Chemistry 5070 Metals Grade 11
Chemistry 5070 Metals Grade 11
Class 11
1. The statements give some of the chemical properties of metal X and its
compounds. 5070/21/M/J/16/QA5
(a) Use the information to help arrange the following metals in order of
reactivity.
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................... [1]
(c) Construct the equation for the reaction between the oxide, XO, and
magnesium.
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................... [1]
(d) Construct the ionic equation for the reaction between X and aqueous
lead(II) nitrate,
Pb(NO3)2(aq).
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................... [1]
(e) Metal X is a good electrical conductor and has a high melting point.
Explain why X
• conducts
electricity, ...................................................................................................
.
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[Total: 8]
A5(a) sodium
magnesium
X
lead
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silver
Sodium, magnesium, lead and silver in correct order (ignore X) (1)
X directly between magnesium and lead (1) [2]
...........................................................................................................................................[1]
(b) Explain why this reaction involves both oxidation and reduction.
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(c) What mass of molybdenum can be made from 125 g of molybdenum (VI) oxide?
[A r: Mo, 96]
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...........................................................................................................................................[1]
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(ii) Suggest why molybdenum has a much higher melting point than aluminium.
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[Total: 10]
3. Copper is a metal.
(a) Draw a labelled diagram to show the bonding in copper.
[2]
(b) Explain why metals are malleable.
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5070/22/O/N/15/A4
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(c) Another ore of iron contains an oxide with the formula Fe3O4.
Calculate the percentage by mass of iron in Fe3O4.
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[2]
(d) Iron can be obtained by the electrolysis of an aqueous acidified solution of iron(II)
sulfate.
The reactions at the electrodes are given.
at the anode (positive electrode): 4OH→ O2 + 2H2O + 4e–
at the cathode (negative electrode): Fe2+ + 2e– → Fe
Which reaction is oxidation and which is reduction? Explain your answer.
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(e) Attaching magnesium strips to the iron hulls of ships can lower their rate of rusting.
Explain how the magnesium stops the iron from rusting.
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(f) Aqueous iron(II) chloride is one of the products formed when iron reacts with
hydrochloric acid. Construct an equation for this reaction.
...........................................................................................................................................[1]
[Total: 10]
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5. Zinc carbonate thermally decomposes to form zinc oxide and carbon dioxide.
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(a) Suggest why the volume of carbon dioxide does not increase by very much when the zinc
carbonate is first heated.
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(b) How is the graph used to find out when the decomposition has finished?
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(c) The same mass of zinc carbonate is heated using a hotter Bunsen flame.
On the axes above, draw the graph you would expect from the results of this experiment.
Explain your answer.
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Predict and explain the time it would take magnesium carbonate and lead carbonate to
decompose.
explanation ............................................................................................................................
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[Total: 8]
(a) Initially zinc carbonate is cold so a low speed of reaction / at start zinc carbonate is not
hot enough to decompose (1) [1]
(c) Graph starts at the origin and ends at the same volume (1)
Graph has same shape as original but always to the left and does not go above
the final volume (1)
Reaction is faster (1)
Particles have more energy / more successful collisions / more energetic
collisions / more fruitful collisions / more effective collisions / more particles have
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5070/21/M/J/14/A4
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(c) Underground iron pipes rust easily. This can be prevented by attaching a piece of
magnesium to the pipe.
Explain this form of rust prevention.
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[Total: 10]
5070/22/M/J/14/A5
7. Haematite, limestone and coke are heated together in a blast furnace in the manufacture
of iron.
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(a) State why each of the following compounds are needed in a blast furnace.
haematite ..............................................................................................................................
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limestone ...............................................................................................................................
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coke ......................................................................................................................................
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(b) Iron has a high melting point because it has strong metallic bonding.
Describe, using a labelled diagram, metallic bonding.
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(c) When iron is made into the alloy steel, the properties of iron are changed.
High carbon steels are stronger than iron but are brittle.
State a property of low carbon steels.
...........................................................................................................................................[1]
(d) When magnesium powder is added to aqueous iron(II) sulfate, the following reaction
occurs.
(i) Explain, using electron transfer, why iron(II) ions are reduced in this reaction.
