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Formulae For: Haloalkane & Hal Oarenes
Formulae For: Haloalkane & Hal Oarenes
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Formulae For HALOALKANE & HALOARENES
By Mir Mohammed Abbas II PCMB 'A'
HALOALKANES AND HALOARENES
carbon. So, the C-X bond is polarized with C having a partial positive
2. Preparation of haloalkanes:
3. Preparation of haloarenes:
b. Sandmeyer’s reaction:
c. Gattermann reaction:
d.
HALOALKANES AND HALOARENES 3
b. Density:
than water.
densities go on increasing.
HALOALKANES AND HALOARENES 4
densities go on increasing.
Mechanism:
SNI SNII
First order reaction Second order reaction
Rate =k [RX]
Rate =k [RX] [Nu]
Racemic mixture Inversion of configuration
Order : Order :
CH3X < 1o < 2o < 3o CH3X > 1o > 2o > 3o
dry ether
R X Mg
RMgX
Wurtz reaction:
R-X + 2 Na + X-R → R-R + 2 NaX
HALOALKANES AND HALOARENES 7
Fittig reaction:
Ar-X + 2 Na + X-Ar → Ar-Ar + 2 NaX
dry ether
R X Mg
RMgX
O
ll
RMgX R CR
Tertairy alcohol