Well
Well
September 2014
Table of Contents
Tables within Text .......................................................................................................... iii
Photographs within Text ................................................................................................. iii
Tables ............................................................................................................................ iv
Figures ........................................................................................................................... iv
Appendices .................................................................................................................... iv
1.0 Introduction ........................................................................................................... 1
1.1 Objective ........................................................................................................... 1
1.2 Report Content and Format............................................................................... 1
2.0 Occupational Health and Safety............................................................................ 2
3.0 Remediation Criteria ............................................................................................. 3
3.1 General ............................................................................................................. 3
3.2 Background Conditions ..................................................................................... 6
4.0 Abandonment and Restoration Activities .............................................................. 7
5.0 Mainland East ..................................................................................................... 11
5.1 Refinery .......................................................................................................... 11
5.1.1 Soil and Groundwat er Remediation Program........................................ 13
5.1.2 Phase II Environment al Site Assessment ........................................... 15
5.1.3 Groundwater Monitoring Program ............................................................ 16
5.2 B-42X Well Site ............................................................................................... 17
5.3 B-38X Well Site ............................................................................................... 17
5.3.1 2013 Status Update ................................................................................. 17
5.3.2 In Situ Soil and Groundwater Remediation ............................................... 18
5.3.3 Groundwater Monitoring Program ............................................................ 19
5.4 Mainland Tank Farm ....................................................................................... 20
5.5 Former A-45X Well Site – Town Lease ........................................................... 21
5.6 Background/Control Point Locations (MEBG).................................................. 22
6.0 Mainland Central ................................................................................................ 23
6.1 Battery #3 ....................................................................................................... 23
6.1.1 Battery #3 Flare Pit (BT3)......................................................................... 24
6.2 Bosworth Creek and Bosworth Delta Area ...................................................... 24
6.3 B-30X Well Site ............................................................................................... 26
6.4 Tank 401 Area ................................................................................................ 27
6.5 Tank 53 Area .................................................................................................. 28
6.6 Background/Control Point Locations (MCBG) ................................................. 29
6.7 Biocell, ARB, and B-33X Area ......................................................................... 29
6.8 Biocell Operation in 2013 ..................................................................................... 31
7.0 Mainland West .................................................................................................... 33
7.1 E-27X Well Site ............................................................................................... 33
7.2 F-28X Well Site ............................................................................................... 34
7.3 Mainland West Background Locations (MWBG) .............................................. 34
8.0 Sumps ................................................................................................................ 35
8.1 Mainland Sumps ............................................................................................. 35
8.2 Cemetery Sump .............................................................................................. 39
8.3 C-27X Sump ................................................................................................... 41
9.0 Bear Island ......................................................................................................... 42
9.1 Phase II Environmental Site Assessment ........................................................ 42
9.2 Groundwater Monitoring and Sampling and Surface Water Sampling ............. 43
9.2.1 Bear Island East Sump ............................................................................ 43
9.2.3 Bear Island East – Other Sites ................................................................. 43
Photo 2 Refinery Bank Gathering Systems Before & After Upgrades .................................... 14
Photo 3 B-38X DPE Remediation Area West of Mainland Tank Farm ................................... 19
2013 Norman Wells Abandonment and Restoration Annual Report Page iii
Tables
Table 1 Soil Analytical Results: General and Salinity
Table 2 Soil Analytical Results: Petroleum Hydrocarbons (PHC)
Table 3 Soil Analytical Results: Metals and Trace Elements
Table 4 Monitoring Well Datum and Groundwater Surface Elevations
Table 5 Water Analytical Results: Field Measurements
Table 6 Water Analytical Results: Indicators and Nitrogen Parameters
Table 7 Water Analytical Results : Petroleum Hydrocarbons and Phenols
Table 8 Water Analytical Results: Dissolved Metals and Trace Elements
Table 9 Water Analytical Results : Polycyclic Aromatic Hydrocarbons (PAH)
Figures
Figure 1 Site Location Map
Figure 2 Site Work Areas
Figure 3A Mainland East and Mainland Sumps
Figure 3B Former Refinery Area
Figure 4 B-38X Area
Figure 5 Town Lease Locations
Figure 6 Mainland Central Area
Figure 7 Mainland West Area
Figure 8 Bear and Frenchy’s Islands
Figure 9 Goose Island
Appendices
Appendix A Background Conditions
Appendix B Determination of Soil Geochemical Background and Glossary of Soil
Quality Parameters
Appendix C Determination of Groundwater Geochemical Background and Glossary of
Groundwater Quality Parameters
Appendix D Norman Wells A&R Work Areas Summary
Appendix E List of Acronyms, Abbreviations and Definitions
This report has been prepared to meet condition Part H, Section 6 of Norman Wells
Water License S03L1-001 and to provide the Sahtu Land and Water Board (SLWB) with
a status update of abandonment and restoration activities at the Imperial Oil Resources
(IOR) Norman Wells site, as indicated on Figure 1. Abandonment and Restoration
activities at the Site are managed by Imperial Oil Environmental Services (IOES).
1.1 Objective
The objectives of the Norman Wells Abandonment and Restoration (A&R) Program
Annual Report are threefold:
• to provide the SLWB with a status update of the overall A&R program;
• to help regulatory inspectors assess alignment of A&R activities with commitments
made in A&R plans previously approved by the SLWB; and
• by addressing the above two objectives, to meet the Terms and Conditions
(Part H, Section 6) of the Norman Wells Water Licence SO3L1-001 to provide
such information.
IOES has a formal occupational health management system in place for all work
completed at the IOR lease in Norman Wells. Specifics of this management system are
not discussed in this report. This section is intended to identify situations that are
periodically encountered during abandonment and restoration activities, but are not
normally encountered in the context of typical IOES work at the site, such as:
• asbestos;
• lead;
• PCBs; and
• mercury.
The management and removal of these materials has been described in previous
reports. None of these materials were encountered in the 2013 work program.
In addition to the above noted special materials management requirements, IOES
applies a comprehensive set of occupational health and safety standards, protocols and
procedures to every task undertaken at the Norman Wells site. Of particular note are the
extensive ground disturbance procedures that are undertaken prior to conducting any
intrusive drilling or excavation activities associated with the A&R program. All lead
project personnel are trained and certified in ground disturbance procedures and each
ground penetration location is typically surveyed and cleared by two independent survey
companies, to ensure all underground infrastructures within 30 m of the work area have
been identified and clearly marked. Where necessary, infrastructure is exposed to
confirm locations before drilling or excavation is initiated.
3.1 General
IOES has proposed that clean-up criteria for the Norman Wells site be consistent with
established Canada-wide standards as defined by the Canadian Council of Ministers of
the Environment (CCME). Given the northern setting of Norman Wells and certain
unique aspects of the site (discontinuous permafrost, presence of natural oil seeps), the
CCME concept of risk-based closure is deemed to represent the most appropriate
clean-up standard for the Norman Wells A&R program.
The above recommendation for adherence to CCME risk-based standards is proposed
for all A&R sites addressed elsewhere in this report. Any reference to guidelines in this
document refers to CCME standards, unless otherwise identified.
For the purposes of this report and as interim remediation targets, analytical results are
compared to existing contaminated site assessment and remediation criteria, as well as
background soil and water conditions. Relevant background information related to
natural seeps is located in Appendix A, while background geochemical parameters are
described in Appendix B (soil) and C (groundwater). Any reference in this report to
background conditions is described below or in these appendices.
The Government of the Northwest Territories (NT) has adopted the soil criteria
established by the CCME (1999 and updates), which are based on specific land uses
(agricultural, residential/parkland, commercial and industrial). However, the NT
Contaminated Site Guidelines were published in 2003, CCME has subsequently revised
and updated numerous guidelines for soil and water quality. Consequently, current
CCME Canadian Environmental Quality Guidelines (CEQG) are considered appropriate.
