SAFETY DATA SHEET

Eastman Texanol(TM) Ester Alcohol

Version Revision Date: SDS Number: Date of last issue: -

2.1 02/24/2017 150000000148 Date of first issue: 09/06/2016
SDSUS / PRD / 0001

SECTION 1. IDENTIFICATION

Product name : Eastman Texanol(TM) Ester Alcohol

Product code : EAN 000701. 02104-00, P0210401, P0210404, P0210406,

P021040A, P0210410, P0210412, P0210415, P0210416,
P02104E1, P02104E2, P0210402, P0210413, E02104D1,
P0210417, P0210418, P0210414, P0210419, P0210420,
P0210421

Manufacturer or supplier's details

Company name of supplier : Eastman Chemical Company

Address : 200 South Wilcox Drive

Kingsport TN 37660-5280

Telephone : (423) 229-2000

Emergency telephone : CHEMTREC: +1-800-424-9300, +1-703-527-3887 CCN7321

Recommended use of the chemical and restrictions on use

Recommended use : Coalescing agent for emulsions

Restrictions on use : None known.

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification
Not a hazardous substance or mixture.
GHS label elements
Not a hazardous substance or mixture.
Other hazards
None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Ingredients
Chemical name CAS-No. Concentration (% w/w)
2,2,4-trimethyl-1,3-pentanediol monoisobutyrate 25265-77-4 100

SECTION 4. FIRST AID MEASURES

If inhaled : Move to fresh air.

Treat symptomatically.
If symptoms persist, call a physician.

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SAFETY DATA SHEET

Eastman Texanol(TM) Ester Alcohol

Version Revision Date: SDS Number: Date of last issue: -

2.1 02/24/2017 150000000148 Date of first issue: 09/06/2016
SDSUS / PRD / 0001

In case of skin contact : Wash off with soap and water.

If symptoms persist, call a physician.

In case of eye contact : In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.

If swallowed : Seek medical advice.

Most important symptoms : None known.

and effects, both acute and
delayed

Notes to physician : Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Water spray

Carbon dioxide (CO2)
Dry chemical

Unsuitable extinguishing : Do not use a solid water stream as it may scatter and spread
media fire.

Specific hazards during fire : None known.

fighting

Further information : None known.

Special protective equipment : Wear an approved positive pressure self-contained breathing

for fire-fighters apparatus in addition to standard fire fighting gear.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Use personal protective equipment.

tive equipment and emer- Local authorities should be advised if significant spillages
gency procedures cannot be contained.

Environmental precautions : Avoid release to the environment.

Methods and materials for : Contain spillage, soak up with non-combustible absorbent
containment and cleaning up material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and transfer to a container for disposal according to local /
national regulations (see section 13).

SECTION 7. HANDLING AND STORAGE

Advice on safe handling : Wash thoroughly after handling.

Use only in area provided with appropriate exhaust ventilation.

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SAFETY DATA SHEET

Eastman Texanol(TM) Ester Alcohol

Version Revision Date: SDS Number: Date of last issue: -

2.1 02/24/2017 150000000148 Date of first issue: 09/06/2016
SDSUS / PRD / 0001

Conditions for safe storage : Keep tightly closed.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Contains no substances with occupational exposure limit values.
Engineering measures : Ensure adequate ventilation.

Personal protective equipment

Respiratory protection : Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.

Hand protection

Remarks : Wear suitable gloves.

Eye protection : Safety glasses

Protective measures : Ensure that eye flushing systems and safety showers are
located close to the working place.

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Color : colorless

Odor : slight

Melting point/freezing point : < -70.25 °C

Boiling point/boiling range : 255 - 261.5 °C

(102.4 kPa)

Flash point : 122 °C

Method: Seta closed cup

Flammability (solid, gas) : Not applicable

Vapor pressure : 1.3 Pa (20 °C)

Relative vapor density : 7.5

Relative density : 0.9464 (20 °C)

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SAFETY DATA SHEET

Eastman Texanol(TM) Ester Alcohol

Version Revision Date: SDS Number: Date of last issue: -

2.1 02/24/2017 150000000148 Date of first issue: 09/06/2016
SDSUS / PRD / 0001

Solubility(ies)
Water solubility : 0.5 - 3.79 g/l (25 °C)

Partition coefficient: n- : log Pow: 2.34 - 3.2 (25 °C)

octanol/water

Viscosity
Viscosity, dynamic : 12.9 mPa.s (25 °C)

Viscosity, kinematic : 13.6 mm2/s (25 °C)

Explosive properties : Not classified

Oxidizing properties : Not classified

Surface tension : 28.6 mN/m, 22 °C

SECTION 10. STABILITY AND REACTIVITY

Reactivity : None reasonably foreseeable.

Chemical stability : Stable under normal conditions.

Possibility of hazardous reac- : Stable

tions

Conditions to avoid : None known.