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.......................................................................................................................................[1]
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[Total: 8]
(a) Haematite – is iron ore / contains the iron / is reduced to form iron (1)
Limestone – (decomposes to) form calcium oxide which removes impurities (1)
ALLOW: lime (in place of calcium oxide)
Coke – forms carbon monoxide / reduces the iron ore (1) [3]
(d) (i) Iron(II) ions gain electrons / iron ions gain electrons / it gains electrons (1) [1]
(ii) Green solution becomes paler / green solution fades / green solution
becomes colourless / magnesium becomes coated with a dark solid (1) [1]
[Total: 8]
5070/22/O/N/14/A5
8. The table below shows the reactivity of five metals with either cold water or steam or
with both.
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(a) Deduce the order of reactivity of these metals using the information in the table.
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Which combination of metals from this list would produce the highest voltage when used
as electrodes in an electrochemical cell?
.......................................................................................................................................[1]
(c) Strips of zinc can be attached to the hull of a ship to stop the steel from rusting.
Explain how these strips of zinc stop the steel from rusting.
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...........................................................................................................................................[2]
[Total: 5]
(a) sodium
barium
magnesium
nickel
copper (1) [1]
(b) (i) voltmeter and two wires either side of voltmeter across the electrodes (1) [1]
(ii) iron and silver (1) [1]
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5070/21/O/N/14/A1 part c
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5070/21/O/N/14/A4
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The voltages produced by different combinations of metal electrodes are shown in the
table below. The more reactive metal is always the negative electrode.
(a) (i) Write an equation showing the conversion of zinc to zinc ions.
.......................................................................................................................................[1]
(ii) How does the table above show that copper is above silver in the reactivity series?
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(iii) Which combination of metals in the table above will give the highest voltage?
.......................................................................................................................................[1]
(iv) Use the information in the table to deduce the order of reactivity of the metals copper,
iron, magnesium, tin and zinc. Explain your answer.
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(c) Explain why plating iron with tin prevents the iron from rusting.
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[Total: 9]
(ii) in the copper / silver cell the copper is the negative electrode (1) [1]
(iv) magnesium
zinc
iron
tin
copper (1)
the higher the voltage (difference between copper and the metal) the more
reactive the metal / voltage (difference) gets smaller, the less reactive the
metal (1) [2]
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(c) tin prevents oxygen and/or water from reaching the iron (1) [1] [Total: 9]
5070/22/M/J/13/A3 part e
11. Aluminium is used to make alloys for the aircraft industry. One reason for this is that
aluminium does not corrode very easily.
(i) State one other reason why aluminium is used in the manufacture of aircraft.
............................................................................................................................. [1]
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............................................................................................................................. [2]
5070/21/M/J/13/B7
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The carbon dioxide formed is collected and has a volume of 96 cm3 at room temperature
and pressure.
(a) What would you observe when malachite reacts with HCl(aq)?
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..................................................................................................................................... [2]
(b) Construct the equation for the reaction between malachite and HCl(aq).
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(c) Calculate the mass of carbonate ion, CO32−, in the sample of malachite.
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(ii) Malachite is a finite resource. Give one other reason why copper should be recycled.
..................................................................................................................................
............................................................................................................................. [1]
[Total: 10]
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5070/21/O/N/13/B6
13. Iron is extracted from its ore (haematite, Fe2O3) in a blast furnace.
Coke (carbon) and limestone (calcium carbonate) are also added to the furnace.
(a) Describe the essential reactions taking place in the blast furnace.
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(c) Iron reacts with dilute hydrochloric acid to form iron(II) chloride.
A student added 2.1 g of iron to 50 cm3 of 0.10 mol / dm3 hydrochloric acid.
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...........................................cm3 [2]
[Total: 10]
(b) in ‘pure’ iron the layers can slide (when force applied) (1)
in alloy the (larger) Mn atoms stop the layers from sliding (1) [2]
5070/22/O/N/13/B6
(a) Describe how this electrolysis is carried out and construct equations for the reactions
occurring at both the anode and cathode.
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(i) Explain why aluminium does not react with aqueous copper(II) sulfate.
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(ii) When a few drops of aqueous sodium chloride are added to a mixture of aluminium
and aqueous copper(II) sulfate, a vigorous reaction occurs.
.............................................................................................................................. [1]
.............................................................................................................................. [1]
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[Total: 10]
5070/21/M/J/12/A5
15. Displacement reactions occur when a metal reacts with a metal compound.
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…………………………….
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(c) Aluminium foil is added to aqueous copper(II) chloride. A displacement reaction takes
place. The temperature of the reaction mixture increases.
(i) Name the type of reaction in which the temperature of the reaction mixture
increases.
