IS 1052 MIO Part.a PDF
IS 1052 MIO Part.a PDF
R10 Flammable.
R36/38 Irritating to eyes and skin.
R43 May cause sensitisation by skin contact.
Harmful to aquatic organisms, may cause long-term adverse effects in the
R52/53
aquatic environment.
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According to 1999/45/EC
Irritant
P. Phrases;
Contains epoxy constituents. See information supplied by the manufacturer.
If the product contains substances that present a health hazard within the meaning of the Dangerous
Substances Directive 67/548/EC, or have occupational exposure limits detailed in EH40, these substances
are listed below.
67/548/EEC EC No. 1272/2008
Ingredient/Chemical Designations Weight % Notes
Classification Classification
Epoxy resin (av.mol.wt.<700) 10 - < 25 R43 Xi;R36/38 N;R51- Eye Irrit. 2;H319
CAS Number: 0025068-38-6 53 Skin Irrit. 2;H315 [1]
EC No. 500-033-5 Skin Sens. 1;H317
Index No.: 603-074-00-8 Aquatic Chronic
REACH Reg. No.: 01-2119456619- 2;H411
26-xxxx
Xylene 2.5 - < 10 R10 Xn;R20/21 Xi;R38 Flam. Liq. 3;H226 C
CAS Number: 0001330-20-7 Acute Tox. 4;H332 [1][2]
EC No. 215-535-7 Acute Tox. 4;H312
Index No.: 601-022-00-9 Skin Irrit. 2;H315
REACH Reg. No.:
Epoxy resin (MW 700 - 1000) 1 - < 2.5 Xi;R36/38 R43 Eye Irrit. 2;H319
CAS Number: 0025036-25-3 Skin Irrit. 2;H315, [1]
EC No. Skin Sens. 1;H317
Index No.:
REACH Reg. No.:
Butan-1-ol 1 - < 2.5 R10 Xn;R22 Xi;R37/38- Flam. Liq. 3;H226
CAS Number: 0000071-36-3 41 R67 Acute Tox. 4;H302 [1][2]
EC No. 200-751-6 STOT SE 3;H335
Index No.: 603-004-00-6 Skin Irrit. 2;H315
REACH Reg. No.: 01-2119484630- Eye Dam. 1;H318
38-xxxx STOT SE 3;H336
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*The full texts of the phrases are shown in Section 16.
Skin
Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognised skin
cleanser. Do NOT use solvents or thinners.
Eye
Irrigate copiously with clean fresh water for at least 10 minutes, holding the eyelids apart and seek medical
attention.
Ingestion
If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
No data available
4.3. Indication of any immediate medical attention and special treatment needed
No data available
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Ventilate the area and avoid breathing vapours. Take the personal protective measures listed in section 8.
Contain and absorb spillage with non-combustible materials e.g. sand, earth, vermiculite. Place in closed
containers outside buildings and dispose of according to the Waste Regulations. (See section 13).
If drains, sewers, streams or lakes are contaminated, inform the local water company immediately. In the
case of contamination of rivers, streams or lakes the Environmental Protection Agency should also be
informed.
In Storage
Handle containers carefully to prevent damage and spillage.
Naked flames and smoking should not be permitted in storage areas. It is recommended that fork lift trucks
and electrical equipment are protected to the appropriate standard.
Smoking, eating and drinking should be prohibited in all preparation and application areas.
Never use pressure to empty a container; containers are not pressure vessels.
Store in a well ventilated, dry place away from sources of heat and direct sunlight.
Store on concrete or other impervious floor, preferably with bunding to contain any spillage. Do not stack
more than 3 pallets high.
Keep container tightly closed. Containers which are opened must be carefully resealed and kept upright to
prevent leakage. Keep in the original container or one of the same material.
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published in EH40.
Material Short term (15 min. ave) Long term (8hr TWA) Comments
ppm mg/m3 ppm mg/m3
Butan-1-ol 50 154 - - +
Xylene 100 441 50 220 +
DNEL/PNEC values
No Data Available
Eye/face protection
Wear safety eyewear, e.g. safety spectacles, goggles or visors to protect against the splash of liquids.
Eyewear should meet the requirements of standard EN 166.
Skin protection
For prolonged or repeated contact use protective gloves. Barrier creams may help to protect the exposed
areas of skin, they should however not be applied once exposure has occurred. Skin should be washed
after contact.
Use chemical resistant gloves classified under Standard EN 374: Protective gloves against chemicals and
micro-organisms. Recommended gloves: Viton® or Nitrile
Breakthrough Time: 480 min
When prolonged or frequently repeated contact may occur, a glove with a protection class of 6
(breakthrough time greater than 480 minutes according to EN 374) is recommended. When only brief
contact is expected, a glove with a protection class of 2 or higher (breakthrough time greater than 30
minutes according to EN 374) is recommended.
NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace
should also take into account all relevant workplace factors such as, but not limited to: Other chemicals
which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection),
potential body reactions to glove materials, as well as the instructions/specifications provided by the glove
supplier.
The user must check that the final choice of type of glove selected for handling this product is the most
appropriate and takes into account the particular conditions of use, as included in the user's risk
assessment.
Other
Overalls which cover the body, arms and legs should be worn. Skin should not be exposed. Barrier creams
may help to protect areas which are difficult to cover such as the face and neck. They should however not
be applied once exposure has occurred. Petroleum jelly based types such as Vaseline should not be used.
All parts of the body should be washed after contact.
Respiratory protection
If workers are exposed to concentrations above the exposure limit they must use the appropriate,certified
respirators.For maximum protection when spraying this product it is recommended that a multi layer
combination type filter, such as ABEK1, is used. In confined spaces use compressed air or fresh air
respiratory equipment.
