Handbook of Chemistry and Physics
Handbook of Chemistry and Physics
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HANDBOOK
1914 OF
December 23 , 1915.
HANDBOOK OF CHEMISTRY AND PHYSICS
EDITION OF 1914
ERRATA
PAGE
17, date of discovery of rubidium ; for " 1660” read 1860.
25 , melting point of calcium sulphate ; for “ 130” read red
heat.
48 , 49, 50, title of table ; for “NORMAL ” read DECI
NORMAL.
123 , line 1 ; for " centimeters” read millimeters.
128 , freezing point of carbon dioxide ; for “ — 79" read – 57 .
152, thermoelectrie power of cadmium ; for “ _ 30.48 ” read
- 3.48.
156 , electrochemical equivalents; for "Grams per coulomb. ”
read Milligrams per coulomb .
201, units of angle ; for " radium ” read radian .
212 , the pendulum ; for “ . . . d is the distance from the
knife edge to the bottom . . . " read . . . d is the
distance from the knife edge to the center . . .
236 , line 3 ; for “ . . . = 3437'. 75 206205 " " read . . . =
3437'.75 = 206265 " .
Relations of electrical units ; for “ 1 microfarad =
1,000,000 farads” read 1 farad = 1,000,000 microfarads .
259, the area of a circle ; for “ . . . = .7854d” read . . .
= .7854ď .
254, functions of the sums of angles :
for " sin ( x + y ) = sin x cos y + cos x cos y ”
read sin ( x + y ) = sin a cos y + cos X sin y
for " sin ( x - y ) = sin x cos y — Cos x cos y ”
read sin (x - y ) = sin x cos y — cos a sin y
268, log 450 ; for " 6352” read 6532.
305, Alloys, composition of ; for " 75" read 13.
307, Composition of alloys ; for " 75 " read 13 .
HANDBOOK
OF
CLEVELAND
CLEVELAND, OHIO
THE CHEMICAL RUBBER COMPANY
1914
Copyright, 1914
BY
THE CHEMICAL RUBBER COMPANY
CLEVELAND, Ohio
RECEIVED
JAN 24 SOA
CABOT SCIENCE LIBRARY
PAGE
Antidotes of Poisons . . . . .. . .. ......... 10
Hydrochloric Acid .
Ammonium Hydroxide . . . . . . . . .
Alcohol by Volume.. . . . . . . . . 70
Specific Gravity of Gases and Vapors . . . 71
Ionization Constants of Acids and Bases . . . . . . . . . . . . 71
Electromotive Force Series of Metals .
73
Functions, Uses, and Composition of Foods . . . .
PROPERTIES OF MATTER
Density :
Density of Various Solids . . . . . 76
Density of Water. . . . . 76
Density of Various Liquids . . . . . 77
Hydrometer Conversion Tables . . . 77
Absolute Density of Water . . . . . . 79
Relative Density of Water . . . . . . . . . . . 80
81
Density and Volume of Mercury . . . . . . . . . . . . . . . . . . . . .
3
CONTENTS
PAGE
Density of Alcohol. . . . . . . . . . .. . . 82
Density of Aqueous Solutions. . .
Density of Dry Air . . . . . . . . . . .
Density of Saturated Vapors at the Temperature of Normal Ebullition
Density of Gases in Liquid and Solid Form . . . . . . . .
Elasticity :
Elastic Constants for Solids . . . . .
Compressibility of Liquids. . . .
Elastic Constants for Gases . . .
Coefficient of Friction . . . . .
VUCICICIIU U ICUIUU . . . . . . . . . . . . . . . . . . . . . . . . .
.
Viscosity of Gases . . . . . . . . . . . . . . .. . . . . . . . . .
.
Diffusion of Gases into Air . . . . . . . . . . . . . . . . . . . . .
.
Diffusion of Aqueous Solutions into Pure Water . . . .
Osmotic Pressure of Aqueous Solutions . . . . . .
HEAT
Conversion of Thermometer Scales . . . . . . . . . .
Centigrade- Fahrenheit Thermometer Scale Reductions . . . . . . . Dual LUCUUUUUIIN . . . . . . . . . . . . . .
Critical Temperature and Pressure and other Constants for Gases . . 111
Freezing Mixtures. . . . . 112
Heat Equivalent of Fusion . . . . . . . . . . 113
Heat
cav Equivalent
yurvaci of
0 Evaporation
VAPOUVON .. .
. .
. .
. . . . . . . . . . . . . . . . . . . . . . . . . . . 114
Change in Volume Due to Fusion . . . . . . . . . . . . . . . 115
Fixed Points for High Temperatures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 115
CONTENTS
PAGE
Vapor Tension :
Vapor Tension of Water, 0° to 100° C . . . . . . . .. 116
Vapor Tension of Water, 100° to 230° C . . . 117
Vapor Tension of Water at Low Temperatures . . . .. 118
Vapor Tension of Mercury . . . . . . 122
Lowering of Vapor Pressure by Salts in Aqueous Solutions . . . . . . . . 123
Vapor Tension of Various Substances . . .. 121
Constants for the Kinetic Theory of Gases . . . . . . . . . . . . . 123
Number of Molecules in a Molecule -gram . . . 123
Mass of the Hydrogen Atom . . . . 123
Heat Conductivity . . . . . . . 126
High and Low Temperatures Obtained by Various Means . . . . . 128
Heat Values of Fuels . . . . . . . . . 128
SOUND
Velocity of Sound in Solids. . . . . . . . 138
Velocity of Sound in Liquids and Gases . . . . . . . 139
Musical Scales . . . . . . . . . 140
LIGHT
PAGE
Standard Candles.. . . . . . .. . . . . 160
Photometric Standards . . . . . . . . 160
Mean Horizontal Candle Power of Various Light Sources . . . . . . . . . . . 161
Primary Color Sensations Produced by Various Light Sources. .. 161
Intrinsic Brilliancy of Light Sources . . . . . . 162
Wave Length of Various Radiations . . . . . . . . . . . . 162
Variation in the Sensitiveness of the Eye with the Wave Length. . . .
Wave Lengths of the Fraunhofer Lines. . . . . .
Wave Lengths for Spectroscopic Calibration . . . . . . . . . . . . 163
Wave Length of Principal Lines of Various Elements . . . . . . . . . 164
Relative Stimulation of the Three Color Sensations . . . . . 168
Index of Refraction :
Optically Isotropic Solids. . . . . . 170
Uniaxial Crystals . . . . . . . . . 171
Glass . . . . . 172
Rock Salt, Silvine, Calcite, Fluorite and Quartz . . .. 172
Biaxial Crystals . . . . . . . . . . . . . 172
Liquids. . . . . . . . . . . . . . . . 173
M etals . . . . . . . . . . . . . . . . .
Aqueous Solutions . . . . .. . .. 174
Gases . . . . . . . . . . . . . . ... 175
Dispersion . . . . . . . . . . . . . . . . . . . . 173
Diffused Reflection . . . . . . . . . . . . . . . . . 174
Coefficients of Transparency . . . . . . . . . 175 , 176
Reflection of Light by Glass in Air . . . . . .. .. .. .. 176
Reflection by Transparent Media in Air . . . . . . . . .. 176
Reflection of Light by Metals . . . . . . . . . . . . . . .. 177
Transmissibility for Radiations . . . . . . . . . . . . . . . . .. . 178
Phosphorescence by Cathode Rays . . . . . . . . 179
Fluorescence of Organic Substances in Solution . . . . . 180
Fluorescence of Gases and Vapors , . . . . . . . . . . . . . . . . . . . . . 180
Specific Rotation . . . . . . . . . 181
Magneto - Optic Rotation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
MISCELLANEOUS TABLES
Röntgen Rays . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 184
Radioactive Substances . . . . . . . . . 185
Declination of the Sun and Equation
un and of Inne
qualo11 01 Time .. .. .. .. .. .. . . . . . . . . . . . . .. . .. 187
Mean Places of Stars . . . . . . . . . . . . . . . . . . . . . . . . . . . 187
Approximate Correction for Refractio
TaCuOnn .. .. . .. ..
. . . . . . . . . . 188
Data in Regard to the Earth . . . . . . . . . 188
Data Concerning the Solar System . . . . 188
Meteorological Data . . . . . 189
Acceleration Due to Gravity , Latitude, Longitude and Elevation . . . . . 190
Moment of Inertia for Various Bodies . . . . . . . . . . . . . . . . . . . . . . . . . . . . 192
Acceleration Due to Gravity and Length of the Seconds Pendulum . . . . 191
Miscellaneous Constants. . . . . . , 195
The Greek Alphabet . . . . . . . . . . . 195
DEFINITIONS AND FORMULAE
Chemical Laws. . . . . . . . . . . . . . . . 196
Chemical Theories. . . 197
Definitions of Chemical Terms. . . . . . . . . . . . . . . . 198
One Hundred Completed Chemical Equations. .. 199
Chemical Equations . . . . . . . . 199
Physical Terms, Quantities and Units . . . . . . .. . . . . . . . . . 201
Physical Formulæ . . . . . . . 209
CONTENTS
PAGE
LABORATORY ARTS AND RECIPES.. .. 224
WIRE TABLES
MATHEMATICAL TABLES
Mensuration Formulæ . . . . . . . . . 257
Trigonometrical Functions in a Right-angled Triangle. . . . . . . . 263
Signs and Limits of Value Assumed by the Functions, . . . . . . 263
Value of the Functions of Various Angles . . . . . . . . . . . . . . . . . . . 264
Relations of the Functions. . . . . . . . . . . . . . . . 264
Functions of Sums of Angles . . . . . 264
Functions of Multiple Angles . . . 265
Relations between Sides and Angles of Any Triangle . . 265
Four-place Logarithms. . . .. 266
Natural Sines, Cosines, Tangents , and Cotangents. . . . . . .. 270
Logarithms of the Trigonometrical Functions . . . . . . . . . . . . . . . . . . . . . . 275
Numerical Table . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 280
Numerical Constants . . . .
APPARATUS LISTS
List of Apparatus and Material for Experiments in Chemistry . . . . . . . . 28 ?
List of Apparatus and Material for Experiments in Physics . . . . . . . . . . 284
BIBLIOGRAPHY
Text-books, Manuals and Reference Books in Chemistry . . . . 288
Bibliography of Physics . . . . . . . . . . . . . . . . . . . . . 291
Periodicals and Publications of Interest to Physicists. . . . . . . . .. . 296
PROBLEMS
Method of Solving Chemical Problems. . . . . . . . . . . . . . . . . 297
Problems in Elementary Physics . . . . . . . . . . . 301
ANTIDOTES OF POISONS
Acetic Acid . — Emetics, magnesia , chalk , soap, oil.
Arsenic, Rat Poison, Paris Green. - Milk , raw egg, sweet oil,
lime water, four and water .
Carbolic Acid . – Any soluble non -toxic sulphate, after pro
voking vomiting with zinc sulphate; uncooked white of egg
in abundance, milk of lime, saccharate of calcium , olive or
castor oil with magnesia in suspension , ice, washing the stomach
with equal parts water and vinegar; give alcohol or whiskey
or about four fluid ounces camphorated oil at one dose .
Chloroform , Chloral, Ether. — Dash cold water on head and
chest, artificial respiration .
Hydrochloric Acid . — Magnesia , alkali carbonates, albumen , ice.
Hydiocyanic or Prussic Acid. — Hydrogen peroxide internally ,
and artificial respiration, breathing ammonia or chlorine from
chlorinated lime, ferrous sulphate followed by potassium car
bonate , emetics , warmth .
Iodine.- Emetics ,stomach siphon, starchy foods in abundance,
sodium thiosulphate. .
Lead Acetate. - Emetics, stomach siphon, sodium , potassium
or magnesium sulphates, milk , albumen .
Mercuric Chloride or Corrosive Sublimate . - Zinc sulphate,
emetics, stomach siphon , white of egg, milk , chalk , castor oil,
table salt , reduced iron .
Nitrate of Silver. - Salt and water .
Nitric Acid . Same as for hydrochloric acid .
Opium , Morphine, Laudanum , Paregoric , etc. - Strong coffee,
hot bath . Keep awake and moving at any cost.
Phosphoric Acid. - Same as for hydrochloric .
Sodium Hydroxide or Potassium Hydroxide. - Vinegar ,
lemon juice, orange juice, oil, milk .
Sulphuric Acid . - Same as for hydrochloric acid with the
addition of soap or oil.
Sulphurous Acid or Sulphur Dioxide. — Mustard plaster on
chest; narcotics, expectorants.
10
JIANDBOOK OF CHEMISTRY AND PHYSICS
Aluminum Hydrogen
Al2O3. . 102 . 2 2 . 00945 H20 . 18 .016 1. 25565
Al (OH ) 6. . 156 . 2 2 . 19368 Iodine
Antimony AgI . . . . 234 . 9 2 . 37088
Sb2S . . . . . 400 . 7 2 . 60282 HI. . . . . 127 . 98 2 . 10714
Sb2S3. . . . . . 336 . 6 2 . 52711 Pbl2. . .. 460. 8 2 .66351
Sb2O3. . . . . 288 . 4 2 . 46000 Iron . . .
Sb205. . . . . . . . . . . 320 . 4 2 . 50569 Fe0 . . . 71. 9 1. 85673
Arsenic Fe2O3. . . 159. 8 2 . 20358
M42AS207. . . . . 310 . 7 2 . 49234 Lead
(MgNH AsO4) 2 · H20 380 . 9 2 .58081 303 . 0 | 2 . 48144
As2S : 310 . 3 2 . 49178 Pbs . 239 . 0 2 . 37840
As2S3. . . 246 . 2 2 . 39129 PbO . . . . . 222 9 2 . 34811
As2O3. . . . . . . . . . 193 . 2 . 29667 PbCl2. 277 . 8 2 . 44373
As205. . . . . . . . . . . 239 . 2 . 36173 PbCr01. . . 323 . 2 . 50920
Barium Lithium
BaSO4. .. 233 . 5 2 . 36829 LiCl. . . 42 .48 1.62818
B:10 . . . . . 153 . 4 2 . 18583 Li2SO4. . . 110 . 12 2 .04187
BaCO3. 197 . 4 2 . 29535 Li20 . . 30 . 06 1 . 47799
BaCrO4. . 253 . 5 2 . 10398 Li2CO3. . . ! 74 . 06 1 . 86958
Bismuth Li3PO4. . . . . . . . . . . . . 116 . 09 2 . 06479
Bi2O3.. .. . . . . . . . . . . . . 464 . I 2 . 66652 Magnesium
Bi2S3 . .. .. .. ..
D123 . . . . . . . .. . 512 . 2 2 . 70944 : Mg. P : 07 . . . . . . . . . . 222 . 7 2 . 34772
BIOCI, . . . . . . . . . . . . 259. 45 2 .41405 Mg() . | 40 . 36 1 . 60595
Bromine Mg (NH4) ASO . + 6H20 . 289 . 6 2 . 46181
AgBr . . 2 . 27390 Mg2A520 ; . . . . . . . . . . 310 . 7 2 . 49234
HBr. . . . . . . . . . . . . . . 00 . 97 1 . 90832 MgSO . . . . . . . . . 120 .42 2. 08070
Cadmium | Manganese
CIS . . . 144 . 5 2 . 15987 MnSO4. . 12. 17926
Cdo . . . . . . . . . . 128 . 4 2 . 10857 Mns . | 1. 94002
Calcium Mn304. . . . . . . . . 229 . 2 . 35984
Ca ) . . 56 . 1 1 . 74896 . Mn20 : . . . . . . . . 158 . 2 . 19866
CaSO4. . 136 . 2 2 . 13418 MnO . . . . . . . . . . 71 . 1 . 85126
CaCO3. . . 100.12. 00043 KMnO4. . . 158 . 15 2 19907
Carbon Mercury
CO2 . . . . . . . . . . . . 44 . 1 .61345 HgS . . 232 . 1 2 . 36568
CN . . . . . . . . . . . . 26 . 01 1 .41514 Hg0 . . . 216 . 2 . 33145
CO . . . . . . . . . . . 28 . 1 . 44716 Hg20 . . . 416 . 2 .61909
HCN . | 27 . 02 1 .43169 HgCl2 .. 470 . 9 2 .67293
Chlorine Nickel
AgCl . . 143 . 38 2 . 15619 Nio . 74 . 7 1 . 87332
HCI. . . . . . . . . . . . . 36 . 46 1 . 56182
NiS04. . . . . . . 154 . 8 2. 18977
Chromium Nitrogen
Cr2O3. . . 152 . 2 2 . 18241 V205 . . 108 . 02 2 . 03350
100.. 1 ! 22 .. 00045
CrO : . . . . . . . . . . . . . . 100 0 N203. 76 . 02 1 . 88093
PbCr04 . . 323 . i 2 . 50920 (NH ) CH . 53 . 19 1 . 72827
BaCrO . . . 253, 5 2 40338 ( NH4)2SO4. . 132 . 14 2 . 12103
Cobalt Phosphorus
Coo . . . . . 75 . 1. 87506 Mg2P207 . 222 . 7 2 . 34772
Co304. . . 241. i 2 . 38202 Ag4P207. . . 605 . 7 2 . 78226
K3CO (NO2) 6 452 . 5 2 . 65562 P20 . . . . . . . .. . .. 142. 2 . 15229
Copper PH3 . . . . 34 . 0 1. 53148
Cuo . . . 79 . 6 1 . 90091 Ag?P04 . . . 418 . 8 2 .62201
Cu2S 159. 3 2 . 20222 Platinum .
Fluorine KPC16 . . . . . . . . . . . 485 . 3 2 . 68646
CaF2 . . . 78 1. 1 . 89265 (NH ) PtCle . . . . . . . . 443 . 6 2 . 64699
HF . ! 20 . 0 1. 30103 Potassium
BaSiF6 . . . 279. 8 2 . 41685 KCI. . . 74 . 6 1 .87271
K2SiF6 . 220 . 7 2 . 31380 K2SO4. , . .. 174 . 36 2 . 24145
H SIF . . . . 144 . 4 2 . 15957 K PtClo . . . . . 485 . 8 2 . 69616
12
HANDBOOK OF CHEMISTRY AND PHYSICS
MOLECULAR WEIGHTS AND THEIR LOGARITHMS (Cont.)
o
3 Argon . . . . . 39 .88 1 . 38
a
heavy
6 Bismuth . . . Unknown . . . . 208 . 0 9 . 78 at 20
Boron . . . . . Borax . . . . . . 11. 0 2 . 45
8 Bromine Gr. bromos, | 79 .92 3. 12 at 20
liquid . stench
Cadmium . . Gr. kadmeia , 112 .4 8 .648 at 20
calamine
10 Caesium .. .. L . caesius , 132. 81 16.88 at 26
sky blue
11 Calcium . . . . L . calx , lime. . 40 . 09 1. 85 cryst .
12 Carbon . . . . . 1 . carbo , 12 . 0 1 . 45 to 2 or 4
charcoal 1 . 88 amorph .
2 . 25 graph .
3 .51 diamond
13 Cerium . . . . . Planet Ceres . 140 . 25 7 . 042 4 or 3
14 Chlorine . . . . Gr. chloros, 35 . 46 2 . 49 at 0
green
15 Chromi:im . . Gr. chroma , 52. 0 6 . 92 at 20 3 or 6
color
16 Cobalt. . . . . .! G . kobold , 58.97 8 .718 at 21 2 or 3
goblin
17 Colombium . Columbia , 93.5 17. 06 to 7.37 3 or 5
niobium
Copper . . . . . Cyprus . . . . . . 1 . 71
63, 57 , 8. 93 to 8 . 95 2 or 1
19 Erbium . . . Ytterby,a town Er 167 . 4 4 . 77
in Sweden
Fluorine . . . L . fluor, flow .. 9 .0 1 . 26
| Gadolinium , Gadolin , a | Gd 157 . 3 1. 31
Russian
22 Gallium . . . . L . Gallia , 69. 9 , 5 . 94 at 23 ,
France
23 Germanium . L . Germania , 72. 5 5. 47 at 20 :
Germany
24 Glucinum . .. Gr. glykys , 9.1 1. 93 !
sweet
25 Gold . . . . . .. Aurun , u 197. 2 19 .32 at 17. 5
Anglo - Sax
26 Helium . The sun , . . . He : 3 . 99 .136
o
trum
29 Iodine.. . . . Gr. iodes, 126 . 92 4 . 948 at 17
violet
30 Iridium . . . .. L . iris, a rain - Ir 193 . 1 22.42at 17
bow
31 Iron , pure.. .| L . ferrum , | Fe 55 .85 7 .86 2 or 3
An. - Sax, iron
14
HANDBOOK OF CHEMISTRY AND PHYSICS
THE ELEMENTS
Phys.-Chem . Tabellen and the Standard Dictionary .
15
HANDBOOK OF CHEMISTRY AND PHYSICS
PHYSICAL CONSTANTS OF
42 Nickel. . . . . . Sw . abb
bbr. of
of Ni 58 .68 8 . 57 to 8 . 93 2 or 3
• 1452
N
kuppar-nickel
43 Nitrogen . . . . Gr. , niter 14 .01 . 967 3 or 5 - 214
forming
44 Osmium . . . Gr. osme, odor Os 190 . 0 22 .48 2 or 3 or 4
or 8
45 Oxygen . . . . Gr., acid - . lo 16 . 00 1 . 053
former
46 Palladium .. . Planet Pallas. | Pd 106 . 7 11. 4 to 11 . 9 2 or 4
47 Phosphorus, Gr., light 31. 04 1 .83 3 or 5
yellow bearing
48 Phosphorus, 1 Gr. , light 31 . 04 2 . 20 to 2 . 34 3 or 5
red . . . . . . . bearing
49 Platinum . . . Sp . platina . .. Pt 195 . 2 21. 50 2 or 4
50 Potassium . . Eng. potash . | 39 . 10 . 867
51 Praseodym Gr. praseos, 140 . 6 6 . 475
ium green ,and did
mos, twin
52 Radium . . . . Ra |226. 4
53 Rhodium . . . Gr. rhodon , Rh 102 . 9 11 . 0 to 12 . 6
rose
54 Rubidium . . . L .rubidius, Rb 85 . 45 1 . 52
red
55 Ruthenium .. 101 . 7 12 . 26 2 or 3 or 4
or 6 or 8
56 Samarium . . . Samarski, 150. 4 | 7 . 7 to8 7 . 3
a Russian
57 Selenium .. . . Gr. selene, 79 . 3 4 .47 to 4 . 80 2 or 4
moon
58 Silicon . . . . . L . siles, fint . Si 28 . 3 2 . 39
59 Silver . . . . . Anglo - Sax., 107 . 88 10 . 50
Seolfor
60 Sodium . . . . . Eng ., soda 23 .00 978
Strontium . . . Strontian ,town 87 . 63 2 . 54
in Scotland
62 Sulphur.. . . . L . sulfur.. . . .IS 32 .07 | 2 .07 at 0 2 or 4 or 6
HANDBOOK OF CHEMISTRY AND PHYSICS
PHYSICAL CONSTANTS OF
in Sweden
Thallium . . . Gr. thallos . . . TI 204 . 0 11 . 85 1 or 3
Name. Formula .
Mol. Crystalline form
wt. and color .
normal
bromide. . Al2Bro ( + 12H2O ) . . 534 . colorless
carbide. . AllC3. . 144 . 4
vo
etc .
1 . 0607
FOOD
17 . 118 . s. a . p . s. a . p . s . al.
2 . 583 657 . s . alk . 8 . HCI,
H2SO4
. . . . . . . . decomp. decomp.
s . a ., alk .
.
13 2 . 59 36 . 1 89 . 1
.
20 2 .367 v. s . v. s.
S.
1. 586 60 . 25 . . . . . . . . .
1 . al.
29 1 . 65 0 .005
-
Name . Formula .
Mol. Crystalline form
wt. and color .
25
HANDBOOK OF CHEMISTRY AND PHYSICS
PHYSICAL CONSTANTS OF
150
151 6 . 739 5. H2SO4
152 6 . 9 -7 . 0 8 . conc. H2SO4.
1. HCI
153 1 . 282 decomp . decomp . S.
154 2 .4502 D - 102 . - 33 . 5 1 :2 .6 vol. 1: 1.4 , (40 %)
155 1.5 - 76 . 10 .
156 ! . . . . . . . . explodes - 19 .
157 6 .8
158 2 . 36 subl. at 1 . al.
white heat
159 2 . 75
160 100 . S. a . ; s . alk .
161 36 . 5 s . alk .
162 5 . 21 white heat 1 . al.
163 1 . 7 (22 ) . .. .. .. ..
164 3 . 77 S . HNO3
165 2 .74 190 . decomp. decom .with al.
166 8 . 951 1505 8. a.
167 decomp.
168 . . . ... 1. al.
169 5.1 decomp. at red heat 1 . al. ; s . a .
170 5 . 8 - 6 . 3 8 . conc. H2SO4
171
172 1 . 84 86 . 75 110 .
1731 250 .
173 . . . . . . .
3 . KCN
174 3 . 507 sl. s . ammonia
175 1 . 83 decomp. at red heat al. 200
176 5 . 68 decomp . 100 . 1. al.
177 1. al.
178 1 . 924 65 . (709) 1. al.
179 | s. a .
180 8 . 85 - 8 . 94 1083 . S. a .
181 150 . decomp 60 . decomp . 1. al.
27
HANDBOOK OF CHEMISTRY AND PILYSICS
PHYSICAL CONSTANTS OF
281 2 . 2 - 2 . 8 decomp.
282 7 .2 1900 . decomp . sl. decomp. S. a .
283 3 .5 1. al.
284 1 . 913 87 . 6 150 . 650 . al. 53
285 4 .7 - 5 .02 300 .decomp.
286 70 . decomp. s . decomp . 5 . H2SO4
287 ) 4 . 33
288 3 . 26 S. a .
289 1.8 87 . 5 130 . V . S. v . s. 8 . al.
290 4 . 32
291 5 .42 260 . - 270 . 300 . 7 . 4 (200) 54 . al. 33 ; ether 25
292 3 . 77 decomp. 12 . 53 . al. 5
293 11. 136 decomp. at red heat sl. s . sl. s . 1. al.
294 . . .. . . .. decomp . a : red heat decomp. to basic salt s . HNO3
295 ) . . . . . . . . decomp. to basic salt 1. al.
296 6 . 444 1 : 2000 1 : 600 1. al.
297 8 . 124 sublimes s . aq. reg .
309 6 . 44
310 . . . . . . . 104 .
311 8 . K28
312 4 . 39 red heat sublimes 0 . 104 8 . NH3
3131 . . . . . . . . S. & .
314 8 .57 - 8 . 8 1484 . 8. a .
315 2 . 56 subllmes
316 ) . . .. . .. 8.
317 ) . . . . . . . . . . s . a . ; S . NH3
318 4 . 36 8 . NH3; s . a .
319 2 . 065 56 . 7 136 50 . S . al.
320 6 . 4 - 6 . 7 S . NH3
321 4 . 846 decomp . 8 . HCI
322 3 .418 37 . 4 | 62. (70°) 1 . al.
3231 2 . 031 280 . 8. S. s . NH3
345
346 1 . 88 40 . 5 213 . decomp. 8 . al.
347 61. appr . 1 v . s. V . s. V .S.
348 1 . 836 44 . 2 290 . S . CS2
349 2 . 16 290 . 1. CS2
350 2 . 34 11. 1. CS2
351 ) 1 .65 (200) 70 . 200 . decomp. v . 8. v . s.
352 148 . sublimes decomp . decomp. decomp.; 1.
CS2
353 1 .6129 . . . . . . . 76 . decomp. decomp. s . CS2
3541 275 . 530 . decomp . decomp. by al.
S . CS2
355 2 . 387 sublimes decomp.
356 ) 1 . 936 22 . 5 173 . decomp .
357 1 . 17 D - 133 . - 85 . sl. s .
358 1 . 01 - 10 . 30 .
359 . . . . . . . . .. 175 . decomp. i.
360 2 . 431 . . . . . V . 8.
decomp. . . . . . . . . . s . al.
361 8.
33
HANDBOOK OF CHEMISTRY AND PHYSICS
PHYSICAL CONSTANTS OF
362 s. a .; S. KOH
363
364 7 . 224 decomp . s . HCI, HNO :
365 5 . 87 decomp. s . FCI
366 S . HCI
.
367 decomp.
.
368 1. a .
369 21. 1 -21. 7 1745 8 . aq . reg .
370 0 . 86 62 . 5 720 . decomp. decomp. decomp. by al.
371 188 . 492 . al. 33
372 1 . 73 92 . red heat 9 .5 357 .
373 s .
374 . . . . . . . . decomp.
375 18 . 87 V . s. s . al. 4
376 . . .. . V. S. V. s.
377 2 .69 decomp. at red beat 12 . 4 (209) 94 . 1 . al.
378 3 . 271 decomp . 6 . 667 49 . 75 sl. s . al.
379 2 .681 750 . subl. white 64 . 4 100 . S . al.
heat
380 2 . 25 decomp. 25 . (59) 59 . (599) a1. 0 .0833 (hot)
381 2.3 1045 . 109 . 156 . 1. al.
382 2 . 326 334 . decomp. 6 . 25 50 . al. 0 . 833
383 1 . 995 790 . subl. white 32 . 56 . 6 al. 0 . 5
heat
384 2 .7 red heat 50 . 60 . 1. al.
385 1 . 83 400 . 20 . 50 . 1. al.
386 sl. s . sl. s . 1. al.
387 2 .048 s . al.
388 ) 1 . 54 red heat v. s. decomp. sl. s . al.
389 1. 861 140 . 80 . 1. al.
390 2 . 05 28 . 100 . 1 . al.
391 s. $ . 1. al.
392 14 . 3 200 .
393 2 . 014 red heat subl. white 200 . V . s. 8 . al.
heat
394 decomp. V. s. v . s.
395 decomp.
396 3 . 98 560 . 8 . (209) 32 . (100 )
397 3 . 06 705 . 128 . 209 . | al. 14.28
398 1 .613 red heat 64 . 5 (189) decomp.
35
HANDBOOK OF CHEMISTRY AND PAYSICS
PHYSICAL CONSTANTS OF
415 2 . 27 decomp.
416 ... . .. . . 12 . 5 100 . al. 4
417 . . . . . . . . S .
38
HANDBOOK OF CHEMISTRY AND PHYSICS
INORGANIC COMPOUNDS (Continued)
Solubility in 100 parts of
Sp . gr . Melting Bolling
water 1 point, point,
D . alr 1 Deg . C . Deg . c . Cold water . Hot water . Alcohol, acids,
etc .
478 . . . . . . . . decomp.
479 2 . 476 617 . 1.
480 1 . 62 0 .
481 2 . 04 200 . decomp. s.
482 1. 8 76 . 7 5 . 4 (0°) 93 .
483 1 . 525 38 . 96 .
484 53 . s.
485 2 . 499 | v . s. v. s .
486 S. s.
487 1 . 48 12 . 16 412 . (34 ) 1. al.
488 1.8 300 . v. s. | v. . 1. al.
489 | s. s . al.
490 1 . 56 decomp. 25 . 100 . 1. al .
491 s . decomp. decomp.
492 1 . 73 48 . 220 . decomp. 102 . (16°) 171. (45°) I. al.
493 1. HNO3
494 2 . 27 - 29 . 120 . S ., decomp. S . CS2
with much H : 0
s . alk . ; 1. a .
496 4 .5 red heat . . . . . . . 8 . al.
decomp.
497 2 .71 40 . 606 . 665 . s. al.
498 ) 6 . 11 decomp. red heat s. NHACI
499 4 . 97 red heat S . HCI
5001 2 . 542 800 . 1000 . decomp. decomp.
501 3 .62 decomp. at red heat 0 . 0056
502 ) 1 . 603 854 . 100 . 44 . (0°) 117 . (1189) al. 4 . 6
503 ) 1 . 396 100 . . . . . . . . 2 . (109) 41. ( 100°)
504 | 2 . 962 570 . . . . . . . . . 40 . (0°) 103 . ( 108 ) sl. s. al.
505 4 . 75 0 . 35 (0 ) 21 .
506 decomp. red heat sl. s .
597 3 . 71- 3 . 95 0 . 0145 (0°) 0 . 01 ( 100°) sl. a .
508 2 . 046 120 . 1. CS2
509 2 . 07 114 . - 115 . 449 . 4 sl. S . al.; S.
CS2
510 1 . 957 120 . 448 . 4 S . CS2
511 ) 1 .62 .. .. .. .. . 70 . decomp. decomp . decomp.
512 2 . 23 D - 79 . - 8 . 688 . vol. 170 . vol. al. 328 . vol.
513 1 . 854 s. a . p . s. a . p .
514 ] 1 .842 10 . 5 40 . S. a. p. S. a . p .
39
HANDBOOK OF CHEMISTRY AND PHYSICS
PHYSICAL CONSTANTS OP
523 oxide
de .. . . . . . . . . Te03. 175 . yellow crystals . . .
524 Tellurous acid . . . . H2TeO3.. . . . 177 . white . .
525 oxide . . . . . . . . . . TeOn. . . . . . 159 . regular , yellow
526 Thallium . . . . . . . . TI. . . . . 2041 .. .. .. .. .. .. ..
527 chloride (Ic) . . . . TICl3 + H20 328 . 5 1.. .. .. .. .. . . .. . .
528 chloride (ous) . . . . TICI. . . . . . 239 . 6 regular, white . . . .
529 ) hydroxide (ous) . TIOH . . . . 221 . 1
530 oxide (ic ) . . . Tl2O3. . . . . 456 . 2 black , hexagonal.. . .
531 oxide (ous) . . . . . . .
T120 . . . . . 424 . 1 black . . . . . .
532 ) nitrate (ous) TINO3. . . 266 . 1 rhombic .
533 ) sulphate (ous) . . . . Tl2SO4. . . . . 504 . 2 rhombic . . . .
534 sulphide (ous) . . . . Tl2s . . . . . . . 440 .21brown. . . . . . . . . . . . .
535 | Thorium nitrate . . . . Th (NO3) 4 . . . . 480 . 7
536 oxide . . . . . . ThO2.. 264 . 5 regular, amorphous,
white
537 | Tin . . . . . . . Sn . . . . . 118 . 5 white . . . . . . . . . . . . . .
538 Titanium . . TI . | 47 . 74 gray . . . . . . . . . . . . . .
539 tetrachloride . . . TIC14 . . . . 189 . 9
540 oxide TIO2 . 80 . 1 tetragonal, rhombic .
541 Tungsten . . . .. W . . .. .. 184 . tetragonal, gray,
white
542 Tungsten dioxide . . . WO2 . . . . . . . . . 216 . brown . . . . . . . . . . . . .
41
ARRANGEMENT
PERIODIC
ELEMENTS
THE
-OF
R
M1911
ENDELEJEFFS
)( EVISED
TO
ZERO VII
GVI
.VLIV
GROUP
III
GROUP
II ROUP
I ROUP
GROUPI GROUP
VIII
GROUP R-R20
RHA
RO
,–R 2O3
RH3°°R
RH OZRH 2O3 .
RO
O SERIES
Hydrogen
.01H= 08
1Lithium
H
Glucinum Ni
Catr
rbog
onen Fluorine
Oxygen
elium Boron
=3.9
He9 Li
=6.9 4
)(Beryllium 10
1|.0=0F0N1.C=1B0946021
9.1=Gl
Neon
Sulphur
Sodium
Chlorine
Magnesiu
Phosphor
Aluminu m
Silicon mus
Al
2.1!S Ne
=3
N
0Cl
334Mg 2
S.P=37608240357i
1a
Potassiu
Argon m Calcium Scandium Titanium Vanadium |Chromium Iron
Manganese Cobalt Nickel
4 4Ca
.0 0
1K.=3A 48099
481=Se .1Ti
=48 .0V=561 95.=0M
|C324rn 6.Ni 8Fe
=59Co85758
)(Cu
Copper Zinc Selenium
Bromine
Arsenic
Gallium
Germanium
5A
79G
6
Ga7
6.9=B
2Se Zn
3
Cu
5 9
7r
3
69524s
e
Krypton Strontiu
Rubidiumm Yttrium
Zirconium Columbium Molybdenum Rhodium
Ruthenium Palladium
869Z
.6 Kr
4R
Sr
0Y=8 rb
057529
3 =96
)(Niobium.0Mo 1Ru
=.7R
9P 01
h
06
02
d
=93
5.Cb )(Ag
Cadmium
Indium
Silver Tin Iodine y
Tellurium
Antimon
1T
1.0|I2=/S84Cd
Ag 19
0820
07
12
59n1426 e
2bn27
Pr
N
- eo eodym
asdy
Xenon Caesium
Barium
Lanthanum
Cerium mium
15H39
P,.0|=1L3B82CXe 30
37
40 ium =144
3.Nd
=1e732
6.Pr a40
Samarium Terbium
Gadolinium Erbium
41.Sa
= 50 .3Gd
2=1T57
59
b =167
4.Er
Ytterbium
Thulium (Neoytter Tungsten
Tantalum Osmium
Iridium
Platinum
51.Tm
= 68 )
bium 0=.W 84
1Ta 81 95
1I.2=P9Os93
t
r90
0=172
.Yb )(Au
Gold
Mercury
Thalium Lead Bismuth
Au
2H
1008
0.21|T
=P
Bi 00
04
07
97
Ig
b
Radium Thorium Uranium
4=2.Ra
26 .0Th
=232 5.U=238
HANDBOOK OF CHEMISTRY AND PHYSICS
SEPARATION OF THE METALS INTO GROUPS
SEPARATION T IE MET
AgCl, HgCI,
Precipitate: Filtrate: add N HOHand (NH4)2S .
PbCl2.
HgS, PbS, B12Ss, Cds,
Precipitate : Filtrate :
CuS, As2S3, Sb2S3, Sns,
AlO3H3 add (NH4)2CO3.
SnS2. Add (NH4)2Sx.
CrOzHz
Precipitate : Filtrate :
Residue: CoS, Nis,
Solution :
BaCO3, Mg. K and
HgS, PbS, (NH4)2Assa ! Fes ,Zns,
SrCO3, Na salts .
BizSs, Cds, (NH4)2Sbs, Mns.
CaCO3
| Cus. | (NH4)2SnSs.
Precipitate : AgCl.
Hg, Precipitate : Precipitate :
PbSO4 Pbs .
43
HANDBOOK OF CHEMISTRY AND PHYSICS
SEPARATION OF MERCURY, LEAD , BISMUTH , CADMIUM
AND COPPER
Outline of the process
Precipitate: HgS, PbS, BizSs, Cds, CuS. Boil with H NOs.
Residue: Hgs. Solution: add H2SO ..
Dissolve in HCI
Precipitate: Filtrate :add NHOH .
and KCIO3; add
SnCl2. PbSO , Precipitate : Filtrate: add KCN and H2S.
Precipitate: HgCI B103Hs.
Precipitate : Solution :
Dissolve in HCI,
Cds. KCN.CuCN
and add to H20 .
Precipitate :
Bioci.
45
.
water
add Fuse
HCldd
FeO3
,awith
H3 .NSrCO3
, a2HPOS
:
Precipitate
NagCO3
.and
Ca , CO3
:
Residue CrOzH3 .
Zns Prec
.
CaC204 : ipitate
,
BaCO3 OH
NH
with
.Fuse
NagMDO PO
.MgNH
SrCO3 :
NazCO .
Reject
,
. ed
|P: recipitate form
.CaCO3 .KCIO3
and
.
Hz
AlO3
.
HNO3
Add
Na2Cros
HANDBOOK OF CHEMISTRY AND PHYSICS
:
Solution
(NO3
2,)Ba .
formed
(NO3
)2,Sr
)Ca
(N2. O3
METALS
M AGNESIUM
BARIUM
,S
CALCIUM
ALKALI
AND
TRONTIUM
SEPARATION
OF
process
the
of
Outline
V
NII
:Balts
CSSolution
M
.)2(As,aKNrdd
nd
CO3
aH
g
a
HNO3
SPrecipitate
inrCO3
aCO3
.,C:Band
Dissolte
SOs
H4
)2(N.and
H
AC204
Filtrate
dd
.Treat
dryness
the
to
solution
porate
era
-ether
alcohol
mixture
.residue
with :
Precipitate Divide
parts
two
into
.Filtrate
.CaC2O4
,BaSO4 the
,adissolve
salts
NH4
Erpel
.0nd
NH
Add
1
dilute
SResidue
2,B
.:a)4(N dd
aO2
O3
H2S04
rolution
and water
in
residue
.add
Cawater nd
K?,inros
Dissolve
aSO4
:C.Precipitate .Na2HPO Test Add
dd
Solution
a:Precipitate in
flame
. HPt
. Cla
.
BaCr04 )2CO3
.(N H4 :
Precipitate
.POA
MgNH ,color
Yellow :
Precipitate
Precipitate
.
Na .
K2PtCl6
.
SrCO3
HANDBOOK OF CHEMISTRY AND PHYSICS
HANDBOOK OF CHEMISTRY AND PHYSICS
49
HANDBOOK OF CHEMISTRY AND PILYSICS
At, or One H
Hydrogen
Name. Formula . mol. equiv .
wt.
equivalent.
in gms.
Antimony . . . . . . Sb . . . . 120 . Sb . . 6 . 0
Arsenic . . . . . . . . . As. . . . . .. . . .. 75 . As. . . . . . . . . 3 . 75
NA
Arsenic trisulphide. . . As2S3. 246 . 18 As2S3. . . 6 . 1515
Arsenous oxide . . . . . . As2O3. 198 . As2O3. . . . 4 . 95
Barium peroxide . . . . BaO2. . . 169 . 4 Ba02. . . . . . 8 . 47
Barium peroxide, hy
drated . . . . . . . . . . . Ba ( 2 + 8 20 . . . 313 . 56 Ba () 2 + 8H20 . . . 15 . 678
Calcium . . . . . . . . . . . . Ca . . . . . . . . . . . . . 40 . Ca . . . . . . . . . . . 20 .
Calcium carbonate .. . CaCO3. . . . . . . . . 100 . CaCO3. . . . . 5 ,0
Calcium hypochlorite Ca (CIO ) 2 . . . . . . . 126 . 9 Ca ( CIO ) 2 . . . . . . | 6 . 345
Calcium oxide . . . . . . . Ca ( . . 56 . Cal . . . . . . 2 .8
Chlorine. . . . . . . ... C .. . . . . . | 35 . 45 CI. . 3 . 545
Chromium trioxide . . CrO3. . . 100 . 1 Cr03. . . 3 . 37
Ferrous ammonium ,
sulphate . . . . . . . . . . FeSO4 (NH4) 2SO4 FeSO4( NH4)2SO4
+ 6H20 . . . . . . 392 . 4 + 6H20 . . . . . . . . 39 . 24
Hydroferrocyanic
acid . . . . . . . .
. . HiFe ( CN) 6 . . . . . 216 . 28 H4Fe (CN ) 6 . . . 21 .628
Hydrogen peroxide . . H2O2. . 31 . 02 311202. . . . . . . 1 . 701
Hydrogen sulphide. . . H2S. . 31. 08H2 . . | 1 . 704
lodine . . . . . . . .
