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Fiitjee: Mid Phase Test-2
Fiitjee: Mid Phase Test-2
FIITJEE Ltd., B – 4, Sec – 16, Noida (U.P), 201301, Ph : 0120 – 4080700. Ph: 9871091470.www.fiitjeenoida.com
FIITJEE Towers, C – 56 A/26 Institutional Area, Sec – 62, Noida (U.P), 201307, 0120-4754800/804/805/811.
FIITJEE Greater Noida, 1st Floor, Wegman's Business Park, Plot no. 3, Sector-KP- III, Greater Noida (U.P), 201308, Ph : 9599773876.
CRP 1820 A LOT –MPT-2 – (PCM) - IITJEE/20
2
x dm x dm kx dx 2L
0
Sol. xcm L
dm dm 3
kxdx
0
6. C
Sol. Impulse, J Fdt area of F t graph
T
F0 F0T
2 2 4
J F T
J mu u 0
m 4m
7. C
2 2
m x m2 x 2 a 0 b c b 2 c
Sol. xcm 1 1 2 2
2 .
m1 m 2 a b a b2
8. C
m x m2 x 2
Sol. xcm 1 1
m1 m2
xcm 0 m1 x1 m2 x 2 0
L L3 13
R 2 R L2 0 R 3 L 2 R
2 2
9. B
Sol. Impulse, J m v2 v1
5iˆ 2 ˆj
Since impulse is perpendicular to wall. Hence unit vector perpendicular to wall,
1
nˆ
29
5iˆ 2 ˆj
FIITJEE Ltd., B – 4, Sec – 16, Noida (U.P), 201301, Ph : 0120 – 4080700. Ph: 9871091470.www.fiitjeenoida.com
FIITJEE Towers, C – 56 A/26 Institutional Area, Sec – 62, Noida (U.P), 201307, 0120-4754800/804/805/811.
FIITJEE Greater Noida, 1st Floor, Wegman's Business Park, Plot no. 3, Sector-KP- III, Greater Noida (U.P), 201308, Ph : 9599773876.
CRP 1820 A LOT –MPT-2 – (PCM) - IITJEE/20
3
10. A
m v m2 v2 1 ˆ
Sol. v 1 1
m1 m2
4i 3 ˆj
2
1 1 1
k m1 v12 m2 v22 m1 m2 v 2
2 2 2
1 1 1 25
40 4 2 40 3 2 80
2 2 2 4
320 180 250
= 250 J
PART - C
1. 5
Sol. 2h 2 80 150 g 50 g
t 4
g 10 v 3v
5
3v v 5 v m/s 80 m
4
5
x vt 4 5m
4
2. 9
Sol. 3 u v 1 v
v u/2
2 2 u 3 v/2
3v
v2 1 v 1
e 2 u
3u 2 3u 3
3u
2
60°
3. 2
Sol. By COM m2 v m1 m2 v1
2
m2 v 1
By COE kx 2
2 m1 m2 2
1 10
x m = 20 cm
5 500
4. 3
Sol. J m v f vi 3miˆ m v f 2iˆ 3 ˆj
v f iˆ 3 ˆj
5. 8
Sol. Height after nth rebound,
n
2n h 1 4
h e h h
4 2
n
1 4 1
2 4
n
2
1 4 1
2 2
n
2n8
4
FIITJEE Ltd., B – 4, Sec – 16, Noida (U.P), 201301, Ph : 0120 – 4080700. Ph: 9871091470.www.fiitjeenoida.com
FIITJEE Towers, C – 56 A/26 Institutional Area, Sec – 62, Noida (U.P), 201307, 0120-4754800/804/805/811.
FIITJEE Greater Noida, 1st Floor, Wegman's Business Park, Plot no. 3, Sector-KP- III, Greater Noida (U.P), 201308, Ph : 9599773876.
