SAFETY DATA SHEET


(according to 1907/2006/EC, Article 31)
DIFFU - THERM Magnetic-Particle-Suspension MPS - F (Aerosol)
Identification of the substance/mixture and of the company/undertaking:
Product identifier
Trade name: Magnet-Particle-Suspension fluorescence (oil based)
Article number: MPS - F
Relevant identified uses of the substance or mixture and uses advised against
Application of the substance / the preparation
As Magnetic-Particle-Suspension at the Magnetic particle inspection
by acc. to EN ISO 9934-1 (DIN 54 132) for finding surface cracks.
Details of the supplier of the safety data sheet
Manufacturer/Supplier
Helmut Klumpf
Technische Chemie KG
Industriestr. 15
D - 45699 Herten Phone.: +49(0)2366 1003 - 0 Fax: +49(0)2366 1003 - 11 Email: [email protected]
Emergency telephone number: a.m. or next Emergency phone:

2. Hazards identification
Classification of the substance or mixture
Flammable Aerosol, Category 1
Labelling according to Regulation (EC) No 1272/2008
The substance is classified an labelled according to the CLP regulation.
Hazard pictograms GHS02
Signal word Danger
Hazard statements
H222 Extremely flammable aerosol.
H229 Pressurised container: May burst if heated.
EUH066 Repeated exposure may cause skin dryness or cracking.
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or burn, even after use.
P271 Use only outdoors or in a well-ventilated area.
P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122°F.
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Labelling according to EEC-Regulation:
The product has been classified and labelled in accordance with EC Directives / Ordinance on Hazardous Materials
(GefStoffV).
Code letter and hazard designation for product:
F Extremely flammable.
Xn Harmful
Risk phrases:
12 Extremely flammable.
65 Harmful; can cause lung disease.
66 Repeated exposure may cause skin dryness or cracking.
Safety - phrases:
16 Keep away from sources of ignition - No smoking.
23 Do not breathe vapour/spray.
24 Avoid contact with skin.
33 Take precautionary measures against static discharges.
62 If swallowed, do not induce vomiting: seek medical advice immediately
and show this container or label.
Special labelling:
Container is under pressure. Protect from sun and temperatures above 50°C. Do not open with force or incinerate
even after use. Do not spray into flames or onto glowing objects.
Keep away from sources of ignition - No smoking. Keep out of reach of children.
Use only in well ventilated areas.

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SAFETY DATA SHEET

(according to 1907/2006/EC, Article 31)
DIFFU - THERM Magnetic-Particle-Suspension MPS - F (Aerosol)
3. Composition/information on ingredients
Chemical characterization: Substances
Identification number(s):
Chemical characterization: Aerosol
Inhaltsstoffe: Name of chemical weight %
CAS: 90622-58-5 aliphatic hydrocarbons, C11-C13, Isoalkane, <2% Aromaten
30-80
EINECS: 920-901-0 Xn; R 65, R66;
GHS08 Asp. Tox .1, EUH066, H304
CAS: 106-97-8 N-Butan
5-20
EINECS: 203-448-7 F+ R12
GHS02 Flam. Gas 1, H220; GHS04
CAS: 74-98-6 Propan
5-20
EINECS: 200-827-9 F+ R12
GHS02 Flam. Gas 1, H220; GHS04

4. First aid measures

Description of first aid measures
General information
Take affected persons out of danger area and instruct to lie down.
Personal protection for the First Aider.
Instantly remove any clothing soiled by the product.
After inhalation
Remove the person from the danger zone under proper respiratory protection . If breathing is irregular or
stopped, give artificial respiration. Comfortable for the patients and provide medical help.
Seek medical treatment in case of complaints.
After skin contact
Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing
before reuse.
After eye contact
Rinse opened eye for at least 15 minutes under running water. Get medical attention if irritation occurs.
After swallowing In case of persistent symptoms consult doctor.
Information for doctor
Most important symptoms and effects, both acute and delayed No further relevant information available.
Indication of any immediate medical attention and special treatment needed
If ingested, material may be aspirated into the lungs and cause chemical pneumonia. Treat appropriately.

