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Vineet Khatri Sir DPP 1-48 Class 11
Vineet Khatri Sir DPP 1-48 Class 11
OH OH OH
(A) (B) (C) (D) All
IR
2. Which of following is 1° amine ?
NH2 CH3
IS
(A) (B) CH3 – C – NH2 (C) CH3 – NH2 (D) All
CH3
R
3. Which of following is 3° amine ?
CH3
(A) CH – N
3
(B) CH3 – NH – Et
AT (C) CH3 – NH – CH3 (D) CH3 – NH2
CH3
H
4. and
K
Number of secondary carbon atoms present in the above compounds are respectively:
(A) 6, 4, 5 (B) 4, 5, 6 (C) 5, 4, 6 (D) 6, 2, 1
T
N N
N N
8. Classify the following alcohols as primary, secondary, or tertiary:
(a) (CH3)3CCH2OH (b) CH3CH(OH)CH(CH3)2
(e)
IR
(e) (f)
IS
“A positive attitude brings much gratitude! Think positive,
R
be positive, speak positive and stay positive!
AT
Do it every day and DO IT BIG!!!”
H
K
T
EE
N
VI
IUPAC & NOMENCLATURE
BY VINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.2
O
CH3
CH–2 CH=CH – C – Cl
1. N
O
CH–2 CH3
IR
(a) Find out the total number of 1° hydrogen. (b) Find out the total number of 2° hydrogen.
(c) Find out the total number of 3° hydrogen. (d) Find out the total number of 1° carbon.
(e) Find out the total number of 2° carbon. (f) Find out the total number of 3° carbon.
IS
(g) Find out the total number of 4° carbon.
(h) Find out the total number of functional groups.
(i) Find out the number of degree of unsaturation.
R
OH
H
2.
OO AT
NH2 NH2
NH
O
H
(a) Find out the total number of 1° hydrogen. (b) Find out the total number of 2° hydrogen.
K
(c) Find out the total number of 3° hydrogen. (d) Find out the total number of 1° carbon.
(e) Find out the total number of 2° carbon. (f) Find out the total number of 3° carbon.
(g) Find out the total number of 4° carbon. (h) Find out the total number of functional groups.
T
3.
I IV
II III
N
Find out the number of 1°, 2° & 3° carbon atoms in the above compounds.
VI
OH
(D) (S) 4° Carbon
“Follow your dreams; they will give meaning to every step that you take.”
IUPAC & NOMENCLATURE
BY VINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.3
1. 2. 3.
IR
COOH
H OH
4. 5. 6. H OH
IS
COOH
R
O
||
7.
||
NH 8. AT 9.
O
H
10. 11. .. 12.
N
K
H
T
CN
CH3
EE
H Br
13. 14. 15.
H Br
|| CH3
O
N
O O
VI
OH
16. 17. 18.
1. 2. N 3. HCOO
IR
H2C
H3C
IS
4. 5.
CH2
R
CH3
AT
O
O
H
O OH
HO
HO N(CH3)2
K
OH
6. 7. O O
T
O
O O
O
EE
O OCH3
O
erythromycin
N
VI
8. 9.
IR
O
O–H
4.
IS
O
R
5. The functional groups in Cortisone are : HOH2C
(A) Ether, alkene, alcohol CH3 OCH3
AT O
(B) Alcohol, ketone, alkene, ether
(C) Alcohol, ketone, amine
(D) Ether, amine ketone
H
O O Cortisone
O
K
O–H
6. H SH
OH
OH
T
CH3 O
O CH3
VI
O
(A) ketone (B) ester (C) ether (D) A and B both
1. Circle the functional group & also find out the degree of unsaturation
O
H
N H
N
O H
(i) (ii) O
N O
Me
IR
OH O
O
O Cl
(iii) (iv)
IS
H
H
O O O O
OH O
R
O
O O HO
AT O
O
(v) (vi)
N
O
NH2
H
O O O NH2
O
K
OH OH OH
T
OH
O
N
NH2 OH
3. OH
VI
O
H
O NH2
C–NH2
4.
NH2 OH
H O
(i) Which functional group is not present in above compound ?
(A) Ketone (B) Carboxylic acid (C) Amine (D) Alcohol
IR
(ii) Which functional group is present in above compound ?
(A) Ester (B) 2° amine (C) Alkyne (D) Amide
(iii) Types of functional group is present in above compound
IS
(A) 5 (B) 6 (C) 7 (D) 8
(iv) Degree of unsaturation in above compound is
(A) 5 (B) 6 (C) 7 (D) 8
R
(v) Above compound is Bicyclo (A) Yes (B) No
(vi) Above compound is spiro (A) Yes (B) No
b
NH2 c
Me
AT
N S
5.
H
O N
H a– O
d Me O–H
e
K
OH (d)
OH (c)
O
(e) O
HO
6. O
N N
Me
OH H
(a) (b)
(i) Total number of different types of functional groups in this compound are
(A) 5 (B) 6 (C) 7 (D) 8
"Let your mind lead you and let your heart guide you."