Soil analytical results have been compared to the CCME CEQG Soil Quality Guidelines
for the Protection of Environmental and Human Health and to the CCME Canada-wide
Standards for Petroleum Hydrocarbons (PHC) in Soil (PHC F1 to F4 only). Appropriate
land uses under the CCME framework have been applied as follows:
• for comparison of soil analytical data from A&R work conducted on the mainland
portion of the Norman Wells lease, CCME CEQG guidelines for industrial land use
have been adopted; and
• for comparison of soil analytical for A&R activities on Bear and Goose Islands as
well as some in Town sites, CCME residential/parkland guidelines are more
consistent with the expected end land use.
At present, no specific groundwater quality guidelines exist for the NT. As a conservative
measure, groundwater and surface water quality assessment parameters in this report
and the A&R program in general are compared to the CCME Freshwater Aquatic Life
(FWAL) guidelines as well as background groundwater quality conditions where
available. It is important to note that exceedances of the CCME FWAL values do not
necessarily indicate a facility-related source, and may reflect natural conditions.
Details of the background wells and calculated background geochemistry for the three
distinct hydrogeological units listed above are described further in Appendix C.
Each year additional water samples are collected from selected background locations
and added to the database. Results are reported in the attached data tables. The
statistical background values for groundwater first calculated in early 2013, and provided
in Appendix C, remain unchanged from the 2012 report. As additional data is compiled,
the information will be periodically reviewed to determine whether the statistical
background data requires updating.
The following sections detail the 2013 A&R Program. A brief description and summary of
work completed prior to and during 2013 is provided for each sub-area on the Norman
Wells site. Portions of the site that did not have work done as part of the 2013 program
have been omitted from this annual report but are included in the summary table in
Appendix D. The primary Norman Wells site areas are illustrated on Figure 2.
The summary table in Appendix D outlines the start date and current status of various
A&R activities undertaken at each Norman Wells sub-area between 1996 and present
day.
In accordance with the Water Licence terms and conditions (Part H, items), the following
table (Table B) lists abandoned well heads and sumps, their current status and planned
mitigation.
Well A-45X Mainland Well abandoned, cut and Minor delineation and
East capped in 2009, excavation work planned
infrastructure removed, for 2014-2015. Preparation
remediation of impacted to close out lease and
soil to Residential/Parkland return property to
guidelines undertaken in productive use
2010 and 2012. Phase 2
ESA with additional
delineation completed in
2013. Remedial excavation
completed in 2013.
Refinery Bank Mainland Ongoing remediation Continued remediation
East activities. Phase 2 ESA with activities. Continued
additional delineation groundwater monitoring
completed in 2013.
Mechanical upgrades to
remedial systems ongoing.
The following table (Table C) summarizes the active piezometers in each of the Norman
Wells areas current to August 2013. These piezometers constitute part of the monitoring
program for areas where abandonment and restoration activities have occurred, are
ongoing or are anticipated to occur.
Phase 2 ESA drilling during 2013 included 49 shallow soil boreholes, 36 of which were
completed as new shallow groundwater monitoring wells and seven as Thermistor
locations. Drilling focused on areas where data gaps had been identified from previous
investigations.
It should be noted that due to the significant ice scouring effects on the Mackenzie River
shoreline during spring ice breakup, piezometers installed within 100 m of the river may
be subject to damage or destruction each year. The exact number of piezometers
monitored, therefore, may change from year to year.
The Mainland East area on the Norman Wells lease includes the land area bounded by
the Town of Norman Wells on the east, the former Battery #3 site to the west, the
Mackenzie River to the south, and the site access ring road to the north (Figure 3A).
Geophysical surveys to assess terrain conductivity related to potential saline shallow
groundwater or buried metal, soil and/or groundwater sampling activities and thermistor
installation for the assessment of shallow permafrost conditions were conducted at the
following Mainland East target areas in 2013:
• Refinery:
− Refinery Bank; and
− Former Reduced Crude Flare Pit (RCFP).
• B-42X Well Site;
• B-38X Well Site:
− Former Fire Training Area (FTA);
− Land Terminal #7 (LT7) area; and
− East of B-38X well.
• Mainland Tank Farm;
• Town Sites (A45X Well Site); and
• Cemetery Sumps.
The following subsections provide summaries for areas where A&R activities were
undertaken in 2013.
5.1 Refinery
The Norman Wells Refinery was located on the north bank of the Mackenzie River on
the east side of the Norman Wells lease area (Figure 3B). It began operation in 1921,
processing crude oil from the Norman Wells oilfield until May of 1996 when IOR
announced that the facility would close. The Phase I and Phase II ESA A&R Plans for
the facility were submitted by IOR in 1998 and 1999, respectively and approved by the
SLWB in 2001. Initial A&R work on the Refinery site began in 1996 with
decommissioning and dismantling activities, followed by environmental assessment,
characterization and development of a remediation and reclamation plan. In 2002, soil
remediation activities were initiated. In 2003, an in situ groundwater containment and
hydrocarbon remediation system was commissioned on the Refinery Bank.
The 2013 A&R program for the former Refinery site included the following activities:
• continuation of in situ groundwater containment and remediation systems at the
Refinery Bank area;
The 2013 Phase 2 ESA investigation focused on the Refinery Bank area, to characterize
and monitor current soil and groundwater conditions down-gradient from the in-situ
remediation system. Results of the drilling investigations in this area are provided below
in Section 5.1.2.
Additional bedrock monitoring wells installed in 2009 on the upper Refinery Bank
indicated that facility-related hydrocarbon impacts are now effectively delineated to the
north. Guideline exceedances of nitrogen species, arsenic, cadmium, copper, selenium
and phenols confirmed from sampling deeper groundwater were consistent with
background conditions. Wells monitored for groundwater chemistry in this area in 2010
and 2011 effectively delineated dissolved hydrocarbon impacts on the perimeter of the
free product hydrocarbon distribution on the Refinery Bank.
Liquid hydrocarbons consisting of both refined light-end free product and
naturally-occurring crude oil seepage are present on the Refinery Bank. A total of
26 monitoring and remediation wells in this area contained free product hydrocarbon
during the 2012 and 2013 programs.
Activity related to the Refinery Bank remediation area during 2013 included
measurement of fluid levels in wells (groundwater depth and hydrocarbon thickness,
where present), lab analysis of hydrocarbon vapours in gas samples from the MPE off
gas, and water sampling for lab analysis from the submersible pump effluent.
A number of repairs, upgrades, and modifications to the groundwater pumping system
were undertaken during 2012 and 2013. These included resolution of instrumentation,
software, and hardware problems. Due primarily to heating and pipe insulation problems,
Borehole and monitoring well locations are shown on Figure 3B, while analytical results
are presented in Tables 1 through 3.
Activity related to the B-38X and FTA area remediation systems during 2013 included
measurement of fluid levels in wells (groundwater depth and hydrocarbon thickness,
where present), lab analysis of hydrocarbon vapours in gas samples from the DPE off
gas, and water sampling for lab analysis from the diaphragm pump effluent.
The dewatering pumps and DPE blower operated periodically for a period of 40 days
from July to October 2013. The run time and hydrocarbon mass removal totals were
limited due to software issues and equipment problems, particularly related to a faulty air
compressor. Engineering re-design of these components is ongoing, while repairs and
enhancements to the systems will be in place by fall 2014.
Over 55,000 kg of hydrocarbon, equivalent to more than 71.5 m3 of hydrocarbon LNAPL,
has been recovered by the DPE in-situ remediation system to date.
Ex-situ soil remediation work has previously been completed nearby in soils not suitable
for in-situ treatment. In 2007, an estimated 2,000 m3 of hydrocarbon impacted soil was
excavated from the B-38X buried pit area located 150 m west of 8-bay. The impacted
soil was transported to an on-site biocell for treatment. This soil was subsequently
tracked and re-used as industrial fill material on site.
Monitoring well locations are shown on Figure 4. Groundwater field measurements and
analytical results are presented in Table 4 through 8.
• the testpit investigation indicated that contaminants of concern for the excavation
area included PHC F1, F2 and F3;
The Mainland Central area on the Norman Wells lease includes the land area bounded
by Bosworth Creek and the barge dock area on the west, the former Battery #3 site to
the east, the Mackenzie River to the south and the site access ring road to the north
(Figure 6).