5. Fire fighting measures

Suitable extinguishing material:
ABC powder, alcohol-resistant foam, carbon dioxide.
Extinguishing material that must not be used for safety reasons:
Full water jet.
Special exposure hazards extinguishing from the substance or
preparation itself, combustible products or resulting gases:
None
Special protective equipment for fire fighters:
None
Additional information’s:
Cool containers at risk with water spray jet.
Danger for bursting of aerosols when heated for more than 50°C.
Aerosols that burst in fire can be mightily shot away.

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
Avoid contact with eyes and skin.
All persons whose presence is not necessary, remove from exposure.
Close leaks, if possible without personal risk to take.
In case of formation of gases / vapors / aerosols are breathing.
Do not breathe Gas / fumes / vapor / spray.

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SAFETY DATA SHEET

(according to 1907/2006/EC, Article 31)
DIFFU - THERM Magnetic-Particle-Suspension MPS - F (Aerosol)
Environmental precautions:
Do not allow to enter drainage system, surface or ground water.
Prevent from spreading (e.g. by damming-in or oil barriers).
Do not allow to enter the ground/soil.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.
Send for recovery or disposal in suitable containers.
Larger amounts should be pumped into containers.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for information on disposal.

7. Handling and storage

Handling:
Advice on safe handling:
Provide good room ventilation even at ground level (vapours are heavier than air).
Advice on protection against fire and explosion:
Keep away from sources of ignition.
Do not smoke.
Take precautionary measures against static discharges.
Storage:
Requirements for storage rooms and vessels:
Filled aerosols must not be exposed to:
1. Heating of more than 50°C by sun beams or other heat sources.
2. Storage in gates, passages, wells of staircases, buildings, floors, and lofts.
Keep container in a well-ventilated place.
Advice on storage compatibility:
Do not store together with oxidizing agents.
Further information on storage conditions:
Keep container in a well-ventilated place.
Classification acc. to prescription:
Aerosols (Aerosol containers) (TRG 300)
Ordinance on Industrial Safety and Health
TRGS 510.
Storage class: 2B

8. Exposure controls/personal protection

Additional advice on system design:
No other information’s, see point 7.
Components with critical values that require monitoring at the workplace:
CAS - NR. Name of chemical % Code Value Unit peak limited category
106-97-8 butane 10 - 20 MAK 1000 (2350) ml/m³ (mg/m³)
74-98-6 propane 10 - 20 MAK 1000 (1800) ml/m³ (mg/m³)
Personal protective equipment
General protective and hygienic measures
Do not eat, drink or smoke while working.
The usual precautionary measures should be adhered to in handling the chemicals.
Keep away from foodstuffs, beverages and food.
Wash hands during breaks and at the end of the work.
Do not inhale gases / fumes / aerosols.
Breathing equipment:
In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer
exposure use breathing apparatus that is independent of circulating air.
Use breathing protection in case of insufficient ventilation.

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SAFETY DATA SHEET

(according to 1907/2006/EC, Article 31)
DIFFU - THERM Magnetic-Particle-Suspension MPS - F (Aerosol)
Protection of hands:
suitable protective gloves.
The glove material has to be impermeable and resistant to the product.
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
Eye protection:
Safety glasses
Tightly sealed safety glasses.
Body protection: Protective work clothing.

9. Physical and chemical properties

General Information
Form: Aerosol Colour: Colourless/brown Smell: Weak, characteristic
Data relevant for safety: (Product without power gas)
Boiling range: 170 -250 °C (DIN 53 171)
Flash point: > 61 °C (DIN 51 758)
Ignition temperature: > 200 °C (DIN 51 794)
Explosive properties: The Product is not explosive, but
may form flammable/explosive vapour-air mixture.
Explosion limits Lower e.l.: 0,6 Vol.%
Upper e.l.: 7 Vol.%
Vapour pressure (20°C): 0,4 hPa
Density (20°C): 0,7-0,85 g/cm³ (DIN 51 757)
Solubility in water (20°C): Not determined.
Viscosity (25°C): 1,3-2,5 mm²/s

10. Stability and reactivity

Reactivity
Chemical stability The material is stable under normal conditions.
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Possibility of hazardous reactions Hazardous polymerization will not occur.
Conditions to avoid
Avoid shock, friction, heat, sparks, open flame and other ignition sources. Prevent electrostatic charging.
Incompatible materials: Reacts with strong oxidizing agents.
Hazardous decomposition products: This product does not decompose at ambient temperatures.