IUPAC & NOMENCLATURE
BY VINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.7
IR
(7) C6H12 (8) C4H8Cl2
IS
(9) C4H8Br2 (10) C4H10O
R
(13) C3H6O (14)
O
AT
(15) (16)
H
O
K
(17) (18)
T
EE
(19) (20)
N
VI
CH2 CH2
O
(21) (22)
CH2 CH2 O
O
O
C–O–H
(23) (24) CH –C–O–H
3
[6]
2. Match the column :
Column I Column II
(Compound) (Double bond equivalent)
(A) (P) 4
H
CH3
C—N S
O
O N
COOH
(penicillin)
IR
(B) (Q) 5
IS
(Hexahelicene)
(C) (R) 7
R
(Prismane)
O
C OH
AT
(D) C (S) 19
C OH
H
O
(Ninhydrin)
K
(A) (P) 5
N
(Limonene)
VI
(B) (Q) 4
(Zingiberene)
(C) (R) 3
(Pyrene)
(D) (S) 12
(Cubane)
IUPAC NOMENCLATURE
BY VINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.8
OH OH OH
(A) (B) (C) (D) All
IR
2. Which of following is 1° amine ?
NH2 CH3
IS
(A) (B) CH3 – C – NH2 (C) CH3 – NH2 (D) All
CH3
R
3. Which of following is 3° amine ?
CH3
(A) CH – N
3
(B) CH3 – NH – Et
AT (C) CH3 – NH – CH3 (D) CH3 – NH2
CH3
H
4. and
K
Number of secondary carbon atoms present in the above compounds are respectively:
T
N N
N N
8. Classify the following alcohols as primary, secondary, or tertiary:
(a) (CH3)3CCH2OH (b) CH3CH(OH)CH(CH3)2
(e)
IR
(e) (f)
IS
R
AT
H
K
T
EE
N
VI
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.9
1. 2. 3.
IR
COOH
H OH
4. 5. 6. OH
IS
H
COOH
R
O
||
7.
||
NH 8.
AT 9.
O
H
10. 11. .. 12.
K
N
H
T
CN
CH3
EE
H Br
13. 14. 15.
H Br
|| CH3
O
N
O O
VI
OH
16. 17. 18.
1. 2. N 3. HCOO
H2C
IR
H3C
IS
4. 5.
CH2
R
CH3
AT
O
O
H
O OH
HO
OH HO N(CH3)2
K
6. 7. O O
O
T
O O
O
EE
O OCH3
O
erythromycin
N
VI
8. 9.
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.11
IR
(7) C6H12 (8) C4H8Cl2 (9) C4H8Br2
IS
O
(13) C3H6O (14) (15)
R
O
(16)
AT (17)
H
(18) (19)
K
CH2 CH2
T
EE
(20) (21)
CH2 CH2
N
O
VI
C–O–H
(22) (23)
O
(24) CH –C–O–H (25) CH3 – NH2
3
(26) C2H3N
2. Match the column :
Column I Column II
(Compound) (Double bond equivalent)
(A) (P) 4
H
CH3
C—N S
O
O N
COOH
(penicillin)
IR
(B) (Q) 5
IS
(Hexahelicene)
(C) (R) 7
R
(Prismane)
O
C OH
AT
(D) C (S) 19
C OH
H
O
(Ninhydrin)
K
(A) (P) 5
N
(Limonene)
VI
(B) (Q) 4
(Zingiberene)
(C) (R) 3
(Pyrene)
(D) (S) 12
(Cubane)
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.12
1.
IR
2.
IS
3.
R
4.
5.
AT
6.
H
K
7.
T
8.
EE
9.
N
10.
VI
11.
12.
13.
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.13
1.
2.
3. CH3 – (CH = CH)2 – CH2CH3
IR
IS
4.
R
6.
7. Br
AT
8.
H
K
9.
T
EE
10.
N
11.
VI
12.
13.
14.
15.
S.No. Compound IUPAC name
16.
Et
17.
Cl
IR
18.
Br
IS
19.
R
AT
20.
H
K
Me
21.
T
EE
22.
23.
N
24.
VI
25.
26.
27.
28.
29.
30.
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.14
CH2 CH3
H3C
1. 2.
H3C
CH2
IR
CH2
H3C CH2
3. 4.
H2C
IS
H3C CH2
H2C
5. 6.
R
CH3
CH
AT Cl
7. HC CH 8.
H3C CH2
H
K
Cl
T
Br Br
EE
9. 10.
N
CH3
VI
CH3
11. HC CH 12.
Br
F
H3C
13. CH2 14.
F
Br
Br Br
Cl Cl
15. 16.
Br
I
H3C Br
O
Cl +
N -
17. 18. O
IR
CH3
IS
R
AT
H
K
T
EE
N
VI
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.15
OH
Br
IR
1. 2.
HO
Br
IS
R
CH3
OH
AT H3C
Cl
CH3
3. 4.
H
HO Br
CH3
K
T
CH3
EE
OH HO HO
Cl
H3C CH3
N
5. 6.
VI
H3C
CH3 Cl
Cl
H3C CH3
Cl
7. 8.
HO
OH
H3C
IR
IS
OH H3C CH2
9. CH2 10.
HO
R
AT
H
K
T
EE
N
VI
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.16
1. 2. H3C OH
OH
H2C
IR
OH
OH H3C Br H3C
IS
CH3
3. 4.
H3C CH3
CH3
R
CH3
H3C
OH
AT O
OH
CH3 +
N
5. 6.
H
-
O
CH3
K
H3C
CH3
CH3 CH3
T
CH3
EE
HO F
7. Br 8.
- +
H3C O N
N
H3C
O
CH3
VI
H3C CH3
Br
HO
CH3
9. H3C CH3 10. H3C
Br
Cl
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.17
Q. Circle the functional groups in the following compounds & find out the DBE value of each
compound ?
1. 7.
IR
IS
8.
R
2.
AT 9.
H
3.
K
10.
T
EE
4.
N
11.
VI
5.
12.
6.
