SAFETY DATA SHEET (according to 1907/2006/EC, Article 31)

DIFFU - THERM  Developer BEA (Aerosol)

1. Identification of the substance/mixture and of the company/undertaking:
Product identifier
Trade name: Developer
Article number: BEA
Relevant identified uses of the substance or mixture and uses advised against
Application of the substance / the preparation
As Developer at the penetration process by colours acc. to EN ISO 3452-1
[EN 571-1] (DIN 54 152 part 1) for finding surface cracks.
Details of the supplier of the safety data sheet
Manufacturer/Supplier
Helmut Klumpf
Technische Chemie KG
Industriestr. 15
D - 45699 Herten Phone.: +49(0)2366 1003 - 0 Fax: +49(0)2366 1003 - 11 Email: [email protected]
Emergency telephone number: a.m. or next Emergency phone:

2. Hazards identification
Classification of the substance or mixture
Flammable Aerosol, Category 1
Labelling according to Regulation (EC) No 1272/2008
The substance is classified an labelled according to the CLP regulation.
Hazard pictograms GHS02, GHS07
Signal word Danger
Hazard statements
H222 Extremely flammable aerosol.
H229 Pressurised container: May burst if heated.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or burn, even after use.
P271 Use only outdoors or in a well-ventilated area.
P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122°F.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Labelling according to EEC-Regulation:
The product has been classified and labelled in accordance with EC Directives / Ordinance on Hazardous
Materials (GefStoffV).
Code letter and hazard designation for product:
Xi Irritant
F+ Extremely flammable
Risk phrases:
R36 Irritating to eyes
R12 Extremely flammable
R67 Vapours may cause drowsiness and dizziness.
Safety phrases:
16 Keep away from sources of ignition - No smoking.
23 Do not breathe vapour/spray.
25/24 Avoid contact with skin and eyes.
33 Take precautionary measures against static discharges.
Special labelling:
Container is under pressure. Protect from sun and temperatures above 50°C. Do not open with force or
incinerate even after use. Do not spray into flames or onto glowing objects.
Keep away from sources of ignition - No smoking. Keep out of reach of children.
Use only in well ventilated areas.

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SAFETY DATA SHEET (according to 1907/2006/EC, Article 31)
DIFFU - THERM  Developer BEA (Aerosol)
Results of PBT and PvB assessment
PBT: Not applicable
vPvB: Not applicable

3. Composition/information on ingredients
Chemical characterization: Aerosol with mixture of substances listed below and non hazardous additions.
Components: Name of chemical weight %
CAS: 67-63-0 propan-2-ol
25-60
EINECS: 200-661-7 Xi R 36, R67; F R11
GHS02 Flam. Liq.2, H225; GHS07 Eye Irrit. 2, H319; STOT SE. 3, H336
CAS: 106-97-8 n-butane
10-30
EINECS: 203-448-7 F+ R12
GHS02 Flam. Gas 1, H220; GHS04
CAS: 74-98-6 propane
10-30
EINECS: 200-827-9 F+ R12
GHS02 Flam. Gas 1, H220; GHS04
4. First aid measures
Description of first aid measures
General information
Instantly remove any clothing soiled by the product.
If you feel uncomfortable consult a doctor and show the label if possible.
Personal protection for the First Aider.
After inhalation
Take affected persons into the open air and position comfortably
Remove the person from the danger zone under proper respiratory protection . If breathing is irregular or
stopped, give artificial respiration. Comfortable for the patients and provide medical help.
Seek medical treatment in case of complaints.
After skin contact
Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing
before reuse.
After eye contact
Rinse opened eye for at least 15 minutes under running water. Get medical attention if irritation occurs.
After swallowing
In case of persistent symptoms consult doctor.
Do not induce vomiting - aspiration!
Do not vomit. Swallow activated carbon and sodium sulphate.
Information for doctor
Most important symptoms and effects, both acute and delayed
Headache, Dizziness, Sickness
Tiredness and other effects on the CNS.
Signs and symptoms of eye irritation may include:
Burning sensation, redness, swelling and / or blurred vision. Dry skin.
Indication of any immediate medical attention and special treatment needed
Causes depression of the central nervous system. Potential of a chemical pneumonia. Information from a
doctor or poison control center to obtain.
If ingested, material may be aspirated into the lungs and cause chemical pneumonia. Treat appropriately.