............................................................................................................................. [1]
............................................................................................................................. [1]
(d) Explain why, even though it is high up in the reactivity series, aluminium does not react
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(e) Molybdenum, atomic number 42, is manufactured by the displacement reaction between
molybdenum(VI) oxide and aluminium.
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5070/22/M/J/12/B7
16. Many carbonates thermally decompose to form carbon dioxide and an oxide.
Copper carbonate forms carbon dioxide and copper oxide.
Six 2.00 g samples of carbonates are heated strongly until there is no further change in
mass. The table shows the mass of solid remaining at the end of the heating.
(a) What is the mass of carbon dioxide formed when 2.00 g of copper(II) carbonate is
heated?
(b) The thermal stability of the carbonates is related to the reactivity of the metal.
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(e) Copper(II) chloride can be prepared by the reaction between copper(II) carbonate and
hydrochloric acid.
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(ii) Describe the essential practical details for the preparation of a crystalline sample of
copper(II) chloride.
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[Total: 10]
(a) 0.71 g
Allow: 0.709 / 0.704 g [1]
(ii) Reacts with sand to make slag / reacts with silicon dioxide to make calcium silicate /
removes silicon dioxide as slag (1) [1]
5070/21/O/N/12/A2
17. Steel is more resistant to corrosion than iron.
(a) What are the essential conditions for the corrosion of iron?
..........................................................................................................................................
..................................................................................................................................... [1]
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(b) Ships’ hulls can be prevented from corroding by attaching pieces of magnesium to them.
Explain why this prevents the hulls from corroding.
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(d) Samples of iron were placed in aqueous solutions having different pH values.
The table shows how the speed of corrosion of iron varies with the pH of the solution.
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[Total: 6]
(d) the higher the pH the less the corrosion/the lower the pH the higher the corrosion (1)
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5070/21/O/N/12/B7
18. Tin is a metal in Group IV of the Periodic Table.
(a) Draw a labelled diagram to show the structure of a metal.
[2]
(b) Explain why metals
............................................................................................................................. [2]
(c) At high temperatures, tin reacts with steam to form tin(II) oxide, SnO, and one other
product.
[1]
(ii) Tin(II) oxide is an amphoteric oxide.
Explain the meaning of the term amphoteric oxide.
............................................................................................................................. [1]
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(d) (i) Concentrated nitric acid reacts with tin to form tin(IV) oxide, SnO2, nitrogen dioxide
and water. Construct an equation for this reaction.
[1]
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[Total: 10]
(ii) add (concentrated aqueous) sodium hydroxide and aluminium foil (1)
ALLOW add sodium hydroxide and Devarda’s alloy
warm and test gas with red litmus paper (1)
(red) litmus turns blue/ammonia produced (1)
ALLOW the brown-ring test [3]
[Total: 10]
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5070/21/O/N/12/B10
(a) Explain why limestone is used in the blast furnace for the extraction of
iron.
Include any relevant equations in your answer.
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(b) Group II carbonates decompose on heating.
The temperatures at which some Group II carbonates decompose are
given in the table
below.
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........ [1]
(ii) Describe how the thermal stability of these carbonates changes with
the reactivity
of the metal.
.....................................................................................................................
........ [1]
(c) The speed of reaction of calcium carbonate with hydrochloric acid can
be calculated by
measuring the volume of gas given off at various time intervals.
(i) Draw a labelled diagram of the apparatus you could use to follow the
course of this
reaction.
[2]
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(ii) State and explain the effect of the following on the volume of a fixed
mass of gas
• increasing the pressure,
• increasing the temperature.
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[Total: 10]
(ii) the more reactive the metal the more stable the carbonate [1]
(c) (i) suitable apparatus e.g. gas syringe/upturned measuring cylinder (1)
closed system – essentially does the method work (1) [2]
(ii) increasing pressure decreases the volume and increasing temperature increases
the volume (1)
(increasing pressure) pushes molecules closer together so more collisions with walls
of container (1)
(increasing temperature) makes molecules move faster/molecules have more
energy (1) [3]
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[Total: 10]
. 5070/22/O/N/12/A2
(a) (i) Predict the order of reactivity of the metals iron, lead, magnesium and zinc.
.............................................................................................................................. [1]
(ii) Construct the equation for the reaction of iron(III) oxide, Fe2O3, with zinc. The
products are zinc oxide, ZnO, and iron.
[1]
(b) Aluminium is high in the reactivity series but does not appear to react with either water
or acids.
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.............................................................................................................................. [2]
(ii) Explain why aluminium is used in the manufacture of aircraft.