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.18
O
||
1. CH3 – CH2–CH–C—OCH3
|
C2H5
IR
(A) Methyl 2-ethylbutanoate (B) 1-methoxy-2-ethylbutanone
(C) 3-Methoxycarbonylpentane (D) 1-methoxy-2-ethylbutanal
IS
O
||
2. CH3 – CH=CH–C—OH
R
(A) But-1-en-4-oic acid (B) 1-hydroxybut-2-en-1-one
(C) But-2-en-1-oic acid (D) But-2-en-4-oic acid
OCH3
AT
3. |
CH3 – CH=C –— CH3
H
(A) 1-Methoxy-1-methylpropene (B) 2-Methoxybut-2-ene
(C) dimethylpropeneether (D) None of these
K
Me O
T
4. | ||
CH2 = C — C — OC2H5
EE
CH3 CH3
5. | |
CH3 – CH — CH — CH2NH2
VI
O
||
CH3 – C — CH — CH — CH3
6. | |
C2H5 CH3
8. CH 3 – CH — CH 2 — OH
|
C 6H 5
IR
(A) 2-Phenylpropan-1-ol (B) 2-Phenylpropan-3-ol
IS
R
CH3
|
9. CH3 — C —— CH — CH — CH2 — CH3
| | | AT
CH3 CH3 I
CH3
|
10. CH3 — CH2 — CH — CH — C — CH3
T
| | |
Cl CH3 OH
EE
1.
IR
CH3 – CO
2. O
CH3 – CH2 – CO
IS
(A) Ethanoic propanoic anhydride (B) Propanoic ethanoic anhydride
(C) 1-Ethanoyloxypropanone (D) 3-Ethanoyloxypropan-3-one
R
3. CH 3 – C –– C – CH 3
|| ||
O O AT
(A) Butane-2, 3-dial (B) Butane-1, 3-dione
(C) Butane-2, 3-dione (D) 1, 2-dimethylethanedione
H
4. CH2 = CH – CH = CH 2
(A) Butane (B) Buta-1, 3-diene (C) Butane-1, 3-diene (D) none of these
K
CH2Cl
|
6. CH2 — CH — CH2
| |
N
Cl Cl
VI
CH3
|
7. CH3 — CH — CH — CH — C — CH3
| | | |
OH CH3 OH CH3
OCH3
|
9. CH3 — CH — CHO
IR
CH3
|
10. CH2 = C — COOCH 3
IS
(A) Methyl-2-methylprop-1-en-3-oate (B) 2-Methoxycarbonylpropene
(C) 2-Methoxycarbonylprop-2-ene (D) Methyl-2-methylprop-2-enoate
R
11. CH3 — CH = CH — COOH
Cl Br OH
EE
Br Cl
| |
14. CH3 — CH2 — C — CH — CH2 — Cl
|
VI
OH
(A) 3-Bromo-4, 5-dichloropentan-3-ol (B) 3-Bromo-1, 2-dichloro-3-hydroxypentane
(C) 3-Bromo-1, 2-dichloropentan-3-ol (D) 3-Bromo-4, 5-dichloro-3-hydroxypentane
OH
O
1.
IR
(A) 2, 6-Dimethylhepta-2, 5-dienoic acid (B) 3, 7-Dimethylhepta-2, 5-dienoic acid
IS
(C) 1-Hydroxy-2, 6-dimethylhepta-2, 5-dienone (D) None of these
R
2. CHO
(A) 3-Methylpent-1-en-4-al
(C) 3-Methylpent-4-carbaldehyde
AT
(B) 3-Methylpent-4-enal
(D) 3-Methyl-5-oxopent-1-ene
H
3. Name the following halides according to IUPAC system and classify them as alkyl, allylic, benzylic (primary,
secondary, tertiary), vinylic or aryl halides :
K
CH3
|
(i) CH3 – CH – CH – C – CH3 (ii) CH3 – CH – CH2 – CH – CH – CH2CH3
| | | | | |
CH3 OH CH3 OH OH C2H5
IR
CH3 CH3
IS
7. Write structures of the compounds whose IUPAC names are as follows :
(i) 2-Methylbutan-2-ol (ii) 3, 5-Dimethylhexene-1, 3,5-triol
(iii) 1-Ethoxypropane (iv) 2-Ethoxy-3-methylpentane
R
(v) Cyclohexylmethanol (vi) 3-Cyclohexylpentane-3-ol
(vii) Cyclopent-3-en-1-ol
AT (viii) 3-Chloromethylpentan-1-ol.
H
K
T
EE
N
VI
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.21
Q. Identify the type of inductive effect of atom or group which is directly attached to the cyclic system ?
CH O
1. OH
8.
IR
O
IS
CH3
CH3
O O
2.
R
9.
O
AT
O
H
3. Cl
10.
K
Cl
T
NH2
4.
EE
11.
OH
N
CH3
5.
VI
12.
CH3
6.
F
F
13. F
7.
O
OH
S
14. O
15.
IR
IS
CH3
R
16.
CH3
AT
O
H
17.
K
T
EE
N
VI
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.22
O
OH CH3
(a) (b) OH (c)
IR
IS
O
|| CCH NO2
(d) (e) (f)
R
NH3
AT
(g) (h) CH 3 – CH = CH 2 (i) CH3 – C CH
H
K
NH2
EE
Cl SO3H
(o) Cl – CH2 – CH2 (p) (q)
VI
CH3 CH3
(r) CH 3 –– CH3 (s) (t)
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.23
6. F
H3C
1.
IR
7. NH2
IS
O S O
CH3
2.
R
AT 8. H2C
H
3. CH3 CH3
K
9.
T
EE
4. O
N
O
10. OH
O
P
VI
O
HO
5.
H3C
O
Cl
11.
O S O
20.
F N
12.