A&R work in 2013 included Phase II ESAs, groundwater and surface water sampling,
remedial excavations, recontouring, closure monitoring and preparation of remedial
action plans. A&R work was conducted at the following sub-areas in 2013:
• Battery #3;
• Bosworth Creek;
• Biocell;
• ARB and B-33X;
• B-30X Well Site;
• Background/Control Point Locations;
• Tank 401 Area; and
• Tank 53 Area.
The following subsections provide summaries for areas where A&R activities were
undertaken in 2013.
6.1 Battery #3
The former Battery #3 site is located on the east side of Bosworth Creek, approximately
200 m north of the Mackenzie River. The Battery was operational from the 1940s until
circa 1990. A&R activities on the site started in 1997 with decommissioning and
dismantling, followed by detailed site characterization (geophysical surveys, soil and
groundwater investigations). The Battery #3 area includes a former flare pit area and a
former tank farm area.
The 2013 A&R activities included groundwater monitoring and sampling as summarized
below.
A Remedial Action Plan (RAP) has been developed to address hydrocarbon, salinity and
metals impacts found in the Battery 3 Flare Pit area. The work is expected to commence
in 2015. It is anticipated that approximately 2100 m3 of impacted soil will be removed.
The soil is considered unsuitable for biotreatment and will require disposal at an
appropriate facility. Backfill with appropriate soils, surface reclamation and restoration
activities will commence once the excavation is complete.
The existing network of groundwater and surface water sampling locations around BT3
and the nearby (down-gradient) Bosworth Creek will continue to be analyzed as part of a
long term monitoring program to assess if remedial objectives have been met.
2013 A&R activities included advancing three boreholes using a hand auger method and
installation of drivepoint monitoring wells at these locations, groundwater sampling and
surface water sampling. A summary of the 2013 A&R activities is included below.
Borehole and monitoring well locations are shown in Figure 6. Analytical results are
presented in Tables 1 and 2.
Well locations are shown on Figure 6. Groundwater field measurements and analytical
results are presented in Tables 4 through 8.
• all samples submitted to the laboratory for analysis of inorganic and major ion
parameters returned results below applicable CCME guidelines;
• soil samples collected from one borehole location (ARB-13-6) had PHC F2
and/or F3 concentrations exceeding the applicable CCME guidelines; and
• soil samples collected from one borehole location had As and Ni concentrations
exceeding the applicable CCME guidelines.
Remedial Activities
A remedial action plan developed for the ARB-Biocell area has identified approximately
13,750 m3 of hydrocarbon impacted soil to be removed. The excavation activities are
intended to be completed over two seasons. The purpose of the 2013 field program was
to remove and treat the impacted area between the Biocell and the Well Services Yard
warehouse access road. The 2013 activities are summarized below:
• approximately 3,240 m3 of clean overburden soil was removed from the area and
used or stockpiled elsewhere on site;
• approximately 2,600 m3 of impacted soil exceeding CCME Industrial land use
guidelines was removed from the excavation and placed in on site biocells for
treatment; and
• the excavation was backfilled using approximately 5,883 m3 of material sourced
from previously removed clean overburden, clean treated material and material
sourced from the local quarry and claypit.
In 2001, IOR constructed two synthetically-lined, engineered biocells for batch treatment
of hydrocarbon-affected soils. These soils are transported to the biocell from various
locations across the field, after they have been appropriately characterized and deemed
suitable for bioremediation, based on evaluation of organic and inorganic soil chemistry.
In 2012 the two original biocells were decommissioned and replaced with a single larger
capacity engineered biocell.
The 2013 scope of work for the Biocell included the following activities:
• collect representative soil samples from each source material prior to Biocell
acceptance and treatment;
• direct transport to and treatment of hydrocarbon impacted material not meeting
Industrial land use guidelines in the Biocell in accordance with the Biocell
Operations Guidance Manual;
• direct addition of fertilizer amendments as required;
• collect representative soil samples from each windrow after treatment sessions;
• submit soil samples to an analytical laboratory;
• assess lab data to determine when remedial objectives are achieved; and
• direct removal and transport of material meeting Industrial land use guidelines
from the Biocell to a stockpile location for future use as fill.
Windrows were treated (twisted) using an excavator mounted twister bucket. Twisting
homogenizes and exposes soil to air, which volatilizes light end petroleum hydrocarbons
(PHCs) containing carbon chain lengths (C) generally less than C10 (benzene, toluene,
ethylbenzene, or total xylenes [BTEX] and PHC F1). Twisting also incorporates oxygen,
which encourages aerobic biological degradation of PHCs from the C10 to C34 range
(PHC F2 and F3).
The level of available nutrients for bacterial activity was monitored through analysis of
soil samples. The aim is to achieve a Carbon: Nitrogen: Phosphorous ratio of 100:2.5:1.
Generally if nutrient levels fall to a point that they are potentially inhibiting bacterial
growth nutrients are added through the use of Urea and/or mono-ammonium phosphate
(MAP) fertilizer incorporated in the windrows using the twister bucket. Soil which has
salinity parameters (EC) close to the acceptance guidelines should be amended with
fertilizer in phases, or not at all, to prevent creating a soil salinity issue.
During the 2013 field season (July to October 2013), an estimated 1,015 m3 of soil was
processed in the Biocell to meet applicable CCME industrial use guidelines, and was
subsequently transferred to various locations on the Site as fill. The treated soil
originated from excavations on Bear Island (M-43X and BI-1X), Goose Island (O-18X),
In 2013, no lab analysis was conducted on the biocell sump water as there was no
discharge to the watershed planned. All the sump water was disposed of at the F-31X
wastewater injection facility. An estimated total of 460 m3 of fluids were removed from
the Biocell sumps in 2013.
The Biocell contained an estimated 5,070 m3 of PHC impacted soil in varying stages of
treatment, as of December 2013. Further treatment of these windrows will be required in
2014 to meet applicable guidelines. Impacted soils remaining in the Biocell were sourced
from the O-18X, Q-06X, M-43X, D-42X/E-35X, and ARB excavations.
The Mainland West area on the Norman Wells lease includes the land area bounded by
Bosworth Creek and the barge dock area on the east, the J-16X well site to the west, the
Mackenzie River to the south and the site access ring road and fire break to the north
(Figure 7).
In 2008, IOR initiated a multi-year Phase 2 Environmental Site Assessment (ESA)
program, to investigate target areas identified by the Phase 1 ESA completed in 2008.
Target areas included historical spill sites, former pits and ponds, former dump sites,
locations of former infrastructure (e.g. storage tanks, batteries, garages, camp sites) and
well sites. No further intrusive investigation was conducted in 2013 for the assessment
areas discussed in Section 7.
A&R work was conducted at the following sub-areas in 2013:
• E-27X Well Site (E27);
• F-28X Well Site (F28); and
• Mainland West Background Locations (MWBG).
Two other sub-areas within Mainland West, the C-27X Sumps and Cemetery Sump
areas, are discussed in sectons 8.2 and 8.3, respectively.
The following subsections provide summaries for areas where A&R activities were
undertaken in 2013.
There are currently four groundwater monitoring wells (F28 series in Table 4) associated
with the F-28X area. Results of the 2013 sampling program are summarized as follows:
• based on local topography and proximity to the Mackenzie River, groundwater
flow direction is inferred to be south towards the river;
• one monitoring well could not be located and is presumed to have been
destroyed; and
• the remaining three monitoring wells contained measurable LNAPL and were
subsequently not sampled for laboratory analysis.
There are three former sump areas on the Mainland that were assessed as part of the
2013 A&R program.
Environmental assessment activities to date at the various sump sites have included soil
sampling by drilling and test pitting, installation and sampling of groundwater monitoring
wells and more recently surface water sampling at ponded areas on the capped sumps.
Mainland area sumps included in the A&R program are as follows:
• Mainland Sumps (Figure 3A); an area which collectively includes the Mainland
Drilling Sump (MDS), Well Services Sump (WSS); and six other smaller Mainland
Sumps;
• Cemetery Sump (Figure 7); and
• C-27X Sump (Figure 7).
Sump Capping
The most northerly of the Mainland Sumps was dewatered and capped in 2013.
Approximately 785 m3 of fluids were removed from the sump and disposed of on site.