.............................................................................................................................. [1]
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(a) (i) lead < iron < zinc < magnesium [1]
(b) (i) (forms an) oxide layer / has a coat of oxide; (1)
which is strongly fixed to the surface / which is not easily removed / which is
unreactive; (1) [2]
5070/22/M/J/11/B9
21. Copper is a transition metal. It is used both in its pure form and in alloys.
(a) The physical properties of copper can be explained in terms of metallic bonding.
Describe, with the aid of a labelled diagram, the metallic bonding in copper.
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(b) Pure copper is used to make electrical wires because it is a good electrical conductor.
(i) Explain why copper is a good electrical conductor.
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(ii) Describe how impure copper can be purified.
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(c) Name an alloy that contains copper.
......................................................................................................................................[1]
(b) (i) electrons can move / has delocalised electrons / electrons are free / has sea of electrons
/ has mobile electrons [1]
(ii) impure copper anode and pure copper cathode ; [1]
electrolysis of (aqueous) copper(II) sulfate / copper(II) nitrate [1]
ALLOW: electrolysis of copper sulfate / copper nitrate
NOT: electrolysis of copper chloride
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(c) brass / bronze / gilding metal / Muntz metal / yellow metal / bell metal / cupro-nickel /
gunmetal / speculum metal / (cupro) nickel-silver / duralumin [1]
ALLOW: smart alloy / gold alloy
IGNORE: steel alloys
(d) Any three of: [3]
• copper ores are in limited supply / are becoming worked out / are finite (resource) /
saves resources / less copper extracted from the soil
IGNORE: no waste of copper
• less energy used (in recycling than in extracting from the ore)
• reduces pollution / reduces waste / reduces trash / less eyesore / not an eyesore / less
landfill / no landfill
IGNORE: does not cause pollution
• (need to) sort out recycled metals / (need to) collect scrap / collecting scrap (costs
money) / collecting scrap requires energy
• need to purify the recycled copper
• (less mining) saves more land for other uses / (less mining) saves land for more
agriculture
IGNORE: costs / time consuming
[Total: 10]
5070/21/O/N/11/A5 part A
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[2]
(ii) Use ideas about the structure of metals to explain why metals are
malleable, .................................................................................................................
............................................................................................................................. [1]
(a) (i) Positive ions in regular layers (1) positive ions can be shown as circles with +
or
labelled as ions NOT atoms
electrons shown interspersed between the ions (1) electrons can be shown in
diagram as e–/e or – or dots labelled electron [2]
(a) One stage in purifying bauxite to obtain pure aluminium oxide involves mixing the
crushed ore with concentrated aqueous sodium hydroxide. The products of the reaction
are aqueous sodium aluminate, NaAlO2, and water.
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(i) What type of oxide is aluminium oxide? Give a reason for your answer.
..................................................................................................................................
............................................................................................................................. [1]
(ii) Write an equation for the reaction of aluminium oxide with aqueous sodium
hydroxide.
............................................................................................................................. [1]
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(b) Pure aluminium oxide is electrolysed in the presence of cryolite to produce aluminium.
............................................................................................................................. [1]
(c) (i) Aluminium is higher in the metal reactivity series than iron.
Apart from differences in malleability, explain why fizzy drinks cans are made from
aluminium rather than iron.
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............................................................................................................................. [2]
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[Total: 10]
(a) (i) amphoteric oxide because it react both with acids and bases/amphoteric because it
reacts as both an acid and a base (1) [1]
(ii) to dissolve the aluminium oxide/to lower the melting point of the mixture (1) [1]
5070/21/M/J/10/A5
24. Mobile phones are made from a large number of different substances.
The table shows the composition of a typical mobile phone.
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............................................................................................................................ [1]
[1]
(b) There is a growing awareness that mobile phones should be recycled.
(i) State two advantages of recycling the substances used to make mobile phones.
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(ii) Suggest one disadvantage of recycling the substances used to make a mobile
phone.
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(d) One of the reasons why copper is used in mobile phones is because it is a good
conductor of electricity.
[2]
(ii) Explain how copper conducts electricity.
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(i) Suggest one way to stop the iron used from rusting.
............................................................................................................................ [1]
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[Total: 14]
(ii) Electrons move / delocalised electrons / free electrons / sea of electrons (1) [3]
(e) (i) Alloy it to make steel / galvanised / tin plate / use of a sacrificial metal / paint (1)
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5070/22/O/N/10/B8
25. Magnesium is a reactive metal.
(a) (i) Name the products formed when magnesium reacts with steam.
