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  • Assignment 01-C On Chemical Kinetics (RC2022)

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    Harshvardhan Singh
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    The document contains 10 questions related to chemical kinetics. The questions cover topics such as rate laws, order of reactions, effect of concentration on rate, and specific rate constants. Rate laws and expressions are given for various reactions and students are asked to determine orders of reactions, relationships between rates, and calculate specific rates based on the information provided.

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    Assignment 01-C on Chemical Kinetics (RC2022)

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    The document contains 10 questions related to chemical kinetics. The questions cover topics such as rate laws, order of reactions, effect of concentration on rate, and specific rate constants. Rate laws and expressions are given for various reactions and students are asked to determine orders of reactions, relationships between rates, and calculate specific rates based on the information provided.

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    44 views2 pages

    Assignment 01-C On Chemical Kinetics (RC2022)

    Uploaded by

    Harshvardhan Singh
    The document contains 10 questions related to chemical kinetics. The questions cover topics such as rate laws, order of reactions, effect of concentration on rate, and specific rate constants. Rate laws and expressions are given for various reactions and students are asked to determine orders of reactions, relationships between rates, and calculate specific rates based on the information provided.

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    © All Rights Reserved
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    15022021 Assignment # 01-C Ranker Batch

    PHYSICAL CHEMISTRY
    (Topic : Chemical Kinetics )
    (for JEE-Mains & Advanced 2022)
    =============================================================================================================

    Q1.  A +  B  Product, dx / dt = k [A] [B] . If conc. of A is doubled, rate becomes four


    times. If conc. of B is made four times, rate is doubled. What is the relation between
    rate of disappearance of A and that of B ?

     d  A    d B    d A   dB 
    (a)  =   (b) –  =4 – 
     dt   dt   dt   dt 

     d  A    d B  
    (c) – 4   = –  (d) None of these
     dt   dt 

    Q2. For the reaction, 2NO (g) + 2H2 (g)  N2 (g) + 2H2O (g) the rate expression can be
    written in the following ways :

     d N2    d H2 O 
      =k 1 [NO][H2 ] ;   =k [NO][H2 ] ;
     dt   dt 

     –dNO  ,  –d H2   ,,
      =k1[NO][H2 ] ;   = k 1 [NO][H2 ] ;
     dt   dt 

    The relationship between k, k1 , k1’ and k1’’ is :

    (a) k = k1= k1’ = k1’’ (b) k = 2k1= k1’ = k1’’

    (c) k = 2k1’ = k1 = k1’’ (d) k = k1= k1’ = 2k1’’

    Q3. For a reaction pA + qB  products, the rate law expression is r = k [A]l [B]m , then :

    (a) (p + q) < (l + m)

    (b) (p + q) > (l + m)

    (c) (p + q) may or may not be equal to (l + m)

    (d) (p + q) = (l + m)
    3
    Q4. For the reaction H2 + Br2  2 HBr overall order is found to be . The rate of reac-
    2
    tion can be expressed as :

    (a) [H2] [Br2]1/2 (b) [H2]1/2 [Br2]

    (c) [H2]3/2 [Br2] 0 (d) all of these


    Nirmal Academy for Science Education (NASE) 117/N/555 Raniganj, Kakadeo, Near Om Chauraha, Kanpur
    Contact Number : 9889655556 , 7458910091 page no # 10
    Q5. If rate constant is numerically the same for three reactions of first, second and third
    order respectively, then which of the following is correct ?

    (a) If [A] = 1 then r1 = r2 = r3 (b) If [A] < 1 then r1 > r2 > r3

    (c) If [A] > 1 then r3 > r2 > r1 (d) All of the above

    Q6. In acidic medium the rate of reaction between (BrO3)– and Br– ions is given by the
    expression.

     d BrO –  
    –  3 
    2
     =K[BrO –3 ][Br – ] H+  . It means :
     dt 

    (a) rate constant of overall reaction is 4 sec–1

    (b) rate constant is independent of the concentration of acid

    (c) the changes in pH of the solution will not affect the rate

    (d) doubling the concentration of H+ ions will increase the reaction rate by 4 times

    Q7. For the reaction A + 2B  C, rate is given by, R = [A] [B]2 then the order of the
    reaction is :

    (a) 3 (b) 6 (c) 5 (d) 2

    d NO2 
    Q8. The rate law for the dimersation of NO2 is : – = k[NO2 ]2
    dt
    Which of the following changes will change the value of specific rate constant, k :

    (a) doubling the total pressure on the system

    (b) doubling the temperature (c) both (a) & (b)

    (d) none of the above

    Q9. For the reaction 3A  products the value of k = 1 × 10–3 L / (mol-min), the value of
    d A 
    – in mol / L-sec when [A] = 2 M is :
    dt
    (a) 6.67 × 10–3 (b) 1.2 × 10–2 (c) 2 × 10–4 (d) 4 × 10–3

    Q10. For the non-equilibrium process, A + B  products, the rate is first order w.r.t. A
    and second-order w.r.t. B If 1.0 mole each of A and B introduced into a 1.0 L vessel
    and the initial rate was 1.0 × 10–2 mol L–1 s–1 , rate when half reactants have been
    turned into products is :

    (a) 1.25 × 10–3 mol L–1 s–1 (b) 1.0 × 10–2 mol L–1 s–1

    (c) 2.50 × 10–3 mol L–1 s–1 (d) 2.0 × 10–2 mol L–1 s–1
    Nirmal Academy for Science Education (NASE) 117/N/555 Raniganj, Kakadeo, Near Om Chauraha, Kanpur
    Contact Number : 9889655556 , 7458910091 page no # 11

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