Approximately 210 m3 of soil was imported to cap the sump. The area was contoured to
shed water. Further restoration work is expected to be undertaken in 2014.
Closure Monitoring
The areas currently undergoing restoration in the Cemetery Sump area were visually
assessed as part of an ongoing closure monitoring program. No signs of plant distress or
ground surface stability issues were identified.
• two chloride concentrations exceeded the both the applicable FWAL guideline
and the expected background chloride value;
• one monitoring well returned concentrations of dissolved nitrite and dissolved
nitrate which exceeded the respective FWAL criteria and background;
• reported total phenols concentrations exceeded the FWAL guideline at two
monitoring wells, with the value from CEM 09-3-2 also exceeding expected
background for phenols;
• dissolved metals and trace elements exceeding FWAL guidelines in one or more
piezometer included Cu, Fe and U. The concentrations for all three parameters
exceeded expected background values; and
• two surface water samples were collected from marshy areas north of the
Cemetery Sump. These samples yielded one guideline exceedance for total
phenols, two exceedances for total Fe and one exceedance for total As. All of
these exceedances, with the exception of Fe at one location, remained within
expected background ranges for surficial sediments.
Monitoring well locations are shown in Figure 7. Groundwater field measurements and
analytical results are presented on Tables 4 through 8.
Bear Island (Figure 8) is one of two natural islands included in the IOR Norman Wells
lease area and is a vital part of the current production field. Bear Island is located
relatively close to the south bank of the Mackenzie River and is accessible by crew boat
or barge in summer, ice road in winter or helicopter for the remainder of the year.
In 2008, Imperial Oil initiated a multi-year Phase 2 ESA program to investigate target
areas identified by a Phase 1 ESA completed in 2008. Target areas included historical
spill sites, former pits and ponds, former dump sites, locations of former infrastructure
(e.g. storage tanks, batteries, camp sites, etc.) and well sites.
Geophysical surveys, soil and/or groundwater sampling have been conducted at the
following Bear Island target areas (Figure 8):
• Background/Control Point Locations (3);
• Bear Island Well 1X Drill Pad (BIDP);
• Q-Pad Area (former tank farm area BIBT1);
• Bear Island Flare Pit (BIFP); and
• Former Drilling Sumps 1 through 6
Assessment work continued in 2013 included further Phase II ESA investigation,
groundwater and surface water sampling. A&R work conducted on Bear Island in 2013 is
summarized in the following sections.
Goose Island (Figure 9) is the second natural island included in the IOR Norman Wells
lease area, and is a vital part of the current production field. Goose Island is seasonally
inundated with river ice and water, creating a challenging work environment for both
industrial and environmental activities. Vehicle access is typically limited to a few months
each year.
In 2008, IOR initiated a multi-year Phase 2 Environmental Site Assessment (ESA)
program, to investigate target areas identified by the Phase 1 ESA completed in 2008.
Target areas included historical spill sites, former pits and ponds, former dump sites,
locations of former infrastructure (e.g. storage tanks, batteries, garages,
camp sites, etc.), and well sites.
No A&R activities were conducted Goose Island in 2013. The monitoring wells were
sampled under the IOR Operations program.
Frenchy’s Island (Figure 8) is the third natural island included in the IOR Norman Wells
lease area. Located east of Bear Island, the western tip of Frenchy’s Island is seasonally
inundated with river ice and water, creating a challenging work environment for both
industrial and environmental activities. Vehicle access is typically limited to a few months
each year.
In 2010, Imperial Oil initiated a Phase 2 ESA program in this area, to investigate target
areas identified by the Phase 1 ESA completed in 2008.
Groundwater sampling was not conducted on Frenchy’s in 2013, as the previously
installed monitoring wells have been destroyed by ice scouring. No A&R work was
conducted on Frenchy’s Island in 2013.
Several research based initiatives were completed in 2013 and on-going research is
planned for 2014. One area of ongoing research focuses on understanding plant and
invertebrate eco-toxicity in relation to specific petroleum hydrocarbon sub-fractions in
soil. There is currently no guidance published in the Northwest Territories for risk-based
development and application of eco-contact guidelines for use in establishing
remediation objectives and/or to meet site closure requirements. The approach to
derivation of site-specific eco-contact guidelines for PHC F3 for the Norman Wells field is
thus been based on the “weight of evidence” approach outlined by CCME. The
guidelines being developed are to be protective of plants and invertebrates native to the
area and reflective of the typically aged and/or weathered nature of hydrocarbons in soil
and bioremediated soils at Norman Wells.
Progress to date for both plant and invertebrate programs is summarized below and
planned work is briefly described.
Plans for 2014 include range finding tests conducted by the Saskatchewan Research
Council (SRC) in consultation with WorleyParsons for the assessment of hydrocarbon
sensitivity of select plants. Following the range finding tests a more detailed definitive
Imperial Oil Environmental Services is in the process of planning the 2014 A&R program
for Norman Wells, based on information gathered from the 2013 and previous programs.
It is anticipated that the following activities will be part of the 2014 program:
• the groundwater monitoring program conducted in 2013 will be optimized and
continued in 2014;
• the groundwater pumping, MPE and DPE remediation systems at the Refinery and
B-38X sites, respectively, will continue operation in 2014 and be optimized and
upgraded as required;
• development of long term management strategy for the mainland sumps area.
Draining and backfiling of select sumps;
• the biocell will be operational, and impacted soil suitable for on site biotreatment
will be treated until soil meets CCME Industrial land use guidelines;
• expansion of the Biocell to double capacity for on site biotreatment of soils;
• remedial excavations are planned for the ARB area south of the biocell, the BIBT1
area on Bear Island, the former flare pit on Bear Island and the former Battery #3
flare pit;
• vegetation cover and physical stability monitoring will continue at the Well Services
and Mainland Sump areas, the Reduced Crude Flare Pit, the B-38X Buried Pit, the
Tank 53 Area, the Cemetery Sump Area, the Tank 401 area and the East Bank of
Bosworth Creek;
• wellhead cut and cap and well site Phase 2 investigations will be conducted at O-
29X, B-42X, E-33X and E-27X);
• enhancement works of Bosworth creek bank including stabilization and
revegetation;
• supplementary Phase 2 assessment and/or Phase 3 delineation sampling will be
conducted at the Mainland Sumps, the Cemetery Sump, the C-27X Sump, the
B-30X well site, the Bear Island Sumps and the BIBT1 site; and
• key research programs related to ecotoxicity and thermistors will continue.
Appendix D provides a list of historical and on-going A&R program activities.
Background Information
Introduction
The following information is provided to document background environmental conditions
at the Norman Wells site, as they are understood based on currently available data. This
information provides the rationale for differentiating naturally occurring conditions from
suspected anthropogenic impacts at the site, particularly with respect to soil and water
quality parameters and concentrations.
Geophysics
Background geophysical conditions were established north of the J-16X Well Site at the
western perimeter of the mainland lease. Results of this survey indicated that permafrost
was generally represented by terrain conductivity values of between 1 and 10 mS/m.
Bedrock (Canol Shale) was represented by terrain conductivity values of up to
200 mS/m. Unfrozen overburden was generally represented by terrain conductivity
values of approximately 20 mS/m. Terrain conductivity values in the unfrozen
overburden that were significantly greater than 35 mS/m were subsequently targeted for
intrusive investigations to confirm the source(s).
REFERENCES
Hume, G.S. and Link, T.A., 1945. Canol Geological Investigations in the Mackenzie River
Area, Northwest Territories and Yukon. Geological Survey of Canada Paper,
45-16.
Link, T.A., 1920. Geological Report on the Ft. Norman Oil Field. Unpublished report
prepared for Imperial Oil Limited.
There were insufficient samples to characterize Islands Surface Organic Soil, and no
bedrock was encountered or sampled during intrusive investigations on the Islands.