.............................................................................................................................. [1]
(ii) Write the equation for the reaction of magnesium with ethanoic acid, CH3COOH.
[2]
(b) Magnesium chloride is a soluble salt.
Describe how you can make pure dry crystals of magnesium chloride from magnesium
carbonate.
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(c) The equation shows the reaction which occurs when magnesium carbonate is heated.
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(d) A student compared the action of heat on three solid metal carbonates.
She heated each carbonate using the apparatus shown below. In each case, she
recorded the length of time taken for the limewater to turn milky.
(i) State one factor that must be kept constant if the speeds of reaction are to be
compared in a fair way.
.............................................................................................................................. [1]
(ii) The time taken for the limewater to turn milky for each metal carbonate is shown in
the table.
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Describe and explain these results in terms of the reactivity of the metals.
..................................................................................................................................
..................................................................................................................................
.............................................................................................................................. [2]
[Total: 10]
(ii) order of decomposition is copper (carbonate) > zinc (carbonate) > magnesium
(carbonate); (1)
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ALLOW: copper carbonate takes shortest time and magnesium carbonate takes
longest time / copper carbonate the fastest and magnesium carbonate the slowest
the less reactive (the metal), the faster the rate (of decomposition) /
the more reactive (the metal) the slower the rate (of decomposition) /
the more reactive (the metal) the longer it takes (to decompose) / (1) [2]
ALLOW: the most reactive takes the most time ORA
[Total: 10]
Iron rusts in the presence of oxygen and water. Rusting involves a series of reactions.
Initially iron atoms lose electrons to form iron(II) ions.
–
Fe(s) →Fe2+(aq) + 2e
At the same time oxygen, O2, and water molecules react to form hydroxide ions.
Aqueous iron(II) ions then react with aqueous hydroxide ions to form solid iron(II)
hydroxide.
Finally the iron(II) hydroxide is oxidised to give hydrated iron(III) oxide (rust).
(a) (i) Explain why the formation of iron(II) ions from iron atoms is an example of
oxidation.
..................................................................................................................................
.............................................................................................................................. [1]
(ii) Write the ionic equation, including state symbols, for the reaction between iron(II)
ions and hydroxide ions.
.............................................................................................................................. [2]
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An iron object plated with either zinc or tin will not rust.
(ii) An iron object plated with tin will start to rust if the layer of tin is scratched.
An iron object plated with zinc will not rust if the layer of zinc is scratched.
Use the information in the table to explain these two observations.
..................................................................................................................................
..................................................................................................................................
..................................................................................................................................
..................................................................................................................................
.............................................................................................................................. [3]
(c) Explain why aluminium will not corrode in the presence of oxygen and water.
..........................................................................................................................................
...................................................................................................................................... [1]
(d) State a use of aluminium and explain why this metal is particularly suited for the stated
use.
..........................................................................................................................................
..........................................................................................................................................
...................................................................................................................................... [2]
[Total: 10]
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(a) (i) Electrons lost/ oxidation number (of iron) increases / oxidation number goes from 0
to +2 ; [1]
NOT: incorrect oxidation numbers
–
(ii) Fe2+(aq) + 2OH (aq) → Fe(OH)2(s) [2]
(b) (i) stops water from getting to the surface (of the iron) / [1]
stops oxygen getting to surface (of the iron) /
stops oxygen / water getting to the iron /
stops air getting to the iron /
ALLOW: acts as a protective barrier / layer
NOT: ideas about sacrificial protection
NOT: tin does not react with water / air / tin less reactive than iron
(ii) with tin: oxygen / water can react with the iron (where it is scratched) ; [1]
NOT: iron more reactive than tin
with zinc any two of: [2]
• zinc more reactive than iron
NOT: zinc oxide protective layer
• zinc is sacrificial metal / idea of sacrificial protection i.e. zinc corrodes more
readily than iron / zinc reacts first
NOT: zinc rusts more readily than iron
• zinc loses electrons more readily than iron
NOT: zinc displaces iron
(c) has layer of (aluminium) oxide that will not flake off / [1]
layer of insoluble / unreactive (aluminium) oxide /
layer of impermeable (aluminium) oxide / protective oxide layer /
NOT: oxide coating without further qualification
NOT: forms a protective layer with oxygen
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. 5070/02/O/N/09/B10
27. Iron is extracted by reducing iron ore in a blast furnace. The raw materials used are iron
ore, coke, air and limestone
...................................................................................................................................... [1]
(b) Explain, by reference to the chemical reactions involved, why limestone is used in the
blast furnace.
