IUPAC & NOMENCLATURE

BY VINEET KHATRI SIR

CLASS-XI TIME : 35 MIN. DPP. NO.1

Single Choice Questions :

1. Which of following is 3° (tertiary alcohol)

OH OH OH
(A) (B) (C) (D) All

IR
2. Which of following is 1° amine ?

NH2 CH3

IS
(A) (B) CH3 – C – NH2 (C) CH3 – NH2 (D) All
CH3

R
3. Which of following is 3° amine ?

CH3
(A) CH – N
3
(B) CH3 – NH – Et
AT (C) CH3 – NH – CH3 (D) CH3 – NH2

CH3
H
4. and
K

Number of secondary carbon atoms present in the above compounds are respectively:
(A) 6, 4, 5 (B) 4, 5, 6 (C) 5, 4, 6 (D) 6, 2, 1
T

5. Number of 1°, 2° and 3° hydrogen in isooctane is:

EE

(A) 9,8,1 (B) 12,5,1 (C) 15,2,1 (D) None of these

Multiple Choice Question :

6. Which of the following compound contain only 1 type of carbon atom

N
VI

(A) (B) (C) (D)

7. Which of the following compound contain only 2 types of carbon atom

N N

(A) (B) N N (C) (D)

N N
8. Classify the following alcohols as primary, secondary, or tertiary:
(a) (CH3)3CCH2OH (b) CH3CH(OH)CH(CH3)2

(c) (CH3)2C(OH)CH2CH3 (d)

(e)

9. Classify the following amines as primary, secondary, or tertiary:

(a) CH3NHCH(CH3)2 (b) CH3CH2CH(CH3)CH2NH2
(c) (CH3CH2)3N (d) (C6H5)2CHCH2NHCH3

IR
(e) (f)

IS
“A positive attitude brings much gratitude! Think positive,

R
be positive, speak positive and stay positive!
AT
Do it every day and DO IT BIG!!!”
H
K
T
EE
N
VI
 IUPAC & NOMENCLATURE
BY VINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.2

O
CH3
CH–2 CH=CH – C – Cl

1. N
O
CH–2 CH3

IR
(a) Find out the total number of 1° hydrogen. (b) Find out the total number of 2° hydrogen.
(c) Find out the total number of 3° hydrogen. (d) Find out the total number of 1° carbon.
(e) Find out the total number of 2° carbon. (f) Find out the total number of 3° carbon.

IS
(g) Find out the total number of 4° carbon.
(h) Find out the total number of functional groups.
(i) Find out the number of degree of unsaturation.

R
OH
H
2.
OO AT
NH2 NH2
NH
O
H
(a) Find out the total number of 1° hydrogen. (b) Find out the total number of 2° hydrogen.
K

(c) Find out the total number of 3° hydrogen. (d) Find out the total number of 1° carbon.
(e) Find out the total number of 2° carbon. (f) Find out the total number of 3° carbon.
(g) Find out the total number of 4° carbon. (h) Find out the total number of functional groups.
T

(i) Find out the number of degree of unsaturation.

EE

3.
I IV
II III
N

Find out the number of 1°, 2° & 3° carbon atoms in the above compounds.
VI

4. Match the column :

Column I Column II
CH3
(A) CH3—CH2—N (P) 1° Carbon
H
(B) CH2 = CH – CH3 (Q) 2° Carbon

(C) (R) 3° Carbon

OH
(D) (S) 4° Carbon

“Follow your dreams; they will give meaning to every step that you take.”
 IUPAC & NOMENCLATURE
BY VINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.3

Calculate DBE value -

–
COO

1. 2. 3.

IR
COOH
H OH
4. 5. 6. H OH

IS
COOH

R
O
||
7.
||
NH 8. AT 9.

O
H
10. 11. .. 12.
N
K

H
T

CN
CH3
EE

H Br
13. 14. 15.
H Br
|| CH3
O
N

O O
VI

OH
16. 17. 18.

19. 20. 21. C9H16 NOCl

COOH
COOH

“Set your goals where the sky is the beginning and if

you land anywhere in between, you are doing Great”
 IUPAC & NOMENCLATURE
BY VINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.4

Calculate DBE value -

1. 2. N 3. HCOO

IR
H2C
H3C

IS
4. 5.

CH2

R
CH3
AT
O
O
H
O OH
HO
HO N(CH3)2
K

OH

6. 7. O O
T

O
O O
O
EE

O OCH3
O
erythromycin
N
VI

8. 9.

“The future is my canvas. Now I

have to paint the right picture”
 IUPAC & NOMENCLATURE
BY VINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.5

1. How many ether is/are possible for molecular formula C4H10O.

(A) 1 (B) 2 (C) 3 (D) 4
2. How many ketone is/are possible for molecular formula C4H8O
(A) 1 (B) 2 (C) 3 (D) 4
3. How many alcohol is/are possible for Molecular farmula C4H10O (only structural)
(A) 2 (B) 3 (C) 4 (D) 5

IR
O
O–H
4.

IS
O

Number of Functional group in above compound is

(A) 3 (B) 4 (C) 5 (D) 6

R
5. The functional groups in Cortisone are : HOH2C
(A) Ether, alkene, alcohol CH3 OCH3
AT O
(B) Alcohol, ketone, alkene, ether
(C) Alcohol, ketone, amine
(D) Ether, amine ketone
H
O O Cortisone
O
K

O–H
6. H SH
OH
OH
T

How many types of functional groups are present in given compound.

EE

(A) 6 (B) 5 (C) 4 (D) 7

CH3 O

7. Present functional group is

N

O CH3
VI

(A) ketone (B) ester (C) ether (D) alcohol

8. Present functional group is/ are
O O
||
OCCH3

O
(A) ketone (B) ester (C) ether (D) A and B both

"Histroy tells stories about great men from the past so

write your story now."
 IUPAC & NOMENCLATURE
BY VINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.6

1. Circle the functional group & also find out the degree of unsaturation
O
H
N H
N
O H
(i) (ii) O
N O
Me

IR
OH O
O
O Cl
(iii) (iv)

IS
H
H
O O O O
OH O

R
O
O O HO
AT O
O
(v) (vi)
N
O
NH2
H
O O O NH2
O
K

2. Which of following is phenol ?

OH OH OH
T

(A) (B) (C) (D)

EE

OH

O
N

NH2 OH
3. OH
VI

O
H
O NH2

(i) Which functional group is not present in above compound ?

(A) Ketone (B) Carboxylic acid (C) Amine (D) Alcohol
(ii) Which functional group is present in above compound ?
(A) Ester (B) 2° amine (C) Alkyne (D) Amide
(iii) Types of functional group is present in above compound
(A) 5 (B) 6 (C) 7 (D) 8
(iv) Degree of unsaturation in above compound is
(A) 5 (B) 6 (C) 7 (D) 8
(v) Above compound is Bicyclo (A) Yes (B) No

(vi) Above compound is spiro (A) Yes (B) No

 O O

C–NH2

4.

NH2 OH

H O
(i) Which functional group is not present in above compound ?
(A) Ketone (B) Carboxylic acid (C) Amine (D) Alcohol

IR
(ii) Which functional group is present in above compound ?
(A) Ester (B) 2° amine (C) Alkyne (D) Amide
(iii) Types of functional group is present in above compound

IS
(A) 5 (B) 6 (C) 7 (D) 8
(iv) Degree of unsaturation in above compound is
(A) 5 (B) 6 (C) 7 (D) 8

R
(v) Above compound is Bicyclo (A) Yes (B) No
(vi) Above compound is spiro (A) Yes (B) No

b
NH2 c
Me
AT
N S
5.
H
O N
H a– O
d Me O–H
e
K

(i) Which functional group is not present in above compound ?