CRP 1820 A LOT –MPT-2 – (PCM) - IITJEE/20
4
6. 2
Sol. Applying momentum conservation,
v
u
mu 2 mv cos 30 v
3
u
v 2 v 2 1 2
Coefficient of restitution, e
u cos 30 u
3 3 3 3
v
7. 9
Sol. 1
ki mu2 u sin 60°
2
1 2
u cos 60° 60°
kf m u sin 60
2 u sin 60°
kf 2 3
sin 60
ki 4
3 3
kf ki 12 9 J
4 4
8. 3
dn dn F 144
Sol. F mv 3
dt dt mv 40
1200
1000
9. 3
Sol. Velocity before hitting 2 gh 9.8 m/s
3
Velocity after hitting 9.8 m/s
4
2v 2 3
T 9.8 1.5 seconds
g 9.8 4
10. 1
Sol.
u1
u1 u2 10 u2 1
u1
gt u1 t 1 second
g
gt gt
v2 v1
SECTION – II (CHEMISTRY)
PART-A
1. B
Sol. For indicator dissociation equilibrium; being an acid
HIn H In
Colour A Colour B
H In
K HIn
HIn
H 80 100
1 10 5
100 20
H 0.25 105 pH = 5.6020
FIITJEE Ltd., B – 4, Sec – 16, Noida (U.P), 201301, Ph : 0120 – 4080700. Ph: 9871091470.www.fiitjeenoida.com
FIITJEE Towers, C – 56 A/26 Institutional Area, Sec – 62, Noida (U.P), 201307, 0120-4754800/804/805/811.
FIITJEE Greater Noida, 1st Floor, Wegman's Business Park, Plot no. 3, Sector-KP- III, Greater Noida (U.P), 201308, Ph : 9599773876.
CRP 1820 A LOT –MPT-2 – (PCM) - IITJEE/20
5
2. A
MT M O
Sol.
n 1 M O
92 M O
0.2
MO
M O 76.66
PM mixture 1 76.66
d mixture = 3.11 g/litre
RT 0.821 300
3. B
Sol. Let x is partial pressure of A and y is partial pressure of C when both equilibrium simultaneously
established in a vessel
X s A g 2 B g
x 2x2 y
2
K P1 PA .P B total
Y s C g 2 B g
y 2 y2x
2
K P2 PC .P B total
K P1 x
x 2y
K P2 y
2
K P1 x 2 x 2 y
x 0.1 atm y 0.05 atm
Total pressure of gases = PA PB PC 3 x y 0.45 atm
4. A
Sol. NaOCN H 2O NaOH HOCN
Kh Kw 1014
h 104
C K a .C 3.33 104 0.003
% hydrolysis = 10 2 %
5. B
Sol. 3Se g
2 Se6 g
moles at eqm a 1 a
3
FIITJEE Ltd., B – 4, Sec – 16, Noida (U.P), 201301, Ph : 0120 – 4080700. Ph: 9871091470.www.fiitjeenoida.com
FIITJEE Towers, C – 56 A/26 Institutional Area, Sec – 62, Noida (U.P), 201307, 0120-4754800/804/805/811.
FIITJEE Greater Noida, 1st Floor, Wegman's Business Park, Plot no. 3, Sector-KP- III, Greater Noida (U.P), 201308, Ph : 9599773876.
CRP 1820 A LOT –MPT-2 – (PCM) - IITJEE/20
6
pH log K a log
Salt
Acid
0.1 V / V 50
4.0 3.80 log
2.5 / V 50
V 39.62 mL
8. D
1 2
LiCl. NH 3 s 2 NH 3 g LiCl.3 NH 3 s K p1 9 atm
Sol.
Initial mole 0.1 a
Final mole 0 (a - 0.2) 0.1
1
At eqm, K P1 2
P' NH 3
P 'NH3 3 atm
PV nRT
3 × 5 = n × 0.0821 × 313 n 0.5837
i.e. a 0.2 0.5837
Initial mole of NH3 = a 0.5837 0.2 = 0.7837 mole
9. A
N 2O4 2NO2
Sol.
Concentration at t = 0 5 5
Kw 10 14
At equilibrium, K h 5.6 10 10
K b 1.8 10 5
FIITJEE Ltd., B – 4, Sec – 16, Noida (U.P), 201301, Ph : 0120 – 4080700. Ph: 9871091470.www.fiitjeenoida.com
FIITJEE Towers, C – 56 A/26 Institutional Area, Sec – 62, Noida (U.P), 201307, 0120-4754800/804/805/811.
