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Dushyantha Et Al., 2020
Dushyantha Et Al., 2020
Keywords: Rare earth elements (REEs) including fifteen lanthanides, yttrium and scandium are found in more than 250
Rare earth elements (REEs) minerals, worldwide. REEs are used in various high-tech applications across various industries, such as electrical
Rare earth applications and electronics, automotive, renewable energy, medical and defence. Therefore, the demand for REEs in the
Rare earth deposits and genesis global market is increasing day by day due to the surging demand from various sectors, such as emerging
Rare earth demand
economies, green technology and R&D sectors. Rare earth (RE) deposits are classified on the basis of their
Environmental concerns
genetic associations, mineralogy and form of occurrences. The Bayan Obo, Mountain Pass, Mount Weld and
China’s ion adsorption clays are the major RE deposits/mines in the world to date and their genesis, chronology
and mineralogy are discussed in this review. In addition, there are other RE deposits, which are currently being
mined or in the feasibility or exploration stages. Most of the RE resources, production, processing and supply are
concentrated in the Asia-Pacific region. In this regard, China holds the dominancy in the RE industry by pro-
ducing more than 90% of the current rare earth requirements. Thus, REEs are used as a powerful tool by China in
trade wars against other countries, especially against USA in 2019. However, overwhelming challenges in
conventional RE explorations and mining make secondary RE resources, such as electric and electronic waste (e-
waste) and mine tailings as promising resources in the future. Due to the supply risk of REEs and the monopoly of
the REEs market, REEs recycling is currently considered as an effective method to alleviate market fluctuations.
However, economical and sustainable processing techniques are yet to be established to exploit REEs via re-
cycling. Moreover, there are growing ecological concerns along with social resistance towards the RE industry.
To overcome these issues, the RE industry needs to be assessed to maintain long-term social sustainability by
fostering the United Nations sustainable development goals (SDGs).
1. Introduction element, which does not occur naturally (De Lima and Leal Filho,
2015). Due to the similar geochemical behavior of Y and Sc to the
Rare earth elements (REEs) are governing the modern lifestyle of lanthanides (Sc only in aqueous medium), they are also considered as
people, although many people do not aware of the enormous impacts of REEs (McLennan and Taylor, 2012; Voncken, 2016). These elements are
these elements. However, it has been critical to pay attention to this mostly found in trivalent oxidation state, whereas europium (Eu) can
special group of metals, REEs, due to the important role in modern also be found in divalent, while cerium (Ce) exhibits tetravalent states
industrial advancement towards a green economy. REEs were first (Leybourne et al., 2000; Wang and Liang, 2016).
discovered as a new set of elements at the end of the 18th century in Generally, atom radii get larger as atomic numbers increase due to
Sweden (Preinfalk and Morteani, 1989; Voncken, 2016). As stated in the attachment of electrons to the outer shell, however, REEs display
the International Union of Pure and Applied Chemistry (IUPAC), REEs decreasing atom radii with the increase of atomic numbers. This phe-
are a group of seventeen chemical elements, including yttrium (Y), nomenon is known as lanthanide contraction. It occurs when electrons
scandium (Sc) and fifteen metallic elements of the lanthanide series in “f” orbitals do not screen the other electrons from the positive pull
(Table 1). Among them, Promethium (Pm) is the only rare earth towards the nucleus. Then, the electrons are pulled towards the nucleus
⁎
Corresponding author.
E-mail address: [email protected] (N. Dushyantha).
https://doi.org/10.1016/j.oregeorev.2020.103521
Received 29 January 2020; Received in revised form 25 March 2020; Accepted 5 April 2020
Available online 06 April 2020
0169-1368/ © 2020 Elsevier B.V. All rights reserved.
N. Dushyantha, et al. Ore Geology Reviews 122 (2020) 103521
Table 1
Description of rare earth elements (REE) (Sources: Taylor and McClennan, 1985; Samson and Wood, 2005; Castor and Hedrick, 2006 and McLemore, 2015). *
Promethium does not occur naturally.
Rare Earth Element Symbol Oxide Conversion Factor (% oxide = % element × conversion factor) Atomic Number Abundance in the upper crust (ppm)
to reduce the atom radii as atomic number increases (Wang and light-emitting diode bulbs (LEDs) (Machacek et al., 2015). Eu, the most
Schwarz, 1995; Wall, 2014), which allows REEs to show diverse che- prominent example, has turned into a highly demanded REE in last half
mical reactivities (Braun et al., 1993; Lee and Byrne, 1993; Braun and of the 20th century, since it was used as a colour-producing phosphor in
Pagel, 1994; Aide and Smith-Aide, 2003). video screens along with Tb and Y (Mertzman, 2019). The usage of
REEs are often categorised into two sub-groups as light rare earth REEs in modern technology has reduced the requirement of other ma-
elements (LREEs) and heavy rare earth elements (HREEs). The elements terials and increased efficiency at a higher rate. Therefore, REEs are
from 57La to 63Eu are considered as LREEs, whereas the elements from defined as “The Vitamins of Modern Industry” (Balaram, 2019). Table 3
64
Gd to 71Lu, including Y are categorised as HREEs. These two cate- shows the specific REE requirements in some applications.
gories of REEs occur in same deposits altogether except Sc. Therefore,
Sc is not included any of the above sub-groups. In general, LREEs are 2.1. Role of REEs in green energy applications
more abundant than HREEs (McLemore, 2015).
REEs do not occur as native elements in nature and they are found The world’s energy requirements have been steadily increasing for
in the form of minerals, such as phosphates, silicates, carbonates, oxides the last few decades and most of the energy demands are fulfilled by the
and halides (Vijayan et al., 1989; Jordens et al., 2013). Earth’s crust fossil-fuel-based energy sources, such as oil, coal and natural gas. As a
accounts for 169.1 ppm of total abundance of REEs, including result, consequences such as air pollution, global warming and climate
137.8 ppm of LREEs and 31.3 ppm of HREEs. Therefore, REEs are not as change have become overwhelming concerns in the present world.
rare as their name suggests. Most of the LREEs have similar abundances Furthermore, impending issues, such as oil price volatility, geopolitical
in the Earth’s crust as much as most industrial metals, such as chro- concerns, economic vulnerability and peak oil have already created a
mium, nickel, copper, zinc, tin, tungsten or lead (King, 2017). For ex- necessity to diversify the energy portfolios towards a global green en-
ample, Ce abundance (60–70 ppm, Table 1) is almost similar to the ergy system (Stegen, 2015). Therefore, renewable energy sources like
copper abundance in the Earth’s crust. Therefore, in this context, the solar, wind and tidal power have drawn global attention to meet future
word ‘rare’ essentially implies that REEs are not commonly con- energy demands. In this regard, due to the aforementioned superior
centrated as economic ore deposits, though the viable deposits are characteristics of REEs, especially HREEs play a key role in high-tech-
distributed across the world in relatively low concentrations (Haxel nology and environmentally friendly energy harvesting techniques, for
et al., 2002). instance, solar panels and wind-power turbines (Judge et al., 2017).