. . 120 . 85 i 12 .685
Iron . . . . . Fe. . . . Fe . . . 5 . 6
Iron oxide, ferrous . . . Fe ( . . 72 . F O . . . . . . 7. 2
Iron oxide, ferric . . . . Fe2O3. . . . . 160 . Fe2O3 . . . . 8.0
Lead peroxide. . . . . . . Pb0 . . . . . . . 238 . 91 PLO2. . . . . 11. 945
Manganes" peroxide . Vn02. 87 . Vn2. . . . . 4 . 35
Nitric acid . . . ... . . . . IIVO3. . . . . . . 03 .05 HNO3. . . . . 2 . 102
Nitrogen trioxide . . . . N203. . . . . . . . 76 . 08 V203. . . . . . 1 . 902
Nitrogen pentoxd 205. . . . . . . . 108 . 08 1 :03 . . . . . . . 1 . 801
Oxalic acid . . . . . . CH :04. . . . . . . . . 90 .02 H : C : O .. . . . . 4 . 501
Oxalic acid . . . . . . . .. . ( 1.04. 2010 . . . . 126 .00 ( 104.21120 . . . . . 6 . 303
Oxygen . . . . . . . .. . . . . . . . . . . . . 10 .. . . . . . . . . . . . . . 0 .8
Potassium bichro
mate . . . . . . . . . . .. .. K . Cr2O7. . . . . . . . ' 294 . 5 KCr2O7. . . . | 4 . 908
Potassium chlorate . . KC103 . . . . . . . . 122 . 6 KCIO3. . . . . . . . . . . 12. 26
Potassium chromate . KCrO4. . . . . . . . . , 191. 1 CrO4. . . . . . 9 . 72
Potassium ferrocyan
ide. . . . . . . . . . . . . . KFC (CV) . . . . . . 368. 84 KiFe (CN). . . . . . . . 36 . 884
Potassium ferrocyan
ide . . . . . . . . .
. . . KiFe(CV) .
+ 3H20 . . . . . . 122 . 9 KiFe (CN) 6 + 3H20 42 . 29
Potassium iodide . . . . KL . . . . . . . . . . . 166 . KI . . .. . . . . . . . . . . 16 . 6
Potassium nitrate . . . KVO3. . . . . . . . . . 101 . 19 TRXO3. . . . .. . . . . 3 . 373
Potassium perchlo
rate . . . . . . . . . . . . . KCIO : . . . . . . .. 1:38. 6 KC10d. ... ..... . ... . . 13 . 86
Potassium perman
no : . . . . . . .
ganate . . . . . . . . . . . K 158 . 15 KV04. . . . . ! 3 . 163
Sodium chlorate. . . . . , VaC103. . . . 106 . 5 VaC103. . . . . . . . . . ' 10 . 65
Sodium nitrate . . . . . . WaV03. . . . . . . . . 83 . 9 VaNO3. . . . . . . 2 . 836
Sodium phosphate,
sec . . . . . . . . . . . . . . . NaHPO4
+ 1211. 0 . . . .
. 3 .58 . 35 ! Va HPO4 + 12H2O 11 . 915
Sodium thiosulphate . NaSO3 + 51120 . 218 . 32 VaSO3-- - 5H20 . . . . 24 . 832
Stannous chloride . . . . SnCl2 . . . . . . . . . . 189 . 1 SnCl . . . . . . . . . 9 . 47
Stannous oxide. . . . . . Sn0 . . . . . . . . . . . 131. 5 Sn0 . . . . . . . . 6 . 425
Sulphur dioxide . . . . . 'SO2. . . . . . . . . 04 . 06 . 02. . . . . . . . . . . . . 3 . 203
Tii. . . . . . . . . . . ••••
. . . . Sn . . . . . . . . . . . . . 118 . 5 Sn . . . . . . . . . . . . . . 5 . 921)
50
.DDDDDDDDDD
rsenate DDDDDD
Desa
CDEDE3
sassa
HANDBOOK OF CỦEMISTRY AND PHYSICS
ادب.Dips
F.| errocyanide
Ferricyanide
C২২২২২২২২২
SOLUBILITY CHART
.>Hydroxide
.|Phosphate
.|Carbonate
EEN
Essss
Esses
.Sulphide
.| yanide
|Tartrate
-|Fluoride
২|.ব=২hloride
.|Arsenite
.A|:Ecetate
.|Oxalate
Silicate
EDDDDDDDDD
Borate
DE
৪
.EE
s
Oxide
.
.
:DDDDD
DDD
DDDD
EEEE
AL
Digi
DE
:DDE
:DDDDD
DDDD
NH, ..
biD
E:DDD
:DDi
ED
Sb . . .
:
D
DDDD
Ba . . .
:
D
>DED
Bi. . .
کحبمےحدنه
تحد
حبه
ح
Cd . .
ت
Ca . . .
:
Cr. . . . .
Co. . . . .
Essa
Cu . . . . - -
: - -
E:DDDD
Au . . .
H . Da
Fe" .
mono
Fe'' .
-
Pb . . . .
Mg. . . .
SED
Mn. .
Hg' . . . Wa A A . .
: -
D
AAA
EDE
Hg'' .
:
Ni. . . A a II!
WWW WWW W W W
-
K .. ...
>
Ag . . . . . A III
>
Na . . . www w WWW
-
-
Sn " . . .. W .. .. .. I W AW w WA
:D
Sn " . . . .
> > >
- -
: :
Sr . . . . . W AA AW AW W w AW W a AWW AW A A
Zn . . . . . W AA AW A WWW A A IW AW W
E:
A A A A
W Soluble in water.
A Insoluble in water but soluble in acids.
L
SOLUBILITIES
In Grams per 100g of Water
Temperature, Deg. C . 0 10 20 30 40 50 60 70 80 90 | 100
51
HANDBOOK OF CHEMISTRY AND PHYSICS
GRAVIMETRIC FACTORS AND THEIR LOGARITHMS
(From the Chemiker Kalender , published by Julius Springer, Berlin .) !
- - - - - - -
Aluminum :
Al2O3. . . . . . . . . . . . . . Al 0 . 53033 9 .72455 - 10
2A1C1z . . . . 2 .61156 10 .41690
Al2 (PO4)2 . . . . . . . . Al2O3 . . . . 0 . 41850 9 .62170
Ammonium :
NH4Cl. . . . . . . NH3. . . . . 0 . 31891 9 . 50367
V H4
. . . . . 0 . 33775 9 . 52860
SHOH . . 0 .65551 9 . 81658
2NH .CL ( NH4). ) . . . 0 . 48720 9 .68771
(NH, PtCI6 . . . . . 2.NH3. . . . 0 . 07695 8 . 88621
2NH4 0 . 08150 8 . 91118
AT
Arsenic :
3BaSO4. . . . . . AS2 . . . 0 - 21417 9 . 33076 - 10
As2O3. 0 . 28271 9 . 45134
2As03. 0 . 35124 9 . 54561
As2S3.. 0 . 35150 9 .54592
As2S5. . 0 . 44305 9 .64645
2 AsS4. 0 . 58038 9 . 76371
2BiAsO4.. . . . . AS2 . . . 0 . 21583 9 . 33411
As202. 0 . 28490 9 . 45460
2ASO3. 0 . 35396 9 . 54896
As2055 . . . 0 . 33094 9 .51979
2AsO4. 0 . 40000 9 .60206
As2S3. 0 . 35422 9 . 54927
As2S5. 0 .44648 9 . 64980
2AsS4. 0 . 58487 9 . 76706
Barium :
BaSO4. Ba.. 0 . 58853 9 . 76979
Bao . 0 .65705 9 . 81760
BaCl2 0 . 89222 9 . 95047
BaCO3. . Ba . 0 .69605 9 . 84624
Ba0 . 0 . 77709 9 . 89047
BaCl2 . 1 . 05521 10 .02334
BaCrO4.. Ba . . . 0 .54201 9 . 73401
Bao . 0 .60512 9 . 78184
BaCl2 0 .82169 9 . 91471
BaSiFe.. Ba. . 0 .49107 9 .69114
Ba0 0 . 54824 9 . 73897
BaCl2... .. . . . Ba . . 0 .65963 9 . 18930
Bao 0 . 73643 9 . 86713
Ba (NO3)2. . . Ba . . . . . . . . 0 . 52547 9 . 72055
Bao 0 .58665 9 . 76838
Bao . Ba . 0 . 89772 9 . 95217
Bismuth :
B1,03. 2Bi . . . . . 0 . 89679 9 . 95269
Bi2S3... . . . . . . . . . . . 2Bi. 0 . 81259 9 . 90987
Bi20 0 . 90611 9 . 95718
BiOCI. . . . . . . . . Bi . 0 . 80208 9 . 90422
2BiOCI. . . .. .. . . . . . . Bi20 0 .89440 9 . 95153
BinSz 0 . 98707 9 . 99435
BiAsO4. . . . . .. Bi 0 .60001 9 . 77816
2BiAsO4.. . . . . . . . . . . Bi_03.. . . . 0 .66907 9 . 82547
Bi2S3. . 0 . 73840 9 . 86829
Boron :
B203. 0 . 31428 9 . 49732
KBF4. . . . . . . 0 . 87199 9 . 94051
2KBF4. 0 . 27745 9 .44318
4KBF4 . . . . . . . . . . . . . B407 0 . 30915 l 9 . 49017
54
HANDBOOK OF CHEMISTRY AND PHYSICS
GRAVIMETRIC FACTORS AND THEIR LOGARITHMS
(Continued )
Weighed . Sought. Factor. Logarithm .
Bromine :
AgBr . . Br. . . 0 . 42557 9 .62897 - 10
HBr . 0 . 43095 9 . 63443
Br03. 0 .68104 9 . 83317
2AgBr . . . . . Br205 0 .63847 9 . 80514
Cadmium :
Cdo . Cd . 0 . 87500 9 . 94201
CdS . . . . . . . . Cd . 0 . 77746 9 . 89068
Cdo 0 . 88853 9 . 94867
CA (NO3)2.. .. .. Cd 0 . 47442 9 .67616
Cdo 0 . 54219 9 .73415
CdS04. cd 0 .53831 9 .73013
CdO . . . . . 0 .61521 9 . 78902
Calcium :
Ca0. . . . . Ca . . : : 0 .71428 9 . 85387
CaCl2 . 1 . 98034 10 . 29674
CaSO4. Ca . . . . . . 0 . 29399 9 . 46833
Ca ( . . 0 . 41159 9 .61446
CaCl2. 0 .81508 9 . 91120
Ca . . . . : : : 0 . 40000 9 .60206
CaCO3. Ca0 . . 0 . 56000 9 . 74819
CaCl2 . 1 . 10900 10 . 04493
Carbon :
CO2. . . . . . . . 0 . 27273 9 .43573
1 . 36361 10 . 13470
CaCO3. . . . . . 0 . 44000 9 .64345
0 . 60000 9 .77815
BaCO3. ... .. 0 . 22289 9 . 34810
0 . 30395 9 . 48280
Chlorine :
AgCl. . CI . 0 . 24725 9 . 39313
0 . 25428 9 . 40532
CIO 0 . 58202 9 . 76494
C104. . . . . 0 .69360 9 . 84111
NaCl. . . . . 0 . 40801 9 .61067
KCI. 0 . 52029 9 .71625
NaCIO : 0 . 74278 9 . 87086
KCI03. 0 . 85507 9 . 93200
2AgCl. . . . . . . . . . C1,05. . . . . 0 . 52622 9 .72117
Chromium :
Cr203. . . . . . Cr2 . . . . . . 0 . 68464 9 . 83546
2Cr03. . 1 . 31538 10 . 11905
2CrO4. . . . . 1 . 52563 10 . 18315
Cr2O7. . . . 1 .42053 10 . 15245
BaCrO4. . Cr. . . .. 0 . 20552 9 . 31286
CrO3. . . 0 . 39187 9 .59615
CrO4. . . . 0 . 15798 9 .66085
55
HANDBOOK OF CHEMISTRY AND PHYSICS
GRAVIMETRIC FACTORS AND THEIR LOGARITHMS
(Continued )
Weighed . Sought. Factor . Logarithm .
Chromium
2BaCr Cr2O3. . . . . 0 . 30019 9 . 47740 - 10
Cr2O7 0 . 42643 9 .62985
Cr. . .
PbCr04. . . . . .. 0 . 16130 9 . 20764
Cr03. 0 . 30991 9 . 49123
Cr04. 0 . 35944 9 . 55563
2PbCr04 . . . .. .. Cr2O3. . . . . 0 . 23560 9 . 37218
Cr207 0 . 33468 9 .52463
K2Cr2O7. . . . . . . Cr2 . . 0 . 35382 9 . 54878
Cr2O3. 0 .51680 9 . 71332
2Cr03. . . . 0 .67978 9 .83237
2Cr04. 0 . 78844 9 . 89677
Cr2O7 . . . . . 0 .73112 9 . 86577
Cobalt :
. . . Co () . 1 . 27119 10 . 10421
Co0 . . . . . . . . 0 .78667 9 . 89579
COSO4. . . . .. 0 . 38050 9 .58035
0 . 48368 9 .68456
K3C0 (NO.2)6.. . . . . 20 . . . . . . . .
Coo . . . . . .
0 . 13033 9 . 11505
0 . 16568 9 . 21926
Copper :
CuO . . . . . . . . . . . Cu . 0 .79901 9 . 90255
Cu2S .. . . . . . . . . . . . . . 112 . . . . . 0 . 79869 9 . 90238
2Cu ( . . 0 . 99961 9 . 99983
( uo . . . 0 . 89915 9 . 95383
Fluorine:
CaF2. . .. .. .. .. . . . . . . . . 1 2 . . . . . . 0 . 18718 9 .68769
2HF 0 . 51309 9 .71019
30
11.Sifo 0 .61716 9 . 79040
Bas 6F . . . . 0 . 40743 9 .61005
6UF . . . 0 . 42909 9 .63255
H SIF . . . . 0 .51614 9 . 71277
Sife. . . . . . 0 . 50893 9 .70666
SiF4. 0 . 37312 9 . 57185
K _ SiFe. . . . . . . . 6F .. . 0 .51654 9 . 71310
6HF 0 . 54400 9 . 73560
H .SiF6. 0 . 65436 9 . 81582
SiF6 0 .64522 9 . 80971
SiF4 0 . 47301 9 .67490
H2SiF6 . . . OF . 0 . 78937 9 . 89728
OHF 0 .83131 9 .91978
SiF6 : : 0 . 98603 9 . 99389
SiF4 . . . . . . 0 .72290 9 . 85908
Hydrogen :
HO . II . . . .. ... 0 . 11210 9 .04960
Iodine:
1205. . . . . . . 12 . . . . . . . . 0 .76026 9 . 88096
56
HANDBOOK OF CHEMISTRY AND PHYSIC'S
GRAVIMETRIC FACTORS AND THEIR LOGARITHMS
(Continued )
Weighed . Sought. Factor . Logarithm .
Iodine
1 05. 2HI 0 . 76630 9 . 88440 - 10
2103. . . . . . 0 .04795 10 . 02034
AgI. . . 0 .54029 9 .73263
0 . 54459 9 . 73607
0 .74490 9 . 87201
104. 0 . 81289 9 . 91003
2AgI.. . . .. . 1.05. 0 .71067 9 . 85167
1207 0 .77883 9 . 89144
PdI.. . . ... . 0 . 70531 9 . 84838
2HI. 0 .71092 9 . 85182
2103 0 . 97221 9 . 98776
1.05. 0 . 92773 9 . 96742
2104. 1 . 06116 10 .02578
1207 1 .01669 10 . 00719
PbI2 . . . . . . 0 . 55081 9 .74100
2HI 0 . 55519 9 . 74444
2103 0 . 75924 9 . 88038
120 .5. . 0 .72450 9 . 86004
Iron :
Fe2O3. . . . . . Fe2 0 . 70000 9 .81510
2FeO 0 . 89999 9 . 95424
2Fes . 1 . 10075 10 . 04169
2Fes 1 . 50152 10 . 17653
FeS . . . . . . . Fe. 0 .63593 9 . 80341
Fel 0 .81762 9 . 91255
2Fes. . . ........... Feza
0 . 90847 9 . 95831
Fez(PO4)2. . . . . . .. . . Fez. 0 . 37086 9 . 56921
2Fel . ... 0 . 47682 9 .67835
Fe.03. . .. . 0 . 52980 9 .72411
Lead :
Pbo . Pb .. ....... . 0 . 92822 9 . 96765
PbS . . . . . . 1 . 07206 10 .03022
PbSO4. . . . 1 . 35916 10 . 13327
PbS. . . . . . . .. Pb . . . . . . . . 0 . 86582 9 . 93743
Pb0 . . . . . . 0 . 93278 9 . 96978
PbSO4. . . 1 . 26780 10 . 10305
PbCl2 .... .... Pb . . . . 0 . 74478 9 . 87203
Pb0 . . 0 . 80238 9 . 90438
PbI.. .. . .. . . Pb . . . 0 . 44920 9 . 65244
PbO : 0 . 48394 9 . 68479
PbSO4. 6 . . . . . Pb .. . . . . 0 .68294 9 . 83438
Pb0 . . 0 . 73575 9 . 86673
Pbs . 0 . 78877 9 . 89695
PbCrOs. . . . .. Ph . 0 . 64056 9 . 80656
PbO . . . . 0 .69010 9 . 83891
PbS . . . . . . ! 0 .73983 1 9 . 86913
57
HANDBOOK OF CHEMISTRY AND PHYSICS
GRAVIMETRIC FACTORS AND THEIR LOGARITHMS
(Continued )
Weighed . Sought. Factor. Logarithm .
Lead :
Pb . . . . PbO . . . . . 1 . 07733 10 .03235 - 10
Lithium :
Li2CO3. . . Li2. . . 0 . 18985 9 . 27841
LiO . 0 . 40589 9 .60841
2LICI 1 . 14718 10 .05963
LiCl. . . . . . . . . . . Li . . 0 . 16549 9 . 21878
2LICI . . . . . . . Li O . 0 . 35382 9 . 54878
Li20 . . . . .. .. . . . . . . . 2Li 0 . 46774 9 .67000
2LICI 2 . 82631 10 .45122
Li2SO4. . . . . . . 2Li. . . . . . . 0 . 12768 9 . 10612
Li20 . . . . 0 . 27297 9 . 43612
2LiCi 0 . 77151 9 . 88734
Li3PO4. .. . .. 3Li . . 0 . 18167 9 . 25929
3LiCl. . . 1 .09779 10 . 04052
2Li3PO4. . 3L1,0 . . . . .. 0 . 38841 9 .58929
Magnesium :
MgO . . . . . ... Mg. . . 0 .60357 9 . 78073
Mg2P :07 . . . . . 2Mg. . 0 . 21875 9 . 33995
2Mg0 . 0 . 36243 9 . 55922
MgSO4.. . . . . . . . Mg . . 0 . 20229 9 . 30598
Mg( ... 0 . 33516 9 .52525
Manganese :
VnO . . . . . . . \ n.. . 0 . 77464 1 . 88910
Mny 6 . . . . . . . . . . . . .12.11n .. . . . 0 .69169 9 .84273
21no 0 . 89873 9 .95363
Mn304. . . . . . 31n . . . . 0 . 72051 9 . 85764
31no . 0 . 93012 9 . 96854
31nO4. . 1 . 55894 10 . 19283
MnS . . . . . . . Mn . . . . . 0 .63174 9 . 80054
Vn0 . . . 0 . 81553 9 . 91144
MnO4. . . . . 1 . 36688 10 . 13573
MnSO4 . . . . Vin . . . . . 0 . 36409 9 . 56121
Mercury : MnO . . 0 . 47001 9 .67211
Hg . . . . . . . . . Hg( . . 1 . 07989 10 . 03338
HgS . . 1 . 16006 10 .06448
2Hg. . . . . . . . . 11g ,0 . 1 . 03994 10 .01701
Ilg,C1, 1 . 17698 10 . 07077
Hg() . . . . . . . Hg . . 0 . 92602 9 . 96662
lgs . 1 . 07124 10 .03110
211g().. . ..... Hg20 . 0 . 96301 9 . 98363
HgS . . . . . . Hg . : 0 . 86203 9 . 93552
Hg( . . . . 0 . 930S9 9 . 96890
lly:Cl, 211g . . . . 0 . 81963 9 . 92923
211g0 . . . . 0 . 91751 9 . 96261
Ig0 . . . 0 . 88357 9 . 91621
2HgS . . . . . 0 . 98.562 9 . 99371
58
HANDBOOK OF CHEMISTRY AND PHYSICS
GRAVIMETRIC FACTORS AND THEIR LOGARITHMS
(Continued )
Molybdenum :
MoSz . . . . . Mo 0 . 49953 9 .69856 - 10
M002. , . . . 0 . 66604 9 . 82350
M002. 0 . 75000 9 . 87506
a
Nickel:
NiO . . . . . . . . . . . 0 . 78581 9 . 89532
NiSO4. . . . . . . . . . . . . . 0 . 37930 9 . 57898
Nitrogen : NiO . . . 0 . 48268 9 . 68836
tore
TA
VOO
inves
1 . 030 4 . 49 0 .046 1 . 240 27 48 32 . 280.400
1 .035 5 . 230 .051 1 . 245 49 32 .860. 409
1 .040 1 5 . 96 0 . 062 1 . 250 .ivave 50 33. 430 .418
1 .045 6 . 0 6 .67 0 .071 1 . 255 29 51 34 . 000 . 426
1 .050 6 . 7 7 . 37 0 .077 | 1 . 260 29. 52 34 .570 . 435
1 . 055 | 7 . 4 8 . 07 0 . 035 1 . 265 30 . 35 . 140 .444
1 . 060 8. 0 8 . 77 / 0 . 093 | 1 . 270 30 35 . 71 0 . 454
1 . 065 8 .7 9 . 4710 . 102 1 . 275 31 36 . 290.462
1 . 070 | 9 . 4 14 10 . 19 0 . 109 1 . 280 31 36 . 870. 472
1 . 075 10 . 0 10 . 90 0 . 117 1 . 285 32 37 . 450. 481
1 . 080 10 . 6 16 11 .600 . 125 1 . 290 32 58 38 .030.490
1 . 085 11. 2 17 12 . 30 0 . 133 1 . 295 32 . 59 38 .610. 500
1 .090 11 . 9 18 12 . 99 0 . 112 1 . 300 33 . 60 39 . 190. 510
1 . 095 12 . 4 13 .67 0 . 150 1 . 305 61 39 . 770 .519
1 . 100 13 . 0 14 . 35 0 . 158 1 . 310 34 . 2 62 40 . 350. 529
1 . 105 13 . 6 15 .03 0 . 166 1 . 315 34 . 6 63 40 . 930 .538
1 . 110 14 . 2 15 .71 0 . 175 . 1 . 320 35 . 0 64 41. 500. 548
1 . 115 14 . 9 16 . 36 0 . 183 | 1 . 325 35 . 65 42 .08 0 . 557
1 . 120 15 . 4 17 . 01 0 . 191 || 1. 330 35 . 8 66 42.660 .567
1 . 125 16 . 0 17 .66 0 . 199 1 . 335 36 . 2 67 13. 2010 . 577
1 . 130 16 . 5 18 . 31 0 . 207 1 . 340 36 . 6 68 43 . 740 . 586
1 . 135 17 . 1 18 . 960 . 215 1 . 345 37 . 69 44 . 280. 596
1 . 140 17 . 7 19 .61 0 . 223 1 . 350 37 . 4 70 44 . 820 .605
1 . 145 18 . 3 20 . 260. 231 1 . 355 37 . 71 45 . 350.614
1 . 150 18 . 8 20 .910 . 239 1 . 360 38 . 72 45 . 880 .624
1 . 155 19 . 3 21 .55 0 . 248 1 . 365 38 . 6 73 46 .410 .633
1 . 160 |19 . 8 22 . 190 . 257 1 . 370 39 . 0 74 46 . 940.643
1 . 165 20 . 3 22 . 83 0 . 266 1 . 375 39. 4 75 47.47 0 .653
1 . 170 20 . 9 23 .47 0 . 275 1. 380 39 .8 76 48 . 00 0 . 662
1 175 21 4 24 . 12 0 . 283 1 . 385 40 . 1 77 48 .53 0 .672
1 . 180 22. 0 24 . 76 0 . 292 1 . 390 40 . 5
78 49 . 06 0 .682
1 . 185 22 . 5 25 .40 0 . 301 1 . 395 40 . 81 79 49 .59 0 .692
1 . 190 23 . 0 26 . 04 0 . 3101 1 . 400 41. 21 80 50 . 11 0 . 702
1 . 195 23 . 5 26 . 68 0 . 319 1 .405 41.6 81 50 .63 0 .711
1 . 200 24 . 0 27 . 32 0 . 328 1 . 410 42 . 0 82 51 . 150.721
1 . 205 24 . 5 41 27. 95 0 .337 | 1.415 42. 3 83 51.66 0 .730
HANDBOOK OF CHEMISTRY AND PHYSICS
SULPHURIC ACID (Continued)
Sp . gr . | Deg . Tw
Dead
g.- uPer Total
. S04 kg . in Sp . gr . Deg . Per Total
cent. H2SO Deg . Twad cent. | H2SO4
at
Bé. i dell | H2SO4 kg . in Bé. | dell. H2SO4 kg . in
15° C by wt. 1 liter. 15° C . by wt. 1 liter .
ACETIC ACID
SPECIFIC GRAVITY OF AQUEOUS SOLUTIONS, AT 15° C .
OUDEMANS
(From the Chemiker Kalender, published by Julius Springer.)
otvornon
1 .000 0 .0 0 . 10 0 . 001
1 . 005 0.7 avairo 1 . 00 0 . 010
1 . 010 1 . 90 0 .019
1 .015 2 . 80 0 . 028
1 .020 3 . 70 0 .038
1 . 025 4 .60 0 . 047
1 . 030 5 . 50 0 . 057
1 .035 6 . 38 0 . 066
concos
1 .040 7 . 26 0 . 075
1 . 045 8 . 13 0 .085
1 . 050 10 8 . 99 0 . 094
10
os
1 . 055 11 9 . 84 0 . 104
1 . 060 10 .68 0 . 113
1 . 065 11. 51 0 . 123
1 . 070 14 12 . 33 0 . 132
15
1 . 075 10 . 0 13 . 15 0 . 141
1 . 080 10 . 6 16 13 . 95 0 . 151
17 14 . 74 0 . 160
1 . 085 11. 2
18
1 . 090 11 . 9 15 .53 0 . 169
1 . 095 12 . 4 16 . 32 0 . 179
1 . 100 13 . 0 20 17 . 11 0 . 188
1 . 105 13 . 6 21 17 . 89 0 . 198
14 . 2 22 18 . 67 0 . 207
OOTA
1 . 110
1 . 115 14 . 9 19 .45 0 . 217
1 . 120 15 . 4 20 .23 0 . 227
1 . 125 16 . 0 21 . 00 0 . 236
1 . 130 16 . 5 21. 77 0 . 246
1 . 135 17 . 1 22 . 54 0 . 256
1 . 140 17 . 7 29
23 . 31 0 . 266
1 . 145 18 . 3 24 . 08 0 . 276
1 . 150 18 . 8 30 24 . 84 0 . 286
1 . 155 19 . 3 31 25 .60 0 . 296
1 . 160 19 . 8 32 26 . 36 0 . 306
27 . 12
co
1 . 165 20 . 3 0 . 316
1 . 170 20 . 9 27 . 88 0 . 326
1 . 175 21 . 28 .63 0 . 336
1 . 180 22 . 0 29 . 38 0 . 347
1 . 185 22 . 5 30 . 13 0 . 357
1 . 190 23 . 0 30 . 88 0 . 367
39
1 . 195 31 .62 0 . 378
1 . 200 24 . 0 40 32. 36 0 . 388
1 . 205 24 . 5 33. 09 0 . 399
1 . 210 25 . 0 33 . 82 0 . 409
A
1 . 220 26 . 0 44 35 . 28 0 . 430
1 . 225 26 . 4 45 36 .03 0 . 441
1 . 230 26 . 9 36 . 78 0 .452
1 . 235 27 . 4 37. 53 0 . 463
1 . 240 27. 9 38 . 29 0 .475
1 . 245 28 . 4 39 . 05 0 . 486
1 . 250 28 . 8 39. 82 0 .498
1 . 255 29 . 3 40 .58 0 . 509
1 . 260 29 . 7 41. 34 0 .521
1 . 265 30 . 2 42 . 10 0 .533
1 . 270 30 . 6 42 . 87 0 . 544
1 . 275 31 . 1 43 .64 0 . 556
1 . 280 31 . 5 44 . 41 0 . 568
1 . 285 32 . 0 45 . 18 0 . 581
1 . 290 32 . 4 45 .95 0 . 593
1 . 295 32 . 8 46 . 72 0 . 605
1 . 300 33 . 3 47.49 0 . 617
1 . 305 33 . 7 48 . 26 0 .630
1 . 310 34 . 2 49. 07 0 .643
1 . 315 34 . 6 49 . 89 0 . 656
1 . 320 35 . 0 50 . 71 0 . 669
1 . 325 35 . 4 65 51. 53 0 .683
1 . 330 35 . 8 66 52. 37 0 .697
1 . 3325 36 . 0 66 . 5 52. 80 0 .704
1 . 335 36 . 2 53 . 22 0 .710
1 . 340 36 . 6 54 . 07 0 . 725
1 . 345 37 . 0 54 . 93 0 .739
1 . 350 37 . 4 55 .79 0 . 753
1 . 355 37 . 8 56 .66 0 . 768
1 . 360 38 . 2 57 .57 0 . 783
1 . 365 38 . 6 58 . 48 0 . 798
1 . 370 59 . 39 0 . 814
1 . 375 39 . 4 60 . 30 0 . 829
1 . 380 39 . 8 61. 27 0 . 846
1 . 3833 40 . 0 61 . 92 0 . 857
1 . 385 40 . 1 77 62. 24 0 . 862
1 . 390 78 63 . 23 0 . 879
1 . 395 40 . 8 64. 25 0 . 896
1 .400 41 . 2 65 . 30 0 . 914
1 . 405 41. 6 66 . 40 0 . 933
1 . 410 42. 0 67 . 50 0 . 952
1 .415 42 . 3 68 .63 0 . 971
1 . 420 42 . 7 69. 80 0 . 991
1 . 425 43 . 1 70 . 98 1 .011
1 .430 43 . 4 72 . 17 1 .032
1 . 435 1 . 053
43 . 8 87 73 . 39
1 . 075
1 . 440 | 44 . 1 88 74 .68
HAVDBOOK OF CHEMISTRY AND PHYSICS
NITRIC ACID (Continued )
Degrees Degrees Per cent HNO3 Total HNO3
at 1:56.C. Baumé. Twaddell. by weight. kg. in 1 liter .
1 .445 44 . 4 75 . 98 1 . 098
1 . 450 44 . 8 77 . 28 1 . 121
1 . 455 45 . 1 78 .60 1 . 144
1 . 460 45 . 4 79 . 98 1 . 168
1 . 465 45 . 8 81 .42 1 . 193
1 . 470 46 . 1 82. 90 1 . 219
1 . 475 46 . 4 84 . 45 1 . 246
1 . 480 46 . 8 86 . 05 1 . 274
1 . 485 47 . 1 87 . 70 1 . 302
1 . 490 47 . 4 89 . 60 · 1 . 335
1 . 495 47. 8 91 . 60 1 . 369
1 . 500 48 . 1 100 94 . 09 1 . 411
1 . 505 48 . 4 101 96 . 39 1 . 451
1 . 510 48 . 7 102 98 . 10 1 . 481
1 .515 49 . 0 103 99 . 07 1 . 501
1 . 520 49 . 4 104 99 . 67 1 .515
HYDROCHLORIC ACID
SPECIFIC GRAVITY OF AQUEOUS SOLUTIONS
(From the Chemiker Kalender, Published by Julius Springer , Berlin .)
VAAVAA
Sp . gr.
Total Total
Deg . ' TDeg
wad . Per HC Sp . gr . | Deg. Per HCI
at Twad - cent. at Twad - cent .
15°C Bé. kg . per 15
Bé. HCI. kg . per
deli HCI.
liter . dell. liter.
AMMONIUM HYDROXIDE
SPECIFIC GRAVITY OF AQUEOUS SOLUTIONS
(From the Chemiker Kalender, published by Julius Springer, Berlin .)
Specific per cent Total NH : Specific Per cent Total NH3
gravity . NH3. g . per liter . gravity . NH3. g . per liter.
69
HANDBOOK OF CHEMISTRY AND PHYSICS
ALCOHOL BY VOLUME
TRALLES
(From the Chemiker Kalender , published by Julius Springer , Berlin .)
cent cent
gravity . by vol./ gravity . by vol. gravity. by vol. gravity .
by vol.
Aoooo
voer
70
HANDBOOK OF CHEMISTRY AND PHYSICS
Mass Density
of 1 |Density , air 1 . referred to
Formu- Mol. liter H2 ( 2 ) .
Name. la . wt. ing. at
760 m . Obs . Mol
0° C . Com . | Obs. lat 00 Mol.
wt.
T. C.
Acetylene . . C2H2 | 26 .02 1 .1620 0 .8988 0 . 92 | 26 .04 25.82
Air . . . . . . . .. . 1 . 2928 1 . 0000
NH3 17 . 06 0 . 7621 10 . 5895 10 . 5971 | 17 . 17 16 . 93
Ammonia . . . .
Argon . . . . . A 39 . 9 1 . 782 1 . 379 1 . 379 39. 60 39. 60
Arsine . . . . . AsH3 78 . 0 3 . 485 12 .696 2 .695 | 77 . 45 77 . 45
Bromine. . . . Br2 159. 92 7 . 1426 15 .5249 5 .5243 158. 54 158 .72
Butane . . . . . C4H10 58 . 08 2 . 5945 12 . 0065 2 . 0100
Carbon dioxide . . . . . . CO2 44 . 1 . 9652 1 .5201 1 .529143. 97 43. 67
Carbon monoxide. . . . CO 28 . 1 . 2506 0 . 9673 0 . 9672 27 . 82 27 . 79
Carbon oxychloride. . COCI: 98 . 90 4 .4172 3 . 4163 3 . 505 100 . 7 98 . 15
Carbon oxysulphide. . . . COS 60 . 06 2 . 6825 2 . 0749 2 . 1046 60 .52 59 .62
Chlorine. . . . . . . . . . . Cl2 70 . 90 3 . 1666 2 .4494 2 .491 71 . 60 70 36
Chlorine dioxide. . . CIO2 67.45 3 .0126 12 .3303 2 . 330 66 . 94
Chlorine monoxide. . . C1, 0 86 . 90 3 . 8813 3 . C022 3 . 0072 86 . 54 86 . 24
Cyanogen . . . . . . . . . C2N2 52. 08 2 . 3261 1 .7993 1 . 8064 51 .75 51 .68
Ethane. . . . . CH6 30 . 05 1 . 3421 1 . 0381 1 . 075 30 7. 29 . 82
Ethyl chloride . . . . . CHCl 64 . 49 2 . 8804 2 .228 2 . 219 63. 14 64 . 00
Ethylene . . . . C2H4 28 .03 1 . 252 0 . 9684 0 .9852 28 . 13 27 . 82
Fluorine . . . . . . . F2 * 38 . 1 .697 1 . 313 1 . 26 37. 82
Helium . . . . He 0 . 1787 10 . 1382 0 . 1368
Hydrobromic acid . HBr | 80 . 97 3 . 6163 12 . 7973 2 . 71 1 77. 77 80 . 36
Hydrochloric acid . . HCI 36 . 46 1 . 6283 1 . 2595 1 . 269236 . 50 30 . 18
Hydrofluoric acid . . . HF 20 . 0 . 894 10 .691 0 . 7126 20 . 19 20
Hydriodic acid . . . . . . HI 127 . 80 5 . 7106 4 . 4172 4 . 3757 126 . 76 126 . 90
Hydrogen . . . . . . . . . . H2 2 . 016 0 .0900 0 . 06965 0 . 06960 2 . 00 2 . 00
Hydrogen selenide. . . H2Se 81. 2 3 . 627 2 . 806 2 . 795 80 . 36 80 . 58
Hydrogen sulphide. . . . H S | 34 . 08 1 .5230 | 1 . 1773 1. 1895 34 25 33 .83
Hydrogen telluride . . . . H . Te 129 .6 5 . 789 4 . 478 4 . 489 129 . 11 128 . 64
Krypton . . . . . . . . . . Kr 81 . 8 3 . 654 2 . 826 2 . 818 | 81. 20 81. 20
Methane . . . . . . . . CH ; 16 . 03 0 . 716 0 . 5539 0 . 5576 16 . 07 15 . 91
Methyl chloride . . CHCI 50 .47 2 . 2543 1 . 7438 1 .731 / 54 .77 50 .09
Methyl ether . . . C2H60 46 .05 2 .0567 1 . 5909 1 . 617 46 . 84 45 . 70
Neon . . . : : : . . . . . Ne 20 . 0 .893 0 .691 0 . 674 19 . 86 19 . 86
Nitric oxide . . . NO 30 . 04 1. 341 1 .0378 1 . 0387 29 . 83 29 . 81
Nitrous oxide . . N20 44 . 08 1 . 9688 1 .5229 1 .5301 | 44 . | 43 .74
Nitrogen . . . . N2 28 . 08 1 . 2542 0 . 9701 0 . 96717 27 . 81 27 . 86
Nitrosyl chloric NOCI 65 .49 2 . 925 2 . 2625 2 . 31 66 . 3 65 .
Oxygen . . . . . . . . . 02 32 . 1 . 4292 1 . 1055 1 . 10535 31. 78 31. 76
Phosphine . . . . . . . . PH3 34 . 11 .520 1 . 175 1 . 214 34 . 08 33 .77
Silicon fluoride . . . . SiF4 104 . 4 . 663 3 . 607 3 . 60 103. 52 103. 82
Sulphur dioxide . . . SO2 64 . 06 2 . 8611 2 . 2131 2 . 2639 64 . 44 63. 59
Xenon . . . . . . . . . . . . Х 128 . 5 . 717 4 . 122 4 . 422 127 . 10 1. 7 10
1. Any metal will replace any other metal, belove it in the series, from
solutions of its salts, thus:
Fe + CuSO4 = FeSO4 + Cu
Zn + FeSO4 = ZnSO4 + Fe
Fe + 2HCI = FeCl2 + H2
Zn + H2SO4 = ZnSO4 + H2
Cu + HCI = No action . Cu insoluble .
Ag + HCI No action . Ag insoluble .
Cu + (dilute ) H2SO4 = No action .
Ag + CuSO4 = No action. Ag below Cu .
Note . It is true that dilute and conc. HNO3 and hot conc. H2SO4 will
dissolve most of the metals. When they thus dissolve metals below hydrogen
in the series, the action is an oxidizing one, and the acids are reduced to
NO and SO2 respectively . The metal is first oxidized to the oxide, the
acid being thus at the same time reduced , and the oxide thus formed then
reacts with the acid molecule present, and goes into solution as a salt .
Cu + (dilute ) H2SO4 = No action .
(b ) Cu + 2 (hot conc.) H2SO4 = CuSO4 + 502 + 2H20 .
In (b ), the Cu is first converted to Cuo , thus
Cu + H2SO4 = CuO + H20 + 502,
then the CuO reacts with another molecule of H2SO4, thus
CuO + H2SO4 = CuSO4 + H20 .
3Cu + 2HNO3 = 3Cu ( + 2NO + H2O
3CuO + 6HNO3 = 3Cu (NO3)2 + 3120
Added 3Cu + SHNO3 = 3Cu (NO3) 2 + 2NO + 4H2O .
2 In Regard to Ease of Reduction of Oxides . The metallic oxides down
to and including Mn can not be completely reduced to the metal state ,
even in a current of hydrogen . The oxides of Cd and succeeding metals
are easily reduced , and far down the list , the oxides of silver , platinum ,
mercury , and gold are reduced (decomposed into metal and oxygen ) even
by heat alone.
3 . In Regard to Ease of Rusting. (Oxidation in the Air.) - The alkali and
alkaline- earth metals rust very rapidly and with considerable evolution
of heat. All the metals down to copper rust with comparative ease .
The metals below copper do not rust . Assuming the electrolytic theory
of the process of rusting to be true , these facts are just about what might
have been predicted .
4 . In Regard to the Occurence of the Metals in the Free State in Nature .
Natural waters are frequently dilute solutions of carbonic, nitric, humic.
etc. , acids. As such they contain displaceable hydrogen . Metals above
hydrogen in the E . M . F . series scarcely , if ever, occur in the free state
in nature, but are practically without exception found in the combined
state , as sulphides, carbonates, etc. Metals below hydrogen are frequently
found in the free state in nature . Thus gold is found in the form of nuggets
of metallic gold . However, metals below hydrogen are also found in the
combined state, as cinnabar , HgS , etc .
5 . In Regard to Action of the Metals on Water. - The alkali and
alkaline-earths metal displace hydrogen from water, even in the cold ,
72
HANDBOOK OP CHEMISTRY AND PHYSICS
and with evolution of much heat. Mg and succeeding metals will dig.
place hydrogen from steam . Metals at the bottom of the list will not
disp! In Rhydrogen
displace eges havefrom steam .
6 . In Regard to the Solubility and Stability of Hydroxides. - The alkali
metal oxides have great avidity for water, forming hydroxides. The
alkaline- earth metal oxides react with less readiness , forming hydroxides .
MgO reacts slowly and incompletely with water , forming the hydroxide .
All the other metallic oxides and hydroxides are insoluble in water and
have no perceptible reaction therewith . When a solution of NaOH acts on
solutions of salts of the metals , the alkali metal salts are not precipitated .
The alkaline -earth metal salts are not precipitated unless in very con
centrated solution . All the other metal solutions are acted upon , with
precipitation of hydroxides, except in the case of copper which first gives
copper hydroxide (blue) , and which , on warming, changes to copper oxide
(black ) . Also in the case of arsenic , no precipitate falls , sodium arsenite
being formed . In the case of the last metals in the series, the oride is
precipitated
le , instead
d of
on the hydroxide, thus NaOH acting on salts of Sb ,
solubAg, Pd,
Hg,
r
RegaPt, and i
t causes
EcepAu, , dises aa pprecipitation
ri of the orides of these metals .
Bismuth , as an exception , gives a normal hydroxide .
7 . In Regard to Carbonates. — The alkali metals form normal stable ,
soluble carbonates, not easily decomposed on heating. The alkaline-earth
metals form normal carbonates , which are insoluble in water, and which
decompose upon heating , leaving the oxide , carbon dioxide being evolved .
When sodium carbonate solution acts on solutions of all the other metals ,
as a rule , a basic carbonate is precipitated , being insoluble in water, and
decomposed by heat into oxide and carbon dioxide. If the solution is cold ,
Ag, Hg, Cd , Fe, and Mn give normal carbonates . It the solution is warm ,
Sb , Hg, Ag, Pd , Pt, and Au give a precipitate of the oride, instead of the
carbonate , thus showing the instability of the carbonates of the lowest
metals in the series.
8 . In Regard to Voltaic Cells . - In choosing metals to acts as electrodes
in voltaic cells, the farther apart the metals chosen , the greater the electro
motive force of the voltaic cell. Thus the Al-Au couple gives a greater
E . M . F . than the Zn -Cu couple .
For complete information , see Alex . Smith ' s Gen . Inorganic Chem . ,
pages 361- 363 : 664 - 680. J . W . Mellor's Modern Inorg. Chem ., pages
362 - 376 .
Fuel
Carbo value
Name of the food Protein . Fat. Ash . Water . in cal
material drates . ories
per lb .
0 . 3 | 13 . 2 3510
Butter . . . . . . . 1.0 85 .0 3 .0 | 11. 0 3410
Buckwheat . . . . . . . 10 .0 2. 2 2.0 12 . 6 1600
19
.