11. Toxicological information

The classification of risk is based on knowledge of the toxicity of the components contained in this product.
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
Oral LD50 >5.000 mg/kg (rad)
Dermal LD50 >5,000 mg/kg (rab)
Inhalative LC50 >5.000 mg/l (rat)
Primary irritant effect:
on the skin:
Irritation possible
Data available. Test results or other study results do not meet the criteria for classification.
on the eye:
weak irritant effect
Data available. Test results or other study results do not meet the criteria for classification.
Irritation of the respiratory system
Can be fatal if swallowed and enters into the airways. Based on physico-chemical properties of the material.
Sensitization: No sensitizing effect known.

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SAFETY DATA SHEET

(according to 1907/2006/EC, Article 31)
DIFFU - THERM Magnetic-Particle-Suspension MPS - F (Aerosol)
12. Ecological information
Toxicity
Aquatic toxicity:
Material - Not expected to be harmful to aquatic organisms.
Material - Expected to aquatic organisms probably show no chronic toxicity.
Persistence and degradability The product is not easily, but potentially (inherently) degradable.
Other information: This substance is highly volatile and evaporates quickly into the air when it is released.
Behaviour in environmental systems:
Bioaccumulative potential No further relevant information available.
Mobility in soil Probably will not take place on the distribution of sediment and wastewater solids.
Additional ecological information:
General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage
system.
Results of PBT and vPvB assessment
The product is neither a PBT or vPvB substance, nor still contains PBT or vPvB substances.
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects No further relevant information available.

13. Disposal considerations

Waste treatment methods
Recommendation
The product is suitable for burning in an enclosed, controlled burner suitable for fuel value or disposal by
supervised incineration at very high temperatures at which it does not come to the formation of undesired
inflammatory products.
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Disposal must be made according the local authority regulations.
European waste catalogue -
Uncleaned packagings:
Recommendation:
Empty contaminated packagings thoroughly. They can be recycled after thorough and proper cleaning.
Packagings that cannot be cleaned are to be disposed of in the same manner as the product.
SECTION 14:
14. Transport information
Land transport
UN-Nr.: 1950 Identification: DRUCKGASPACKUNGEN flammable
Class: 2 Package Group: -- Tunnel restriction code: D
Classifications code: 5 F shipment category: 2
Labelling of the Package: UN 1950 AEROSOLE Label-no.: 2.1
Packing instruction: P 003, MP 9 Limited Quantities Only: 1L (Package ≤ 30 kg)
Marine transport IMDG/GGVSee
UN-No.: 1950 Class: 2.1 Package Group: --
EMS-No.: F-D, S-U Label-no.: -- Marine Pollutant: -- Label: --
Proper Shipping Name: Aerosols (Limited Quantities Only) (Package ≤ 30 kg)
Air transport ICAO-TI and IATA-DGR
Class/Division: 2.1 UN/ID-Nr.: 1950
Package Group: --, Label: 2.1
Packing inst. Passenger aircraft: 203/Y203 Max. netto/Package: 75 kg/30 kg
Packing inst. Cargo aircraft: 203 Max. netto/Package: 150 kg
Proper Shipping Name: Aerosols, flammable

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SAFETY DATA SHEET

(according to 1907/2006/EC, Article 31)
DIFFU - THERM Magnetic-Particle-Suspension MPS - F (Aerosol)
15. Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labelled according to the CLP regulation.
Hazard pictograms GHS02
Signal word Danger
Hazard statements
H222 Extremely flammable aerosol.
H229 Pressurised container: May burst if heated.
EUH066 Repeated exposure may cause skin dryness or cracking.
Risk phrases:
12 Extremely flammable.
65 Harmful; can cause lung disease.
66 Repeated exposure may cause skin dryness or cracking.
National regulations
Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
Chemical safety assessment: A Chemical Safety Assessment has been carried out.

16. Other information

These data are based on our present knowledge. However, they shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Department issuing data specification sheet:
Contact: Helmut. Klumpf Technische Chemie KG
Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative

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