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N. Dushyantha, et al. Ore Geology Reviews 122 (2020) 103521
Table 2
Industrial applications of REEs (Source: Balaram, 2019).
Area Applications
Electronics Television screens, computers, cell phones, silicon chips, monitor displays, long-life rechargeable batteries, camera lenses, light emitting diodes (LEDs),
compact fluorescent lamps (CFLs), baggage scanners, marine propulsion systems.
Manufacturing High strength magnets, metal alloys, stress gauges, ceramic pigments, colorants in glassware, chemical oxidizing agent, polishing powders, plastics creation,
as additives for strengthening other metals, automotive catalytic converters.
Medical Science Portable X-ray machines, X-ray tubes, magnetic resonance imagery (MRI) contrast agents, nuclear medicine imaging, cancer treatment applications, and for
genetic screening tests, medical and dental lasers.
Technology Lasers, optical glass, fiber optics, masers, radar detection devices, nuclear fuel rods, mercury-vapor lamps, highly reflective glass, computer memory, nuclear
batteries, high temperature superconductors.
Renewable Energy Hybrid automobiles, wind turbines, next generation rechargeable batteries, biofuel catalysts.
Others The europium is being used as a way to identify legitimate bills for the Euro bill supply and to dissuade counterfeiting. An estimated 1 kg of REE can be
found inside a typical hybrid automobile.
Holmium has the highest magnetic strength of any element and is used to create extremely powerful magnets. This application can reduce the weight of
many motors.
solar cells (Yu et al., 2019; Zhang et al., 2019). thus have been used in fertilizers in soluble forms at low concentration
in China since 1972 (Baisheng, 1985). Crops absorb soluble REE ions
2.1.2. Wind turbines like other cations and accumulate in plant tissues. This REE accumu-
Wind energy is a fast-growing green energy source, which is used to lation causes positive agronomic effects, such as quality and yield im-
generate electricity via wind turbines. In this process, the kinetic energy provements of various kinds of crops (Buckingham et al., 1999; Pang
of the wind is converted to mechanical energy by wind turbines to et al., 2002). Although applied REEs could enter the human body via
power a synchronous electric generator. Since REEs show strong mag- food chains, it is supposed that the REE concentration is low (i.e. 12 to
netism, 100 g of RE permanent magnet can produce the same magnetic 120 mg per day) and thus adverse effects are not yet reported
field produced by 1 kg of non-rare earth permanent magnet (Baisheng, 1985; Ramos et al., 2016).
(Athurupane, 2014). Therefore, powerful permanent magnets con-
taining REEs, such as Nd and Dy are employed in synchronous gen- 2.3. Role of REEs in military applications
erators in direct-drive wind turbines (Heier, 2014). These magnets
allow more lightweight designs and compacted direct-drive wind tur- REEs have also considered as strategic elements due to their ad-
bines compared to the gearbox wind turbines (Dodd, 2018). Therefore, vanced military applications. Permanent magnets such as samarium
direct-drive wind turbines offer more advantages, such as low turbine cobalt (SmCo) and neodymium iron boron (NdFeB) magnets are highly
downtime, high reliability and less maintenances over gearbox tur- used in many defence applications, such as tomahawk cruise missiles,
bines. As a result, direct-drive turbines have been effective and more smart bombs, joint direct attack munitions, joint air and ground fin
preferable even for offshore wind farms and sites with low wind speed actuators and predator unmanned aircrafts. SmCo magnets are capable
(Polinder et al., 2006; Ribrant and Bertling, 2007; Morris, 2011). of retaining high magnetic strength even at a higher temperature.
However, due to the turbulences in REE supply in the market, many Therefore, SmCo magnets are significantly used in precision-guided
companies and governments have already developed alternative REE missiles, smart bombs and aircrafts. Since NdFeB magnets show the
free generators for wind turbines using new materials with similar strongest magnetic strength, they are used in small quantities to pro-
functionality (Pavel et al., 2017). duce lighter magnets in military weapons system (Humphries, 2010;
Grasso, 2013). Moreover, REEs are used for energy storages, density
2.2. Role of REEs in agricultural applications amplifications and capacitance in electronic warfare and directed en-
ergy weapons. In addition, REEs like Y, Eu and Tb are used in energy
REEs have been used in zootechnical and agricultural applications, and resolution amplifiers in targeting applications, such as in night-
as they are essential in functional and structural molecules in biological vision goggles and laser weapons (Preinfalk and Morteani, 1989; Meyer
systems (Abdelnour et al., 2019). In this context, REEs are used as and Bras, 2011; Massari and Ruberti, 2013).
feeding additives to enhance growing and fattening of farming animals,
such as pigs, chicken, cattle, fish, ducks and rabbits. This REE appli- 3. Rare earth (RE) occurrences and global distribution
cation is also beneficial to increase the milk productions of dairy cows,
survival rates of fish and egg production of laying hens (He et al., 2001; Rare earth (RE) deposits are also formed via primary and secondary
Redling, 2006). Moreover, REEs are beneficial elements to plants and processes (i.e. two geological processes). Primary processes consist of
Table 3
REE requirements by application (Sources: Long et al., 2012; Jordens et al., 2013).
REE application La% Ce% Pr% Nd% Sm% Eu% Gd% Tb% Dy% Y% Others%
*Percentages are estimated from the total REE content required in a given application.
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Table 4
RE resources and their global distribution (Source: Voncken, 2016).
Deposit Location Type Main REEs REE-mineral(s)
magmatic, hydrothermal and/or metamorphic processes, though sec- breccia fillings in Permian sandstone (Gupta and Krishnamurthy,
ondary processes imply weathering and sedimentary transport 2005).
(Mitchell, 2015; Zhou, 2017). In this regard, RE deposits can be cate-
gorised into primary and secondary deposits. Primary deposits are
commonly associated with carbonatites and alkaline-peralkaline ig- 3.1.2. Monazite
neous rocks, whereas secondary deposits, such as placer and ion ad- The second largest segment is the monazite deposits distributed in
sorption deposits (e.g. China), are formed due to the erosion and Australia, Brazil, China, India, Malaysia, South Africa, Sri Lanka,
weathering of primary deposits (Goodenough et al., 2016; Zhou, 2017). Thailand and USA. Monazite is a widespread RE mineral, which com-
Beside this classification scheme of RE deposits, they can be further monly occurs in beach sands. However, it also occurs in granite, gneiss
classified on the basis of their genetic associations, mineralogy and and other igneous and metamorphic rocks as an accessory mineral
form of occurrences (Balaram, 2019). (Wall, 2014). In addition, it can be found in complex ores together with
About 34 countries have been identified with RE deposits and iron oxides, aluminosilicates and apatite (Ferron et al., 1991). Monazite
Table 4 shows the RE resources distribution in the world (Chen, 2011). is usually associated with heavy minerals, such as ilmenite, magnetite,
According to the United States Geological Survey (USGS) Mineral rutile and zircon due to its high specific gravity and resistance to che-
Commodity Summaries 2016, worldwide RE reserve estimation was mical weathering (Long et al., 2012).