The data summarized in Table App-B2 (provided in this appendix) have been screened
against generic contaminated sites guidelines for fine-grained soils that were selected to
be a conservative screening tool for the likely post-industrial use of the Norman Wells
Field. Maximum parameter concentrations as well as 95th percentile concentrations
have been provided for each stratigraphic unit when sufficient data were available for
statistical analysis. This land use assumes Imperial Oil will maintain ownership of the
land but will not prevent occasional access by people or wildlife and as such is modified
from CCME Industrial and Residential/Parkland land use conceptual models. In general
terms, the Industrial land use guidelines were applied to Mainland areas, whereas
Residential/Parkland guidelines were applied to the Natural Islands (Bear, Frenchy’s and
Goose). The majority of the soils assessed at the Norman Wells Site were determined to
be fine-grained, especially on the Mainland and Bear Island. On Goose Island, both
coarse and fine-grained alluvial deposits have been identified.
It is also noteworthy that concentrations of one or more BTEX and PHC parameters
below the applicable CCME guidelines were present in all of the samples analyzed.
In general, it is not uncommon to find elevated hydrocarbon and metals concentrations
in association with peat/organic material at the Site. Metals tend to bond strongly to
organic matter, and the lower pH of the peat may also increase metals concentrations in
pore water. The elevated EC values are not associated with chloride, a typical indicator
of industrial impact. Based on the available data set, it is considered likely that the above
listed parameters and concentrations are naturally occurring.
ISLANDS
Reported metals concentrations for Island mineral surface soils were within generic
guidelines.
In addition to the above noted guideline exceedances at background locations,
concentrations of one or more BTEX and PHC parameters below the applicable CCME
guidelines were present in all of the samples analyzed. Maximum reported values for
Island Surface Soil included: Benzene (0.0025 mg/kg), Toluene (0.01 mg/kg),
Ethylbenzene (0.019 mg/kg), Xylenes (0.087 mg/kg), PHC F1 (14 mg/kg), PHC F2
(72 mg/kg), PHC F3 (370 mg/kg) and PHC F4 (140 mg/kg). The naturally occurring
levels of PHC F3, in particular, should be considered when determining appropriate soil
remediation objectives relative to background conditions.
The few locations with EC values above CCME Parkland guidelines are not associated
with chloride, a typical indicator of industrial impact. Based on the available data set, it is
considered likely that the above listed parameters and concentrations are naturally
occurring.
Siltstone
Samples of the weathered siltstone bedrock encountered in the majority of sampling
locations on the Mainland were collected from four background locations. A total of eight
samples have been analyzed to date for chemical analyses, including:
• detailed salinity (pH, electrical conductivity [EC], major soluble ions [calcium,
sodium, magnesium, potassium, sulphate and chloride], and sodium adsorption
ratio [SAR];
• trace elements and metals (antimony [Sb], arsenic [As], barium [Ba], beryllium
[Be], boron [B], cadmium [Cd], chromium [Cr], cobalt [Co], copper [Cu], lead [Pb],
mercury [Hg], molybdenum [Mo], nickel [Ni], selenium [Se], thallium [Tl], uranium
[U], vanadium [V], and zinc [Zn];
• petroleum hydrocarbon fractions 1 through 4G (PHC F1 through F4G);
• benzene, toluene, ethylbenzene and xylenes (BTEX); and
• polycyclic aromatic hydrocarbons (PAHs).
Analytical data are summarized in Table App-B2. The analyzed parameters which were
measured at concentrations/levels exceeding the generic CCME soil quality guidelines
included:
th
Parameter Range of Values 95 Percentile Value
SAR 0.28 to 26 17.9
As 7.6 to 24 mg/kg 23 mg/kg
Ni 22 to 64 mg/kg 63 mg/kg
PHC F2 5 to 1200 mg/kg 899 mg/kg
PHC F3 58 to 2900 mg/kg 2144 mg/kg
Shale
As noted above, shale bedrock from the Town of Norman Wells quarry located to the
northeast of the IOL Site has been extracted for use as fill material both on the Site and
throughout the developed Town site.
To date, a limited number of shale samples have been collected for laboratory analysis
for the purpose of characterizing background conditions. These samples were obtained
from the Town of Norman Wells quarry rather than the Site, to minimize the potential for
industrial effects. Additional investigations are on-going into the potential for this shale fill
to affect underlying and adjacent soil and/or water chemistry.
Analytical results for four shale samples have been included in this background
characterization section. The analysis included pH, and trace elements/metals.
Analytical data are summarized in Table App-B2. The analyzed parameters which were
measured at concentrations/levels exceeding the generic CCME soil quality guidelines
included:
th
Parameter Range of Values 95 Percentile Value
As 7.19 to 42.9 mg/kg 39.6 mg/kg
Mo 29.8 to 66.4 mg/kg 64.7 mg/kg
Se 4.38 to 7.9 mg/kg 7.56 mg/kg
Tl 0.88 to 2.33 mg/kg 2.29 mg/kg
Summary
From the review of the available background data, some general trends are apparent:
• concentrations of one or more metals/trace elements (As, Mo, Ni, Se, Tl and Zn)
exceeding CCME guidelines have been confirmed in background organic surface
soil, mineral subsurface soil, and underlying siltstone bedrock on the Mainland.
• concentrations of As, Mo, Se and Tl exceeding CCME guidelines have also been
confirmed in shale bedrock samples collected from the Town of Norman Wells
quarry. This shale material is used as fill throughout the Site and the adjacent
Town.
• above guideline SAR values have been measured/calculated for a limited number
of mineral subsurface soil samples on the Mainland, as well as the siltstone
bedrock.
• in the Island soils, background metals concentrations in surface mineral soil are
typically below CCME Parkland use guidelines. However, several metals (As, Mo,
Se, Tl) may be present at concentrations above guidelines in the subsurface soil.
Calcium (Ca) and Calcium and magnesium naturally present in soil result from the
Magnesium (Mg) weathering of Ca and Mg-rich rocks. These parameters are not usually
indicators of contamination in soil. There are no current regulatory
guidelines for Ca or Mg in soil. Soluble salt levels are measured and
monitored indirectly through the EC parameter noted above.
Sodium (Na) Sodium is a naturally occurring element; however, if present in large
concentrations, soil structure can be adversely affected. There is no
current regulatory guideline for sodium levels in soil – this parameter is
usually measured indirectly through the SAR ratio noted above.
Potassium (K) Potassium is an essential nutritional element for humans, animals and
plants, and is naturally occurring in soils. However, at high concentrations
(>100 milligrams per litre (mg/L)) this constituent may be an indicator of
spills of specific materials such as drilling muds/fluids. There is no current
regulatory guideline for potassium in soil. Soluble salt levels are measured
and monitored indirectly through the EC parameter noted above. Optimum
available potassium levels for good plant growth should be around
200 parts per million (ppm).
Chloride (Cl) Higher chloride levels in soil (i.e. >500 mg/L) can be an indicator of
industry related impact; as this constituent is not usually present at high
concentrations in a natural non-marine, non-saline environment. However,
in marine or naturally saline environments, high concentrations
(>1,000 mg/L) of chloride may be common in soils. There is no current
regulatory guideline for chloride in soil. Soluble salt levels are measured
and monitored indirectly through the EC parameter noted above.
Sulphate (SO4) High concentrations of soluble sulphate in soils (i.e. >1,000 mg/L) are
usually an indicator of naturally occurring salinity. There is no current
regulatory guideline for sulphate in soil. Soluble salt levels are measured
and monitored indirectly through the EC parameter noted above. Optimum
levels of sulphate for good plant growth are around 10 ppm available
sulphate.
Nitrate and Nitrite Nitrate and nitrite occur in natural and contaminated soil. Common
(NO3 and NO2) sources include food preservatives, commercial fertilizers, sewage and
manure. Nitrate presence in soil is essential for plant growth; optimum
levels are plant-specific, but should generally be around 40 ppm available
nitrate.
Metals Metals in soil naturally result from the weathering of mineral and rock
fragments present in the subsurface. Industry related sources may include
commercial fertilizers, sewage, drilling fluids/muds, process waters,
industrial combustion and smelting activities. When present at high
concentrations, some metals can be toxic to plants and soil
micro-organisms. At northern sites, metals are of particular importance as
certain constituents (e.g. arsenic, molybdenum, nickel, selenium) occur
naturally at high concentrations due to the bedrock geochemistry. There
are a number of metals that are currently regulated by NT and CCME as
listed below, along with the respective CCME (1999 and updates)
Parkland and Industrial guideline concentrations, and interpreted
background levels in milligrams per kilogram (mg/kg).
