Vidyamandir Classes

SOLUTIONS
JEE Main – 2020 | 9th January 2020 (Morning Shift)
PHYSICS
SECTION – 1
1.(3)

h h 3 2
Apparent depth d    h
2 2 2 4

2.(4)

4 6 20
Req    2  i from battery  A  10 A
5 5 2
Current division in the resistors is as shown,

 iBD  2 A

3.(2) V 1  uiˆ
 iˆ  ˆj 
V 2  u 
 2 
As collision is completely inelastic both particles move with the same velocity after collision.
Conserving linear momentum.
m1V 1  m2V 2  ( m1  m2 )V

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 i  ˆj   3iˆ  ˆj 
 muiˆ  mu    2mV  V  u 
 2   4 
1 1  u 2  3mu 2
(KE)initial  mu 2  m   
2 2  2  4
1  10u 2  5mu 2
(KE)final  (2m)  
2  16  8
mu 2
Loss in energy  ( KE )initial  ( KE ) final 
8
E0 E
4.(2) B1  cos(t  kx) kˆ & B2  0 cos(t  ky ) iˆ
C C
F 1  q V  B1   qE1  q0.8 E0iˆ  qE0 ˆj
F 2  q V  B 2   qE 2  q0.8E0 kˆ  qE0 kˆ  0.2qE0 kˆ
F  F 1  F 2  qE0  0.8iˆ  ˆj  0.2kˆ 

5.(4) [c]  [ LT 1 ]
[ h]  [ ML2T 1 ]
[G ]  [ M 1L3T 2 ]
[ f ]  [h]1/ 2 [c]5 / 2 [G ]1/ 2
 [ M 1/ 2 L1T 1/ 2 ][ L5 / 2T 5 / 2 ][ M 1/ 2 L3 / 2T 1 ]
 [ ML2T 2 ]

d
6.(1) dOA  dOB  dOC 
3
2  d  22
 d  
I0   M    M   3
 5  2   3  
 Md 2 Md 2 
  3
 10 3 
39 Md 2 13Md 2
 
30 10
2 2
2  d  2  d  
IA  M     M    Md 2   2
5  2  5  2  
Md 2 11Md 2  23Md 2 I 0 13
  2   
10  10  10 I A 23

h 1 1 E2
7.(2)     
2mE E 2 E1
 E2
  E2  4 E1

  E1
 
2
Also, E1  E & E  E  E
 E  E  4 E  E  3E

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0 I  I
8.(1) BA   0
2(2a) 4a
a
0 I  
BB   3   0 I
2 a 2 6 a
BB 4 2
 
BA 6 3

9.(2) PA  PB  P  700 Nm 2
A0  40cm 2 AB  20cm 2
By equation of continuity
Q  AAVA  ABVB  VB  2VA
1 1
PA  VA2  PB  VB2
2 2
1 1
PA  PB   (2VA ) 2  (VA ) 2   3(VA ) 2
2 2
1 Q2
700  (1000)  8
 Q  2732 cm3 / s
2 1600  10

k p
10.(1) E  Direction of electric field is opposite to P
r3
Hence E  iˆ  3 ˆj  2kˆ

11.(1)

Aresultant  A 0  2  1
2
Iresultant   2  1 I 0  5.8I 0

1 1
12.(3) WE  WB  k  qE (2a)  0  m(2V ) 2  mV 2
2 2
3mV 2 3mV 2
 qE (2a)  ; E
2 4qa
Power at P duet to E  F  V
 qE  V
3mV 2 3mV 3
q V 
4qa 4a
Power at Q  F E  V  F B  V  0  F E  V & F B  V 
L  m(2a)(2V )  maV  3maV

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13.(3) F   xiˆ  yjˆ

B (0,1)


W  F  ds   (  xi  yj )  (dxiˆ  dyjˆ )
0 (1,0)
0 1


  xdx  ydy 
0 0
0 2 1
 x  y 
        1J
 2 1  2  0

14.(1) lmin  r  min

1.22  5500  1010
 4  108   53.68 m
5
Hence l is close to 60 m

 4   3 
k      
3  2   k 4R
15.(4) EA  0  2

R 6
 
2
3
 4 3  k   4     
k   R     
EB  3    3  2    17  k 4R 
 
R2  3R 
2 9 6 
 
 2 
EA 9 18
 
EB 17 34

fR
16.(2) CV 
2
f R f R
CVA  A & CVB  B
2 2
CVA  CVB  f A : f B
=5:7 ( Diatomic gas)