130 million tonnes and China and Brazil have 42.3% and 16.9% of This mineral generally contains 10–40% La2O3, 4–12% ThO2,
these reserves, respectively (United States Geological Survey (USGS), 20–30% Ce2O3 and high amount of Nd, Pr and Sm (Gupta and
2016). The majority of REEs are found in carbonatite deposits, where Krishnamurthy, 2005; Thompson et al., 2012). It is considered as a
LREEs are typically enriched. Fig. 1 shows the global carbonatite dis- major source of cerium and LREEs (Fernando, 1986; Voncken, 2016;
tribution. Alkaline-peralkaline igneous rocks also comprise of sig- Xaba et al., 2018). REO content in monazite is approximately 70% (i.e.
nificant REE concentrations, where HREEs are often enriched. similar to bastnaesite). However, unlike bastnaesite, monazite contains
thorium and uranium (Trifonov, 1963; Cesbron, 1989; Ferron et al.,
3.1. Rare earth (RE) minerals 1991; Gupta and Krishnamurthy, 2005). Monazite in placer deposits
contains a higher amount of thorium and uranium than monazite from
More than 250 REE-bearing minerals have been identified to date in carbonatite deposits. The estimated inland monazite placer deposit
various mineral classes, such as carbonates, phosphates, silicates, tonnage was 10.21 million tonnes in 2005, in which China, USA and
oxides and halides (Vijayan et al., 1989; Chi et al., 2001; Gupta and India possess 36%, 13% and 3%, respectively (Pandey, 2011). Table 6
Krishnamurthy, 2005). Generally, LREEs are concentrated in carbo- presents the potential monazite sources in the world.
nates and phosphates, whereas HREEs are concentrated in oxides and a
part of phosphates (Kanazawa and Kamitani, 2006). Bastnaesite and
monazite are the most common RE minerals found in RE deposits. 3.1.3. Other RE minerals
Therefore, most of the global RE production is provided via bastnaesite The rest of the resources constitute xenotime, allanite, euxenite,
and monazite along with xenotime (Haque et al., 2014; Zhou, 2017). apatite, cheralite, eudialyte, loparite (Table 5), phosphorites, rare earth
Table 5 indicates primary REE minerals and their formulae. bearing (ion absorption) clays, secondary monazite and spent uranium
solutions. Xenotime is an yttrium phosphate mineral with 67% of REO
content, mostly containing HREEs (Gupta and Krishnamurthy, 2005).
3.1.1. Bastnaesite Allanite is commonly occurred as an accessory mineral in igneous rocks,
The largest percentage of world’s economic RE resources is con- such as granites, syenites, diorites and associated pegmatites. However,
sidered as the bastnaesite deposits distributed in China and the USA. it is rarely enriched of concentrations enough to form an ore of REEs.
Bastnaesite does not contain U or Th and it is considered as the primary Euxenite is a common oxide mineral which generally occurs in granite
source of LREEs (Table 5). This mineral contains approximately 70% of pegmatites associated with quartz, feldspars, ferrocolumbite, ferro-
REOs (Jordens et al., 2013; Voncken, 2016). Bastnaesite is often found tantalite and monazite (Long et al., 2012).
in geological environments, such as vein deposits, contact metamorphic
zones and pegmatites. In addition, it occurs in carbonate – silicate rocks
with alkaline intrusive, quartz veins, fluorite – bearing veins and
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N. Dushyantha, et al. Ore Geology Reviews 122 (2020) 103521
Fig. 1. Global carbonatite distribution including deposit in production and exploration targets (Sources: Eggert et al., 2016; Verplanck et al., 2016).
Table 5 considered as the host for most RE ores, which extends 18 km from east
Primary REE-bearing minerals and their formulae (Source: Dostal, 2017). to west with an approximate width of 2 km. However, different types of
Mineral Formula
carbonatite dikes are widely distributed with an intrusive sequence of
dolomite (ferroan) type, dolomite-calcite (magnesian) type, and calcite
Allanite (Y,La,Ca)2(Al,Fe3+)3(SiO4)3(OH) (calcic) type (Yang et al., 2011a,b). Due to the wide distribution of
Apatite (Ca,La)5(PO4)3(F,Cl,OH) carbonatite dikes in the Bayan Obo deposit, genesis of RE ores have
Bastnaesite (La,Y) (CO3)F
Eudialyte Na4(Ca,La)2(Fe2+ ,Mn2+,Y)ZrSi8O22(OH,Cl)2
been deduced to be associated with carbonatite. According to Liu et al.
Fergusonite (La,Y)NbO4 (2018), the Bayan Obo deposit is formed by the Mesoproterozoic car-
Gittinsite CaZrSi2O7 bonatite magmatism, followed by the Paleozoic hydrothermal dolomi-
Limoriite Y2(SiO4)(CO3) tization. Liu et al. (2018) also reported that REEs were re-fertilized
Kainosite Ca2(Y,La)2Si4O12(CO3).H2O
during the Paleozoic hydrothermal dolomitization. Moreover, different
Loparite (La,Na,Ca)(Ti,Nb)O3
Monazite (La,Th)PO4 models of ore genesis, such as syngenetic sedimentary deposition
Mosandrite (Na,Ca)3Ca3La (Ti,Nb,Zr)(Si2O7)2(O,OH,F)4 (Meng, 1982), metasomatism associated with granitic magmatism
Parisite Ca(La)2(CO3)3F2 (Wang, 1973), and deposition from exhalative, probably carbonatite
Pyrochlore (Ca,Na,La)2Nb2O6(OH,F) related, hydrothermal fluids (Zhongxin et al., 1992) have been pro-
Rinkite (Rinkolite) (Ca,La)4Na(Na,Ca)2Ti(Si2O7)2(O,F)2
Steenstrupine Na14La6Mn2Fe2(Zr,Th)(Si6O18)2(PO4)7·3H2O
posed for the Bayan Obo deposit (Fan et al., 2016). However, the
Synchysite Ca(La)(CO3)2F genesis of this deposit still remains a subject of debate mainly due to
Xenotime YPO4 immense post-ore magmatic and hydrothermal modifications (Smith
Zircon (Zr,La)SiO4 et al., 2015; Hu et al., 2019). Furthermore, ore bodies in the Bayan Obo
deposit have complex geochronology. Smith et al. (2016) reported that
the age of carbonatites in the Bayan Obo deposit is about
3.2. Major RE deposits in the world
1230–1350 Ma (million years) and about 400–450 Ma based on Sm-Nd
mineral isochrones and Th-Pb mineral isochrones, respectively. Both
3.2.1. Bayan Obo deposit
periods have also been identified from core to rim U-Pb isotope varia-
The Bayan Obo deposit is considered as the world’s biggest RE de-
tion in zircon (Campbell et al., 2014). This has supported interpreta-
posit and it was discovered as an iron deposit (REE-Nb-Fe) in 1927 (Fan
tions of multistage mineralisation, metamorphism and metasomatic
et al., 2016). This deposit is located in Inner Mongolia (at the north
overprint of the ores (Smith et al., 2015). The variation of elemental
margin of the North China Craton) bordering an early Paleozoic active
composition in different types of carbonatites is crucial for under-
continental margin to the north (Xiao andKusky, 2009). The Bayan Obo
standing the genesis of RE mineralization. The RE concentrations in the
deposit is hosted by the Bayan Obo group, which was traditionally di-
Bayan Obo deposit thus differ according to the type of carbonatite dike.