(A) Ketone (B) Phenol (C) Amine (D) Alcohol
(ii) Which functional group is present in above compound ?
T

(A) Ester (B) 2° amine (C) Alkyne (D) Amide

EE

(iii) Types of functional group is present in above compound

(A) 5 (B) 6 (C) 7 (D) 8
(iv) Degree of unsaturation in above compound is
(A) 5 (B) 6 (C) 7 (D) 8
N

(v) Above compound is Bicyclo (A) Yes (B) No

(vi) Above compound is spiro (A) Yes (B) No
VI

Observe following compound and answer questions given below.

OH (d)
OH (c)
O
(e) O
HO
6. O
N N
Me
OH H
(a) (b)
(i) Total number of different types of functional groups in this compound are
(A) 5 (B) 6 (C) 7 (D) 8

"Let your mind lead you and let your heart guide you."
 IUPAC & NOMENCLATURE
BY VINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.7

1. Find - D.B.E. of the following

(Write your answer in box)

(1) C4 H10 (2) C4H8

(3) C4H6 (4) C5H12O

(5) C5H10O (6) C5H8O

IR
(7) C6H12 (8) C4H8Cl2

IS
(9) C4H8Br2 (10) C4H10O

(11) C10H20 (12) CNH5

R
(13) C3H6O (14)

O
AT
(15) (16)
H
O
K

(17) (18)
T
EE

(19) (20)
N
VI

CH2 CH2
O

(21) (22)

CH2 CH2 O

O
O
C–O–H
(23) (24) CH –C–O–H
3

(25) CH3 – NH2 (26) C2H3N

[6]
2. Match the column :
Column I Column II
(Compound) (Double bond equivalent)

(A) (P) 4
H
CH3
C—N S
O
O N
COOH
(penicillin)

IR
(B) (Q) 5

IS
(Hexahelicene)
(C) (R) 7

R
(Prismane)
O
C OH
AT
(D) C (S) 19
C OH
H
O
(Ninhydrin)
K

3. Match the column :

Column I Column II
(Compound) (Double bond equivalent)
T
EE

(A) (P) 5
N

(Limonene)
VI

(B) (Q) 4

(Zingiberene)

(C) (R) 3

(Pyrene)

(D) (S) 12

(Cubane)
 IUPAC NOMENCLATURE
BY VINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.8

Single Choice Questions :

1. Which of following is 3° (tertiary alcohol)

OH OH OH
(A) (B) (C) (D) All

IR
2. Which of following is 1° amine ?

NH2 CH3

IS
(A) (B) CH3 – C – NH2 (C) CH3 – NH2 (D) All
CH3

R
3. Which of following is 3° amine ?

CH3
(A) CH – N
3
(B) CH3 – NH – Et
AT (C) CH3 – NH – CH3 (D) CH3 – NH2

CH3
H
4. and
K

Number of secondary carbon atoms present in the above compounds are respectively:
T

(A) 6, 4, 5 (B) 4, 5, 6 (C) 5, 4, 6 (D) 6, 2, 1

5. Number of 1°, 2° and 3° hydrogen in isooctane is:

EE

(A) 9,8,1 (B) 12,5,1 (C) 15,2,1 (D) None of these

Multiple Choice Question :
6. Which of the following compound contain only 1 type of carbon atom
N

(A) (B) (C) (D)

VI

7. Which of the following compound contain only 2 types of carbon atom

N N

(A) (B) N N (C) (D)

N N
8. Classify the following alcohols as primary, secondary, or tertiary:
(a) (CH3)3CCH2OH (b) CH3CH(OH)CH(CH3)2

(c) (CH3)2C(OH)CH2CH3 (d)

(e)

9. Classify the following amines as primary, secondary, or tertiary:

(a) CH3NHCH(CH3)2 (b) CH3CH2CH(CH3)CH2NH2
(c) (CH3CH2)3N (d) (C6H5)2CHCH2NHCH3

IR
(e) (f)

IS
R
AT
H
K
T
EE
N
VI
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.9

Calculate DBE value -

–
COO

1. 2. 3.

IR
COOH
H OH
4. 5. 6. OH

IS
H
COOH

R
O
||
7.
||
NH 8.
AT 9.

O
H
10. 11. .. 12.
K

N
H
T

CN
CH3
EE

H Br
13. 14. 15.
H Br
|| CH3
O
N

O O
VI

OH
16. 17. 18.

19. 20. 21. C9H16 NOCl

COOH
COOH
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.10

Calculate DBE value -

1. 2. N 3. HCOO

H2C

IR
H3C

IS
4. 5.

CH2

R
CH3
AT
O
O
H
O OH
HO
OH HO N(CH3)2
K

6. 7. O O
O
T

O O
O
EE

O OCH3
O
erythromycin
N
VI

8. 9.
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.11

1. Find - D.B.E. of the following

(Write your answer in box)

(1) C4 H10 (2) C4H8 (3) C4H6

(4) C5H12O (5) C5H10O (6) C5H8O

IR
(7) C6H12 (8) C4H8Cl2 (9) C4H8Br2

(10) C4H10O (11) C10H20 (12) CNH5

IS
O
(13) C3H6O (14) (15)

R
O

(16)
AT (17)
H
(18) (19)
K

CH2 CH2
T
EE

(20) (21)

CH2 CH2
N

O
VI

C–O–H
(22) (23)

O
(24) CH –C–O–H (25) CH3 – NH2
3

(26) C2H3N
2. Match the column :
Column I Column II
(Compound) (Double bond equivalent)

(A) (P) 4
H
CH3
C—N S
O
O N
COOH
(penicillin)

IR
(B) (Q) 5

IS
(Hexahelicene)
(C) (R) 7

R
(Prismane)
O
C OH
AT
(D) C (S) 19
C OH
H
O
(Ninhydrin)
K

3. Match the column :

Column I Column II
(Compound) (Double bond equivalent)
T
EE

(A) (P) 5
N

(Limonene)
VI

(B) (Q) 4

(Zingiberene)

(C) (R) 3

(Pyrene)

(D) (S) 12

(Cubane)
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.12

S.No. Compound IUPAC name

1.

IR
2.

IS
3.

R
4.

5.
AT
6.
H
K

7.
T

8.
EE

9.
N

10.
VI

11.

12.

13.
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.13

S.No. Compound IUPAC name

1.

2.
3. CH3 – (CH = CH)2 – CH2CH3

IR
IS
4.

R
6.

7. Br
AT
8.
H
K

9.
T
EE

10.
N

11.
VI

12.

13.

14.

15.
S.No. Compound IUPAC name

16.

Et
17.

Cl

IR
18.
Br

IS
19.

R
AT
20.
H
K

Me

21.
T
EE

22.

23.
N

24.
VI

25.

26.

27.

28.

29.

30.
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.14

Write IUPAC names of following compounds :

CH2 CH3
H3C
1. 2.
H3C
CH2

IR
CH2
H3C CH2
3. 4.
H2C

IS
H3C CH2

H2C
5. 6.

R
CH3
CH
AT Cl

7. HC CH 8.
H3C CH2
H
K

Cl
T

Br Br
EE

9. 10.
N

CH3
VI

CH3
11. HC CH 12.

Br
F
H3C
13. CH2 14.
F
Br
 Br Br
Cl Cl
15. 16.
Br

I
H3C Br
O
Cl +
N -
17. 18. O

IR
CH3

IS
R
AT
H
K
T
EE
N
VI
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.15

Write IUPAC names of following compounds :

OH
Br

H3C CH3 H3C

CH3

IR
1. 2.
HO
Br

IS
R
CH3

OH
AT H3C
Cl

CH3
3. 4.
H
HO Br
CH3
K
T

CH3
EE

OH HO HO
Cl

H3C CH3
N

5. 6.
VI

H3C
 CH3 Cl

Cl

H3C CH3
Cl

7. 8.
HO
OH
H3C

IR
IS
OH H3C CH2
9. CH2 10.
HO

R
AT
H
K
T
EE
N
VI
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.16

Write IUPAC names of following compounds :

CH2
F

1. 2. H3C OH
OH
H2C

IR
OH

OH H3C Br H3C

IS
CH3
3. 4.
H3C CH3
CH3

R
CH3

H3C
OH
AT O
OH

CH3 +
N
5. 6.
H
-
O
CH3
K

H3C
CH3
CH3 CH3
T

CH3
EE

HO F

7. Br 8.
- +
H3C O N
N

H3C
O
CH3
VI

H3C CH3
Br
HO
CH3
9. H3C CH3 10. H3C

Br
Cl
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.17

Q. Circle the functional groups in the following compounds & find out the DBE value of each
compound ?

1. 7.

