D) 3 Alcohol

Chapter 10,11,14 Homework
Chapter 10
10.1 Classify 2,3-dimethylbutan-2-ol.

a) 0o alcohol
b) 1o alcohol
c) 2o alcohol
d) 3o alcohol
10.2 Give the common name for (CH3)3CCH2OH.

a) tert-Pentyl alcohol
b) tert-Butyl alcohol
c) Isopentyl alcohol
d) Isobutyl alcohol
e) Neopentyl alcohol
10.3
a) Butan-1-ol
b) Butan-2-ol
c) Butane-1,2-diol
d) Butane-1,2-ol
10.4
a) 1-Propylphenol
b) 2-Propylphenol
c) 3-Propylphenol
d) 4-Propylphenol
10.5 Give the name of the alcohol that is in beer and wine.
a) Methanol
b) Ethanol
c) Propan-2-ol
d) Propan-1-ol
10.6 Give the common use for ethane-1,2-diol.

a) Drinking alcohol
b) Rubbing alcohol
c) Vinegar
d) Antifreeze
10.7
a) NaCH2CH2CH2OH
b) CH3CH(Na)CH2OH
c) CH3CH2CH(Na)OH
d) CH3CH2CH2ONa
10.8
a) CH3CH2CH2OH
b) CH3CH2OCH3
c) CH3CH2OH
d) CH3CH2OMgBr
10.9 Identify the alcohol formed when a Grignard reagent adds to a ketone.
a) 0o alcohol
b) 1o alcohol
c) 2o alcohol
d) 3o alcohol
10.10
a) 3-Methylpentan-3-ol
b) 2-Methylbutan-2-ol
c) 2-Methylbutan-3-ol
d) 2-Methylpentan-3-ol
10.11
a) 3-Methylpentan-3-ol + methanol
b) 2-Methylbutan-2-ol + ethanol
c) 2-Methylbutan-3-ol + methanol
d) 2-Methylpentan-3-ol + ethanol
10.12
a) CH3CH2CH(OH)CH3
b) CH3CH2OH
c) CH3CH2CH2OH
d) CH3CH2CH2CH2OH
10.13 Give the reason why Grignard reactions must have dry glassware.
a) Grignard reagents react vigorously and irreversibly with water.
b) Magnesium dissolves in water.
c) The alkyl halide dissolves in water.
d) Grignard reagents do not react with water.
10.14 Identify the compounds that sodium borohydride reduces.