SOIL - HYDROCARBONS
Petroleum Petroleum products such as crude oil, jet fuel, and heating oil contain
Hydrocarbon numerous compounds in varying proportions. For the purpose of
Fractions regulating these compounds, CCME (2008) and NT have classified the
1 (PHC F1), hydrocarbons on the basis of specified ranges of carbon present. For
2 (PHC F2), soils, petroleum hydrocarbon fractions (PHC) include F1 (C6 to C10
3 (PHC F3) and excluding BTEX), F2 (>C10 - C16), F3 (>C16 - C34), and
4 (PHC F4) F4 (>C34 - C50+). Due to the more complex molecular structure, these
compounds tend to be less soluble than the lighter hydrocarbons, such as
the BTEX components. As soil texture is one of the primary factors
governing hydrocarbon migration through soil, regulatory guidelines have
been recommended for both fine- and coarse-grained soil as defined by
having a median grain size <75 µm (fine) or >75 µm (coarse).
The CCME PHC guidelines for soil are currently set as follows for
Parkland and Industrial land uses (based on ecological soil contact
pathway).
REFERENCES
CCME (Canadian Council of Ministers of the Environment), 1999 and updates. Canadian
Environmental Quality Guidelines. Updated September 2007.
CCME (Canadian Council of Ministers of the Environment), 2008. Canada-Wide
Standards for Petroleum Hydrocarbons (PHC) in Soil. Canadian Council of
Ministers of the Environment, Winnipeg. January 2008.
Determination of Groundwater
Geochemical Background and Glossary
of Groundwater Quality Parameters
DETERMINATION OF GROUNDWATER GEOCHEMICAL BACKGROUND
In order to effectively evaluate the origin of groundwater parameters which may exceed
regulatory guidelines (in this case, CCME FWAL criteria), it is important to defensibly
determine naturally occurring background concentrations for the parameters of interest.
Background monitoring wells would ideally be installed in an undisturbed, up-gradient
area, isolated from any potential sources of anthropogenic impact. However, these
locations tend to be heavily influenced by permafrost in the vicinity of Norman Wells.
Previous attempts to install background wells in up-gradient areas of the lease, removed
from the IOL facilities and in areas of natural vegetation, have resulted in rapidly frozen
groundwater monitoring wells that consistently remain frozen. As such, the use of the
term “background” in this report does not necessarily mean the groundwater monitoring
well is installed in an undisturbed, up-gradient area. Rather, the term is used for
locations inferred to be removed from site facilities and free of facility-related impacts.
In an effort to improve characterization of background soil and groundwater conditions,
the 2010 and 2012 Phase 2 ESA programs focused on installation of new potential
background wells in surficial sediments. This included 6 new wells on the Natural Islands
and 5 wells distributed throughout Mainland East, Central, and West areas over the past
three years. As a result of these new wells, supplemented by annual groundwater
sampling from 1997 to 2012, a sufficient database has now been compiled to determine
a statistical background for key geochemical parameters from a range of
hydrogeological units of interest. As summarized in Table App C-1, twenty-four wells
within the monitoring network have been identified as background locations. These wells
are separated into four groups, based on the hydrogeological zone where the well
screen is completed, as follows:
• surficial sediments on Mainland (10 wells, 9 producing water, total 28 samples);
• surficial sediments on Natural Islands (7 wells, all producing water, total 20
samples);
• shallow bedrock on Mainland (3 wells, all producing water, total 21 samples); and
• deeper bedrock on Mainland (4 wells).
Data from the first three hydrogeological is of primary interest for analysis of the
environmental monitoring results collected to date. As such the statistical background
analyses concentrated on these categories. The deep bedrock category is not
characterized to the same extent, and considering that groundwater quality in the deeper
bedrock is less important for comparison to the environmental monitoring program,
deeper bedrock data will not be considered further in this discussion.
A geometric mean, minimum, maximum, and 95th percentile value for each parameter
listed below was determined for each of the three hydrogeological units of interest.
One of the key aspects of the statistical calculations is the method of dealing with results
reported below the laboratory method detection limit (MDL), which is a frequent
occurrence with some of the dissolved trace metals in particular. In order to calculate the
95th percentile value, a real number is required rather than a “less than” result. The
approach used was as follows. In cases where the MDL is the normal precision reported
for that particular parameter, then a real number value of ½ the MDL is used in the
calculation. For example, if the dissolved copper result was reported as <0.001 mg/L,
then a real number value of 0.0005 mg/L is assumed for the statistical calculations. In
cases where matrix interferences increase the MDL, this method cannot be used and the
data point is typically discarded for the purpose of the 95th percentile calculation. Note
that although this method is acceptable for 95th percentile calculations, it is much more
problematic in the calculation of geometric means (U.S. EPA Unified Guidance, 2009).
Results of the statisitical analyses are provided in Table App-C2. The following results
are of particular note in the interpretation of data in the attached report:
• The CCME FWAL water quality guidelines for a number of trace metals vary
depending on the pH and total hardness of the water (see footnotes of Table 9).
For the purpose of selecting appropriate guidelines for comparison to Norman
Wells water samples, the pH value is considered greater than 6.5, and the total
hardness as calcium carbonate (CaCO3) is greater than 180 mg/L (very hard
water). The 95th percentile value for groundwater samples from background
locations was as follows:
− surficial sediments on mainland, pH of 7.1 and hardness of 1345 mg/L;
− surficial sediments on islands, pH of 7.2 and hardness of 1681 mg/L; and
− shallow bedrock, pH of 7.8 and hardness of 254 mg/L.
• The attached analysis of background geochemistry in local groundwater has
intentionally avoided using chloride values derived from a background well which
is located within a historically documented natural seepage zone on the
Mackenzie River shore, directly south of the Former Refinery. Well NWR 03-38-3
represents a natural crude oil and saline formation water seepage zone, where
shallow bedrock subcrops within a few metres of ground surface under sediments
along the shoreline. Chloride readings from this well, on the order of 250 mg/L,
have been discounted in the determination of the 95th percentile chloride value for
surficial sediments on the Mainland.
• The 95th percentile analyses indicate that the following parameters may naturally
exceed the applied CCME FWAL criteria in groundwater at this site:
Calcium (Ca) Calcium in groundwater results from the weathering of Ca-rich rocks and
soils. It is important as a constituent or hardness (see hardness). Excess
calcium may be detrimental for domestic uses such as washing, bathing,
and laundering because of its tendency to neutralize soap and cause
encrustations plumbing fixtures. There is no set limit in the current CCME
FWAL guidelines.
Magnesium (Mg) Magnesium is also a constituent of hardness, and an essential element in
human metabolism. At high concentrations, magnesium may have a
laxative effect, particularly upon new users. Nevertheless, the body can
develop a tolerance over time. There is no direct evidence of adverse
health effects associated with magnesium; therefore no limit has been set
for Canadian drinking water. There is no set limit in the current CCME
FWAL guidelines.
Sodium (Na) Sodium is not considered to be acutely toxic to humans, and up to
5 grams/day are consumed by the average person without apparent
adverse effects. The average intake of sodium from water is only a small
fraction of that consumed in a normal diet. There is no set limit in the
current CCME FWAL guidelines.
Potassium (K) Potassium is an essential nutritional element in human metabolism.
However, at high concentrations (>1,000 mg/L) this constituent may have
laxative effects. Concentrations rarely exceed this value (in most potable
aquifers). There is no set limit in the current CCME FWAL guidelines.
Chloride (Cl) Concentrations of chloride are generally quite low in most shallow
groundwater systems. However, due to the presence of natural shallow
seeps containing hydrocarbon and associated produced water at the
Norman Wells site, significant measurable chloride can be locally present.
The current CCME FWAL guidelines is 120 mg/L chloride.
Sulphate (SO4) No serious health effects are associated with high sulphate levels. At
concentrations above 500 mg/L, sulphate may impart a noticeable taste to
the water and cause a laxative effect in occasional users. There is no set
limit in the current CCME FWAL guidelines.
