Module 1 Chem 2
Module 1 Chem 2
A gas cylinder containing 1.50 mol compressed methane has a volume of 3.30 L. What pressure does the
methane exert on the walls of the cylinder if its temperature is 25°C?
(R = 0.08206 L • atm/K • mol)
0.933 atm
1.11 atm
1.70 atm
✓ 11.1 atm
References
2. Award: 2 out of 2.00 points
What is the volume occupied by 25.2 g of CO2 at 0.840 atm and 25°C?
(R = 0.08206 L • atm/K • mol)
0.060 L
1.34 L
✓ 16.7 L
24.2 L
734 L
References
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3. Award: 2 out of 2.00 points
A fixed quantity of gas, initially at 600ºC, undergoes a temperature change at constant pressure in a cylinder
with a movable piston. What final temperature of the gas can result in the change of state depicted below?
1473ºC
1200ºC
600ºC
300ºC
✓ 163ºC
References
4. Award: 2 out of 2.00 points
0.0176 g/L
0.0250 g/L
0.0561 g/L
✓ 1.78 g/L
181 g/L
References
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5. Award: 2 out of 2.00 points
References
6. Award: 2 out of 2.00 points
What is the density of carbon dioxide gas at –25.2°C and 98.0 kPa? (R = 0.08206 L • atm/K • mol, 1 atm =
101,325 Pa)
0.232 g/L
0.279 g/L
0.994 g/L
1.74 g/L
✓ 2.09 g/L
References
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7. Award: 2 out of 2.00 points
A sample of a gas occupies 1.40 L at 25°C and 760 mmHg. What volume will it occupy at the same
temperature and 380 mmHg?
rev: 08_28_2014_QC_51825
✓ 2.8 L
2.10 L
1.40 L
1.05 L
0.700 L
References
8. Award: 2 out of 2.00 points
Gases are sold in large cylinders for laboratory use. What pressure is exerted by 2.500 kg of oxygen gas (O2)
stored at 22°C in a 40.0-L cylinder?
(R = 0.08206 L • atm/K • mol)
3.55 atm
✓ 47.3 atm
10.2 atm
References
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9. Award: 2 out of 2.00 points
The catalytic decomposition of hydrogen peroxide yields oxygen gas and water. In an experiment, decomposition of
hydrogen peroxide yielded 75.3 mL of gas collected over water at 25°C and 742 torr. What mass of oxygen gas was
collected?
(Pwater = 24 torr at 25°C, R = 0.08206 L • atm/K • mol)
0.00291 g
✓ 0.0931 g
0.0962 g
0.0993 g
0.962 g
References
10. Award: 2 out of 2.00 points
A flask containing neon gas is connected to an open-ended mercury manometer. The open end is exposed
to the atmosphere, where the prevailing pressure is 745 torr. The mercury level in the open arm is 5.0 cm
below that in the arm connected to the flask of neon. What is the neon pressure, in torr?
–50. torr
50. torr
✓ 695 torr
745 torr
795 torr
References
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11. Award: 2 out of 2.00 points
A flask containing neon gas is connected to an open-ended mercury manometer. The open end is exposed
to the atmosphere, where the prevailing pressure is 745 torr. The mercury level in the open arm is 5.0 cm
below that in the arm connected to the flask of neon. What is the neon pressure, in torr?
–50. torr
50. torr
✓ 695 torr
745 torr
795 torr
References
12. Award: 2 out of 2.00 points
1.000 atm of oxygen gas, placed in a container having a pinhole opening in its side, leaks from the container
2.14 times faster than does 1.000 atm of an unknown gas placed in this same apparatus. Which of the
following species could be the unknown gas?
Cl2
✓ SF6
Kr
UF6
Xe
References
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13. Award: 2 out of 2.00 points
References
14. Award: 2 out of 2.00 points
A block of dry ice (solid CO2, density = 1.56 g/mL) of dimensions 25.0 cm × 25.0 cm × 25.0 cm is left to sublime (i.e., to pass
from the solid phase to the gas phase) in a closed chamber of dimensions 4.00 m × 5.00 m × 3.00 m. Once the sublimation
is complete, what is the partial pressure of carbon dioxide in the chamber at 25°C?
(R = 0.08206 L • atm/K • mol, 1 atm = 760 mmHg)
✓ 172 mmHg
107 mmHg
0.225 mmHg
0.172 mmHg
14.4 mmHg
References
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15. Award: 2 out of 2.00 points
volume/density
temperature × area
moles/volume
✓ force/area
volume × force
References
16. Award: 2 out of 2.00 points
A sample of carbon dioxide gas at 125°C and 248 torr occupies a volume of 275 L. What will the gas pressure
be if the volume is increased to 321 L at 125°C?