Incompatible materials : Strong oxidizing agents

Hazardous decomposition : Carbon monoxide

products Carbon dioxide (CO2)

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Not classified based on available information.
Ingredients:
2,2,4-trimethyl-1,3-pentanediol monoisobutyrate :
Acute oral toxicity : LD50 Oral (Rat): 6,500 mg/kg

Acute inhalation toxicity : LC50 (Rat): > 3.55 mg/l

Exposure time: 6 h
Remarks: (highest concentration tested)

Acute dermal toxicity : LD50 Dermal (Rabbit): > 15,200 mg/kg

Skin corrosion/irritation
Not classified based on available information.

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SAFETY DATA SHEET

Eastman Texanol(TM) Ester Alcohol

Version Revision Date: SDS Number: Date of last issue: -

2.1 02/24/2017 150000000148 Date of first issue: 09/06/2016
SDSUS / PRD / 0001

Ingredients:
2,2,4-trimethyl-1,3-pentanediol monoisobutyrate :
Species: Rabbit
Exposure time: 4 h
Result: slight

Serious eye damage/eye irritation

Not classified based on available information.
Ingredients:
2,2,4-trimethyl-1,3-pentanediol monoisobutyrate :
Species: Rabbit
Result: slight

Respiratory or skin sensitization

Skin sensitization: Not classified based on available information.
Respiratory sensitization: Not classified based on available information.
Ingredients:
2,2,4-trimethyl-1,3-pentanediol monoisobutyrate :
Test Type: Skin Sensitization
Species: Guinea pig
Result: non-sensitizing

Germ cell mutagenicity

Not classified based on available information.
Ingredients:
2,2,4-trimethyl-1,3-pentanediol monoisobutyrate :
Genotoxicity in vitro : Test Type: Mutagenicity - Bacterial
Metabolic activation: +/- activation
Result: negative

: Test Type: Chromosome aberration test in vitro

Metabolic activation: +/- activation
Result: negative
Remarks: Read-across from a similar material

: Test Type: Mutagenicity - Mammalian

Metabolic activation: +/- activation
Result: negative
Remarks: Read-across from a similar material

Genotoxicity in vivo : Test Type: Mutagenicity - Mammalian

Species: Mouse
Application Route: oral: gavage
Result: negative

Carcinogenicity
Not classified based on available information.
IARC No ingredient of this product present at levels greater than or

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SAFETY DATA SHEET

Eastman Texanol(TM) Ester Alcohol

Version Revision Date: SDS Number: Date of last issue: -

2.1 02/24/2017 150000000148 Date of first issue: 09/06/2016
SDSUS / PRD / 0001

equal to 0.1% is identified as probable, possible or confirmed

human carcinogen by IARC.

OSHA No ingredient of this product present at levels greater than or

equal to 0.1% is identified as a carcinogen or potential carcino-
gen by OSHA.

NTP No ingredient of this product present at levels greater than or

equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

Reproductive toxicity
Not classified based on available information.
Ingredients:
2,2,4-trimethyl-1,3-pentanediol monoisobutyrate :
Effects on fertility :
Species: Rat
Application Route: Oral
NOAEL: NOEL 1,000 mg/kg,
F1: NOEL 1,000 mg/kg

Effects on fetal development : Species: Rat

Application Route: Oral
NOAEL (No observed adverse effect level)1,000 mg/kg
NOAEL (No observed adverse effect level) 300 mg/kg

STOT-single exposure
Not classified based on available information.
STOT-repeated exposure
Not classified based on available information.
Repeated dose toxicity

Ingredients:
2,2,4-trimethyl-1,3-pentanediol monoisobutyrate :
Species: Rat
NOAEL: 1,000 mg/kg
Application Route: by gavage
Exposure time: 51 d

Aspiration toxicity
Not classified based on available information.
Information on likely routes of exposure

Product:
Inhalation : Remarks: None known.

Skin contact : Remarks: None known.

Eye contact : Remarks: None known.

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SAFETY DATA SHEET

Eastman Texanol(TM) Ester Alcohol

Version Revision Date: SDS Number: Date of last issue: -

2.1 02/24/2017 150000000148 Date of first issue: 09/06/2016
SDSUS / PRD / 0001

Ingestion : Remarks: None known.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Ingredients:
2,2,4-trimethyl-1,3-pentanediol monoisobutyrate :
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 33 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 147.8 mg/l
aquatic invertebrates Exposure time: 48 h

Toxicity to algae : ErC50 (Pseudokirchneriella subcapitata (algae)): 15 mg/l

Exposure time: 72 h

Persistence and degradability

Ingredients:
2,2,4-trimethyl-1,3-pentanediol monoisobutyrate :
Biodegradability : Result: Readily biodegradable.
Biodegradation: > 77 %
Exposure time: 28 d
Method: Ready Biodegradability: CO2 Evolution Test

Bioaccumulative potential

Ingredients:
2,2,4-trimethyl-1,3-pentanediol monoisobutyrate :
Partition coefficient: n- : log Pow: 3.2 (25 °C)
octanol/water

Mobility in soil

Product:
Distribution among environ- : Medium: Soil
mental compartments log Koc: 1.5 - 2.8

Other adverse effects

Product:
Ozone-Depletion Potential : Regulation: 40 CFR Protection of Environment; Part 82 Pro-
tection of Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks: This product neither contains, nor was
manufactured with a Class I or Class II ODS as defined by the
U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A +
B).