IR
IS
8.

R
2.

AT 9.
H
3.
K

10.
T
EE

4.
N

11.
VI

5.

12.

6.
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.18

Write IUPAC name of the following compound :

O
||
1. CH3 – CH2–CH–C—OCH3
|
C2H5

IR
(A) Methyl 2-ethylbutanoate (B) 1-methoxy-2-ethylbutanone
(C) 3-Methoxycarbonylpentane (D) 1-methoxy-2-ethylbutanal

IS
O
||
2. CH3 – CH=CH–C—OH

R
(A) But-1-en-4-oic acid (B) 1-hydroxybut-2-en-1-one
(C) But-2-en-1-oic acid (D) But-2-en-4-oic acid

OCH3
AT
3. |
CH3 – CH=C –— CH3
H
(A) 1-Methoxy-1-methylpropene (B) 2-Methoxybut-2-ene
(C) dimethylpropeneether (D) None of these
K

Me O
T

4. | ||
CH2 = C — C — OC2H5
EE

(A) Ethyl 2-methylprop-2-enoate (B) Ethyl 2-methylprop-1-enoate

(C) 1-Ethoxy-2-methylprop-2-enone (D) 1-Ethoxy-2-methylprop-2-enal
N

CH3 CH3
5. | |
CH3 – CH — CH — CH2NH2
VI

(A) 2, 3-Dimethylbutan-4-amine (B) 2, 4-Dimethylbutan-1-amine

(C) 2, 4-Dimethylbutan-4-amine (D) 2, 3-Dimethylbutan-1-amine

O
||
CH3 – C — CH — CH — CH3
6. | |
C2H5 CH3

(A) 3-(Methylethyl)pentan-2-one (B) 3-(Methylethyl)pentan-4-one

(C) 3-Ethyl-4-methylpentan-2-one (D) 3-Ethyl-2-methylpentan-4-one
 O
||
CH3 – CH — CH2 — C — Br
7. |
CH3

(A) 2-Methylbutanoyl bromide (B) 2-Methylbutan-4-oyl bromide

(C) 1-Bromo-3-Methylbutanone (D) 3-Methylbutanoyl bromide

8. CH 3 – CH — CH 2 — OH
|
C 6H 5

IR
(A) 2-Phenylpropan-1-ol (B) 2-Phenylpropan-3-ol

(C) 1-(2-Hydroxy-1-methylethyl)benzene (D) 1-((Hydroxymethyl)ethyl)benzene

IS
R
CH3
|
9. CH3 — C —— CH — CH — CH2 — CH3
| | | AT
CH3 CH3 I

(A) 3-lodo-4, 5, 5-trimethylhexane (B) 4-lodo-1, 1, 3-trimethylhexane

H
(C) 4-lodo-2, 2-dimethylheptane (D) 4-lodo-2, 2, 3-trimethylhexane
K

CH3
|
10. CH3 — CH2 — CH — CH — C — CH3
T

| | |
Cl CH3 OH
EE

(A) 4-Chloro-2, 3-dimethylhexane-2-ol (B) 4-Chloro-2-hydroxy-2, 3-dimethylhexane

(C) 4-Chloro-1, 1, 2-trimethylpentan-2-ol (D) 3-Chloro-2, 3-dimethylhexane-2-ol

N
VI
 IUPACE NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.19

1.

(A) 2-Methylbutan-3-one (B) 3-Methylbutan-2-al

(C) 2-Methylbutan-3-al (D) 3-Methylbutan-2-one

IR
CH3 – CO
2. O
CH3 – CH2 – CO

IS
(A) Ethanoic propanoic anhydride (B) Propanoic ethanoic anhydride
(C) 1-Ethanoyloxypropanone (D) 3-Ethanoyloxypropan-3-one

R
3. CH 3 – C –– C – CH 3
|| ||
O O AT
(A) Butane-2, 3-dial (B) Butane-1, 3-dione
(C) Butane-2, 3-dione (D) 1, 2-dimethylethanedione
H
4. CH2 = CH – CH = CH 2
(A) Butane (B) Buta-1, 3-diene (C) Butane-1, 3-diene (D) none of these
K

5. CH2 — CH2 –– CH2

| |
COOH COOH
T

(A) Pentane-1, 5-dioic acid (B) Pentane-1, 5-dicarboxylic acid

EE

(C) Propane-1, 3-dioic acid (D) None of these

CH2Cl
|
6. CH2 — CH — CH2
| |
N

Cl Cl
VI

(A) Tris(chloromethyl) methane (B) 1, 3-Dichloro-2-(chloromethyl) propane

(C) 1-Chlorobis(chloromethyl) ethane (D) None of these

CH3
|
7. CH3 — CH — CH — CH — C — CH3
| | | |
OH CH3 OH CH3

(A) 3, 5, 5-Trimethylhexane-2, 4-diol (B) 2, 2, 4-Trimethylhexane-3, 5-diol

(C) 1, 2,4, 4-Tetramethylpantane-1, 3-diol (D) 2, 2,4, 5-Tetramethylpantane-3, 5-diol
8. HOOC — CH = CH — COOH
(A) But-2-ene-1, 4-dicarboxylic acid (B) But-2-ene-1, 4-dioic acid
(C) Ethene dicarboxylic acid (D) Ethene dioic acid

OCH3
|
9. CH3 — CH — CHO

(A) 1-formyl-1-methoxyethane (B) 2-Methoxypropan-3-one

(C) 2-Methoxypropanal (D) 2-Methoxypropan-3-al

IR
CH3
|
10. CH2 = C — COOCH 3

IS
(A) Methyl-2-methylprop-1-en-3-oate (B) 2-Methoxycarbonylpropene
(C) 2-Methoxycarbonylprop-2-ene (D) Methyl-2-methylprop-2-enoate

R
11. CH3 — CH = CH — COOH

(A) But-2-ene-1-oic acid AT (B) But-1-ene-1-oic acid

(C) But-2-ene-1-carboxylic acid (D) Propene-1-carboxylic acid

12. (CH3)3C . CH2CH2Cl

H
(A) 2,2-Dimethyl-4-chloro butane (B) 1-Chloro-3, 3-dimthylbutane
(C) 4-Chloro-2,2-dimethyl butane (D) None of these
K

13. CH3 — CH — CH — CH — CH3

| | |
T

Cl Br OH
EE

(A) 3-Bromo-4-chlorpentan-2-ol (B) 3-Bromo-2-chloro-4-hydroxypentane

(C) 3-Bromo-2-chloropentane-4-ol (D) None of these
N

Br Cl
| |
14. CH3 — CH2 — C — CH — CH2 — Cl
|
VI

OH
(A) 3-Bromo-4, 5-dichloropentan-3-ol (B) 3-Bromo-1, 2-dichloro-3-hydroxypentane
(C) 3-Bromo-1, 2-dichloropentan-3-ol (D) 3-Bromo-4, 5-dichloro-3-hydroxypentane

15. CH3 — CH — CH2 — O — C2H5

|
OH

(A) 1-Ethoxypropan-2-ol (B) 3-Ethoxypropan-2-ol

(C) 1-Ethoxy-2-hydroxypropane (D) None of these
 IUPACE NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.20

OH

O
1.

