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JA DPP No.A1 To A10 For Online
JA DPP No.A1 To A10 For Online
O/I-CHEMISTRY
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DPPs BOOKLET-1 VIKAAS (JA) | CHEMISTRY
8. How many and bond are present in CH2=CH–CH2–CCH
CH2=CH–CH2–CCH esa fdrus rFkk cU/k mifLFkr gSa \
(A*) 10 , 3 (B) 8 , 3 (C) 3 , 10 (D) 12 , 3
9. How many and -bonds are there in tetracynoethylene (CN) 2C=C(CN)2 molecule.
VsVªk lk;uks,Fkhyhu (CN2)C=C(CN)2 v.kq esa fdrus rFkk -cU/k gSA
(A*) 9 , 9 (B) 9 , 7 (C) 5 , 9 (D) 5 , 7
10. Which of the following alkanes contain primary, secondary, tertiary and quaternary carbon atoms
together?
fuEu esa ls fdl ,Ydsu esa izkFkfed] f}fr;d r`rh;d vkSj prq"d dkcZu ijek.kq mifLFkr gS \
(A) (CH3)3CH (B) (C2H5)3CH
(C*) (CH3)3CCH2CH(CH3)2 (D) (CH3)4C
11. Ketene CH2=C=O has
(A) Only sp2 carbon atom (B) Only sp carbon atom
(C*) sp2 and sp carbon atoms (D) sp3, sp2 and sp carbon atoms
dhVhu CH2=C=O esa gS %
(A) dsoy sp2 dkcZu ijek.kq (B) dsoy sp dkcZu ijek.kq
(C*) sp2 rFkk sp dkcZu ijek.kq (D) sp3, sp2 rFkk sp dkcZu ijek.kqa
12. Number of primary hydrogen is the given compound are
fn;s x;s ;kSfxd esa izkFkfed H dh la[;k gSA
14.
Ans. 2
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DPPs BOOKLET-1 VIKAAS (JA) | CHEMISTRY
O/I-CHEMISTRY
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DPPs BOOKLET-1 VIKAAS (JA) | CHEMISTRY
6. Which of the following is/are alicyclic hydrocarbon
fuEu esa ls dkSulk ,fylkbfDyd gkbMªksdkcZu ugha gS &
, , , , , , , ,
N
Ans. 3
N NH NH
(6) (7) (8) (9)
NH2
Ans. 3
Sol. 1, 4, 6
Column-I Column-II
(Compounds) (Class of compounds)
dkWye-I dkWye-II
¼;kSfxd½ ¼;kSfxd dk oxhZdj.k½
Saturated compound
(A) (p)
(vlar`Ir ;kSfxd)
O Heterocyclic compound
(B) (q)
(fo"kepØh; ;kSfxd)
Unsaturated compound
(C) (r)
(vlar`Ir ;kSfxd)
Ans. (A p, s) ; (B p, q) ; (C r, s) ; (D p)
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DPPs BOOKLET-1 VIKAAS (JA) | CHEMISTRY
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4
4 Cl
3 1
2 4
6 3 6
(A) 7 5 3 (B) (C*) 2 (D)
1 5 2
1
2 Br Cl
1
3. In following compound -
fuEu ;kSfxd esa &
CH3 CH3
CH3 CH3
The correct lowest set of locants are :
fuEu esa ls dkSulk LFkkukadks dk U;wure leqPp; lgh gS \
(A*) 3,3,4,5 (B) 3,4,5,5 (C) 4,5,3,3 (D) 5,5,4,3
CH3 CH3
1 2 3
| 4 5| 6 7
Sol. (A) CH3–CH2–C – CH–CH–CH2–CH3
| |
CH3 CH3
Lowest set of Locant (3, 3, 4, 5)
4. Which of the following has longest chain of carbon :
fuEu esa ls fdlesa dkcZu dh lokZf/kd yEch J`a[kyk gS %
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DPPs BOOKLET-1 VIKAAS (JA) | CHEMISTRY
CH2 — CH3
|
(A) CH3 — CH — CH2 — CH — CH3 (B)
|
CH2 — CH3
CH3
|
(C*) (D) CH3 — CH — CH2 — CH2 — CH — CH2 — CH3
|
CH2 — CH3
9.