vided into nine lithological units; named as H1 to H9 in the ascending
For example, the calcite type carbonatite dikes have higher RE con-
order. All units are mainly comprised of meta-sandstones and slates
centrations over others (Yang et al., 2019).
except for H8. The H8 predominantly consists of dolomitic marbles
The Bayan Obo deposit contains RE reserves (non-Joint Ore
with both fine- and coarse-grained varieties and it is the host rock for
Reserves Committee (JORC) compliant) of over 57.4 million tonnes,
the majority of ores (Chao et al., 1992). Therefore, dolomite is
niobium (Nb) reserves of 2.16 million tonnes and iron (Fe) reserves of
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Table 6
Primary monazite mineral sources and their rare earth contents (percentage of total rare-earth oxide) (Sources: Hedrick, 1999; Kumari et al., 2015).
Rare earth elements Monazite
North Capel, West North Stradbroke Island, Green Cove Springs, Nangang, Guangdong, East Coast, Mount Weld,
Australia Queensland, Australia USA China Brazil Australia
ND – not detected.
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et al., 2016). significantly contributed the RE enrichment of this deposit and thus
Bastnaesite-(Ce) is the major RE mineral found in the Mountain Pass formed an economic resource (Smith et al., 2016).
deposit, and parisite-(Ce) and monazite-(Ce) are present as minor RE The Mount Weld deposit has a secondary RE phosphate mineralogy
minerals (Smith et al., 2016). This deposit has an ore grade of 8.5% of and these phosphates, mostly monazite, are contained in iron oxide
REOs particularly with extreme LREE enrichment. Moreover, high Ba minerals (Haque et al., 2014). The carbonatite bed rock is comprised of
enrichments are shown in this deposit and however, Nb and P are de- RE minerals, such as apatite, monazite-(Ce) and synchysite, whereas the
pleted (Castor, 2008; Smith et al., 2016; Zhou et al., 2016). lateritic profile contains neoformed apatite and monazite-(Ce), cran-
From 1960s to mid-1990s, this deposit was known as the largest dallite, goyazite, gorceixite and florencite-(Ce) which were formed by
LREE resource in the world as it is significantly enriched by LREEs weathering and redeposition of carbonatite and other RE minerals. In
(Table 4) despite the Nd depletion. Due to the wastewater pipeline addition, certain parts of the deposit constitute distinct xenotime and
leakages to the environment, REE operations were suspended in 1998, churchite mineralogy, resulting in significant HREE concentrations
and consequently, mining operations and RE production of this sole (about 3% of heavy REOs) in the deposit (Hoatson et al., 2011; Haque
domestic producer were ceased in 2002 (Koltun and Tharumarajah, et al., 2014). This deposit has the capacity of producing more than 26
2014). Since the deposit has the potential of producing around 19 thousand tonnes REOs per annum over more than 25 years. The Mount
thousand tonnes of REOs per year, Molycorp acquired this deposit in Weld consists of four deposits, namely, the Central Lanthanide Deposit
2008 and it was subsequently reopened in 2012. However, due to the (CLD - one of the highest grade REE deposits in the world), Duncan,
bankruptcy of Molycorp and the low prices of REEs in China, the op- Crown and Swan (Lynas, 2015).
erations were terminated again in 2015. Nevertheless, due to the on-
going trade disputes between the USA and China, rare earth mining 3.2.4. Ion adsorption clay deposits in Southern China
activities have been reconsidered and will be restarted by the end of Ion adsorption deposits are another type of unique RE deposits ty-
2020 to extract RE concentrates and oxides, such as La, Ce, Nd and Y pically found in Southern China as weathered-crust elution-deposits
(Eric, 2019a). with HREE enrichments (Table 4) (Li and Yang, 2014; Voncken, 2016).
Since unique geological conditions are required to form ion adsorption
3.2.3. Mount Weld deposit RE deposits, these deposits are only found in certain parts of Southeast
The Mount Weld deposit in Western Australia is considered to be Asia to date, in addition to the deposits in Southern China (Takeda and
one of the richest RE deposits in the world and it is found in a 70–130 m Okabe, 2014). These deposits were first discovered in 1970 in Ganzhou,
thick lateritic profile over an alkaline carbonatite complex (Hoatson China. These ion adsorption clays contain 0.02 – 1% of REOs and ac-
et al., 2011). Moreover, there are significant RE concentrations in the count for 2.9% of China’s total RE reserves (Su, 2009). Therefore, 26%
lacustrine sediments which is developed on the lateritic profile. Beside of China’s total RE production was originated from these deposits
RE resources, this acts as the host to many significant resources, such as during the period of 1988–2008, and since 2009, it has been reached up
Nb, Ta, Zr and phosphate (Smith et al., 2016). This carbonatite intru- to 35% (Su, 2009).
sion follows a sequence of Archaean volcano-sedimentary within the These clay deposits are formed through a process of REE leaching
fault bounded Laverton tectonic zone and it is metamorphized under from granite, granite porphyry or even gneisses by groundwater under
greenschist facies. The age of the primary carbonatite intrusion is re- high temperature and humidity where RE minerals are dissolved in
ported as 2080–2100 Ma, whereas the age of the lateritic profile is groundwater. During the penetration and migration processes, the
unknown. However, it has been recorded that the lacustrine sediments produced REE ions are weakly adsorbed onto the surface of the clay-
which overlies the lateritic profile belongs to the age of late Cretaceous rich thick soil layer developed above the granite bedrock (Van Gosen
to early Cainozoic. According to isotropic constraints, the primary et al., 2014; Estrade et al., 2019). Some of the adsorbed REEs can be
carbonatite in the Mount Weld deposit was derived from melting of an easily extracted from the clay by ion exchange (Wall, 2014; Deng et al.,
enriched mantle source. The Mount Weld deposit consists of Palaeo- 2019). Therefore, extraction of REEs from these clay deposits is eco-
proterozoic alkaline magmatic province which includes kimberlites and nomically viable due to the easy extractability, despite their low con-
other carbonatites (Willett et al., 1986; Hoatson et al., 2011; Jaireth centrations. In addition, radioactive elements in clay deposits are de-
et al., 2014). The lateritic regolith is concerned as the host to main pleted away during the weathering, and as a result, the adverse effects
economic RE resources. The long term leaching and redeposition of of radioactive contaminants in these deposits are minimized.
REEs by groundwater during the Mesozoic and Cainozoic ages has Table 8 presents the REE contents of major RE deposits, including
Table 8
REO% in Bayan Obo, Mountain Pass and ion adsorption clay deposits (Sources: Gupta and Krishnamurthy, 2005; Schüler et al., 2011; Shi, 2009).