12400
17.(2) E photon   1.89eV
6561
mVmax
Radius of most energetic electron: r 
Bq
1 2 B 2q2r 2
 mvmax 
2 2m
(3  104 )2 (1.6  1019 ) 2 (10  103 ) 2
K max  eV
2  9.1  1031 (1.6  1019 )
 0.79eV
K max  E photon  
   1.89  0.79  1.1eV

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18.(4) At after collision velocity of the combined mass is less than the velocity required for circular motion
hence the combined body will move in elliptical path around the planet.

3
19.(3) Pitch of the screw gauge  mm  0.5mm
6
Pitch 0.5
Least count   mm  0.01mm  0.001cm
( No. of divisions 50
on circular scale)

20.(4) 1  2 : Adiabatic process (TV 1  k )

2  3 : Isobaric process (V / T  k )
3  1 : Isobaric process (V = k)
Hence V – T graph will be

SECTION – 2
21.(15) Loss in GPE = Gain in KE
l 1
mg sin 30  I H 2
2 2
2
l  1  1 ml 2
mg    
2 2 2 3
3gl 3  10  1
2
 2     15s 1
2l 2
n  15

22.(3) x 2  at 2  2bt  C
at  b
2 xV  2at  2b  xV  at  b  V 
x
V 2  xa  a
2
 at  b 
a  
a V 2  x 
Acceleration  
x x
ax 2  ( a 2t 2  b2  2abt ) a 2t 2  2abt  ac  a 2  2  2abt  b 2 ac  b 2
  
x3 x3 x3
Acceleration  x 3  x3

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23.(4) Tension in the string T  m2l

Breaking stress  4.8  107 Nm 2
Maximum tension in the string (Tmax )  4.8  107  10 6 N  48 N
48
m2max l  48  max   4rad / s
10  0.3

di i  0.25  0 
24.(10) VL  L L  100  L  3 
 L  102 H  10 mH
dt t  0.025  10 

25.(12)

Assume VB  0V
Hence right diode is reversed bias. As built in potential is 0.7V  VA  12V

CHEMISTRY
SECTION – 1
Ea Ea
 1  2
RT1 RT2
1.(3) r1  Ae ; r2  Ae

r1  r2 [Given]
  Ea1    Ea 2 
    Ea1 Ea 2
RT RT
, Ae 1   Ae 2  Or 
T1 T2

Also, Ea 2  Ea1  30, T1  700 K, T2  500 K (Given)

Ea1 Ea1  30
, 
700 500
Or 5Ea1  7 Ea1  210

2 Ea1  210

Ea1  105kJ / mol

Ea 2  105  30

Ea 2  75kJ / mol

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
Θ
2.(1) (v) C N  least basic [-ve charge on sp-hybridised C-atom bonded to an electro-ve N-atom.]
Θ Θ
(iii) HC  C  More basic than C N but less basic than the others as –ve charge is present on sp-
hybridised C-atom.

(ii) -ve charge is present on allylic C-atom, therefore, can be delocalized

by mesomeric effect
CH3
Θ
 |
(iv) CH3 (i) H 3C  C : Θ
|
CH3
(i) is more basic than (iv) due to + I-effect of 3 Methyl groups in (i) and these two are more basic than
the others due to no stabilizing factor for –ve charge.
So, order of basicity: (v) < (iii) < (ii) < (iv) < (i)

3.(3) In the given diagram, the plot for A  O 2  AO2 is below the plot for B  O2  BO 2 when
T  1400C, which shows that A can spontaneously reduce BO 2 .

