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Time: 1 Hrs Max. Marks: 75 Single Correct: OH H OH H CH Oh CH Oh O
Time: 1 Hrs Max. Marks: 75 Single Correct: OH H OH H CH Oh CH Oh O
Marks: 75
Single correct
Q.1 Monomer used to prepare Orlon is: [7 × 3=21]
(A) CH2=CHCN (B) CH2=CH–Cl (C) CH2=CHF (D) CH2=CCl2
Q.5 How many products are produced respectively when optically pure glucose and fructose are reduced
one by one by NaBH4.
(A) 1 & 1 (B) 2 & 2 (C) 1 & 2 (D) 2 & 1
Page No.1
Q.7 N H 3 – CH(R)– CO2H has its Ka1 = 10–7. The isoelectric point of the -amino acid occur at pH = 8.2
hence pKa2 of the conjugate acid of -amino acid is equal to
(A) 9.4 (B) 1.2 (C) 7.6 (D) 2.4
Comprehension [3 × 3 = 9]
Question No. 8 to 10 (3 questions)
A research scholar synthesised the compound A in the laboratory
A:
He wanted to study this compound in acidic medium and kept for some time in it. After an hour, when
isolated the compound, to his surprise, he got the mixture of two compounds B, C. He studied their
properties and compared them with A.
A B C
reaction with HaHCO 3 brisk effervescence no no
blue litmus red no no
NaOI no no yellow ppt.
[Ag(NH 3) 2] no no silver - mirror
B C carbon 54.55%,
H3O
clue original A
hydrogen 9.1%
Q.8 B formed is
Q.9 Compound C is
O
||
(A) CH 3CCH 3 (B) CH3CH2CHO (C) HCHO (D) CH3CHO
Q.10 B is formed due to
(A) cleavage of C–O bond followed by esterification between –COOH and –OH present.
(B) decarboxylation of –COOH group
(C) oxidation of –CH2COOH into –COOH
(D) none
Page No.2
Me Me Me
| | conc.H 2SO 4 |
Q.12 Statement-1: Me C CH 2 C Me
Me 3C CH CMe 2 + Me3C CH 2 C CH 2
| | P1 P2
Me OH Major
Q.16 + PhN 2 Cl– ? H
3O
Page No.3
Match the column [14]
Q.17 Column I Column II
H 2O Cu Cl
(A) Mg2C
3 A2
2 ? (P) Purple colour
NH 4OH
neutral
O3 Cr2O3 Oleum ( i ) NaOH ,
(B) HexaneAl
2 B C D FeCl
3 ? (Q) Yellow colour
( ii ) H
Et SO air FeSO
(C) Ethanol 2
4 E F 4 ? (R) Red colour
hv KCNS
O
NK
Na Br O
(D)
Ethylpropandioate G 2 H
I (S) No colour
3 H O
J Ninhydrin
?
Subjective [2 × 5 = 10]
Q.18 Reaction :–1 CH3–CH2–CH2–CH2–CH3 Cl
2 Optically active monochloro product(s) are (R)
h
Cl
Reaction :–2 2 Optically active di-chloro product(s) are (S)
h
Cl
Reaction :–3 2 Optically active di-chloro product(s) are (P)
h
Q.19 (reaction-1)
( i ) x CH MgBr
3
( ii ) H 3O
( i ) y CH MgBr
3 (reaction-2)
( ii ) H3O
O OH
|| | (reaction-3)
Et O C O Et ( i ) z PhMgBr
Ph C Ph
( ii ) H |
Ph
What is the value of x + y + z = ?
Page No.4
Answers
1. A 2. D 3. B 4. C
5. C 6. C 7. A 8. A
18. 9 19. 12