Bicarbonate Bicarbonate is formed by the weathering of organic matter and
(HCO3) carbonate-bearing minerals (e.g. limestone) present in the subsurface.
The concentration of this anion in natural and contaminated waters is
related to such factors as temperature, pH, concentrations of other
dissolved solids, and biological activity. This parameter is not considered a
health hazard. There is no set limit in the current CCME FWAL guidelines.
Nitrate and Nitrite Nitrite-nitrogen (NO2) and nitrate-nitrogen (NO3) occur in natural and
(NO2 and NO3) contaminated waters. The current CCME FWAL guidelines are 0.06 mg/L
and 2.9 mg/L for nitrite and nitrate as N, respectively.
Iron and Although iron and manganese are essential elements in humans and
Manganese animals, drinking water is not considered to be an important source. At
(Fe and Mn) high enough levels these metals can stain laundry and plumbing fixtures,
and causes an undesirable taste in beverages. The precipitation of excess
iron gives an objectionable reddish-brown colour to drinking water. There
is no set limit in the current CCME FWAL guidelines for manganese. The
CCME FWAL guideline for dissolved iron is 0.3 mg/L.
Trace Metals Metals are a common occurrence in groundwater, and result from the
weathering of mineral and rock fragments present in the subsurface.
There are a number of dissolved metals, other than iron and manganese,
which are currently regulated for protection of Freshwater Aquatic Life
under the Canadian Council of Ministers of the Environment guidelines
(CCME 2007).
ORGANIC INDICATORS
Dissolved DOC provides a measure of the total amount of dissolved organic matter
Organic Carbon in water. This bulk parameter cannot be used to distinguish between the
(DOC) various compounds making up the organic loading of a sample; therefore
it is only used as an indicator of organic loading.
High DOC readings can be related to soluble compounds originating from
the breakdown of natural organic matter in the subsurface, or soluble
hydrocarbon components originating from an industrial source. DOC
concentrations in most natural waters generally fall within the range of
10 mg/L or less (Hem 1989). Higher concentrations (up to 60 mg/L) can
sometimes occur in pore waters associated with organic-rich soils, such as
lake and swamp sediments and muskeg deposits (Thurman 1985). There
is no current CCME FWAL guideline for DOC.
Phenols (total) Phenols are a common occurrence in groundwater. This class of
compounds is derived from the degradation of natural organic matter, the
distillation of wood and coal, and the refining of oil. Phenols are also
associated with heavy oil. Phenols are quite soluble in water, and easily
degraded by subsurface bacteria. At present the CCME FWAL guideline
for phenols is 0.004 mg/L.
Concentrations of total phenols are generally quite low in most natural
groundwater systems. However, due to the presence of shallow natural
hydrocarbon seeps at the Norman Wells site, measurable phenols are
also present.
VOLATILE ORGANICS
HYDROCARBONS
Total Purgeable Due to the more complex molecular structure, these compounds tend to
Hydrocarbons be less soluble than the lighter hydrocarbons, such as the BTEX
(TPH) components.
Total Extractable These parameters can only be used to indicate the presence of higher
Hydrocarbons molecular weight hydrocarbons, as the method of analysis is incapable of
(TEH) distinguishing between the different compounds present. However, the
results can be used to more fully characterize areas identified by key
indicator parameters such as DOC and phenols. Therefore these analyses
are useful as an indicator parameter of higher-order hydrocarbons.
Petroleum The former TPH and TEH scans have been replaced with the newer
Hydrocarbon AENV (2001) petroleum hydrocarbon fractions, which include PHC F1 (C6
Fractions 1 and 2 through C10, excluding BTEX) and PHC F2 (C>10 through C16). No CCME
(PHC F1, PHC F2) FWAL guidelines are defined for PHC F1 and F2.
Norman Wells Area Phase I Phase I Phase 2 ESA - Phase 2 ESA - Drilling Groundwater Dismantling/ Remediation Surface Current Status Planned 2014 Activities
ESA ESA Update Geophysics Monitoring Demolition Restoration
Mainland East
Office Building 2000
Abandoned Camp Site 1999 2008 2008 2008 Phase 2 delineation complete Groundwater Monitoring
Phase 2 delineation complete, Screening Level Risk
Assessment complete. In-situ remediation at Refinery Groundwater Monitoring, Continue operation of
Former Refinery 1999 2008 pre-2008 1993, 97, 98, 99, 2000, 02, 03, 08, 09, 2012, 2013 1997-present 1996-1997 1999, 2002 excavations Bank area from 2003 to present in-situ systems.
API Separator 1999 2008 2003, 2009 2003-present 1997 1997 1997 Phase 2 delineation complete Groundwater Monitoring
In-situ DPE remediation system active seasonally,
upgrades and expansion in 2009, expanded solar panel
water heater capacity in 2012. Completed 2012 soil &
gw sampling to verify current PHC levels in-situ at FTA, Groundwater Monitoring, Operation and
B-38X Well Area 1999 2008 pre-2008 1993, 97, 98, 99, 2000, 02, 03, 08, 2012 1997-present 1992 ongoing 2004-present LT7, B38. Optimization of In-situ Remediation System
Surface restoration complete, delineation drilling to
B-38X Buried Pit/Sump 2008 Pre-2008, 2009 1999, 2000, 02, 03, 2010 1998-present 2006-present 2008-2009 south of former sump in 2010 Vegetation, Groundwater Monitoring
B-40X Well Site 1999 2008 2003, 2008, 2010 2003-present Phase 2 delineation completed in 2010 Groundwater Monitoring
C-36X Well Site 1999 2008 2009, 2010 2009-present Phase 2 delineation completed in 2010 Groundwater Monitoring
C-38X Well Site 1999 2008 1997, 2008 2008-present 2005 Phase 2 delineation complete
D-44X Well Site 1999 2008 2008 2008 Phase 2 delineation complete
F-50X Well Site 1999 2008 1997 Phase 2 delineation complete
Phase 2 delineation completed in 2010, Geophysical
B-42X Well Site 1999 2008 2013 2006, 2010 Investigation complete in 2013 Cut and Cap and limited Phase 2
Well abandoned. Cut and capped in 2012, Phase 2
B-35X Well Site 2012 2012 2012 2012 assessment complete in 2012 Groundwater Monitoring
In-situ DPE remediation system active seasonally,
upgrades and expansion in 2009. Upgrades ongoing to Groundwater Monitoring, Operation and
Fire Training Area 1999 2008 pre-2008 1993, 98, 99, 2000, 03, 08, 2012 1998-present 1992-2008 2008-present engineered system in 2013-2014. Optimization of In-situ Remediation System
Historical Dump Sites and Pits 1999 2008 2009, 2010 On-going
Former Pits (South of E-38X) 2008 2010 Phase 2 delineation complete
Reduced Crude Flare Pit 1999 2008 pre-2008 1993, 98, 99, 2003, 09 1998-present 2002 2002, 2003 2004 Remediation complete Groundwater and Vegetation Monitoring
In-situ remediation system active, groundwater pumping
system upgraded to run year-round in 2012, MPE
running seasonally, Screening Level Risk Assessment
complete, soil & gw sampling. Drilling on beach area in
2013. Upgrades to engineered systems ongoing 2013- Groundwater Monitoring, Operate and
Refinery Bank, Seeps, Former Flare pit 1999 2008 pre-2008 1993, 98, 99, 2001, 03, 08, 09, 2010, 12, 13 1998-present 1999, 2003-present 14. Optimization of In-situ Remediation System.