4.(2) (I) Electron from 2p can be removed more easily than from 2s, as nucleus shows less
attraction towards 2p electrons than 2s electron. Hence B has smaller first Ionization enthalpy.
(II) Shielding of 2p (Shielding by 4 Inner electrons) is more than 2s (Shielding by 3 inner
electrons)
(III) Order of penetration power: s > p > d > f (fact)
(IV) Atomic Radius of B is less than be
Hence, It is incorrect option.
Correct option is (2) (I), (II) and (III)

5.(1)

h nh
6.(3) n  ; mvn rn 
mvn 2
nh n
rn   n
2mvn 2
2rn 2n 2a 0
n  ; n 
n n
 n  (2a 0 )n
Here, n = 4,    8a 0

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7.(2) Magnetic moment  n(n  2) B.M.  3.85 of complex

 n(n  2)  3.83
 n(n  2)  15
 n (no. of unpaired electrons) = 3
So, Cr x  has 3 unpaired electrons, then x has to be 3
Hence complex is Cr(H 2O)6 Cl3
As complex shows geometrical Isomerism and also react with AgNO3 , Hence formula of complex is
 Cr(H 2 O)4 Cl2  Cl  2H 2O
IUPAC Name: Tetraaquadichlorido chromium (III) chloride dihydrate
Correct option is (2)

8.(4)

Answer (4)

9.(3)

Clearly, xy

10.(3)

Saccharin: B

Alitame: D
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Aspartame: A

Sucralose: C

11.(4)

12.(1) Given: PbCl2 (s)  Pb2 (aq)  2Cl (aq), K sp  1.6  105
And 300 mL of 0.134 M Pb(NO 3 )2 with 100 mL of 0.4 M NaCl
On mixing above two solutions, Molar concentration changes as volume changes. Hence New molar
concentrations are as follow:
For Pb(NO3 )2 :
300  0.134
 M New Pb NO3  
2 400
 M New Pb NO3   0.1005
2

So, M  0.1005
Pb2 
For NaCl:
100  0.4
 M New  NaCl 
400
 M New  NaCl  0.1
So, M  0.1
Cl
For a reaction,
Q(Re action Quotient)  Pb 2  [Cl ]2t
 t
Q  0.1005  (0.1) 2
Q  1.005  103  K sp
Hence, Correct option is (1) Q  Ksp
Reaction will go in Backward direction i.e. precipitation of PbCl2 (s)

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1
13.(2) Heat of combustion (HOC) 
Stablity of an alkene
i.e., As the stability increases, Heat of combustion decreases and order of stability of an alkene is
Trans > cis (due to less steric Hindrance in Trans alkenes)

Hence, Stability order:

Stability order (c) > (b) > (a)

14.(3) Compound in which central atom is present, in its Intermediate oxidation state can act as both Oxidant
as well as Reductant.
+4 1 4
So HNO2 , H 2 O 2 , H 2SO3 , can act as both Oxidising and Reducing agent
-5
But In H3PO4 , phosphorous is present in its highest possible Oxidation state. Hence can act only as
oxidizing agent But not as Reducing agent since phosphorous can’t be oxidised further.
Correct option is (3) H3PO 4

15.(3) N 2 O3 , Li 2O, Al2 O3

N 2 O3 is a acidic oxide (it is a non metal oxide)
Whereas, Li2 O oxide of Li (alkali metal) is Basic in nature and Al2O3 reacts with both acids and
alkali and Hence it is amphoteric in nature.
Other examples of Amphoteric oxides are ZnO, BeO, Ga 2 O3 , Cr2O3 etc.

16.(1) ZnS, SiC are covalent solids and hence they have high melting paints.
Hg being a metal conduct electricity in liquid state.
CCl4 is Non-polar having low MP and is non- conductor in both liquid and solid state.

17.(3)

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18.(3) Electronic configuration of O 2 as per MOT is

O2 :   2     
1s 2 1s 2s2 2s 2 2pz 2 2px 2
2px1

 2  1
2py 2py

O 2 has 2 unpaired electrons,

 O 2 , O 2 will have 1 unpaired electron

19.(3) Eu : [Xe]4 f 1 6s 2  Eu 2 :[Xe] 4f 7

Ce : [Xe]4 f 1 5d1 6s 2  Ce3 :[Xe] 4f 1

20.(3) [Pd(F) (Cl) (Br) (I)]2 is square planar of the type [M abcd]n 
Hence No. of geometrical Isomers for [M abcd]n   3
 n 3
3
n 6  3 
 Fe(CN)6   Fe(CN)6 
 
Fe3 : 3d5 & CNΘ is a strong field ligand
CFSE  5  (0.4 0 )   2.0  0
Here, no. of unpaired e   1
 Spin only magnetic moment  1(1  2)  3 B.M  1.73B.M