a) Aldehydes and ketones
b) Esters and carboxylic acids
c) Aldehydes, ketones, esters, and carboxylic acids
d) Alkenes and alkynes
10.15
a) CH2=CHCH(OH)CH2COOH
b) CH3CH2CH(OH)CH2COOH
c) CH2=CHCH(OH)CH2CH2OH
d) CH3CH2CH(OH)CH2CH2OH
10.16
10.17
10.18 Identify the compounds that hydrogen and Raney nickel reduces.
e) Aldehydes, ketones, alkenes, and alkynes
10.19
10.20
a) CH3CH2CH2SOH
b) CH3CH2CH2SO2H
c) CH3CH2CH2SO3H
d) CH3CH2CH2SO4H
Chapter 11
11.1
a) (CH3)2CHOH
b) (CH3)2C=O
c) CH3CH2COOH
d) No reaction
11.2
a) CH3COOH
b) CH3CH2COOH
c) CH3CH2CHO
d) No reaction
11.3
a) CH3COOH
b) CH3CH2COOH
c) CH3CH2CHO
d) No reaction
11.4
a) (CH3)3COH
b) (CH3)2C=O
c) CH2=C(CH3)2
d) No reaction
11.5 Identify the reagent that is notused to oxidize a primary alcohol to a carboxylic acid.
a) HNO3
b) PCC
c) Na2Cr2O7, H2SO4
d) CrO3, H2SO4
11.6
a) CH3CH2CH2OTs
b) CH3CH2CH2OCl
c) CH3CH2CH2Cl
d) CH3CH2CH2Ts
11.7
a) CH3CH2CH2OTs
b) CH3CH2CH2OCl
c) CH3CH2CH2Cl
d) CH3CH2CH2Ts
e) CH3CH2CH3
11.8
a) (CH3)2CHBr
b) CH3CH2Br
c) CH3CH2CH2Br
d) BrCH2CH2CH2Br
11.9
a) (CH3)2CHCH2Br
b) (CH3)3CBr
c) CH3CH2CH2CH2Br
d) BrCH2CH2CH2CH2Br
11.10
a) CH3CH2CH2OPBr3
b) CH3CH2CH2OBr
c) CH3CH2CH2Br
d) CH3CH2CH2PBr2
11.11
a) CH3CH2CH2OSCl2
b) CH3CH2CH2Cl
c) CH3CH2CH2OCl
d) CH3CH2CH2SO2H
11.12
a) But-1-ene
b) cis-But-2-ene
c) trans-But-2-ene
d) All of the above
11.13
a) 140 °C gives dipropyl ether.
b) 180 °C gives dipropyl ether.
c) 140 °C gives dipropyl ether + propene.
d) 180 °C gives dipropyl ether + propene.
11.14
a) 2,3-Dimethyl-3-hydroxybutan-2-one
b) 2,3-Dimethylbutane-2,3-dione
c) 2,3-Dimethylbutane-2,3-diol
d) 3,3-Dimethylbutan-2-one
11.15
a) Two aldehydes
b) Aldehyde + ketone
c) Two ketones
d) Ketone + carboxylic acid
e) Two carboxylic acids
11.16
a) CH3CH2COOCH3
b) CH3COOCH2CH3
c) CH3CH2COOCH2CH3
d) CH3COOCH3
11.17
a) CH3OSO3H
b) CH3OSO3CH3
c) CH3OSO2CH3
d) CH3OSO2H
11.18
a) CH3ONO2
b) CH3NO2
c) CH3ONO
d) CH3OH
11.19
a) CH3OPO(OH)2
b) (CH3O)2PO(OH)
c) (CH3O)3PO
d) CH3OCH3
11.20
a) CH3CH3
b) CH3CH2OCH3
c) CH3OCH3
d) CH3CH2OCH2CH3
Chapter 14
14.1
a) Ethyl propyl ether
b) Diethyl ether
c) Ethyl isopropyl ether
d) Pentyl ether
14.2
a) 1-Ethoxypropane
b) 2-Ethoxypropane
c) 1-Propoxyethane
d) 2-Propoxyethane
14.3
a) 12-Crown-4
b) 15-Crown-5
c) 18-Crown-6
d) 21-Crown-7
14.4
a) Oxetane
b) Furan
c) Pyran
d) Dioxane
e) Epoxide
14.5
a) Oxetane
b) Furan
c) Pyran
d) Dioxane
e) Epoxide
14.6
a) CH3CH2OCl
b) CH3CH2Cl
c) CH3CH3
d) CH3CH2OCH3
14.7
a) (CH3)2C(OCH3)CH3
b) (CH3)2CHCH2OCH3
c) (CH3)3CCH3
d) (CH3)2C(OCH2CH3)CH3
14.8
a) CH3CH=CH2
b) (CH3)2CHOCH(CH3)2
c) CH3CH2CH2OCH2CH2CH3
d) CH3CH2CH2OCH(CH3)2
14.9
a) CH3CH=CH2
b) (CH3)2CHOCH(CH3)2
c) CH3CH2CH2OCH2CH2CH3
d) CH3CH2CH2OCH(CH3)2
14.10
a) C6H5OH + CH3CH2Br
b) C6H5Br + CH3CH2OH
c) C6H5OH + CH3CH2OH
d) C6H5Br + CH3CH2Br
14.11
a) CH3CH2CH2Br + CH3CH2OH
b) CH3CH2CH2OH + CH3CH2Br
c) CH3CH2CH2OH + CH3CH2OH
d) CH3CH2CH2Br + CH3CH2Br
14.12
a) Dimethyl sulfide
b) Dimethyl thiol
c) Dimethyl sulfone
d) Dimethyl sulfoxide
14.13
a) Dimethyl sulfide
b) Dimethyl thiol
c) Dimethyl sulfone
14.14
a) Dimethyl sulfide
b) Dimethyl thiol
c) Dimethyl sulfone
14.15
a) Ethyl methyl sulfide
b) Ethyl methyl thiol
c) Ethyl methyl sulfone
d) Ethyl methyl sulfoxide
14.16
a) Alcohol + carboxylic acid
b) Two alcohols
c) Two carboxylic acids
d) Epoxide + carboxylic acid
e) Two epoxides
14.17
a) Epoxide
b) Alcohol
c) Alkyl halide
d) Ether
e) Carboxylic acid
14.18
a) HOCH2CH(OH)CH3
b) HOCH2CH(OCH2CH3)CH3
c) CH3CH2OCH2CH(OH)CH3
d) CH3CH2OCH2CH(OCH2CH3)CH3
14.19
a) HOCH2CH(OH)CH3
b) HOCH2CH(OCH2CH3)CH3
c) CH3CH2OCH2CH(OH)CH3
d) CH3CH2OCH2CH(OCH2CH3)CH3
14.20
a) HOCH2CH(OH)CH3
b) HOCH2CH(CH2CH3)CH3
c) CH3CH2CH2CH(OH)CH3
d) CH3CH2CH2CH(CH2CH3)CH3

D) 3 Alcohol

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Chapter 10,11,14 Homework

10.1 Classify 2,3-dimethylbutan-2-ol.

10.2 Give the common name for (CH3)3CCH2OH.

10.6 Give the common use for ethane-1,2-diol.

10.14 Identify the compounds that sodium borohydride reduces.

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