Ore Bayan Obo Mountain Pass Ion adsorption clays
REOs Bastnaesite Monazite Basnasite *Site A *Site B *Site C *Site D *Site E *Site F
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N. Dushyantha, et al. Ore Geology Reviews 122 (2020) 103521
Bayan Obo, Mountain Pass and ion adsorption clays. million tonnes are heavy REOs (Zhou et al., 2016). The Zandkopsdrift
deposit in South Africa also contains around 0.79 million tonnes of
3.3. Other RE deposits REOs, according to its reserve estimations in 2014. Preliminary feasi-
bility studies in 2015 revealed that REE extraction is technically fea-
In addition to the above-mentioned prominent RE deposits, there sible and economically viable (Zhou et al., 2016). Even though mining
are many other RE deposits which are currently being mined or having of the Zandkopsdrift deposit was expected to commence in 2017 by the
potential economic RE concentrations. The Lovozero deposit on the Frontier Rare Earth Limited, the current status is not yet reported.
Kola Penisula in Russia is considered as the World’s largest layered
peralkaline syenite intrusion and mining operations were started since 3.3.1. Secondary RE deposits
1951 for Nb and REEs (Wall, 2014; Zartman and Kogarko, 2017). Besides the primary RE deposits, secondary RE deposits, such as
However, the underground mine at Karnarsurt is the only active mine in placers and offshore sediments are currently considered as valuable RE
the deposit, which is currently operated by Lovozerskiy Gok (Smith resources. RE placer deposits are formed by weathering and erosion
et al., 2016). RE mineralization of the Lovozero deposit is dominated by processes of REE-bearing rocks, and they are mostly found in environ-
loparite-(Ce) along with RE minerals, such as steenstrupine-(Ce), ments, such as streams, lakes, and shorelines. These RE placer deposits
vuonnemite, nordite-(Ce), vitusite-(Ce), mosandrite, monazite-(Ce) and are widely distributed in the world, for example, in Australia, India,
cerite (Kogarko et al., 2002). Brazil, Malaysia and Sri Lanka (Kanazawa and Kamitani, 2006; Amalan
Another RE deposit which is currently in the production stage is the et al., 2018; Dushyantha et al., 2019). The erosion process of REE-
Maoniuping deposit in the eastern Tibetan Plateau. It is the second bearing rocks also concentrates RE minerals, particularly monazite and
largest carbonatite-related REE deposit (CARD) in China. This deposit is xenotime (Table 5), along with heavy minerals, such as ilmenite and
hosted by a carbonatite-syenite complex which consists of two sections; rutile. Therefore, monazite is recovered as a by-product during heavy
namely Guangtoushan and Dagudao (Zheng and Liu, 2019). This car- mineral extraction processes from beach placer deposits, especially in
bonatite-syenite complex is located in the Cenozoic Mianning-Dechang the southern coast in India. In addition, xenotime is generally recovered
(MD) REE belt. The India-Asia continental collision, 65–26 Ma ago, as a by-product during tin placer mining (Van Gosen et al., 2014). RE
resulted in this MD REE belt which was formed by magmatism along resources can also be found in marine environments (i.e. as seafloor
with torsional and shear deformations (Hou et al., 2006). This deposit deposits). Deep-ocean manganese nodules and iron-manganese crusts
was formed approximately 25 Ma ago through melting of sub- found in the Pacific Ocean are identified as RE deposits with higher
continental lithospheric mantle which had been subjected to the me- amount of HREEs than carbonatite related deposits (Hein et al., 2011;
tasomatism by high fluxes of REE- and CO2-rich fluids derived from Wall, 2014). Deep-sea mud in the Pacific Ocean is also identified as low-
subducted marine sediments (Hou et al., 2015). The total estimated grade RE resources with low thorium content (Kato et al., 2011). In-
reserves of the Maoniuping deposit is 3.17 million tonnes and it is ty- dustrial rare earth extraction from these has not been reported yet.
pically enriched of LREEs (Zheng and Liu, 2019). Furthermore, the
Weishan Lake deposit located in Shandong, China, the carbonatite-as- 4. Global RE demand, production, consumption and China’s role
sociated REE deposits (CARDs), is currently being mined. The total in REE industry
reserves of REEs in this deposit is estimated to be about 2.55 million
tonnes with an average grade of 3.13% REOs. Main REE-bearing mi- 4.1. Global RE demand characteristics
nerals in this deposit are bastnaesite and parisite along with several
associated minerals, such as barite, calcite, quartz and fluorite (Li and With the impending rate of overall economic growth and the new
Yang, 2016). developments in material applications, demand for REEs has been es-
In addition to the RE deposits which are in production, many de- calating dramatically during the past few decades. RE demand experi-
posits have been identified to date with economical RE concentrations. enced its initial fast growth during the 1960s, due to the introduction of
However, while most of them are in the feasibility study stage, others colour televisions to the market. At the beginning (in 1953), demand
remain either being explored or untouched. In this context, the Bear was around 1000 tonnes of REOs, which accounted for US$ 25 million.
Lodge in South Dakota, USA (a deposit associated with a carbonatite The demand then increased up to 66 thousand tonnes in 1997 and
complex with an estimated 18 million tonnes of RE) is a potential RE reached up to 125 thousand tonnes in 2008 (Zhou et al., 2016). How-
deposit, which has attracted the attention of the U.S Government due to ever, Roskill (2015) reported that demand was 118 thousand tonnes of
its high grade of REEs. However, this deposit is yet to be mined due to REOs in 2014 and the estimated demand will be around 170 thousand
regulatory delays, despite the completion of environmental assessment tonnes by 2020. Currently, over 60% of the demand for REOs is for new
and exploratory activities (Borzykowski, 2019). The Bear Lodge deposit applications and it will continue to grow due to the frequent usage of
was formed by magma derived from the subcontinental lithospheric REEs in clean technologies (Mancheri et al., 2019b). According to
mantle and it was modified by subduction-related metasomatism. Due Kingsnorth (2016), demand for REEs could increase by 7–8% annually
to weathering, this deposit is oxidised to a depth between 120 and and Dutta et al. (2016) predicted an annual growth rate of 5% by 2020.
180 m. The fresh carbonatite in the Bear Lodge deposit consists of RE Alonso et al. (2012) suggested that Nd and Dy demands will be in-
minerals, such as burbankite, early-stage parisite-(Ce) and synchysite- creased by 700% and 2600%, respectively within the next two decades.
(Ce) along with bastnaesite-(Ce) in minor quantities. In contrast, Similarly, the price of the REOs is also increasing along with the de-
fluorcarbonates, cerianite and monazite-(Ce) are present in the oxidised mand. The cost of neodymium oxide, for example, is US$ 107 thousand
zone. This deposit is enriched of LREEs, however REE distribution per tonne in 2018 and it is expected to increase up to US$ 150 thousand
patterns differ based on the paragenesis (Chakhmouradian et al., 2017). by 2025 (Mertzman, 2019).