SECTION – 2
21.(100) 103 M MgSO4
103 moles MgSO 4 in 1 L solution
 2  103 gm eq of MgSO 4 in 1 L solution
 2  103 gm eq of Ca CO3 in 1 L solution
 103 mole Ca CO3 in 1 L solution
 103  100 gm Ca CO3 in 1 L solution
 0.1gmCa CO3 in 1 L solution
 0.1 gm Ca CO3 in 1000 gm solution
 0.1  103 gm Ca CO3 in 106 gm solution
 100 gm Ca CO3 in 106 gm solution 100 ppm CaCO3

22.(37.84)

 Molecular Formula  C5 H9 N3
Molar mass  111gm / mol
Mass of N per mole  3  14  42gm
42
 Mass% of N   100  37.84%
111

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10 xd
23.(14) Using the standard result M 
M0
Where, x  mass%
d  density (gm / ml)
M 0  Molar mass
10  63 1.4
 Molarity(M)   14 mole / l
63

24.(5.67) Ag   e 
 Ag 
1F charge deposits 1 mole Ag i.e. 108 gm Ag
 Quantity of Electricity required = 1 F
1
H 2O   O 2  2H   2e 
2
1
Here 2 F charge   mole O 2
2
1
So, 1F charge   mole O 2
4
1
n O RT 4  0.08314  273
VO2  2   5.674 litre
P 1

25.(1.76) Here NaCl is to be added to water such that afterwards Freezing point of water should be
–0.2°C .
 Depression in Freezing point  0.2  Tf
We know, Tf  i  K f  m 
i NaCl  2
 m NaCl 
 58.5 
 0.2  2  2     m NaCl  1.76 gm
 600 
 
 1000 

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MATHEMATICS
SECTION – 1
1 1
2 bx 2 cx3  b c
1.(3)  (a  bx  cx ) dx  ax 
2

3
 a   
 2 3
0 0
f (1)  a  b  c
f (0)  a
1 b c
f  a 
2 2 4
Now,
1  1 
f (1)  f (0)  4  f  
6   2 
1  b c 
 a  b  c  a  4  a   
6  2 4 
1 b c
 6a  3b  2c   a  
6 2 3
So option (3) satisfies.
1
 sin( a  2) x  sin x
2.(2) LHL  f (0 )  lim   (a  2)  a3
x  0  (a  2) x 
 x
f (0)  b
 (1  3x )1/ 3  1 
RHL  f (0 )  lim   1
x  0  x 
For continuity at x = 0,
f (0 )  f (0)  f (0 )
 a  3  b 1  a  2 ; b = 1
Hence, a  2b  0

3.(4) | z  i |  | z  2i |  | z  ( 2i )
This is the equation of perpendicular bisector of the line segment joining (0, 1) & (0, -2)

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| z  3i |  | z  (3i ) |
2 25
  6 
4
25 49 7
 6  
4 4 2
1 2 3
  ......
4.(4) 24 16 48

1 1
4 4
1 1 1 1 1 1
  ..... 1
4 8 16
2 2 2  22  22  2

5.(3) f '( x )  tan 1 (sec x  tan x )

  2
x x 
  sin  cos  
 1  sin x  1  2 2 
 tan 1    tan 
 cos x   2 x 2 x
  cos  sin  
 2 2
   x   x
 tan 1  tan      
  4 2  4 2
 x  x2
  f '( x) dx   
4   dx
2
 f ( x) 
4
x
4
C

 x2  1
f (0)  C  0  f ( x )  x  f (1) 
4 4 4
6

 x 3  7 1
6.(2)  
 x4
 
( x  4) 2
dx

x 3 7
Let t
x4
1/ 7
7  x 3 
2
dx  7t 6  dt  t 6  t 6 dt  t  C  
  C
( x  4)  x4

7.(1) Applying tangent secant theorem

OA  OB  OP 2
 2  OB  16
 OB  8
 B  (8,0)
Equation of circle
( x  5)2  ( y  4) 2  52
C (5,4) ; r  5
For tangency, distance from centre i.e, p = r
Now,
(i) 4x  3 y  8  0
| 4  5  3  4  8 | 24
p   r  Not tangent
5 5

VMC | JEE Main-2020 14 Solutions |9th January Morning

 Vidyamandir Classes

(ii) 3 x  4 y  24  0
| 3  5  4  4  24 |
P  5  r  Tangent
5
(iii) 3x  4 y  6  0
3 5 4 4  6
P  5  r  Tangent
5
(iv) 4 x  3 y  17  0
| 4  5  3  4  17 |
P  5  r  Tangent
5

8.(2)  ( p  q)  p  q
5 is not an integer and 5 is not irrational.

