 2 x  2 x 2  1  4 x  1
 1  2x  2 x 2  1
5
x  but does not satisfy
4
7. 5
Sol. x 2  8x   n 2  10n   0
11
D0 2n8
n  3, 4, 5, 6, 7
8. 0
Sol. x 3  3x 2  4 x  5  0  x   is root
x 3  3 x 2  4 x  5  0  x   is root
   0
9. 0
Sol. x 2  4x  3  0
 x  3  x  1  0  x  1, 3
but x > 0
10. 4
 1 
Sol.  2  log 10 x  4
 log 10 x 

Fiitjee: Mid Phase Test-2

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FIITJEE MID PHASE TEST-2

BATCHES: CRP 1820 A LOT (CLASS- XI)

SECTION – III (MATHEMATICS)

HINTS & SOLUTIONS

Observed number of moles at equilibrium M T

This is buffer of HCN + NaCN

GNO2O4   100kJmol-1 ; GNO

 pOH   log OH    5.025

SECTION – III (MATHEMATICS)

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