CALORIES
HYDRATES
TABLES SHOWING THE FUNCTIONS, USES AND
VALLE
COMPOSITIONS OF FOODS-- Continued
FUEL
IN
WATER
PROTEIN
CARBO
PER
LB
NAME OF THE FOOD MATERIAL
,
ASH
FAT
Oyster . . . . . . . . . . . . 6 .2 1. 2 3.7 2 .0 86 . 9
235
coiocco
Parsnip . . . . . . . . . . . . 1 .6 0 .5 13 . 5 1 . 4 83 . 0 230
Potato . . . . . . . . . . . . . . 0. 1 18 . 4 1. 0 | 78 .31 385
ORN
Peanut butter . . . . .
Rye . 10 . 5 1750
Rice . 2 .0 77 . 0 1. 0 12 . 0 1720
0 .5 11. 5 84 . 5 285
O
DENSITY OF WATER
The temperature of maximum density for pure water, free from air
= 39.98 C .
The density at this temperature - 0.999973 ( C . G . S .).
( International Bureau ofWeights and Measures, 1910 .)
76
HANDBOOK OF CHEMISTRY AND PHYSICS
DENSITY OF VARIOUS LIQUIDS
(Selected from Smithsonian Tables.)
Degrees Baumé.
Density .
. 00 . 01 .02 . 03 . 04
Degrees Baumé.
Density .
. 05 . 06 . 07 . 08 .09
0 . 60 85 . 38 82 . 12 78 . 95 75 . 88 72 . 30
56 .67 54 . 21 51. 82 49 . 49 47 . 22
. 80 34 .71 32 . 79 30 . 92 29 .09 27 . 30
: 90 17 . 37 15 . 83 14 . 33 12 . 86 11 . 41
1 . 00
HANDBOOK OF CHEMISTRY AND PHYSICS
8 INE
Density. Baumé. Twaddell . Density . Baimé. Twaddell.
1 . 00 0 .00 ANO
.S
OS
00 1 .41 42 . 16 82
1 .01 144 1 . 42 42 . 89
1 .02 2 . 84 1 . 43 43 .60
1 .03 4
1 . 44 44 . 31
1 . 04 1 . 45 45 . 00
1 . 05 6. 1 .46 45 . 68
1 . 06 8 1 . 47 46 . 36
1 .07 9 .49 1 .48 47 . 03
1 .08 10 . 74 1 .49 47 .68
1 .09 11 . 97 1 . 50 48 . 33 100
1 . 10 13 . 18 1 .51 48 . 97 102
1 . 11 14 . 37 1 . 52 49 .60 104
112 15 .54 1 . 53 50 . 23 106
1 . 13 16 .68 1 .54 50 . 84 108
1 . 14 17 . 81 1 . 55 51 . 45 110
1 . 15 18 . 91 1 . 56 52 . 05 112
1 . 16 20 . 00 1 . 57 52 .64 114
og
1 . 17 21 . 07 36
1 . 58 53 . 23 116
1 . 18 22 . 12 1 .59 53. 80 118
1 . 19 23 . 15 38 1 .60 54 . 38 120
1 . 20 24 . 17 40 1 .61 54 . 94 122
1 . 21 25 . 16 1 . 62 55 . 49 124
1 . 22 26 . 15 44 1 .63 56 . 04 126
1 . 23 27 . 11 46 1 .64 56 .58 128
1 . 24 28 . 06 48 1 .65 57 . 12 130
- --
1 . 25 29 . 00 1 . 66 57 .65 132
8222
1 . 26 29 .92 1 . 67 58 . 17 134
1 . 27 30 . 83 1 .68 58 .69 136
1 . 28 31 .72 1 . 69 59 . 20 138
129 32 .60 1 . 70 59 . 71 140
1 . 30 33 . 46 1 .71 60 . 20 142
1 . 31 34 .31 62 60. 70 144
32 35 . 15 61 61. 18 146
1 . 33 35 . 98 66 61.67 148
1 . 34 36 .79 68 62. 14 150
1 . 35 37 .59 0 62.61 152
1 . 36 38 . 38 03. 08 154
1 . 37 39 . 16 63 . 54 156
1 . 38 39 . 93 1 . 79 63 . 99 158
1 . 39 40 .68 1 . 80 64 .44 160
NO
1 . 40 41. 43
HANDBOOK OF CHEMISTRY AND PHYSICS
Degrees
10 . 999841 847 854 860 866 872 878 884 889 895
900 905 909 914 918 923 927 930 934 938
941 944 947 950 953 955 958 960 962 964
965 967 968 969 970 971 972 972 973 973
973 973 973 972 972 972 970 969 968 966
965 963 961 959 957 955 952 950 947 944
941 938 935 931 927 924 920 916 911 907
902 898 893 888 883 877 872 866 861 855
849 843 837 | 830 824 817 810 803 796 789
781 774 766 758 751 742 734 726 717 709
7001 691 682 673 664 654 645 635 625 615
605 595 585 574 564 553 542 531 520 509
498 486 475 463 451 439 427 415 402 390
377 364 352 339 326 312 299 285 272 258
244 230 ) 216 202 188 173 159 | 144 129 | 114
099 084 069 054 038 023 007 * 991 * 975 * 959
0 . 998943 926 910 893 877 860 843 826 809 792
774 757 739 722 704 686 668 650 632 613
595 576 ) 558 5391 520 ) 501 482 463 444 424
405 385 365 345 325 305 285 265 244 | 224
044 018 *992 * 967) * 941 * 914 * 888 *862 * 836 / * 809
10 . 996783 756 729 703 676 649 621 594 567 | 540
512 485 457 429 401 373 345 317 289 261
232 204 175 147 118 089 060 031 002 * 973
29 0 . 995944 914 885 855 826 796 766 736 706 676
30 646 616 586 555 525 494 464 433 402 371
HANDBOOK OF CHEMISTRY AND PHYSICS
TIIIIIIIII+i
RELATIVE DENSITY AND VOLUME OF WATER
The mass of one cubic centimeter of water at 4° C is taken as unity .
The absolute density in C . G . S . units is obtained by multiplying the rel
ative density by 0 . 999973.
( Smithsonian Tables, Compiled from Various Authors.)
Temp. Tc
Ho emp.
o C . Density. Volume. . Density. Volume
- - -
0 . 99815 1 . 00186 + 35 0 . 99406 1 . 00598
843 157 371 633
869 131 336 669
892 108 299 706
912 088 262 743
0 . 99930 1 . 00070 0 . 99224 1 . 00782
945 055 186 821
958 042 147 861
970 031 107 901
979 021 066 943
0 . 99987 1 . 00013 45 10 . 99025 1 . 00985
993 007 46 0 . 98982 1 .01028
997 003 47 940 072
999 001 48 896 116
1 . 00000 1 . 00000 852 162
0 . 99999 1 . 00001 0 . 98807 1 . 01207
997 003 762 254
993 007 715 301
988 012 669 349
981 019 621 398
0 . 99973 | 1 . 00027 | 0 . 98573 1 . 01448
11 963 037 324 705
12 952 048 059 979
13 940 060 70 0 . 97781 1. 02270
14 927 073 489 576
0 . 99913 | 1 . 00087 80 0 . 97183 1 . 02899
897 103 85 | 0 . 96865 1 . 03237
17 880 120 90 534 590
18 862 138 95 192 959
19
843 157 100 0 . 95838 1 . 04343
0 . 99823 1 . 00177 110 0 . 9510 1 . 0515
802 198 120 0 . 9434 1 . 0601
780 221 130 0 . 9352 1 . 0693
756 244 140 0 . 9264 1 . 0794
732 268 150 0 . 9173 1 .0902
0 . 99707 1 . 00294 160 0 . 9075 1 . 1019
681 320 170 0 . 8973 1 . 1145
654 347 180 0 . 8866 1 . 1279
626 375 190 0 .8750 1 . 1429
597 405 200 0 . 8628 1 . 1590
0 . 99567 1 . 00435 210 0 . 850 1 . 177
537 466 220 0 .837 1 . 195
505 497 230 | 0 . 823 1 . 215
473 530 240 0 . 809 1 . 236
34 440 563 250 0 . 794 1 . 259
80
HANDBOOK OF CHEMISTRY AND PHYSICS
DENSITY AND VOLUME OF MERCURY
BASED ON THE DENSITY OF MERCURY AT 0° C . BY THIESEN AND SCHEEL
( 1898 )
(Selected from Smithsonian Tables.)
coo is
Temp.
OC . OC .
per cu .cm . in cu .cms. per cu . cm . 1 in cu .cms.
voer
.°"Temp
Density in grams per cubic centimeter.
C
Substance . Parts of solute in 100 parts of solution by weight
5 10 15 20 25 30 40 50
DENSITY OF ALCOHOL
DENSITY OF ETHYL ALCOHOL IN GRAMS PER CUBIC CENTIMETER ,
COMPUTED FROM MENDELEJEFF' S FORMULA
(Selected from Smithsonian Tables.)
Temp. °C. 0 2
Temp.°C. 9
C2
HANDBOOK OF CHEMISTRY AND PHYSICS
DENSITY OF DRY AIR
AT THE TEMPERATURE I, AND UNDER THE PRESSURE HCM . OF MERCURY,
THE DENSITY OF AIR
0 .001293 H
1 + 0 .00367 1 76
(From Miller's Laboratory Physics, Ginn & Co, publishers, by permission.)
Pressure H in Centimeters.
Proportional
Parts.
72.0 * 73. 0 74 . 0 75 . 0 76 . 0 77 . 0
Too
verwong
17
100 . 001182 0 . 001198 0 . 001215 0 . 001231 0 . 001247 0 . 001264 cm .
11 178 193 210 227 243 259 0 . 1
?
12 173 190 206 222 239 255 0. 2
13 169 186 202 218 234 251
165 181 198 214 230 246 0.4
0
0 .7
15 0 . 0011610 . 001177 0 . 0011930 . 001210 0 . 001226 0 . 001242 0 .8
16 1571 173 189 205 221 238
17 153 169 185 201 217 233 16
18 149 165 181 197 213 229
iang
30
Cm .
145 161 177 193 209
0 . 2
ore
0 . 3
000
0 . 4
200 . 001141 0 . 001157 0 . 0011730 . 001189 0 . 001205 0 . 001221 0 .5
21 137 152 169 18 201 216
22 134 14 . 165 181 197 212
0
cm .
- 25 0 . 001122 0 . 001138 0 . 0011530 . 001169 0 . 001185 0 . 001200 0. 1
como
83
HANDBOOK OF CHEMISTRY AND PIIYSICS
DENSITY OF GASES IN LIQUID AND SOLID FORM
Temperatures marked * are the temperatures of normal ebullition .
Liquid . Solid .
Gas . Observer .
Temp.ID Temp . | D
OC .
2 cm3 OC .
g / cm3.
Acetylene . . . . . . - 23 . 5 0 . 52 Mathias, 1909
1 30 0 . 40
Air (20 . 95% oxygen ). 0 . 92
Ammonia . . - 10 . 7 0 . 65 Andreeff , 1859
+ 16 . 3 0 .61 Andreeff, 1859
Argon . . . . . . . . . - 187 . * 1 . 41 Baly & Donnan ,
1902
Carbon dioxide. . - 60 . I 1 . 19 1 . 53 Behn , 1910
+ 20 . 0 . 77 Amagat
Carbon monoxide. .. 190 . * . 79
68 . . 86 Baly & Donnan
1
Hydrogen . . . . . .
- 253. * 0 . 07 - 260 .076 Den ar, 1904
Hydrogen sulphid - 61 . 10 . 86
Nitrogen . . . – 196 . * 0 . 804 – 253 1 . 03 Dewar , 1904
Nitrous oxide . . . 20 . 1. 0 Cailletet & Mathias
.
feuille, 1881
- 182. 7 * 1 . 14 - 1 . 41 Kamerling -Onnes &
1
Perrier, 1910
- 20 .5 . 1 . 25 . Baly & Donnan
Sulphur dioxide . . . . - 10 . 1 . 16 ; Pierre
+ 20 . 1 . 38 .. Cailletet & Mathias
flint . . . . ! | 3.6 - 3. 8
Gold . . . . . . 15 . 6 16 . 0
Iron :
drawn . . . 20 . 96 . 15 . 4
cast. . . . . 18 . | 9 .6
Lead . . . . . 14. 4 0 . 76
Manganin .
. . . .
12. 1
Nickel . . . . 17 . 0
Platinum . . 24 . 0
Quartz . . . . 3.7
Silvei . . . . . 15 . 10 . 0
Steel, mild. 20 . - 100 . 51. - 21 16 . 0
Tin, . . . . 12 . 5.0
Zinc . . . . . . . . . . . . . . . . . . . | 8.7 | 3. 5
HANDBOOK OF CHEMISTRY AND PHYSICS
COMPRESSIBILITY OF LIQUIDS
CONTRACTION IN UNIT VOLUME PER ATMOSPHERE PRESSURE
(From Smithsonian Tables .)
Temp . Pressures in
Liquid . atm
atmos Coefficient. Observer
phere .
86
HANDBOCK OF CHEMISTRY AND PHYSICS
Oxygen . Air.
Atm .
100 9910
200 5195 7445 9532 5690 7567 9420
300 3786 5301 6715 4030 5286 6520
400 3142 4265 5331 3207 4147 5075
500 2780 3655 4515 2713 3462 4210
600 2543 3258 3973 2387 3006 3627
700 2374 2980 3589 2149 2680 3212
800 2240 2775 3300 1972 2444 2900
900 2149 2616 3085 1832 2244 2657
1000 2068 1720 2093
HANDBOOK OF CHEMISTRY AND PHYSICS
COEFFICIENT OF FRICTION
(From Rankine's Compilation , 1858 ; Smithsonian Tables.)
Coefficient of Angle of repose
Materials. friction . in degrees .
Resistance to Resistance to
Material. crushing in Material. crushing in
lbs. per sq. in . lbs. per sq .in .
Tensile Strength
Metal. in lbs. per sq .in .
Modulus, Modulus,
Material. lbs. per sq .in Material. lbs. per sq.in .
HARDNESS
SCALE OF HARDNESS
1 Talc 4 Fluorite 8 Topaz
2 Rocksalt 5 Apatite 9 Corundum
3 Calcite 6 Feldspar 10 Diamond
7 Quartz
HARDNESS OF MATERIALS
Omaer
The numbers give only the order of arrangement as to hardness.
( From Smithsonian Tables.)
CONVANN
Nerer
Agate . . . . . . . 7 . Hematite . ..
Alabaster . . . . 1.7 || Hornblende . . . . . . .
coort
Iridium .. . . . .
coco
Alum . . . . . .
er
'scr
CT
Aluminum .. . Iridosmium . .
Amber . . . . . Iron . . . . . . .
OOON
Kaolin . . . . . . .
coer
Andalusite . . . . . .
Anthracite . . . Lead . . . . . . .
Antimony . .. Loess (0°) . .
Apatite . . . . . Magnetite . .
erer
Aragonite . . . Marble . . . . . 3 -4 .
Arsenie .. . . . Meerschaum . 2– 3.
cöcerco
Asbestos . . . Mica . . . . . . . . . .
Asphalt . . . Opal. . . . . . . . . . . . .
Augite . . . . . Orthoclase . . . . . . . .
Barite .. . . . . Palladium . . . . . . . .
Beryl . . . . . . Phosphor bronze . . .
er
000
Plat -iridium . .
ACON
er
Bismuth .. .
Boric acid . Pyrite .
Brass . . . . . . . Quartz . . . . . . . . . .
Calimine . . . . Rock -salt . . . . . . . .
Calcite. . . . . Ross' metal. . . 2.5-3.0
Copper. . . . . . .5 - 3 . Silver chlori . 1. 3
Corundum . . . Sulphur . . . .de. . . . . 1.5 -2.5
Diamond . . . . . 10 . Stibnite . . . . . . 2
Dolomite . . . . 3 .5 -4 . Serpentine . . 3–4 .
Feldspar . . . . 6. Silver . . . . 2 .5 - 3 .
ér
isco Orocov
Flint .. . . . . . 7. Steel. . . . . 5 -8 .5
er
Fluorite . . . . . Talc . . . .
Galena . . . . . . 2 .5 Tin , . . •••
Garnet . . . . . . Topaz .. . . .
Glass . . . . . . . 4 . 5 -6 . 5 Tourmaline . .
Gold . . . . . . . 2 .5 - 3 . Wax (0°) . .
Graphite . . . 0 . 5 - 1. Wood ' s metal. .
Gypsum . . . . . 16 - 2 Zinc . . . . . . . . . . . . . .
90
HANDBOOK OF CHEMISTRY AND PHYSICS
Tension ,
Liquid . Temp. ° C . dynes per Observer
cm .
* Heydweiller.
Ethyl Ethyl
Water. alcohol Water. aicohol.
75 . 6 23 . 5 55 67 . 8 18 . 6
74. 9 23 . 1 60 67 . 1 18 . 2
10 71. 2 22 . 6 65 66 . 4 17 . 8
15 73 . 5 22. 2. 70 65 . 7 17 . 3
73
20 72 . 8 21 . 7 65 . 0 16 . 9
25 72 . 1 21. 3 80 64. 3
30 711 20 . 8. 85 63. 6
35 70 . 7 20 . 1 90 62. 9
20 . 0 95 62. 2
10 70 . 0
45 19 . 5 100 61. 5
69 . 3
50 68. 6 19 . 1
92
HANDBOOK OF CHEMISTRY AND PHYSICS
VISCOSITY OF WATER AND OTHER LIQUIDS
( 1) Thorpe-Rogers, 1894 : ( 2 ) Garten meister , 1890 .
Coefficient of viscosity , C . G . S .
Temp .
Carbon
oc .
Water Alc ohol, Chloro - Ether Benzol
ethyl form
Acetic
acid bisul. Amyl
acetate
phide
(1) ( 1) ( 1) ( 2) (1 ) (2) (1) (2)
VISCOSITY OF LIQUIDS
Coefficient of Viscosity in C . G . S . Units
Temp.
Liquid. OC . Viscosity. Observer .
20 .
Acetone. . . . 0033 Thorpe-Rogers
Air , liquid . . . 0 . 0033 Forch
Bromine .. . In
0 . 010 | Thorpe - Rogers
Carbon dioxide (liquid ) 20 . 0 .00071 Warburg- Babo
Glyceri 42 . 2 Schottner
20 . 3 8.3 Schottner
Mercury 0 . 0170 Koch
20 . 0 . 0157 Koch
300 . 0 . 0093 Koch
Olive oil. . . .. 15 . 0 . 9890 Brodmann
Sulphuric acid . . . . . . . . . 20 . 0 . 22 | Graham
VISCOSITY OF GASES
C . G . S . Units.
Temp.
Gas. OC . Viscosity. Observer.
Temp. Coefficient of
Gas or vapor. diffusion ,
C . Observer .
sg .cm . / sec .
Alcohol, vapor. . . . . . . . 40 . 4 0 . 137 Winkelmann
Carbon dioxide . . . 0 .0 0 . 139 Mean of various
Carbon disulphide . . 19 . 9 0 . 102 Winkelmann
Ether, vapor. . . . . 19 . 9 0 . 089 Winkelmann
Hydrogen . . . . 0 . 0 0 .634 Obermayer
Oxygen . . . . . . . 0 . 0 0 . 178 Obermayer
Water, vapor . . . 8 . 0 0 . 239 Guglielmo
Glycerine. . . . . . . . . . 00199 0 36 . 7
Gum arabic .. . . . . . . . 0 . 0099 15 . 5 7.0 | Pfeffer
Gum arabic . . . . . . .:::: 0 . 164 15 . 6 | 119 . 3 | Pfeffer
Phenol (carbolic acid ) . 00127 23 . 3. | Naccari
Gm .-mol. sub
stance in 1
ccm . sol.
Temp. 1 1 2 3
OC .
0 32 . 0 33 . 8 35 . 6 ) 37 . 4 39 . 2 41. 0 42 . 8 44 . 61 46 .4 48 . 2
10 50 . 0 51 . 8 53 . 6 55 . 4 57 . 2 59 . 0 60 . 8 62. 61 64 . 4 66 . 2
68 . 0 69 . 8 71 . 0 73 . 4 75 . 2 77 . 0 78 . 8 80 . 61 82 . 4 81 . 2
30 86 . 0 87 . 8 89 . 6 91 . 4 93 . 2 95 . 0 96 . 8 98 . 6 100 . 4 102. 2
40 104. 0 | 105 . 8 | 107 . 6 | 109 . 4 1111. 2 113. 0 114 . 8 / 116 . 6 118 . 4 120 . 2
50 122 . 0 123 . 8 | 125 . 6 | 127 . 4 129 . 2 131 . 0 132 . 8 / 134 .6136 . 4 138 . 2
60 140 . 0 141. 8 143 . 6 | 145 . 4 147 . 2 149 . 0 150 . 81152.6154 . 4 156 . 2
70 158 . 0 159 . 8 161 . 6 | 163 . 1 165 . 2 167 . 0 / 168 . 8170 .6172 . 4 174 . 2
80 | 176 . 0 177 .8179 6. 181. 4 183 . 2 185 .0186 .8188 .6190 . 4 192 . 2
90 1940 195 . 8 197 . 6 | 199 . 4 2012 203 . 0 / 201. 8 / 206 .6208 . 4 210 . 2
100 212 .01
Reading.. . 0° | 10 20 30 40 50
Correction 0°.000 - 0 .055 - 0 .090 - 0 . 109 – 0 . 115 - 0 . 109
Reading. .. | 50 60 70 80 90 100
Correction - 0°. 109 - 0 .096 - 0 .076 - 0 .053 - 0 .027 0. 000
95
HANDBOOK OF CHEMISTRY AND PHYSICS
COEFFICIENTS OF THERMAL EXPANSION
LINEAR EXPANSION
(Compiled from Smithsonian Tables.)
The Table gives the increase in length per unit length per degree Centi
grade .
Temp .
limits. Observer.
Substance.
° C .
99
CUBICAL
OF
EXPANSION
LIQUIDS
cubical
mean
The
expansion
1quantities
of
coefficient
gives
0-table
range
the
C.for
of
values
a,Bathe
nd
y 00°
the
Ve
equation
(1ain
=Vt0).+ßtyts
.)Tables
FSmithsonia
( rom n
Mean
Liquid Te
. mp
Ran coef
. .
Observer
.°C ge l0
C.-100°
acid
.Acetic 1071
16
01
-61.0
8Z 01433
630X10
264x10
876X10
ander
Acetone
. 5-0 4 210
1.3161 6 3.8090 798
0.8Zander
Alcohol
:
amyl
. +8-105
to 0.8900 0.6573 Pierre
1.1846
8ethyl
.g,srp095 0-80 1.0414 0.7836 1.7168 Kopp
5et
vo ,0-30y9hy
.i%b lulme 0.7450 1.850 0.730 Recknagel
,3eth
%b
.vol
0y yl
ume -39
18 0.2928 917
. 00 .87
11 Recknagel
...methyl to
+7-31433
1.180856 1.5649 0.9111 Pierre
Be
. nzene 1.1111
1385
-8763 1.2775 0.8065 Kopp
Br
. omine 11
t.-7+610o038
682 114
447
0.517Pierre
Calcium
chloride
:
,58%solution
.CaCl2 -2180.05788
0506 4.2742 Decker
9%s,4olution
.CaCl2
0 -20510
17 0.44238 0.8571 Decker
Carbon
disulphide
.to
-31468
+6
114398
0 1.3706 1.9122
Pierre
Chloroform
.: 0-6071
1399
1.1 3 4.6647 Pierre
1.7433
Ether
.. to
+3–12150
1.558132 2 592
.3 4.0051
Pierre
Glycerine
. 0.4853
0534 0.4895 Emo
HANDBOOK OF CHEMISTRY AND PHYSICS
:Hydrochloric
acid
2HCl
,0.+6 5H 0489
0.40-30460 4.0 30 Marignac
HCI
+5,0. 01 -300933
.00625 8.710 Marignac
(Continued
LIQUIDS
OF
EXPANSION
)CUBICAL
Mean
.
Liquid Tem .
Observer
de .lo000 .1coef
°C
-1Range C.0-100°
Me
. rcury 1
10.-3
6)240078X10
0
208182X10
99 Scheel
oilive
;.:Ol
0.6000
8274
1 2 X10
.5 39
405
-8S11pring
ch
: lo
Po tari ssde ium
ILANDBOOK
sKCI
5%,2. olution 0572 Decker
,24olution
.3%sKCI 0477 Decker
. . . . . . . . . . . . . .
:
nitrate
Potassium
,53%solution
.KNO3 0539 Nicol
. . . . .
,2olution
.9%sKNO3
1 05771 Nicol
Phenol
C., 6H60 -157
36 0.8340
0899 0.1073 4.0 446 Pinette
.0,srp467
8gPetroleum -120
24 0.8994
1039 |1.396 Frankenheim
NaCl
chloride
,1.6%Sodium
solu
. tion 0.0213
1067 .462
10 Marignac
. aso
,N
sul
Sod pha
iumate
s24
.% olution -40
10 0.3599
0611 2.516 .Marignac
OF CHEMISTRY AND
N
, aNO3
nitrate
Sodium
s36
.%2 olution 7-208 0.5408
0627 1.075 Nicol
. . . . . . . . .
acid
:Sulphuric
H2S
. O4 0-30 0489
0.5 758 0.864 Marignac
+50H20
.H2SO4 0-30 0.2835
0799 .15 60
. . . . . . . .
Marignac
PHYSICS
Turpentine
. +1-9to06 /0.9003
1051 1.959 Kopp
.
Water 0-33 0
-. 643 8.505 6.790 Scheel
HANDBOOK OF CHEMISTRY AND PHYSICS
Pressure
Gas. Temp. Coeffi
OC . in cm . of cient.
Observer.
mercury .
102
HANDBOOK OF CHEMISTRY AND PHYSICS
00 1 . 0000 1 . 0037 1 . 0073 1. 0110 1 . 0147 1 . 0183 1 . 0220 1 . 0257 1 . 0294 1 . 0330
10 1 . 0367 ! 1 . 0404 1 . 04401 1 . 0477 1. 0514 1. 0550 1. 0587 1. 0624 1. 0661 1. 0697
20 1. 0734 1. 0771 1. 0807 ) 1. 0844 1 . 0881 1 . 0917 1 . 0954 1 . 0991 1 . 1028 1 . 1064
30 ! 1 . 1101 1 . 1138 ) 1 . 11741 1 . 1211 1 . 1248 1 1284 1 . 1321 1 . 1358 ) 1 . 1395 1 . 1431
40 1 . 14681 1 . 1505 1 . 1541 1 . 1578 1 . 1615 1 . 1651 1 . 1688 1 . 1725 1 . 1762 1 . 1798
| 1 . 1835 1 . 1872 1 . 1908 1 . 1945 ] 1 . 1982 1 . 2018 1 . 2055 1 . 2092 1 . 2129) 1 . 2165
| 1 . 2202 1 . 2239 1 . 2275 1 . 23121 1 . 2349 1 . 2385 1 . 2422 1 . 2459 1 . 2496 1 . 2532
1 . 2569 1 . 2606 1 . 2642 1 . 2679 ) 1 . 2716 1 . 2752 1 . 2789 1 . 2826 1 . 2863 1 . 2899
1. 2936 1 . 2973 1 . 3009 1 . 3046 1 . 3083 1 . 3119 1 . 3156 1 . 3193 1 . 3230 1 . 3266
90 1 . 3303 1 . 33401 1 . 3376 1 3413 1 . 3450 1 . 3486 1 . 3523 1 . 3560 1 . 3597 1 . 3633
100 1 . 3670 1 . 3707 1 . 3743 1 . 3780 1 . 3817 ! 1 . 3353 1 . 3890 1 . 3927 1 . 3964 1 . 4000
110 1 .4037 1 .4074 1 . 4110 1 . 4147 1 . 4184 1 . 4220 1 .4257 1 . 4294 1 . 4331 1 . 4367
120 1 .4404
VALUES OF H /760 FOR PRESSURES FROM 700 to 780 MM . OF MERCURY.
H 0 3 7 8 9
700 0 . 9211 0 . 9224 0 . 9237 0 . 9250 0 . 9263 0 . 9276 0 . 9289 0 . 9303 0 . 9316 ! 0 . 9329
710 0 . 9342 0 . 9355 0 . 9368 ' 0 . 9382 0 . 9395 0 . 9408 0 . 9121 0 . 9434 0 . 9447 0 . 9461
720 0 . 9474 0 . 9487 0 . 9500 0 . 9513 0 . 9526 0 . 9539 0 . 95531 0 . 9566 0 . 9579 0 . 9592
730 0 . 9605 0 . 9618 0 . 9632 0 . 9645 0 . 9658 0 . 9671 0 . 9684 0 . 96971 0 . 9711 0 9724
740 0 . 9737 0 . 9750 0 . 9763 0 . 9776 0 . 9789 0 . 9803 0 . 9816 0 . 9829 0 . 9842 0 . 9855
750 0 . 9868 ' 0 . 9882 0 . 9895 0 . 99031 0 . 9921 0 . 9934 0 . 9947 0 . 9961 0 . 9974 0 . 9987
760 1 . 0000 1 . 0013 1 .0026 , 1 . 0039 1 .053 1 . 0066 1 .0079 1. 0092 1 .0105 1 . 0118
770 1 . 0132 1 .0145 1 . 0158 1 .0171 1 . 0184 ! 1 . 0197 1 . 0211 1 . 0224 1 . 0237 1 . 0250
780 1. 0263
Toemp.
Temp. Water. Mercury. c Water. Mercury .
Bli | B | Bt 1 B
cm cm cm cm cm cm
72 . 0 98 . 49 73 . 0 98 . 8874 .099 . 26 75 .099 .6376 . 0 100 .0077 . 0 100 . 37
53 . 29 . 67 . 04 . 40
HAWN
Voer
1 . 92
000
. 33 . 70 . 07 .44
Consor
95
74 4S
. 398 . 99 | . 371
.499 . 03 | .4 . 11 | 51
. 65 !
98. 69| 73.599 . 07||74 .599. 44||75 . 5 99 .8276 . 5 100 77 . 5 100 . 55
. 10
.7 . 14 · 62
. 80 .8 . 181
. 84
106
HANDBOOK OF CHEMISTRY AND PHYSICS
107
HANDBOOK OF CHEMISTRY AND PIIYSICS .'
Acid , hydrochloric . . . . . . . . 93 . 85
nitric . . . . . . . . . . . 95 . 82
sulphuric .. . . .. .. . . . . . . . 95 . 84
Alcohol, ethyl. . . . . 1 .02 1 . 05
Ammonia .. . . . . . . . . . . . . . . . 998
Carbonate sodium 1 . . . . . . . . . 93
Chloride calcium . . . . 94
sodium . . . . . . . . . . 94 .81
Hydrate potassium . . . 93
sodium . . . . . . . . . . . . 94 . 86
Sugar . . . . . . . . . . . . . . . . 97 . 89
108
HANDBOOK OF CHEMISTRY AND PHYSICS
manano
za
Benzol . . . . . . . . . . . . 34 - 115 0 . 2990 W 1 . 403
Bromine . . . . . . . . . . . 83– 228 0 . 0555 20 - 388 1 . 293
Carbon dioxide. . . . . 15 - 100 0 . 2025 R
Carbon monoxide. . . 23 - 99 0 . 2425 W 10 1 .403
Carbon disluphide . . 86 – 190 0 . 1596 R | 3 .67 1 . 205
Chlorine. . . . . . . . . . 13 - 202 0 . 1241 R 20 - 340 1 . 323
Chloroform . . . . . . . . 27 - 118 0 . 1441 22 – 78 1 . 102 B
Ether . 25 - 111 0 .4280 W 12 - 20 1 .024
Hydrochloric acid . . 13 - 100 0 . 1940 120 1 . 389
Hydrogen . . . . . . . 12 - 198 3 . 4090 R
Hydrogen sulphide. . 20 - 206 0 . 24511 R 10 - 40 1 . 276
Methane . . . . . . . . . . 18 – 2080. 5929 R 11 - 30 1 . 316 | Mr
Nitrogen . . . . . . . . . . 0 - 200 0 . 2438 R | . . . . 1 .41 C
Nitric oxide.. . . . . 13 - 1720 . 23171
AFEE
109
HANDBOOK OF CHEMISTRY AND PHYSICS
MELTING AND BOILING TEMPERATURES
Temperature of Fusion for Various Substances for Atmospheric
Pressure
For the melting- and boiling-points of the chemical elements and of
inorganic compounds, see under Physical Constants of the Elements ,
page 15 , and Physical Constants of Inorganic Compounds, page 21.
Acetone . . . . . . . . 57 . 0 . 39
Acetylene . . – 72 . 2
Alcohol, ethyl.. . . .. . .. .. .. .. 78 . 3 0 . 34
methyl. . 64 . 7 0 . 35
Amyl acetate . 148 .
Benzene.. .. . . . . . . . . . . . 80 . 0 .43
Camphor . . . 205 . 0 . 56
Chloroform .. . . . . . . . . . . . . . . . . 61 . 2 0 .41
Ether . . . . . . . . . . . . . . 34 . 6 0 . 40 ,
Gasoline. . . . . . . . . . . . . . . . . . . 70 - 90 .
Glycerine . . . . . . . . . . . 291 .
Turpentine . .. .. .. . . . . . . . . . . . . . 159 .
0 .0 1410 - 12 . 5
336 - 2.5 1625 - 15 . 0
615 - 5 .0 1835 -- 17 .5
890 2042 -- 20 . 0
1155 - 10 . 0 2200 - 22 . 1
110
GASES
OF
CONSTANTS
OTHER
AND
PRESSURE
AND
TEMPERATURE
CRITICAL
.)1gder
Constants
Waals
,Vcm an
(fCritical
Data
aPoint
nd
B6or
roiling
7Freezing
HT
.LAT .
DENS .
CRIT
HT
.LAT .OF
AP PRIT
C RES
.CRIT ать
.
Gas .
PT
FREEZING PT
.BOIL .
BOIL
AT
.
FUS
OF .
BOIL
AT TEMP )DTM
.(A ENS
.PT .
°C
.
PT
Hy
. drogen .–2016
.060 .5-252 070
.0200 .14-825340 5160 9.28
.Oxygen 0(92- 27m
).m .5-181 35
.0152 0-1.50 .018 .90|168320
5
Nitrogen
. .)9mm 4
0(-210 .0-194 790
.048 .0-1345
4 0
1.4/|1037700
.
Air 0-1. 91 .0-137 .8 42
Argon
. 10.- 88 .0–186 1.212 .0-1517
2 810 0.77
.Helium .8–268 02-2.3 68 0.15
dioxi
. hur
Sulp de .0-10 460
.0182 155
.078 .9 0.55 1610 0.87
EC. hlorine 0.-102 6-3. 3 .067 146
.0593
5
.0-7|108 .5-38 0 13800 2.11
.
Ammonia .0
295 131
.0113
.
Nitrogen
peroxide .0
93 .2
171
.
dioxide
Carbon .2-78 77
.031
.0 9971
0.21857
Ethylene
. 0-1. 03 38
.010 0.22
.
overcrosOc0Oorer
Acetylene 6.36
561 1.85930
0301
Water
. .080 537
.0100 .0364
01
195 0.418000
1834
.Acetic
acid 0.17 .7
43 85
.0118 0.321
57 |1.74884
03851
.
alcohol
Ethyl 3201
.578 240
.064 1828 34
0.25700
.
Benzol 2.345 0 293
.080 .0
288
Acet
. one .4125
356 52
.0238
.0
HANDBOOK OF CHEMISTRY AND PHYSICS
.bisul
Carbonphide 03
.846 78
.0277
.0 0.354
Ethe
. r 90
.038 37
.0190
.0 |1846 2
0.23180
Chlor
. oform 1|59
.060 55
.0260
.0
FOON Cooo
HANDBOOK OF CHEMISTRY AND PHYSICS
IIIIIIIIIIIIIIIIIIIIIIII
FREEZING MIXTURES
A is the proportion of the substance named in the first column to be
added to the proportion of the substance given in column B . The table
gives the temperature of the separate ingredients and the temperature
attained by the mixture.
(From Smithsonian Tables.)
Snow 1 . 31 - 17 . 5
* Or finely pulverized ice .
112
ILANDBOOK OF CHEMISTRY AND PHYSICS
113
HANDBOOK OF CHEMISTRY AND PHYSICS
HEAT EQUIVALENT OF VAPORIZATION
The table gives the heat equivalent (or latent heat) of vaporization in
calories per gram , at the temperature of ebullition , and at the pressure
of the vapor for that temperature .
(Principally from the Smithsonian Tables.)
Alcohol, ethyl. . . 78 . 26 0 . 34
Aniline . . . . . . . . . . . . . . 184 . 0 .51
Benzene . . . . . . . . . . . . 80 . 0 . 43
Chloro benzene. . . 132 . 0 .50
Diphenylamine. . .. . . . . . . . . . . 302 .
Mercury . . . .. .. .. .. . . . . . . . . . . . . . . 356 .
Naphthaline .. .. .. . . . . . . .. . . . . . 218 . 0 . 59
Sulphur . . . . . 445. 2
Toluidine , o . . . 199. 7 0 . 58
Toulene . . . . . . . 109 . 2 0 . 45
Water . . . . . . . . . . 100 . 0 . 37
Xylene , m . . . . . . 138 . 8 0 . 50
. . . . . . . . . . . . . . . . . . . . . . . . 930 .
115
IIIIIIIIIIIIIIII
HANDBOOK OF CHEMISTRY AND PHYSICS
0 .0 / 1. 2 0 0 .6 0.8
Тетр.
0 . 3805
0 . 4185 0 . 4106 0 . 4028 0 . 3952 0 . 3878
0 . 4598 0 . 4512 0 . 4428 0 . 4316 0 .4265
0 . 5047 0 . 4954 0 .4862 0 . 4772 0 . 4684
0 . 55.35 0 . 5433 0 .5333 0 . 5236 0 . 5141
0 . 6064 0 .5955 0 .5817 0 . 5741 0 . 5637
116
HANDBOOK OF CHEMISTRY AND PHYSICS
Temp.
oc 0. i 1. i - 2 .
111
0 .1 .2 L 3 ' .4
voooo
eros
Тетр. .6 1 .8 .. 9
Temp.
OC . 0. 0 0.2 0 .4 0.6 0.8
voor
A UNO
21 18 .694 19 . 157
18 . 466 18 . 924 19 . 392
19 .630 19 . 870 20 . 113 20 . 359 20 .607
20 . 858 21. 111 21. 367 21 .626 21 . 888
22 . 152 22 .420 22 .690 22 . 963 23 . 239
23 .517 23 .799 24 .084 24 . 371 24 . 662
24 . 956 25 . 252 25 . 552 25 . 855 26 . 161
26 . 471 26 .783 27 .099 27 .418 27 . 740
28 . 065 28 . 394 28 .727 29 . 062 29 . 401
29 . 744 30 .090 30 . 440 30 . 793 31. 149
31 .510 31 . 873 32 . 341 32 .612 32 . 988
31 33 . 366 33 . 749 34 . 136 34 .526 34 . 920
32 35 . 318 35 .720 36 . 126 36 .536 36 . 951
33 37 . 369 37 . 791 38 . 218 38 . 649 39 . 084
39.523 39. 966 40 . 414 40 . 866 | 41 . 323
118
HANDBOOK OF CHEMISTRY AND PHYSICS
Temp .
o C .
0. 0 0. 2 0 .4 0 .6 0. 8
Temp.
OC 0 . 0 0.2 0 .4 0 .6 0 .8
120
HANDBOOK OF CHEMISTRY AND PHYSICS
VAPOR TENSION OF WATER
TENSION OF AQUEOUS VAPOR, 100 -230° C .
Giving the vapor tension in millimeters of mercury , in pounds per square
inch and the corresponding temperature Fahrenheit .
(From Regnault - Smithsonian Tables.)
Pressure . Pressure .
Temp . Temp. Temp. Temp .
Pounds C . Pounds OF
inm . per mm . per
sq .in . sq .in .
z
ܝܟܬܛ݁ܪ
ܘܣ
ܘܗܣ
ܘܣ
ܘܗܶܗܟܪܟܬ
102 816 . 01 15 . 79 215 . 6 147 3301 . 87 63. 86 296 . 6
16 . 35 217 . 4 298 . 4
ܤܛܪ
103 845 . 28 148 3392. 98 ! 65 .62
104 875 .41 16 . 94 219 . 2 3486 .09 67 .41 300 . 2
ܛ
105 906 . 41 17 . 53 221 . 0 150 3581. 2 69 . 26 302 . 0
106 938 . 31 18 . 15 222 . 8 151 3678 . 4 71 . 14 303 . 8
107 971. 14 18 . 78 224 . 6 152 3777 . 7 73 . 06 305 . 6
108 1004 . 91 19 . 44 226 . 4 153 3879 . 2 75 . 02 307 . 4
109 1039 . 65 20 : 11 228 . 2 154 3982 . 8 77 . 03 309 . 2
Pressure. Pressure .
0 . 0004 200 18 . 3
20 0 . 0013 220 , 33 . 7
0 . 006 240 59 .
0 . 03 260 98 -
0 . 09 280 156 .
100 0 . 28 300 246 .
120 0.8 320 371 .
140 1 . 85 340 548 .
160 4.4 360 790 .
180 9 .2
122
HANDBOOK OF CHEMISTRY AND PHYSICS
VAPOR PRESSURES OF
In centimeters
tctrachloride
(Principally from
phide
Carbon
.Chloroform
bisulon
,C4H100
Carb
,CHC13
dioxide
.Ammonia
Carbon
.Ethyl
Ether
Alcohol
,
Ethyl
.Acetone
,
,NH3
,C3H60
Acetic
,
.C°Temp
acid
C2H60
.
CO2
CC14
. 2
CS
.
.
86 .61
1300 . 70 110 . 43
4 . 73 1514 . 24 . 98 6 . 89 139 . 21
6 . 16 1758 . 25 1 . 35 8 . 93 173 . 65
01
.
856co
7 . 94 2034 . 02 1 . 85 . 65 11 . 47 214 . 16
10 . 13 2344 , 13 2 . 48 .911 14 .61 264 . 42
12 . 79 2690 . 66 3 . 29 1 . 27 18 . 44 0 . 35 318 . 33
16 . 00 3075 . 38 4 . 32 1. 76 23 . 09 383 . 03
19 . 85 3499 . 86 5 .60 2 . 42 28 . 68 457 . 40
24 . 41 3964 . 69 7 . 17 3 . 30 35 . 36 543 . 34
29 . 80 4471 . 66 9 . 10 4 . 451 43 . 28 17. 96 638 . 78
36 . 11 5020 . 73 11 . 43 20 . 02 5 . 94 52 . 59 22 .63 747 . 70
43 . 46 5611 . 90 14 . 23 24. 75 7 . 85 63 . 43 28 . 10 870 . 10
51 . 97 6244 . 73 17 . 55 30 . 35 10 . 29 76 . 12 34 .52 1007 . 02
61. 75 6918 .44 21 .48 36 . 93 13 . 37 90 . 70 42 . 01 1159 . 53
45 | 72 . 95 7631.43 26 . 08 44 .60 17 . 22 107 . 42 50 . 75 1328 . 73
85 . 71 31. 44 53 .50 21 . 99 126 .48 5 .63 62 . 29 1515 . 83
100 . 16 37 . 63 63 . 77 27 . 86 148 . 11 72 . 59 1721 . 98
60 116 . 45 44 . 74 75 . 54 35 . 02 172. 50 8 . 83 86 . 05 1948 . 21
65 134 . 75 52 . 87 88 . 97 43 . 69 199 . 89 101
TUI .43
. 2196 . 51
155 . 21 62, 11 104 . 21 54 . 11 230 .49 13 .70 118 . 94 2467 . 55
177 . 99 72 . 57 121 . 42 66 . 55 264 . 54 .. . . 138 . 76 2763 . 00
: iis
VARIOUS SUBSTANCES
of mercury .