F F
O S O
21.
13. CH
IR
22.
IS
14. OH
R
15.
SH
AT
23.
H3C
H
K
16.
Br 24.
CH3
T
O NH
EE
17.
Cl
N
25.
O NH2
VI
CH3
18.
26. O
F N
19.
F F
27. O
OH
36.
O S O H2C NH2
37.
H2C
- CH2
28. C
+
N 38. H3C CH2
IR
H3C CH3
39.
CH3
IS
CH3
O O N
R
40.
29.
AT
O CH3
O 41.
H
O
K
30.
T
CH3
CH3 42.
EE
31.
CH3
N
HC
32. 43.
CH2
CH3
VI
33. H2C
O N
H2C 44.
34.
H3C O
CH3
35.
N O
H2C 45.
IUPACE NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.24
Compare Stability
1. , 2. ,
IR
NO2 NO2
3. , 4. ,
IS
R
5. , 6. F – CH2 – CH 2 , Cl – CH2 – CH2
AT
F
7. , 8. , O
H
O F
K
O
F O Cl O
9. O , 10. O ,
T
F Cl O
EE
CH2 O O
11. 12. , ||
, CH3 – C – O
H O
N
VI
O O O O
|| || || ||
13. CF3 – C – O , CCl3 – C – O 14. CHCl2 – C – O , O2N – CH2 – C – O
O
15. , 16. ,
O
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.25
CH3
1. 11.
H2C
CH2
IR
12.
H2C
2.
IS
13. H3C
CH3
3. CH3
R
14. H2C CH2
4.
AT H2C
15.
H
H2C CH2
5.
K
16.
6.
T
EE
CH2
7.
N
H2C
17.
VI
8.
9. H2C CH2
H3C CH3
10.
18.
19. 26.
20. 27.
21. 28.
IR
22.
IS
H3C
29.
R
23.
AT 30.
H H H2C
+
N
H
H
K
24.
T
H
EE
H +
P CH2
H
25. 31.
N
VI
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.26
-
1. H2C CH2
IR
2. H3C
-
O
IS
NH2
3.
R
CH
-
AT
4.
H
NH2
K
5. O
T
EE
-
C
6.
N
VI
-
CH
7.
8. -
O -
O
CH3
O
9.
S.No. Compound Resonating Structure
Cl
10.
- CH3
11. H2C
12. H3C
IR
NH2
IS
CH
13.
R
-
CH
14.
AT
H
H3C
K
O
T
15.
EE
O
N
O
CH3
VI
16. H3C
O
-
O
17.
18. H3C
OH
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.27
CH
1.
IR
CH
IS
2.
R
CH
3. AT
H
K
T
4.
HC
EE
H2C CH
5.
N
CH3
VI
6.
H2C
CH3
7.
O
S.No. Compound Resonating Structure
H2C
8.
O
O +
CH
9.
H
N +
10. CH
IR
HO
IS
+
11. CH
H3C
R
S +
CH
12. AT
H
+
13. C
K
OH
T
O
EE
14. +
CH
N
VI
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.28
1. 2.
NH2
IR
3. 4.
IS
–
OO
R
AT O
5. 6.
O
H
K
7. 8.
T
EE
N
9. 10.
VI
11. 12.
13. 14.
15. 16.
–
O
CH2
..
17. 18. H2 N C N:
NO2
19. NOO
3 20. O=C=O
IR
21. 22.
IS
23. 24.
R
25. AT
26.
–
O
H
27. 28.
K
T
EE
–
29. 30. OO– C = O
–
OO
N
VI
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.29
OCH3
O – CH3
1. ;
IR
O
O
IS
2. ;
O O O
||
R
3. CH3 – C – OH , CH3 – C– OH, CH3 – C = O– H
NH2
NH2
AT
NH2
H
4. ; ;
K
5. O = C = O ; O C – O ;
+2
O = C – O ; O – C – O
T
EE
O O
6. || ; | ;
H – O – C – NH2 H – O = C – NH2
O O
N
| ; |
H – O – C = NH2 H – O – C – NH2
VI
7. ;
O O O
8. ; ;
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.30
IR
O O–
|| |
–
(2)
IS
(a) (b)
– –
CH2 – CH = NH H2C = CH – NH
R
(3)
(a) (b)
+ + AT
(4) CH3 – O – CH2 CH3 – O = CH2
(a) (b)
+ – – +
(5) H–N=C=O H–N C–O H–N–C O
H
(a) (b) (c)
..