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SAFETY DATA SHEET

Eastman Texanol(TM) Ester Alcohol

Version Revision Date: SDS Number: Date of last issue: -

2.1 02/24/2017 150000000148 Date of first issue: 09/06/2016
SDSUS / PRD / 0001

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Dispose of in accordance with local regulations.

SECTION 14. TRANSPORT INFORMATION

International Regulations

IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation

49 CFR
Not regulated as a dangerous good

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know

SARA 311/312 Hazards : No SARA Hazards

SARA 302 : No chemicals in this material are subject to the reporting

requirements of SARA Title III, Section 302.

SARA 313 : This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

Clean Air Act

This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by
the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean
Air Act Section 112 (40 CFR 61).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for
Accidental Release Prevention (40 CFR 68.130, Subpart F).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111
SOCMI Intermediate or Final VOC's (40 CFR 60.489).
Clean Water Act
This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act,
Section 311, Table 116.4A.

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SAFETY DATA SHEET

Eastman Texanol(TM) Ester Alcohol

Version Revision Date: SDS Number: Date of last issue: -

2.1 02/24/2017 150000000148 Date of first issue: 09/06/2016
SDSUS / PRD / 0001

This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act,
Section 311, Table 117.3.
This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section
307

The ingredients of this product are reported in the following inventories:

TSCA : On TSCA Inventory

DSL : All components of this product are on the Canadian DSL

AICS : On the inventory, or in compliance with the inventory

ISHL : On the inventory, or in compliance with the inventory

KECI : On the inventory, or in compliance with the inventory

PICCS : On the inventory, or in compliance with the inventory

IECSC : On the inventory, or in compliance with the inventory

TSCA list
No substances are subject to a Significant New Use Rule.

No substances are subject to TSCA 12(b) export notification requirements.

SECTION 16. OTHER INFORMATION

Full text of other abbreviations

AICS - Australian Inventory of Chemical S ubstances; AS TM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Sub-
stances List (Canada); ECx - Concent ration associated with x% response; EHS - Extremely Haz-
ardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys-
tem; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC -
International Agency for Research on Canc er; IA TA - International Air Transport Association; IB C
- International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals
in Bulk; IC50 - Half maximal inhibitory concentration; ICA O - International Civil A viation Organiza-
tion; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime
Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health
Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemi-
cals Inventory; LC50 - Let hal Concentration to 50 % of a test population; LD50 - Let hal Dose to
50% of a test population (Median Lethal Dose); MARPOL - Int ernational Convention for the Pre-
vention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Oth-
erwis e Specified; NFPA - National Fire P rotection Association; NO(A)EC - No Observed (Adverse)
Effect Concentration; NO(A )EL - No Observed (A dverse) Effect Level; NOE LR - No Observable
Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of
Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office

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SAFETY DATA SHEET

Eastman Texanol(TM) Ester Alcohol

Version Revision Date: SDS Number: Date of last issue: -

2.1 02/24/2017 150000000148 Date of first issue: 09/06/2016
SDSUS / PRD / 0001

of Chemical Safety and Pollution P revention; PB T - P ersistent, Bioaccumulative and Toxic sub-
stance; PICCS - Philippines Invent ory of Chemicals and Chemical Substances; (Q)SA R - (Quanti-
tative) Structure Activity Relationship; RCRA - Resourc e Conservation and Recovery Act;
REACH - Regulation (E C) No 1907/2006 of the E uropean Parliament and of the Council concern-
ing the Registration, E valuation, Authorisation and Restriction of Chemicals; RQ - Reportable
Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund Amend-
ments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance
Inventory; TS CA - Toxic Substanc es Cont rol Act (United States); UN - Unit ed Nations; UNRTDG -
United Nations Recommendations on the Trans port of Dangerous Goods; vP vB - Very Persistent
and Very Bioaccumulative
Further information

NFPA: HMIS® IV:

Flammability
HEALTH / 1
1 FLAMMABILITY
0
Instability
Health

0 0
PHYSICAL HAZARD 0

HMIS® ratings are based on a 0-4 rating

Special hazard. scale, with 0 representing minimal haz-
ards or risks, and 4 representing signifi-
cant hazards or risks.

Revision Date : 02/24/2017

The information provided in this Material S afety Data S heet is correct to the best of our
knowledge, information and belief at the dat e of its publication. The information given is designed
only as a guidance for safe handling, use, processing, storage, transportation, disposal and re-
lease and is not to be considered a warranty or quality specification. The information relates only
to the specific material designat ed and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.

US / Z8

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