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Class XI P REPARED BY :
E R . V INEET L OOMBA
(B.T ECH . IIT R OORKEE )
ALP
ADVANCED LEVEL PROBLEMS

TARGET : JEE Main/Adv MOLE CONCEPT-1

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Q.1 Equal volumes of 10% (v/v) of HCl is mixed with 10% (v/v) NaOH solution. If density of pure NaOH
is 1.5 times that of pure HCl then the resultant solution be.

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(A) basic (B) neutral (C) acidic (D) can’t be predicted.

Q.2 A definite amount of gaseous hydrocarbon having (carbon atoms less than 5) was burnt with sufficient

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amount of O2. The volume of all reactants was 600 ml, after the explosion the volume of the products
[CO2(g) and H2O(g)] was found to be 700 ml under the similar conditions. The molecular formula of
the compound is
(A) C3H8 (B) C3H6 .c (C) C3H4 (D) C4H10
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Q.3 A mixture (15 mL) of CO and CO2 is mixed with V mL (excess) of oxygen and electrically sparked. The
volume after explosion was (V + 12) mL. What would be the residual volume if 25 mL of the original
mixture is exposed to KOH. All volume measurements were made at the same temperature and pressure
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(A) 7 mL (B) 12 mL (C) 10 mL (D) 9 mL

Q.4 One gram of the silver salt of an organic dibasic acid yields, on strong heating, 0.5934 g of silver. If the
weight percentage of carbon in it 8 times the weight percentage of hydrogen and one-half the weight
percentage of oxygen, determine the molecular formula of the acid. [Atomic weight of Ag = 108]
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(A) C4H6O4 (B) C4H6O6 (C) C2H6O2 (D) C5H10O5

Q.5 The density of vapours of a particular volatile specie was found to be 10 miligram / ml at STP. Its atomic
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weight in amu is
(A) 20 amu (B) 112 amu (C) 224 amu (D) data insufficient
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Q.6 A mixture of C3H8 (g) & O2 having total volume 100 ml in an Eudiometry tube is sparked & it is
observed that a contraction of 45 ml is observed what can be the composition of reacting mixture.
(A) 15 ml C3H8 & 85 ml O2 (B) 25 ml C3H8 & 75 ml O2
(C) 45 ml C3H8 & 55 ml O2 (D) 55 ml C3H8 & 45 ml O2
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Q.7 Carbon can react with O2 to form CO & CO2 depending upon amount of substances taken. If each
option is written in an order like (x, y, z, p) where x represents moles of C taken, y represents moles of
O2 taken z represents moles of CO formed & p represents moles of CO2 formed, then which options are
correct.
(A) (1, 0.75, 0.5, 0.5) (B) (1, 0.5, 0, 0.5)
(C) (1, 0.5, 0.5, 0) (D) (1, 2, 1, 1)
Class (XI) 2

Q.8 One mole mixture of CH4 & air (containing 80% N2 20% O2 by volume) of a composition such that
when underwent combustion gave maximum heat (assume combustion of only CH4). Then which of the
statements are correct, regarding composition of initial mixture.(X presents mole fraction)
1 2 8 3 1 1
(A) X CH  , XO  , XN  (B) X CH 4  , X O 2  , X N 2 
4 11 2 11 2 11 8 8 2
1 1 2
(C) X CH 4  , X O 2  , X N 2  (D) Data insufficient
6 6 3
Q.9 To 500 ml of 2 M impure H2SO4 sample, NaOH soluton 1 M was slowly
added & the followng plot was obtained. The percentage
purity of H2SO4 sample and slope of the curve respectively are: ( A)
1 1
50%,  (B) 75%, 
3 2

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(C) 75% , –1 (D) none of these

Q.10 Two gaseous ions of unknown charge & mass initially at rest are subjected to same potential difference
for accelerating the charges & then subjected to same magnetic field (placed perpendicular to the velocity)

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& following observations were made.

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Obs 1. Before entering the magnetic field zone both ions had same kinetic energy.
Obs 2. The radius of curvature of ion A was greater than that of B.
Stat 1: The magnitude of charge on both the ions should be same
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Stat 2: Particle A is more massive than particle B
Stat 3: The e/m ratio of A is higher than that of B
(A) Only Stat 1 & Stat 2 are correct (B) Only Stat 3 is correct
(C) Only Stat 2 is incorrect (D) Only Stat 1 is incorrect
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Q.11 Two gases A and B which react according to the equation

aA(g) + bB(g)  cC(g) + dD(g)
to give two gases C and D are taken (amount not known) in an Eudiometer tube (operating at a constant
Pressure and temperature) to cause the above.
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If on causing the reaction there is no volume change observed then which of the following statement is/
are correct.
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(A) (a + b) = (c + d)
(B) average molecular mass may increase or decrease if either of A or B is present in limited amount.
(C) Vapour Density of the mixture will remain same throughout the course of reaction.
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(D) Total moles of all the component of taken mixture will change.