K
(6) Me .. N Me + N –
O
.. O O
.. O
(a) (b)
T
H +
O OH
|
|| |
EE
(7)
+
(a) (b)
+
N
(8)
+
+ (c)
(a) (b)
VI
O–
O
||
(9) –
O O
(a) (b)
S–
S
||
(10) H H
–
(a) (b)
+ –
: :
(11) H–O–CN:
:
(a) (b)
O O O
| || ||
(12) | | ||
||| ||| C
||
(a) (b) (c)
N N N
O O O
|| |+ + ||
(13) | | ||
C C C
||| (a) ||| (b) || (c)
IR
N N N
O O O
|| | |
IS
+ CH C
||
(14) H CH2 H H CH2
|
2
(a) (b) (c)
O+
: :
R
O
+
(15)
(a) (b)
AT
N N
H
(16)
K
(a) (b)
O O O O
|| || | ||
T
(17)
EE
(a) (b)
N:
|||
+
(18) N
+
:
N
(a) (b)
VI
O O O
|| | ||
(19)
+
+
O CH2 O CH2 O CH2
||
||
||
(1)
IR
(a) (b) (c)
+ +
:
:
(2)
IS
H2N – CH = NH2 H 2N = CH – NH 2
(a) (b)
O O +O O O O+
|| || | || || |
R
+
(3)
(a) (b)
AT (c)
O O
||
(4) Me – N +
H
Me – N +
||
|
O O
(a) (b)
K
+ +
:
H–C=N=N–H H–CN–N–H
(5)
T
(a) (b)
(6) +
Me – CH – C O
EE
H3C – HC = C = O
(a) (b)
O O
|| |
:
H–C–N–H H–C=N–H
N
(7)
:
(a) (b)
VI
O O
|| |
(8) CH3 – C – CH2 CH3 – C = CH2
(a) (b)
+ +
(9) CH2 – C = C – CH 3 CH2 = C – C – CH3
| | | |
H H H H
O O
(10) || |
C C
||
|
|
O O O O
O O
|| |
+
: :
(11) Me OH Me O–H
(a) (b)
N O N O N O
(12)
(a) (b) (c)
O O
|| |
(13)
IR
(b)
(a)
IS
O O
| ||
(14)
R
| ||
C C AT
(a) (b)
Me – CH – C CH
H
(15) Me – CH = C = CH
(a) (b)
K
+ +
: :
(a) (b)
T
EE
(17)
: :
S S
(a) (b)
N
+ +
VI
+
:
(19) H2 N – C N: H2N = C = N:
(a) (b)
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.32
S.N. Compound Huckel Rule (4n + 2)e– All carbon of ring Cyclic Complete delocalisation Nature
are sp2 or sp
1.
IR
2.
IS
R
3.
AT
4.
H
5.
K
T
6.
EE
7.
N
|
N
H
VI
8. N O
|
H
N
9.
N
10.
(1)
IR
(2)
IS
(3)
R
(4)
+
(5)
AT
(6)
H
K
(7)
O
T
(8)
EE
(9)
N
(10)
VI
(11)
B
|
H
(12)
O O
(13)
O O
B
|
H
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.34
(1)
(2)
IR
O
(3)
IS
S
R
(4)
N
|
H AT
H
(5)
O
K
T
(6)
O
EE
(7)
O
N
(8)
VI
(9)
(10)
(11)
O
O
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.35
(1)
O
IR
(2)
IS
N O
|
H
R
O
(3)
N
AT
H
H
N
K
(4)
N
T
N
EE
(5)
N
N
(6)
N
VI
(7)
N
H
N N—H
(8)
1.
IR
O
2.
IS
R
3.
AT
CH3
|
H
B
4.
K
T
5.
N
EE
6.
N
N
|
H
VI
7. N :S:
8. N
O
N N
9. N N
H N
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.37
1.
IR
IS
2.
R
AT
3.
H
K
4.
T
EE
5.
CH2
N
6.
VI
CH2
7.
8.
N
9.
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.38
1.
IR
2.
IS
3.
R
H
N
4. AT
CH2
H
5.
K
6.
T
EE
7.
N
VI
8.
9.
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.39
(2) H3C
H3C CH2
(12)
CH3
H3C
IR
(3) CH3
H3C CH2
H3C
IS
(13)
H3C CH3
(4)
CH3
R
(14)
H3C
(5)
H3C
CH3 AT
(15)
H
H3C
CH3
H3C
K
(6) CH3
H3C
(16)
T
H3C CH3
EE
(7) CH3
H3C CH3
(17)
CH3
N
CH3
(8) H2C
VI
CH3
(9) H3C CH3
(18)
H3C
(10)
H3C CH2
CH3
H3C (19)
CH3
CH3
(11)
H3C
H3C H3C CH3
(20)
(28)
H3C CH3
(21)
CH3
IR
(29)
(22)
H3C
IS
R
(23)
CH3
AT
(30)
H3C
(24)
H
K
H3C CH3
T
(31)
(25)
EE
H3C
N
(32)
VI
(26)
H3C
(33)
H3C
(27)
H3C CH3 H3C
(34)
(40)
CH3
H3C CH3
CH3
IR
(35)
H3C
IS
CH3
(41) CH3
R
CH3
(36) CH3
AT
H3C
H
CH3
(42)
K
CH3
EE
CH3 H3C
(43) H3C
N
(38) H3C
VI
CH3
(44)
H3C
H3C
(39)
(45)
CH3
H3C CH3
(46)
H3C
(52)
CH3
IR
(47)
CH3
IS
(53)
R
(48)
AT
(54)
H
K
(55)
(49)
T
EE
H3C
(50)
H3C
CH3
(57)
H3C
(51)
(58)
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.40
CH3
(1) (2)
IR
IS
(3) (4)
R
AT
H
CH3
K
(5) (6)
CH3
T
EE
H3C
CH3
N
(7) (8)
CH3
VI
CH3
CH3
CH3
(9) (10)
CH3
CH3
No of No. of
-hydrogen -hydrogen
CH3
(11) (12)
CH3
CH2
(14) H2C
IR
(13) CH3
CH3
IS
H3C CH3
(15) (16) H3C CH3
H3C
R
H3C
H 3C CH3
(17) CH2 AT (18)
CH3
CH3
H
H3C CH3
H2C
CH3
K
(19) (20)
H3C
H3C
T
EE
N
VI
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.41
CH3
IR
(3) (4)
IS
H3C H3C
CH3
R
(5) (6)
AT
CH3
H
H3C
CH3
K
(7) (8)
T
CH3
EE
H3C
(9) (10)
N
H3C
VI
H2C H3C
(11) (12)
CH3
(13) (14)
No of -hydrogen No. of -hydrogen
H2C H3C
(15) (16)
CH3 CH3
(17) (18)
CH3 CH3
IR
CH3 CH3
IS
CH3
(19) (20)
H3C
H3C CH3
R
H3C
CH3
H3C CH3
AT
(21)
H3C
H
H3C CH3
K
T
EE
N
VI
H3C CH3
(1) CH3
CH3 (11)
H3C
(2)
IR
H3C CH3
(3) (12)
H3C CH3
IS
H3C CH3
R
(4) (13)
H3C CH3
H3C
AT
(14)
(5)
H
H3C CH3
K
H3C (15)
(6) CH3
H3C
T
EE
H3C (16)
(7)
H3C CH3
H3C
N
CH3
CH3
VI
CH3
(9)
(18)
(10)
H3C
(22)
(19)
H3C CH3
(23)
IR
(20)
IS
CH3
R
(24)
(21) AT
H
CH3
K
(25)
T
H3C
EE
N
VI
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.43
1.
