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Bengkel Ambang SPM 2009 Kertas 3
Bengkel Ambang SPM 2009 Kertas 3
QUESTION 1:
A group of students carried out an experiment to investigate the effect of type of electrodes
when aqueous copper(II) chloride solution is electrolyzed.
The electrolysis was first carried out by using carbon electrodes.
Both the electrodes were weighed.
Copper(II) chloride solution was electrolyzed for 45 minutes.
Then both the carbon electrodes were weighed again.
The experiment was repeated by replacing carbon electrodes with copper electrodes.
Diagram 1.1 shows the set-up of apparatus used for the electrolysis of copper(II) chloride
solution using carbon electrodes.
A A
Carbon electrodes
Diagram 1.1
Diagram 1.2 shows the set-up of apparatus for the electrolysis of copper(II) chloride
solution using copper electrodes.
A A
Copper electrodes
Diagram 1.2
(a) Write the observation and inference obtained at the carbon anode and both the
copper electrodes during the electrolysis.
Carbon anode
Copper anode
Copper cathode
[6 marks]
…………………………………………………………………………..………………
…………………………………….…………………………………………………….
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[3 marks]
(c) State the hypothesis for the experiment.
…………………………………………………………………………………………
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[3 marks]
(d) Based on the experiment in Diagram 1.1, state the colour change of the copper(II)
chloride solution after 45 minutes.
…………………………………………………………………………………………
…………………………………………………………………………………………
[3 marks]
(e) Classify all the ions present in copper(II) chloride solution into cations and anions.
[3 marks]
QUESTION 2
A student carried out an experiment to determine the end-point for the titration of 25.0 cm 3 of
1.0 mol dm-3 sodium hydroxide solution with 1.0 mol dm-3 hydrochloric acid. Phenolphthalein is
used as the acid-base indicator. Hydrochloric acid is added until the end-point of titration is
reached.
Table 2 shows the three burette readings for the titrations that have been conducted.
cm3
0 13 25
Initial burette
reading 1 14 26
2 15 27
12 25 38
26
Final burette 13 26 39
reading
27
14 27 40
Table 2
(a) Record the burette readings for the three titrations in the spaces provided in Table 1.
[3 marks]
(b) Construct a table and record the initial burette reading, final burette reading and the volume
of acid used for each titration.
[3 marks]
(c) Calculate the average volume of hydrochloric acid used in the experiment.
.
[3 marks]
(d) If the experiment is repeated by replacing 1.0 mol dm -3 of hydrochloric acid with
1.0 mol dm-3 of sulphuric acid, predict the volume of sulphuric acid needed to reach the end-
point of titration.
………………………………………...………………………………………………………..
[3 marks]
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[3 marks]
QUESTION 3
Diagram 3.1 shows the set-up of apparatus for an experiment to compare the reactivity of
alkali metals towards their reaction with oxygen.
Gas jar
Oxygen gas
Alkali metal
Diagram 3.1
The experiment is carried out using a small piece of lithium, potassium and sodium
respectively to react with oxygen gas.
Observations on the alkali metals in the experiment are shown in Table 3.
White fumes
Lithium
White fumes
II
Potassium
White fumes
III
Sodium
Table 3
(a) Look at the flame produced in each experiment in Table 3. Complete the Table 3
by stating the observation for each reaction of alkali metals towards oxygen.
[3 marks]
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[6 marks]
(c) State one hypothesis for the experiment.
………………………………………………………………………………………
………………………………………………………………………………………
[3 marks]
(d) Give one inference based on the results of the reaction between lithium and oxygen
gas.
………………………………………………………………………………………
………………………………………………………………………………………
[3 marks]
(e) Based on the observation in Table 3, arrange lithium, potassium and sodium in
descending order of reactivity towards oxygen.
………………………………………………………………………………………
[3 marks]
(f) The experiment is repeated using a small piece of rubidium to react with oxygen.
Rubidium is more reactive than lithium, potassium and sodium.
Predict the observation for this experiment.
………………………………………………………………………………………
………………………………………………………………………………………
[3 marks]
(g) Diagram 3.2 shows the reading of pH meter when the metal oxides formed in Set I,
II and III dissolved in water.
pH value 13.19
pH meter
I
Litium hydroxide
solution
pH value 13.61
pH meter
II
Potassium hydroxide
solution
pH value 13.33
pH meter
III
Sodium hydroxide
solution
Diagram 3.2
(i) Record the pH value to one decimal place for Set I, Set II and Set III.