..........................................................................................................................................
..........................................................................................................................................
..........................................................................................................................................
..........................................................................................................................................
..........................................................................................................................................
..........................................................................................................................................
...................................................................................................................................... [3]
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..........................................................................................................................................
..........................................................................................................................................
..........................................................................................................................................
..........................................................................................................................................
..........................................................................................................................................
..........................................................................................................................................
...................................................................................................................................... [3]
(d) In the centre of the blast furnace iron(III) oxide, Fe2O3, is reduced by carbon monoxide
to form iron and carbon dioxide. Near the bottom of the blast furnace the remaining
iron(III) oxide is reduced by carbon to form iron and carbon monoxide.
Write equations for both of these reactions.
..........................................................................................................................................
...................................................................................................................................... [2]
(e) When cold, the iron obtained from the blast furnace is brittle.
How can this iron from the blast furnace be converted to mild steel?
..........................................................................................................................................
...................................................................................................................................... [1]
[Total: 10]
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(c) energy needed to break the bonds (in carbon and oxygen) / bond breaking is endothermic;
[1]
energy released on forming bonds in CO2 / bond forming is exothermic; [1]
more energy involved in bond making than bond breaking / more energy released than
absorbed [1]
(e) remove (some) carbon / blow oxygen through (the molten iron) / react it with oxygen /
use a basic oxygen converter [1]
NOT: use a furnace / use a converter
NOT: adding other metals to form stainless steel / alloys
[Total: 10]
28. In the production of aluminium, sodium hydroxide is used to separate aluminium oxide
from the impurities in the bauxite ore. The main impurity in the ore is iron(III) oxide.
Aluminium oxide is an amphoteric oxide whilst iron(III) oxide is a basic oxide.
Suggest how these two oxides can be separated by the addition of aqueous sodium
hydroxide.
..........................................................................................................................................
..........................................................................................................................................
...................................................................................................................................... [2]
(d) Aluminium is extracted by the electrolysis of a mixture of molten aluminium oxide and
cryolite. What is the function of the cryolite? 5070/02/O/N/08/A6 part c, d and e
...................................................................................................................................... [1]
..........................................................................................................................................
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...................................................................................................................................... [2]
(e) (aluminium) covered with (aluminium) oxide layer/there is (aluminium) oxide on the
surface
ALLOW: protective layer formed by reaction with oxygen
NOT: wrong layer e.g. oxygen layer/layer of nitrogen
layer/aluminium oxide is unreactive/layer stops (chemical) reaction/protective layer
formed
NOT: aluminium is unreactive [2]
5070/02/M/J/07/A7
29. The carbonates of many metallic elements decompose when heated.
(a) Name the gas produced during the decomposition of a metal carbonate and describe a
chemical test for this gas.
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......................................................................................................................................[2]
......................................................................................................................................[1]
The student heats a 0.010 mol sample of each carbonate using the blue flame of the
same Bunsen burner. She measures the time it takes for 100 cm3 of gas to be collected
in the gas syringe.
The table shows her results.
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Explain how you used the student’s results to identify each metal.
..........................................................................................................................................
..........................................................................................................................................
.....................................................................................................................................[3]
Page 59 of 77
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A 0.010 mol sample of calcium nitrate is heated. Calculate the number of moles of gas
produced when this sample is completely decomposed.
(c) U – copper
V – magnesium
X – calcium
Y – sodium
Z – zinc correct order = 2 marks
U – sodium
V – magnesium
X – zinc
Y – copper
Z – calcium order reversed = 1 mark [2]
reason e.g.
the more reactive the metal, the longer the time taken to decompose ORA/
the more reactive the metal, the slower the rate (of decomposition) ORA/
ALLOW: more reactive metal (carbonates) take longer to decompose
ALLOW: the more reactive the metal (carbonate) the more stable it is to heat(ing) [1]
NOT: the metals are in order of the reactivity series
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5070/02/O/N/06/A2 part a
30. The table shows the decomposition temperatures of some metal carbonates.
(a) (i) Describe how the decomposition temperature depends on the position of the metal
in the reactivity series.
...................................................................................................................................
...............................................................................................................................[1]
(ii) Write an equation for the thermal decomposition of magnesium carbonate.