✓ 212 torr
289 torr
356 torr
441 torr
359 torr
References
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17. Award: 2 out of 2.00 points
A pressure that will support a column of Hg to a height of 256 mm would support a column of water to what
height? The density of mercury is 13.6 g/cm3; the density of water is 1.00 g/cm3.
✓ 348 cm
1.00 × 102 ft
18.8 mm
33.8 ft
76.0 cm
References
18. Award: 2 out of 2.00 points
True
✓ False
References
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19. Award: 2 out of 2.00 points
What is the pressure in atmospheres exerted by a column of mercury that is 100. m high?
(density of mercury = 13.5951 g/cm3, gravitational constant = 9.80665 m/s2, 1 atm = 101,325 Pa = 760 torr =
760 mmHg)
0.013 atm
0.73 atm
1.37 atm
✓ 132 atm
References
20. Award: 2 out of 2.00 points
The average kinetic energies of molecules from samples of different "ideal" gases are the same at the
same temperature.
✓ All molecules of an ideal gas have the same kinetic energy at constant temperature.
Molecules of a gas undergo many collisions with each other and the container walls.
Molecules of greater mass have a lower average speed than those of less mass at the same
temperature.
References
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21. Award: 2 out of 2.00 points
If 2.3 mol of a gas occupies 50.5 mL, how many moles of the gas will occupy 85.5 mL at the same
temperature and pressure?
1.4 mol
0.59 mol
✓ 3.9 mol
0.26 mol
2.3 mol
References
22. Award: 2 out of 2.00 points
When active metals such as magnesium are immersed in acid solution, hydrogen gas is evolved. Calculate
the volume of H2(g) at 30.1°C and 0.85 atm that can be formed when 275 mL of 0.725 M HCl solution reacts
with excess Mg to give hydrogen gas and aqueous magnesium chloride.
Mg(s) + 2HCl(aq) → MgCl2(aq) + H2(g)
(R = 0.08206 L • atm/K • mol)
3.4 × 10–3 L
2.2 L
✓ 2.9 L
5.8 L
11.7 L
References
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23. Award: 2 out of 2.00 points
The temperature of the carbon dioxide atmosphere near the surface of Venus is 475°C. Calculate the
average kinetic energy per mole of carbon dioxide molecules on Venus.
2520 J/mol
4150 J/mol
5920 J/mol
✓ 9330 J/mol
5920 kJ/mol
References
24. Award: 2 out of 2.00 points
In the van der Waals equation, the constant a is a constant that is part of a correction factor for _________.
References
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25. Award: 2 out of 2.00 points
A gaseous compound is 30.4% nitrogen and 69.6% oxygen by mass. A 5.25-g sample of the gas occupies a
volume of 1.00 L and exerts a pressure of 1.26 atm at –4.0°C. What is its molecular formula?
(R = 0.08206 L • atm/K • mol)
NO
NO2
N3O6
✓ N2O4
N2O5
References
26. Award: 2 out of 2.00 points
What is the freezing point of an aqueous solution of NaCl that boils at 102.5°C?
(For water, Kf = 1.86°C/m; Kb = 0.52°C/m)
2.5°C
–2.5°C
–0.70°C
0.70°C
✓ –8.9°C
References
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27. Award: 2 out of 2.00 points
What is the name given to a solution that contains more solute than it has the capacity to dissolve?
Unsaturated
Saturated
Soluted
✓ Supersaturated
Oversaturated
References
28. Award: 2 out of 2.00 points
Potassium fluoride is used for frosting glass. Calculate the molarity of a solution prepared by dissolving 78.6
g of KF in enough water to produce 225 mL of solution.
0.304 M
0.349 M
1.35 M
3.29 M
✓ 6.01 M
References
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29. Award: 2 out of 2.00 points
What is the percent CdSO4 by mass in a 1.00 molal aqueous CdSO4 solution?
0.001%
0.10%
✓ 17.2%
20.8%
24.4%
References
30. Award: 2 out of 2.00 points
References
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31. Award: 2 out of 2.00 points
Which of the following aqueous solutions should demonstrate the most ideal behavior?
0.1 M K2SO4
0.1 M CaCl2
3.0 M LiF
0.1 M MgSO4
✓ 0.1 M NaCl
References
32. Award: 2 out of 2.00 points
✓ the entropy of the solution must be greater than that of its pure components.
References
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33. Award: 2 out of 2.00 points
What is the value for the van't Hoff factor for all nonelectrolytes?