H
(i) (ii) (iii) (iv) (v)
Me Me Me
| l
IR
l
2. Ph – CH2 – CH CH – C – Me Me – CH – CH CH – C – Me
l l
Me Me
IS
(i) (ii)
R
(iii) (iv)
3. Me – CH – CH – CH3
Me – CH2
AT
C H3
Me
l
Me – C – CH2
l l
Me
Me
H
(i) (ii) (iii) (iv)
K
4.
T
EE
5.
VI
6.
7. Me – CH = CH2
1.
IR
IS
2.
R
(i) (ii) (iii) (iv)
AT
H
K
3.
T
EE
4.
IR
IS
R
6.
AT
(i) (ii) (iii) (iv)
H
K
T
EE
N
VI
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.45
1.
IR
2.
IS
(i) (ii) (iii) (iv)
R
3. (Et)2 CH (Et)3 C
(i) (ii)
AT (iii) (iv)
H
4.
K
5.
EE
6.
VI
7.
1.
(i) (ii)
IR
IS
2.
R
3.
AT
(i) (ii)
H
K
(iii)
T
EE
4.
5.
CH3 H3C
(i) (ii)
IR
IS
R
AT
H
K
T
EE
N
VI
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.47
IR
IS
CH3 CH3
3. 4.
R
CH3
CH3
(iii)
H
CH3 CH3
K
5. 6.
(i) (ii)
T
(i) (ii)
EE
7. 8.
N
(i) (ii)
VI
(i) (ii)
H3C H3C
O O
CH2 CH3
9. 10.
(i) (ii)
(i) (ii)
IUPAC NOMENCLATURE
BYVINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.48
IR
2.
IS
CH3
CH3
CH3
CH3
3.
R
CH3 CH3
4.
H3C CH3
H3C
AT
CH3
CH3
CH3
H3C
CH3 CH3
H
CH3
5.
T
EE
H3C
+ +
CH + C
CH
N
6.
VI
7. CH3 CH3
CH3
H3C
CH3
8.
9.
ANSWER KEY
DPP No.-1
1. D 2. D 3. A 4. A 5. C 6. CD
7. ABCD 8. (a) 1°, (b) 2°, (c) 3°, (d) 3°, (e) 2°
9. (a) 2°, (b) 1°, (c) 3°, (d) 2°, (e) 2°, (f) 3°
DPP No.-2
1. a-9, b-12, c-1, d-5, e-9, f-1, g-1, h-4, i-6 2. a-9, b-11, c-3, d-5, e-9, f-3, g-0, h-7, i-5
1°
2° 1° 3° 2°
3° 4° 3° 4° 3° 3° 1° 3° 3° 1°
2° 1° 1°
2° 3° 3° 2° 2° 2° 3° 3°
3. 2° 1° 2° 3° 2°
IR
2° 3° 3° 4° 1° 3° 2° 2° 3° 1°
2° 3° 3° 2°
1°
(I) (II) (III) (IV)
IS
4. (A) P; (B) P, Q; (C) P, Q, R, S; (D) Q,R
DPP No.- 3
R
1. 4 2. 2.5 3. 7 4. 10 5. 10 6. 2 7. 7
8. 2 9. 10 10. 3 11. 3 12. 3 13. 4 14. 6
15. 0 16. 4 17. 3 18.
AT 5 19. 4 20. 4 21. 2
DPP No.- 4
1. 5 2. 0 3. 1.5 4. 2 5. 11 6. 21 7. 5
H
8. 16 9. 5
DPP No.- 5
K
1. C 2. A 3. C 4. B 5. B 6. B 7. C
8. D
T
DPP No.- 6
EE
DPP No.- 7
1.
(1) 0 (2) 1 (3) 2 (4) 0 (5) 1 (6) 2 (7) 1
(8) 0 (9 0 (10) 0 (11) 1 (12) 0 (13) 1 (14) 4
(15) 2 (16) 5 (17) 2 (18) 3 (19) 7 (20) 7 (21) 17
(22) 4 (23) 5 (24) 1 (25) 0 (26) 2
2. A Q ; B S ; C P ; D R 3. A R ; B Q ; C S ; D P
DPP -8
1. D 2. D 3. A 4. A 5. C 6. CD
7. ABCD 8. (a) 1°, (b) 2°, (c) 3°, (d) 3°, (e) 2°
9. (a) 2°, (b) 1°, (c) 3°, (d) 2°, (e) 2°, (f) 3°
DPP - 9
1. 4 2. 2.5 3. 7 4. 10 5. 10 6. 2 7. 7
8. 2 9. 10 10. 3 11. 3 12. 3 13. 4 14. 6
15. 0 16. 4 17. 3 18. 5 19. 4 20. 4 21. 2
IR
DPP - 10
1. 5 2. 0 3. 1.5 4. 2 5. 11 6. 21 7. 5
IS
8. 16 9. 5
DPP -11
R
1.