Set I : ………………………………………………………………………..
Set II : ………………………………………………………………………..
[3 marks]
(ii) Construct a table to record the pH value for Set I, Set II and Set III.
[3 marks]
.................………………………………………………………………………
………….………………………………………………………………………
[3 marks]
Ammonia solution
11
Potassium hydroxide solution
14
Sodium hydroxide solution
13
[3 marks]
QUESTION 4
A student carried out three experiments to study the reaction of alkali metal with water.
.
Set up of experiment
Observation of the alkali metal
apparatus
hiss
‘Hiss’
‘pop’
(a) Complete the diagram by stating the observations for the reaction of group 1 metals
with water
(b) After each experiment , a pH meter is dipped into the solution in the basin.
The pH value of the solution is 13.
…………………………………………………………………………………………
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(c) Based on the observations in the experiment above, state the relationship between the position
of the elements in Group 1 of the Periodic Table of Elements with the reactivity of the
elements towards water.
…………………………………………………………………………………………..
…………………………………………………………………………………………..
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5. An experiment is carried out to study the relationship between the concentration of hydrogen
ions,H+ and the pH value of hydrochloric acid.
Diagram 5 shows the pH value of five solution of hydrochloric acid, a strong acid with different
concentration.
3.0 4.0
(b) Construct a table and record the concentration of acid and the pH value for this experiment.
………………………………………………………………………………………..
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Manipulated variable:………………………………………………………………...
Responding variable:………………………………………………………………...
Controlled variable:…………………………………………………………………..
…………………………………………………………………………………………
…………………………………………………………………………………………
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(f) Classify the ions in hydrochloric acid solution into anion and cation.
(g) Calculate the number of moles of hydrogen ion in 50 cm3 of 0.01 mol dm-3 hydrochloric acid.
(h) Predict the pH value if the experiment is repeated by using 0.01 mol dm-3 of ethanoic acid.
………………………………………………………………………………………..
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QUESTION 5
The diagram 6 below shows the set-up apparatus of the experiment to investigate the
effect of metal on rusting of iron, when it is in contact with other metals. Three iron nails
coil with different metals are placed separately into three test tubes A, B and C, the test
tube D as a control. Each of the test tubes is filled with a agar-agar solution containing a
small amount of phenolphthalein and potassium hexacyanoferrate(III) solution. The
apparatus is set aside for one day.
Magnesium
Zinc strip
Copper strip
strip
Diagram 6
Table below shows the result of the experiment is set aside after 1 day.
Test tube
A B C D
Intensity of dark
blue colour None None Very high Low
Pink colouration
Present Present Present Present
Inference
………………………………………………………………………………………
……………………………………………………………………………………
[ 3 marks]
…………………………………………………………..
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[3 marks]
(c) Based on the observations, complete the inferences in the table above.
[3 marks]
(d) Write half-equation in oxidation and reduction for the rusting of iron.
Oxidation : ………………………………………………………….
[3 marks]
Reduction: …………………………………………………………..
[3 marks]
……………………………………………………………………….
[3 marks]
…………………………………………………………………………..
………………………………………………………………………….
[3 marks]
……………………………………………………………………………...
[3 marks]
(h) Explain why the present of pink colour all over the test tube.
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[3 marks]
(i) State the change of the oxidation number of iron occurs in test tube C.
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[ 3 marks]
(j) Based on this experiment classify the metals can provide sacrificial protection and
metals that cannot provide sacrificial protection to iron.
[3 marks]
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[3 marks]
QUESTION 6
Diagram 1.1 shows the set-up of apparatus for Experiment I, II, III, IV, V and VI to investigate
the effect of temperature on the rate of reaction between sodium thiosulphate and sulphuric
acid. 50 cm3 of 0.1 mol dm-3 of sodium thiosulphate solution is poured into a conical flask and
is heated to 30°C. 5 cm3 of 2 mol dm-3 of sulphuric acid is added immediately to the sodium
thiosulphate solution. The conical flask is then placed on a paper with ‘X’ as shown in
Diagram 1.1. The time taken for the mark ‘X’ to disappear from sight is recorded.
