Chemistry Exam

Chemistry Test ( Boards pattern questions)
Cbse Pattern
Time :3 hours
12th April 2020
MCQ 1x 10 = 10 marks
1. The molality of pure water is (a) 55.5 (b) 50.5 (c) 18 (d) 60.5
2. The number of moles of NaCl in 3 litres of 3M solution is (a) 1 (b) 3 (c) 9 (d) 27
3. Low concentration of oxygen in the blood and tissues of people living at high altitude is due
to _________ . (a) low temperature (b) low atmospheric pressure (c) high atmospheric pressure
(d) both low temperature and high atmospheric pressure
4. An unripe mango placed in a concentrated salt solution to prepare pickle, shrivels because
_________ (a) it gains water due to osmosis. (b) it loses water due to reverse osmosis. (c) it
gains water due to reverse osmosis. (d) it loses water due to osmosis.
5. The boiling point of an azeotropic mixture of water and ethanol is less than that of water
and ethanol. The mixture shows (a) no deviation from Raoult’s Law. (b) positive deviation from
Raoult’s Law. (c) negative deviation from Raoult’s Law. (d) that the solution is unsaturated.
6. . Benzoic acid, when dissolved in benzene, which of the following is correct. (a) The
benzoic acid will undergo dissociation. (b) The benzoic acid will undergo association. (c)
Observed molar mass of benzoic acid in benzene will less than normal molar mass. (d)
Observed molar mass of benzoic acid in benzene is more than normal molar mass
7. 21. Which has the highest freezing point? (a) 1 M glucose (b) 1 M NaCl (c) 1 M CaCl (d) 1 M
AlF3
8. 15. What is mole fraction of solute in 1.00 m aqueous solution? (a) 0.0354 (b) 0.0177 (c)
0.177 (d) 1.770
9. Conc. H SO is 98 % H SO by mass has d = 1.84 g cm . Volume of acid required to make one

litre of 0.1 M H SO is (a) 5.55 mL (b) 10 mL (c) 20 mL (d) 30 mL
10. The value of Henry’s constant K is _________ .(а) greater for gases with higher solubility. (b)
greater for gases with lower solubility. (c) constant for all gases. (d) not related to the
solubility of gases
One markers 1x6 = 6
1.State the condition resulting in reverse

Osmosis
2.Give the example of amalgam
3.State the main advantage of molality over

molarity as the unit of concentration.
4.What is meant by colligative properties?
5. Define the following term :

Molal elevation constant (Kb)
6.How is the vapour pressure of a solvent affected

when a non-volatile solute is dissolved in it?
2 marks question (15x2=30)
1.Calculate the molarity of 9.8% (w/W) solution

of H2SO4 if the density of the solution is
1.02 g mL–1.
(Molar mass of H2SO4 = 98 g mol–1
2.Differentiate between molarity and molality of

a solution. How can we change molality value
of a solution into molarity value?
3.Define :
(i) Mole fraction (ii) Molality
4.An antifreeze solution is prepared from 222.6 g

of ethylene glycol (C2H4(OH)2) and 200 g of
water. Calculate the molality of the solution.
If the density of this solution be 1.072 g mL–1
what will be the molality of the solution?
5.A solution of glucose (molar mass = 180 g mol–1)

in water is labelled as 10% (by mass). What
would be the molality and molarity of the
solution?
(Density of solution = 1.2 g mL–1)
6.State Henry’s law correlating the pressure of a

gas and its solubility in a solvent and mention
two applications for the law.
7.What is meant by positive and negative
deviations from Raoult’s law and how is the
sign of DeltamixH related to positive and negative
deviations from Raoult’s law?
8.Explain why a solution of chloroform and

acetone shows negative deviation from Raoult’s
law.
9.What type of intermolecular attraction exists

in each of the following pairs of compounds :
(i) n-hexane and n-octane
(ii) methanol and acetone
10.Defne the terms, ‘osmosis’ and ‘osmotic

pressure’. What is the advantage of using
osmotic pressure as compared to other
colligative properties for the determination of
molar masses of solutes in solutions?
11.Why does a solution containing non-volatile

solute have higher boiling point than the pure
solvent? Why is elevation of boiling point a
colligative property?
12.An aqueous solution of sodium chloride freezes

below 273 K. Explain the lowering in freezing
point of water with the help of a suitable
diagram.
13.Outer hard shells of two eggs are removed.