Regnault.)
Methyl
ogen
alcohol
.Turpentine
.Sulphur
ide
,CHO
dioxide
b4CO
Naphthalene
N,. 20 ous
sulph
Hydr
,SO2
v
,+61
SO
,Col16
oxide
4
Nitr
,
caso
Pictet
.Benzol
. phor
todo
'sfluid
,C6H5
weight
Temp
.
Cam
.°C
SH
58. 52 28 . 75
l:
11569. 49 67 . 64 37 . 38 374 . 93
1758 . 66 74 . 48 47 . 95 443 . 85
. 88 . 93 1968 . 43 89 . 68 60 . 79 519 . 65
1 . 29 1 . 35 2200 . 80 101 . 84 76 . 25 608 . 46
1 . 83 1 . 92 2457 . 92 121 . 60 94 . 69 706 .60
2 .530. 006 2 .68 0 . 00212742. 10 139 .08 116 .51 820 . 03
3 . 42 .. 3 . 69 3055 . 86 167 . 20 142, 11 949 . 08
4 . 52 0 . 010 5 .01 0 . 005 3401 . 91 193 . 80 . 171. 95 1089 .63
5 . 89 6 .711 0 . 0053783 . 17 226 . 48 206 . 49 1244 . 79
7 .56 0 . 015 8 . 87 0 . 008 4202 . 79 258 . 40 246 . 2014 15 . 15
9 . 59 :: : 11 .60 . . . . 4664 . 14 297 . 92 291. 60 1601. 241
12 . 02 0 . 026: 15 . 00 0 . 013 5170 . 85 338 . 20 343 . 18 1803 . 53 .69
er
Substance , Temp.
OC.
Conduc Observer.
tivity
ooooo
Aluminum . . . . . 18 0 . 48 Jaeger & · Disselhorst,
1900
Antimony
wy .. . . . . . . . .0442 | Lorenz
Bismuth . . . . . . .0177 | Lorenz
Brass , yellow . . . 2041 | Lorenz
red . . . . . . . . . 2460 Lorenz
Cadmium . . . . . 2200 Lorenz
Constantin . . . 18 . 5402 Jaeger & Disselhorst
Copper, pure . . . . . 1 . 00 Angström , 1863
Copper . . . 7189 Lorenz
German silver.. . . . . . . . . 0700 Lorenz
Gold . . . . . 10 – 97 . 75 Gray, 1895
.. . . . . . . .
Iron . . . . . . . . . 1665 | Lorenz
wrought. . . . . 2070 J. Forbes
Lead . . . . . .0836 | Lorenz
Mercury . . . . . . . 0148 H . F . Weber
Magnesium . . . . 0 - 100 . 3760 Lorenz
Manganin
84Cu + 4Ni + 12Mn 18 . 5186 | Jaeger & Disselhorst
Nickel. . . . . . 18 . 1420 | Jaeger & Disselhorst
Platinum . . . . . . 18 . 1664 | Jaeger & Disselhorst
Silver . . . 1 . 0960 H . F . Weber
Steel, hard . . 0620 Kohlrausch
soft .. . . . . 1110 Kohlrausch
Tin. . . . . . . . . 1528 Lorenz
Zinc . . . . . . . . . . 2653 Jaeger & Disselhorst
VARIOUS SOLIDS
Approximate Values.
Conduc
Substance. Observer.
tivity .
Conduc
Liquid or gas. . Temp. tivity . Observer .
Fuel. Calories B . T. U .
per gm . per lb ,
Coal:
Lignite
low grade. . .. .. .. . . . . . . . . . . . . . . . . . . . . . . . 3526 3647
high grade . . .. . .. . . . . . . . . . . . . . . . . . . . . . , 3994 7189
Sub -bituminous
low grade. . . . . 5115 9207
high grade . . . . . . . . . . . . . . . . . . . . . . 5865 10557
Bituminous
low grade. . . . . 6088 10958
high grade. . . . .. . . . . . . . . . . . . . . . . . . . . . . 7852 14134
Semi-bituminous
Low grade. . .. .. .. . . . . . . . . . . . . . . . . 7845 14121
high grade . . . . . . 8166 14699
Semi-anthracite . . 7612 13702
Anthracite
low grade. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6987 12577
high grade. . . . . . . . . . . . . . . . . . . 7417 13351
Peats (air dried ) :
From Franklin Co ., N . Y . . ........... . 5726 10307
From Sawyer Co ., Wis . . . . . . . . . . . . . . . . . . . 4867 8761
Liquid fuel:
Petroleum ether. . . . . . . . . 12215 21987
Gasoline . .. .. .. .. . . . . . . . . . . . . . . . . . . . . . . . . 11250 20250
Kerosene . . . . . . . . . . . . . . . . . 11100 19980
Fuel oils , heavy petroelum or refinery residue ] 10350 18630
Alcohol, fuel or denatured with 7 - 9 per cent
water and denaturing material . . . . . . . . . . 6455 | 11619
128
HYGROMETRIC AND BAROMETRIC
TABLES
CONVERSION TABLE FOR BAROMETRIC READINGS
U . S . inches to cm .
04 19
Inches. .00
Inches. .01 .02 .03 .04 .05 .06 .07 .08 .09
27 . 0 68 . 580 . 606 .631 . 656 . 682 . 707 . 733 .758 1783 . 809
27 . 1 . 834 . 860 . 885 . 910 . 936 . 961 . 987 * .012 * . 037 * .063
27 . 2 69 . 088 114 , 139 . 164 . 190 . 215 . 241 . 266 . 291 . 317
27 . 3 . 342 . 368 . 393 .418 .444 . 469 .495 . 5201 . 545 . 571
27 . 4 :596 . 622 647 . 672 . 698 . 723 .749 .774 .799 . 825
27 . 5 . 850 . 875 . 901 . 926 . 952 . 977 * . 002 * . 028 * . 053 * . 079
27 . 6 70 . 104 . 130 . 155 . 180 . 206 . 231 . 257 . 282 . 307 . 333
27 . 7 . 358 . 384 . 409 . 434 .460 .485 .511 .536 . 561| . 587
27 . 8 .612 .638 . 663 .688 . 714 . 739 . 765 . 790 . 815 . 841
27 . 9 . 866 . 892 . 917 . 942 . 968 . 993 * .018 * .014 * . 969 * . 095
28 . 0 71 . 120 . 146 . 171 . 196 . 222 . 247 . 273 298 . 323 . 349
28 . 1 . 374 . 400 . 425 . 450 . 476 .. 501 . 5271 . 552 . 577 . 603
28 . 2 .628 . 654 . 679 79
.. 755 / .781 . 831 . 857
. 704 . 730 . 806
28 . 3 . 882 . 908 . 933 . 958 . 984 * . 009 * . 035 * . 060 * . 085 * . 111
28 . 4 72 . 136 . 162 . 187 . 212 . 238 263 . 289 . 314 . 339 . 365
28 . 5 . 390 . 416 . 441 . 466 . 492 .517 . 543 . 568 . 593 .619
28 . 6 .644 . 670 . 695 . 720 . 746 . 771 . 797 ). . 822 .847 . 873
28 . 7 . 898 . 924 . 949 . 974 * . 000 * . 025 * . 051 * . 076 * . 101 * . 127
28 . 8 73 . 152 . 178 . 203 . 228 . 254 . 279 . 305 . 330 . 355 . 381
28 . 9 . 406 . 432 . 457 .482 . 508 . 533 . 559 . 584 .609 .635
29 . 0 . 660 . 686 .. 711 . 736 . 762 . 787 . 813 .838 . 863 .889
29 . 1 . 914 . 940 . 965 . 990 * . 016 * . 041 * . 067 * .092 * . 117 * . 143
29 . 2 74 . 168 . 194 . 219 244 . 270 . 295 . 321 . 346 . 371 . 397
29 . 3 .422 . 448 . 473 .498 .524 .549 . 575 .600 .625 . 651
29 . 4 .676 . 702 . 727 . 752 . 778 . 803 . 829 . 854 . 879 . 905
29 . 5 . 9301 . 956 . 981 * . 006 * . 032 * . 057 * . 083 * . 108 * . 133 * . 159
29 . 6 75 . 184 . 210 . 235 . 260 . 286 . 311 . 337 . 362 . 387 413
29 . 7 . 438 . 464 . 489 .514 . 540 . 565 . 591 .616 . 341 .667 .
29 . 8 . 692 . 718 | . 768 . 794 . 819 . 845 . 870 . 895 . 921
29 . 9 . 946 . 972 . 997 * . 022 * . 048 * . 073 * . 099 * 124 * . 149 * . 175
30 . 0 76 . 200 . 226 . 251 . 277 . 302 . 327 . 353 . 378 .404 .429
30 . 1 . 454 . 480 . 505 .531 . 556 .581 . 607 .632 .658 . 683
30 . 2 . 708 . 734 1 . 759 1 . 785 . 810 . 835 . 861 . 886 . 912 . 937
30 . 3 . 962 . 988 * . 013 * . 039 * . 064 * . 089 * . 115 * . 140 * . 166 * . 191
30 . 4 77 . 216 . 242 . 267 | .293 . 318 . 343 . 369 . 394 .4201 .445
30 . 5 .470 . 496 . 521 | . 547 . 572 . 597 .623 . 648 .674 .699
30 . 6 .724 . 750 1 . 775 . 801 . 826 . 851 . 877 902 928 953
30 . 7 . 978 * . 004 * .029 * . 055 * . 080 * . 105 * . 131 * . 156 * . 182 * 207
30 . 8 78 . 232 . 258 . 283 . 309 . 334 1 . 359 . 385 .410 . 436 461
30 . 9 . 486 512 . 537 . 563 . 588 .613.613 .639 .664 1 . 690 .715
129
HANDBOOK OF CHEMISTRY AND PHYSICS
70 71 72 73 74 | 75 76 77 78
cm . cm . cm . cm . cm . cm . cm . cm . cm .
4 .835 5 . 176 5 .538 5 . 922 6 . 330 6 . 761 7 . 219 7 . 703 8 . 215 8 . 757
10 | 9 . 330 | 9 . 935 10 .574 11 . 249 11. 961 12 . 712 13 . 505 14 . 339 13. 218 16 . 144
20 17 . 118 18 . 143 19 . 222 20 . 355 21.546 22 . 796 24 . 109 25 . 487 26 .933 28 .450
30 30 . 039 31. 704 33. 449 35 . 275 37 . 187 39. 187 41. 279 43 .465 45 .751 48 . 138
131
HANDBOOK OF CHEMISTRY AND PHYSICS
REDUCTION OF BAROMETER READINGS TO STANDARD
TEMPERATURE
BRASS SCALE , BRITISH UNITS .
The table gives the corrections for the barometer reading in inches
and the temperature in degrees Fahrenheit for a brass scale graduated
to be correct at 62° F . The correction is to be subtracted .
cm . cm . cm . cm . cm . cm . cm . cm . cm .
0 .4 0 . 083 0 . 1221 0 . 154 0 . 198 0 . 237
0. 5 . 047 . 065 . 086 . 119 . 145 0 . 180
0.6 . 027 . 041 . 056 . 078 . 098 . 121 0 . 143
0 . 7 . 018 . 028 . 040 . 053 . 067 . 082 . 097 . 113
0 . 8 . 020 . 029 . 038 . 046 . 056 . 065 0 . 077
0 . 015 0 . 021 0 . 028 0 . 033 0 . 040 0 . 046 0 . 052
.015 .020 .025 . 029 . 033 . 037
1. 1 . 010 . 014 . 018 . 021 . 024 . 027
1. 2 . 007 .010 . 013 . 015 . 018 .019
1.3 . 004 . 007 .010 . 013 . 014
132
HANDBOOK OF CHEMISTRY AND PHYSICS
REDUCTION OF BAROMETER TO SEA LEVEL
METRIC UNITS
Correction to be added (in cm .)
(From Smithsonian Tables.)
ENGLISH UNITS
. 116
.096 . 099 . 102 . 104 . 107 . 110
30 0 .091 0 . 094 0 . 096 0 . 098 0 . 101 0 . 104
.085 .087 . 090 . 092 . 095 . 097
32 . 079 . 082 . 081 . 086 . 089 .091
. 074 . 076 .078 . 080 . 082 . 084
. 068 . 070 . 072 .074 . 076 . 078
35 0 . 062 0 . 064 0 . 066 0 . 067 0 . 069 0 . 071
. 056 1 . 058 . 0 .59 . 061 . . 063 .064
53 . 050 ..051 . 053 . 054 . 056 . 057
.014 . 015 .016 . 018 .019 .030
. 038 .039 . 010 . 041 . 042 . 043
40 50 0 . 031 0 . 032 0 . 033 0 . 031 0 . 035 0 . 036
41 19 .025 ..026 .027 .027 .028 . 029
NO
English SCALE
Corrections in inches.
97
4680246802468 0246802468024680246802468
97 97
95 96 96
4 94
04
AS
4
77
76
66
67 的
66 68
65 67
63
64
60
64
60
63
61
58 60 63
135
HANDBOOK OF CHEMISTRY AND PHYSICS
RELATIVE HUMIDITY - DEW -POINT (Continued )
Depression
DEW -POINT (d ).
cositio
cositivo
of dew -point
i- d C . Oooooo - 10 | 0 1 + 10 + 20 + 30
88285
58838
c0c0
00
10 .0
10 . 5
11. 0
11 . 5
12 . 0
12 . 5
13 . 0
13 . 5
14 . 0
14 . 5
15 . 0
15 . 5
16 . 0
16 . 5
17 . 0
17 . 5
18 . 0
18 . 5 26
19 . 0
19 . 5
20 . 0
21 . 0
22 . 0
23 . 0
24 . 0
25 . 0
26 . 0 16
27 . 0 15
28 . 0 14
29 . 0 13
30 . 0
136
HANDBOOK OF CHEMISTRY AND PHYSICS
cm . cm . cm . cm . 1 cm . cm . cm . cm .
0 . 047 0 . 048 0 . 048 0 . 049 0 . 050 0 . 050 0 . 051 10. 052
ocov
137
SOUND
VELOCITY OF SOUND
Solids
Approximate values.
(From Smithsonian Tables.)
Metals.
Aluminum . . . 5104 16740 Masson
Brass . . . . . . 3500 11480 Various
Cadmium . . 2307 7570 Masson
Cobalt . . . . . 4724 15500 Masson
Copper. . . . . . . . 3560 11670 Wertheim
Copper . . . . . 100 3290 10800 Wertheim
Copper . . . . . 200 2950 9690 Wertheim
Gold , soft . . . 20 1713 5717 Wertheim
Gold , hard . 2100 6890 Various
Iron and soft steel . 5000 16410 Various
Iron . . . 20 5130 16820 Wertheim
Iron . . . . . . . . . . . . 100 5300 17390 Wertheim
Iron . . . . . . . . . . 200 4720 15480 Wertheim
Iron cast steel. . 20 4990 16360 Wertheim
Iron cast steel. . . 200 4790 15710 Wertheim
Lead . . . . . . . . . . 20 1227 4026 Wertheim
Magnesium . . . . 1602 15100 Melde
Nickel 4973 16320 Mass
Masson
Palladium . . . . 3150 10340 Various
Platinum . . . . 20 2690 8815 Wertheim
Platinum . . . . 100 2570 8437 Wertheim
Platinum . . . 200 2460 8079 Wertheim
Silver . . . . . 20 2610 8553 Wertheim
Silver . . . . . . . 100 2610 8658 Wertheim
Tin . . . . . 2500 8200 Various
inc . . . . . 3700 12140 Various
Various :
Brick . . . . . . 3652 11980 Chladni
Clay rock . 3480 11420 Gray and Milne
.
L Co rk .. . . . . .
OIR . . . 500 1640 Stefan
.
Liquids:
Alcohol, 95 % . . . . . . . . . 12 . 5 1241. 4072 . Dorsing, 1908
Alcohol . . . . 20 . 5 1213 . 3890 . Dorsing, 1908
Ammonia , conc . . 16 . 1663 . 5456 . Dorsing, 1908
Benzine . . . . 17 . 1166 . 3826 . Dorsing , 1908
Carbon bisulphide 15 . 1161 . 3809 . Dorsing, 1908
Chloroform . . . . 15 . 983 . 3225 . Dorsing, 1908
D Ether . . . .
UITCI . . . . . . . . . 15 . 1032 . 3386 . Dorsing , 1908
NaCl, 10 % sol . . . 15 . 1470 . 4823 . Dorsing , 1908
NaCl, 15 % sol . . 15 . 1530 . 5020 . Dorsing, 1908
NaCl, 20 % sol. . . . 15 . 1650 . 5414 . Dorsing , 1908
Turpentine oil. . 1326 . 4351 . Dorsing, 1908
Water, air -free . . . . 13 . 1441 . 4728 . Dorsing , 1908
Water , air - free . . . . . 19 . 1461 . 4794 . Dorsing , 1908
Water , air - free . . . . . 1505 . 4938 . Dorsing, 1908
Water, Lake Geneva . 1435 . 4708 . Colladon -Sturm
Water , Seine River . . 1437 . 4714 . Wertheim
Water , Seine River . . . 1528 . 5013 . | Wertheim
Water, Seine River . . 1724 . 5657 . Wertheim
Gases ;
Air, dry , CO2- free . . . 331. 78 1088 . 5 Rowland
Air , dry , . . . . . . . . . . 331 . 361 1087 . 1 Violle , 1900
Air , dry , CO2-free . . . 331 . 92 1089 . 0 Thiesen , 1908
Air 1 atmosphere . . . . . 331 . 7 1088 . Mean
Air 25 atmospheres . . 332 .01 1089 . Mean (Witkowski)
Air 50 atmospheres . . 334 .71 1098 . Mean (Witkowski)
Air 100 atmospheres 350 . 6 1150 . Mean (Witkowski)
Air . . . . . . . . . . . . . . . 314 . 1129 .
Air . . 100 . 386 . 1266 . Stevens
Air . . . . . 500 . 553 . 1814 . Stevens
Air . . . . . 1000 700 . 2297 . Stevens
Ammonia . . . . . 415 . 1361. Masson
Carbon monoxide. 337 . 1 1106 . Wullner
Carbon dioxide. . . 258 . 0 816 . Bückendahl, 1906
Carbon disulphide . 189 . 606 . Masson
Chlorine . . . . . . . . . . . 205 . 3 674 . Strecker
0 .
Ethylene . . . . . . . . . 314 . 1030 . Dulong
Hydrogen . . . . . . . . . 1269. 5 4165 . Dulong
Illuminating gas. . . . 490 . 4 1609 . Zoch
Methane . . . . . . . . . 432 . 1417 . Masson
Nitric oxide . . . . 325 . 1066 . Masson
Nitrous oxide . . 261. 8 8 .59 . Dulong
Oxygen . 317 . 2 1011. Dulong
Vapors :
Alcohol . . . . . 230 . 6 756 . | Masson
Ether . . . . . 179 . 2 Masson
Water. . . . .. 401 . 1315 . Masson
Water. . . . . 100 . 401. 8 1328 . Treitz , 1903
Water . . . . .. . .. 30 1 421. 4 , 1392 . Treitz , 1903
139
HAVDBOOK OF CHEMISTRY AND PHYSICS
MUSICAL SCALES
(From Miller's Laboratory Physics,Ginn & Co.. publishers , by permission.)
VIBRATION FREQUENCY OF TONES IN THE MUSICAL SCALE FOR
HIGHER OR LOWER OCTAVES ARE OBTAINED BY MULTIPLYING
BY SOME POWER OF 2
256 . G3
258 .65 GS 387 . 54
288 . 274 . 03 410 . 58
320 . Dz 290 . 33 435 .
341. 33 D #3 307 . 59 A# 460 . 87
384 . E3 325 . 88 488 . 27
426 .66 F: 345 . 26 517 . 30
480 . 365 . 79
512 .
140
ELECTRICITY AND MAGNETISM
SPARKING POTENTIAL OR DIELECTRIC STRENGTH
AIR
Potential in volts necessary to produce a spark in air at atmospheric
pressure and ordinary temperatures, the poten : ial required depends on the
shape and size of the electrodes and increases with the pressure of the air .
(From Smithsonian Tables.)
09804971
1530
2430
040.0
3240
3990 3770
3720 4560 4400
4680 8490 7510
5310 11340 10480
.5970 14340 13360
6300 17220 16140
6840 20070 18700
8070 24780 23820
8670 27810 28380
10140 45480 42950
11250 46710
12210 49100
13050 50310
8 .0 52400
10 . 0 74300
141
HANDBOOK OF CHEMISTRY AND PHYSICS
Wave Specific
Substance. inductive Observer .
length .
capacity.
Calcspar :
Ito axis . . 8 . 49 Fallinger, 1902
Il to axis . . 7 . 56 Fallinger, '1902
8
6 . 96 Hopkinson , 1891
lead (Powell ) 5 . 4 - 8 . 0 Gray -Dobbie, 1898
Jena, barium : 7 . 8 - 8 . 5 Löwe, 1898
Gutta percha . . 3 . 3 - 4 . 9 (submarine-data )
Ice - 50 C . . . . 1200 2 . 85 Thwing, 1894
- 18° . . . . . . 5000 3 . 16 Abegg, 1897
– 190° . . . . . . 75 1 . 76 - 1 . 88 Behn -Kiebitz , 1904
Iodine, cryst.. . 4 . 00 Schmidt, 1903
Marble , Carrara . 8 . 3 Schmidt, 1903
Mica . . 5 .66 – 5 . 97 Elsas, 1891
Mica, Canadian am
ber . . . . . . . . . . . 3 .0 E . Wilson
Paraffin . . . . . . . . 2 . 10 Zietkowski; 1900
Phosphorus , yellow . . 3.60 Schmidt, 1903
Porcelain , hard
(Royal Berlin ) . . 5 .73 Starke, 1897
8
Quartz :
Ito axis . . . . . . 4 .69 Fallinger, 1902
8
IS
Il to axis . . . . . 5 . 06 Fallinger, 1902
Selenium 6 . 13 Vonwiller-Mason , 1907
Shellac. 3 . 10 Winkelmann , 1889
Sulphur, amorphous. . 3 . 98 v . Pirani, 1903
Sulphur, cast, fresh . . 4 . 22v. Pirani, 1903
Wood , dry :
red beech . . . 83 - 2 .51
8
142
HANDBOOK OF CHEMISTRY AND PHYSICS
SPECIFIC INDUCTIVE CAPACITY (Continued)
. GASES
The specific inductive capacity of a vacuum is taken as unity . Wave .
lengths of the measuring current greater than 10 ,000 cm .
(Dielectric constant.)
Temp. inPressure
atmos Specific
Gas. O inductive Observer .
pheres . | capacity .
LIQUIDS
Where the wave -length is not specified it is greater than 10 ,000 cm .
Specific
Temp. Wave induc
Liquid . O
length . tive ca Observer,
pacity .
amyl. . . . . .
ethyl. . . . . . frozen | 2 .7 Abegg -Seitz , 1899
ethyl. . – 120 54 . 6 Abegg-Seitz , 1899
HANDBOOK OF CHEMISTRY AND PHYSICS
SPECIFIC INDUCTIVE CAPACITY (Continued )
LIQUIDS (Continued)
Specific
Temp. Wave induc
Observer
Liquid length . tive ca
pacity .
Alcohol: Abon
g
ethyl. 44 . 3
Abegg-Seitz , 1899 )
ethyl. . 35 . 3 Abegg -Seitz , 1899
28 . 4.
Sy
ethyl. . . Abegg-Seitz , 1899
ethyl. 25 . 8 Abegg -Seitz , 1899
INN
Air , liquid . . 40 - 90
Ebonite . . . . . . . . . 300 - 1100
Fiber . . . . . . . . . . 20
Glass . . . . . . . .. . . . . . . . . . . . . . . . . . . 300 - 1500
Guttapercha . . . . . . . . . . . . . . . . . 80 - 200
Kerosene . . 10 164
Linen , varnished . 100 - 200
Mica . . . . 1500 - 2200
M ica .. . . . . . . . 1.0 300 - 700
Oils :
castor. . . . . . . . . . 0.2 190
castor . . . . . . . . . 1. 0 130
cottonseed . . . 70
lard . . . . . . . . . . 0 .2 140
lard .. . . . . . . . 1.0 40
linseed , rawW .. .. . . . . . . . . . . . . . . . 0.2 185
. . . . . . . . . . . . . . . . . . . . 1.0 90
boiled . . 0 .2 190
boiled . 1.0 SO
lubricating . 50
olive . . . . . . . . . . . . 0.2 170
olive . . . . . . . . . . . . 1.0 75
paraffin . . . . . . . . . . . . . . . . . 0 . 2 215
paraffin . . . . . . . . . 1. 0 160
sperm , mineral. 0 . 2 180
mineral.. . . . 1.0 85
natural. . . . . . . . . . 0 . 2 195
· natural.. .. . . .. . . . . . . . . . . . . . . .! 1. 0 90
turpentine. . . . . 0 .2 160
turpentine . . . . . . . . . . . . . . . . . ..
10 110
Papers :
beeswaxed . . . . . . . . . . . . . . 770
blotting . . . . . . . . . . . . . . . . . . .. . . . . . . . . . 150
Manilla . . . . . . . . . . . . . . . . . . . . . . . . . . 25
paraffined . . . . . . . . . . . . . . . . . 500
varnished . . . . . . . . . . . 100 - 250
Paraffin :
melted . . . 75
solid , melt. point 43°.. 350
solid , melt . point 70°. . . . 450
Rubber . . . . 160 -500
Vaseline.. . . . . . . . . . . 90 - 130
0 . 2 140
Xylol. . . . . . . . . . . . . . . . . . . . . . . .
Xylol. . . . . . . . . . . . . . . . . . . . . . . . . . 1.0 80
145
ELECTROMOTIVE
FORCE
COMPOSITION
AND
VOLTAIC
OF
CELLS
CELLS
STANDARD
(From
.Smithsonian
)Tables
Name
.of
cell Negative
pole
. Solution
Positive
. Depolarizer
. EF.M
.
pole
normal
Weston
amalgam
.Cadmium solution
Saturated
.
CaSO4
of Mercury
Paste
Hg2SO4
10
CdS04
and
at 191
C.of
20°
standard
Clark
amalgam
.Zinc Saturated
.solution
ZnSO4
of ZnSO4
Mercury
Hg2SO4
C.14
15°
and
of 34
Pataste
Temperature
:
equations
Clark
:
cell 00007
?]4–1)(0.0t[1-E=434
50119
Weston
:
cell =0000406 191
0000095
2](Q-)–0.0t[1Eq
DOUBLE
CELLS
FLUID
911
of
.cell1
Name Negative
.pole Solution
. Positive Solution
. .MFEin
.
pole .
volts
Bunsen
. Ainc
.z mal H2SO4
:1p
to
. art
H20
parts
12 Fuming
.nitric
acid
Carbon
. .91 4
Bunsen
. Amal
z. inc .,13HNO3
dH2SO4
toH20
12 art
.1pCarbon
parts
.8ensity 1.86
KC
25
.tor2O7
parts
1 Bichromate
A2inc
z mal
H2SO4
|toart
H2O
parts
12 arbon
H20
and
H2SO4
1pC.parts
100 2.00
Bichromate
to
H2Oart
parts
12
zH2SO4
.Amal
1pK2Cr2O7
100
to
.Carbon
.inc
.
H20
part s 2.03
solu
of
H2O
SCto
H2S
.zAma opp
atu
art
4p1Dan
.inc tion
iel
O4
lrat
serled
+5H20
.CuSO4 1.06
.
Daniell Amal
of H20
5%s.ZnSO4
inc
+6zolution
.
of
solution
Copper
S
. aturated
+5H20
.CuSO4 1.08
HANDBOOK OF CHEMISTRY AND PHYSICS
Daniell
. zinc
.Amal to H20art
CNaCl
opper
.Ssolution
aturated
4p1ofarts
+5H20
.CuSO4 .01 5
Grove
. .zinc
Amal H2SO4
art
.!to
H2O
parts
12
1pPlatinum Fuming
nitric
acid
. 1.93
..Grove A
z mal
.| inc Solut
ZnSO
of
. ion
4 Platinum
HNO3
density
.133 1.66
(Continued
CELLS
VOLTAIC
OF
COMPOSITION
AND
FORCE
)ELECTROMOTIVE
(Continued
Cells
Fluid
)Double
.
cell
of
Name Nega
.pole tive .
Solution Positive .
Solution E.MFin
.pole .
volts
Gr
.. ove Amal
.,z inc solution
PdH2SO4
H
3densityensity
latinum
NO3
.1, 336 1.79
.Grove .Amal
,zinc solution
.11H2SO4
latinum
,ddensity
H NO3
P49ensity 1.66
Gr
. ove .Amal
zinc NaCl
solution
. P
H
,1:d
3 latinum
.3 NO
ensity 1.88
SINGLE
Fluid
CELLS
.
cell
of
Name pole
. tive
Nega .
Solution .
pole
Positive E.MF
.
Leclanché inc
.zAmal Solution
a
sal
of
-. mmoniac dm epolarize
:,Carbon
angan r
147
.carbon
powd
with
peroxide
ese .41 6
-Lalande
.Edison Am
z al
.. inc
Solution
of
caustic
.potash. . . . d,Copper
.Cepolarizer
uO 0.70
.
silver
of
Chloride Zin
.. c asal
-o.%s23fol
mmoniac dSilver
epolarizer
s,: ilver
.
chloride 1.02
CELIS
STORAGE
.
cell
of
Name .
pole
Negative .
Solution Posit
.pole ive E.MF
Lead
accumulator
.,Lead 1.
density
of
solution
H2SO4 Pb
. O2 2.
.Regnier
Copper
(1). CuSO4
H
+. 2SO4 PbU
2. 0.81658
,to
..
HANDBOOK OF CHEMISTRY AND PHYSICS
.
H2SO4
in
PbOz ,1.3
average
(2)|Ainc
.zRegnier
.
mal ZnSO 4
.solution .32 6
.,
Main zinc
.Amal ,dH2SO
1.abou
ensitt4y Pb02 2.50
Edison
. Ir KOH
2s,%. 0olution .:oxide
Anickel 1.,mean
full
of
.. on . . . . . . . . . . . .
discharge
HANDBOOK OF CHEMISTRY AND PHYSICS
CONTACT DIFFERENCE OF POTENTIAL
METALS
The values in the table give the potential in volts of the metal at the top
of the column with respect to the
( Tabulated from results by Pellat, 1881.)
Anti- | Bis Cop
mony. muth . Brass. | per.
Gold . Iron .
irr
Ili
Antimony . . . . . . 0 - . 08 - . 06 - . 30 15
Bismuth . . . . . + . 08 0 . 07
| |
i:I+|
Brass . . . . . . . . + . 06 + . 07 O 0
Copper . . . . . . . . + . 30 - . 15 .. 15
7 . 48
II
Gold . . + . 33 . 33
1|+11 + +
0
I1
+
Iron . . . + . 15
+1
Lead . . . . .
- 26
11+
Nickel . . . + . 06
Piatinum + . 46
+ +
Silver . . . + . 50 + .42
Tin . . . . . . . . - . 16 - . 24 3
Zinc . . - 41 -. . 49
+1
8
Carbon * . . . . + .41 ...
Mercury . + . 31 . 50
Plati Zinc. Car
Lead . Nickel. num . Silver. Tin . bon ,
Antimony . . . . . . + . 26 - . 06
I
Bismuth . . . . . . . + . 02
+ + + + + + + + + + +
| | | | | | | | |
II+
Brass . . . . . . . . .09
+ + + + +
+ + + + + !
Copper. . . + . 24
Gold . . 4 + . 42
Iron . + . 09
Lead . . . . .
Nickel .
+I
Platinum . . .
1
. 11
Silver . . . . . .
NO
il:+
Tin. . . . . . . . - . 63
Zinc . . - . 88 0 - 1 . 10
+1
.
| |
Carbon * . . . + . 11 - . 79 + 1 . 100
+1
1+:
Mercury . . . . . . .
+
+ . 16 . .. . . . ... . + . 09
* Ayrton and Perry.
Variation of
Metal. resistance per ohm
Specific resistance. per dgeree C . , at
20° C .
Aluminum .. . . 2 . 6 - 3 . 0 x10 - 6 .0039
Antimony . . . . 35 . 4 -45 . 8 . 0039
Arsenic . . . . . 33 . 3 . 0042
Bismuth . . . . . . . 108 . 0 . 0045
Brass . . . . . . . . . 8.5 . 0010
Cadmium . . . . . . 6 . 2 –7 . 0 . 0042
Cobalt 9 .8 . 0033
Constantin . . . . . . 49 . - . 00001
Copper , annealed .. 1. 55 - 1 .63
hard drawn . . . . . . . . 1 .61 - 1 .68
pure . . . . . . . . . . . . 1 .54 . 0041
Gas carbon . . . . . . . . 5000 . . 0005
German silver. . . . . 30 . . 00036
Gold . . . . . . . . . : 2 . 04 – 2 . 09 . 0037
Iron , commercial 9 . 7 - 12 . 0 . 0055
cast hard . . . 97 . 8
Lead . 18 . 4 - 19 . 6 . 0042
Magnesium . . . . . 4 . 1 -5 . 0 . 0039
Manganin . . . . 42 . . 00003
Mercury . . . . . 94 . 0009
Nickel . . . . . . . . 10 . 7 - 12 . 4 . 0060
Platinum . . . . 9 . 0 - 15 . 5 . 0038
Platinum iridium 24 . . 0012
Silver . . . . . . 1.5 - 1 .7 . 0040
Steel, hard.. . 45 . 7 . 0016
soft. . . . .. .. . . . . . . . . . . 15 . 9 . 0042
Tantalum . . . 14 . 5 .0027
Tin . . . . . . . . . . 9 . 53 – 11 . 4 . 0043
Tungsten . . . . . . . 7.0 . 0039
Zinc . . . . . . . . . . . . 5 . 56 - 6 . 04 . 0040
149
HANDBOOK OF CHEMISTRY AND PHYSICS
RESISTANCE OF ELECTROLYTES
Resistance of aqueous solutions of various salts and acids in ohms per
centimeter cube for a temperature of 18° C .
(From observations by Kohlrausch.)
Number of grams of salt in 100 grams solution .
Salt .
5 10 15 20 25 30 40 50
Acetic acid . . ... 654. 1616 . 1622.5 658. 1714. 925 . 11351.
Amnionium chloride . 10 . 89 5 . 63 3 . 86 2 . 97 2 . 48
Copper nitrate . . . . . 27 . 4 15 . 7 11. 7 9 . 82 9 . 17
sulphate . . . . 52 9 31 . 2 23 . 7
.
Hydrochloric acid . . . . | 2 54 1 59 1 . 34 1 . 31 1 . 38 1 . 51 1 . 94
Potassium iodide . . ..
.
29 . 5 14 . 7 . . . . . 6 . 88 4 . 34 3 . 16 2 . 55
.
1 .624
2 . 048
2 .583
3 . 257
4 . 106
5 . 178
6 .530
CA 15
91 8 . 234
ervoo
102 10 . 380
ĎO
114 13 .090
-N
128 16 .510
144 20 .820
162 26 . 250
182 33 . 100
204 41.740 92
229 52 .630 110
258 66 . 370 131 88
289 83 .690 156 105
325 105 . 500 185 125
365 133 . 100 220 150
150
HANDBOOK OF CHEMISTRY AND PHYSICS
RESISTANCE OF VARIOUS SUBSTANCES
SOLIDS
Resistance in ohms per centimeter cube.
Fusen SALTS
(Poincaré.)
Substance. Temp. °C. | Resistance , ohms.
THERMOELECTRIC POWER
The table gives the electromotive force in microvolts per degree difference
in temperature between the two junctions, for various metals with lead .
The temperature given is the mean temperature of the two junctions.
A is the thermo-electric power at 0 ° C . and B the coefficient in the equa
tion for the thermoelectric power at any temperature ,
Q = A + Bt,
where t is the mean temperature of the two junctions. The thermo
electric power of any two metals in the table may be found by subtracting
the value for the first from that of the second , a positive difference indicating
that the current will fiow from the cold to the hot junction in the second
metal .
The sign of the values given is so chosen that if A is positive the cur
rent flows in the metal listed from the cold to the hot junction . When B
is positive Q increases with the temperature .
(Principally from the Smithsonian Physical Tables .)
B Thermo
electric Neu
Metal. micro micro
volts Temp . °C . portor
er , tral
volts . micro - point.
per °C .
volts .
Aluminumi. . . . 0 . 70 - 0 .0039 20 0 . 08
Antimony comm ' l.- press
ed wire . . . :20 - 0.0
pures . . . . . . . - 0) OIS | -- 100 - + 100 - 1 . 19
Argentan . . . . . . . . 11. 94 0 . 0 .700), 20 12 . 95 - 236
Arsenic2 . . . . . . . . . . . . . . . 20
Bismuth comm 'l - pres
13 .56
ed wire ? 20 97 . 0
.
commercial! . . . . . 50 39 . 9
.
Cadmium !. . . - 0 . 0121 20 - 30 . 48 1- 62
1
Cobalt . . . . 20 22 .
Constantin 50
. .
+ 19 . 3
Copper ! . . . - 1 . 34 - 0 . 0094 20 - 1 . 52 - 113
commercial ? 20 - 0 . 10
German silver3 + 0 . 019 - 100 - + 100 + 10 . 7
Gold ' . . . . . . . . . - 2 . 80 - 0 . 0101 20 - 3.0 277
Iron ! . . . . . . . . . . . . . . . - 17 . 15 0 . 0182 20
- 16 . 2 356
pianoforte wire ? . . . 20 - 17 . 5
Magnesium ! . . - 2 2 .) 0 . 0091 - 2 .03 236
Manganiny. . . 0 . 003 - 100 - + 100 1 . 12
.
Mercury ? . . . 20 0 .413
.
Nickelt . . 50 15 . 50
Paladium ' . . . . 0 . 18 0 . 035 .) 20 6 .9 - 174
Platinum , purpo + 0 . 011 0 - 200 + 3 . 04
Platinum - iridium alloys :
85 % Pt + 15 % 111. . . . . . - 7 . 90 - 0 . 0062 20 - 8 .03 1 - 1274
90C7 Pt + 10 Irl. . . . . -- 5 . 90 0 .0133 20 - 5 .63 444
Selenium ? . . . . . . . . . 20 - 807 .
Silver ! . . . . . . . - 2 . 12 - 0 . 0147 20
- 2 .41 - 144
pure hard2. . 20 -- 3 . 00
Steel - 11 . 27 0 .0325 20 - 10 .62 347
Tellurium ?. . . . . . . 20 - 502 .
Tin , commerciali . . . 50 - 0 . 33
Tin , . . . 0 . 13! - 0 .0055 20 0 . 33 78
Zinci . . . . . . . . . . . . . - 2 . 32 - 0 .0238 20 - 2 . 79 - 98
Induced Induced
Field in magnet Field in magnet
Substance. tensity . ization . Substance . tensity9 ..
ization .
( For saturation .) ( For saturation .)
153
HANDBOOK OF CHEMISTRY AND PHYSICS
Temp. Susceptibility
TOT
Substance. o C . ( vacuum = 0 ) .
Observer
Aluminum . . . - 1 . 8 X10 - 6
Antimony . . . . . - 4 .6 Curie , 1895
Bismuth . . . . . 3. 3 Curie , 1895
Copper . . . . . 1. 3 Becquerel, 1855
Gold . . . . . . . - + 5 Hapriot & Raoult , 1911
Lead. . . . . . - 1 . 21 Becquerel
Mercury . . . . . - 2. 1 St. Mayer
Platinum . . . . . + 29 . 00 J. Königsberger , 1898
Selenium . . . . - 1 . 54 Curie , 1895
Silver . . . . . . . . - 1.8 Becquerel, 1855
Tellurium . . . . . 20 - 1 . 94 Curie , 1895
Zine . . . . . . . . . . . . - 1 . 16 Owen , 1912
Iron annealed . . . . + 37 . 4 X101 For weak fields
Nickel. . . . . . . . . . + 4 . X101 For H = 100 C . G . S .
Steel tempered . . . . . + 3 . 4 X10 For weak fields
INORGANIC COMPOUNDS
LIQUIDS
Substance. Te
O mp .
Susceptibility Observer .
C
C . (vacuum = 0 ).
154
HANDBOOK OF CHEMISTRY AND FHYSICS
VARIATION OF RESISTANCE DUE TO A
MAGNETIC FIELD
BISMUTH
The table shows the proportional values of the resistance for values of
the magnetic field from 0 to 35 ,000 and for different temperatures. The
resistance at 0° C . and H = 0 is taken as 1 .
Proportional values of resistance.
(From Smithsonian Tables.)
VARIOUS METALS
The table gives the per cent. change in the resistance due to a field of
10 ,000 gauss with respect to the value at 0° C . and H = 0 .
(Grumach.)
HALL EFFECT
If a strip of metal of thickness t, in which a current i is flowing (longi
tudinally ) is subjected to a transverse magnetic field H , a difference of poten
tial E is produced at opposite points at the side of the strip . E = RX Hilt
where R is a constant specific with different metals and E , H , i and tin C . G . S .
units. The table gives values obtained at ordinary room temperatures,
18 - 21° C . If the value of R is independent of the field , or nearly so , the
field intensity is not given . The positive sign indicates that if a strip of
metal were considered to be in the plane of this page with its long axis
horizontal, the primary current flowing from left to right and the magnetic
field directed away from the observer, normal to the plane of the strip ,
the upper edge of the strip would be at a higher potential than the lower.
Field
Substance . strength , R. Observer .
gausses.
ELECTROCHEMICAL EQUIVALENTS
N ONCN
Gramsper coulomb.
Coercoco
156
ILANDBOOK OF CHEMISTRY IND PHYSICS
State. Horizontal
NOTO
Dip , degrees. intensity .
Alabama . . 62. to 66 . . 23 to 26
Alaska . . . . . . 67 . 74 . . 21
Arizona . . . . . . 59 .
.
Arkansas . . . . . 63 .
California . . . . 58 02
OOONOOINOOOOOOOOOO
3
67 .
OOST
Colorado . . . . . .
Connecticut . . 72 . 73 . 18
Delaware . . . . . 70 . 71 . 5
Florida . . . . . 58 .
Georgia . 0
Hawaii. . . . .
Idaho . . . . . . 09 .
Indiana . . . . 69 .
lowa . . . . . . 73 , 20
kansas. . . . . 67 . 69 . 23
Kentucky . . . 08 . 70 . . 22
74 .
Maine . . . . . 76 .
Maryland . . . . 70 . 5
Massachusetts . . . . 73 .
Michigan . . . . . . . 73 .
Mississippi . . . . . 00
Missouri . . . . . . . 67 . 71 .
Montana . . . . 70 72 . 20
Nebraska . . . . . 70 . 71.
New Hampshir 73 . 74 . 17
New Jersey . . . . 71 .
New Mexico . . . . . 63 . . 25
New York . . . . . . . . 74 . 17
North Carolina . . . 66 . : 23
North Dakota . . . 74 . 16
Ohio . . . . . . . . . . 20
Oklahoma . . . . . 63 . 67 .
Oregon . . . . . . . . 69 .
Pennsylvania . . . . . 71 .
72 .