Moreover, Araxà complex in Paranaiba Province, Southern Brazil is
known for the vast production of Nb for the global market. This RE 4.2. Global RE production and consumption
mineralization is associated with a carbonatite intrusion and it is
mainly enriched of LREEs. The major RE mineral found in this deposit is Fig. 2 graphically illustrates the history of RE production. In 2014,
monazite and there are minor RE minerals, such as burbankite, carbo- the calculated global value of RE products was worth around US$ 1.5 to
cernaite, ancylite and huanghoite (Traversa et al., 2001). Furthermore, 2 trillion (Tukker, 2014). However, around 130, 126, 132 and 170
the Kvanefjeld deposit in south Greenland is famous for multi-element thousand tonnes of REOs were produced globally in 2015, 2016, 2017
resources, including REEs. According to the estimations in 2011, this and 2018, respectively (United States Geological Survey (USGS), 2018).
deposit has about 6.6 million tonnes of REOs, in which about 0.25 Fig. 3 illustrates the global RE production and consumption in 2016. In
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N. Dushyantha, et al. Ore Geology Reviews 122 (2020) 103521
electric vehicles. Therefore, the demand for REEs, such as Nd, Dy, La, Pr
and Ce will rise precipitously during the next decade (Li et al., 2019).
this context, China has currently contributed to more than 90% of the
global supply of REEs (Mancheri et al., 2019b). REOs production in
China, for example, increased from 73 thousand tonnes to 120 thousand
tonnes from 2000 to 2018 (United States Geological Survey (USGS),
2018). Since 2001, China has supplied RE products in the form of
concentrates, REOs, chemicals, alloys, salts and metals (Tse, 2011; Liu
et al., 2016; Ilankoon et al., 2018a). EU, USA and Japan collectively
imported 78 thousand tonnes of REOs in 2008, in which 71 thousand
tonnes were produced by China (Zhang and Shan, 2001).
In addition, China has experienced a marked increase in their RE
consumption since 2000. By 2000, the Chinese RE consumption was
about 19 thousand tonnes, whereas it reached a staggering 73 thousand
tonnes by 2009 (global RE consumption in 2000 and 2009 were about
91 and 130 thousand tonnes, respectively) and this is equivalent to
380% increase compared to 2000 (Tse, 2011; Fernandez, 2017).
Therefore, the Chinese dominated the RE market as the global con-
sumer, besides being the global supplier (Section 5.5). Fig. 4 illustrates
the production and consumption data of REOs in China from 2007 to
2015. Moreover, China is planning to accelerate automotive elec-
trification to overcome the oil shortage and environmental concerns by
Fig. 5. Indexed prices for selected REOs from 2006 to 2016 (Source: Eggert
2030. This approach will heavily rely on REEs and their applications in
et al., 2016).
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N. Dushyantha, et al. Ore Geology Reviews 122 (2020) 103521
production. However, by 2013, China increased their RE productions to win the trade wars. Similarly, a trade war has begun between the
and removed export quotas. Therefore, the overall surplus was experi- USA and China since 2018. In this context, the USA has imposed a 10%
enced in certain elements, such as Nd, Eu, Tb and Dy, whereas the RE tariff on US$ 300 billion of products imported from China, including
price started to decrease (Fig. 5) (Mancheri et al., 2019a). However, REEs effective from September 2019. The China Rare Earth Industry
China is still withstand as the dominant force in the RE industry even at Association has decided that they will pass the tariffs on REEs to the US
lower prices for REEs (Chen et al., 2018). consumers. Therefore, China is ready to use REEs as a trade weapon
even against the USA in their trade disputes (Eric, 2019b).
4.4. China’s illegal RE trading
5. Secondary RE resources and RE recycling
Illegal RE trading in China has been increasing at a significant rate
from 2007. It was mainly due to the imposed restrictions by the Chinese Since primary RE resources are finite and their supply is at a risk of
government on RE trading. On the other hand, tracing of the exact il- uncertainty, production and usage of REEs need to be ensured in a
legal RE mining and export quantities is a difficult task and therefore sustainable manner. This can be achieved by reducing the RE quantity
different agencies estimate different quantities (Ilankoon et al., 2018a). in single-use products, recycling and reusing of RE products as sec-
However, illegal REEs trade is estimated based on export and import ondary RE resources and finding sustainable alternatives or substitutes
quantity differences (Mancheri, 2016). China’s illegal RE activities, for REEs (Atwood, 2013). Reducing the RE quantity in end-use products
mainly in two southern provinces: Jiangxi and Guangdong, has grown has been made significant progress, especially in permanent magnets.
rapidly from 2007 to 2015, which accounted for about 25% of RE Nissan, for example, was able to reduce Dy usage by 40% in a newly
supply from China. During this period, 59 to 65% for HREE oxide and developed electric motor over conventional electric vehicle motor in
14 to 16% of LRRE oxide productions were illegally produced in China 2012. In addition, LEDs contain a very low content of phosphors (about
(Nguyen and Imholte, 2016). This illegal RE production boom has 1%) compared to CFLs. Since LEDs have a longer lifetime and higher
caused RE prices to drop down due to the low-cost trading, and as a efficiency than CFLs, LEDs have been more established in the lighting
result, the legal operations were forced to offer low prices. Therefore, market. Therefore, RE demand for phosphors in high-efficiency lighting
most of the RE mining companies in China incurred losses due to the is decreasing continuously (Zhou et al., 2016).
plummet in RE prices in 2015 (Chang and Hui, 2015). When REEs containing materials are no longer economically valu-
The Chinese government has now been restricting and controlling able as industrial products, they are considered as waste materials and
the illegal RE output and smuggling via regulating the market. In this subsequently become secondary RE resources, namely, electrical and
regard, the government and Lynas Corp, the Australian RE producer, electronic waste (or e-waste), mine tailings, red mud and phospho-
planned to install a system to trace the origin of the products gypsum. Recovering REEs from secondary resources has been a pro-
(Jamasmie, 2016a; Paul and Stanway, 2016). The Chinese ministry of mising solution to alleviate impending challenges associated with RE
industry and information technology have taken initiatives in October mining and processing, such as removal of radioactive elements, energy
2016 to restrict illegal RE production, transaction and processing in requirements and resource accessibility (Schüler et al., 2011). Table 9
China and address other internal issues, such as overproduction, less contains the currently available secondary streams for RE recycling and
innovative measures, low efficiency and lax environmental standards in green recycling methods, such as bioleaching could reduce the en-
RE industry (Ilankoon et al., 2018a; Mancheri et al., 2019a). vironmental footprint of recycling. Recycling can be categorized as
closed-loop and open-loop. In closed-loop recycling, recovered RE al-
4.5. China’s current status in RE industry loys will be used for similar applications, and however, this category
has its challenges in collecting, sorting, components-separating and
Since the end of 2016, the RE prices have experienced a growth. For processing. In open-loop recycling, recovered REEs from RE alloys will
example, the prices of Pr-Nd oxides, which are primarily used in per- be used in other applications (Koltun and Tharumarajah, 2014).
manent magnets, have escalated by 72% from October 2016 to October Therefore, instead of primary mining operations, recycling of REEs
2017. The global demand for REEs is expected to rise continuously from secondary resources will be an effective approach to fulfil the RE
during the next decade (Chen et al., 2018) and this includes the re- demand, independent of the Chinese rare earth export restrictions and
quired REEs for the implementation of emerging technologies. The RE price fluctuations.
industry thus heavily depends on the Chinese RE supply. It is envisaged
that China’s RE production will reach its peak levels in 2038–2045 with 5.1. E-waste
a peak production of 265–385 thousand tonnes (Wang et al., 2017).