...............................................................................................................................[1]
(i) the more reactive the metal the higher the (decomposition)
temperature/the less readily the carbonate is decomposed (or reverse
argument) [1]
NOTE: comparison essential
NOT: the smaller the cation, the lower the decomposition temperature
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(a) Explain why the physical properties of brass are different from those of zinc and copper.
[1]
(b) A sample of powdered brass is added to excess dilute nitric acid.
The mixture is heated gently until all the brass reacts.
The resulting solution, A, contains aqueous copper(II) ions and aqueous zinc ions.
(i) Suggest the colour of solution A. [1]
(ii) Describe and explain, with the aid of equations, what happens when aqueous sodium
hydroxide is slowly added to solution A. [5]
(c) Another sample of powdered brass is added to excess dilute hydrochloric acid.
The mixture is heated and an aqueous solution of a compound B together with a solid C
are formed.
(i) Name both B and C. [2]
(ii) Write an ionic equation for this reaction. [1]
5070/02/M/J/05/A2
32. Iron is one of the most important metals. It is a transition element.
Most iron is used in the alloy steel.
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(a) Explain, in terms of metallic bonding, why iron is a good electrical conductor.
..........................................................................................................................................
..........................................................................................................................................
......................................................................................................................................[2]
(b) Describe how different proportions of carbon can modify the physical properties of steel.
..........................................................................................................................................
..........................................................................................................................................
......................................................................................................................................[2]
(i) State the essential conditions needed for the rusting of iron.
...................................................................................................................................
(ii) Pieces of magnesium are often attached to underwater iron pipes. Explain how the
magnesium protects the iron pipes against rusting.
...................................................................................................................................
...................................................................................................................................
…............................................................................................................................[3]
(d) Write two typical properties that are generally common only to transition elements.
1. ......................................................................................................................................
2. ..................................................................................................................................[2]
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(e) A sample of a compound of iron is analysed. The sample contains 0.547 g of potassium,
0.195 g of iron, 0.252 g of carbon and 0.294 g of nitrogen.
Calculate the empirical formula of this compound.
Answer .........................................................................................................................[3]
(b) high carbon steels are strong or are brittle (allow harder) (1)
low carbon steels are soft or are more easily shaped
(allow more malleable) (1) [2]
(c) (i) conditions are air (oxygen) and water or moist air (1)
(ii) magnesium is above iron in the reactivity series
(or is more reactive) (1)
hence it corrodes before the iron (1) [3]
(e) calculation
for idea of dividing by correct Ar (1)
dividing by the smallest (1)
for final formula only if first 2 fully correct (1)
33. The diagram below shows an experiment in which steam was passed over hot iron filings.
The products of the reaction are iron oxide, Fe3O4, and a gas which burns with a blue
flame. 5070/02/O/N/05/B10
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(a) Write an equation, including state symbols, for the reaction and describe what you would
see as the iron reacts with the steam. [3]
(b) Describe how the observations would be different if the experiment was repeated using
each of the following two metals in place of the iron filings.
(i) magnesium
(c) (i) Both copper and aluminium are good conductors of electricity. Explain why overhead
cables are usually made from aluminium and not copper.
(ii) Draw a diagram to show the structure and bonding of aluminium metal. Use your
diagram to explain why aluminium conducts electricity so well.
[4]
[Total: 10 marks]
ii)
oxygen relights a glowing splint;
hydrogen pops when lit; 4
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34. The table below shows some of the ores of iron. 5070/02/M/J/04/B10
(a) Which ore in the table contains the greatest percentage by mass of iron? Explain your
answer. [2]
(b) Give the equations for the redox reactions taking place in the extraction of iron from
haematite.
In each case state which substance is oxidised and which is reduced. [4]
(c) Iron is malleable. Describe how this property can be explained in terms of its structure.
[2]
(d) State and explain how the properties of iron can be changed by the addition of carbon.
[2]
C + O2 → CO2
C oxidised and O2 reduced
C + CO2 → 2 CO
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Fe2O3 + 3 CO → 2 Fe + 3 CO2
Fe2O3 reduced and CO oxidised
Fe2O3 + 3 C → 2 Fe + 3 CO
Fe2O3 reduced and C oxidised
{4}
…………………………………………………………………………………………
(c) metals have +ve ions in sea of electrons {1}
ions can slide around {1}
{2}
…………………………………………………………………………………………
(d) low carbon gives softer/more malleable steel {1}
carbon disrupts the packing {1}
{2}
___________________________________________________________________
5070/02/O/N/04/B9
35. Iron from the Blast Furnace contains carbon as an impurity. To remove the carbon,
oxygen is blown on the molten iron in a large vessel known as a converter. The carbon is
oxidised to carbondioxide.