Philippines . . . . . . 0 .
OOOO
Porto Rico . . . . . . 49 .
O
South Carolina . . . . 66 .
South Dakota . . .
Tennessee . . . . .
Texas . . . . . . . . 57 . 63 .
Utah .. . :
66 . 67 .
.
Vermont . . . 73 . 75 .
68 . 70 .
Virginia . . . . . . .
Washington . . . . . . 71 .
70 . 5 . 20
ha
West Virginia . . . .
Wisconsin . . . . . . . . 15 . 17
Wyoming . . . . . . . . . 68 . 22
!
157
HANDBOOK OF CHEMISTRY AND PHYSICS
MAGNETIC DECLINATION
An annual decrease in declination is indicated by the negative sign,
an increase by the positive.
(From U . S . Coast and Geodetic Survey)
++ + + +
Glenwood Sp . . . . 16 . 3 E 16 . 1 E 15 .6 E 16 . 1 E + . 062
Conn . . Hartford . . . . . 8. 7 W 9. 4 W 10 . 4 W 11. 0 W + .097
Del . . . . . ' Doyer . . . . . . . 4 .7 W 5.3 W 6 .4 W 7.0 W + . 080
^
D . C . . . . . . Washington . . . . . 2 .4 W 4.7 W + . 075
Fla . . . . . . . Jacksonville . . . . 3. 1 E 2 .4 E 1. 2 E - .033
*-
+ ! ! !
Tampa . . . . . . . . . 3. 9 E 3. 3 E 2 .0 E - .013
Ga . . . . . .. .. Vacon . . . . . . 3. 9 E 3. 2 E - .033
Hawaii. . . . Honolulu . . . . 10 .6 E
4. 1 E 3. 6 E 3. 4 E - . 013
1
Lansing. . . . . . . . . 22 .. 11 EE 1.
1 . 03 E 0.4 E ! + .040
+1
158
HANDBOOK OF CHEMISTRY AND PHYSICS
+ + + +
Elmira . . . . . 5 .4 W 6 .3 W 7 .0 W 7.6 W 8.1 W + . 075
N . C .. .. . Newbern . . . . I 1. 0 W 1 .6 W 2.2 W 2 .8 W .3 W + . 057
Salisbury . . . 1 .5 E 0 .8 E 0 .2 E 0 .4 W 0 .7 W + . 047
N . Dak . . 14 . 0 E 13. 5 E 12. 7 E 12. 4 E 12. 8 E + . 030
Dickinson . . . . . 17 . 4 E 17 . 0 E 16 . 4 E 16 . 2 E 16 . 6 E + . 010
+ + +
Ohio . . . . Columbus . . . 1.2 E 0 .6 E 0 .0 E 0.7 W 1.1 W + . 047
Okla . . . . . Okmulgee . . . 9 . 8 E | 9 .4 E 8 .8 E 8 .5 E 8 . 9E + .033
Enid . . . . . . . 10. 9 E 10 .5 E 9 .9 E 9 .7 E 10 . 1 E + . 043
Oregon . . Sumpter . . . 20 .0 E 20 . 2 E 20 . 2 E 20 .4 E 21. 0 E + . 077
Detroit . . . . . 20 . 1 E 20 .4 E 20 , 5 E 20 . 8 E 21. 5 E + . 080
Penn .. . Philadelphia . . | 5 .5 W 6.3 W 6 .8 W 7 .4 W 8.0 W + . 083
Altoona . . . . . 3.1 W 3. 8 W 4.5 W 5 .1 W 5 .6 W + . 067
P. R. San Juan . . . . ... . .... 1. 0 W 2.0 W
R . I. Newport . . . . . . . 10 . 3 W 10 . 8 W 11. 3 W 11. 9 W 124 W + . 100
. C . . . . Columbia . . . . . 2. 1 E 1. 4 E 0.8 E 0.2 E 0. 1 W + . 013
S . D . .. Huron . . . . . . . 12. 6 E 12 . 1 E 11. 4 E 11. 1 E 11. 4 E + . 030
Rapid City . . . . . . 16 . 3 E 15 . 8 E 15 . 3 E 15 . 1 E 15 . 1 E + . 012
Tenn . . . Chattanooga . . . . 53 . 3) 2.6 E 2.0 E 1.5 E 1. 3 E - . 033
159
LIGHT
PHOTOMETRIC STANDARDS
VALUE OF VARIOUS STANDARDS IN INTERNATIONAL CANDLES
Standard Pentane Lamp, burning pentane . . . . . . . 10 . 0 candles
Standard Hefner Lamp, burning amyl acetate . . . . 0 . 9 "
Standard Carcel Lamp, burning colza oil. . . . . . . . . 9 .6 "
Standard English Sperm Candle , about . . . . . . . . . . 1. 0 "
The Carcel unit is the horizontal intensity of the carcel lamp,
burning 42 grams of colza oil per hour. For a consumption
between 38 and 46 grams per hour the intensity may be con
sidered proportional to the consumption .
The Hefner unit is the horizontal intensity of the Hefner
lamp burning amyl acetate , with a flame 4 cm . high . If the
flame is l mm . high , the intensity I = 1 + 0 .027 (1 — 40 ).
STANDARD CANDLES
The horizontal intensity may be considered proportional to the rate of
consumption of material if the variation is small.
160
HANDBOOK OF CHEMISTRY AND PHYSICS
Acetylene flame. . . 95 6 .9 17 . 7
Electric arcs :
Carbon , open air, continuous
current . . . . . 435 171 0 .92
alternating current . . . . . . . 181 98 2 . 27
Flaming arc, yellow . . . . . . . 350 816 0 . 34
Mercury arc, uviol tube . . . . . . 199 393 0 .64
quartz tube. . . . . . . . . . . . . . . 691 3050 0 . 25
Incandescent electric , carbon fil
ament. . . . . . . . . . . . . . . . . . . 98 28 . 3 4 .54
tantalum filament . . . . . . . . . . . 31 . 1 1 . 83
38 1 . 59
tungsten filament. . . . . 32 . 7
Incandescent gas mantle , vertical 717 96 . 3 8.9
inverted . . . . . . . 57 96 . 3 7 .7
Nernst lamp . . . . . . . . . . . . . . . . . 181 108 2 . 12
Sun . . . . . . . . . . . . . . . . . . . . . . . .
Hefner lamp . . . . . . . . . . . . . . .
Acetytene flame.. .. .. . . . . . . . . . . . . . . . . 40
Incandescent carbon filament
Tungsten filament . . 41
Nernst filament. . . . 40
Electric arc, carbon .. .. .. . . . . . . . . 36
Mercury arc . . . . . . . . . . . . 30
Flaming arc . . . . . . . . . 37 . 5
Incandescent gas mantle, thorium
with 0 .25 part in 100 of cerium . . . . 41
161
HANDBOOK OF CHEMISTRY AND PHYSICS
Electric arc :
current of 10 amperes. . . . . . 16000 Blondel, 1897
current of 25 amperes . . . . . . 19500 Blondel, 1897
current of 250 amperes . . . . . 30000 |·Rey & Blondel, 1902
Flaming arc . . 4000
Flames, candle . . . . . 0 . 4 -0 . 6
petroleum lamp, round wick 3. 3 Stockhausen , 1910
petroleum lamp, flat wick . . . | .67 Stockhausen , 1910
gas, argand burner. . . . . . . 1 . 14 Stockhausen , 1910
acetylene, flat flame. . . . . 5 .6 Stockhausen , 1910
Incandescent electric :
filament of carbon ( 3. 3 watts
per candle ) . . . . . . . . . . . . . 75 . Blondel, 1911
filament of tungsten (1 . 2
watts per candle). 150 . Blondel, 1911
Nernst . . . . . . . . . . . . . . . 350 -470 Ives & Luckiesch , ' 11
Gas mantle . . . . . . . 4 . 8 -6 . 7 ) Ives & Luckiesch
Mercury arc . . . . . . 2 .5 Ives & Luckiesch
Moon . . . . . . . . . . . . . . . . . . 0 .4 Pickering , 1908
Star (Algol). . .. .... .. . . . . . . . . . . . 840000 Nordmann, 1910
Sun at zenith . . . . 160000 Palaz, 1893
Wave length .. . .410 . 430 . 450 .470 .490 .510 .530 .550 . 570 .590 .610
Mean sensitive
ness . . . . . ...10.
. . . 02 0. 06 0.23 0.49 0. 81 1.00 0. 81 (0. 49 (0 .22 0.077 0.026
Fe 2947 . 9 H 4101 . 9
2994 . 4 4226 . 7
3020 . 7 4307. 7
3047. 6 | Fe í 4307 . 9
( 3099 . 9 4340 . 5
3100 . 0 4861.4
1 Fe, Mn 3100 . 3 5167 . 3
09
V 3440 . 6 5895 . 9
3441 . 0 6562 . 8
3581 . 2 6867 . 2
3719 . 9 7593 . 8
3820 . 4 8228 . 5
3933. 7 8990 . 0
3968 . 5
163
HANDBOOK OF CHEMISTRY AND PHYSICS
WAVE LENGTH OF PRINCIPAL LINES OF VARIOUS
ELEMENTS
innn
SOLIDS
Wave lengths of the most prominent lines in microns. The letters
a , s and f after a wave length indicate its occurrence as a strong line in
the arc, spark or flame spectrum respectively .
nosos
nn
on
an
Aluminum . . . . . . . . 3082 Caesium . . . . . . . . 4555 a , f
osos
. 3092 a, s . 4593 a . f
. 3587 .6723 a
. 3944 .6974 a
3961 a , s Calcium . . . . . 3934 a , s
.5697 . 3969 a , s
. 5723 . 4227 a , s, f
Antimony .. . . . .3268 s Calcium chloride
.6005 s. in the Bunsen
.6079 s flame also gives
Ooooooooooo
.6130 s lines not due to
Arsenic. . . . . . . . 2745 s calcium . . . . . . . . .5517
2861 s . 5543
.3923 s .6181
4037 s .6202
Barium . . . . 3891 s .6265
4131 s . 4012
4554 . 4134 s.
.4934 a , s 4150 s
. 5535 4165 s
. 5853 4187 s
.6141 a , s 4297 s
.6497 a , s . 4527
Barium chloride in . 4628
the Bunsen flame . 5274
gives other lines . 5353
not due to bar Chromium * .. . . .. 4255 a , s
ium . . . .5136 . 4275 a, s
. 5242 . 4290 a, s
5313
Bismuth . 3596 s. . 4559
1723 a , s . 4588
1994 S 5205 a , s
Cadmium . . . 3611 a , 5206 a,
4678 . 5209 a , s
1800 a , . 5410
. 5086 a , s Cobalt t . . 3846 a , s
.5338 S . 3873 a , s
. 5378 S . 3894 a, s
.6439 a , s . 4531 a
* More than twenty fairly prominent lines occur in the spark spectrum
of cbromium having wavelengths from 2763 to 3606u.
F A large number of lines occur in the are and spark spectrum of cobalt
having wave lengths less than . 3600 (ultraviolet) .
164
HANDBOOK OF CHEMISTRY AND PHYSICS
WAVE LENGTH OF PRINCIPAL LINES OF VARIOUS
ELEMENTS ( Continued)
Solids (Continued )
ம மமமமமமமமமமம
Cobalt (Cont.) . . .1.4581 a Iron *. . . . . . .. . . 4046
. 4780 , . 4064
ದ
ದ
4793 ೩, S . 4071]
. 4814 . 4118 ೩ |
. 4840
ದ
. 4132
.4868 . 4134
Copper. . . . . . . . . 3248 a
. 4143
4144 8, S
ದ
. 3274 a
.4023 4187) 8 , S
.'ம
4063
4188
4191|
ದ
. 5106 ೩, S 4198 a ,' s
5153 a , S . 4199
. 5218
4202 8, S
5700 ೩ | 4227
. 5782
4234 8, S
Gold. . . . . . . 2428 4236 a, S
4250 ೩, S
TUV೧ದ
2676 a , S
2802 s 4251
3899 S . 4261
4065 4272
4315 S 4282
.6278 4294
4299
Iodine (spark ) . .. .5159 4308
. 5244 . 4315 a
4326
ದ
. 5339)
5349 . 4337
.5408 4384
. 5448 4405)
.5471 .4415
. 5631 . 4476
மம
. 5686 4528 a, S
. 5716 4655 a, S
. 5741 4736 a
. 5766 . 4892 a
. 5781 .4921 a, S
. 4957)
ದ
. 5961
20
. 5139 a , S
Iridium . . . . . . , 3606) S . 5167||
. 3653 s .5192
. 3675 S . 5227) a
0
3800 S 5233 8, S
. 3903 | S . 5267| ೩, s
4400 a, S . 5270) ೩, S
* The ultraviolet spectrum of iron shows over 100 lines of intensity
comparable with those listed above .
165
HANDBOOK OF CHEMISTRY AND PHYSICS
WAVE LENGTH _ OF PRINCIPAL LINES OF VARIOUS
ELEMENTS (Continued)
Solids (Continued )
a
. 5302) a , s . 6104
*ದಈ
s5324 . 6708] 8 , S , f
.5328 Mercury . . . . . . . 2537)
ದ
. 5372 . 2967|
. 5397
maneno
. 3022
. 5406| . 3023
. 5447 . 3126
.5455 . 3132
.5570 . 3341)
5573 . 3650
5587| ೩
. 56 . 3654
man
16 . 3663
.56 9/
5 . 3984
aner
. 5763| . 4046
.5862 4078
ದ೧
.5930 - 4358
. 6065 . 5426
. 6137 . 5461] , S
. 6138| . 5770
. 6192|| . 5791
1. 6231 ೩ . 5804
1.6253 a
ದ
. 6318) a
ದ
. 6337| ೩ . 2852
ದ
.6400 a . 3097)
ದ
. 6495 a . 3829
ದ
. 6546 8 . 3832||
ದ
. 6593 ೩ . 3838]
4481
Lead * , . . . . . .3640
m
.5173
cono
. 3684 8, S .5183
con
3740
3786 Manganese . . 3807] 8, S
. 4031 ]
ದ
. 3854 40.
4058
4245 .4035
.4387 .4042|
5374 .4754
5547 .4784
non
non
5608 .4824
. 6657 6014
. 6017| ೩,
Lithium . ... . . . . . . . 4132 a . 6022
un
* The arc and spark spectra of lead include a large number of lines in
the ultraviolet not given above .
166
HANDBOOK OF CHEMISTRY AND PHYSICS
WAVE LENGTH OF PRINCIPAL LINES OF VARIOUS
ELEMENTS ( Continued )
Solids (Continued)
Molybdenum . . . . 3635 s Radium (Cont.).. .4826 s, f
. 3688 s . 5661) s
. 3798 a , s . 5814 ) s
. 3864 a , s band .6130 .6330 f
. 3903 a , s .6349 f
. 3961 S band .6530 . 6700
.5506 a , s
.5533 a , s Rubidium . . . . .4202
es cordoconcom
. 4215 a ;
ထဲဟဲ
. 5570 a , s
.6207
.6030 .6298
. 7806
=ဟဲ
Nickel. .. . 4714 a, s
ono
. 7811
cosaco
.4855 a , s .7950 a
. 4866 a , s
=
. 4873 s Selenium . ... .. . .4606
. 5035 a , s 4840
. 5081 . 4842
. 5477 .4972
no
. 5893 4993
on
.5094 8.
Osmium .. . . . . . . 3753 .5142 s os
4067 5176 s
41361
5225 e
o ond
. 4
5270 s
5305 s
மம
மம
Silicon . . . . . . . . . 2516 a, s
o
2881
Platinum . . . . . .
os oscom
3687 ) s
. 3923 Silver . . . . . . 3281
3383
a, s .4055
5301 .4212 a
.5369 s 5209 a , s
5466 a , s
Potassium . . . . .. . 3447 a , s, fla
.4044 a , s . f Sodium . . . . . . 3302 a , s, f
one
enaseenof
.6911 a 3303
5683
ದ
.6939
7665 a , s, 5688
7699 a , s, f 5890
Radium . . . . .
.5896
our cus
. 3650 .6154
ಈ20
. 3815 .6161 a
4341
Strontium . . . . .. . 4078 a , s
4533 . 4216 a , s
1683 1607 a , s , f
167
HANDBOOK OF CHEMISTRY AND PHYSICS
mo
.6351 .6453
.6464 Tungsten . . . . . .4843
.6597 . 5059
on
. 6664 . 5224
.6694 - 5514 s
Sulphur . . . .4465
o
Uranium . . . . . . 5478 s.
.4486 . 5480 s
|Մ Մ
.4525 . 5482
4552
o o
. 5494
Մ
. 5021 s . 5528
5033 Zinc . . . . . . . . .
.3345 | a , s
Մ
1.5201 s
.5215 s . 4680
.5320 s.
.4722
con
.5343 s . 4811 a , s
. 4912
. 5605 .4925
Մ
. 5640
.6103 ' s
Մ
.6290 s
.6362 a, s
Tantalum . . . . . 3906
Zirconium . . . . . . 3958 a, s
Մ
. 4059 s
4080 3982 a
conoona
3991 a, s
Մ
4101 s
. 4124 s
. 3999
una
. 4049 a , s
Thallium . . . . . . .2918 .4073 a
Ե
3230 .4081 a
Թ
. 3519
nama
. 4149 a , s
«Թ
. 3529 a . 4156 a , s
. 3776 . 4161 a , s
«
.4737
oscomosons
. 4360
Մ
5351 a , . 4371 a,
Thorium . . . . . . 3221 . 4380 a .
Մ
. 3272 s 4443
3291 .4494
Մ
. 3301 . 4497
Մ
. 3314 s .4688
3508 . 4710
Մ Մ
3539 .4739
.4019 . 4772
Մ
4382 .4816 s
Մ
.4391 .6128
Մ
4555 s .6142
168
HANDBOOK OF CHEMISTRY AND PHYSICS
Wave
length .. . 0 . 364 0 . 38 0 .40 0 .42 0. 44 0 .46 0 . 48 0 .50 0 .52 0 .54
Red . . 1 0.0 0.0 2. 0 1. 0 i 1 . 0 1. 0 3.0 9 .0 23 . 0 39 . 0
Green , . . 0.0 0.0 0.0 0.0 0 .0 2.0 | 7.0 23 . 0 61. 0 87 . 0
Blue . . . 10. 0 10 . 5 29 . 0 52. 0 76 . 0 78 . 0 68 . 0 46 . 0 16 . 0 7.0
Wave
length. . . 10 . 564 0 . 58 0 . 60 0 . 62 0 . 64 0 .66 0 .68 0 . 70 0 . 72 0 . 74
Red . . . . . . 156 . 0 69 . 0 71 . 5 59 . 0 30 . 0 12. 0 | 5 . 0 | 2 . 0 | 1 . 0 | 0 . 0
Green . . . . . 36 0 67 . 0 37 . 0 10 . 0 2.5 1. 0 0.0 0.0 0.0 0.0
Blue . . . . . . 4 . 0 | 1. 5 0 .0 0.0 0 .0 0.0 0.0 0.0 0.0 0.0
169
HANDBOOK OF CHEMISTRY AND PHYSICS
INDEX OF REFRACTION OF OPTICALLY ISOTROPIC
SOLIDS
(From 'Smithsonian Tables.)
Line of
Substance . spec
Index of Observer .
trum . refraction .
170
HAND BOOK OF CHEMISTRY AND PHYSICS
INDEX OF REFRACTION OF OPTICALLY ISOTROPIC
oooooooooooo
· SOLIDS (Continued )
Line of Index of
Substance . spec refraction . Observer.
trum ,
172
HANDBOOK OF CHEMISTRY AND PHYSICS
INDEX OF REFRACTION , LIQUIDS
(From Smithsonian Tables.)
DISPERSION
The dispersion for various types of optical glass is shown in the following
table . nd = index of refraction for the D line (of the solar spectrum ) and
ng and nc the index for the F and C lines respectively (np - nd) shows the
dispersion for these two wave lengths.
173
HANDBOOK OF CHEMISTRY AND PHYSICS
INDEX OF REFRACTION, AQUEOUS SOLUTIONS
Index for
Substance. Density. Temp. °C . X = .5893 Observer.
( Na )
Index of Index of
Metal. refraction . Metal. refraction ,
Aluminum . . . . . 1 . 44 Mercury . . . . . 1 . 73
Antimony . . . . . 3 . 04 Nickel. . . . . . . . 1 . 79
Bismuth . . . . . . 1 . 90 Platinum . . . . . . 2 . 06
Cadmium . . . 1 . 13 Silver 0 . 181
Copper. . . . . 0 . 641 Steel . 2 . 41
Gold . . . . . . . 0 . 366 Tin , solid . .. 1 . 48
Iron . . . . . . . . . 2 36 Tin , fluid . . .. . 2 . 10
Lead . . . . . . . . . 2 . 01 Zinc. . . . . . . .. .. 2 . 12
Magnesium . . . 0 . 37
sagessei
Kind of
Substance . light. Indices of refraction . Observer.
Acetone . . . . . . . . . D 1 . 001079 - 1 . 001100
Air . . . . . . . . . . . . . . . . D 1 . 0002926 Perreau
Ammonia . white 1 . 000381 - 1 . 000385
Ammonia 1 . 000373 - 1 . 000379
Argon . . . . . . 1 . 000281
Benzene . . . . 1 . 001700 - 1 . 001823
Rayleigh
Bromine . . . . 1 . 001132 Mascart
Carbon dioxide . . white 1 . 000449 - 1 . 000450
dioxide. . . . . 1 . 000448 - 1 . 000454
disulphide . . . . . white 1 . 001500 Dulong
disulphide . . . . . D . 1 . 001478 - 1 . 001485
. . monoxide. . . . . . . white 1 . 000340 Dulong
monoxide. . white 1 . 000335 Mascart
Chlorine . . . . . . . white 1 . 000772 Dulong
Chlorine . . . . . . 1 . 000773 Mascart
Chloroform . . . . 1 . 001436 - 1 . 001464
Cyanogen . white 1 . 000834 Dulong
Cyanogen . . . . . 1 . 000784 - 1 . 000825
Ethyl alcohol. . 1 . 000871 - 1 . 000885
ether. . . . . . . . . . . 1 . 001521 - 1 . 001544
Helium . . . . . . . . 1 . 000036 Ramsay
Hydrochloric acid . . white 1 . 000449 Mascart
Hydrochloric acid . . D 1 . 000447 Mascart
Hydrogen . white 1 . 000138 - 1 . 000143
Hydrogen . . . . 1 . 000132 Burton
sulphide. . 1 . 000644 Dulong
sulphide. . . . . . . . 1 . 000623 Mascart
Methane . . . . . . . . . white 1 . 000443 Dulong
Methane . 1 . 000444 Mascart
Methyl alcohol. . 1 . 000549- 1 . 000623
Methyl ether . . . . 1 . 000891 Mascart
Nitric oxide . . . . white 1 1 . 000303 Dulong
Nitric oxide. . . D 1 . 000297 Mascart
Nitrogen . . . . . . . white 1 . 000295 - 1 . 000300
Nitrogen . . . . . . . . D 1 . 000296 - 1 . 000298
Nitrous oxide . . . . . white 1 . 000503 - 1 . 000507
Nitrous oxide . . . . . D 1 . 000516 Mascart
Oxygen . . . . . . . . . . white 1 . 000272 - 1 . 000280
Oxygen . . . . . . . . D 1 . 000271- 1 .000272
Pentane . . . . . . . D 1 . 001711 Mascart
Sulphur dioxide . . . white 1 . 000665 Dulong
Sulphur dioxide . . . D 1 . 000686 Ketteler
Water . . . . . . . . . . . . white 1 . 000261 Jamin
Water. . . . . . . . . . . . . . . . . D 1 . 000249 - 1 . 000259
Wave length , mi
crons . . . . . . . . . . 10 . 2800. 309 0 . 325 0 . 346 0 . 361 0 . 3830. 397
Uviol crown . . . . . . 0 .56 0 .95 0 .990 0 .996 0 .999 1.000 1 .000
175
HANDBOOK OF CHEMISTRY AND PHYSICS
R R
4 .65
4 .65 35° 4 . 98 12 .91
4 .66 5 . 26 18 . 00
4 . 66 5 . 73 26 . 19
4 .68 6 . 50 39 .54
4 .73 74 X
61 .77
4 .82 9 .73 90 100 .
• R
1 .0
Gerincs
0 . 00 6 . 72 17 . 0
.ܒf m - l
1. 1 0 . 23 8 . 16 18 . 4
1.2 0 . 83 9 .63 19 . 8
1 . 70 11 . 11 21 . 1
ܒܝܘܪ
2 .78 12 .6 22 . 5
4 . 00 14 . 1 23 . 8
5 . 33 15 . 5 25 . 0
Mer
Magna- Mag
Wave Anti Bronze Copper,
(68Cu , commer -
Gold ,
electro lium , cury,
ne backed
length . mony . 68Sn ). cial. lytic . Mach ' s . sium .
glass .
251 30 25 . 9 38 . 8 67 . 0
. 288 24 . 3 34 . 0 70 . 6
. 305 25 . 3 31. 8 72 . 2
. 326 24 . 9 28 . 6 75 . 5
. 357 27 . 3 27 . 9 81 . 2
296 27 . 1
. 385 83 . 9
. 420 2 . 7 29 . 3 83 . 3
.450 37 . 0 33 . 1 .GT 83 . 4 72 . 8
.500 43 . 7 47 . 0 83 . 3 70 . 9
. 550 47 . 7 74 . 9 82 . 7 71. 2
. 600 71. 8 84 . 4 83 . 0 69 . 9
650 80 . 0 88 . 9 82. 7 71. 5
21:
700 83 . 1 92 . 3 83 . 3 72 . 8
800 88 . 6 94 . 9 84 . 3
1 . 00 90 . 1 84 . 1
2 .0 . 80 95 . 5 96 . 8 86 . 7
97 . 1 87 . 4
.
. 88 97 . 3 96 . 9 . 89 88 . 7
. 93 98 . 4 98 . 0 . 94 90 . 6 l . 93
Silver,
Plati chemi Silver Specu
Wave Nickel, num , Tung
electro cally backed lum Steel.
length . electro sten .
lytic. depos glass. metal.
lytic. ited .
. 251 37 . 8 33 . 8 34 . 1 29 . 9 32 . 9
. 288 42 . 7 38 . 8 21 . 2 37 . 7 35 . 0
. 305 44 . 2 39 . 8 9.1 41 . 7 37 . 2
. 326 45 . 2 41. 4 14 . 6 40 . 3
. 357 48 . 8 43 . 4 74 . 5 51.09 45 . 0
. 385 49 . 6 45 . 4 81 . 4 53 . 1 47 . 8
. 420 56 . 6 51. 8 86 . 6 56 . 4 51. 9
. 450 59 . 4 54 . 7 90 . 5 85 . 7 60 . 0 54 . 4
. 500 60 . 8 58 . 4 91. 3 86 . 6 63 . 2 54 . 8 . 49
. 550 62 . 6 61. 1 92 . 7 88 . 2 64 . 0 54 . 9
. 600 64 . 9 64 . 2 92 . 6 88 . 1 64 . 3 55 . 4 . 51
. 650 66 . 6 66 . 5 94 . 7 89 . 1 65 . 4 56 . 4
. 700 68 . 8 69 .0 95 . 4 89 . 6 66 . 8 57 . 6 .54
. 800 69 . 6 70 . 3 96 . 8 58 . 0
1 . 00 72 . 0 72 . 9 97 . 0 70 . 5 63 . 1 . 62
2.0 83 . 5 80 . 6 97 . 8 80 . 4 76 . 7 . 85
3. 0 88 . 7 88 . 8 98 . 1 86 . 2 83 . 0 . 90
4 .0 91 . 1 91. 5 98 . 5 88 . 5 87 . 8 . 93
9 .0 95 . 6 95 . 4 98 . 7 92 . 2 92 . 9 95
177
HANDBOOK OF CHEMISTRY AND PHYSICS
GLASS.
Glass in general is opaque to the ultra -violet and infra - red . Uviol glass
is transparent to the longer radiations of the ultra - violet.
efficient of transparency of glass for visible and ultra -violet radiations.
QUARTZ
Quartz is very transparent to the ultra -violet and to the visible
spectrum , but opaque for the infra -red beyond 7 . 04 .
( PAüger.)
FLUORITE
Fluorite is very transparent to the ultra -violet, nearly to
0 . 10u . Coefficient of transparency at 1 = 186 is found by
Pflüger to be 0 . 80 .
For the infra- red the values are given in a table below .
178
HANDBOOK OF CHEMISTRY AND PHYSICS
Wave length ,
microns . Rock salt. Sylvine KCI. Fluorite.
. 844
0 . 005
995 1 . 000 . 543
.995 . 988 . 164
. 993 . 995 .010
. 931 . 975 .000
. 661 . 936
.275 . 862
19 . . 096 .758
20 . 7 . 006 . 585
23 . 7 .000 . 155
Wave
One part. 100 parts. . length . Color. Observer.
Antimony oxide . . calcium oxide | 0 .560 yellow Bruninghaus, 1910
Antimony trisul
phide . . . . . . . . . calcium sulphide 0 . 569 yellow Bruninghaus , 1910
Bismuth oxide . . . calcium oxide 0 .522 blue Bruninghaus, 1910
Bismuth sulphate , calcium sulphate 0 . 640 red Bruninghaus, 1910
Manganous car
bonate . . . . . . . . magnesium car
bonate 0 . 620 red Bruninghaus. 1910
oxide. . . . . . . . . calcium oxide 0 . 589 yellow Lecoq & Boisbaudran ,
1886
phosphate. . . . . calcium phosphate
Ca3 (PO4) 2 0 .633 red Bruninghaus, 1910
sulphate.. . . . . . calcium sulphate 0 . 540 green Lecoq & Boisbaudran ,
1886
sulphide.. . . . .. calcium sulphide 0 .589 yellow Bruninghaus, 1910
179
HANDBOOK OF CHEMISTRY AND PHYSICS
Wave
Substance . Solvent. length Observer.
microns.
10 . 400
Anthracene . . . . alcohol 0 .430 Stark & Meyer, 1907
10 .436
Eosine. . . alcohol or 0.589 Nichols & Merritt, 1907
water
Esculine . . . . alcohol 0 . 460 Nichols & Merritt, 1907
Fluorescein . . . . . . water (al 0 . 542 Nichols & Merritt , 1907
kaline )
Naphthalin , red . . alcohol 0 .632 Nichols & Merritt, 1907
Quinine sulphate . water 0 .437 Nichols & Merritt, 1907
Resorcin blue . . . . water 0 .65 Nichols & Merritt, 1907
Rhodamin . . . . . . . water 0 . 554 Nichols & Merritt, 1907
FLUORESCENCE
GASES AND VAPORS.
Gas or
Color or wave
Condition . Excitation . l length of emitted Observer
vapor .
light.
Iodine . . . Vapor at or- Mercury arc Strongest bands
dinary tem - = .516u = .5460u, .5774u
perature . 5730 , .5796 . Wood , 1911
Mercury . Vapor at or - Spark between Broad band
dinary tem aluminum = .5900 - 3000 Wood, 1909
perature | electrodes
Oxygen . . .......... Vercury arc in Strongest lines
quartz tube . = .1849, . 1851
(ultra - violet ) Streubing, 1910
Potassium Vapor, 300° - White light Many strong lines
| 400° C . from .6416
.6768, strongest Wood & Carter,
.6544 and .6584 1908
Rubidium Vapor, at White light Strong red band
| 270° C . ( elec. arc ) = .6900 - 6620 . Dunoyer, 1912
Sodium . . Vapor at White light D , X = .5893
350° C . (elec, arc) (mean ) Dunoyer, 1912
180
HANDBOOK OF CĦEMISTRY AND PHYSICS
SPECIFIC ROTATION
The tables give the specific rotation in degrees for one decimeter; + sig .
nifies right-handed rotation , - left. Rotation is for sodium light.
LIQUIDS
Specific
Liquid . Тетр. Rotation .
Degrees.
Observer.
SOLUTIONS
Giving the rotation for one decimeter, for one gram of active substance
in one cubic centimeter of solution .
Temp . Observer .
Active substance. Solvent. | Spec. rot.
Solids
181
HANDBOOK OF CHEMISTRY AND PHYSICS
MAGNETO OPTIC ROTATION
a
Verdet' s Constant: P
tH cos 0
The specific power of magnetic rotation p, is expressed in the above
formula , where a is the total angle of rotation in minutes, t the thickness
of the substance in centimeters, H the magnetic field intensity in gausses
and o the angle between the direction of the magnetic field and the path
of light.
SOLIDS
For sodium light.
(Values from the Smithsonian Tables. )
LIQUIDS
For sodium light.
Verdet' s
Substance . Density Temp.
C . Constant, Observer .
g / cm . 3 minutes.
GASES
For sodium light.
Verdet' s
Substance . Pressure. Temp. constant, Observer .
minutes.
B RAYS
The B rays are similar to the cathode rays produced by an
electric discharge in a vacuum tube. They are judged to be
negatively charged particles moving with high velocity . They
are much more penetrating than the a rays, and are strongly
deviated by a magnetic or electric field . The velocity of the
moving particle is in the neighborhood of that of light, about
2X1010 cm . / s . The charge on each particle is approximately
4 . 7 X 10 - 10 electro static units .
y RAYS
The y rays are similar to the X rays and are not deviable
by magnetic or electric fields. They are more penetrating than
either the a or B rays, and are considered to be of the nature
of wave pulses in the ether .
RÖNTGEN RAYS
SCALE OF HARDNESS
The “ radiochrometer ” of Benoist consists of a disk of silver
0 .11 mm . thick , which is surrounded by 12 sectors of aluminum
ranging in thickness from 1 to 12 millimeters. The sector
which shows the same absorption as the central disk gives the
degree of hardness according to Benoist. The relation of this
to other scales is shown below .
Benoist .. . . . . . . . . ...
. . .. . . 2 3 4 5 6 7 8
Wehnelt . . . . . . . . . . . . . . . 1 . 8 2- 5 6 .5 7.5 8 9 10 - 11
Walter . . 2. 0 - 3 4 -5 5 -6 6 6 -7 7 7 -8
The absorption of rays is very nearly proportional to the
mass of substance penetrated .
181
SUBSTANCES
RADIOACTIVE
.IAlist
products
transformati
and
substances
radioactive
recognized
fully
the
,eof
series
each
is
product
nach
ishe
.T
preceding
substance
the
from
1obtained
also
gives
(2)table
emitted
rays
t
period
,transformati
he
hat
he
:ict
prod
active
half
for
taken
time
(3)the
and
change
undergo
to
,t
constant
radioactive
active
of
proportion
he
he
.
second
each
change
undergoes
which
matter
.
Substance ,etc
.Properties Transformation Radioactive
.
Rays . iod
per .constant
I.l'ranium ,238
weight
.5Atomic .5X109
yrs
IIanium
.['r .(?)2X106
yrs
. . . . . . . . Chemically
X.
Uranium separated
uranium
.from days
18 -73.X10
.
Ionium .(?)25X105
yrs
.
Radium ,from
barium
to
similar
Metal
is
it
which
of
crystallization
fractional
by
separated
.Atomic
chloride
or
bromide
the
weight
226
.5 a,B .
yrs
1750 –1.3X110
.
radium
from
Emanation high
of
gas
Inert
weigh
given
molecular
t
.
salts
radium
by
off a
3.8days -62.1x10
A.
Radium Deposited
exposed
bodies
of
surface
the
on
,concentrated
emanation
to
the
on
cathode
an
in
field
Velectric
. olatile
at
C.
900°
to
800
about 3minutes –3.85
X10
B.
Radium 600
to
at
vradium
Origin
A,as
ofolatile
C.
700° minutes
19 -4.33
X10
C.
Radium A,volatile
radium
of
as
ahOrigin
at
igher
B.
radium
than
temperature minutes
14 -45.9X10
C.Radium 1 inute
m
D.
Radium 1000°
vbelow
olatile
Soluble
,C.in
acids y16
.5 rs -91.3X10
HANDBOOK OF CHEMISTRY AND PHYSICS
E.
Radium -volatile
C.Non
1000°
at . . . . . . . . : :
4days 6-1.X10
F.
Radium acid
an
from
bismuth
or
silver
on
Deposited
Isolution
ndentical
with
.polonium days
136 X
8–.75 10
RADIO ACTIV
ANCES
ontinue
)(CSUBST d E
etransform
lproducts
recognize
radioacti
substance
of
fully
,Iand
theseries
each
is
.ist
nach
Aproduct ve
dsat
period
t ishe
transform
obtained
substanc
preceding
T(2)1gives
the
.from hat
emitted
,rays
table
also he eat
radioacti
constant
active
the
active
change
to
,a
proportio
of
taken
time
the nd
product
half
for
(3)undergo ve
n
second
each
change
.
which
matter
undergoe s
,e.Propertie .
Rays Transformation Radioactive
.Substance tc s . iod
per .Constant
.Actinum rays
No
HANDBOOK
.Radioactinum B,a 5d
.•19ays X -7.04 10
XActinum da
10 ys 7-.6 10
X
of
Emanation
.actinum radium
similar
properties
of
those
to
Gas
.emanation .9s
3 econds .17
AActinum 0.002
second .350
B
Actinum the
with
correspo
mem s
Analogounding minutes
36 3X
.0-4 10
CActinum of
bers
radium
the
group 1minute 3X
–5.4 10
Actinum
D By 4.7minutes 3X
-2. 10
Tho
. rium weight
.,2Atomic
32 2X1010
years
1.tho
Mesriuom rays
No 4years
2.tho
Mesriu
o m B,v h
4.5 ours
Rad
tho io m
. riu 2years
Tho )?(b,a d
3.6 ays X
2. 10
..X rium
Emanatio
of
.thorium n seconds
38 X10
1.31
OF CHEMISTRY AND
.orium . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
AThorium .14
second
BThorium corresponding
Analogous
members
of
to 11
hours X
1.8 10
CThorium actinum
the
radium
and
groups minutes
55 4-2.1X10
D
Thorium B,y 3.1minutes 3X
-.7 10
yes á
Pot
. assium weight
9
.1,3Atomic
Rub
PHYSICS
.. idium weight
5
.1,8Atomic
re
from
compiled
above
Debierne
Rutherford
vby
:Talues
Note
are
data
,Cresults
.given
and
urie
he The
others
figures
approximate
only
considered
be
.can
HANDBOOK OF CHEMISTRY AND PHYSICS
DECLINATION OF THE SUN AND EQUATION OF TIME
Decli Diff. Equation Decli- | Diff . Equation
Bwerder
Date . nation . | 1 day . of time. Date . nation . 1 day . of time.
o
m S
S
Jan . - 23 .1 0 . 11 + 3 15 + 22 . 4 0 . 15 49
19
! ! ! ! !
- 22 . 0 10. 18 + 20 . 9 0 . 21
+ + + + +
12 29 0 . 26 13
20 . 2 0 . 25 + 18 . 8
AONA
3
ONAO
17 . 7 0 . 30 8 + 16 . 2 0 . 30 27
Feb . 14 . 7 | 0 . 34 + 13 . 2 0 . 34 44
WWN
11 . 3 o 37 9.8 0 . 36
Door
15
0 . 38
7.6 0 . 39
+ + ! ! !
Mar .
+ ! ! ! !
1 96
3. 8 0 . 39
il+.
0 . 2 23 27
4
0 . 38
4 . 1 0 . 38
-
2
Apr. + 7. 9 0 . 35 17 - 9. 2 0 . 35
+ 11 . 4 0 . 33 27 12 . 7 0 . 32
+ 14 . 7 0 . 29 0 . 26
! ! ! !
May + 17 . 6 0 . 23 18 . 7 0 . 22
+ 19 . 9 0 . 18 20 . 9 10 . 16
ANNNNWCHA
(From Young's General Astronomy, by permission .)
34 50 47 . 7 39 . 5
35
A
24 . 5 1 22 . 1
04 . 4 40 08 . 6
27 . 0 45 57 . 6
37 48 . 3
45 55 . 5 40 . 3
23 37 . 0 33 . 2
21 . 6 26 . 8
29 08 . 6 20 . 9
5 49 57 . 6 10 . 2
5 16 48 . 0 0 .0
For every 5° F . by which the temperature is less than 50° F ., ald one
per cent to the tabular refraction , and decrease it in the same ratio for
temperatures above 50° F .
Increase the tabular refraction by three and a half per cent for every
inch of barometric pressure above 29 .6 inches, and decrease it in the same
ratio below that point. These corrections for temperature and pressure ,
though only approximate , will give a result correct within 2" except in
extreme cases.
DATA IN REGARD TO THE EARTH
(Radius, U . S . C . & G . Survey .)
Equatorial radius, 6 ,378,388 meters, 3 ,963.399 miles.
Polar radius, 6 , 365,909 meters, 3 ,949.992 miles .
1° latitude at the equator = 68.70 miles.
1° latitude at the pole = 69.41 miles.
Mean density of the earth , 5 .52 g . per cu .cm .
Mean distance from the earth to the sun
149,500 ,000 kilometers,
92 ,900 ,000 miles.
Mean distance from the earth to the moon
384,393 kilometers,
238 ,854 miles.
DATA CONCERNING THE SOLAR SYSTEM
(Values from Young's General Astronomy, by permission.)
Mean dis. Mass , Mean
from sun , Period in Mean dia .
Name. the earth density .
millions years . in miles.
of miles.
= 1. water = 1 .
METEOROLOGICAL DATA
THE ATMOSPHERE
Total mass, estimated by Elkholm :
5 . 2 X1021 grams.
11 . 4 X1018 pounds.
Composition :
The total volume = 1 .
Elevation .
Substance .
Sea level. 10000 meters. 50000 meters.
ATMOSPHERIC POTENTIAL
The potential of the atmosphere increases with the elevation
130 to 200 volts per meter.
SOLAR CONSTANT
The energy falling on one sq .cm . area at normal incidence
equals 1 .92 small calories per minute .
189
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194
HANDBOOK OF CHEMISTRY AND PHYSICS
MISCELLANEOUS CONSTANTS
Mean radius of the earth , 6 . 371 X 108 cm . = 6371 kilometers .
1 degree of latitude at 40° = 69 miles.
1 knot or nautical mile = 1 ' of arc on the earth' s surface at
the equator.
Mean density of the earth , 5 .52 grams per cu . cm .
Constant of gravitation , K = 6 .667 X10 – 8 = the attraction in
dynes between two gram masses one centimeter apart.
Acceleration due to gravity at sea level, lat. 45º = 980.60 cm .
per sec. per sec . = 32 .172 feet per sec . per sec .
Length of seconds pendulum at sea level, lat. 45º = 99.356
cm . = 39.116 in .
Density of mercury at 0° C . = 13.5955 g . per c .Co
Density of water, maximum at 3 .98° C . = 0 .999973 g . per c .c .
Density of dry air at 0° C . and 760 mm . = .001293 g. per c .c .
Velocity of sound in dry air at 0° C ., 33 ,136 cm . per sec. = 1089
feet per sec.
Velocity of light in a vacuum = 2 .9989 X 1010 cm . per sec. =
984 X106 feet per sec.
Heat equivalent of fusion of water 79 .24 cal. per gram .
Heat equivalent of vaporization of water, 535 .9 cal. per gram .
Coefficient of expansion of gases, .003665 .
Specific heat of air, at constant pressure, 0 .238 ,
Electrochemical equivalent of silver, 0 .001118 g . per sec . per
ampere.
Mean wave length of sodium light, .00005893 cm . or 5893.
ångström units.