FIITJEE Greater Noida, 1st Floor, Wegman's Business Park, Plot no. 3, Sector-KP- III, Greater Noida (U.P), 201308, Ph : 9599773876.
CRP 1820 A LOT –MPT-2 – (PCM) - IITJEE/20
7
Kh 5.6 1010
Degree of hydrolysis, h 3.74 10 5
C 0.4
Kh
And, H C.h C K h .C 1.5 105
C
Or, log H pH log1.5 105 4.8239 5
2. 8
dy
8B g 8 A g C s
dx
4V 2V
Initial number of moles
RT RT
Sol.
4V 2V
No. of moles at eq. x x
RT RT
2V
x
RT
8 8
4V 2V
Kc / 8
RT RT
3. 9
Sol. Let V mL of 0.1 M NaOH and 0.1 M HA reacts to give NaA.
NaOH HA NaA H 2O
Meq. before reaction 0.1×V + 0.1 × V 0 + 0
Meq. at end point 0 + 0 0.1 × V
0.1 V
NaA 0.05M (Total volume become 2V mL).
2V
Now 0.05 M NaA solution undergoes hydrolysis.
A H 2 O OH HA
1 0 0
1 H H H
OH C .h 9.45 106
4. 2
Sol. XA D C
a 1 a a
x x
2 2
a
KC x
2 1
2
V x a
V
Since is independent of A
2 x 0
x2
5. 3
Sol.
N2 3H 2 2NH 3
Initial mole 1 3 0
At equilibrium 1 x 3 3x 2x
Out of 4 mole of mixture, q mole have reacted and hence 2 mole are left
1 x 3 3x 2
FIITJEE Ltd., B – 4, Sec – 16, Noida (U.P), 201301, Ph : 0120 – 4080700. Ph: 9871091470.www.fiitjeenoida.com
FIITJEE Towers, C – 56 A/26 Institutional Area, Sec – 62, Noida (U.P), 201307, 0120-4754800/804/805/811.
FIITJEE Greater Noida, 1st Floor, Wegman's Business Park, Plot no. 3, Sector-KP- III, Greater Noida (U.P), 201308, Ph : 9599773876.
CRP 1820 A LOT –MPT-2 – (PCM) - IITJEE/20
8
x 0.5
Total mole at equilibrium = 1 x 3 3 x 2 x 3
Number of mole of NH3 at equilibrium = 2x = 1
1 p
pNH3 p y3
3 3
6. 2
Sol. The two conditions when colour of indicator will be visible are derived by
In
pH pK a log
HIn
pH 5 log10 6 ...(i)
pH 5 log 0.1 4 ...(ii)
Thus, minimum change in pH = 2
7. 1
Sol. Sb2 S3 s 3H 2 g 2Sb s 3H 2 S g
0.01 x 0.013 x 2x 3x
Where 3x 0.005
H 2 S Pb 2
PbS 2 H
1.19
Number of moles of PbS formed = = 0.005 mole
238
0.005
At equilibrium, H 2 S
250
0.005
Kc 1
0.005
8. 5
Sol. Anilium acetate + H2O Aniline + Acetic acid
1 0 0
(1–x) x x
Let concentration of salt be C mol/litre.
[Acetic acid] = Cx
x Kw 1014
Kh 1.054
1 x K a Kb 5 1010 1.8 105
x 0.513
1
pH log Kb log Ka log K w
2
1
pH 9.3010 4.7447 14 4.7219 5
2
9. 1
n g
Sol. KP Kx P
KP K x P
Thus, K P K x , when P = 1 atm
10. 9
NH 4
Sol. pOH pK b log
Base
pK b log K b log K NH 4OH
FIITJEE Ltd., B – 4, Sec – 16, Noida (U.P), 201301, Ph : 0120 – 4080700. Ph: 9871091470.www.fiitjeenoida.com
FIITJEE Towers, C – 56 A/26 Institutional Area, Sec – 62, Noida (U.P), 201307, 0120-4754800/804/805/811.