(1) 0 (2) 1 (3) 2 (4) 0 (5) 1 (6) 2 (7) 1
(8)
(15)
(22)
0
2
4
(9
(16)
(23)
0
5
5
(10)
(17)
(24)
0
2
1
AT
(11)
(18)
(25)
1
3
0
(12)
(19)
(26)
0
7
2
(13)
(20)
1
7
(14)
(21)
4
17
2. A Q ; B S ; C P ; D R 3. A R ; B Q ; C S ; D P
H
DPP - 12
K
DPP - 13
1. 5-methyl-hex-2-ene 2. 2-octene
VI
3. 2, 4-heptadiene 4. 3, 7-dimethyl-1-octene
6. 2-methyl-2-butene 7. 3-bromopropene
8. Deca-3, 7-diene 9. 1-methylcyclohexene
10. 3-methylcyclohexene 11. 4-methyl cyclohexene
12. 2,6-dimethyl-Octa-2,6-diene 13. Hex-2-ene
14. Hex-2-ene 15. 3-methyl-Pent-2-ene
16. 3-methyl-Pent-2-ene 17. Ethylcyclohexene
18. 1-Bromo-2-chlorocyclobutene 19. 4-ethyl-3-propyl Hept-1-ene
20. 4-(1, 2-dimethyl Butyl)-1, 3, 5-Hepta triene 21. 5-ethyl-4,6-dimethyl-oct-1-ene
22. But-2-yne 23. Hex-2-yne
24. Oct-1-yne 25. Non-3-yne
26. 1-Heptene 27. Hex-1-en-5-yne
28. 1-Decen-5-yne 29. 4-Propyl hept-2-yne
30. Oct-6-en-1-yne
DPP - 14
1. hexa-1,3-diene 2. 2-ethylbut-1-ene
3. buta-1,3-diene 4. penta-1,3-diene
5. buta-1,2-diene 6. 4-propylhex-1-en-5-yne
7. Ethyne 8. 2-chloropropene
IR
9. 1-bromocyclopenta-1,3-diene 10. 4-bromo-6-chloro-3-cyclobutylcyclohexene
11. buta-1,3-diyne
IS
12. 1-isopropylcycloheptene or methylethylcycloheptene
DPP - 15
R
1. nonan-4-ol 2. 5-bromo-6-(2-bromocyclopropyl)octan-3-ol
3. 5-(2-cyclopropylcyclopropyl)heptan-3-ol AT 4. 6-(2-bromocyclopropyl)-3-chlorooctan-2-ol
5. 6-cyclohexylnon-4-ene-3,7-diol 6. 5-(3-chloro-4-cyclobutylcyclohexyl)octan-2-ol
7. 3(4-chloro-1-propylhexyl)cyclohexan-1-ol 8. 5-chloro-6-(3-chlorocyclohexyl)octan-3-ol
9. hept-6-en-1-ol 10. hex-5-en-2-ol
H
DPP - 16
K
1. 3-(cyclopropyl)-5-fluorohepta-1,6-dien-4-ol 2. methanol
3. 7-bromo-5-ethylnonan-3-ol 4. 6-ethyloctan-3-ol
T
5. 5-methylheptan-3-ol 6. 5-nitrooctan-3-ol
7. 5-bromo-4-ethyl-6-methyldecane 8. 9-fluoro-6-nitroundecan-4-ol
EE
DPP - 17
N
DPP - 19
1. D 2. A 3. C 4. B 5. A 6. B 7. A
8. B 9. C 10. D 11. A 12. B 13. A 14. C
15. A
DPP - 20
1. A 2. B
3. (i) 2-chloro-3-methylbutane (ii) 3-chloro-4-methylhexane
IR
(iii) 1-Iodo-2, 2-dimethylbutane (iv) 1-bromo-3, 3dimethyl-1-phenylbutane
(v) 2-bromo-3-methylbutane (vi) 3-chloro-3-methylpentane
(vii) 3-bromomethyl-3-methylpentane (viii) 3-chloro-5-methyl-hex-2-ene
IS
(ix) 4-bromo-4-methyl-2-pentene
4. (i) 2-bromo-3-chlorobutane (ii) 1-bromo-1-chloro-1,2,2-trifluoroethane
(iii) 1-bromo-4-chloro-but-2-yne (iv) 1,1,1,2,3,3,3-heptachloro-2-trichloromethylpropane
R
Cl
5. (i) (ii)
I
AT (iii)
Br
Br
OH OH Et – O
T
OH Cl
OH
(v) (vi) (vii) (viii)
OH HO
N
VI
DPP - 21
1. –I 2. –I 3. –I 4. –I 5. –I
6. +I 7. +I 8. –I 9. –I 10. –I
11. –I 12. +I 13. –I 14. –I 15. –I
16. No effect 17. –I
DPP - 22
IR
(s) +I (t) None
DPP - 23
IS
1. +I 2. +I 3. +I 4. –I 5. –I 6. –I 7. –I
8. +I 9. None 10. –I 11. –I 12. –I 13. –I 14. –I
15. –I 16. –I 17. –I 18. +I 19. –I 20. –I 21. +I
R
22. +I 23. +I 24. –I 25. –I 26. –I 27. –I 28. –I
29. –I 30. –I 31. None 32. –I 33. +I 34. +I 35. +I
36. +I 37. None 38. +I 39.