5. Fire fighting measures

Description of first aid measures
Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam.
foam, water haze, water spray-jet.
For safety reasons unsuitable extinguishing agents Water with a full water jet.
Special hazards arising from the substance or mixture
Hazardous Combustion Products: Smoke, Fume, Incomplete combustion products, Oxides of carbon.
Can be released in case of fire: Carbon dioxide (CO2), Carbon monoxide (CO)
Advice for fighters
Protective equipment: Wear self-contained breathing apparatus.
Additional information:
Cool containers at risk with water spray jet.
Danger for bursting of aerosols when heated for more than 50°C.
Aerosols that burst in fire can be mightily shot away.

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SAFETY DATA SHEET (according to 1907/2006/EC, Article 31)
DIFFU - THERM  Developer BEA (Aerosol)
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources
Bring persons out of danger.
Environmental precautions:
Do not allow product to reach sewage system or water bodies.
Prevent material from reaching sewage system, holes and cellars.
Inform respective authorities in case product reaches water or sewage system.
Dilute with much water. Prevent from spreading (e.g. by damming-in or oil barriers).
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
Reference to other sections
See Section 8 for information on personal protection equipment.

7. Handling and storage

Handling:
Advice on safe handling:
Provide good room ventilation even at ground level (vapours are heavier than air).
Advice on protection against fire and explosion:
Keep away from sources of ignition.
Do not smoke.
Take precautionary measures against static discharges.
Storage:
Requirements for storage rooms and vessels:
Filled aerosols must not be exposed to:
1. Heating of more than 50°C by sun beams or other heat sources.
2. Storage in gates, passages, wells of staircases, buildings, floors, and lofts.
Keep container in a well-ventilated place.
Advice on storage compatibility:
Do not store together with oxidizing agents.
Further information on storage conditions:
Keep container in a well-ventilated place.
Classification acc. to prescription:
Aerosols (Aerosol containers) (TRG 300)
Ordinance on Industrial Safety and Health
TRGS 510.
Storage class: 2B

8. Exposure controls/personal protection

Additional information about design for technical systems:
No other information’s, see point 7.
Control parameters
Components with critical values that require monitoring at the workplace:
Not required.
Components with critical values that require monitoring at the workplace:
67-63-0 propan-2-ol (25 - 60%)
WEL Short-term value: 1250 mg/m³, 500 ppm
Long-term value: 999 mg/m³, 400 ppm
106-97-8 butane (10 – 30%)
WEL 2400 mg/m , 1000 ml/m3; 4(II); DFG
3

74-98-6 propane (10 – 30%)

WEL 1800 mg/m3, 1000 ml/m3; 4(II); DFG
Exposure controls
Personal protection equipment

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SAFETY DATA SHEET (according to 1907/2006/EC, Article 31)
DIFFU - THERM  Developer BEA (Aerosol)
General protective and hygienic measures
Keep away from foodstuffs, beverages and food.
Instantly remove any soiled and impregnated garments.
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer
exposure use breathing apparatus that is independent of circulating air.
Use breathing protection in case of insufficient ventilation.
If user operations generate dust, fume or mist, use local exhaust ventilation to keep exposure to dust below the
exposure limits.
Protection of hands: Protective gloves.
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and
has to be observed.
Eye protection:
A chemical goggles is recommended.
Tightly sealed safety glasses.
Gauze goggles
Body protection: Protective work clothing.

9. Physical and chemical properties

General Information
Form: Aerosol Colour: white Smell: alcoholic
Data relevant for safety: (Product without power gas)
Boiling temperature: 82 °C (DIN 53 171)
Flash point: 12 °C (DIN 51 758)
Ignition temperature: > 350 °C (DIN 51 794)
Explosive properties: The Product is not explosive, but
may form flammable/explosive vapour-air mixture.
Explosion limits Lower e.l.: 2 Vol.%
Upper e.l.: 12 Vol.%
Vapour pressure (20°C): 48 mbar
Density (20°C): 0,862 g/cm³ (DIN 51 757)
Solubility in water (20°C): 1,000 g/l (Solvent)

10. Stability and reactivity

Reactivity
Chemical stability
The material is stable under normal conditions.
Under normal storage conditions peroxides can accumulate which may explode in heat or shock. Distillation
or evaporation increase the formation of peroxides and thus also the risk of explosion.
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Possibility of hazardous reactions
Reacts with strong oxidizing agents.
Hazardous polymerization will not occur.
Conditions to avoid
Avoid shock, friction, heat, sparks, open flame and other ignition sources. Prevent electrostatic charging.
Incompatible materials:
Reacts with strong oxidizing agents.
Reacts with strong acids.
Hazardous decomposition products:
Thermal decomposition is highly dependent on conditions. A complex mixture of airborne solids, liquids and
gases, including carbon monoxide, carbon dioxide and other organic compounds will be evolved when this
material undergoes combustion or thermal or oxidative degradation.
This product does not decompose at ambient temperatures.