IR
(A) 2, 6-Dimethylhepta-2, 5-dienoic acid (B) 3, 7-Dimethylhepta-2, 5-dienoic acid

IS
(C) 1-Hydroxy-2, 6-dimethylhepta-2, 5-dienone (D) None of these

R
2. CHO

(A) 3-Methylpent-1-en-4-al
(C) 3-Methylpent-4-carbaldehyde
AT
(B) 3-Methylpent-4-enal
(D) 3-Methyl-5-oxopent-1-ene
H
3. Name the following halides according to IUPAC system and classify them as alkyl, allylic, benzylic (primary,
secondary, tertiary), vinylic or aryl halides :
K

(i) (CH3)2CHCH(Cl)CH3 (ii) CH3CH2CH(CH3)CH(C2H5)Cl

(iii) CH3CH2C(CH3)2CH2I (iv) (CH3)3CCH2CH(Br)C6H5
T

(v) CH3CH(CH3)CH(Br)CH3 (vi) CH3C(Cl)(C2H5)CH2CH3

EE

(vii) CH3C(C2H5)2CH2Br (viii) CH3CH = C(Cl)CH2CH(CH3)2

(ix) CH3CH = CHC(Br)(CH3)2
N

4. Give the IUPAC name of the following compounds :

(i) CH3CH(Cl)CH(Br)CH3 (ii) CHF2CBrClF
VI

(iii) ClCH2C  CCH2Br (iv) (CCl3)3CCl

5. Write the structure of the following organic halogen compounds.

(i) 2-Chloro-3-methylpentane
(ii) 4-tert-Butyl-3-iodoheptane
(iii) 1, 4-Dibromobut-2-ene.
6. Write IUPAC names of a following compounds :

CH3
|
(i) CH3 – CH – CH – C – CH3 (ii) CH3 – CH – CH2 – CH – CH – CH2CH3
| | | | | |
CH3 OH CH3 OH OH C2H5

(iii) CH3 – CH – CH – CH3 (iv) HOCH2 – CHOH – CH2OH

| |
OH OH

(v) CH3 – O – CH2 – CH – CH3 (vi) CH3 – CH2 – O – CH – CH2 – CH3

| |

IR
CH3 CH3

IS
7. Write structures of the compounds whose IUPAC names are as follows :
(i) 2-Methylbutan-2-ol (ii) 3, 5-Dimethylhexene-1, 3,5-triol
(iii) 1-Ethoxypropane (iv) 2-Ethoxy-3-methylpentane

R
(v) Cyclohexylmethanol (vi) 3-Cyclohexylpentane-3-ol
(vii) Cyclopent-3-en-1-ol
AT (viii) 3-Chloromethylpentan-1-ol.
H
K
T
EE
N
VI
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.21

Q. Identify the type of inductive effect of atom or group which is directly attached to the cyclic system ?

CH O

1. OH
8.

IR
O

IS
CH3
CH3
O O
2.

R
9.

O
AT
O
H
3. Cl
10.
K

Cl
T

NH2
4.
EE

11.

OH
N

CH3
5.
VI

12.

CH3

6.
F
F

13. F

7.
 O
OH
S
14. O

15.

IR
IS
CH3

R
16.

CH3
AT
O
H
17.
K
T
EE
N
VI
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.22

1. Identify + I or – I effect which is present by circled group ?

O
OH CH3
(a) (b) OH (c)

IR
IS
O
|| CCH NO2
(d) (e) (f)

R
NH3
AT
(g) (h) CH 3 – CH = CH 2 (i) CH3 – C  CH
H
K

(j) H2C = CH – C  CH (k) CD3 – CH = CH2

T

NH2
EE

(l) (m) CH3 – CH2 (n) NO2 – CH 2 – CH 2

N

Cl SO3H
(o) Cl – CH2 – CH2 (p) (q)
VI

CH3 CH3
(r) CH 3 –– CH3 (s) (t)
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.23

Q. Circle-group shows inductive effect – I & I effect.

6. F
H3C

1.

IR
7. NH2

IS
O S O
CH3
2.

R
AT 8. H2C
H
3. CH3 CH3
K

9.
T
EE

4. O
N

O
10. OH
O
P
VI

O
HO

5.
H3C
O
Cl
11.
O S O
 20.
F N
12.
F F
O S O

21.

13. CH

IR
22.

IS
14. OH

R
15.
SH
AT
23.
H3C
H
K

16.
Br 24.
CH3
T

O NH
EE

17.
Cl
N

25.
O NH2
VI

CH3
18.

26. O
F N
19.
F F
27. O
OH
36.
O S O H2C NH2

37.
H2C
- CH2
28. C
+
N 38. H3C CH2

IR
H3C CH3
39.

CH3

IS
CH3
O O N

R
40.
29.
AT
O CH3
O 41.
H
O
K

30.
T

CH3
CH3 42.
EE

31.

CH3
N

HC
32. 43.
CH2
CH3
VI

33. H2C
O N

H2C 44.
34.

H3C O
CH3
35.
N O
H2C 45.
 IUPACE NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.24

Compare Stability

1. , 2. ,

IR
NO2 NO2

3. , 4. ,

IS
R
5. , 6. F – CH2 – CH 2 , Cl – CH2 – CH2
AT
F
7. , 8. , O
H
O F
K

O
F O Cl O
9. O , 10. O ,
T

F Cl O
EE

CH2 O O
11. 12. , || 
, CH3 – C – O
H O
N
VI

O O O O
|| || || || 
  
13. CF3 – C – O , CCl3 – C – O 14. CHCl2 – C – O , O2N – CH2 – C – O

 O

15. , 16. ,
O
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.25

Q. Draw resonance hybrid.

CH3
1. 11.
H2C

CH2

IR
12.
H2C
2.

IS
13. H3C
CH3

3. CH3

R
14. H2C CH2

4.
AT H2C
15.

H
H2C CH2
5.
K

16.
6.
T
EE

CH2

7.
N

H2C
17.
VI

8.

9. H2C CH2

H3C CH3
10.
18.
19. 26.

20. 27.

21. 28.

IR
22.

IS
H3C

29.

R
23.
AT 30.
H H H2C
+
N
H
H
K

24.
T

H
EE

H +
P CH2
H

25. 31.
N
VI
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.26

Q. Draw the Resonating structure and Resonance Hybrid of following species ?

S.No. Compound Resonating Structure

-
1. H2C CH2

IR
2. H3C
-
O

IS
NH2

3.

R
CH
-
AT
4.
H
NH2
K

5. O
T
EE

-
C
6.
N
VI

-
CH

7.

8. -
O -
O

CH3
O
9.
S.No. Compound Resonating Structure

Cl

10.

- CH3
11. H2C

12. H3C

IR
NH2

IS
CH

13.

R
-
CH

14.
AT
H
H3C
K

O
T

15.
EE

O
N

O
CH3
VI

16. H3C
O

-
O

17.

18. H3C
OH
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.27

Q. Draw the Resonating structure and Resonance Hybrid of following species ?

S.No. Compound Resonating Hybrid

CH
1.

IR
CH

IS
2.

R
CH

3. AT
H
K
T

4.

HC
EE

H2C CH
5.
N

CH3
VI

6.

H2C
CH3
7.
O
S.No. Compound Resonating Structure

H2C
8.
O

O +
CH
9.

H
N +
10. CH

IR
HO

IS
+
11. CH
H3C

R
S +
CH
12. AT
H
+
13. C
K

OH
T

O
EE

14. +
CH
N
VI
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.28

1. Draw Resonance hybrid of the following compounds

1. 2.

NH2

IR
3. 4.

IS
–
OO

R
AT O
5. 6.

O
H
K

7. 8.
T
EE
N

9. 10.
VI

11. 12.

13. 14.
15. 16.

–
O
CH2

..
17. 18. H2 N  C  N:

NO2


19. NOO
3 20. O=C=O

IR
21. 22.

IS
23. 24.

R
25. AT
26.