–1
0
✓ 1
½
–½
References
34. Award: 2 out of 2.00 points
Human blood has a molar concentration of solutes of 0.30 M. What is the osmotic pressure of blood at 25°C?
(R = 0.08206 L • atm/K • mol)
0.012 atm
0.62 atm
6.8 atm
✓ 7.3 atm
11 atm
References
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35. Award: 2 out of 2.00 points
What is the vapor pressure above a solution prepared by dissolving 0.500 mol of a nonvolatile solute in 275
g of hexane (86.18 g/mol) at 49.6°C? P°hexane = 400.0 torr at 49.6°C.
54 torr
154 torr
246 torr
✓ 346 torr
400. torr
References
36. Award: 2 out of 2.00 points
When 12.1 g of the sugar sucrose (a nonelectrolyte) are dissolved in exactly 800 g of water, the solution has a
freezing point of –0.082°C. What is the molar mass of sucrose?
(Kf of water is 1.86°C/m.)
426 g/mol
99.2 g/mol
178 g/mol
266 g/mol
✓ 343 g/mol
References
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37. Award: 2 out of 2.00 points
Below is a diagram representing a solvent A(l) in a 1-L beaker, and a solute X dissolved in the solvent. Solvent
A has a density of 0.8 g/mL, and a molar mass of 40 g/mol. Solute X has a molar mass of 30 g/mol. Each
circle of X represents 1 mol of X. Assume that the solute addition does not significantly change the volume of
liquid in the beaker.
2m
4m
✓ 5m
0.004 m
0.005 m
References
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38. Award: 2 out of 2.00 points
What volume of water (d = 1.00 g/mL) should be added to 600. mL of ethanol in order to have a solution that
boils at 95.0°C?
(For ethanol, Kb = 1.22 °C/m; density = 0.789 g/cm3; boiling point = 78.4°C)
186 mL
245 mL
518 mL
✓ 116 mL
322 mL
References
39. Award: 2 out of 2.00 points
From the following list of aqueous solutions and water, select the one with the highest boiling point.
1.0 M KNO3
0.75 M NaCl
✓ 0.75 M CuCl2
pure water
References
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40. Award: 2 out of 2.00 points
Aqueous ammonia is commercially available in a solution that is 28% (w/w) ammonia. What is the mole fraction of
ammonia in such a solution?
0.017
0.023
0.012
0.24
✓ 0.29
References
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41. Award: 2 out of 2.00 points
Below is a diagram representing a solvent A(l) in a 1-L beaker, and a solute X dissolved in the solvent. Solvent
A has a density of 0.8 g/mL, and a molar mass of 40 g/mol. Solute X has a molar mass of 30 g/mol. Each
circle of X represents 1 mol of X. Assume that the solute addition does not significantly change the volume of
liquid in the beaker.
0.4%
3%
12%
✓ 13%
20%
References
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42. Award: 2 out of 2.00 points
What is the name for a solute that does not exert a vapor pressure when it is dissolved in a liquid?
Colloid
Amorphous solid
✓ Nonvolatile
Crystalline solid
Electrolyte
References
43. Award: 2 out of 2.00 points
What is the molarity of a solution prepared by diluting 1.85 L of 6.5 M KOH to 11.0 L?
0.28 M
0.91 M
✓ 1.1 M
3.1 M
3.9 M
References
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44. Award: 2 out of 2.00 points
What is the name given to a solution that contains the maximum amount of solute that will dissolve in a
solvent at a specific temperature?
✓ Saturated
Unsaturated
Solvent
Solute
Supersaturated
References
45. Award: 2 out of 2.00 points
References
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46. Award: 2 out of 2.00 points
HCl
C6H12O6 (glucose)
O2
NaCl
References
47. Award: 2 out of 2.00 points
The solubility of the oxidizing agent potassium permanganate is 7.1 g per 100.0 g of water at 25°C. What is the
mole fraction of potassium permanganate (KMnO4) in this solution?
✓ 0.0080
0.0086
0.066
0.071
0.48
References
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48. Award: 2 out of 2.00 points
Solutions A and B have the same vapor pressure and it is higher than the vapor pressure of solution C.
Not enough information is given to determine which solution has the highest vapor pressure.
References
49. Award: 2 out of 2.00 points
What is the freezing point of a solution prepared from 50.0 g ethylene glycol (C2H6O2) and 85.0 g H2O?
(For water, Kf = 1.86°C/m)
17.6°C
–176°C
–1.50°C
1.50°C
✓ –17.6°C
References
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50. Award: 2 out of 2.00 points
salute
gas
✓ solvent
solid
solute
References
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