Question No. 12 to 13 (2 questions)

A mixture of H2 and Acetylene (C2H2) was collected in a Eudiometer tube. Then, 60 ml of oxygen were
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also introduced. The resulting mixture of all the gases was exploded. After cooling a resulting gaseous
mixture passes through Caustic potash solution a contraction of 32 ml occurred and 13 ml of oxygen
alone were left behind.

Q.12 After explosion, on cooling of resulting mixture, contraction in volume will be

(A) 21 ml (B) 30 ml (C) 45 ml (D) none

Prepared By:
Er. Vineet Loomba (IIT Roorkee)
Jupiter (XI) 3

Q.13 Percentage composition of the gaseous mixture of H2 & acetylene are

(A) 53.3, 46.7 (B) 46.7, 53.3 (C) 15.7, 84.3 (D) 84.3, 15.7

Question No. 14 to 17 (4 questions)

A 4.925 g sample of a mixture of CuCl2 and CuBr2 was dissolved in water and mixed thoroughly with
a 5.74 g portion of AgCl. After the reaction the solid, a mixture of AgCl and AgBr, was filtered, washed,
and dried. Its mass was found to be 6.63 g.

Q.14 % By mass of CuBr2 in original mixture is

(A) 2.24 (B) 74.5 (C) 45.3 (D) None

Q.15 % By mass of Cu in original mixture is

(A) 38.68 (B) 19.05 (C) 3.86 (D) None

Q.16 % by mole of AgBr in dried precipate is

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(A) 25 (B) 50 (C) 75 (D) 60

Q.17 No. of moles of Clr ion present in the solution after precipitation are

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(A) 0.06 (B) 0.02 (C) 0.04 (D) None

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Question No. 18 to 20 (3 questions)
NaBr, used to produce AgBr for use in photography can be self prepared as follows :
Fe + Br2  FeBr2 ....(1)
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FeBr2 + Br2  Fe3Br8 ....(2) (not balanced)
Fe3Br8 + Na2CO3  NaBr + CO2 + Fe3O4 ....(3) (not balanced)
How much Fe in kg is consumed to produce 2.06 × 103 kg NaBr. ....(4)
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Q.18 Mass of iron required to produce 2.06 × 103 kg NaBr

(A) 420 gm (B) 420 kg (C) 4.2 × 105 kg (D) 4.2 × 108 gm

Q.19 If the yield of (ii) is 60% & (iii) reaction is 70% then mass of iron required to produce 2.06 × 103 kg
NaBr
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(A) 105 kg (B) 105 gm (C) 103 kg (D) None

Q.20 If yield of (iii) reaction is 90% then mole of CO2 formed when 2.06 × 103 gm NaBr is formed
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(A) 20 (B) 10 (C) 40 (D) None

Question No. 21 to 23 (3 questions)

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In the gravimetric determination of sulfur the ignited precipitate of BaSO4 sometimes partially reduces
to BaS. This cause an error, of course, if the analyst does not realize this and convert the BaS back to
BaSO4. Suppose a sample which contains 32.3% SO3 is analyzed and 20.0% of the final precipitate that
is weighed is BaS. (80.0% is BaSO4). What percentage of SO3 in the sample would the analyst calculate
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if he assume the entire precipitate as BaSO4? Repeat the question if BaS was 20% by mole.

Q.21 Calculate the mass of sample, assuming 100 gm precipitate is formed

(A) 106.3 gm (B) 114.35 gm (C) 110.5 gm (D) None

Q.22 Percentage of SO3 in the sample, calculated by analyst is (if the assume the entire precipiate as BaSO4)
(A) 30 (B) 30.5 (C) 32 (D) 32.3

Prepared By:
Er. Vineet Loomba (IIT Roorkee)
Jupiter (XI) 4

Q.23 If BaS was 20% by mole in precipitate, then percentage of SO3 in the sample calculated by analyst is (if
he assume the entire precipitate as BaSO4)
(A) 30 (B) 30.5 (C) 32 (D) 32.3

Question No. 24 to 25 are based on the following Passage. Read it carefully & answer the questions
that follow
A monobasic acid of weight 15.5 gms is heated with excess of oxygen & evolved gases when passed
through KOH solution increased its weight by 22 gms and when passed through anhydrous CaCl2, increased
its weight by 13.5 gms. When the same mass of this organic acid is reacted with excess of silver nitrate
solution form 41.75 gm silver salt of the acid which on ignition gave the residue of weight 27 gm.