Airport Landfill 1999 2008 pre-2008 1998 1998-present Preliminary Phase 2 complete
Airport Landfarm 1999 2008 1996-2004 Closure report complete
Phase 2 delineation complete, installed 2 thermistors in
Mainland Tankfarm 1999 2008 1993, 97, 98, 2001, 02, 03 1997-present the area in 2013. Groundwater Monitoring (under Ops)
Historical Dump Site (NE of C-34-1X) 2008 2010 Phase 2 Assessment complete
Former Garage Site on Refinery at NWPC Yard 2008 2010 2010 Phase 2 Assessment complete Groundwater Monitoring
Mainland Tank Farm (former storage yard) 2008 Phase 2 Assessment complete
Former Drum Storage South of NWPC Yard 2008 2010 2010 Phase 2 Assessment complete Groundwater Monitoring
Former Fueling Site near Flint shop 2008 2010 2010 Phase 2 Assessment complete Groundwater Monitoring
Former Camp Site near Flint shop 2008 2009 2009-present Phase 2 Assessment complete Groundwater Monitoring
Mainland Central
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Appendix D - Norman Wells A&R Work Areas Summary
Norman Wells Area Phase I Phase I Phase 2 ESA - Phase 2 ESA - Drilling Groundwater Dismantling/ Remediation Surface Current Status Planned 2014 Activities
ESA ESA Update Geophysics Monitoring Demolition Restoration
Mainland West
Former Battery #1 (LH1 Area) 1999 2008 2008 2008, 2010 2008-present circa 1980 Phase 2 assessment complete Groundwater Monitoring
CPF 1999 2008 1997, 1998, 2006, 2008, 2009 1997-present Phase 2 delineation complete Groundwater Monitoring (under Ops)
E-26X Well Site 1999 2008 2008 Phase 2 assessment complete
D-27X Utilidor 1999 2008 2008 2008 2008-present Phase 2 delineation complete Groundwater Monitoring
E-27X Well Site 1999 2008 2013 2008, 2009 2008-present Phase 2 delineation complete Groundwater Monitoring, cut & cap wellhead.
Phase 2 delineation complete, Screening Level Risk Groundwater Monitoring. Develop Management
F-28X Well Site 1999 2008 1997, 2009 1997, 1998, 2009, 2010 1997-present Assessment complete. Plan
Phase 2 delineation complete, Screening Level Risk Groundwater Monitoring. Develop Management
F-29X & G30X Well Sites 1999 2008 2008 2008, 2009, 2010 2010 Assessment complete. Plan
Former Pit/Tank/Dump Site Near LT3 2008 2010 Phase 2 delineation complete
Sumps
Preparation of long term Sump Management
Interim capping and surface restoration complete, Strategy. Vegetation and Groundwater
Mainland Drilling Sump 1999 2008, 2012 2008, 2013 1992, 93, 97, 98, 2002, 08, 09, 2012, 2013 1997-present 2006 2007, 2008 2008 Screening Level Risk Assessment complete. Monitoring.
Excavation and surface restoration complete, Screening Preparation of Sump Management Strategy,
Well Services Sump 1999 2008 2008 1998, 2002, 2009 1998-present 2006 2007, 2008, 2009 2009 Level Risk Assessment complete. Vegetation and Groundwater Monitoring
Phase 2 and 3 delineation complete, data gaps filled by
drilling in 2009-10, 2012, 2013. Screening Level Risk Drain and re-contour other sumps, reconstruct
Assessment complete. Install thermistors in 2013 to sump caps. Preparation of long-term Sump
characterize permafrost. Reconstruct cap on northern- Management Strategy, groundwater & surface
Closed Mainland Sumps 1999 2008 2008 1997, 1998, 2002, 09, 2010, 2012, 2013 1997-present most sump. water monitoring.
B-38X Sump 1999 2008 pre-2008 1997, 2006, 2007, 2010 1997-present 2007, 2008 2008 Excavation and surface restoration complete Vegetation & groundwater monitoring
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Appendix D - Norman Wells A&R Work Areas Summary
Norman Wells Area Phase I Phase I Phase 2 ESA - Phase 2 ESA - Drilling Groundwater Dismantling/ Remediation Surface Current Status Planned 2014 Activities
ESA ESA Update Geophysics Monitoring Demolition Restoration
Frenchy's Island
Phase 2 assessment complete, piezometers destroyed
Well Site, Frenchy's Island East End 2008 2010 2010 by ice, no further gw monitoring needed.
Goose Island
EM Anomalies 1999 2008 2009 Phase 2 delineation complete
Former Borrow Area (T-10X Area) 1999 2008 2008 2009 2009-present Phase 2 delineation complete Groundwater Monitoring (under Ops)
Former Camp Site 1999 2008 2009 Phase 2 delineation complete
Former Drilling Sumps (sump 2, P-9X Area) 1999 2008 2009 2009-present Phase 2 delineation complete Groundwater Monitoring (under Ops)
Former Tank Farm Areas (Q-8X Area) 1999 2008 2009, 2010 2009-present Phase 2 Delineation Completed 2010 Groundwater Monitoring (under Ops)
GIT 4 1999 2008 2008 On-going
GIT 7 1999 2008 2008 On-going
GIT 9 1999 2008 2008 On-going
Historical Spill Sites (Q-10X Area) 1999 2008 2009 Phase 2 delineation complete
O-14X Well Site 1999 2008 2009 Phase 2 delineation complete
O-18X Well Site 2012, 2013 2012-present Phase 2 delineation & remedial excavations complete Groundwater Monitoring (under Ops)
N-25X Well Site 1999 2008 2008 2009 Phase 2 delineation complete
P-11X Well Site 1999 2008 2008 2009, 2010 2009-present Phase 2 Delineation Completed 2010 Groundwater Monitoring (under Ops)
Wellhead Areas 1999 2008 2009 On-going
Town Leases
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Appendix D - Norman Wells A&R Work Areas Summary
Norman Wells Area Phase I Phase I Phase 2 ESA - Phase 2 ESA - Drilling Groundwater Dismantling/ Remediation Surface Current Status Planned 2014 Activities
ESA ESA Update Geophysics Monitoring Demolition Restoration
Landfill / Borrow Area / Biocell Siting 2009, 2010 Landfill and new Biocell options deferred. Construction of new Biocell in Yard D
Plots dismantled at T401 for soil remediation activities in Continue closure monitoring on reclaimed T401
Revegetation Trial Plots 2011. site.
Characterized new inferred background locations in
2010 and 2012 to supplement existing information,
Background Conditions in Soil/Groundwater various years, 1997 to 2012 1997-present completed statistical analysis. Fill in data gaps as needed.
Seventy damaged/surplus monitoring wells were
Monitoring Well Abandonments 2009-2010 abandoned or confirmed destroyed by ice as of 2010
Mackenzie River Scour Study Field work completed in 2012. Continue data analysis.
Cut and cap activities planned for O-29X, B-42X,
E-27X and E-33X wells, with preliminary Phase 2
Former Production Well Abandonments B-30X and B-35X cut and capped in 2012 assessment.
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Appendix E
List of Acronyms,
Abbreviations and Definitions
As Arsenic
Attenuation Several mechanisms tend to slow the forward migration of
mechanisms dissolved phase constituents (hydrocarbon compounds, metals,
anions and cations, etc.) compared to water molecules as they
migrate through porous soils or bedrock. Specifically, these
mechanisms include intrinsic biodegradation, sorption on
hydrophobic or charged particle surfaces, hydrodynamic dispersion,
and molecular diffusion. Each dissolved constituent will experience
a different degree of attenuation or retardation as it migrates,
depending on the geochemical properties of both the specific
chemical parameter and the porous media through which it is
travelling.
Ba Barium
Be Beryllium
bgs below ground surface
BIT Bear Island terminal
BTEX benzene, toluene, ethylbenzene, and xylenes are among the more
compounds water-soluble compounds found in petroleum hydrocarbons
CCME Canadian Council of Ministers of the Environment
Cd Cadmium
Co Cobalt
Cr, Cr6+ Chromium and Hexavalent Chromium
Cu Copper
Dissolved phase Some of the more soluble compounds within a hydrocarbon LNAPL
hydrocarbon will tend to dissolve into adjacent groundwater. These include
BTEX compounds, PHC-F1, and PHC-F2 fractions.
DPE Dual phase extraction, an in-situ remediation method involving a
combination of groundwater extraction and application of high
vacuum to remove vapour phase hydrocarbon
Drivepoint A shallow groundwater monitoring well that is installed without a
piezometer drill rig, using a post pounder to push the well 1 to 2 m deep into
soft ground, often near a muskeg or riverbank
dS/m deci-siemens per metre
EC electrical conductivity
EM Electromagnetic, referring to geophysical surveys
ERT Electrical resistance tomography, a type of geophysical survey