Therefore, the Chinese government has introduced new environmental Electric and electronic equipment’s components, such as printed
and resource exhaustible taxes to control RE production and exports. circuit boards, cathode-ray tubes, batteries and magnets are categorized
Currently, China produces primary RE products, such as permanent as e-waste (Ilankoon et al., 2018b). E-waste is a fast-growing waste
magnets, catalysts, luminescent and polishing materials, targeting the stream throughout the world, growing at a rate of 3–5% per year, ac-
high-tech industries, especially the global renewable energy industry counting for about 5% of municipal waste (Tan et al., 2015; Balde et al.,
which has a promising future for RE applications (Research and 2017).
Markets, 2019). By October 2019, China had filed 25,911 patents on all Due to the unique characteristics of REEs, they are indispensable in
the REEs, whereas USA, Japan and the European Union had only filed electric and electronic components in the modern world. Thus, REE-
9810, 13,920 and 7280 patents, respectively. In addition, the number of bearing components in e-waste have much higher RE concentrations
Chinese filed patents related to REEs has escalated since 2011 com- than natural minerals (Tan et al., 2015). This justifies REE extraction
pared to the rest of the world (Fig. 6, Eric, 2019b). Therefore, China is from e-waste, though base and precious metal extraction has been the
leading in emerging technologies associated with REEs, which indicate current norm in e-waste recycling. Neodymium-iron-boron (NbFeB)
the expansions and shifts of the RE industry in China. magnets, also known as RE magnets, used in many different electrical
Due to the strategic importance of REEs in global high-tech in- and electronic applications, such as in computer hard disk drives,
dustry, they have now become a diplomatic weapon. In this regard, loudspeakers and household electric appliances are recycled via hy-
China has the power to use REEs in trade wars against other countries. drogen decrepitation. A significant amount of magnetic property (about
For example, China previously banned RE exports to Japan in 2010 due 90%) is recovered by this technique (Jiles, 2015; Walton et al., 2015;
to a territorial dispute (Humphries, 2010). It created a significant im- Awais et al., 2017).
pact on Japanese high-tech industry and REEs became the China’s tool REEs such as Eu, Tb and Y are highly used in lamp phosphor
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N. Dushyantha, et al. Ore Geology Reviews 122 (2020) 103521
Fig. 6. Global patent filings in REEs held by firms in China compared to firms in rest of the world (Source: Eric, 2019b).
powders in lighting products due to the luminescent properties of REEs 5.3. Red mud
(Machacek et al., 2015). Since fluorescent lamp waste contains more
than 20% of REEs by weight, the phosphor powder in fluorescent lamps Bauxite is the primary aluminium ore (or main source of alumi-
is a rich source of Eu, Tb and Y (Gijsemans et al., 2018). It can be nium), which contains about 30–50% of alumina along with trace
recycled for value recovery and recycled phosphor powder can be re- elements, such as calcium, sodium, zinc, gallium and REEs
used in new lamps. Recycling of phosphor powder is used to recover (Ochsenkühn-Petropulu et al., 1995; Smirnov and Molchanova, 1997).
individual phosphor components via physicochemical separations and The Bayer process is applied to extract aluminium from bauxite,
REEs by chemical processes (Binnemans et al., 2013a). Since Eu and Y whereas it generates a solid residue, which is known as bauxite residue
have high recoverability, those have been continuously extracted from or red mud. Despite minor applications in cements and ceramics, red
red phosphor (Gijsemans et al., 2018). mud does not have industrial-scaled applications in any sector. There-
RE alloys like misch-metal show hydrogen storage properties, and fore, long-term red mud storage has become a storage (i.e. limited space
therefore, these alloys are highly used in rechargeable nickel metal for future mining activities) and environmental issue (Borra et al.,
hydride (Ni-MH) batteries. La, Ce, Pr and Nd (misch-metal) are pre- 2015). REEs, especially Sc, are enriched in red mud during the Bayer
dominantly used in these batteries and it is equivalent to 10% of REEs. process and they can be extracted from red mud either by direct
In addition to recycling of Ni-MH batteries to recover Ni in stainless leaching or by smelting followed by leaching (Borra et al., 2015).
steel production, studies have focused on recycling Ni-MH batteries to
recover REEs via hydrometallurgical or pyrometallurgical processes 5.4. Phosphogypsum
(Jowitt et al., 2018). Considering the potential of e-waste as secondary
RE resources, sustainable RE recycling techniques still need to be de- Production of phosphoric acid via acid digestion of phosphate rocks
veloped and implemented. generates phosphogypsum as the main by-product of the process.
Phosphogypsum mainly contains calcium sulphate dihydrate,
5.2. Mine tailings CaSO4·2H2O, along with some other trace elements, such as uranium,
thorium and REEs (Koopman and Witkamp, 2000; El-Didamony et al.,
Mine tailings from RE deposits contain REEs in high concentrations 2011). Generally, phosphate rocks contain about 0.01–0.1% of REEs in
due to the low recovery via currently available extraction processes. which cerium, lanthanum and neodymium contribute to 80% of the
Mountain Pass mine tailing dams, for example, possess a REO content total RE content. During the phosphoric acid production process, about
about 3–5% and can be considered as viable RE resources. REEs are also 70–85% of REEs in phosphate rocks are enriched in phosphogypsum.
enriched in uranium, iron ore and titanium mine tailings in Australia, Although RE content in phosphogypsum is low compared to the RE
Kazachstan and Sweden (Jha et al., 2008; Peelman et al., 2016a). deposits, the generated phosphogypsum volume is very high and thus
Kiruna iron ore mine tailings in Sweden, for example, is recognised as a phosphogypsum can still be considered as a secondary source of REEs
potential RE resource and the tailings contain about 5000 ppm of REEs (Habashi, 1985; Skorovarov et al., 1992; Zielinski et al., 1993;
after the beneficiation. About 8 million tonnes of mine tailings are Binnemans et al., 2013b). Phosphogypsum waste in the Wizów Che-
being annually produced, and thus, it is capable of producing 15 mical Plant in Poland, for example, has been accumulated since 1948,
thousand tonnes of REEs. In addition, 50–100 million tonnes of tailings containing lanthanides (as Ln2O2) about 0.3–0.7% by weight. This
are remained in the tailing ponds which could also be used to recover waste could be used to produce 6–10 thousand tonnes of REEs (Grabas
REEs (Peelman et al., 2018). Peelman et al. (2016b) reported that acid et al., 2014; Kulczycka et al., 2016). Moreover, Rychkov et al. (2018)
leaching of iron ore mine tailings in the Kiruna mine extracted HREEs, introduced a process to recover 97–99% RE concentrate from phos-
such as Eu, Dy and Y with leaching efficiencies more than 75%. This phogypsum containing 0.43–0.52% of REEs in the Sredneuralsky
implies the economic viability of mine tailings for RE extraction as a Copper Smelting Plant in Russia.
secondary RE resource. In addition, coal and its by-products, such as coal middling and
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Table 9
Availability of REE-containing streams for recycling (Source: Binnemans et al., 2013a).