One of the egg is placed in pure water and the
other is placed in saturated solution of sodium
chloride. What will be observed and why
14. What is van’t Hoff factor? What types of values

can it have if in forming the solution the solute
molecules undergo
(i) Dissociation (ii) Association
15. the molecular masses of polymers are

determined by osmotic pressure method and
not by measuring other colligative properties.
Give two reasons.
Three Markers 8x3= 24
1.The partial pressure of ethane over a saturated

solution containing 6.56 × 10–2 g of ethane is
1 bar. If the solution contains 5.0 × 10–2 g of
ethane, then what will be the partial pressure
of the gas?
2.If N2 gas is bubbled through water at

293 K, how many millimoles of N2 gas would
dissolve in 1 litre of water? Assume that N2
exerts a partial pressure of 0.987 bar. Given
that Henry’s law constant for N2 at 293 K is
76.48 k bar
3.18 g of glucose, C6H12O6 (Molar mass =

180 g mol–1) is dissolved in 1 kg of water in
a sauce pan. At what temperature will this
solution boil?
(Kb for water = 0.52 K kg mol–1, boiling point
of pure water = 373. 15 K)
4.Some ethylene glycol, HOCH2CH2OH, is added

to your car’s cooling system along with 5 kg
of water. If the freezing point of water-glycol
solution is –15.0°C, what is the boiling point of
the solution?
(Kb = 0.52 K kg mol–1 and Kf = 1.86 K kg mol–1
for water)
5.A 0.1539 molal aqueous solution of cane sugar

(mol. mass = 342 g mol–1) has a freezing point
of 271 K while the freezing point of pure
water is 273.15 K. What will be the freezing
point of an aqueous solution containing 5 g of
glucose (mol. mass = 180 g mol–1) per 100 g of
solution.
6.A solution containing 8 g of a substance in

100 g of diethyl ether boils at 36.86°C, whereas
pure ether boils at 35.60°C. Determine the
molecular mass of the solute. (For ether
Kb = 2.02 K kg mol–1)
7.A decimolar solution of potassium ferrocyanide

K4[Fe(CN)6] is 50% dissociated at 300 K.
Calculate the value of van’t Ho_ factor for
potassium ferrocyanide.
8.The depression in freezing point of water
observed for the same molar concentration
of acetic acid, trichloroacetic acid and
tri_uroacetic acid increases in the order as
stated above. Explain.
(ii) Calculate the depression in freezing point
of water when 20.0 g of
CH3CH2CHClCOOH is added to 500 g of
water.
[Given : Ka = 1.4 × 10–3, Kf = 1.86 K kg mol–1]

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Chemistry Exam

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Chemistry Test ( Boards pattern questions)

12th April 2020

9. Conc. H SO is 98 % H SO by mass has d = 1.84 g cm . Volume of acid required to make one

1.State the condition resulting in reverse

2.Give the example of amalgam

3.State the main advantage of molality over

4.What is meant by colligative properties?

5. Define the following term :

6.How is the vapour pressure of a solvent affected

2 marks question (15x2=30)

1.Calculate the molarity of 9.8% (w/W) solution

2.Differentiate between molarity and molality of

4.An antifreeze solution is prepared from 222.6 g

5.A solution of glucose (molar mass = 180 g mol–1)

6.State Henry’s law correlating the pressure of a

8.Explain why a solution of chloroform and

9.What type of intermolecular attraction exists

10.Defne the terms, ‘osmosis’ and ‘osmotic

11.Why does a solution containing non-volatile

12.An aqueous solution of sodium chloride freezes

13.Outer hard shells of two eggs are removed.

14. What is van’t Hoff factor? What types of values

15. the molecular masses of polymers are

1.The partial pressure of ethane over a saturated

2.If N2 gas is bubbled through water at

3.18 g of glucose, C6H12O6 (Molar mass =

4.Some ethylene glycol, HOCH2CH2OH, is added

5.A 0.1539 molal aqueous solution of cane sugar

6.A solution containing 8 g of a substance in

7.A decimolar solution of potassium ferrocyanide

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