Absolute wave length of red cadmium line in air , 760 mm .
tabtax
Alpha Nu
BB Beta Xi
Iy Gamma Omicron
AS Delta Pi
EE Epsilon Rho
ZE Zeta Sigma
Η η Eta Tau
ⓇO Theta Upsilon
Ιι Iota Phi
К к Kappa Chi
Λλ Lambda Psi
Mv Mu Omega
DEFINITIONS AND FORMULÆ
FUNDAMENTAL CHEMICAL LAWS
Scientific laws are statements of facts which have been estab
lished by direct experiment.
Boyle's Law for Gases. - At a constant temperature the vol
ume of a given quantity of any gas varies inversely as the pressure
to which the gas is subjected . This idea is expressed in the fol
lowing formulæ :
PV = a constant, or P = 1 / V , or V = 1 / P , or PV = P Vi
The Law of Combining Weights. - If the weights of elements
which combine with each other be called their “ combining
weights," then elements always combine either in the ratio of
their combining weights or of simple multiples of these weights.
Law of Definite Proportions. - In every sample of each com
pound substance the proportions by weight of the constituent
elements are always the same.
Dalton ' s Law of Partial Pressures. — The pressure exerted by
a mixture of gases is equal to the sum of the separate pressures
which each gaswould exert if it alone occupied the whole volume.
This fact is expressed in the following formula :
PV = V (pı + p: + ps, etc.)
Faraday 's Law . — The amounts of decomposition effected by
the passage of equal quantities of electricity through them are,
for the same electrolyte , equal, and for different electrolytes are
proportional to the combining weights of the elements or radicles
which are deposited .
Gay -Lussac' s Law forGases (or Charles ' Law ) . – At a constant
pressure, the volume of a given quantity of any gas increases
about 1 / 273 of its volume at 0° C . for each rise of 1º-C . and at
constant volume the pressure of a given quantity of any gas
increases about 1 / 273 of the pressure at 0° C . for each rise of
Gay -Lussac' s Law of Combining Volumes. - If gases interact
and form a gaseous product , the volumes of the reacting gases
and the volumes of the gaseous products are to each other in .
very simple proportions, which can be expressed by small whole
numbers .
Hess' Law of Constant Heat Summation . The amount of
heat generated by a chemical reaction is the same whether
reaction takes place in one step or in several steps, or all chemical
reactions which start with the same original substances, and end
with the same final substances, liberate the same amounts of
heat, irrespective of the process by which the final state is
reached .
Henry's Law . — The amount of gas which a liquid will dissolve
is directly proportional to the pressure of the gas. This holds
for all gases which do not unite chemically with the solvent.
196
HANDBOOK OF CHEMISTRY AND PHYSICS
The Law of Mass Action . – At a constant temperature the
product of the active masses on one side of a chemical equation
when divided by the product of the active masses on the other
side of the chemical equation is a constant, regardless of the
amounts of each substance present at the beginning of the action .
Law of Multiple Proportions. — Two elements may combine
in more than one proportion by weight, but if so , the weights of
one element which combine with a fixed weight of the other
element, are always in a simple ratio to each other.
The Periodic Law . – The physical and chemical properties of
the elements are functions of their atomic weights , and most
of these properties are periodic functions of the atomic weights.
Heat
Temperature. — The condition of a body which determines
the transfer of heat to or from other bodies. The unit of tem
perature is the Centigrade degree, 1 / 100 the difference in tem
perature between that of melting ice and boiling water at 76
centimeters pressure . The degree Fahrenheit is 1 / 180 and the
degree Reaumur is 1 / 80 the above-mentioned difference of
temperature . .
· Heat Quantity is measured by the change of temperature
produced . The unit of heat is the calorie , the quantity of heat
necessary to change the temperature of one gram of water from
3 .5° C . to 4 .5° C . (called a small calorie ). If the temperature
changed involved is from 14 . 5 to 15 . 5° C . the unit is the normal
calorie . Themean calorie is 1 / 100 the quantity of heat necessary
to raise one gram of water from 0° C . to 100° C . The large
calorie is equal to 1000 small calories. The British thermal unit
is the heat required to raise the temperature of one pound of
water at its maximum density, 1° F . It is equal to 252 calories.
Coefficient of Thermal Expansion . — The coefficient of linear
expansion is the ratio of the change in length per degree to the
length at 0° C . The coefficient of surface expansion is two
times the linear coefficient. The coefficient of volume expan
sion (for solids) is three times the linear coefficient. The co
efficient of volume expansion for liquids is the ratio of the change
in volume per degree to the volume at 0° C . The value of the
coefficient varies with temperature . The coefficient of volume
expansion for a gas under constant pressure is nearly the same
for all gases and temperatures and is equal to 0 .00367 for 1° C .
Absolute Zero. — The temperature at which a gas would show
no pressure if the general law for gases should hold for all tem
peratures . It is equalto – 273° C . or – 459. 4° F .
Specific Heat. - The quantity of heat necessary to cause a
unit change of temperature in unit mass measured in C . G . S .
units as calories per gram per degree centigrade.
Thermal Capacity or Water Equivalent. — The total quantity
of heat necessary to raise any body or system unit temperature ,
measured as calories per degree centigrade in the C . G . S . system .
Heat Equivalent, or Latent Heat, of Fusion . - - The quantity
of heat necessary to change one gram of solid to a liquid with
no temperature change .
Latent Heat of Vaporization . — The quantity of heat necessary
to change one gram of liquid to vapor without change of tem
perature. Both the above quantities are measured as calories
per gram .
Thermal Conductivity . - Time rate of transfer of heat by
conduction , through unit thickness, across unit area for unit
difference of temperature. It is measured as calories per
second per square centimeter for a thickness of one centimeter
and a difference of temperature of 1° C .
Mechanical Equivalent of Heat is the quantity of energy
204
ILANDBOOK OF CHEMISTRY AND PIIYSICS
which , when transformed into heat, is equivalent to unit quan
tity of heat, 4 . 18 X 107 ergs = 1 calorie (20° C .) .
Isothermal. — When a gas passes through a series of pressure
and volume variations without change of temperature the
changes are called iosthermal. A line on a pressure -volume
diagram representing these changes is called an isothermal line .
Adiabatic. - A body is said to undergo an adiabatic change
when its condition is altered without gain or loss of heat. The
line on the pressure -volume diagram representing the above
change is called an adibatic line.
Entropy . - A quantity depending on the quantity of heat
in a body and on its temperature, which , when multiplied by
any lower temperature (minimum available ) , gives the unavail
able energy or unavoidable waste when mechanical work is
derived from the heat energy of the body .
Absolute Humidity . - Mass of water vapor present in the
atmosphere measured as grams per cubic meter .
Relative Humidity . — The ratio of the quantity of water vapor
present in the atmosphere to the quantity which would saturate
at the existing temperature.
Wave Motion and Sound
Wave Motion . -- A progressive disturbance propagated in a
medium by the periodic vibration of the particles of the medium .
Transverse wave motion is that in which the vibration of the
particles is perpendicular to the direction of propagation . Longi
tudinal wave motion is that in which the vibration of the parti
cles is parallel to the direction of propagation .
Pitch of sound is determined by the frequency or number
of vibrations per second.
Intensity or loudness of a sound increases or diminishes with
the amplitude of the vibrating air particles at the ear.
Quality or timbre of a sound depends on the coexistence
with the fundamental of other vibrations of various frequencies
and amplitudes.
Lissajou' s Figures. — The path described by a particle which
is simultaneously displaced by two simple harmonic motions
at right angles, when the periods of the two motions are in the
ratio of two small whole numbers, shows a variety of character
istic curves called Lissajou 's figures.
Beats . - Two tones of slightly different frequencies sounded
together interfere to give a sound of regularly varying intensity .
The number of beats per second is the difference in frequency
of the two tones.
Static Electricity
Unit Quantity of electricity or charge is the quantity which ,
when concentrated at a point and placed at unit distance from
an equal and similarly concentrated quantity, is repelled with
unit force. If the distance is one centimeter and the force
of repulsion one dyne and the surrounding medium a vacuum ,
205
HANDBOOK OF CHEMISTRY AND PHYSICS
we have the electrostatic unit of quantity . The coulomb =
3X10 ' electrostatic units .
Line of Force. - A line such that its direction at every point
is the same as the direction of the force which would act on a
small positive charge placed at that point. A line of force is
supposed to start from a positive charge and end on a negative
charge .
Conductors. - A class of bodies which are incapable of support
ing electric strain . A charge given to a conductor spreads to
all parts of the body.
Dielectrics or Insulators or Non -Conductors. -- A class of
bodies supporting an electric strain . A charge on one part
of a non -conductor is not communicated to any other part .
Electric Surface Density. - --Quantity of electricity per unit area .
Intensity of Electric Field is measured by the force exerted
on unit charge. Unit field intensity is the field which exerts
the force of one dyne on unit positive charge .
Electric Potential at any point is measured by the work
necessary to bring unit positive charge from an infinite distance .
Difference of potential between two points is measured by the
work necessary to carry unit positive charge from one to the
other. If the work involved is one C . G . S . unit of work we
have the electrostatic unit of potential.
Electromotive Force. - The same as difference of potential,
a term commonly used in current electricity . The volt is the
electromotive force which performs work at the rate of one
joule per second (one watt) in producing a current of one ampere.
À watt hour is the work equivalent to a current of one ampere
at a pressure of one vodt flowing for one hour. A kilowatt hour
equals 1000 watt hours. A volt equals 108 electrostatic units
of potential.
Capacity is measured by the charge which must be communi
cated to a body to raise its potential one unit. Electrostatic
unit capacity is that which requires one electrostatic unit
of charge to raise its potential one electrostatic unit. The
farad = 9X1011 electrostatic units.
Specific Inductive Capacity. — The ratio of the capacity of a
condensor with a given substance as dielectric to the capacity
of the same condensor with air or a vacuum as dielectric is called
the specific inductive capacity .
Magnetism
Unit Magnetic Pole or Quantity of Magnetism . - Two unit
quantities of magnetism concentrated at points unit distance
apart in a vacuum repel each other with unit force. If the dis
tance involved is one centimeter and the force one dyne the
quantity of magnetism at cach point is one C . G . S . unit of
magnetism .
Surface Density of Magnetism .---Quantity of magnetism
per unit area .
Magnetic Line of Force is a line which at every point has the
direction of the magnetic force at that point.
206
HANDBOOK OF CHEMISTRY AND PHYSICS
Magnetic Field Intensity is measured by the force acting
on unit magnetic pole . The unit of magnetic field intensity,
the gauss, is that field which exerts a force of one dyne on unit
magnetic pole .
Magnetic Moment of a magnet is given by the product of
the quantity of magnetism in each pole by the distance between
the poles.
Intensity of Magnetization is given by the quotient ofmagnetic
moment of a magnet by its volume or it is magnetic moment
per unit volume.
Declination . - The angle between the vertical plane contain
ing the direction of the earth 's field at any point and a plane
containing the geographic north and south meridian .
Dip. -- The angle measured in a vertical plane between the
direction of the earth 's magnetic field and the horizontal.
Paramagnetic bodies are those which tend to set the longest
dimension parallel to the magnetic field , e.g ., iron , cobalt , nickel.
Diamagnetic bodies tend to set the longest dimension across
the magnetic field , e . g ., bismuth .
Hysteresis . — The magnetization of a sample of iron or steel
due to a magnetic field which is made to vary through a cycle
of values, lags behind the field . This phenomenon is called
hysteresis.
Current Electricity
Electric Current. — The rate of transfer of electricity . The
transfer at the rate of one electrostatic unit of electricity in one
second is the electrostatic unit of current. The electromagnetic
unit of current is a current of such strength that one centimeter
of the wire in which it flows is pushed sideways with a force
of one dyne when the wire is at right angles to a magnetic field
of unit intensity . The practical unit of current is the ampere,
a transfer of one coulomb per second .
Conductivity . - A property of electric conductors depending
on their dimensions, material and temperature which deter
mines the current produced by a given electromotive force.
The practical unit of conductivity is the mho, the reciprocal of
the ohm .
Resistance. The reciprocal of conductivity . The unit of
resistance, the legal ohm is defined as the resistance to an
unvarying current of a column of mercury at 0° C ., 14 . 4521
grams in mass , of a constant cross-section , and 106 . 3 centi
meters long. The cross-section is nearly one square millimeter.
Specific Resistance. — The resistance at 0° C . of a portion of .
substance of unit length and cross-section .
Temperature Resistance Coefficient. — The ratio of the change
of resistance in a wire due to a change of temperature of 1° C .
to its resistance at 0° C .
Induction . - Any change in the intensity or direction of a
magnetic field causes an electromotive force in any conductor
in the field . The induced electromotive force generates an
induced current if the conductor forms a closed circuit.
207
· HANDBOOK OF CHEMISTRY AND PHYSICS
Self - Induction . - The change in magnetic field due to the
variation of a current in a conducting circuit causes an induced
electromotive force in the circuit itself. This phenomenon is
-
--
known as self- induction . It is measured as electromotive force
-
produced in a conductor by unit rate of variation of the current
--
through it. Units of self- induction are the centimeter (electro
static ) and the henry , which is equal to 109 centimeters of in
ductance .
Mutual Induction . - A change of current in a conductor is
accompanied by a change of magnetic field which induces an
electromotive force in a neighboring circuit . The mutual
induction is measured by the electromotive force induced in
one circuit by unit rate of variation of current in the other .
Units, as of self - induction .
Light
Index of Refraction for any substance is the ratio of the
velocity of light in a vacuum to its velocity in the substance .
It is also the ratio of the sine of the angle of incidence to the
sine of the angle of refraction . In general, the index of re
fraction for any substance varies with the wave length of the
refracted light .
Minimum Deviation . — The deviation or change of direction
of light passing through a prism is a minimum when the angle
of incidence is equal to the angle of emergence .
Principal Focus of a lens or spherical mirror is the point of
convergence of light coming from a source at an infinite distance.
Conjugate Foci. — Under proper conditions light divergent
from a point on or near the axis of a lens or spherical mirror is
focused at another point. The point of convergence and the
position of the source are conjugate foci.
Spherical Aberration . — When large surfaces of spherical
mirrors or lenses are used the light divergent from a point
source cannot be exactly focused at a point. The phenomenon is
known as spherical aberration .
Chromatic Aberration . - Due to the difference in the index
of refraction for different wave lengths, light of various wave
lengths from the same source cannot be focused in a point by
a simple lens. This is called chromatic aberration .
Acromatic . - A term applied to lenses signifying their more
or less complete correction for chromatic aberration .
Magnifying Power of an optical instrument is the ratio of
the angle subtended by the image of the object seen through
the instrument to the angle subtended by the object when seen
by the unaided eye at a distance of 25 cms. (10 ins.)
Resolving Power of a telescope or microscope is indicated
by the minimum separation of two objects for which they appear
distinct and separate when viewed through the instrument.
Angular Aperture of an objective is the largest angular extent
of wave surface which it can transmit .
Numerical Aperture is the sine of half the angular aperture ,
used as a measure of the optical power of the objective.
208
HANDBOOK OF CHEMISTRY AND PHYSICS
Dispersion . The difference between the index of refraction
of any substance for any two wave lengths is a measure of the
dispersion for these wave lengths, called the coefficient of dis
persion .
Diffraction . - If the light source were a point the shadow of
any object would have its maximum sharpness ; a certain amount
of illumination, however, would be found within the geometrical
shadow due to the diffraction of the light at the edge of the
object.
Polarized Light. — Light which exhibits different properties
in different directions at right angles to the line of propagation
is said to be polarized . Specific rotation is the power of liquids
to rotate the plane of polarization . It is stated in terms of
specific rotation or the rotation in degrees per decimeter per
unit density .
PHYSICAL FORMULÆ
Mechanics
Composition of Vectors. - If the angle between two vectors is
A , and their magnitudes a and b, their sum ,
( = Vap + bº + 2ab cos A .
Velocity . - If s is space passed over in time t, the velocity,
A = 91 - 00
tan 0 = 25X .
Elastic Coefficients
Young's modulus by stretching. - If an elongations is pro
duced by the weight of the mass m , in a wire of length l, and
radius r , the modulus,
NI - mg]
aris '
Young 's modulus by bending, bar supported at both ends.
If a flexure s is produced by the weight of mass m , added midway
between the supports separated by a distance l, for a rectangular
bar with vertical dimensions of cross-section a and horizontal
dimension b , the modulus is ,
Mmg/3
M = Asub:
For a cylindrical bar of radius r,
M = mg/3
127145
213
HANDBOOK OF CHEMISTRY AND PHYSICS
For a bar supported at one end . In the case of a rectangular
bar as described above,
M = 4msag1
3
3
For a round bar supported at one end ,
: - M = 4mg/3
* 3arts
Modulus of Rigidity. - If a couple C ( = mgx ) produces a
twist of e radians in a bar of length I and radius r, the modulus is
M = 2C1
Tr40
Coefficient of Restitution . — Two bodies moving in the same
straight line with velocities vi and v2 respectively, collide and
after impact move with velocities V3 and V4. The coefficient
of restitution is
C = V4 —V3
V2 - vi
Viscosity . - Flow of liquids through a tube; where l is the
length of the tube, r its radius, t the difference of pressure at
the ends, n the coefficient of viscosity, the volume escaping
per second,
pre
Vv = Bln (Poiseuille.)
T = "hD !
Pressure . — The pressure due to a force F distributed over
an area A ,
PA
Hydrostatic pressure on an area A at a distance h from
the surface of a liquid of density D is,
F = PA (total pressure ) = AhDg.
Archimedes' Principle. — A body of volume V immersed in
a liquid of density D is buoyed up by a force
F = DgV.
Velocity of Efflux of a Liquid . - If h is the distance from the
opening to the free surface of the liquid , the velocity of
efflux is
V = V2gh .
Diminution of Pressure at the Side of a Moving Stream .
If a fluid of density d moves with a velocity v the diminution
of pressure due to the motion is (neglecting viscosity) ,
p = hdg = dv2.
Boyle's Law . -- For a perfect gas, changing from pressure p
and volume v to pressure p ' and volume u without change of
temperature,
purp'v'.
Altitudes with the Barometer . - If b , and b2 denote the cor
rected barometer readings at two stations , t the mean of the
temperatures ti and t2 of the air at the two stations, e , and (2,
the tension of water vapor at the two stations, h the mean height
above sea level, o the latitude, then the difference in elevation
in centimeters is
H = 1,843,000 (log ba – log b2) (1 + 0.00367t) (1 + 0.0026 cos 20
+ 0 .00002h + 3k ),
where
Heat
Thermal Expansion . If lo is the length at 0° C ., a the
the coefficient of linear expansion, the length at t° C . is,
le = l. (1 tat).
General Formula for Thermal Expansion . — The rate of
thermal expansion varies with the temperature . The general
equation giving the magnitude mt (length or volume) at a
temperature t, where mo is the magnitude at 0° C ., is
me= mo(1 + at + ßt? + yt3 . . .) :
where a , b , y , etc., are empirically determined coefficients.
Volume expansion . If V represents volume and B the coeffi
cient of expansion,
Ve = V /( 1 + Bi).
For solids, B = 3a (approximately ).
Expansion of Gases. - For an original volume V , at 0° C .
the volume at t° C . (at constant pressure) is
Ve = V (1 + 0.003671).
General Law for Gases:
pur=prov'o(1+ 273)
Reduction of a Gas Volume to 0°C ., 760 mm . Pressure. If
V is the original volume of a gas at temperature t and pressure
p the volume at 0° C . and 760 mm . pressure will be,
V H
Vo = (1 +al) 760
If d is the original density the density at 0° C . and 760 mm .
pressure will be,
. do = d(1 + at) '.
a = 0.00367 approximately .
Gas Thermometer. - Where Po, Ps, and Px represent the total
pressures with the bulb at 0° C ., at the boiling -point of water
and at the unknown temperature respectively , ts the tem
perature of steam and tx the unknown temperature ,
, Pr - P ,
to = lsPs - P .
(approximately ). The total pressure on the gas in the bulb
is the sum of barometric pressure at the time and that measured
by the manometer.
216
HANDBOOK OF CHEMISTRY AND PHYSICS
Specific Heat. - If a quantity of heat H calories is necessary
to raise the temperature of a grams of a substance from ti
to t2° C ., the specific heat,
H
m (t2 — 41)
Specific Heat by the Method of Mixtures. Where a mass
mi of the substance is heated to a temperature ti, then placed
in a mass of water m2 at a temperature to contained in a cal
orimeter with stirrer (of same material) of mass m3, specific
heat of the calorimeter c , v the volume of the immersed portion
of the thermometer, tz the final temperature, the specific heat
of the substance ,
_ (m2 + mzc + 0 .46v) (t3 - ta)
s =
mi(t1 – 13)
Black 's Ice Calorimeter. - If a body of mass m and tem
perature t melts a mass m ' of ice , its temperature being reduced
to 0° C ., the specific heat of the substance is,
80. lan ”
s =
mt
V = ^ =n .
Velocity of a transverse wave in a stretched cord . If T is
the tension of the cord and m the mass per unit length ,
V = mi
217
HANDBOOK OF CHEMISTRY AND PHYSICS
Velocity of Sound. — In terms of elasticity (bulk modulus)
E and density d ,
V= V
Frequency of Vibrating Strings. - For a string of length 1,
tension T , density d , and radius r, the frequency is,
m _ 1 IT
n = rin ad
.n = (fundamental.)
In an open pipe,
n = ž (approximate.)
Velocity of sound in air at a temperature t,
V = 33,136 +60.7 cm . per sec.
Static Electricity
Force between Two Charges. --If two charges q and q' are
at a distance r in a vacuum , the force between them is,
HD
If the dielectric in the above cases is not a vacuum the
dielectric constant K must be introduced . The formulæ
become,
C= .
Capacity of a spherical conductor of radius r ,
C = Kr.
Capacity of two concentric spheres of radii r and pl,
C - KA
41d
Magnetism
Force between Two Magnetic Poles. - If two poles of strength
m and m ' are separated by a distance r in a medium whose
permeability is u (unity for a vacuum ) ,the force between them is
+ - mm '
ur ?
H= m
Magnetic Moment.-- If the poles are separated by a distance
which is great compared with the dimensions of the magnet,
the magnetic moment of a magnet of length 1 whose poles have
values of + m and – m is ,'
M = ml.
Couple acting on a magnet of magnetic moment ml in a
field of strength H . If the magnet is perpendicular to the
direction of the field ,
C = Hml =HM .
If the angle between the magnet and the field is 0,
C = IIml sin 0 .
219
HANDBOOK OF CHEMISTRY AND PHYSICS
i Action of One Magneton Another. — The turning moment
experienced by a magnet of pole strength m ' and length 21
placed at a distance r from another magnet of length 21 and
pole strength m , where the center of the first magnet is on the
axis (extended ) of the second and the axis of the first is per
pendicular to the axis of the second ,
C' — mm 'll' 2MM
- 3 p3
The susceptibility ,
B = 7I + 411.
A = N = 1 + 47K .
R
Current in a Simple Circuit. The current in a circuit including
an external resistance R and a cell of electromotive force E ,
and internal reistance i ,
E
i= Rti
220
HANDBOOK OF CHEMISTRY AND PHYSICS
For two cells in parallel,
i=
R+
For two cells in series ,
2E
i = R + 27
Resistance of a conductor at 0° C ., of length 1, cross -section
s and specific resistance p , .
Ro = ps
Resistance of a conductor at a temperature t whose resistance
at 0° C . is R , and whose temperature resistance coefficient is a ,
Re = Ro(1 + at).
Resistance of Conductors in Series and Parallel. -- The total
resistance of any number of resistances joined in series is the
sum of the separate resistances. The total resistance of con
ductors in parallel whose separate resistances are ri, r2, 13,
. . . rn is given by the formula
1 = 1- + 1- + 1- . . 1
R 11 . 12 13 T
12
" or "1=
13
"?
14 1'3
m = cit.
Light
Spherical Mirrors . - If R is the radius of curvature, F
principal focus, and fi and f2 any two conjugate focal distances,
1 , 1 _12
Fif2F - R
Lenses. - For a single thin lens whose surfaces have radii
of curvature rı and r2, whose principal focus is F , the index
of the fraction n and conjugate focal distances fi and fa,
1 - fitfai
1 + 1 =(n - 1) (4 + )
Radius of Curvature from Spherometer Readings. - If I is the
mean length of the sides of the triangle formed by the points
of the three legs, d the spherometer reading, the radius of cur
vature of the surface is
R = 6d +
Index of Refraction . If i is the angle of incidence, r the
angle of refraction, v the velocity of light in the first medium ,
' the velocity in the second medium , the index of refraction ng
sin i v
" * sin r =
For a prism of angle A where light passes at the angle of
minimum deviation D , the index of refraction ,
sin } ( A + D )
n =
sin A
222
HANDBOOK OF CHEMISTRY AND PHYSICS
Reflection of Light by a Transparent Medium in Air . (Fresnel's
Formula ) . - If i is the angle of incidence, r the angle of refrac
tion , ni the index of refraction for air (nearly equal to unity ) ,
Na index of refraction for a medium , then the ratio of the reflected
light to the incident light is, '
R - 1 sin ? (i – r ) tan ? (i - r) 7
* 2 ( sin ” (i + r) * tan (i + r) ]
If i = 0 (normal incidence), and ni = ] (approximate for
air ),
R = 07371)"
Diffraction Grating. - If s is the distance between the rulings,
d the angle of diffraction , then the wave length where the
angle of incidence is 90° is (for the nth order spectrum ),
ssin d
п
If i is the angle of incidence, d the angle of diffraction , s the
distance between the rulings, n the order of the spectrum ,
the wave length is,
1 = (sin i + sin d ).
Specific Rotation . If there are n grams of active substance
in v cubic centimeters of solution and the light passes through
1 centimeters, r being the observed rotation in degrees, the
specific rotation (for 1 centimeter),
[a] = ?
223
LABORATORY ARTS AND RECIPES
ACID PROOF WOOD STAIN
SOLUTION No. 1
125 grams of copper sulphate
125 grams of potassium chlorate
1000 grams of water
SOLUTION No. 2
150 grams of good fresh anilin oil
180 grams of concentrated hydrochloric acid
1000 grams of water
Wood must be free from paint, varnish , grease or chemicals .
Apply two coats of solution No. 1 boiling hot with a paint brush ,
allowing each coat to dry thoroughly before the next coat is
applied . Then apply two coats of solution No. 2 in the same
way . When the wood is completely dried wash off excess chem
icals with hot soapsuds. Finish with raw linseed oil. Polish
comes from rubbing the oil down well with a cloth or sponge .
Whenever the tables get dingy again go over them with a coat
of linseed oil and rub smooth .
CEMENTS
Glues of all kinds are useful for wood , leather, paper and
glass, where the joints are not required to be waterproof. .
For waterproof joints of nearly all substances, including
metals , shellac may be used . Flakes of solid shellac may be
used with heat or it may be used as a solution in alcohol.
Kotinsky cement, Chatterton 's compound and other resinous
cements are used for similar purposes and in the same way as
solid shellac. Glass cells made up with compounds of this nature
may be made impervious to alcohol by painting over the joints
with a rubber cement made by melting up small pieces of rubber
tubing and adding carbon disulphide to make a thin syrup .
For celluloid a cement made by dissolving celluloid shavings
in acetone is recommended .
Brass fittings are usually cemented on glass tubing with
sealing wax. The glass tube should be wound with thread or
twine to secure a close fit. The glass and the brass fitting
should be warmed slightly above the melting-point of wax.
( Thick , or pressed glass should be warmed slowly .) Wax may
be applied to both parts and the thread well saturated with the
melted wax . Enough should be used to insure filling the space
224
HANDBOOK OF CIIEMISTRY AND PHYSICS
completely . Join the parts while the wax is very soft and clamp
in position until it is thoroughly cold .
For optical purposes, cementing glass , etc., Canada balsam
is universally employed , and makes a permanent and nearly
invisible joint.
CLEANING MERCURY
Mercury may be cleaned sufficiently for many laboratory
purposes without distilling . Allow the mercury to fall in a fine
spray into a quantity of dilute nitric acid , 25 parts of acid to
75 parts distilled water. After being passed through the acid
one or more times it should be passed through distilled water
and dried . Most of the water may be removed with a clean
filter, and the mercury heated in a porcelain dish to about
110° C . To produce the spray the stem of a glass funnel may
be drawn down so as to leave only a small opening for the escape
of mercury or a glass tube with a capillary point attached to a
funnel with a tightly fitting rubber tube.
A three- to four-foot length of one -inch glass tube closed at
one end and supported in a vertical position may be used to
contain the acid solution . If a small glass tube be fused into
the Jower closed end of the large tube, and bent so as to stand
up for a distance a little greater than 1 / 13 . 6 , the column of acid
solution in the large tube, a U -tube is formed in which a short
column of mercury supports the long column of acid solution .
The end of the small tube should be bent over at the top
so as to facilitate the delivery of the mercury and a short piece
of clean rubber tubing with a pinch -cock put on at the start;
as soon as mercury enough has collected in the bottom of the
tube the pinch -cock may be opened . The mercury will rise
nearly or quite to the top of the small tube, and as the quantity
increases will be delivered from the small tube as fast as it falls
in the spray .
The reversed end of the small tube should be short to avoid
forming a siphon , which would completely empty the apparatus.
An efficient procedure , especially if the mercury is greasy ,
consists in spraying the mercury by means of the above appa
ratus, first, through a dilute solution ( 10 % ) of potassium hy .
droxide, then through dilute nitric acid (10 - 15 % ) and finally
through distilled water.
CLEANING OPTICAL SURFACES FOR SILVERING
(From Miller's Laboratory Physics, Ginn & Co ., publishers ,by permission .)
Probably the most important part of the silvering process is
the proper cleaning of the surface to be silvered .
The surface is thoroughly cleaned of grease or other organic
matter by the usual methods, using alcohol or chromic acid .
Then it should be carefully cleaned with strong nitric acid ,
the whole surface being firmly rubbed with pure cotton tied to
a rod of wood or glass. Care should be taken not to injure the
surface . Rinse with water, and then wash the surface thor
oughly with a strong solution of caustic potash , rubbing with a
225
HANDBOOK OF CHEMISTRY AND PHYSICS
cotton brush as before. Finally , rinse with distilled water,
and keep the surface wet until it is placed in the silvering solu
tion . If the distilled water wets the whole surface uniformly
the cleaning may be sufficient; if it does not wet uniformly , the
operations must be repeated . The fingers should not touch
the edges of the glass during the latter cleaning operations,
as a layer of organic matter is apt to spread over the surface
and render the silvering uneven .
Dr. Brashear recommends that the surface, after the washings
described above, be rubbed with prepared chalk on a cotton
wad until it is thoroughly dry and clean . It may then be put
into the silvering solution at one's convenience.
COLORED LIQUIDS
For rendering columns of water easily visible , add a few
drops of one per cent alcoholic solution of fluorescein to a liter
of water. The dilute solution of fluorescein is bright green by
reason of its fluorescence, although colorless by transmitted
light.
A small quantity of an aqueous ( 1 % ) solution of uranine
(the sodium salt of fluorescein ) may be used in place of the
alcoholic solution mentioned above .
If solutions showing color by transmission are desired , dilute
aqueous may be made with any of the following dyes :
Dye Color
Erythrosine Pink
Eosine Pink (green fluorescence )
Rhodamine B Pink (red fluorescence )
Ponceau 2R Scarlet
Naphthol green Green
Methylene green Bluish green
Methylene blue Blue
Methyl violet Purple
CROSS HAIRS
The spider lines which serve as an index in reading telescopes
may be quickly replaced in an emergency by single silk fibers
(from ordinary sewing silk ) attached by soft wax. Single fibers
may easily be removed from an untwisted strand .
Spider web should be used in permanent work . The fibers
of the egg nest of certain species are employed and may be ob
tained of most dealers in scientific apparatus. In mounting
them the following suggestions may be useful: The cross hair
diaphragm of the telescope should be removed and clamped in
a horizontal position . A bow of brass wire, about No. 28 ,
should be employed to stretch the fiber. A background of black
velvet makes the fibers more easily visible . With soft wax
or other convenient adhesive ready on both tips of the bow ,
a fiber of the required length is to be disentangled with tweezers
and wrapped several times about the ends of the bow under
tension sufficient to straighten the fiber . The fiber, now con
226
HANDBOOK OF CHEMISTRY AND PILYSICS
veniently handled by the wire bow , should be cautiously lowered
onto the diaphragm in the proper position , the wire left hanging.
A small drop of shellac varnish applied at each side will hold
the fiber in position as soon as it is thoroughly dry, after which
the ends of the fiber should be cut away .
FLUORESCENT SCREENS )
For observations of the ultra-violet spectrum , moisten a small
quantity of anthracene with water and brush a thin layer over
a ground -glass surface. On drying most of the anthracene will
adhere to the glass. The prepared surface should be placed
so as to receive the radiation directly , glass being comparatively
opaque to the shorter wave lengths.
GLASS -GRINDING FLUID
Turpentine . . . . . . . . . . . . . . . .45 c.cm .
Ether (ethyl oxide). . . . . . 22. 5 c.cm .
Camphor gum . . . . . . . . . . . . . . . . 31 grams
To be used with powdered emery for grinding glass.
For smoothing edges a sheet of emery cloth moistened with
the above solution may be used . .
Plane surfaces should be ground on thick plate glass.
For grinding glass stoppers use coarse emery, turn in one
direction , finish with fine emery .
LABELS FOR BOTTLES
Ordinary gummed labels written upon , preferably , with India
ink ,may be protected after being gummed to the bottle by a coat
of lacquer or varnish . A more complete protection is obtained
by painting the label, after it is in place , with melted paraflin .
MIRRORS FOR SPECTROMETER ADJUSTMENT
A small square of thick plate glass with edges ground smooth
and silvered on one surface affords a means of accurate adjust
ment.
To avoid the necessity of frequently resilvering , which arises
where the mirrors are in constant use , the following course is
suggested :
From selected German plate mirror 2 to 3 mm . thick , cut
two pieces of the same size , say 4 X5 cm . Remove the pro
tective layer of varnish or paint from both pieces by soaking
in alcohol and rubbing with cotton , being careful not to injure
the silver surface. From one piece remove every trace of varnish
by repeated rinsing, dry and polish the silver surface thus exposed
by stroking lightly with a chamois rouge pad . From the other
piece remove the silver by nitric acid , wash thoroughly in dis
tilled water and dry. Cement the clear piece on the silver face
of the other with Canada balsam . This is accomplished by
placing two or three drops of Canada balsam in xylol (ob
tained in collapsible tubes) on the center of the silver face, and
227
ILANDBOOK OF CHIEMISTRY AND PHYSICS
evenly lowering upon it the clear glass . The balsam should
spread rapidly to the edges of the plates. Minute bubbles of
air in the balsam film are harmless; if large bubbles are present
the plates should be slipped apart, cleaned with alcohol and the
process repeated .
The balsam will be sufficiently hard in a few days to allow
the excess to be scraped from the edges and the plates bound
together with lantern slide binding strip . Gentle heat may be
used to harden the balsam more rapidly .
SODIUM LIGHT
Paper is to be soaked in a saturated solution of common salt,
borax or other salt of sodium , and dried . When wrapped around
a Bunsen burner, secured by a twist of wire and pushed up into
the edge of the flame, a sodium flame of considerable intensity
is obtained . As the ash of the paper breaks away it must be
occasionally raised . Lithium chloride may be used in place of
or with sodium salt to give the lithium line for spectrometric
measurement. Sheet asbestos (thin ) may replace the paper if
convenient.
SOLDERS
Composition by weight.
Tem Metals for Flux com
perature which it is
Cop - Zinc. Sil - Goola
ld . of used . monly used .
9 fusion .
Lead . Tin per. ver .
STOPCOCK GREASE
Vaseline . . . . . . . . . 16 parts
Pure gum rubber . . . . . 8 parts
Paro
.. . . . . . . . . . . . . . . . . . . . . . . . . 1 part
Melt all together. More paraffin may be added if the com
pound is not stiff enough .
UNIVERSAL WAX
( 1) A soft wax useful in the laboratory may be made by
melting together paraffin , vaseline and paraffin oil in various
proportions according to the pliability desired .
( 2 ) Another authority recommends equal quantities of bees
wax and turpentine (by weight ). It is customary to color the
wax by adding finely-powdered Venetian red .
(3 ) Melt together 1 part of Venice turpentine and 5 parts of
beeswax. Color with vermilion .
231
MEASURES AND UNITS
WEIGHTS AND MEASURES
U . S . System
LENGTH
12
36 3
198 16 ;
. . . . . . . 5280 1760 320
1 fathom = 6 feet
1 furlong = 40 rods = 660 feet
1 knot or nautical mile = 1 . 15 statute miles = 1' of arc on the
earth 's surface at the equator
1 surveyor's chain = 66 feet = 100 links (each link = 7 . 92 inches)
1 engineer's chain = 100 feet = 100 links
1 mil = .001 inch
AREA
114
1296 . . . . . . . . . . . . . . . . . . . . . .
2721 301
43560 : 4840 160
VOLUJE
1728 cubic inches = 1 cubic foot
27 cubic feet = 1 cubic yard
232
HANDBOOK OF CHEMISTRY AND PHYSICS
WEIGHTS AND MEASURES (Continued )
U . S . System (Continued) .
LIQUID MEASURE
Gills. Pints . Quarts. Gallons. Cubic inches.
28 . 38
57 . 75
4
231 . .
1 hogshead = 63 gallons
1 tun = 252 gallons
1 British imperial gallon = 277. 3 cu.in . = 1 . 2 U . S. gallons
APOTHECARIES' FLUID MEASURE
60
480
7680 128 16
128
DRY MEASURE
67 . 2
537 . 6
2150 . 4
27 . 34
437 . 5
7000 . 256
2000
1 long ton = 2240 lbs. = 20 hundred weight (long )
1 hundred weight (short measure ) = 100 lbs.
1 pound avoirdupois = the mass of 27 . 70 cu . in . of water weighed
in air at 35 . 85° F . barometer pressure 30 of mercury
233
HANDBOOK OF CHEMISTRY AND PHYSICS
WEIGHTS AND MEASURES (Continued )
U . S . System (Continued )
Troy Weight
Grains. Pennyweight. Ounces. Pounds.
24
480 20
5760 240 12
20
60
480 24
5760 288
TIME
- - - -- - -- -
60
3600 60
21
86400 2010
365 . 24 1 (common )
365 . 256 1 ( sidereal)
ANGLE
60
3600 60
...... 360
235
HANDBOOK OF CHEMISTRY AND PILYSIC'S .
MISCELLANEOUS REDUCTION FACTORS
i radians = 180 degrees
1 degree = 0 .017453 radian
1 radian = 57° . 2958 = 3437' . 75 206205 " .
1 sidereal second = 0) . 99727 mean solar second
1 pound per cubic foot = .01602 gram per cubic centimeter
1 foot per second per second = 30 . 4796 cm . per second per second
1 poundal = 13825 dynes
76 cm . of mercury at 0° C . (g . = 980 ) = 1 . 012630 dynes per
sq .cm . or 14 .697 pounds per sq .in .
1 foot-pound (g . = 980 ) = 13 .55 X 106 ergs
1 foot-poundal = 421 . 390 ergs
1 horse power ( g . = 980 ) = 745 . 2 watts
1 mean calorie = 4 . 184 X107 ergs (mechanicalequivalent of heat)
1 B . T . U . = 251. 99 calories.
1 calorie = 0 . 003968 B . T . U .
1 B . T . U . per pound = 0 . 5556 calorie per gram
1 calorie per gram = 1 . 800 B . T . U . per pound
-calorie
.1Gram 401–965313019591
21.44267
-3X10
X10
68
85
87
59
.2BTU 52 .91055
7107
.5 77 .41
10 .3676 029
-4X13.9.5030
.
Joule 9 3
.29 X10
9.4 82 -73.7
2744X10
96
X11019 385
89
3756
.1.0325
3
..-p24
Foou0nd
ot 13
-XX10
24.7 253
56
381
21.33086
1L1 13826 1-7x5.0 505
2
43074
Ki
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loer .2098
-X119 39806
1.72 327 33 6
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177
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107
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150403
319
UNITS
PRESSURE
OF
CONVERSION
237
Perkins
Thermodynamics
General
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ohn
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Mm .per
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p
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.