–
O
H
27. 28.
K
T
EE

–
29. 30. OO– C = O
–
OO
N
VI
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.29

S.No. Resonting Structure Relative stability

OCH3 
O – CH3

1. ; 

IR

O
 O

IS
2. ;

O O O
||

R
3. CH3 – C – OH , CH3 – C– OH, CH3 – C = O– H

NH2
 
NH2
AT
NH2

H
4. ; ;


K

5. O = C = O ; O  C – O ;
  +2
O = C – O ; O – C – O
T
EE

O O
6. || ;  | ;
H – O – C – NH2 H – O = C – NH2

O O
N

|  ; |

H – O – C = NH2 H – O – C – NH2
VI


7. ;


 
O O O

8. ; ;

 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.30

1. Compare relative stability of following resonating structures

S.No. Resonating structures Order of Reason
Stability
– +
(1) H2C = CH – Cl H2C – CH = Cl
(a) (b)

IR
O O–
|| |
–
(2)

IS
(a) (b)

– –
CH2 – CH = NH H2C = CH – NH

R
(3)
(a) (b)

+ + AT
(4) CH3 – O – CH2 CH3 – O = CH2
(a) (b)

+ – – +
(5) H–N=C=O H–N C–O H–N–C O
H
(a) (b) (c)
..
K

(6) Me .. N Me + N –
O
.. O O
.. O
(a) (b)
T

H +
O OH
|

|| |
EE

(7)
+
(a) (b)

+
N

(8)
+
+ (c)
(a) (b)
VI

O–
O
||
(9) –
O O
(a) (b)

S–
S
||
(10) H H
–
(a) (b)
 + –

: :
(11) H–O–CN:

:
(a) (b)

O O O
| || ||
(12) | | ||
||| ||| C
||
(a) (b) (c)
N N N

O O O
|| |+ + ||
(13) | | ||
C C C
||| (a) ||| (b) || (c)

IR
N N N

O O O
|| | |

IS
+ CH C

||
(14) H CH2 H H CH2

|
2
(a) (b) (c)

O+
: :

R
O
+
(15)

(a) (b)
AT
N N
H
(16)
K

(a) (b)

O O O O
|| || | ||
T

(17)
EE

(a) (b)

N:
|||

+
(18) N
+
:
N

(a) (b)
VI

O O O
|| | ||
(19)

(a) (b) (c)

 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.31

1. Compare relative stability of following resonating structures

S.No. Resonating structures Order of Reason
Stability

+
+
O CH2 O CH2 O CH2

||
||

||

(1)

IR
(a) (b) (c)
+ +
:

:
(2)

IS
H2N – CH = NH2 H 2N = CH – NH 2
(a) (b)

O O +O O O O+
|| || | || || |

R
+
(3)
(a) (b)
AT (c)

O O
||

(4) Me – N +
H
Me – N +
||
|

O O
(a) (b)
K

+ +
:

H–C=N=N–H H–CN–N–H
(5)
T

(a) (b)

(6) +
Me – CH – C  O
EE

H3C – HC = C = O
(a) (b)
O O
|| |
:

H–C–N–H H–C=N–H
N

(7)
:

(a) (b)
VI

O O
|| |
(8) CH3 – C – CH2 CH3 – C = CH2
(a) (b)

+ +
(9) CH2 – C = C – CH 3 CH2 = C – C – CH3
| | | |
H H H H

O O
(10) || |
C C
||
|
|

O O O O
 O O
|| |
+

: :
(11) Me OH Me O–H
(a) (b)

N O N O N O
(12)
(a) (b) (c)

O O
|| |

(13)

IR
(b)
(a)

IS
O O
| ||

(14)

R
| ||
C C AT
(a) (b)

Me – CH – C  CH
H
(15) Me – CH = C = CH
(a) (b)
K

+ +
: :

(16) Me – O – CH = CH – CH2 Me – O = CH – CH = CH2

:

(a) (b)
T
EE

(17)
: :

S S
(a) (b)
N

+ +
VI

(18) O=C=O O–CO OC–O

:

(a) (b) (c)

+
:

(19) H2 N – C  N: H2N = C = N:
(a) (b)
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.32

S.N. Compound Huckel Rule (4n + 2)e– All carbon of ring Cyclic Complete delocalisation Nature
are sp2 or sp

1.

IR
2.

IS
R
3.

AT
4.
H
5.
K
T

6.
EE

7.
N
|
N

H
VI

8. N O
|
H
N

9.
N

10.

Note : Huckel Rule (4n + 2)e– is for aromatic compound only.

 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.33

1. Identify the Nature of compound

S.No. Compound Aromatic Anti-aromatic Non-aromatic

(1)

IR
(2)

IS
(3)

R
(4)
+

(5)



AT
(6)
H
K

(7)
O
T

(8)
EE

(9)
N

(10)
VI

(11)
B
|
H

(12)
O  O

(13)
O O
B
|
H
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.34

S.No. Compound Aromatic Anti-aromatic Non-aromatic

(1)

(2)

IR
O

(3)

IS
S

R
(4)
N
|
H AT
H
(5)
O
K


T

(6)
O
EE

(7)
O
N

(8)
VI

(9)

(10)

(11)
O
O
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.35

S.No. Compound Aromatic Anti-aromatic Non-aromatic

(1)
O

IR
(2)

IS
N O
|
H

R
O

(3)
N
AT
H
H
N
K

(4)
N
T

N
EE

(5)
N
N

(6)
N
VI

(7)

N
H

N N—H
(8)

(9) H—N N—H

 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.36

1. Identify the Nature of compound

S.No. Compound Aromatic Anti-aromatic Non-aromatic

1.

IR
O

2.

IS
R
3.

AT
CH3
|
H
B
4.
K
T

5.

N
EE

6.
N
N

|
H
VI

7. N :S:

8. N
O

N N

9. N N
H N
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.37

S.No. Compound Aromatic Anti-aromatic Non-aromatic

1.

IR
IS
2.

R
AT
3.
H
K

4.


T
EE

5.


CH2
N

6.
VI


CH2
7.

8.
N

9.
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.38

S.No. Compound Aromatic Anti-aromatic Non-aromatic

O

1.

IR
2.

IS
3.

R
H
N

4. AT
CH2
H
5.
K

6. 
T
EE

7.
N
VI

8.

9.
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.39

Q. Find number of -Hydrogen :

(1) H2C = CH2
CH3

(2) H3C
H3C CH2
(12)
CH3
H3C

IR
(3) CH3
H3C CH2
H3C

IS
(13)
H3C CH3
(4)
CH3

R
(14)
H3C
(5)
H3C
CH3 AT
(15)
H
H3C
CH3
H3C
K

(6) CH3
H3C
(16)
T

H3C CH3
EE

(7) CH3
H3C CH3
(17)
CH3
N

CH3
(8) H2C
VI

CH3
(9) H3C CH3
(18)
H3C

(10)
H3C CH2
CH3

H3C (19)
CH3
CH3
(11)
H3C
 H3C H3C CH3

(20)
(28)

H3C CH3

(21)
CH3

IR
(29)
(22)
H3C

IS
R
(23)
CH3
AT
(30)
H3C

(24)
H
K

H3C CH3
T

(31)
(25)
EE

H3C
N

(32)
VI

(26)
H3C

(33)
H3C

(27)
 H3C CH3 H3C

(34)

(40)

CH3
H3C CH3
CH3

IR
(35)
H3C

IS
CH3
(41) CH3

R
CH3
(36) CH3
AT
H3C
H
CH3

(42)
K

(37) H3C CH3

CH3
T

CH3
EE

CH3 H3C

(43) H3C
N

(38) H3C
VI

CH3

(44)
H3C

H3C

(39)
(45)

CH3
 H3C CH3

(46)

H3C
(52)

CH3

IR
(47)
CH3

IS
(53)

R
(48)
AT
(54)
H
K

(55)
(49)
T
EE

H3C

CH3 CH3 (56)

N
VI

(50)
H3C

CH3

(57)

H3C

(51)

(58)
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.40

No of -hydrogen No. of -hydrogen

CH3

(1) (2)

IR
IS
(3) (4)

R
AT
H
CH3
K

(5) (6)
CH3
T
EE

H3C

CH3
N

(7) (8)
CH3
VI

CH3

CH3
CH3
(9) (10)
CH3

CH3
 No of No. of
-hydrogen -hydrogen

CH3

(11) (12)

CH3

CH2
(14) H2C

IR
(13) CH3
CH3

IS
H3C CH3
(15) (16) H3C CH3

H3C

R
H3C
H 3C CH3
(17) CH2 AT (18)
CH3

CH3
H
H3C CH3
H2C
CH3
K

(19) (20)
H3C
H3C
T
EE
N
VI
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.41

No of -hydrogen No. of -hydrogen

CH3
H2C
(1) (2)
CH3

CH3

IR
(3) (4)

IS
H3C H3C
CH3

R
(5) (6)
AT
CH3
H
H3C
CH3
K

(7) (8)
T

CH3
EE

H3C

(9) (10)
N

H3C
VI

H2C H3C

(11) (12)

CH3

(13) (14)
 No of -hydrogen No. of -hydrogen

H2C H3C

(15) (16)

CH3 CH3
(17) (18)
CH3 CH3

IR
CH3 CH3

IS
CH3
(19) (20)
H3C
H3C CH3

R
H3C
CH3

H3C CH3
AT
(21)
H3C
H
H3C CH3
K
T
EE
N
VI

“The strongest light is the light that shines within you.”