Q.24 The molecular formula of the organic acid is

(A) C2H6 (B) C2H5O2 (C) C2H6O2 (D) C2H4O

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Q.25 The molar masses of the acid & its silver salt respectively are
(A) 60, 168 (B) 167, 60 (C) 60, 167 (D) 168, 60

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Question No. 26 to 28 (3 questions)
N2O5 and H2O can react to form HNO3, according to given reaction
N2O5 + H2O  2HNO3

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the concentration of a mixture of HNO3 and N2O5 (g) can be expressed similar to oleum. Then answer
the following question.
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Q.26 Find the percentage labelling of a mixture containing 23 gm HNO3 and 27 gm N2O5.
(A) 104.5% (B) 109% (C) 113.5% (D) 118%
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Q.27 Find the maxmum and minimum value of percentage labelling

(A) 133.3 % (B) 116.66%, 0% (C) 116.66%, 100% (D) None

Q.28 Find the new labelling if 100 gm of this mixture (original) is mixed with 4.5 gm water
4.5 4.5 4.5 4.5
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(A) 100 + (B) 100 + (C) 100 + (D) 100+

1 1.045 104.5 1.09

Question No. 29 and 30 are based on the following piece of information. Mark the appropriate
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options on the basis of information.

342 gm of 20% by mass of Ba(OH)2 solution (sp. gr. 0.57) is reacted with 200 ml of 2M HNO3 according
to given balanced reaction.
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Ba(OH)2 + 2HNO3  Ba(NO3)2 + 2H2O

Q.29 The nature of the final solution is

(A) acidic (B) neutral (C) basic (D) can't say
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Q.30 If density of final solution is 1.01 gm /ml then find the molarity of the ion in resulting solution by which
nature of the above solution is identified, is
(A) 0.5 M (B) 0.8 M (C) 0.4 M (D) 1 M

Question No. 31 & 32 are based on the piece of information.

For a gaseous reaction,

Prepared By:
Er. Vineet Loomba (IIT Roorkee)
Jupiter (XI) 5

2A(g)  3B(g) + C(g)

Whose extent of dissociation depends on temperature is performed in a closed container, it is known
that extent of dissociation of A is different in different temperature range. With in a temperature range
it is constant. (Temperature range T0 – T1, T1 – T2, T2 – T). A plot of P v/s T is drawn under the given
condition.

Q.31 If  Ti  Ti 1 is the degree of dissociation of A then in the temperature range

Ti  Ti + 1
(A)  T is lowest (B)  T is highest
0  T1 0  T1

(C)  T2 T = 1 (D)  T2 T = 0

Q.32 If initially 1 mole of A is taken in a 1 l container then [R = 0.0821 atm lit / k]

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1 1 1 1
(A)  T =  (B)  T = 
0  T1 2 3R 2 0  T1 2 3R 2

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1 1
(C)  T1 T2  1 (D)  T1 T2  1
R R

Q.33
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Which has maximum number of atoms of oxygen
(A) 10 ml H2O(l) (B) 0.1 mole of V2O5
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(C) 12 gm O3(g) (D) 12.044 ×1022 molecules of CO2

Q.34 In a mass spectrometry experiment, various ions H+, Li+, O2+ & N 3 were projected with a same velocity
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into a same magnetic field zone (alligned perpendicular to the direction of velocity). The sheet on which
they are striking is pierced at certain points (marked as H1, H2 etc.) as shown in the diagram. It is known
that H+ comes back to zone-I from H2 when projected from H1. Mark out the correct options.
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(A) Out of all remaining ions when projected from H1, only N 3 will come back to zone-I.
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(B) When all the remaining ions were projected from H2, only O2+ will come back in zone-I.
(C) When all the remaining ions were projected from H3, none of the them will come back to zone-I.
(D) When all the remaining ions were projected from H4, none of the them will come back to zone-I.
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Prepared By:
Er. Vineet Loomba (IIT Roorkee)
Jupiter (XI) 6

ANSWER KEY

Q.1 A Q.2 A Q.3 C Q.4 B

Q.5 D Q.6 A,B Q.7 A Q.8 A
Q.9 D Q.10 A Q.11 A,C Q.12 C
Q.13 B Q.14 C Q.15 A Q.16 B
Q.17 C Q.18 B,C,D Q.19 C Q.20 B
Q.21 B Q.22 A Q.23 B Q.24 C
Q.25 C Q.26 B Q.27 C Q.28 B
Q.29 C Q.30 A Q.31 A Q.32 D
Q.33 C Q.34 B,C,D

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Prepared By:
Er. Vineet Loomba (IIT Roorkee)