Atmospheres
.msq .9(m$ sq
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52.0
-3X10
X10
697
504
887
198
0198
c980
sq
per
.Gram
. entimeter 61 10 730551
96
44
X1X10
.-20777
223
181
-1.0
10
9.kilogram
m86eter
sq
per 73223
96
54
32.0
-1X10
X10
777
481
551
Millimeter
mercury
.of 133
.213 595 1395
.5 X10
3
19
X103
-2.7158
337
815
Atmosphere
. |1033
.31013200 10333 760 11496
.6 .32
2116
70
68941
08
.3Pound
inoh
square
per .12
703 .715
51 -216.8016
X10 144
X1
-4.8883
74!foo
Po
pe
sq78
ua
r0un
t re
d
:735445
46.9X10
-3
X10
912
252
1
HANDBOOK OF CHEMISTRY AND PILYSICS
units
in
left
at
named
unit
pressure
or
energy
of
value
show
numbers
above
tables
two
the
In
Falorie
top
the
at
pamed
,1g
cexample
9
to
equivalent
-3B.TUis
X10
68
ram
or
1TO
FROM
UNITS
CUSTOMARY
AND
METRIC
OF
COMPARISON
10
Length
MILLI CENTI FEET U.S U.S KILO
INCHES INCHES METERS METERS
METERS METERS YARDS MILES METERS
COWN
IAWNH
WNNW
0.19685 .51 748 3=1.219202 2.743205 21869
0.23622 1.9685 3.2=1580833
24003 2.48548
0.27559 08001 28804
4=1.82016 3 607
657 82801
cinco
0.31496 2.3622 2 67
=561 4.374444 3.10685
0.35433 2.7559 5=2.133604 3.7452824
72009
VOOR HA
wo er OTHA
000 voor
ܛܘܒ ܠ
.40013
25 =7.62002 .468056
=5438405 =6.43 40. 3739
| 001
.8
50 496 9 62.743205 544959
=4.3 86411
.2002
76 9.84250 =6.561667 9|.4= 7096
coco
06002 5=6.400813 8.04674
ܗܗ
=101
.6 002 1=1.132333
Oooo
003
10.= 27 7.655278
=516
.47120417
0003 .55=9 9233
=152
.4 003 2=154003
.6
619 8500 6=7.315215 = 5608
9.6
IIANDBOOK OF CHEMISTRY AND PHYSICS
18 004
.= 77 .7=1722
978004
6583 =8.748889 17 =116543
.2
03
.2= 004 OOTA
|23602004
=8.2 4667 8=.229616 .8=127478
6=2. 28005 58=9292
.26005
2750 89=. 42500 9 =148412
.4
O O
coco Vot
COMPARISON
AND
METRIC
OF
UNITS
CUSTOMARY
1Tontinued
—CFROM
10O
Area
SQUARE SQUARE SQUARE
BQUARE SQUARE SQUARE SQUARE SQUARE SQUARE SQUARE
MILLI INCHES CENTI KILO
INCHES FEET METERS YARDS METERS MILES
METERS METERS METERS
AWNH
Ora
0.0075 0.7750 =0.46452 52.= 084 1.5444
19
0.00930 =0.9300 = 5742
0.5 80 =3 .91 305
1085 452 =0.65032 =3.3445 2 = .5
A Coco
=0.01240 =1.0850 =0.74323 4= 2=.3166 6
=0.01395 =1.2400 =0.83613 cinco # =4.1807 2=.7027 7
voor
Fam
6.,52= 580 4307
.0=82555 =6 .3=10600
Hirincisi ooo oo *
5000
= .1416
4,5 .1=4561 =775
.347 =7. .1= 8300
= .35,1061 =513
.6 1 =886
.111 =89.5679 =20200
.7
0000
00 00
= 45,8. 606 .0=565
8 =996
.875 9.7639
=10 .3=23100
Locorro
COMPARISON
AND
METRIC
FROM
UNITS
CUSTOMARY
1Tontinued
–COF
10
O
Volume -Continued
AREA
CUBIC CUBIC
CUBIC CUBIC CUBIC CUBIC CUBIC CUBIC
MILLI CENTI ACRES HECTARES
INCHES INCHES FEET METERS YARDS METERS
METERS METERS
-
=0.000122 .10 220 0.0= 5663 =1.3079 0.8094
=0.000183 0.1831 =0.08495 =1.5291 1
0.0= 00244 =10.2441 =0.11327 |=2 2.1 141
Hanim
A4
HAWN
=0.000305 .3051
=10 0.1= 4159 2. 937 1.6187
0.000366
=49 .30 661 =0.16990 =3
=0.000427 0.4= 272 =0.19822 =3.0582 =2.0234
0.0= 00488 =0.4882 =0.22654 3.8= 228 4
2. 281
tir
0 0 30 g
Coco VO
coop voor HWNH
ooooo
.16
,387 12 = .316872 .314
=135 5.4= 874
32
.3i2774 = .7743
32 .629
=270
= 5,161
.49 = .1615
49 .943
=3105 =5.3519
= 48
5.6,65 = .5486
65 .258
=4141
mica
9.884
Hoo #
Winoco
Noooo
HWF
.8,9= 135 9=8. 1358 .572
176 16.= 165 .355
12
HANDBOOK OF CHEMISTRY AND PHYSICS
.1,7= 14
10 .7=114
101 .2= 01
7247 =9.71556 .297
=717
.3,0=131 97 0=1. 31
973 .516
=8282 .4635
8=10 .768
=819
Ovo
47
.=15,484 .4=147 845 8317
9=. 30 .97715
=11 .239
=922
COMPARISON
AND
METRIC
OF
UNITS
CUSTOMARY
1TO
FROM
Continuou
10
+ ,323
.038 11
7
. 101
11
como
COM
MET
OF
AND
CUS
CTFRO
—1UNI
10 RIC
TOM
MPAR
O TS
onti ARYN
nuedISO
Capacity
U.S U.S U.s
MILLI U.S MILLI MILLI U.S
APOTHE APOTHE LITERS
LITERS LIQUID LITERS
'
LIQUID LITERS LIQUID LITERS
'
CARIES CARI ES
.)(cc OUNCES .)(cc ).(cc QUARTS GALLONS
DRAMS SCRUPLES
ostria
opria
AWNH
wamo
Cow
och
=0.23670 =1.6231 = 4 :1.5378543
8502
cinc
241
=0.27051 =1.8936 13
=4
cinco
= 4. =1.84919
=0.30432 =7.3934
= 2 5 |2=4.73179 57.7087
000 VOT
VOTA -Cowo
.52974 2.1641 1. 1336
-
o
er
.147
59 =937753
N
.721
=388 011 .3=15630
1
000 VNDUA
=. 901
cicios
.295
=118 14
.7869 6
.6= 2451 .1= 54174
-
VND
Tinoco
cicim * W
co co t
.869
=5147 .418836 .9=182717
177
4=6. 42 122. 803 = 8.6257 =221261
.7
HANDBOOK OF CHEMISTRY AND PHYSICS
.016
=7207 .8770
=25 =8
15 =269801
.4
.5= 90
8236 .5737
=29 =9.8579 9 2=3. 08348
10000
=8.6
.163
=9266 .2704
=33 .0=11901 =9
14 .0=346891
OOD
ricos
1Tontinued
FROM
UNITS
CUSTOMARY
AND
METRIC
OF
—CCOMPARISON
10O
U.S .SU HECTO
U.SDRY DEKA SU. U.S HECTO
1 QUARTS LITERS LITERS BUSHELS PER
LITERS
PECKS LITERS .PECKS BUSHELS LITERS
ACRE
PER HECTARE
Hain
" N
A WNW
Hrvai
.50 6755 6=. 429 =1.40957 62.= 1233
= 3.3037 0.68106 4053 =1.76196 3.4451
= 93
Haam
= 4 0.79457 =2
67548 4.3= 8311
= 4.4049 0.90808 5404 1.2= 1436 =4.59359
44- 049
O voor
AICCO
242
HA HA cow
Hoon
aiman * *
*
citing
= 55. 061 = 57
9021 5.6755 =2.81914 74199 =5
00
5.26=17859
1964 8.51323
= 3 =5.22467
=6.6074 6.4=262946 6.8106 1.3= 7154 8903=9 6
low co
6.12=35669
3928 11
.35097 =4 =6.09545
WNE
con
voer
49107
=7.944
0457 .1= 8871
514 =6.96622
8-7.08=52479 5892 .02645
=617 0
=78. 3879
88.= 098 =97.96288
16874 .86420
=719 9 =7.83700
HANDBOOK OF CHEMISTRY AND PHYSICS
=91727 =9.08478080
7856 .70194 -
=822 =89.18719
0000
=9.9110 9.2=7108838
9159 .53968
=925 .33558
=910
coco voo
tricocos
1Tontinued
FROM
UNITS
CUSTOMARY
AND
METRIC
OF
—CCOMPARISON
10O
(or
)Weight
Mass
AVOIRDU AVOIRDU
TROY KILO TROY KILO
GRAINS GRAMS POIS GRAMS GRAMS POIS
OUNCES GRAMS POUNDS GRAMS
OUNCES POUNDS
CNN
3.0= 2399 0.17637 0.16075 81. 1437 =1.49297
3.0= 8879 =0.21164 0.1= 9290 4.40924 =1.86621
=0.45359 =0.24692 =0.22506 2.26796 35846
=0.51839 =0.28219 =0.25721 =2.72155 =2.23945
243
co voo HWNN
6. 1387
OOTORIA
000 voor
415
1=. 324 321.= 8495 .1=30348
1 7 3.1| 7515 2.98593
=230
.8647 .6991
256 .2=60696
2 8 =3.62874 8.03769
=46
.2971 80.3= 5486 3=9. 31044 8.81849
35918
.761
294 4.3=1981 13 =124
.4 1392
9 .7!1=4008233
1691
WNH
cima
How
OOO OOO
AWNE
.1618
77 5.7=1476
41 11 2311
1740
5=.0155 39614
.13
.592941 972
06.=170 .26=11386 2088
2773 .07537
16
HANDBOOK OF CHEMISTRY AND PHYSICS
.0265
108 7.4=198
467 47=.15
23236 2437
17 .75460
=18
OOT
= 589
.4
123 =226
8.7 962 8248
.6 3698
2785
=817 = 3383
.4
821
O voo
1111111
.8912
=138 9.1=255
457 .89=279
919 3133
4160 .11306
=924
coop voor
OOO
COO VOO
WIRE TABLES
COMPARISON OF WIRE GAUGES
Birmingham
Washburn
Imperial
DIAMETER OF WIRE IN INCHES
Music
.'s teel
Gauge
SStub
.&Moen
Stub
Sharpe
wire
Brit
.Std
or
or
n
No
's.
.USStd
Brow
plate
.
.
.
& !
00000000 .0083
.
. 500 . 0087
: : :
0000000
.
Birmingham
DIAMETER OF WIRE IN INCHES
Washburn
Imperial
Stubs
Music
Stub
Gauge
's teel
Sharpe
Moen
Brit
wire
.Std
or
or
No
Brown
.USStd
.plate
.
.
.
.
.
&
No . Size No. ize . No . Size. No. Size No. Size. No. Size .
245
HANDBOOK OF CHEMISTRY AND PHYSICS
DIMENSIONS OF WIRE
Stub's GAUGE
Giving the diameter and cross -section in English and metric system
for the Birmingham or Stub 's gauge.
246
AANDBOOK OF CHEMISTRY AND POYSICS
DIMENSIONS OF WIRE (Continued )
British STANDARD GAUGE
Giving the diameter and cross-section in English and metric system
for the British Standard Gauge.
Diameter Section Diameter Section
(Gauge No. in ins. in sq .ins. in cms. in sq .ems.
219
· HANDBOOK OF CHEMISTRY AND PHYSICS
Gauge
number . Ohms per ft. Ft. per ohm . Ohms per lb . Lbs. per ohm .
0 . 03855 25 . 94 50 . 06 0 . 019976
. 04861 20 . 57 79 . 60 .012563
. 06130 16 . 31 126 . 57 . C07901
. 07729 12 . 94 201. 26 . 004969
. 09746 10 . 26 320 . 01 .003125
0 . 1229 8 . 137 508 . 8 0 . 0019654
.. 1550 6 . 452 809 . 1 . 0012359
. 1954 5 . 117 1286 . 5 . 0007773
. 2464 4 . 0 .58 2015 . 6 . 0004889
. 3107 3 . 218 3252 . 6 . 0003074
0 . 3918 2 . 552 5172 . 0 . 0001934
. 4941 2 . 024 8224 . . 0001216
. 6230 1 . 605 13076 . . 0000765
. 7856 1 . 273 20792 . 1 . 0000481
. 9906 1 . 009 33060 . . 0000303
249
HANDBOOK OF CHEMISTRY AND PHYSICS
250
ILANDBOOK OF CHEMISTRY AND PILYSICS
21 003967 25 . 21 0 .010859 92 . 09
. 05002 19 . 99 . 017266 57 . 92
23 . 06305 15 . 85 027154 36 . 42
24 . 07954 12 . 57 043653 22. 91
25 . 10030 9 . 97 . 069411 11. 88
251
HANDBOOK OF CHEMISTRY AND PHYSICS
252
HANDBOOK OF CHEMISTRY AND PHYSICS
. 8866 . 3035
1194 . 39 . 063 . 9318 1 . 0230 . 3190
1236 .61 1 . 118 0 . 980 1 . 076 0 . 3355
1320 . 23 175 1 . 030 . 130 . 3525
1385 . 41 . 233 . 081 . 186 . 3693
1152 . 20 . 292 . 133 . 243 . 3877
1520 . 53 . 353 . 186 . 302 . 4060
1590 . 43 1. 413 1 . 241 1 . 361 0 . 4246
1661 . 90 . 479 . 296 . 423 . 4437
1731 . 94 . 544 . 353 . 485 . 4632
1809 . 56 .611 . 411 . 549 . 4832
1885 . 74 .678 . 471 .614 . 5035
50 1963. 50 1 .748 1 . 532 1 . 681 . 5243
51 2042 . 82 . 818 .. 593 . 753 . 5454
52 2123 . 72 . 890 . 657 . 818 . 5670
53 2206 . 18 . 964 . 721 . 888 . 5891
2290 . 22 2 . 038 . 786 . 960 .6115
254
HANDBOOK OF CHEMISTRY AND PHYSICS
Gauge No. 10 | 11 | 12 | 13 | 14 | 15 | 16
Diameter in dec. in.. . . 0 . 106 0 .091 0 .081 0 .072 0 .064 0 .057 0 . 051
Approximate mass in
grams, per foot. . . . . 137 . 5 28 . 0 22 . 0 17 . 5 14 . 0 11.0 9.0
Gauge No . 17 18 19 | 20 | 21 | 22
Diameter in dec. in . . . 0 .045 0 . 041 0 .036 0 .032 0 . 029 0 . 026
Approximate mass in
grams, per foot. . . . . 20 | 5 . 7 4 .4 3. 4 | 2. 9 2.3
GAUGE No. | 23 24 25 26 27 28
Diameter in dec. in . . . 0 . 023 0 .020 0 .018 0 . 016 0 .014 0 .013
Approximate mass in
in grams, per foot . . . 1.8 1.4 1. 1 0.9 0.7 0.6
GAUGE No. 29 30 31 32 33 34 35
Diameter in dec. in . . . 0 .0115 0 . 010 0 . 009 0.008 0 .007 0.0063 0 .0056
Approximate mass in
in grams, per foot. . . 0 . 45 0 . 35 | 0 . 28 | 0 . 22 0 . 17 | 0 . 15 0 . 11
Gauge Ohms per Ohms per Gauge Ohms per Ohms per
number . 1000 ft. kilometer . number . 1000 ft . kilometer .
. 128 . 419 26 . 5 86 . 9
NNNNN
OCH
WCOW
OOOOOO CONO
33 . 4 110 .
. 161 . 529 42 . 1 138 .
. 203 . 667
10
. 648
. 817 2 .68 169 . 555 .
1 . 03 3 . 38 213 . 700 .
1 . 30 4 . 26 269 . 883 .
1 . 64 5 . 38 339 . 1110 .
2 . 07 6 . 78 428 . 1400 .
OO
OOOO
4 , 14 13 . 6 858 .
5 . 22 17 . 1 1080 . 3550 .
OU
250
MATHEMATICAL TABLES
MENSURATION FORMULÆ
Plain Figures Bounded by Straight Lines
The area of a triangle whose base is b and altitude h
hb
= 2:
The area of a triangle with angles A , B , and C and sides
opposite a , b , and c, respectively
= 1 /2ab sin C .
or = V s(s - a) (s - b) (s — c ),
where s = 1 / 2 (a + b + c ).
A rectangle with sides a and b has an area = ab .
The area of a parallelogram with side b and the perpendicular
distance to the parallel side h
= bh.
The area of a parallelogram with sides a and b and the included
angle 8
= ab sin 0 .
The area of a rhombus with diagonals c and i ,
= 3c11.
The area of any quadrilateral with diagonals a and b and
the angle between them 0
= ab sin 0.
The area of a regular polygon with n sides, each of length 1,
= {nl cot 180
For a regular polygon of n sides, each side of length 1, the
radius of the inscribed circle,
ISO
o
invoor
ooo
Triangle, equilateral 0 .4330112 0 . 288671 | 0 . 577351
co
Square . . . . . . 1 . 0000012 0 . 500001 0 . 707101
Pentagon . . . . . . . . . 1 . 7204812 0 .688191 | 0 . 850651
Hexagon . . . . 2 . 5980812 | 0 . 866021 | 1 . 00002
Heptagon . . . . 3 .6339112 1 . 03831 1 . 15231
Octagon . . . . . . 4 . 8284312 1 . 20711 1 . 30651
Nonagon . . . . . 6 . 1818212 1 . 37371 1 . 46192
Decagon . . . . . 7 .6942112 | 1 . 53881 1 .61802
Undecagon . . . 11 9 . 3656412 1 . 70281 1 .77471
Dodecagon . . . . . . . . 12 11 . 1961522 1 . 86601 1 . 93181
= 2nr sin -
The area of the inscribed polygon,
= 2nr tan
The area of the circumscribed polygon
= nratan .
258
HANDBOOK OF CHEMISTRY AND PHYSICS
= 180°
Fig . 1.
Fig . 2.
200
HANDBOOK OF CHEMISTRY AND PHYSICS
Solids Bounded by Planes
The lateral area of a regular prism = perimeter of a right section
x the length .
The volume of a regular prism = area of base x the altitude.
The lateral area of a regular pyramid , slant height l and length
of one side of base a,
= {nal.
The volume of a pyramid = { area of base X altitude. .
-
Fig . 3 .
Surface and Volume of Regular Polyhedra
Surface and volume of regular polyhedra in terms of the
length of one edge l.
Name. Nature of surface . Surface. Volume.
on san
=
in up d
sin A cos A
tan A = cot A =
secant A = cosec A =
.
Fig . 4.
sin . . . . .. 0 to 1 + 1 to 0 0 to 1 1 to 0
| 1 to 0 - 1 to 0) 0 to 1
+ + + + + +
COS . . . . . 0 to 1
tan . . . . | 0 to os o to 0 + O to oo to 0
cot . . to 0) O to oc 2 to 0 O to os
I
sec . . . | 1 to o oto 1 1 to 0 to 1
cosec. . . oto 1 1 to of o to 1 11 to
+1.
263 -
HANDBOOK OF CHEMISTRY AND PHYSICS
VALUE OF THE FUNCTIONS OF VARIOUS ANGLES
0° 30° 45° 60° 90° 180° 270°
sin...... O 1/2 vo V3 1 0 -1
cos...... 1 \V3 0 -1 0
tan ..... O 1/V3 1 13 0 0 0
cot...... v 1 1 0 0 0
RELATIONS OF THE FUNCTIONS
cosec X =
cosec z sin x
COS X = sec X = s
sec co x
1 _ sin c
cot x cos x
cot x = - 1 _= cos- r
t tan x sin x
sin x = V1 -- cos? x . cos x = V1 - sin 2x .
tan x = V sec? - 1. sec x = vtan? + 1.
cot x = V cosec? x - 1. cosec x = V cot x + 1 .
sin x = cos (90 — x ) = (sin 180 ---x ).
cos x = sin ( 90 — x ) = - cos ( 180 — x ).
tan x = cot ( 90 —- x ) = - tan ( 180 — x ).
cot x = tan (90 — x ) = – cot ( 180 — x ).
1 + cos x
cos 13 = V 2
1 - ( OS X
tan iII Vi + cos X
( $ - b) ( $ - c )
tan
tan
= V - $( — a )
26€ .
HANDBOOK OF CHEMISTRY AND PHYSICS
100 0000 0001 0009 0013 0017 0022 0026 0030 0035 0039
101 0043 0048 0052 0056 0060 0065 0069 0073 0077 0082
102 0086 0090 0095 0099 0103 0107 0111 0116 0120 0124
103 0128 0133 0137 0141 0145 0149 0154 0158 0162 0166
104 0170 0175 0179 0183 0187 0191 0195 0199 0204 0208
105 0212 0216 0220 0224 0228 0233 0237 0245 0249
106 0253 0257 0261 0265 0269 0273 0278 0282 0286 0290
107 0294 0298 0302 0306 0310 0314 0318 03322 0326 0330
108 0334 0338 0342 0346 0350 0354 | 0358 0362 0366 0370
109 0374 0378 0382 0386 0390 0394 0398 0402 0406 0110
110 0414 1 0118 0122 0426 0430 0434 0438 0441 0445 0449
111 0453 0457 0461 0465 0469 0473 0477 0481 0484 0488
112 0492 0496 0500 0504 0508 0512 0515 0519 0523 0527
113 0531 0535 | 0538 0542 0546 0550 0554 0558 0561 0565
114 0569 0573 0577 0580 0584 0588 0592 0596 0599 0603
115 0607 0611 0615 0618 0622 0626 0630 0633 0637 0641
116 0645 0618 0652 0656 0560 0663 0667 0671 0674 0678
117 0682 0686 0689 0693 0697 0700 0704 0708 0711 0715
118 0719 0722 0726 0730 0734 0737 | 0741 0745 0748 0752
119 0755 0759 0763 0766 0770 0774 0777 0781/ 0785 0788
120 0792 0795 | 0799 0803 0806 0810 0813 0817 0821 0824
121 0828 0831 10835 0839 0842 0846 0849 0853 0856 0860
122 0864 0867 0871 0874 0878 0881 0885 0888 0892 0896
123 0899 0903 0906 0910 0913 0917 09200924 0927 0931
124 0934 0938 0941 0915 0918 0952 0955 0959 0962 0966
125 0969 0973 0976 | 0980 0983 | 0986 0990 0993 0997 1000
126 1004 1007 1011 1014 1017 1021 1024 1028 1031 1035
127 1038 1041 1045 1048 1052 1055 1059 1062 1065 1069
128 1072 1075 1079 1082 1086 1089 1092 1096 1099 1103
129 1106 1109 1113 1116 1119 1123 1126 1129 1133 1136
130 1139 1143 1116 1149 1153 1156 1159 1163 1166 1169
131 1173 1176 1179 1183 1186 | 1189 1193 1196 1199 1202
132 1206 1209 1212 1216 1219 | 1222 1225 1229 1232 1235
133 1239 | 1212 1245 1248 1252 1255 1258 1261 1265 1268
134 1271 | 1274 1278 1281 1284 1287 1290 1294 1297 1300
135 1303 1307 1310 1313 1316 1319 13231 1326 1329 1332
136 | 1335 1339 1312 1345 1318 1351 1355 1358 1361 1361
137 | 1367 1370 1374 1377 1380 1383 1386 1389 1392 1396
138 1399 1402 1405 1408 1411 1414 1418 1421 1424 1427
139 1430 1433 1436 1440 1443 1446 1449 1452 1455 1458
140 1461 1464 1467 1471 1474 1477 1480 1483 1486 1489
141 | 1492 1495 1498 1501 1504 1508 1511 1514 1517 1520
142 1523 1526 1529 1532 1535 1538 1541 1544 1547 1550
1556 1559 1562 1565 1569 1572157
143 1553 1572 1575 1578 1581
144 1584 1587 1590 1593 1596 1599 1602 1605 1608 1611
145 1614 | 1617 1620 1623 1626 | 1629 1632 1635 1638 ' 1641
146 1644 1617 1619 1652 1655 1658 1661 1664 1567 1670
147 1673 1676 1679 1682 1685 | 1688 1691 1694 1697 1700
148 1703 1706 | 1708 1711 1714 1717 1720 1723 1726 1729
149 1732 | 1735 1738 1741 1744 11746 1749 1752 1755 1758
266
HANDBOOK OF CHEMISTRY AND PHYSICS
155 1903 1906 1909 1912 1915 1917 1920 1923 1926 1928
156 1931 1934 1937 1 1940 1942 1915 1948 1951 1953 1956
157 1959 1962 1965 | 1967 1970 1973 1976 1978 1981 1984
158 1987 1939 1992 1995 1998 2000 2003 2006 2009 2011
159 2014 2017 2019 2022 2025 2028 2030 2033 2036 2038
160 2041 2014 2017 2019 2052 2055 2057 2060 2063 2066
161 2008 2071 2074 2076 2079 2082 2081 2017 2090 2092
162 2095 2093 2101 2103 2106 2109 2111 2114 2117 2119
163 2122 2125 2127 2130 2133 2135 2138 2146
164 2148 2151 2154 2156 2159 2162 2161 2167 2170 2172
165 2175 2177 2180 2183 2185 2188 2191 2193 2196 2198
166 2201 2204 2206 2209 2212 2214 2217 2219 2222 2225
167 2227 2230 2232 2235 2238 22 10 2213 22151 2218 2251
168 2253 2256 2258 2261 2263 2266 2269 2271 2274 2276
2279 2281 2284 2287 2289 2292 2291 2297 2299 2302
169
170 2304 2307 2310 2312 2315 2317 ! 2320 2322 2325 2327
171 2330 2333 2335 2338 2310 2313 2318 2350
2315 2353
172 2355 2358 2360 2363 2365 2368 ' 2370 2373 2375 2378
173 2380 2383 2385 2388 2390 2393 23951 23981 2400 2403
174 2405 2408 2410 2413 2415 2418 2420 2423 2425 2128
175 2430 2433 2135 2438 2440 2413 2445 2448 2450 2453
176 2455 . 2458 2160 2463 2465 2167 - 2470 2172 2475 2477
177 2480 2482 2185 2187 2490 2492 2494 2497 2499 2502
178 2504 2507 2509 2512 2514 2516 2519 2521 2524 2526
179 2529 2531 2533 2536 2538 2541 2543 2545 2548 2550
180 2553 2555 2538 2560 2562 2565 2567 2570 2572 2574
181 2577 2579 2 : 82 2554 2586 2589 2591 2594 2596 2598
182 2001 2003 2605 2608 2010 2613 2615 2617 2620 2622
183 2625 2627 2629 2632 2634 2636 2639 2641 2643 2646
181 2648 2051 2653 2655 2653 2000 2662 2665 2667 2669
185 2672 2671 2676 2679 2681 2683 2686 2688 2690 2693
186 2695 2697 2700 2702 2704 2707 2709 2711 2714 2716
187 2718 2721 2723 2725 2728 2730 2732 2735 2737 2739
188 2742 2711 2716 2749 2751 2753 2755 2759 2760 2762
2772 2774 2776
2778 2781 2783 2785
189 2765 2767 2769
190 2788 2790 2792 2794 2797 2799 2801 2804 2806 2808
2810 2813 2815 2817 2819 2822 2821 2826 2828 2831
191
192 2833 2835 2833 2810 2812 2814 2817 2849 2851 2853
193 2856 2858 2860 2862 2865 2867 2869 2871 2874 2876
194 2878 2880 2582 2885 2887 2899 2891 2894 2896 2898
195 2900 2903 2905 2907 2909 2911 2914 2916 2918 2920
196 2923 2925 2927 2929 2931 2934 2936 2938 2910 2942
2945 2017 29 :19 2951 29 .53 2950 2958 2960 2962 2904
197 2982 2981 2980
2969 2971 2973 2975 2978 2850
193 2967
2999 3002
2989 2991 2993 2995 2997 3001 3000 3003
199
207
HANDBOOK OF CHEMISTRY AND PHYSICS
FOUR-PLACE LOGARITHMS
Logarithms of Numbers from 100 to 999
PROPORTIONAL
PARTS
N o 1 2 3 4 5 6 7 8 9
1 1 2 3 4 5
10 0000 0043 0086 0128 0170 0212 0253 0294 0334 0374 4 8 12 17 21
11 0414 0453 0492 0531 0 .569 0607 0645 0682 0719 0755 4 8 11 15 19
12 0792 0828 0864 C899 0934 0969 0104 1038 1072 1106 3 7 10 14 17
13 1139 1173 1206 1239 1271 1303 1335 1367 1399 1430 3 6 10 13 16
14 1461 1492 1523 1553 1584 1614 1644 1673 1703 1732 3 6 9 12 15
Anore
15 1761 1790 1818 1817 1875 1903 1931 1959 1987 2014 3 6 8 11 14
16 2041 2068 2095 2122 2148 2175 2201 2227 2253 2279 3 5 8 11 13
17 2304 2330 2355 2380 2405 2430 2455 2480 2504 2529 2 5 7 10 12
18 2553 2577 2601 2625 2648 2672 2695 2718 2742 2765 2 5 7 9 12
19 2788 2810 2833 2856 2878 2900 2923 2945 2967 2989 2 4 7 9 11
wwwwwHALA
| ovelvoo
20 3010 3032 3051 3075 3096 3118 3139 3160 3181 3201 2 4 6 8 11
21 3222 3243 3263 3284 3304 3324 3345 3365 3385 34011 2 4 6 8 10
13424 3144 3164 3183 3502 3522 3541 3560 3579 3598
DOM
8 10
3617 3636 3655 3674 36923711 3729 3747 3766 3784 7 9
OXOCO
3802 3820 3838 3856 3874 3892 3909 3927 3945 3962 2 4 7 9
c
25 3979 3997 4014 4031 4048 4065 4082 4099 4116 41331 2 3 5
26 1150 4166 4183 4200 4216 4232 4219 4265 4281 4298 2 3 5 7
27 4314 4330 4316 4362 4378 4393 4109 4125 4440 4156 2
28 4472 1487 4502 4518 4533 4518 4564 4579 4594 4609 2 3
29 4624 4639 4651 4669 4683 1698 4713 4728 4742 4757 1 3
30 4771 4786 4800 4814 4829 1813 4857 4871 4886 4900 1 3 erre
31 4914 4928 4912 4955 4969 1983 4997 5011 5024 5038 1 3
32 5051 5065 5079 5092 5105 5119 5132 5145 5159 5172 1 3 4
33 5185 5198 5211 5224 5237 5250 5263 5276 5289 5302 1 3 4
34 5315 5328 5340 5353 5366 5378 5391 5103 5416 5428 ! 1
19
www !
35 5111 5153 5165 5178 5190 5502 5511 5527 5539 5551 1
36 5563 5575 5587 5599 5611 5623 56.35 50 17 5058 5670 1 2
37 5682 5691 5705 5717 5729 5740 5752 5763 5775 5786 1 2
5798 5803 5821 5532 5813 5855 5566 5877 5888 5899 1 2
39 5911 5922 5933 5914 5955 5966 5977 5958 5999 6010 1 2
atot
6128 6138 6119 6160 6170 6180 6191 6201 6212 62221
42 6232 6213 6253 6203 6274 6284 6294 6301 6314 6325 1
wwwww
6335 6345 6355 6365 6375 6385 6395 6105 6415 0425 1
واانن
ܠ
6135 6441 6454 6101 6174 6181 6493 6503 6513 6522 1 2
ܩ
6352 6512 6551 6561 6371 6550 6590 0599 6609 6018 1 2
ܩ
6028 6637 6616 6656 6665 6675 6081 60193 6702 6712 1 2
47 6721 6730 0739 67.19 6755 6767 6776 ( 785 6794 6303 1 2 4
ܛ
48 6812 6821 6830 6839 6848 68.57 6866 6875 6884 6893 1 2
It
6902 6911 6920 6928 6937 6916 6955 6964 6972 6981 1
ww
t
50 6990 0998 7007 7016 7024 7033 7042 7050 7059 7067 1 2
CSC
NION
51 7076 7081 7093 7101 7110 7118 7126 7135 7143 7152 1 2
the
52 7160 7168 7177 7185 7193 7202 7210 7218 7226 7235 ) 1 2
ithe
of
7213 7251 7259 7267 7275 7254 7292 7300 7308 7316 1 2
17324 7332 7340 7348 7350 7364 7372 7380 7388 7396 1
N O 1 2 3 4 5 6 7 8 9 1 2 3 4 5
Avoid interpolation for numbers between 1000 and 1999 by using the
preceding auxiliary table ,
268
HANDBOOK OF CHEMISTRY AND PHYSICS
CCC
7782 7789 7796 7803 7810 7818 7825 7832 7839 7846 1 1 2 3
HA
7903
HA
61 7853 7860 7868 7875 7882 7889 7896 7910 7917 1 1 2 3
62 7924 7931 7938 7945 7952 7959 7966 7973 7980 7987 1 1 2 3
63 7993 8000 8007 8014 8021 8028 8035 8041 8048 8055 1 1 2 3
64 8062 8069 8075 8082 8089 8096 8102 8109 8116 8122 1 1 2 3
65 8129 8136 8142 8149 8156 8162 8169 8176 8182 8189 1 1 2 3 3
66 8195 8202 8209 8215 8222 8228 8235 8241 8248 8254 1 1 2 3 3
67 8261 8267 8274 8280 8287 8293 8299 8306 8312 8319 1 1 2 3 3
68 8325 8331 8338 8344 8351 8357 8363 8370 8376 8382 1 1 2 3 3
69 8388 8395 8401 8407 8414 8420 8426 8432 8439 8445 1 1 2 2 3
70 8451 8457 8463 8470 8476 8482 8488 8494 8500 8506 1 1 2 2 3
71 8513 8519 8525 8531 8537 8513 8549 8555 8561 8567 1 1 2 2 3
72 8573 8579 8585 8591 8597 8603 8609 8615 8621 8627 1 1 2 2 3
73 8633 8639 8645 8651 8657 8663 8669 8675 8681 8686 1 1 2 2 3
74 18692 8698 8704 8710 8716 8722 8727 8733 8739 3745
ಲ
1 1 2
75 8751 8756 8762 8768 8774 8779 8785 8791 8797 8802 1 1 2 2
76 8808 8814 8820 8825 8831 8837 8812 8848 8854 8859 1 1 2 2 3
77 8865 8871 8876 8882 8887 8893 8899 8904 8910 8915 / 1 1 2 2 3 wwww
8921 8927 8932 8938 8943 8949 8954 8960 8965 8971 1 1 2 2
79 8976 8982 8987 8993 8998 9001 9009 9015 9020 9025 1 1 2
80 9031 9036 9042 9047 9053 9058 9063 9069 9074 9079 1 1 2 2
81 9085 9090 9096 9101 9106 9112 9117 9122 9128 9133 1 1 2 2
82 9138 9143 9149 9154 9159 9165 9170 ..9175 9180 9186 1 1 2 2
83 9191 9196 9201 9206 9212 9217 9222 9227 9232 9238 1 1 2
84 9243 9248 9253 9258 9263 9269 9274 9279 9284 9289 1 1 2
NNNW
85 9294 9299 9304 9309 9315 9320 9325 9330 9335 9340 1 1 2
86 9345 9350 9355 9360 9365 9370 9375 9380 9385 9390 1 1 2 2 3
87 9395 9400 9405 9410 9415 9420 9125 9430 9435 9410 0 1 1 2 2
9445 9450 9455 9460 9465 9469 9474 9479 9484 9489 0 1 1
89 9494 9499 9504 9509 9513 9518 9523 9528 9533 9538 0 1 1 2 2
90 9542 9547 9552 9557 9562 9566 9571 95766 9581
9581 536
99586 0 1 1 2 2
91 9590 9595 9600 9605 9609 9614 9619 9624 9628 9633 0 1 1 2 2
92 9638 G9643
643 9647
9647 09652
650 9657
609 9661
99703 9614 9666
9610 9671 9675 9680 0 1 1 2 2
93 9685 9689 9694 9699 9708 9713 9717 9722 9727 0 1 1 2 2
94 9731 9736 9741 9745 9750 9754 9759 9763 9768 9773 0 1 1 2 2
95 9777 9782 9786 9791 9795 9800 9805 9809 9814 9818 0 1 1 2 2
9823 9827 9832 9836 9841 9845 9850 98,54 9859 9863 0 1 1 2
9868 9872 9877 9881 9886 9890 9894 9899 9903 9908 0 1 1 2
98 9912 9917 9921 9926 9930 9334 9939 9943 9948 9952 0 1 1 2 2
99 9956 9961 9965 9969 9974 9978 9983 9987 9991 9996 0 1 1 2 2
N O 1 2 3 4 5 6 7 8 9 1 2 3 4 5
269
HANDBOOK OF CHEMISTRY AND PHYSICS
NATURAL SINES, COSINES, TANGENTS AND
COTANGENTS
Degrees. Sin . Cos. Tan . Cot. Degrees.
0° 00 ' 0 . 0000 1 . 0000 0 . 0000 90° 00 '
10 . 0029 1 . 0000 . 0029 343 . 77 50
20 . 0058 1 . 0000 . 0058 171 . 89 40
. 0087 30
. 0087 1 .0000 114 . 59
20
****** ****** * ** ******* ************ ****** ****** * ****
. 0116 . 9999 . 0116 85 . 940
. 0145 . 9999 .0145 68 . 750 10
271
HANDBOOK OF CHEMISTRY AND PHYSICS
NATURAL SINES , COSINES , TANGENTS AND
COTANGENTS (Continued )
Degrees. Sin . Cos. Tan . Cot. Degrees.
272
HANDBOOK OF CHEMISTRY AND PHYSICS
NATURAL SINES, COSINES, TANGENTS AND
COTANGENTS (Continued )
Degrees. Sin . Cos. Tap . Cot. Degrees.
273
HANDBOOK OF CHEMISTRY AND PHYSICS
NATURAL SINES, COSINES, TANGENTS AND
TANGENTS (Continued )
Degrees . Sin . Cos. Tan . Cot. Degrees.
Degrees. Log cos Log sin | Log cot | Log tan Degrees.
275
ILANDBOOK OF CHEMISTRY AND PIIYSICS
LOGARITHMS OF THE TRIGONOMETRICAL FUNCTIONS
(Continued )
Degrees. | Log sin | Log cos Log tan | Log cot | Degrees .
9° 00 ' 9 . 1943 9 . 9946 9 . 1997 0 . 8003 81° 00 '
. 9944 . 2078 .7922 50
10 . 2022
. 2100 . 9942 . 2158 . 7842
. 2176 . 9940 . 2236 . 7764
. 2251 . 9938 . 2313 . 7687
50 . 2324 . 9936 . 2389 . 7611
10° 00 ' 9 . 2397 9 . 9931 9 . 2463 0 . 7537 80° 00 '
. 2468 . 9931 . 2 .736 . 7464 50
10
20 . 2538 . 9929 . 2009 . 7391 40
30 . 2006 . 9927 . 2680 . 7320 30
40 . 2074 . 9921 . 2750 . 7250
. 9922 . 2819 • 7181 10
50 . 2710
11° 00 ' 9 . 2806 9 . 9319 9 . 2887 0 . 7113 79° 00 '
10 . 2870 . 9917 . 2953 . 7047
. 2934 . 9914 . 3020 . 6980
30 . 2997 . 9912 . 3085 .6915
. 3058 . 9909 . 3119 . 6851
. 9907 . 3212 .6788 10
50 . 3119
120 00 9 . 3179 9 . 9901 9 . 3275 0 . 6725 78° 00 '
10 . 3238 . 9901 . 3336 .6664
20 . 3296 . 9899 . 3397 . 6603
30 . 3353 . 9896 . 31.58 . 6512
40 . 3410 .. 9893 . 3517 . 6483
. 3166 . 9890 . 3576 . 6424
279
HANDBOOK OF CHEMISTRY AND PHYSICS
NUMERICAL TABLE
RECIPROCALS, POWERS AND Roots OF NUMBERS, CIRCUMFERENCES AND
AREAS OF CIRCLES
Circum . Area of
27 of circle
1 /n circle
in an2
NNNNNNNNNN
11. 11. 3 . 14 0 . 79
. 50000 11. 414 1 . 260 6 . 28 3 . 14
. 33333 27 1 .732 1 . 442 9 . 42 7 . 07
. 25000 61 2 . 000 1 . 587 12 . 57 12 . 6
. 20000 25 125 2 . 236 1 . 710 15 .71 19 . 6
NINUN
NON
. 16667 36 216 2 . 449 1 . 817 18 . 85 28 . 3
. 14286 49 343 2 . 646 1 . 913 21 . 99 38 . 5
. 12500 64 512 2 . 828 2 . 000 25 . 13 50 . 3
ooon
9 . 11111 81 729 3 . 000 2 . 080 28 . 27 63 . 6
10 . 10000 100 1000 3 . 162 2 . 154 31 .42 78 . 5
280
HANDBOOK OF CHEMISTRY AND PHYSICS
NUMERICAL TABLE (Continued )
RECIPROCALS, POWERS AND Roots Of NrMHERS, CIRCUMFERENCES AND
AREAS OF CIRCLES (Continued )
Circum . Area of
In2 of circle circle ,
an ?
281
HANDBOOK OF CHEMISTRY AND PHYSICS
NUMERICAL CONSTANTS
= 3. 14159
log r = 0 .497150
41 = 12 . 56637 ] log 41 = 1.099210 ,
= 1.57080 log =0. 196120
too
= 1.04720 logo = 0.020029
4
282
APPARATUS LISTS
General Equipment
Interchangeable supports, bases, rods, clamps, arms, rings, etc .
Balances, platform scales and enclosed , sensitive balance, with
appropriate weights.
Barometer. Electric Motor, H . P.
Water Still. Bunsen Burners.
Cells , for open and for closed Blast Lamp .
circuit . Foot Blower:
Portable Storage Cells. Drawing Instruments .
Rheostats. Projection Lantern .
284
HANDBOOK OF CHEMISTRY AND PHYSICS
Supplies
Wire ; brass, iron , steel, copper, of various sizes.
Insulated wire ; heavy, for connections; bell wire ; cotton or silk
covered magnet wire of various sizes.
Rubber Tubing. Soft wax.
Glass Tubing, various sizes. Shellac, flakes and solution .
Asbestos Board and Wire Stop - cock Grease.
Gauze . Emery , various grades.
Corks, Ordinary and Rubber. Powdered Pumice.
Cork Borer . Rouge.
Pinch Cocks. Resin .
Filter Paper . Paraffin .
Absorbent Cotton . Canada Balsam .
Glass Beakers, a variety of Mercury.
sizes and shapes. Acids, C . P ., Sulphuric, Hy
Crystallizing Dishes. drochloric and Nitric .
Evaporating Dishes, Porcelain . Alcohol, Ethyl.
Flasks, Wash Bottles and Dry - Ether.
ing Tubes. Carbon Disulphide.
Watch Glasses. Glycerine.
Graduates. Ammonia .
Bottles, Reagent and Common Potassium Hydroxide.
Stock . Sodium Chloride ( common
Vaseline. salt) .
Watch Oil. . Borax .
Machine Oil. Copper Sulphate.
Sealing Wax, Calcium Chloride.
Tools
Bench Vise . Metal Shears.
Hammers, Ordinary and Wrenches.
Heavy and Light Machine Oil Stone.
Hammers. Soldering Outfit .
Rawhide Mallet. Wood Working Tools - saws,
Drill Press and Drills. planes, chisels, augers and
Screw Drivers. bit brace, etc.
Files . Stock of Machine and Wood
Hack Saw . Screws, Nails , Brads, Rivets,
Pliers, Square, Round Nose etc.
and Wire Cutters, Tweezers. Sand and Emery Paper.
Taps and Dies.
Measurements
Metric Models, Charts, etc . Level.
Meter Scales of wood and Demonstration Balance with
metal. weights.
Vernier Model, Vernier and Clock with arrangement for
Micrometer Calipers . giving time signals.
Micrometer Microscope, Stop Watch .
Spherometer.
285
HANDBOOK OF CHEMISTRY AND PHYSICS
Properties of Matter
Adhesion Disk . Inertia Apparatus.
Cohesion Plates. Elasticity of Flexure Appa
Prince Rupert Drops. ratus.
Capillary Tubes and Support . Breaking Strength of Wire
Osmose Apparatus. Apparatus.
Mechanics of Solids
Collision Balls . Center of Gravity Apparatus
Composition of Forces. Rotator, Whirling Table .
Models of Simple Machines, Centrifugal Hoop .
Block and Tackle , Differen Gyroscope.
tial Pulley , Wall Crane, In Spring Balances.
clined Plane. Jolly Balance.
Mechanics of Fluids
Equilibrium Tubes . Lift Pump.
Hall' s Pressure Gauge .' Force Pump.
Bottle Imp and Jar. Demonstration Hydrometer,
Hydraulic Press. Hydrometer for heavy liquids.
Boyle's Law Tube. Hydrometer Jar, 12x21.
Siphon . Barometer Tube, Cup and
Archimedes Principle Appa Pipette.
ratus.
Pneumatics
Oil-sealed Air Pump. Hand and Bladder Glass.
Pressure Tubing . Sheet Rubber.
Vacuum Gauge. Mercury Shower.
Bell in Vacuo . Magdeburg Hemispheres.
Bursting Cubes. Bacchus Illustration .
Freezing Apparatus. Water Hammer .
Bell Glass, 1 gallon . Guinea and Feather Tube.
Heat
Copper Boiler. Calorimeter.
Air Thermometer. Tyndall's Specific Heat Appa
Thermometers. ratus.
Heat Conduction Apparatus. Fire Syringe.
Ball and Ring. Convection Apparatus.
Compound Bar. Radiometer.
Palm Glass. Sectional Model of Steam En .
Linear Expansion Apparatus. gine.
286
HANDBOOK OF CHEMISTRY AND PHYSICS
Magnetism
Lodestone. Electro Magnet.
Bar Magnet, 6 inch . Magnetic Needle.
Horseshoe Magnet, 6 inch . Compass, 40 mm .
Iron Turnings.
Electricity
Friction Rod, wax. Induction Coil.
Friction Rod , vulcanite . Electric Motor, Demonstra
Catskin . tion Model.
Pith Balls , 1 dozen . Decomposition of Water Ap
Pith Images, pair . paratus.
Electrical Pendulum . Galvanometers with reading
Electroscope. telescopes.
Toepler-Holtz Electric Ma Contact Keys.
chine with attachment and Wheatstone Bridges, slide wire
shocking handles. and box form .