 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.42

Q. Find Number of -hydrogen in carbocation :

H3C CH3
(1) CH3

CH3 (11)
H3C
(2)

IR
H3C CH3

(3) (12)
H3C CH3

IS
H3C CH3

R
(4) (13)
H3C CH3

H3C
AT
(14)
(5)
H
H3C CH3
K

H3C (15)
(6) CH3
H3C
T
EE

H3C (16)
(7)
H3C CH3

H3C
N

CH3
CH3
VI

(8) H3C (17)

CH3

CH3
(9)

(18)

(10)
 H3C
(22)

(19)

H3C CH3
(23)

IR
(20)

IS
CH3

R
(24)
(21) AT
H
CH3
K

(25)
T

H3C
EE
N
VI
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.43

Q.1 Give the relative Stability of the following compound

1.
H
(i) (ii) (iii) (iv) (v)

Me Me Me
| l

IR
l
2. Ph – CH2 – CH  CH – C – Me Me – CH – CH  CH – C – Me
l l
Me Me

IS
(i) (ii)

R
(iii) (iv)

3. Me – CH – CH – CH3

Me – CH2
AT 
C H3
Me
l
Me – C – CH2
l l
Me
Me
H
(i) (ii) (iii) (iv)
K

4.
T
EE

(i) (ii) (iii) (iv)

N

5.
VI

(i) (ii) (iii) (iv)

6.

(i) (ii) (iii) (iv)

7. Me – CH = CH2

(i) (ii) (iii)

 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.44

Q.1 Give the relative Stability of the following compound

1.

(i) (ii) (iii) (iv) (v) (vi) (vii)

IR
IS
2.

R
(i) (ii) (iii) (iv)

AT
H
K

3.
T
EE

(i) (ii) (iii) (iv)

N
VI

4.

(i) (ii) (iii) (iv)

5.

(i) (ii) (iii) (iv)

IR
IS
R
6.

AT
(i) (ii) (iii) (iv)
H
K
T
EE
N
VI
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.45

Q.1 Give the relative Stability of the following compound

1.

(i) (ii) (iii)

IR
2.

IS
(i) (ii) (iii) (iv)

R
3. (Et)2 CH (Et)3 C

(i) (ii)
AT (iii) (iv)


H
4.
K

(i) (ii) (iii) (iv)

T

5.
EE

(i) (ii) (iii) (iv)

N

6.
VI

(i) (ii) (iii) (iv)

7.

(i) (ii) (iii)

 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.46

Q.1 Give the relative Stability of the following compound

1.

(i) (ii)

IR
IS
2.

(i) (ii) (iii)

R
3.
AT
(i) (ii)
H
K

(iii)
T
EE

4.

(i) (ii) (iii)

N
VI

5.

(i) (ii) (iii)

6. CH3 – C  C – CH3 H3C – CH2 – C  CH

(i) (ii)
7. CC CC CC

(i) (ii) (iii)

H3C – C  C – CH3
(iv)

CH3 H3C

(i) (ii)

IR
IS
R
AT
H
K
T
EE
N
VI
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.47

Q.1 Give the relative Stability of the following compound

H2C
1. 2.

(i) (ii) (i) (ii)

IR
IS
CH3 CH3
3. 4.

R
CH3

(i) (ii) AT CH2

(i) (ii) CH3

CH3
(iii)
H
CH3 CH3
K

5. 6.

(i) (ii)
T

(i) (ii)
EE

7. 8.
N

(i) (ii)
VI

(i) (ii)

H3C H3C
O O
CH2 CH3

9. 10.
(i) (ii)

(i) (ii)
 IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.48

S.No. Compound Relative Stability

CH3
CH3 CH3
H3C H3C H3C
1.
CH3 CH3 CH3

IR
2.

IS
CH3
CH3
CH3
CH3
3.

R
CH3 CH3

4.
H3C CH3
H3C
AT
CH3
CH3
CH3

H3C
CH3 CH3
H
CH3

H3C H3C H2C

K

CH3 CH3 H3C

5.
T
EE

H3C
+ +
CH + C
CH
N

6.
VI

CH3 CH3 CH2

7. CH3 CH3
CH3

H3C

CH3
8.

9.
 ANSWER KEY
DPP No.-1
1. D 2. D 3. A 4. A 5. C 6. CD
7. ABCD 8. (a) 1°, (b) 2°, (c) 3°, (d) 3°, (e) 2°
9. (a) 2°, (b) 1°, (c) 3°, (d) 2°, (e) 2°, (f) 3°
DPP No.-2
1. a-9, b-12, c-1, d-5, e-9, f-1, g-1, h-4, i-6 2. a-9, b-11, c-3, d-5, e-9, f-3, g-0, h-7, i-5
1°
2° 1° 3° 2°
3° 4° 3° 4° 3° 3° 1° 3° 3° 1°
2° 1° 1°
2° 3° 3° 2° 2° 2° 3° 3°
3. 2° 1° 2° 3° 2°

IR
2° 3° 3° 4° 1° 3° 2° 2° 3° 1°
2° 3° 3° 2°
1°
(I) (II) (III) (IV)

IS
4. (A) P; (B) P, Q; (C) P, Q, R, S; (D) Q,R

DPP No.- 3

R
1. 4 2. 2.5 3. 7 4. 10 5. 10 6. 2 7. 7
8. 2 9. 10 10. 3 11. 3 12. 3 13. 4 14. 6
15. 0 16. 4 17. 3 18.
AT 5 19. 4 20. 4 21. 2

DPP No.- 4
1. 5 2. 0 3. 1.5 4. 2 5. 11 6. 21 7. 5
H
8. 16 9. 5

DPP No.- 5
K

1. C 2. A 3. C 4. B 5. B 6. B 7. C
8. D
T

DPP No.- 6
EE

1. Function group DBE

(i) ene, yne, ketone 5
(ii) aldehyde, 2° amine, 3° Amine, Amide, ene, ketone 6
(iii) ene, yne, anhydride, ketone and aldehyde 8
N

(iv) alcohol, naphthol, acid chloride, aldehyde 9

(v) ketone, alkene, anhydride 5
VI

(vi) ketone, aldehyde, ene, yne, alcohol, amide, 1° amine, ester 11

2. C 3. (i) B, (ii) D, (iii) B, (iv) B, (v) A, (vi) B

4. (i) B, (ii) D, (iii) B, (iv) B, (v) B, (vi) B 5. (i) A, (ii) D, (iii) C, (iv) C, (v) B, (vi) B 6. (i) C