Eye
Mark ‘X’
Diagram 1.1
The experiment is repeated with sodium thiosulphate solutions at 40 oC, 50 oC, 55 oC, 60 oC
and 65 oC.
Diagram 1.2 shows the readings of the stopwatch in each experiment.
(a) (i) Record the stopwatch readings in the space provided in Diagram 1.2.
[3 marks]
At 30 oC At 40 oC At 50 oC
At 55 oC At 60 oC At 65 oC
Diagram 1.2
1
(ii) Calculate for each experiment. Construct a table to record and show all the data in
Time
the experiments. These data will be used to plot a graph in 1 (e).
[3 marks]
...................................................................................................................................................
[3 marks]
(c) State three conditions that must be kept constant in this experiment.
1. …………………………………………………………………………………………
2. …………………………………………………………………………………………
3. …………………………………………………………………………………………
[3 marks]
(d) State the operational definition of the rate of reaction based on this experiment.
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[3 marks]
1
(e) Plot a graph of against temperature.
time
[3 marks]
(f) Based on the graph you have drawn, find the time taken for the mark ‘X’ to disappear
from sight if the temperature of the sodium thiosulphate solution is 45 oC.
[3 marks]
(g) If 50 cm3 of 0.05moldm-3 of sodium thiosulphate is used in Experiment I, predict the time
taken for the mark ‘X’ to disappear from sight. Explain your answer.
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[3 marks]
(h) Food becomes stale more quickly when the weather is hot. Explain this observation.
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[3 marks]
(i) In another experiment, the effect of concentration on the rate of reaction is studied. 50
cm3 of 0.08 mol dm-3 sodium thiosulphate solution is prepared from 0.1 mol dm -3 sodium
thiosulphate solution. Calculate the volume of 0.1 mol dm -3 sodium thiosulphate solution
used.
[3 marks]
(j) Describe how you would prepare the sodium thiosulphate solution in (i) accurately.
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[3 marks]
QUESTION 1
(a) Diagram 2(a) shows two sets, Set I and Set II, of the apparatus set-up and the results
for an experiment to study the effects of metals X and Y on the rusting of iron.
Iron nail
Metal X
Diagram 2(a)
Referring to the information above, plan a laboratory experiment to investigate the effect of
named metals X, Y and named electrolyte Z on the rusting of iron.
ANSWER:
Problem statement:
How do/(Do) different type of metals / (metals X and Y) in contact with iron in the
presence of an electrolyte affect rusting of iron ?
Variables:
Hypothesis:
Metal Y causes iron nail rusting while metal X does not.// A more electropositive
metal/(metal X) will prevent iron from rusting while a less electropositive metal (metal Y)
will be rusting iron.
Materials:
Iron nails, magnesium strip, zinc strip, aluminium strip, tin strip ,copper strip, lead strip,
silver strip, agar-agar solution + potassium hexacyanoferrate(III) solution+phenolphthalein
indicator, any suitable electrolyte.
Apparatus:
Procedure:
1. Clean iron nails, magnesium ribbon and copper strip with sand paper.
2. Coil the iron nails with magnesium ribbon and copper strip.
3. Place all the iron nails in separate test tubes.
4. Pour the hot agar containing potassium hexacyanoferrate(III) solution and
phenolphthalein indicator into the test tubes.
5. Keep the test tubes in a test tube rack and leave them aside for 3 days.
6. Record your observations.
Tabulation of data:
QUESTION 2
ANSWER:
Hypothesis:
Variables:
Manipulated : temperature
Responding : rate of reaction
Constant : volume and concentration of acid /
volume and concentration of sodium thiosulphate
Materials:
1 mol dm -3 sulphuric acid, 0.2 mol dm -3 sodium thiosulphate solution, white paper
Apparatus:
Conical flask, measuring cyclinder, stopwatch, Bunsen burner, wire gauze, tripod stand,
thermometer.
Procedure:
Tabulation of data:
Temperature of solution/ 0 C 30 35 40 45 50
Time / s
1/time ( s -1 )
QUESTION 3
2H2O2 2H2O + O2
Answer:
Hypothesis:
Variables:
Materials.
Apparatus:
Procedures:
Tabulation of data:
Question:
[ 17 marks ]