Brass Chains with hook and Resistance Boxes.
snap . Ammeters and Voltmeters,
Leyden Jar, quart. various ranges for direct
Discharger. - and alternating current.
Hollow Globe. Normal Cell.
Proof Plane. Condenser.
Geissler Tubes. Telephone and Telegraph Ap- .
X -Ray Tube and Fluorescent paratus.
Screen .
Light
Newton ' s Disk . Optical Bench with lens sur
Concave and Convex Mirrors. ports, slit, biprism , screen ,
Multiple Image Apparatus. eye piece, etc.
Incidence and Reflection Ap - Iceland Spar.
paratus. Newton ' s Rings.
Sextant. Nicol Prisms.
Equilateral Prism . Replica Grating.
Demonstration Lenses of vari- Spectrometer.
ous types and focal lengths. Microscope.
287
BIBLIOGRAPHY
TEXT-BOOKS, MANUALS AND REFERENCE -BOOKS IN
CHEMISTRY
Allen . . . . . . . . . . . . . . . . . . Organic Analysis.
Allmand . . . .. .. . . . . . . . . . . . . Applied Electrochemistry .
Arrhenius. . . . . . . . . . Immuno-Chemistry .
Bailey . . . . . . . . . . . . . . . . . Qualitative Analysis .
Sanitary and Applied Chemistry .
Baskerville . . . .General Inorganic Chemistry .
Baskerville and Curtis . . . Laboratory Manual.
Baskerville and Curtman. . . Qualitative Analysis.
Benson . . . . Industrial Chemistry .
Bigelow . . ... Physical Chemistry .
Blake . . . . . . . . . .General Chemistry .
Blanchard . . . . . . Synthetic Inorganic Chemistry .
Blount . . . . . . Practical Electro -Chemistry .
Blucher . . . .. .. . . . . . . . . . . . .Modern Industrial Chemistry .
Bottger .. . . . . . . . . . . . . Qualitative Analysis ( Trans. by i
Smeaton ) .
Bradbury . . . . . . . . . . . . . . . Elementary Chemistry .
Browning . . . . . . . . . . . . . . . Introduction to the Rarer Elements.
Brownlee and others . . . . . . Laboratory Manual.
Principles of Chemistry.
Chicago High School Manual of
Chemistry . .
Clark and Dennis . . . . . . . . . Elementary Chemistry .
Laboratory Manual.
Classen . . . . . . . . . . Electrochemical Analysis .
Cohn .. . . . . . . . . . Tests and Reagents .
Indicators and Test Papers.
Dennis . . . . . . .Gas Analysis.
Dennis and Whittelsey . . . .Qualitative Analysis .
Duncan . . . . . . . . . . . . The New Knowledge.
Erdman - Dunlap . . . .. . . . . . Introduction to Chemical Prepara- on
tions.
Fraps . . . . . . . . Principles of Dyeing .
Freer.. . . . . . . . . Elements of Chemistry .
Fresenius . . . . . . . .Qualitative Chemical Analysis .
Gardner . . . . . . . . . . Paint Technology and Tests.
Garvin . . . . . . . . . . Qualitative Analysis.
Gattermann .. . . . . . . . Practical Methods of Organic Chem
istry ( Trans. by Shober ) .
288
HANDBOOK OF CHEMISTRY AND PHYSICS
Gill ...Oil Analysis.
Gooch and Walker . . . . . . . .Outlines of Inorganic Chemistry.
Hardin . . . . . . . . . . . . . . . . . .Liquefaction of Gases.
Hemple . . . . . . . . .Methods of Gas Analysis .
Hessler and Smith . . . . . . . . Essentials of Chemistry with Man
ual.
Hilly . . Laboratory Manual of Chemistry .
Hinds . Inorganic Chemistry .
Laboratory Manual of Chemistry .
Qualitative Analysis.
Holley . . . . . Lead and Zinc Pigments .
Hunt. . . Lubricating Oils, Fats and Greases.
Irish . . . . . . . . Qualitative Analysis for Secondary
Schools.
Johnson . . . . . . . . Analysis of Special Steels and Steel
Making Alloys.
Jones. . Electrolytic Dissociation .
Elements of Inorganic Chemistry .
Elements of Physical Chemistry .
New Era in Chemistry
Julian . . . . . : : : : ; : : . Qualitative Analysis.
Kipping and Perkins Inorganic Chemistry .
Kahlenberg . . . . . . . . . . Outlines of Chemistry .
Landauer . . . . Blow -pipe Analysis (Trans. by Tay
lor).
Lassar-Cohn . . . . . . . . . . . . .Chemistry in Daily Life.
Manual of Organic Chemistry .
t Leach
each .. . . . . . . . . . . Food Inspection and Analysis.
Le Blanc. . . . . . . . . . . . . . Text- Book of Electrochemistry .
Lee . . . . . . . ...Experimental Chemistry.
e Lengfeld . . . . .Inorganic Preparations.
Lewkowitsch . . . . . . . Chemical Technology and Analysis
of Oils , Fats and Waxes.
El Linebarger . . . . . . . . . Elementary Chemistry .
Lord . . . . . . . . . . . . . .Metallurgical Analysis,
Low . . . . . . . . . Technical Methods of Ore Analysis .
McGregory . . . . . . . . . . . . . .Manual of Qualitative Chemical
Analysis .
McPherson and Henderson . An Elementary Study in Chemistry .
Exercises in Chemistry .
General Chemistry .
Mahin . . . . . . . . . . . : .Quantitative Analysis .
M ason . . . . . . . . . . .
Water Analysis .
Mead . . . . . . . . . . . . . . . . . . Portland Cement.
Mellor . . . : : : : .Chemical Statics and Dynamics .
Meyer and Jacobson1.. . . . Organic Chemistry .
Moody . Quantitative Analysis.
is. Morgan . Elements of Physical Chemistry .
Muir , Pattison . . . Practical Chemistry .
Munroe and Kibler . . Explosives.
CheNernst . . . . . . . . Theoretical Chemistry from the
Standpoint of Avogadro's Rules
and Thermodynamics .
289
HANDBOOK OF CHEMISTRY AND PHYSICS
Newell. . . .. .. . Descriptive Chemistry.
Experimental Chemistry .
Manual of Experiments.
Newth . . . . Inorganic Chemistry .
Noyes . . . . . . . . . . . . . . . Elements of Qualitative Chemical
Analysis.
General Principles of Physical
Science.
Organic Chemistry .
Qualitative Chemical Analysis .
Ostwald . . . . . . . . Conversations in Chemistry ( Trans.
by Ramsey ) .
Foundations of Analytical Chem
istry .
Manual of Physical and Chemical
Measurements.
Principles of Inorganic Chemistry .
Solutions.
Perkins and Kipping . . . . . .Organic Chemistry .
Prescott and Johnson . . . . . . Qualitative Analysis .
Water Bacteriology .
Price and Meade.. . . . . . .Analysis of Brass and Non -ferrous
Alloys.
Remsen . . . . . . . . . . . . . College Text-Book in Chemistry .
General Chemistry .
Inorganic Chemistry.
Introduction to Study of Chemistry.
Laboratory Manual.
Organic Chemistry .
Richards . . . . . . Water Analysis.
Richards and Woodman . . . Air , Water and Food .
Richardson . . . . . . . . . . . . . . . The Modern Asphalt Pavement.
Richter -Smith . . .. . Organic Chemistry .
Rolfe . . . . . . . . . . . . . . . . . The Polariscope in the Chemical
Laboratory .
Roscoe . . . . . . . . . . . . . . . . . . Lessons in Elementary Chemistry.
Roscoe and Lunt. . . . ... . . .Inorganic Chemistry.
Roscoe and Scharlemmer. . . Treatise on Chemistry .
Rutherford .. . . Radioactivity,
Sabin . . . . . . . . . . . . Technology of Paint and Varnish .
Sachman. . . . The Spirit of Organic Chemistry .
Sadtler . . . . . . . . . . .Handbook of Industrial Organic
Chemistry .
Schaffer, James. . . . . . . . .. .Experiments in General Chemistry.
Segerblom . . . . . . . . .. .. .. .... . .Qualitative
. Qualitative Analysis
An .
Tables of Properties of Inorganic
Sell
Substances.
ers . . . : : : : : : :
. .Qualitative Analysis .
Smith . . . . . . . . . . . . . . . . . . . Electrochemical Analysis .
Smith and Hale. . . . . ... . . Laboratory Outline in General
Chemistry .
Smith, Alexander . . .. ... .. . Inorganic Chemistry .
Laboratory Manual of Chemistry.
290
HANDBOOK OF CHEMISTRY AND PHYSICS
Speyers . . . . . . . . . . . . . . Physical Chemistry .
Stewart . . . . . . . . . . . . . . . . . Recent Advances in Organic Chem
istry .
Stieglitz . . . . . . . . . . . . . . . . . Qualitative Analysis.
Stillman . . . . . . . . . . . . . . . . .Engineering Chemistry .
Stoddard . . . . . . . . . . . . . . . . Introduction to General Chemistry .
Outline of Qualitative Analysis.
Storer and Lindsay.. . . . . . . Elementary Manual of Chemistry .
Sutton . . . . . . . . . Volumetric Analysis.
Tach . . . . . . . . . The Chemistry of Paints.
Talbot. . . . . . . . ... Quantitative Analysis.
Talbot and Blanchard . . . . . Electrolytic Dissociation Theory .
Thompson . . . . Applied Electrochemistry ,
Thomsen . . . . . . . . . . Thermochemistry .
Thorp . . . . . . . . . . . . . Industrial Chemistry,
Inorganic Preparations.
Treadwell-Hall. . . . . . . . . . .Qualitative Analysis .
Quantitative Analysis.
Unger..... Review Questions and Problems in
Chemistry .
Van 't Hoff. ... .. . .. .. .... Lectures on Theoretical and Physical
Chemistry .
Physical Chemistry in the Service of
Science.
Walker . . . . . . . . Introduction to Physical Chemistry .
White . . . . . . . . . Elementary Chemistry.
Williams. , . . . . Chemical Experiments .
Elements of Chemistry .
Introduction to Chemical Science.
Laboratory Manual in General
Chemistry .
Laboratory Manual in Inorganic
Chemistry .
Young . . . . . . . . . . . Elementary Principles of Chemistry.
Fractional Distillation .
Young, Sydney . . . . . . . . . . . Stoichiometry .
Zsigmondy . . . . . . . . . Colloids and the Ultramicroscope
( Trans. by Alexander) .
BIBLIOGRAPHY OF PHYSICS
The following brief list of works on Physics and allied subjects is offered
for reference:
Elementary Texts
Andrewsand Howland. .Elements of Physics. 1903. 386 pp .
Avery , E . M . . . . . . . . . . School Physics. 1895 . 600 pp.
Elementary Physics. 1897. 315 pp .
Carhart and Chute , . . . . The Elements of Physics . 1895 . 382 pp .
Crew . . . . . . Elements of Physics. 1900 . 350 pp .
Gage , A . P . . . . . . . . . Principles of Physics. 1895 . 630 pp .
Gorton , F . R . . . . . . A High School Course in Physics. 1910 .
480 pp .
Hoadley , G . A . . . . . . . . A Brief Course in Physics. 1900 . 450 pp .
Mann and Twiss . . . . . . Physics. 1905 . 453 pp .
Milliken and Gale . . . . . A First Course in Physics. 1906 . 488 pp .
Mumper, W . N . . . . . . . . A Text- Book in Physics. 1907 . 411 pp .
Nichols , E . L .. . . . . . . . . The Outlines of Physics. 1897 . 450 pp .
291
HANDBOOK OF CHEMISTRY AND PHYSICS
College Texts
Ames, J . S . . . . . . . . . . . Theory of Physics. 1897 . 513 pp .
Text-Book ofGeneral Physics. 1904 . 768 pp .
Carhart, H . S .. . . . . . . . . University Physics. 1898 . 3 vol.
Crew , Henry . . . . . . . . . . General Physics. 1908 . 515 pp .
Duff , A . W .. . . . . . A Text- Book of Physics. 1912. 3d Ed . 686
Franklin and McNutt . , The Elements of Mechanics and Heat. ] 07
409 pp .
The Elements of Light and Sound. 1909 . 344 pp.
The Elements of Electricity and Magnetism . 1908 .
350 pp .
Ganot- Atkinson . . . . . . . Physics. 1892. 1115 pp . ( Trans.)
Hastings and Beach . . . . General Physics. 1901. 768 pp .
Hurst and Lattey . . . . . . A Text - Book of Physics. 1910 . 638 pp .
Poynting and Thomson . Text-Book of Physics. 1899 . 3 vols .
Watson , W .. . . . . . . . . . . A Text Book of Physics. 1907. 4th Ed. 928 pp .
General Physics. 1912 . 564 pp .
Reference
Frick , J . . . . . . Physikalische Technik . 2d Ed. 1909. 2 vols .
Thomson and Tait. . . . . Treatise on Natural Philosophy . 1903. 2d vol.
Weinhold , A . F . . . . . . . . Physikalische Demonstrationen . 1899. 879 pp .
Winkelmann . . . . . . . . . . Handbuch der Physik . 2d Ed. 1905 . 6 vols .
Laboratory Manuals
Adams, C . F . . . . . . . . . .Physical Laboratory Manual. 1896 . 180 pp .
Ames and Bliss . . . . . . . . A Manual of Experiments in Physics. 1898 .
544 pp .
Austin and Thwing . . . . Physical Measurement . 1896 . 198 pp .
Fer ry , E . S .. . . . . . . . . . . Practical Physics. 1903 . 331 pp .
Gilbert, N . E .. . . . . . . . . Experiments in Physics. 1907 . 155 pp .
Glazebrook and Shaw . . Practical Physics . 1894 . 633 pp .
Hall and Bergen . . . . . . . A Text - Book of Physics. 1897 . 596 pp .
Kohlrausch , F . . . . . . . Lehrbuch der Praktischen Physik . 11th Ed. 1909.
736 pp .
Kohlrausch -Waller and
Proctor. . . . . . . . .. . . .An Introduction to Physical Measurements. 1894 .
476 pp . ( Trans.)
Loudon and McLennan . Experimental Physics. 1895 . 302 pp .
Miller, D . C . . . . . . . . . . . Laboratory Physics . 1903. 403 pp .
Nichols, E . L .. . . . . . . . . A Laboratory Manual of Physics and Applied
Electricity . 1894 . 2d vol.
Ostwald , L . . . . . . . . . . . . Physiko - Chemische Messungen . 1902. 2d Ed.
490 pp .
Ostwald -Walker. . . . . . . Manual of Physico-Chemical Measurements. 1894.
254 pp . ( Trans.)
Schuster and Lees . . . . . Exercises in Practical Physics. 1901. 368 pp .
Stewart and Gee. . . . . . . Lessons in Elementary Practical Physics. * 1891.
2 vols .
Whiting, H ... . . . . . . . . . Physical Measurement. 1891. 1226 pp .
Zeleny, A ., and Erikson ,
H . A .. . . . .. .. .. . . A Manual of Physical Measurements. 1912 .
248 pp .
Laboratory Arts
Ebert, H .. . . Anleitung zum Glasblasen . 3d Ed . 1904. 120 pp .
Rowell, H . . . . . Hard Soldering. 1898 . 63 pp.
Threlfall, R . . . . . . . . . . On Laboratory Arts. 1898 .
Woollatt , G . H . . . . . . . . Laboratory Arts. 1908 ,
P .
292
HANDBOOK OF CHEMISTRY AVD PHYSICS
Light (General)
Drude-Mann
ken . . . . . .
and Milli
. . . Theory of Optics. 1902. 546 pp . ( Trans.)
Emtage , W . T . A . . . . . . Light. 1896 . 352 pp .
Hastings, C . S . . . . . . . . . Light. 1902. 224 pp .
Mann, C . R . . . . . . . . . . .Manual of Advanced Optics. 1902. 196 pp .
Preston , Thomas . . . . . . Theory of Light. 2d Ed. 1895 . 574 pp .
Schuster , A . . . . . . . . . . . Theory of Optics. 1904 . 340 pp.
Thompson , S . P . . . . . . . . Light, Visible and Invisible . 1897 . 294 pp .
Walker, James . . . . . . . . The Analytical Theory of Light. 1904. 416 pp .
R . W . Wood . . . . . . . . . . Physical Optics . 1911. 705 pp.
294
HANDBOOK OF CHEMISTRY A .VD PHYSICS
Photography
Bolas, Tallent and
. . . . . . A Handbook of Photography in Colors. 1900.
Senior. . . . . . . . . . . .
230 pp .
Derr . . . . . . . . . . . . . .. . . Photography for Students of Physics and Chem
istry . 1906 . 243 pp .
König , E .. . . . . . .. . . . . . Die Farben Photographie. 1906 . 96 pp .
Die Autochrom - Photographie . 1908. 60 pp .
Lummer - Thompson . . . . Photographic Optics . 1900 . 135 pp .
Miethe, A .. . . . . . . . . . . . Photographie nach der Natur. 1908 .
82 pp .
Rohr, Moritz von . . . . . . Photographischen Objektivs. 1899. 435 pp .
Spitta , E . . . . . . . . . Photo - Micrography . 1899. 163 pp .
Taylor, J . T ... . . .. . . . . The Optics of Photography . 1892. 242 pp .
Miscellaneous
Brauer-Walters. . . . . . . . The Construction of the Balance. 1909. 314 pp
Cajori, E . . . . . . . . . . . . . A History of Physics. 1899 . 322 pp .
Hiorns, A . H . . . . . . . Mixed Metals. 1901. 445 pp .
Knott, C . G .. . . . The Physics of Earthquake Phenomena . 1908.
283 pp .
Milham . W . I . . . . . . . . Meteorology. 1912 . 550 pr .
Moore , W . L . . . . . . . . . . Descriptive Meteorology . 1911. 341 pp .
Waldo , T . . . . . . . . . . . . Elementary Meteorology. 1896 . - 373 pp .
29.5
HANDBOOK OF CHEMISTRY AND PHYSICS
296
PROBLEMS
THE METHOD OF SOLVING CHEMICAL PROBLEMS
(From Talbot's Quantitative Analysis ,by permission.)
Detailed solutions of a few typical problems are given below .
The student should study these carefully , and assure himself that
they are fully understood .
1 . A “ chemical factor” expresses the ratio between a specific
quantity of a chemical compound and the equivalent quantity of
some other body . For example , if it is wished to determine the
weight of sulphur which corresponds to a specific weight of barium
sulphate, the latter is multiplied by the factor, or ratio , repre
S 32.07 = 0 . 1373. It may also
sented by the fraction i on Baso , or 233 .50 –
233.5 32.07
be expressed by the proportion BaSO4 : S = wt. BaSO , : x , from
which it is plain that x = 9. wt. BaSO4.
Again , if the weight of FeO in Fe2O3 is desired, the factor
hormos 2 FeO _ 144 .04
honom
A _= 00
0 . 9000. Similarly, the factor for the
omes Fe2O3 = 160.04 =
· K ,0
94 .22 == 00. 0 . 632
ga The lo
1 ,2 KCİ
conversion of KCl to K20 is - 149.12
rithmic equivalents of these values are called log factors.
In the calculation of these factors, the atomic or molecular
relations of the two substances must be kept clearly in mind ;
thus, it is plainly incorrect
Fe
to express the ratio of ferrous to ferric
l
oxide by the fraction Fe2O3,
o - since each molecule of the higher
oxide must correspond to two molecules of the lower. Careless
ness in this respect is one of themost frequent sources of error.
2 . To calculate the volume of a reagent required for a specific
operation , it is necessary to know the exact reaction which is to
be brought about, and, as with the calculation of factors, to keep
in mind the molecular relations between the reagent and the
substance reacted upon . For example , to estimate the weight of
barium chloride necessary to precipitate the sulphur from 0 . 1 gram
488.70
of pure pyrite (FeS2), the proportion should stand 2BaClg. 2 H20 :
120.16
FeS2 = x : 0 . 1, where x represents the weight of the chloride
* Talbot's " Quantitative Analysis."
297
HANDBOOK OF CHEMISTRY AND PHYSICS
required . Each of the two atoms of sulphur will form a mole
cule of sulphuric acid upon oxidation , which , in turn , will require
a molecule of the barium chloride for precipitation . To deter
mine the quantity of the barium chloride required , it is necessary
to include in its molecular weight the water of crystallization ,
since this is inseparable from the chloride when it is weighed .
This applies equally to other similar instances.
If the strength of an acid is expressed in percentage by weight,
due regard must be paid to its specific gravity . For example ,
hydrochloric acid (sp . gr. 1.12) contains 23.8 per cent HCl by
weight; i.e ., 0 . 2666 gram .
3 . No rules for universal application to “ indirect gravimetric
analyses” can be laid down . A single example will be explained .
Given a mixture of KCl + NaCl weighing 0 . 15 gram , which
contains 53 per cent chlorine, to calculate the weight of KCI
and NaCl in the mixture.
The weight of chlorine in the mixture is (0 . 15 x 0.53) or 0 .0795
gram . Assuming that this chlorine was all in combination with
potassium , the corresponding weight of KCI would be 0 . 1672
gram (Cl : KCl = 0 .0795 : 0 . 1672 ). This is an excess of 0 .0172
gram over the actual weight of the mixture, and it is plain that
this difference is occasioned by the replacement of certain of the
molecules of potassium chloride, weighing 74. 56 units, by mole
cules of sodium chloride weighing 58.50 units. To express this ,
let it be supposed that the mixture is made up of n molecules
74.56
KCl and n ' molecules NaCl; then it may be said that n KCl +
58.50 74 .56 74.56
n ' NaCl = 0 .15 gram , and n KCl + n ' KCl = 0 . 1672 gram , then
by subtracting the first equation from the second it is shown
74 .56 58. 50
that n ' (KCI - NaCl) = 0 .0172 gram . That is, the difference in
weight is equal to n ' times the difference in themolecular weights
of the two chlorides. The actualweight of NaCl present (x ) is equal
0 .0172 - 0 .0172 -
to 58.50n', or, since n ' = ,74 .56 – 58 50 , 2 = 58.50• \74. 56 - 58.50 )
This may be expressed in the form (74 .56 – 58 .50 ) : 58 .50 =
0 .0172 : x , from which x = 0 .0626 . The weight of NaCl subtracted
from that of the mixture gives the weight of KCI.
The weights of the chlorides may also be calculated algebra
ically by solving the equations x + y = 0 . 15 anda 74.56
93 . 72x% ++ 20:40
58.50 ?
= 0 .0795 , where x is the weight of KCl and y is the weight of
NaCl in the mixture:
4 . It is sometimes desirable to weigh out such a quantity of
substance for analysis , that the number of cubic centimeters of
standard solution entering into the reaction shall represent di
rectly the percentage of the desired constituent. This may be
readily done , by considering the relation of the solution to a
normal solution and the atomic or molecular weight of the desired
component. For example, suppose it is desired to calculate such
a weight for K2CO3 in pearl ash , when a half -normal acid solution
298
HANDBOOK OF CHEMISTRY AND PHYSICS
is used . Since half -normal acid and alkali solutions are equiva
lent, and since by definition the half -normal K2CO3 solution
contains 34 .55 grams per liter, each cubic centimeter of the acid
solution must be equivalent to 0 .03455 gram K2CO3. Hence,
100 cc. would neutralize 3 .455 grams pure K2CO3and this becomes
the desired weight of the pearl ash . Similarly the required weight
of limonite where the iron (Fe) is to be determined by means of
a deci-normal K ,Cr,07 solution is 0 .5602 gram .
5. One of the most frequently recurring cases in volumetric
analysis is that in which it is wished to express the value of a
specific solution in terms of some substance other than that
against which it has been standardized as for instance, the value
of a permanganate solution which has been standardized against
oxalic acid , in terms of iron . Although such problems appar
ently vary widely , there are common principles which can be
applied to them all. These are stated below , and the student
should assure himself that they are fully understood .
Suppose , for example , it is desired to find the iron value ( Fe ) of
a permanganate solution , of which 1 cc. is equivalent to 0 .006302
gram C2H204 . 2H20 .
From a comparison of the reactions it is seen that 10 molecules
of ferrous sulphate and 5 molecules of oxalic acid each react
with the same amount (2 molecules ) of the permanganate .
These two quantities being, then , equivalent to the same third
quantity, must be equivalent to each other; in other words, 10
molecules of ferrous sulphate and 5 molecules of oxalic acid
have the same reducing power. But, as stated above , the value
is desired in terms of metallic iron (Fe), not FeSO4, but as it is
plain that 10FeSO4 are equivalent to 10Fe, it is proper to make
the proportion
560.2 630.25
10 Fe : 5C2H204. 2H2O = x : 0 .006302
in which x = 0 . 005602 gram . IIere, again , as in example 2 , it is
necessary to include the water of crystallization in the molecular
weight of the oxalic acid , as it is weighed with it .
The same conclusion is arrived at, if we consider the relation of
the solution to the normal. As given , it is deci-normal and must,
therefore, be equivalent to a deci-normal solution of iron . From
the equations cited , it is seen that 10FeSO4, unite with 50 , there
fore each molecule is equivalent to 1 hydrogen atom in reducing
power. The normal solution must, then , contain 1 gram -mole
cule of ferrous sulphate, or 56 .02 grams Fe, and each cubic centi
meter of the deci-normal solution would contain 0 .005602 gram ,
the value obtained above .
Again , suppose the value of the same permanganate solution
were desired in terms of molybdenum (Mo), the reactions with
permanganate being
5M0.2019 + 17110 , 0) , = 60M0O3 + 34MnO , and
5C211.04. 211, 0 + Mn207 = 2MnO + 10CO, + 15H ,0 .
(Mn20 , is the anhydride of HMn04.)
299
HANDBOOK OF CHEMISTRY AND PHYSICS
It is plain that in these equations as they stand , the molecular
quantities of oxidizing agent are not equal. They can be made
so by simply multiplying the second equation by 17 , and they then
become,
5M012019 + 17Mn20 , = 34MnO + 60M003, and
85C2H204. 2H , 0 + 17Mn20 , = 34MnO + 170 CO2 +
255 H2O .
It is now possible to reason in the same way as before, and to
conclude that 85 molecules of the oxalic acid have the same reduc
ing power as 5 molecules of the oxide M012019, or 60 atoms of
molybdenum . Accordingly,
5758.8 10714 .25
60Mo : 85C2H204.2H20 : : 2 : 0 .006302
in which x 0 . 003387 gram .
Since 5M012019 unite with 850 , a normal solution of the former
as a reducing agent, would contain 1 / 170 . of the 5 gram -molecules
or 33.87 grams Mo, and the deci-normal solution 3.387 grams per
liter. This agrees with the values already obtained .
6 . It is sometimes necessary to calculate the value of solutions
according to the principles just explained , when several succes
sive reactions are involved . Such problemsmay be solved by a
series of proportions, but it is usually possible, after stating these
to eliminate the common factors and solve but a single one.
For example , suppose it is desired to express the value of a
permanganate solution , of which 1 cc. = 0 .008 gram iron ( Fe), in
terms of calcium oxide (CaO ) . The reactions involved in the
volumetric determination of calcium are the following ; CaCl2 +
(NH4)2C204 = CaC204 + 2NH4Cl; CaC204 + H2SO4 + 2H20 =
CaSO4 + C2H ,04. 2H20 ; 5C2H204 . 21 , 0 + 2KMnO4 + 3H2SO4
= K2SO4 + MnSO4 + 10CO2 + 18H20 .
From the considerations stated under 5 , the following propor
tions may be made .
10Fe : 5C , H ,04 . 2H2O = 0 .008 : x
5C2H204. 2H20 : 5CaC204 = x : Y
5CaC204 : 5CaO = y : x
Canceling the common factors, there remains simply
560 .2 280.4
10Fe : 5 Ca0 = 0.008 : 2
Similarly , from the reactions, the equivalent of the iodine liber
ated may be calculated in terms of MnO2 as follows: Supposing
the weight of iodine to be 0 . 5 gram then
21 : 2KI = 0 .5 : x
2KI : 2C1 = x : y
2Cl : 2HCl = y : %
2HCl : MnO2 = 2 : W
Canceling the common factors, there remains
21 :MnO , = 0.5 : w
300
HANDBOOK OF CHEMISTRY AND PHYSICS
To solve such problems as 5 and 6 , it is necessary to know the
reactions involved , and the way in which the various components
break up ; then to compare the reactions and to search for those
molecular quantities of the compounds in question , which are
equivalent in their action upon a common agent. Having found
these , as shown above, express the molecular ratio between them
253.7 86.99
in the form of a proportion ; as, for example, 2 I : MnO2 = 0.5 : w .
86 .99
Expressed in the form w = 0 , - 0 .5 , it is plain that this ratio is
in no way different in principle from the chemical factor men
tioned in paragraph 1 ; indeed , it is the factor for the conversion
of iodine to manganese dioxide.
304
INDEX
PAGE
Abberation, chromatic , definition . . . . . 208
" spherical, definition . . . 208
Absolute humidity, definition . . . 205
Absolute zero , definition . . . . . . .. . . . 204
PAGE
Apothecaries fluid measure .. . . . . . . . . . . 233
.
weight. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . wu
. . . . . . . . . . . . 234 234
Apparatus list for experiments in chemistry . . . . 283
283
.
" " physics . . , 284
.
Archimedes' principle, formula . . . . . . . . . . . . . . . . . 215
.
Area of circles, table . . . . . . . . . . . . . . . . . . . . . . . 280
" " various regular figures.. . . . . . . . . . ... . . 257
Area, table of units . . . . . . . . . 235
unit of. . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 201
Atmosphere , mass , composition and potential. . . . .. .. . . ... .. . . . . . . . . . 189
Atom , definition . . . . . . 198
Atomic theory .. . . . .. 197
" weights . . . . . . . . . . . . .. . 11
Avogadro 's theory . . . . . . . . . . . . . . . . . . . . . .. . ... .. . .. 197
Avoirdupois weight . . .. . . 234
в
Balanced action , definition . . . . . . . 198
Balance , sensitiveness of, formula .. . . . . . . .. . 213
Barometer, altitudes with, formula.. . . . . . . . . . . . . . . . . 215
Barometer readings, conversion table for. 129
" reduction to latitude 45°. . . . . . . 134
reduction to sea level. . . . . . . . . 133
temperature corrections for.. . . . . . . . . . 130 , 131, 132
Base, definition .. . .
Base , definition . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 198
198
Base of natural logarithms. . . . . . 282
Beaumé hydrometer scale, conversion to density . . . . .. 77
Bibliography of chemistry . . . . . . . . . . . . . . . . . . . . . . . 288
" physics. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 291
Boiling-point for various substances.. . . . . . . . . . . . . . . . . . . 110
" of
U inorganic CUIIPUUL
ILIUIKUIC compoundsOS .. .. .. .. .. . . . . . . . . . . . . . .
21
" " water, variation with pressure . . . . . . . . 106
Boyle's Law . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 196
196
" " formula . . . . . . . . . .. .. . . . . .. . ... . .. .. .. .. .. .. .. .. .. . .. . 215
215
Brilliancy , intrinsic . . . . . . . . . . . 162
British standard wire gauge . . . . . . . . . . 247
Brown and Sharpe wire gauge . . . . . . . . . . . . . . . . . . . . . . . . . . 248
Bulk modulus . . . . . . . . . . . 85
PAGE
Cells, internal resistance .. . . 155
Cements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 224
Centrifugal force, definition . .. . . . . 202
" " formula . . . . . . . . 211
Centripetal force, definition . . .. 202
Change of volume due to fusion . . . 115
Charge, unit , definition . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205
205
Chemical equations . . . . . . . .. . 199
" laws and definitions. . . . . . 196
" theories. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 197
Chromatic abberation , definition . . . . . . . . . . . . 208
Circles, area of. . . . . . . . . . . . . .
" inscribed and circumscribed for regular polygons. . . .
Circular motion, formulæ . . . . . . . . .
Circumference of circles , table. . . . . . . . .
Cleaning mercury . . . . . . . . . . 225
" optical surfaces for silvering . . . . . . 225
Coefficient of friction . . . . . . . . . . . . . . . . . . . . . . 88
PAGE
Critical temperature , pressure , and other constants for gases . . . . 111
Cross -hairs . . . . . . . . .. 226
Cross-section and mass of wire . . . . . . . . . . . . . . . 254
Cryohydrate , definition . . . . . 198
Crystalline form of inorganic compounds. . . . . . . . . . . . . . . . 20
Cube roots , table . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. ... .. ... 280
Cubes, table . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 280 280
Cubical expansion coefficients. . . . . . . . . . 99, 100 , 101
Current, electric, definition . . . . . . . . . . . 207
" maximum safe for copper wire. . .. . . . . . . . . 150
26 2
Cylinder, area of surface and volume. . . .. . . . . . . . . . . . . . . . . . . . . .
D
D alton ' s law . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. .. .. .. .. . . 196
190
. .
Date of discovery of the elements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
15
. . . . . . . . . .
Declination , magnetic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 158
" definition . . . . . . . . . . . . . . . . . 207
Declination of the sun and equation of time. . . . . 187
Definitions of chemical terms.. . . . . . . . . . . . . .
198
198
" physical terms. . . . . . . . . . . . . . . . . . 201
Definite proportions, law of. . . . . . 196
Density . . . . . .. . 76 to 84
definition . . . . . . . . . . 201
of air . . . . . . . ..
“ alcohol. . . . . . . . . . . .
“ aqueous solutions . . . . .
“ gases in solid and liquid m .. .
" mercury . . . . . . . .
“ various liquids.. . . . . . .
" " solids. . . . . . . . . . . . . . . . . .
" water , absolute . . . . . . . .
" " maximum . . . . . . .
" " relative . . . . . . . . .
Derivation of the elements.. . . . . . . . . . . . . . . . . . . .
14
юст
Elements, derivation of.. . . .. . .
от
е
discoverers of. . . . . .
melting-point of. . . . .
periodic table of.. .. . .
physical constants of. . . .
14
specific gravity of. . . . . .
symbols for. . . . . . . . . . . . . .
كه
.
valence of . . . . . . . . . . . .
.
هارن
when and where found . . . . . . . :
309
INDEX
PAGE
Foods, functions and uses.. . . . . . . . . 73
Force between two static charges, formula . . . . 218
“ “ magnetic poles, formula . . . .. . 219
“ definition . . . . .. . 202
“ formula . . . . . . . . . . 211
Formulæ of inorganic compounds. . . . . : 20
" of mens ration .. . . . 257
Formulæ , physical . . . . . . . . . . . . 209
Formulæ , trigonometrical. . . . . . . . . . . . 263
Foucault 's pendulum , formula .. . . . . ... 212
Fraunhofer lines, wave length of.. . . . . . . . 163
Freezing mixtures. . . . . . . . . . . . . . . . . . . 112
Friction , coefficient of. . . . . . . . . . . . . . . . 88
Fuels , heat value of. . . . . . . . . . . . . . . . . .
Functions and uses of foods.. . . . . . . . .
Fusion , heat equivalent of. . . . . . . . . . . . 113
temperature of, various substances.. . . . .. . . .... .... .. 110
.. .. . 1155
11
volume change due to.. . . . . . . . . .
H
Hall effect . . . . . . . . . .. 156
Halos, angular radius of . . . . . . . . . . . . 189
Hardness, scale and table. . . . . . . . . . . 90
Heat conduction , formula . . . . . . . . . . . . . . . 217
conductivity of substances. . . . . . . . . 126
definition . . . . . . . . . . 204
effect of electric current, formula . . . . . 221
" equivalent, definition . . . . . . . 204
of fusion , table . . . . . . . . . . . .... 113
of vaporization, table. .. . . . . . . .. .. 114
310
INDEX
PAGE
Heat of combustion , definition . . . ... .. 198
" specific , tables. . . . . . . . . . . . . . .. . . . . 104 to 109
" " formulæ . . . . . . . . . . . .. . . . . . .. . . . .. .. . . . . . .. . . . . 217
" value of fuels . . . . . . . . . . . . . . . 128
Hefner unit . . . . . . . . 160
Henry 's law . . . . . 196
Hess ' s law of heat summation . . . . . . . . . . . . . . . . . . . . . 196
High and low temperatures attained . . . . . . . .
High temperatures, fixed points for calibration . .
Horizontal intensity of the earth 's magnetism . . .
Humidity , absolute, definition . . . . . . . . . . . . . . . . . . 205
Joule, definition . . . .. . .
K
Kinetic energy , definition . . . . . . . .. .
Kinetic theory of gases, constants of. . . . . . . . . . . . 123
311
INDEX
PAGE
MI
PAGE
Melting -point of the elements . . . . . . . . . ... 15
“ “ ice, variation with pressure . . . 110
" inorganic compounds. . .. 21
" " various substances . . . . . . . . ... 110
Mensuration formulæ . . . . . . . . .. . . 257
Mercury , density and volume, table. . . . . . . . . . . . . . . . . 81
" to clean . . . . . . . . . . 225
Meteorological data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 189
. . . 282
Natural logarithms, formula for obtaining . . . . . . . . . . . . . . . .
" trigonometric functions , table . . . . . 270
Nitric acid , density of aqueous solutions.. . . . . . . . . . . . . . . . . . . . . 66
313
INDEX
PAGE
PAGE
Solar constant.. . . . . . . . . . . . . . . . . . . 189
189
" system , data concerning the.. . . . . . . .. .. . .. .. . 188
Solders . . . . . . . . . . . . . . .
Solid angle . . . . . . . . . . . . . . . . 201
Solubility of inorganic compounds . 21
. . 198
product, definition .. . . .
tables . . . . . . . . . . . . . . . . . • 51
Sound , definition of terms . . . . . . . . . . . . • 205
" velocity in air . . . . . . . . . . . . . . . . . . . . . ..
“ of propagation , formula . . . . . . . . . . . . 217
• " table
av e .. .. .. .. .. ... . .. ..
. . . . . . . . . . . . . . . . . . . . . 138
Sparking potential or dielectric strength of air .. . . . . . . . . . 141
• for various insulators . . . . . . . . . . . . 145
Specific gravity, definition . . . . . . . .
of gases. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
" “ inorganic compounds. . . . . . . . . . . . . . . . . . . 21
" the elements . . . . . . . . . . . 14
: : : : : : : : : : : : : : : :
“ gases . . . . . . . . . . . 109
“ “ liquids.. . . . . . . . . . . 108
“ “ mercury . . . . . . . . . . . . . . . . . . . . 104
solids. . . . . . . . . .. . 107
" " water . . . . . . . . ... 104
inductive capacity , definition . . . . . .. .. 206
1 tables. . . . . . . . . . . . . . . . . . . . . . . . ... 142
resistance , definition . . . . . . . . . . . . .. . 207
and temperature coefficient for metals . . . . . . . . . . . . 149
rotation , formula . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 223
" table . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 181
Spectroscopic calibration , table of wave lengths for . . . . 163
Spectrum lines , wave lengths for various elements . . 164
Speed , definition .. . . . . . . . . . 202
Sphere, surface and volume. . . . . . . . . . . . . . . . . . . . 261
Spherical aberration , definition . . . . . 208
m irrors, formulæ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 222
polygon , area of. . . . . . . . .. 262
segment, area of curved surface and volume, formulæ . . . . . . 262
triangle , area of, formula . . . . . . . . . . . . . . 262
Spheroids, surface and volume. . . . . . . . . 262
Spherometer readings, to reduce, formula . . . . . . . . 222
Square roots, table . . . . . . . . . .. 280
Squares, table .. . . . . . . . 280
Standard cells, electromotive force and composition . . . . .
" candles . . . . . . .
Stars, mean places of.. . . . . . . .
Static electricity , definition and units. . . . . . . 205
316
INDEX
PAGE
Τ
Tangent galvanometer, formula . . . . . . . . . . . . . . 222
Temperature, definition . . . . . . . . . .. . .
corrections for barometer readings
Temperatures, fixed points for calibration .. .. .. .. .. .. .. .. . . . . . . . . . . . . .. .. . 115
" high and low , attained by various means. . . . . . . . 128
Temperature-resistance coefficient, definition . . . . 207
" table .. . . . . . . . .. 149
Tensile strength of metals . . . . . . .. 89
Tension of aqueous vapor.. . . . . . . . . . . . . .. .. . . . . . . . . . . . . . . . . . . . . . . . 116
Thermal capacity, definition . . . . . . . . .... 204
conductivity , definition .. . . 204
" expansion , definition . . . . . . . . . .. 204
formulæ . . . . . . . . . . 216
coefficients.. . . . . .
Thermoelectric power . . . . 152
Thermometer scales, conversion of. . . . .. 96
Time, table of units. . . . . 234
" unit of. . . . . . . . . . . . 201
Torque, definition . . . . 202
o formula . . . . . . . . . 211
Tractive force of a magnet, formula . . . .. .. .. .. . .. . 220
220
Transmissibility for radiations, glass . . . 178
Transparency coefficient.. . . . . . . . . . 178
Triangle , area of.. . . . . . . . .. . . . . . . . . . 257
Trigonometrical formulæ . . . . . . . . . . . 263
" functions, tables . . . . 270
Troy weight, table .. . . . . . . . . 234
Twaddell hydrometer scale, conversion to density 78
Twist drell and steel wire gauge. . . . 245
U
Universal
UM Y wax .. .
EIsal Was . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. ... . 231
Viscosity , definition. . . . .
IV O U . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 203
forme
formula . . . . . . . . . . 214
tables . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 93
Volt, definition . . .. . . . . 206
Voltaic cells, electromotive force and composition .
" internal resistance
vance .. .. .. .. .. .. .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . 155
volume, relative . . . . . . . . . . . . . . . . . . . . . . .. 80
Wave length of the Fraunhofer lines . . . . . . . . . . . . 163
" lengths for spectroscopic calibration . . . . . . . . . . . . . . . . . . .
" of the principal lines of various elements . . . . . . . . . .. . . . 164
" " the red cadmium line. . . . . . . . . . . 195
" ' various radiations. . . . . . . .
motion , formula . . . . . . . . . . . . . . . . . . . . . . . . . . 217
Wax, soft (universal) . . . . . . . . . . . . . . . . . . . . . . . . 231
Weighing, double , formula . . . . . . . 213
Weight, definition . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 202
" formula . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -
Weights and measures , metric system , .. . .. . IIIIIIIIIIIIIIIII . . . . 250
318
INDEX
PAGE
Wet and dry bulb thermometer readings, table for the reduction of. . . 137
Wire , cross-section and mass . . . . . . . . 252
diameter and cross- section, B . and S . gauge. . .. . . . . . . . . 248
mass and resistance for copper . . . . . . . 248
" for platinum .. . . . . . . .
resistance for aluminum .. . . . . . . . . .
gauge, British Standard .. . . . . . 247
" Brown and Sharpe . . . . . . 248
1 " Stub ' s . . . . . . . . . . . . . . . . 246
gauges, comparison of. . . . . . . . . . . 244
table , platinum . . . . . . . . . . . . 256
Wheatstone's bridge, formula . . . . . . 221
Wood stain , acid proof. . . . . . . . 224
Work , definition .. . . . . . . . . . . . . . 203
" formula . . . . 212
319
CHEMICAL RUBBER COMPANY
RUBBER TUBING
25 19 17
22 16 14
2Ors
17 13 8
Pure Gum Tubing carried in stock in and I in . All other sizes not
listed , made to order.
221
CHEMICAL RUBBER COMPANY
RUBBER STOPPERS
Approximate No.
Order by Diameter Diameter
No . of Stoppers at Top . at Bottom . Length .
per Pound .
h
150 per lb . 1 in .
Ic
80
ole
65
50
40
w
: :: :: : :: :
le
hole
ole
2
1
322
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32044 019 690 874