DPP No.- 7
1.
(1) 0 (2) 1 (3) 2 (4) 0 (5) 1 (6) 2 (7) 1
(8) 0 (9 0 (10) 0 (11) 1 (12) 0 (13) 1 (14) 4
(15) 2 (16) 5 (17) 2 (18) 3 (19) 7 (20) 7 (21) 17
(22) 4 (23) 5 (24) 1 (25) 0 (26) 2
2. A  Q ; B  S ; C  P ; D R 3. A  R ; B  Q ; C  S ; D P
 DPP -8
1. D 2. D 3. A 4. A 5. C 6. CD
7. ABCD 8. (a) 1°, (b) 2°, (c) 3°, (d) 3°, (e) 2°
9. (a) 2°, (b) 1°, (c) 3°, (d) 2°, (e) 2°, (f) 3°

DPP - 9
1. 4 2. 2.5 3. 7 4. 10 5. 10 6. 2 7. 7
8. 2 9. 10 10. 3 11. 3 12. 3 13. 4 14. 6
15. 0 16. 4 17. 3 18. 5 19. 4 20. 4 21. 2

IR
DPP - 10
1. 5 2. 0 3. 1.5 4. 2 5. 11 6. 21 7. 5

IS
8. 16 9. 5

DPP -11

R
1.
(1) 0 (2) 1 (3) 2 (4) 0 (5) 1 (6) 2 (7) 1
(8)
(15)
(22)
0
2
4
(9
(16)
(23)
0
5
5
(10)
(17)
(24)
0
2
1
AT
(11)
(18)
(25)
1
3
0
(12)
(19)
(26)
0
7
2
(13)
(20)
1
7
(14)
(21)
4
17

2. A  Q ; B  S ; C  P ; D R 3. A  R ; B  Q ; C  S ; D P
H
DPP - 12
K

1. 4, 4-Dipropyl heptane 2. 2, 2-dimethyl propane

3. Pentane 4. 2-methyl butane
T

5. 3,3,5,5-tetramethyl heptane 6. Butane

7. 1, 2-dimethyl cyclobutane 8. 1, 2-dimethyl cyclobutane
EE

9. 4, 5-diethyl octane 10. 4-ethyloctane

11. 2, 6-dimethyl octane 12. 2, 6-dimethyl octane
13. 2, 2-dimethyl pentane
N

DPP - 13
1. 5-methyl-hex-2-ene 2. 2-octene
VI

3. 2, 4-heptadiene 4. 3, 7-dimethyl-1-octene
6. 2-methyl-2-butene 7. 3-bromopropene
8. Deca-3, 7-diene 9. 1-methylcyclohexene
10. 3-methylcyclohexene 11. 4-methyl cyclohexene
12. 2,6-dimethyl-Octa-2,6-diene 13. Hex-2-ene
14. Hex-2-ene 15. 3-methyl-Pent-2-ene
16. 3-methyl-Pent-2-ene 17. Ethylcyclohexene
18. 1-Bromo-2-chlorocyclobutene 19. 4-ethyl-3-propyl Hept-1-ene
20. 4-(1, 2-dimethyl Butyl)-1, 3, 5-Hepta triene 21. 5-ethyl-4,6-dimethyl-oct-1-ene
22. But-2-yne 23. Hex-2-yne
24. Oct-1-yne 25. Non-3-yne
26. 1-Heptene 27. Hex-1-en-5-yne
28. 1-Decen-5-yne 29. 4-Propyl hept-2-yne
30. Oct-6-en-1-yne

DPP - 14
1. hexa-1,3-diene 2. 2-ethylbut-1-ene
3. buta-1,3-diene 4. penta-1,3-diene
5. buta-1,2-diene 6. 4-propylhex-1-en-5-yne
7. Ethyne 8. 2-chloropropene

IR
9. 1-bromocyclopenta-1,3-diene 10. 4-bromo-6-chloro-3-cyclobutylcyclohexene
11. buta-1,3-diyne

IS
12. 1-isopropylcycloheptene or methylethylcycloheptene

DPP - 15

R
1. nonan-4-ol 2. 5-bromo-6-(2-bromocyclopropyl)octan-3-ol
3. 5-(2-cyclopropylcyclopropyl)heptan-3-ol AT 4. 6-(2-bromocyclopropyl)-3-chlorooctan-2-ol
5. 6-cyclohexylnon-4-ene-3,7-diol 6. 5-(3-chloro-4-cyclobutylcyclohexyl)octan-2-ol
7. 3(4-chloro-1-propylhexyl)cyclohexan-1-ol 8. 5-chloro-6-(3-chlorocyclohexyl)octan-3-ol
9. hept-6-en-1-ol 10. hex-5-en-2-ol
H
DPP - 16
K

1. 3-(cyclopropyl)-5-fluorohepta-1,6-dien-4-ol 2. methanol
3. 7-bromo-5-ethylnonan-3-ol 4. 6-ethyloctan-3-ol
T

5. 5-methylheptan-3-ol 6. 5-nitrooctan-3-ol
7. 5-bromo-4-ethyl-6-methyldecane 8. 9-fluoro-6-nitroundecan-4-ol
EE

9. 2-bromo-3,6-diethylnonan-5-ol 10. 3-bromo-2-chloro-6-ethyloctane

DPP - 17
N

Functional Groups DBE

VI

1. Alkene, ketone, Aldehyde 4

2. Alkene, 1° amine 2
3. Alkene, Carboxylic acid 3
4. Alkene, cyanide, aldehyde 6
5. Alkene, isocyanide 6
6. Thioalcohol, ester 3
7. Aldehyde, Acid halide 3
8. Alkene, Alkyne, Sulphonic acid 5
9. Ketone, alcohol, Thio alcohol 3
10. Anhydride 4
11. Alkene, alcohol (enol) 1
12. Ketone, Thio ketone 2
 DPP - 18
1. A 2. C 3. B 4. A 5. D 6. C 7. D
8. A 9. D 10. A

DPP - 19
1. D 2. A 3. C 4. B 5. A 6. B 7. A
8. B 9. C 10. D 11. A 12. B 13. A 14. C
15. A
DPP - 20
1. A 2. B
3. (i) 2-chloro-3-methylbutane (ii) 3-chloro-4-methylhexane

IR
(iii) 1-Iodo-2, 2-dimethylbutane (iv) 1-bromo-3, 3dimethyl-1-phenylbutane
(v) 2-bromo-3-methylbutane (vi) 3-chloro-3-methylpentane
(vii) 3-bromomethyl-3-methylpentane (viii) 3-chloro-5-methyl-hex-2-ene

IS
(ix) 4-bromo-4-methyl-2-pentene
4. (i) 2-bromo-3-chlorobutane (ii) 1-bromo-1-chloro-1,2,2-trifluoroethane
(iii) 1-bromo-4-chloro-but-2-yne (iv) 1,1,1,2,3,3,3-heptachloro-2-trichloromethylpropane

R
Cl
5. (i) (ii)
I
AT (iii)
Br
Br

6. (i) 2,2,4-trimethyl-3-pentanol (ii) 5-ethyl-2,4-heptanediol

H
(iii) 2, 3-butanediol (iv) 1, 2,3-propanetriol
(v) 1-methoxy-2-methylpropane (vi) 2-ethoxybutane
K

OH OH Et – O
T

7. (i) (ii) (iii) O (iv)

OH OH
EE

OH Cl
OH
(v) (vi) (vii) (viii)
OH HO
N
VI
 DPP - 21
1. –I 2. –I 3. –I 4. –I 5. –I
6. +I 7. +I 8. –I 9. –I 10. –I
11. –I 12. +I 13. –I 14. –I 15. –I
16. No effect 17. –I
DPP - 22

(a) –I (b) –I (c) +I (d) –I (e) –I (f) –I

(g) –I (h) +I (i) +I (j) –I (k) +I (l) –I
(m) +I (n) –I (o) –I (p) –I (q) –I (r) None

IR
(s) +I (t) None

DPP - 23

IS
1. +I 2. +I 3. +I 4. –I 5. –I 6. –I 7. –I
8. +I 9. None 10. –I 11. –I 12. –I 13. –I 14. –I
15. –I 16. –I 17. –I 18. +I 19. –I 20. –I 21. +I

R
22. +I 23. +I 24. –I 25. –I 26. –I 27. –I 28. –I
29. –I 30. –I 31. None 32. –I 33. +I 34. +I 35. +I
36. +I 37. None 38. +I 39.
AT +I 40. –I 41. –I 42. +I
43. +I 44. –I 45. –I

DPP - 24
H
1. i > ii 2. i > ii 3. i > ii 4. ii > i 5. i > ii 6. i > ii 7. i > ii
8. i > ii 9. i > ii 10. i > ii 11. ii > i 12. i > ii 13. i > ii 14. i > ii
K

15. ii > i 16. i > ii

DPP - 25
T
EE

1. 2. 3. 4.