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(a) The temperature of the molten iron increases as the oxygen is blown onto it. Explain why.
[1]
(b) During the oxygen blow, some of the molten iron is oxidised to iron(III) oxide. Write an
equation for this reaction. State symbols are not required. [2]
(c) Scrap steel is recycled by being added, as a solid, to the molten iron, before the oxygen
blow.
The graph below shows how the temperature of the molten iron changes during the
oxygen blow.
(i) Describe how the temperature of the molten iron changes during the oxygen blow.
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Explain why the solid scrap steel affects the temperature change during the oxygen blow.
(iii) How do the properties of the two types of steel differ? Use your diagrams to explain why
the properties are different. [4]
[Total: 10 marks]
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(iii) Property:
low C steel softer/weaker/more easily shaped/less brittle
than high carbon steel; ORA
Structure:
properties change because carbon atoms are smaller
than iron atoms (may come from reference to
diagram)/metallic bonding is disrupted/lattice is
disrupted/alloy structure is less regular/layers need to slip
when steel changes shape[2]
10 marks
5070/02/M/J/04/B8
• Stage 1 – nickel(II) sulphide is heated in air to form nickel(II) oxide and sulphur dioxide.
• Stage 2 – nickel(II) oxide is heated with carbon to give impure nickel.
• Stage 3 – impure nickel is reacted with carbon monoxide to make nickel tetracarbonyl,
Ni(CO)4.
• Stage 4 – nickel tetracarbonyl is decomposed to give pure nickel.
(a) (i) Construct the balanced equation for the reaction in stage 1.
(ii) Calculate the mass of sulphur dioxide that is formed when 182 kg of nickel sulphide
is heated in air. [3]
(c) Suggest one possible environmental consequence of the manufacture of nickel. [1]
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(e) In an experiment, small amounts of three metals were added to three aqueous metal
nitrate solutions.
Predict the observations when nickel is added to separate solutions of zinc nitrate and
copper(II) nitrate.
Write an ionic equation for one of the reactions that takes place. [3]
(a)
(ii)
(59 + 32) kg NiS forms (32 + 32) kg SO2 {1}
182 kg NiS forms 182x64/91 = 128 kg SO2 {1}
{3}
…………………………………………………………………………………………..
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{3}
…………………………………………………………………………………………..
an equation {1}
Zn + Ni2+ → Zn2+ + Ni
2+
Zn + Cu2+ → Zn + Cu
2+
Ni + Cu2+ → Ni + Cu {3}
……………………………………………………………………………………….
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5070/2/O/N/03/B9
37. This diagram shows an electrolysis tank used industrially to produce aluminium from
aluminium oxide.
One reason that this process is expensive is that the graphite anodes need replacing
regularly.
(a) Explain, with the help of an equation, why the graphite anodes need replacing regularly.
[2]
(b) Adding molten cryolite reduces the cost of the process by lowering energy demand.
Explain how adding molten cryolite reduces the energy demand of the process. [2]
(c) State two uses of aluminium. State the property of aluminium which makes it suitable for
each use. [2]
(d) Aluminium is above hydrogen in the reactivity series.
The following experiments were set up.
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38. Zinc can be extracted from calamine, ZnCO3, in a two-stage process. 5070/2/O/N/02/B7
(a) Explain why the gases from stage 2 must be removed for the safety of the workers. [1]
(b) Explain why the same two-stage process cannot be used to extract sodium from sodium
carbonate, Na2CO3. [2]
(c) Industrial processes release large amounts of carbon dioxide. This contributes to global
warming.
Describe two environmental consequences of an increase in global warming. [2]
(d) In the laboratory, two experiments were set up using zinc metal.
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For each experiment, describe what you would observe and how you would test any
gases evolved. Write an equation for the reaction in each beaker. [5]
[Total : 10]
5070/2 Nov01/B10
39.(a) You are provided with the following substances.
magnesium metal
copper metal
aqueous chlorine
aqueous iodine
aqueous copper(II) sulphate
aqueous magnesium nitrate
aqueous potassium chloride
aqueous potassium iodide.
Your answer should include details of your observations and the equations for the
reactions which occur. [7]
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(b)(i) XZY1
(ii) X = Ag / Au / Pt
Z = Zn / Cu / Fe / Sn
Y = Al
3 correct (2)
2/1 correct only (1) 3
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