 ( xi  5) 10
9.(4) ( xi  5)   1
10 10
( xi  3) [( xi  5)  2]
  1 2  3
10 10
 ( xi  5) 2  ( xi  5)
  3
10 10

  3  3 
10.(4) sin     cos  sin
2 8  8 8
 3  3
 cos3  cos  sin 3  sin
8 8 8 8
   
 cos3  sin  sin 3  cos
8 8 8 8
   
 sin  cos  cos2  sin 2 
8 8 8 8
1  1
 sin 
2 4 2 2

11.(3) Let’s apply LMVT for x  [a, c ]

f (c )  f (a )
 f '( x1 ); x1  ( a, c)
ca
Also, applying LMVT for x  [c, b]
f (b)  f (c )
 f '( x2 ) ; x2  (c, b)
bc
 f ''( x )  0  f '( x) is decreasing
 If , x1  x2 , then f '( x1 )  f '( x2 )
f (c)  f ( a) f (b)  f (c)
 
ca bc
f (c)  f ( a ) c  a
  ( f(x) is increasing )
f (b)  f (c) b  c

VMC | JEE Main-2020 15 Solutions |9th January Morning

 Vidyamandir Classes

12.(3)
2

Number of numbers  8  8  7  6  2688  336K

 K 8

13.(1) Let, thickness be x can

4
Total volume, V  (10  x)3
3
dV dx
 4(10  x ) 2  …(i)
dt dt
dV
Now,  50cm3 / min (Given)
dt
dx dx 1
 50  4  (10  5)2    cm / min
dt dt 18

 3  1  2 1  3  4 
14.(4) C   , 
 3 3 
  2,2 
P : x  3y 1  0 …(i)
3x  y  1  0 …(ii)
(i)  (ii )  3
1
10 x  2  0  x 
5
1 2
y  3 1 
5 5
 1 2 
 P , 
 5 5
Equation of line passing through points C & P
2
2
y2 5 ( x  2)
1
2
5
8
 ( x  2)
11
 11y  22  8 x  16  8 x  11y  6  0 ; also passes through (-9, -6)

x2 y2 4 14 7 7
15.(1)   1 ; e1  1    
18 4 18 18 9 3
x2 y2 4 13 13
  1 ; e2  1   
9 4 9 9 3
 7 13  2 2
(e1 , e2 )   ,  lies on the ellipse 15 x  3 y  k
 3 3 
7 13 105  39 144
 15   3   k  k   16
9 9 9 9

VMC | JEE Main-2020 16 Solutions |9th January Morning

 Vidyamandir Classes

16.(1) e 4 x  e3 x  4e 2 x  e x  1  0
Divide by e 2x on both sides
 1   1 
 e2 x  e x  4  e  x  e 2 x  0   e2 x  2 x    e x  x   4  0
 e   e 
 1   1
 Let e x  t ; t  (0, )   t2  2    t    4  0
 t   t
2
 1  1
 t    2  t    4  0
 t  t
1 1  5
Let t   y ; y  (,  2]  [2, )  y2  y  6  0  y   2, 3
t 2
1 1
t   2,  3  t   2  t 1  ex  1  x0
t t
1 3  5
 t   3  t 2  3t  1  0  t ; No solution
t 2