N

CH2
VI

5. 6. 7.    8.


CH3
9. 10. 11.
H2C

12. 13. 14.

15. 16. 17. 18.

IR
19. 20. 21.

IS
H
H + H
N

R
+ +
+ +

22. 23. AT 24. No d-orbital in nitrogen ,

+ + +
Resonance in
benzene only
H
K

25. 26. 27.

T
EE
N
VI

28. 29. 30.

31.
 DPP - 26

NH2

O
1. 2. 3.  
  CH3–C

O


  
NH2  
 
O
4. 5. 6.
    



IR
OCH3
 O
 
7. 8. C 9.

IS
  O O


Cl

R

O
  
10. 11.  AT 12.
 
NH2



OCH3
H
    
K

13. 14. 15.

  

O
T


EE

O
 
O   OH
16. 17. 18.
O O

N

DPP - 27
VI



   
 
 
1. 2. 3. 4.
  
  

 

–
O



     
5. 6. 7.

O–

  H
O 
 N
  – 
8. O 9. 10.

  
 
OH S O
 
11. 12. 13.  14.
 

OH

DPP - 28



IR
1.  2. 3. 
 OH 
 O
 

IS
NH2 O

    
O
4. 5. 6. 


R
 

O
AT  
CH — CH — NH2

O
 
H


7. NH 8. 9.
 
K

 
O H
T

1 1
2 O O 2
1
EE

O 2

10.   11. 12. H
H2N   O
1 1
1
O 2
O 2
2 O
N

•  
CH2
VI

 
13. 14. 15. Me — S — CH 2
• •  


CH2

  
O
  
16. Me N 17. 18. H 2N — C — N:

 
O N
 
O O
 
O
    Me
19. N 20. O — C — O or O—C—O 21.  
  O  N:
O O

  
H2N NH2 O
C
22. 23. 24.
NH     
OH
 


    15

IR
O O 
 15  15
25. 26.   27.  or 
 15 15
  

IS

O

O


R
   O


28. 29. 30. C O

  
O
 AT 
O

DPP - 29
H
1. I > II 2. II > I 3. I > III > II 4. I > II > III 5. I > II > III > IV
K

6. I > III > II > IV 7. I > II 8. I > II > III

T

DPP - 30
EE

1. a>b 2. b>a 3. b>a 4. b>a

5. a>b>c 6. a>b 7. a>b 8. a=b=c
9. a=b 10. b>a 11. b>a 12. a>c>b
N

13. a>b>c 14. c>a>b 15. b>a 16. a>b

17. b>a 18. a>b 19. b>c>a
VI

DPP - 31

1. a>b>c 2. a=b 3. a>b 4. a=b

5. b>a 6. a>b 7. b>a 8. b>a
9. b>a 10. a=b 11. a>b 12. b>c>a
13. b>a 14. b>a 15. a>b 16. b>a
17. b>a 18. a>b=c 19. a>b
 DPP - 32
1. ×, ×, , ×, Non - Aromatic 2. 6 , , , Aromatic
3. ×, ×, , ×, Non - Aromatic 4. 6 , , , Aromatic
5. × , , , Anti-Aromatic 6. × ×, , ×, Non-Aromatic
7. 6 , , , Aromatic 8. 6 , , , Aromatic
9. 6 , , , Aromatic 10. × , , , Anti-Aromatic

DPP - 33

Aromatic : Aro, Antiaromatic : A.A. Non-aromatic : N.A.

IR
1. NA 2. AA 3. Aro 4. Aro 5. Aro
6. NA 7. NA 8. NA 9. Aro 10. AA
11. AA 12. Aro 13. Aro

IS
DPP - 34
1. AA 2. Aro 3. Aro 4. Aro 5. NA

R
6. Aro 7. NA 8. NA 9. Aro 10. NA
11. Aro

1. Aro 2. Aro
AT
3.
DPP - 35
Aro 4. Aro 5. Aro
6. NA 7. Aro 8. Aro 9. Aro
H
DPP - 36
K

1. Aro 2. AA 3. Aro 4. Aro 5. Aro

6. NA 7. Aro 8. Aro 9. Aro
T

DPP - 37
1. Aro 2. Aro 3. Aro 4. Aro 5. Aro
EE

6. Aro 7. Aro 8. AA 9. Aro

DPP - 38
1. Aro 2. NA 3. Aro 4. Aro 5. Aro
N

6. AA 7. AA 8. Aro 9. Aro
VI
 DPP-39
1. 0 2. 3 3. 6 4. 6 5. 9 6. 12 7. 11
8. 2 9. 5 10. 5 11. 7 12. 7 13. 7 14. 4
15. 4 16. 7 17. 10 18. 6 19. 8 20. 3 21. 8
22. 8 23. 5 24. 3 25. 5 26. 4 27. 7 28. 4
29. 6 30. 6 31. 6 32. 3 33. 2 34. 1 35. 0
36. 6 37. 6 38. 5 39. 4 40. 4 41. 6 42. 9
43. 12 44. 4 45. 7 46. 10 47. 8 48. 5 49. 1
50. 7 51. 5 52. 4 53. 10 54. 8 55. 3 56. 3
57. 8 58. 8

IR
DPP-40
1. 4 2. 5 3. 6 4. 8 5. 2

IS
6. 8 7. 6 8. 6 9. 6 10. 10
11. 5 12. 3 13. 3 14. 2 15. 5
16. 5 17. 2 18. 12 19. 4 20. 4

R
DPP-41
1. 5 2. 8 3. 5 4. 3 5. 2
6.
11.
1
1
7.
12.
0
6
8.AT
13.
4
3
9.
14.
2
3
10.
15.
7
4
16. 7 17. 6 18. 4 19. 6 20. 0
21. 6
H
DPP-42
1. 6 2. 5 3. 6 4. 6 5. 6 6. 7 7. 9
K

8. 1 9. 4 10. 4 11. 7 12. 3 13. 4 14. 5

15. 3 16. 4 17. 6 18. 2 19. 3 20. 6 21. 5
22. 2 23. 4 24. 4 25. 3
T
EE

DPP-43
1. i > ii > iii > iv > v 2. iii > i > ii > iv 3. i > ii > iv > iii
4. i > iii > iv > ii 5. i > iv > ii > iii 6. i > iii > ii > iv
7. iii > i > ii
N

DPP-44
VI

1. i > ii > iii > iv > v > vi > vii 2. i > ii > iii > iv 3. i > ii > iii > iv
4. i > ii > iii > iv 5. i > ii > iii > iv 6. i > ii > iv > iii

DPP-45
1. i > iii > ii 2. iii > ii > iv > i 3. iii > ii > iv > i
4. iii > ii > iv > i 5. i > ii > iv > iii 6. i > ii > iv > iii
7. ii > iii > i

DPP-46
1. i > ii 2. i > ii > iii 3. ii > i > iii
4. i > ii > iii 5. ii > i > iii 6. i > ii
7. iv > iii > ii > i 8. ii > i
 DPP-47
1. ii > i 2. i > ii 3. i > ii
4. iii > i > ii 5. i > ii 6. ii > i
7. i > ii 8. i > ii 9. i > ii
10. i > ii
DPP-48
1. b>a>c 2. a>b>c 3. b>c>a 4. c>a>b
5. a>b>c 6. c>a>b 7. a>b>c 8. a=b
9. a>b

IR
IS
R
AT
H
K
T
EE
N
VI