AT +I 40. –I 41. –I 42. +I
43. +I 44. –I 45. –I
DPP - 24
H
1. i > ii 2. i > ii 3. i > ii 4. ii > i 5. i > ii 6. i > ii 7. i > ii
8. i > ii 9. i > ii 10. i > ii 11. ii > i 12. i > ii 13. i > ii 14. i > ii
K
DPP - 25
T
EE
1. 2. 3. 4.
N
CH2
VI
5. 6. 7. 8.
CH3
9. 10. 11.
H2C
IR
19. 20. 21.
IS
H
H + H
N
R
+ +
+ +
31.
DPP - 26
NH2
O
1. 2. 3.
CH3–C
O
NH2
O
4. 5. 6.
IR
OCH3
O
7. 8. C 9.
IS
O O
Cl
R
O
10. 11. AT 12.
NH2
OCH3
H
K
EE
O
O OH
16. 17. 18.
O O
N
DPP - 27
VI
1. 2. 3. 4.
–
O
5. 6. 7.
O–
H
O
N
–
8. O 9. 10.
OH S O
11. 12. 13. 14.
OH
DPP - 28
IR
1. 2. 3.
OH
O
IS
NH2 O
O
4. 5. 6.
R
O
AT
CH — CH — NH2
O
H
7. NH 8. 9.
K
O H
T
1 1
2 O O 2
1
EE
O 2
10. 11. 12. H
H2N O
1 1
1
O 2
O 2
2 O
N
•
CH2
VI
13. 14. 15. Me — S — CH 2
• •
CH2
O
16. Me N 17. 18. H 2N — C — N:
O N
O O
O
Me
19. N 20. O — C — O or O—C—O 21.
O N:
O O
H2N NH2 O
C
22. 23. 24.
NH
OH
15
IR
O O
15 15
25. 26. 27. or
15 15
IS
O
O
R
O
28. 29. 30. C O
O
AT
O
DPP - 29
H
1. I > II 2. II > I 3. I > III > II 4. I > II > III 5. I > II > III > IV
K
DPP - 30
EE
DPP - 31
DPP - 33
IR
1. NA 2. AA 3. Aro 4. Aro 5. Aro
6. NA 7. NA 8. NA 9. Aro 10. AA
11. AA 12. Aro 13. Aro
IS
DPP - 34
1. AA 2. Aro 3. Aro 4. Aro 5. NA
R
6. Aro 7. NA 8. NA 9. Aro 10. NA
11. Aro
1. Aro 2. Aro
AT
3.
DPP - 35
Aro 4. Aro 5. Aro
6. NA 7. Aro 8. Aro 9. Aro
H
DPP - 36
K
DPP - 37
1. Aro 2. Aro 3. Aro 4. Aro 5. Aro
EE
DPP - 38
1. Aro 2. NA 3. Aro 4. Aro 5. Aro
N
6. AA 7. AA 8. Aro 9. Aro
VI
DPP-39
1. 0 2. 3 3. 6 4. 6 5. 9 6. 12 7. 11
8. 2 9. 5 10. 5 11. 7 12. 7 13. 7 14. 4
15. 4 16. 7 17. 10 18. 6 19. 8 20. 3 21. 8
22. 8 23. 5 24. 3 25. 5 26. 4 27. 7 28. 4
29. 6 30. 6 31. 6 32. 3 33. 2 34. 1 35. 0
36. 6 37. 6 38. 5 39. 4 40. 4 41. 6 42. 9
43. 12 44. 4 45. 7 46. 10 47. 8 48. 5 49. 1
50. 7 51. 5 52. 4 53. 10 54. 8 55. 3 56. 3
57. 8 58. 8
IR
DPP-40
1. 4 2. 5 3. 6 4. 8 5. 2
IS
6. 8 7. 6 8. 6 9. 6 10. 10
11. 5 12. 3 13. 3 14. 2 15. 5
16. 5 17. 2 18. 12 19. 4 20. 4
R
DPP-41
1. 5 2. 8 3. 5 4. 3 5. 2
6.
11.
1
1
7.
12.
0
6
8.AT
13.
4
3
9.
14.
2
3
10.
15.
7
4
16. 7 17. 6 18. 4 19. 6 20. 0
21. 6
H
DPP-42
1. 6 2. 5 3. 6 4. 6 5. 6 6. 7 7. 9
K
DPP-43
1. i > ii > iii > iv > v 2. iii > i > ii > iv 3. i > ii > iv > iii
4. i > iii > iv > ii 5. i > iv > ii > iii 6. i > iii > ii > iv
7. iii > i > ii
N
DPP-44
VI
1. i > ii > iii > iv > v > vi > vii 2. i > ii > iii > iv 3. i > ii > iii > iv
4. i > ii > iii > iv 5. i > ii > iii > iv 6. i > ii > iv > iii
DPP-45
1. i > iii > ii 2. iii > ii > iv > i 3. iii > ii > iv > i
4. iii > ii > iv > i 5. i > ii > iv > iii 6. i > ii > iv > iii
7. ii > iii > i
DPP-46
1. i > ii 2. i > ii > iii 3. ii > i > iii
4. i > ii > iii 5. ii > i > iii 6. i > ii
7. iv > iii > ii > i 8. ii > i
DPP-47
1. ii > i 2. i > ii 3. i > ii
4. iii > i > ii 5. i > ii 6. ii > i
7. i > ii 8. i > ii 9. i > ii
10. i > ii
DPP-48
1. b>a>c 2. a>b>c 3. b>c>a 4. c>a>b
5. a>b>c 6. c>a>b 7. a>b>c 8. a=b
9. a>b
IR
IS
R
AT
H
K
T
EE
N
VI