17.(4) Required probability  AA  ABA  BAA  ABBA  BABA  BBAA

1 1 1 1 1 1
     
4 8 8 16 16 16
1 1 3 1 3 11
     
4 4 16 2 16 16

18.(4) Let x  7 y  5 z    0 passes through line of intersection of x  4 y  2 z  1  0 & x  5 y  z  5  0

 x  7 y  5 z    0 can be written as ( x  4 y  2 z  1)   ( x  5 y  z  5)  0 ;   R
 x(1  )  y (5  4)  z (  2)  (5  1)  0
1   5  4   2 1(5  1 1   5  4
       7  7  5  4
1 7 5 1 1 7
3
 2  3    
2
  2 3 1 5  1
 1   1   1 
5 2 2 
5 1  5
   2     13
2 1 
9
      3 ;     10
2
2
x sin8 x
19.(4) Let I   sin8 x  cos8 x dx
0
Substitute x  2  x
2 2
(2  x)sin 8 x 2 sin 8 x
I  sin8 x  cos8 x dx  2I   sin8 x  cos8 x dx
0 0
2a a
Using the property  
f ( x )dx  2 f ( x )dx
0 0
If f ( x )  f (2a  x)

VMC | JEE Main-2020 17 Solutions |9th January Morning

 Vidyamandir Classes

/2 /2
sin 8 x sin 8 x
 2 I  2  4  sin8 x  cos8 x
dx  I  4  sin8 x  cos8 x
dx
0 0


Substitute x  x
2
/ 2
cos8 x
I  4  sin8 x  cos8 x
dx
0
/2 2
 x sin8 x
2 I  4  dx  4   22  I   sin8 x  cos8 x dx  
2
2
0 0

1 1 2 
20.(2) A  1 3 4  ; | A |  1(9  4)  1(3  4)  2( 1  3)  13  1  8  6
1 1 3 
B  adj ( A) C  3A
 | B |  | adj ( A) | | C |  | 3A |
 | A |2  33 | A |  27 | A |
| adj ( B) | | A |4 | A |3 63
 | adj ( B ) |  | B |2  | A |4     8
|C | 27 | A | 27 27
SECTION – 2
21.(8)

Projection
 
of AB on CD
AB  CD
 
| CD |
(4iˆ  4 ˆj  7 kˆ) 4  12  56 72
 (iˆ  3 ˆj  8kˆ )    8
81 9 9
22.(615) (1  x  x 2 )10
10! 10!(1) x 2 
General Term: (1) ( x) ( x 2 )   ; where       10
 !  !  ! !  !
If   2   4
10! 10  9
  0,   2 ;   8   45
8! 0! 2! 2
10! 10  9  8  7!
  2,   1,   7   360
7! 2!1! 7!  2
10! 10  9  8  7  6!
  4,   0,   6   210
6! 4! 0! 6!  24
Coefficient of x 4 is 45  360  210  615

VMC | JEE Main-2020 18 Solutions |9th January Morning

 Vidyamandir Classes

23.(3) ( x  1) dy  (( x  1) 2  y  3) dx
dy  1  3
    y  x 1
dx  x  1  x 1
 dx
Integrating factor  e  x 1  e  ln ( x 1) 
1
x 1
1 1  3 
y
x 1
 
x 1   ( x  1) 
x  1 
dx

3
 1  ( x  1) 2
dx

3
x C
x 1
 3 
 y  ( x  1)  x   C
 x 1 
Given y (2)  0  x  2 & y  0
 3 
 0  3  2   C   C  3
 3 
 3 
y  ( x  1)  x  3 
 x  1 
 3
Put x  3  y (3)  4 0    3
 4
y (3)  3
 3
24.(8) log 1 | sin x |  2  log 1 | cos x | ; | sin x |  0 & | cos x |  0  x  0, , , , 2
2 2
2 2
 log 1 | sin x |  log 1 | cos x |  2
2 2
 log 1 | sin x cos x |  2
2
1
 | sin x cos x | 
4
1
 | sin 2 x | 
2
1
sin 2 x  
2
x  [0,2]

No. of solutions = 8

VMC | JEE Main-2020 19 Solutions |9th January Morning

 Vidyamandir Classes
  
25.(1)  p, q, r are coplanar vectors
  
 p, q , r   0
a 1 a a
1
a a 1 a  0  a  
3
a a a 1
 
p  q  a (a  1)  a( a  1)  a 2
 a 2  a  a 2  a 2  3a 2  2a
1 2
 3 
9 3
1 2 1
  
3 3 3
 2 2  2  2
|r q |  |r | |q| |r q |
2
2 2  1
   
3 3  3
4 1 3 1
   
9 9 9 3
2
  2    1  1
3  p  q    | r  q |2  3      
 3  3
1 
  0
3 3
 1

VMC | JEE Main-2020 20 Solutions |9th January Morning