Material stream and application REEs Present/future contribution
Post-smelter and Electric Arc Furnace residues Ce, La, critical REEs Future levels depend on End-of-Life pre-smelter recycling
Fluorescent lamps (straight/curved) Eu, Tb, Y (Ce, Gd, La) Relatively stable
Compact fluorescent lamps (CFLs) Eu, Tb, Y (Ce, Gd, La) Increasing
LEDs Y, Ce Increasing
Automobiles (small magnets as motors, switches, sensors, actuators, etc.) Nd, Dy, Tb, Pr Relatively stable
Mobile phones (loudspeakers, switches, microphones, etc.) Nd, Dy, Tb, Pr Relatively stable
Hard disk drives (HDDs) Nd, Dy, Tb, Pr Will decrease (due to solid state devices)
Computers and peripherals (cooling fans, switches, drive motors, scanner head motors, Nd, Dy, Tb, Pr Relatively stable
small HDDs etc.)
Consumer electric and electronic devices (kitchen utensils, handheld tools, electric Nd, Dy, Tb, Pr Relatively stable
shavers etc.)
Industrial applications (electric motors etc.) Medium Dy level increasing (due to increasing energy efficiency demands for
electric motors)
Electric vehicle and hybrid electric vehicle motors Higher Dy level Increasing (but inertia for availability)
Industrial residues (phosphogypsum, red mud, etc.) All Depending on residue type
refuse are also identified as potential alternative RE resources (Huang from oil sand elucidate the potential of a secondary source of REEs,
et al., 2018). The Junger coal field in China, for example, has the po- though it has not yet exploited (Roth et al., 2017).
tential of supplying 12 thousand tonnes of REOs (Seredin and Dai,
2012). Moreover, oil sands in Alberta, Canada is used to extract bi-
6. Current status of secondary RE resources and RE substitution
tumen, where sand itself contains low RE concentrations and tailings
accumulated in solvent recovery unit contained average concentration
RE extractions from secondary sources are still under development
of 1100 ppm of REEs. Therefore, the tailings from bitumen extraction
and thus RE recycling accounted only for less than 5% of the global RE
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N. Dushyantha, et al. Ore Geology Reviews 122 (2020) 103521
supply in 2019 (Linnenkope, 2019). Although, various technologies several stages of the RE industry, such as mining, processing, trans-
have been introduced for RE extraction, those are still in its infancy due portation, waste disposal and decomposition (Rim, 2016). Table 10
to the impending challenges, such as extraction efficiency and se- summarises the general environmental concerns related to mining and
lectivity, and process economic considerations (Peelman et al., 2016a). processing of REEs. Pollution due to the chemical reagents, such as
Therefore, novel extraction techniques combined with conventional sulphates, oxalates and extract solvents used in extraction, processing
methods are crucial to facilitate RE extraction from secondary sources. and recycling of REEs is another aspect of environmental issue, if those
In this context, efficient RE recycling helps to conserve finite and non- are discharged to the environment without any pre-treatments (De Baar
renewable RE resources in the globe. et al., 1983; Ali, 2014). These environmental impacts have already
The substitution of REEs is also currently drawn attention to address created a social resistance to RE mining in countries like China and
the RE scarcity. REE can be substituted by another REE, which is more India.
abundant and cheaper for a given application (Carbonaro et al., 2016). People who are working in RE mining and processing industry ex-
In permanent magnets, for example, less abundant Sm is substituted by pose to long-term rare earth dust exposure. Lung diseases and pneu-
more abundant Nd. As a result, SmCo magnets are replaced by NdFeB moconiosis are thus reported among workers in the rare earth industry
magnets since 1985. Furthermore, REEs can be replaced by non-REEs. due to the inhalation of dust containing lanthanides, especially cerium
For example, RE-free electric motor was built by Japanese researchers oxide (Sabbioni et al., 1982; McDonald et al., 1995). Bioaccumulation
and Hybrid Electric Vehicle Technologies in 2011. In addition, RE of REEs and pathological changes are reported among local residents,
phosphors in LEDs are substituted by silicon quantum dot phosphors, who live near RE mining areas (Pang et al., 2002; Tong et al., 2004). In
whereas organic lighting devices are becoming good candidates to re- addition, it is reported that prolonged exposure to Ce is associated with
place REE-based lighting. However, non-RE substitution has still been lung pathologies and heart diseases in India during monazite mining
challenging due to its less efficiency (Zhou et al., 2016; Ganguli and and processing (Chakhmouradian and Wall, 2012). Furthermore,
Cook, 2018) and more future studies are intended. cerium oxide (CeO2) nanoparticles are used as a catalytic additive in
diesel fuel and it results in the emission of CeO2 nanoparticles as a
diesel exhaust particulate matter, causing air and soil pollution. It also
7. Environmental problems and health issues related to RE mining poses occupational and environmental exposure of REEs to the humans
and processing to cause Ce-induced diseases (Pagano et al., 2015; Rim, 2016).
However, the radioactivity of the associated elements, such as
Despite the global expansion of the RE industries during the last thorium (Th) and uranium (U) in rare earth minerals is the critical
decade, detailed toxicological investigations on REE-induced health environmental concern of RE deposits (Massari and Ruberti, 2013;
problems have been relatively scarce. Exposure of the people to RE Mehmood, 2018). A high level of radiation has been reported in mon-
toxicity can occur in various environments, such as iatrogenic, occu- azite mining and storage areas in India, and it has been eventually
pational and environmental routes. Since Gd is used as a contrast agent linked to different human health hazards (Padmanabhan, 2002). In
in magnetic resonance imaging (MRI), anomalously high Gd con- addition, strong public protests citing the adverse impacts of the
centrations in the femoral head bones of patients have been identified radioactive wastes were seen in Malaysia in November 2008 against the
due to Gd exposure via iatrogenesis. This excess Gd accumulation issuance of the operating licensee for the Lynas Company to process
causes medical conditions, such as acute kidney failure, nephrogenic REEs in Malaysia (Phua, 2016). Australia experienced a significant
systemic fibrosis and even death (Chien et al., 2011; Bernstein et al., decline in monazite exports from 1989 to 1992 due to the radioactivity
2012). However, toxic side-effects of Gd ions is markedly reduced using concerns and thus RE companies preferred RE concentrates from China
the technique of chelated complex formation in MRI contrast agents instead of Australia (Koltun and Tharumarajah, 2014). These radio-
(Xiao et al., 2016). active components make RE extraction expensive and challenging. In
Occupational and environmental exposures of REEs are evident in
Table 10
Environmental issues associated with REE mining and processing (Source: Schüler et al., 2011).
Risk Affected compartments Relevant toxic compounds
Collapse of tailing dam by poor construction Groundwater, surface water, soil • Radionuclide
• Heavy metals
Collapse of tailing dam by seismic event Groundwater, surface water, soil • Acids
• Fluorides
Pipe leakage Groundwater, surface water, soil Air emission
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