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Thermal hazards
No Data Available
10.1. Reactivity
No data available
10.2. Chemical stability
Stable under recommended storage and handling conditions (see section 7).When exposed to high
temperatures may produce hazardous decomposition products such as carbon monoxide, carbon dioxide,
oxides of nitrogen and smoke.
Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid possible
exothermic reactions.
10.3. Possibility of hazardous reactions
May react exothermically with: oxidising agents, strong alkalis, strong acids.
10.4. Conditions to avoid
Stable under recommended storage and handling conditions (see section 7).
10.5. Incompatible materials
Keep away from the following materials: oxidising agents, strong alkalis, strong acids.
10.6. Hazardous decomposition products
Fire will produce dense black smoke. Decomposition products may include the following materials: carbon
monoxide, carbon dioxide, smoke, oxides of nitrogen.
Avoid exposure and use breathing apparatus as appropriate.
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Acute toxicity
Exposure to solvent vapour concentrations from the component solvents in excess of the stated
occupational exposure limits may result in adverse health effects such as mucous membrane and
respiratory system irritation and adverse effects on the kidneys, liver and central nervous system.
Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme
cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin
resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed
through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible
damage.
Based on the properties of the epoxy constituents and considering toxicological data on similar
preparations this preparation may be an irritant and a skin and respiratory sensitiser. Low molecular weight
epoxy constituents are irritating to eyes, mucous membranes and skin. Repeated skin contact may lead to
irritation and sensitisation, possibly with cross-sensitisation to other epoxies. Skin contact with the
preparation and exposure to spray mist and vapour should be avoided.
Inhalation
Inhalation
Oral LD50, Skin LD50, Dust/Mist
Ingredient Vapour LD50,
mg/kg mg/kg LD50,
mg/L/4hr
mg/L/4hr
Butan-1-ol - (71-36-3) 2,292.00, Rat 3,430.00, Rabbit Not Available Not
Available
Epoxy resin (av.mol.wt.<700) - (25068-38- 2,000.00, Rat 2,000.00, Rabbit Not Available Not
6) Available
Epoxy resin (MW 700 - 1000) - (25036-25- Not Available Not Available Not Available Not
3) Available
12.1. Toxicity
The preparation has been assessed following the conventional method of the Dangerous Preparations
Directive 1999/45/EC and is classified for eco-toxicological properties accordingly. See Sections 2 and 3
for details.
Aquatic Ecotoxicity
Epoxy resin (MW 700 - 1000) - Not Available Not Available Not Available
(25036-25-3)
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Butan-1-ol - (71-36-3) 1,328.00, Daphnia 500.00 (96 hr), Scenedesmus
1,376.00, Pimephales magna subspicatus
promelas
Using information provided in this data sheet advice should be obtained from the Waste Regulation
Authority, whether the special waste regulations apply.
The European Waste Catalogue Classification of this product, when disposed of as waste is 08 01 11
Waste paint and varnish containing organic solvents or other dangerous substances. If mixed with other
wastes this code may no longer apply and the appropriate code should be assigned. For further
information contact your local waste authority.
EmS F-E,S-E
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No further information
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not Applicable
EU Legislation
REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL on
classification, labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
IMPORTANT NOTE: the information contained in this data sheet (as may be amended from time to time) is
not intended to be exhaustive and is presented in good faith and believed to be correct as of the date on
which it is prepared. It is the user's responsibility to verify that this data sheet is current prior to using the
product to which it relates.
Persons using the information must make their own determinations as to the suitability of the relevant
product for their purposes prior to use. Where those purposes are other than as specifically recommended
in this safety data sheet, then the user uses the product at their own risk.
MANUFACTURER’S DISCLAIMER: the conditions, methods and factors affecting the handling, storage,
application, use and disposal of the product are not under the control and knowledge of the manufacturer.
Therefore the manufacturer does not assume responsibility for any adverse events which may occur in the
handling, storage, application, use, misuse or disposal of the product and, so far as permitted by applicable
law, the manufacturer expressly disclaims liability for any and all loss, damages and/or expenses arising
out of or in any way connected to the storage, handling, use or disposal of the product. Safe handling,
storage, use and disposal are the responsibility of the users. Users must comply with all applicable health
and safety laws.
Unless we have agreed to the contrary, all products are supplied by us subject to our standard terms and
conditions of business, which include limitations of liability. Please make sure to refer to these and / or the
relevant agreement which you have with AkzoNobel (or its affiliate, as the case may be).
© AkzoNobel
The information in this Health & Safety Data Sheet is required pursuant to EC Regulation 1907(2006) and
the Chemicals (Hazard Information & Packaging for Supply) Regulations 2009.
The full text of the R, H & EUH phrases appearing in section 3 is:
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H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness and dizziness.
H411 Toxic to aquatic life with long lasting effects.
R10 Flammable.
R20/21 Harmful by inhalation and in contact with skin.
R22 Harmful if swallowed.
R36/38 Irritating to eyes and skin.
R37/38 Irritating to respiratory system and skin.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R43 May cause sensitisation by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R67 Vapours may cause drowsiness and dizziness.
This is the first revision of this SDS format, changes from previous revision not applicable.
End of document
Your attention is drawn to the disclaimer on the Product Data Sheet which with this Safety Data
Sheet and the package labelling comprise an integral information system about this product. Copies
of the Product Data Sheet are available from International Paint on request or from our Internet
sites : www.yachtpaint.com , www.international-marine.com, www.international-pc.com
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