FIITJEE Greater Noida, 1st Floor, Wegman's Business Park, Plot no. 3, Sector-KP- III, Greater Noida (U.P), 201308, Ph : 9599773876.
CRP 1820 A LOT –MPT-2 – (PCM) - IITJEE/20
9
K NH 10 9 K NH K NH 4OH K w
4 4
14
10
K NH 4 OH 9
105
10
Given, NH 4 2 SO4 0.2M NH 4 0.2 2 0.4 M
And NH 4 OH 0.40 M
0.4
pOH log105 log 5
0.4
pH 14 pOH 14 5 9
FIITJEE Ltd., B – 4, Sec – 16, Noida (U.P), 201301, Ph : 0120 – 4080700. Ph: 9871091470.www.fiitjeenoida.com
FIITJEE Towers, C – 56 A/26 Institutional Area, Sec – 62, Noida (U.P), 201307, 0120-4754800/804/805/811.
FIITJEE Greater Noida, 1st Floor, Wegman's Business Park, Plot no. 3, Sector-KP- III, Greater Noida (U.P), 201308, Ph : 9599773876.
CRP 1820 A LOT –MPT-2 – (PCM) - IITJEE/20
10
z1 3 z1 6
Sol. x ,y
2 5
13
z z1 6 1
if xy z 3 2 ; z3 2 z .
2 5 10
10. B
Sol. Case I
2x 3 1
3x 4 1
5
x x2
3
Case II
0 2x 3 1
0x41
5 3 5
x x
3 2 3
PART - C
1. 7
Sol. Let P t1 , Q t 2 2 t12 2 t 22 17, 2t 12 2t 22 11
ST 2 SP SQ 2 1 t12 2 1 t 22 34 4 11 49.
2. 8
Sol. family of line passes then (2, 0)
chord is x = 2 and point are (2, 4)
3. 2
Sol. Let the normal at ‘t’ must curve again t1
2
t 1 t but t1 t 4
t
4 2
t t 2 2
t t
4. 2
Sol. If A is t1 and B is t2
2
t 2 t1 , t1 t 2 4
t
Eliminate t 2 t 12 2
Slope = t1 Slope m 2 2
5. 1
6 x 2 18 21
Sol. Let y 2
6 x 18 17
6 y 1 x 2 18 y 1 x 17 y 21 0
D0
15
1 y .
7
6. 0
Sol. x 1 x 1 4x 1
Square 2 x 2 x 2 1 4 x 1
1 2x 2 x 2 1
5
x but does not satisfy
4
7. 5
Sol. x 2 8x n 2 10n 0
FIITJEE Ltd., B – 4, Sec – 16, Noida (U.P), 201301, Ph : 0120 – 4080700. Ph: 9871091470.www.fiitjeenoida.com
FIITJEE Towers, C – 56 A/26 Institutional Area, Sec – 62, Noida (U.P), 201307, 0120-4754800/804/805/811.
FIITJEE Greater Noida, 1st Floor, Wegman's Business Park, Plot no. 3, Sector-KP- III, Greater Noida (U.P), 201308, Ph : 9599773876.
CRP 1820 A LOT –MPT-2 – (PCM) - IITJEE/20
11
D0 2n8
n 3, 4, 5, 6, 7
8. 0
Sol. x 3 3x 2 4 x 5 0 x is root
x 3 3 x 2 4 x 5 0 x is root
0
9. 0
Sol. x 2 4x 3 0
x 3 x 1 0 x 1, 3
but x > 0
10. 4
1
Sol. 2 log 10 x 4
log 10 x
FIITJEE Ltd., B – 4, Sec – 16, Noida (U.P), 201301, Ph : 0120 – 4080700. Ph: 9871091470.www.fiitjeenoida.com
FIITJEE Towers, C – 56 A/26 Institutional Area, Sec – 62, Noida (U.P), 201307, 0120-4754800/804/805/811.
FIITJEE Greater Noida, 1st Floor, Wegman's Business Park, Plot no. 3, Sector-KP- III, Greater Noida (U.P), 201308, Ph : 9599773876.