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SAFETY DATA SHEET (according to 1907/2006/EC, Article 31)
DIFFU - THERM  Developer BEA (Aerosol)
11. Toxicological information
Information on toxicological effects
Acute Toxicity: (LD/LC50-values that are relevant for classification):
Component Method Value
67-63-0 propan-2-ol Oral LD 50 4.570 mg/kg (rat)
Dermal LD 50 13.400 mg/kg (rabbit)
Inhalative LC50/6h 30 mg/l (rat) (6h/ LC50 > 25.000 mg/m³
Primary irritant effect:
on the skin:
Possible due to defatting action on prolonged contact may damage the skin.
weak irritant effect
Data available. Test results or other study results do not meet the criteria for classification.
on the eye: Irritant effect.
Irritation of the respiratory system
slightly irritating
Test results or other study results do not meet the criteria for classification.
Sensitization: No sensitizing effect known.
Additional toxicological information:
Increased concentrations of vapor may cause irritation of the eyes and respiratory tract. Headache, dizziness
and disorders of the central nervous system can also be caused.
Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.
Taking or vomiting can cause small amounts of liquid aspirated into the lungs, chemical pneumonitis or
pulmonary edema.

12. Ecological information

Toxicity
Aquatic toxicity:
Material - Not expected to be harmful to aquatic organisms.
67-63-0 propan-2-ol
LC 50 >100 mg/l (alg)
>100 mg/l (Daphnia)
>100 mg/l (fi2) (96h/)
>100 mg/l (kru) (48h/)
Persistence and degradability
This substance is rapidly degraded in the air.
Easily biodegradable
Other information: The product is easily biodegradable.

13. Disposal considerations

Product:
Recommendations:
Hand over to authorized disposal agency.
Waste code No.:
EAV: 14 06 03 term: Mixture of solvent
Contaminated packaging:
Recommendations:
Container must be completely emptied and must not be opened by force.
Hand over to authorized disposal agency.
Waste code No.:
EAV: 15 01 10 term: Iron-metal containers with a contaminated rest of the contents
Waste treatment methods
Recommendations
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Disposal must be made according the local authority regulations.

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SAFETY DATA SHEET (according to 1907/2006/EC, Article 31)
DIFFU - THERM  Developer BEA (Aerosol)
14. Transport information
Land transport
UN-Nr.: 1950 Identification: DRUCKGASPACKUNGEN flammable
Class: 2 Package Group: -- Tunnel restriction code: D
Classifications code: 5 F shipment category: 2
Labelling of the Package: UN 1950 AEROSOLE Label-no.: 2.1
Packing instruction: P 003, MP 9 Limited Quantities Only: 1L (Package ≤ 30 kg)
Marine transport IMDG/GGVSee
UN-No.: 1950 Class: 2.1 Package Group: --
EMS-No.: F-D, S-U Label-no.: -- Marine Pollutant: -- Label: --
Proper Shipping Name: Aerosols (Limited Quantities Only) (Package ≤ 30 kg)
Air transport ICAO-TI and IATA-DGR
Class/Division: 2.1 UN/ID-Nr.: 1950
Package Group: --, Label: 2.1
Packing inst. Passenger aircraft: 203/Y203 Max. netto/Package: 75 kg/30 kg
Packing inst. Cargo aircraft: 203 Max. netto/Package: 150 kg
Proper Shipping Name: Aerosols, flammable

15. Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture
Labelling according to Regulation (EC) No 1272/2008
The substance is classified an labelled according to the CLP regulation.
National regulations
Water hazard class: Water hazard class 1 (Assessment by list): slightly hazardous for water.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16. Other information

These date are based on our present knowledge. However, they shall not constitute a guarantee for any specific
product features and shall not establish a legally contractual relationship. (TRGS 555)
Relevant phrases
H220 Extremely flammable gas.
H222 Extremely flammable aerosol.
H225 Highly flammable liquid and vapour.
H229 Pressurised container: May burst if heated.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
R36 Irritating to eyes
R11 Highly flammable liquid
R12 Extremely flammable
R67 Vapours may cause drowsiness and dizziness.
Department issuing data specification sheet:
Contact: Helmut. Klumpf Technische Chemie KG
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
GefStoffV: Gefahrstoffverordnung (Ordinance on Hazardous Substances, Germany)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent

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