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DPPs BOOKLET-1 VIKAAS (JA) | CHEMISTRY
10. Which of the following groups is attached to the cyclohexane ring in the following compound.
11. Which of the following alkyl group are possible from Iso-butane ?
(A) Iso-Butyl & n-butyl (B) Sec. butyl & Ter. butyl
(C) n-butyl & Ter. butyl (D*) Iso-butyl & Ter. butyl
fuEu ls dkSu ls ,fYdy lewg vkblksC;qVsu ls lEHko gaS
(A) vkblksC;wfVy o n-C;wfVy (B) f}rh;d C;wfVy o r`rh;dC;wfVy
(C) n-C;wfVy o r`rh;d C;wfVy (D*) vkblksC;wfVy o r`rh;d C;wfVy
12. Number of sp2 – sp2 C-C -bond in the given compound are :
fn;s x;s ;kSfxd esa gkbMªkstu ijek.kqvksa dh la[;k gSA
Ans. 3
13. How many carbon atoms are present in the principle chain of following compound .
uhps fn;s x;s ;kSfxd dh eq[; J`a[kyk esa fdrus dkcZu ijek.kq ekStqn gSaA
Ans. 11
14. How many 1° hydrogens are present in Iso-octane:
vkblks&vkWDVsu esa fdrus 1° gkbMªkstu mifLFkr gS\
Ans. 15
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DPPs BOOKLET-1 VIKAAS (JA) | CHEMISTRY
(iii) Vinylic Compounds : In these compounds, the monovalent functional group is attached to one of the
carbon atoms of the carbon - carbon double bond.
Note : The compounds which have double bond and OH group on same carbon are unstable hence vinylic
alcohol are unstable.
(i),fyfyd ;kSfxd % bu ;kSfxdksa esa ,dy la;ksth fØ;kRed lewg ml sp3– ladfjr dkcZu ijek.kq ls tqM+k gksrk gS tks vkxs
dh vksj dkcZu dkcZu f}caèk vFkkZr~ ,fyfyd dkcZu j[krk gSA bUgsa Hkh 1°, 2° ;k 3° esa oxhZd`r fd;k x;k gSA
(iii) fouk;fyd ;kSfxd % bu ;kSfxdksa esa ,dy fØ;kRed lewg dkcZu&dkcZu f}caèk ds fdlh ,d dkcZu ls tqM+k gksrk gSA
uksV % ;kSfxd ftuesa leku dkcZu ij f}caèk rFkk OH lewg ik;k tkrk gS] os vLFkk;h gksrk gSA vr% fouk;fyd ,YdksgkWy
vLFkk;h gksrk gSA
Memorize this theory as soon as you get the DPP. Revize it regularly and master this concept by practice.
(i). Which of the following compound is unstable
fuEu esa ls dkSulk ;kSfxd vLFkk;h gS %
(A) CH3–CH=CH–Cl (B) CH2=CH–CH2–OH
(C) CH2=CH–CH2–Cl (D*) CH3–CH=CH–OH
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DPPs BOOKLET-1 VIKAAS (JA) | CHEMISTRY
(iii). Which of the following statement is / are correct for following compound
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DPPs BOOKLET-1 VIKAAS (JA) | CHEMISTRY
O/I-CHEMISTRY
1. Which of the following IUPAC names of alkyl radicals is/are correct :
(A*) 1- Ethyl-2-methylcyclopropane
(B*) 4-Ethyl-2-methyl-1-propylcyclohexane
(C*) 1,1,2-Trimethylcyclopentane
(D*) 1,1-Dimethyl-4-propylcyclohexane
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DPPs BOOKLET-1 VIKAAS (JA) | CHEMISTRY
fuEu esa ls dkSulk@dkSuls IUPAC uke lgh gS %
(A*) 1- ,fFky-2-esfFkylkbDyksizksisu
(B*) 4-,fFky-2-esfFky-1-izksfiylkbDyksgsDlsu
(C*) 1,1,2-VªkbesfFkylkbDyksisUVsu
(D*) 1,1-MkbZesfFky-4-çksihylkbDyksgsDlsu
(C*) C2(CN)4 has 9 and 9 bonds. (D*) Cyclohexane has only one type of carbon atoms.
fuEu esa ls dkSulk@dkSuls lgh gS@gSa \
Cl Br
(A*) 1-C;wVhu-3-vkbu 7 rFkk 3 ca/k j[krk gSA (B) OH esa izfrLFkkih dh dqy la[;k 4 gSA
(C*) C2(CN)4 9 rFkk 9 ca/k j[krk gSA (D*) lkbDyksgsDlsu dsoy ,d izdkj dk dkcZu ijek.kq j[krk gSA
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DPPs BOOKLET-1 VIKAAS (JA) | CHEMISTRY
Sol.
(A) H—C C C—H 7, 3
C
H H
Cl Br
(B) OH 3 Substituent (izfrLFkkih)
(C) N C C N 9, 9
C C
N C C N
CH2–CH2–CH3
(D*) CH2=CH—CH(C2 H5)C=CH2 is ..... 2-Bromo-3-ethylpenta-1,4-diene 2-czksekss-3-,fFkyisUVk-1,4-MkbbZu
Br
(B*) 5,6-Diethyl-3,8-dimethyldec-4-ene
5,6-MkbZ,fFky-3,8-MkbZesfFkyMsd-4-bZu
4-,sfFkukbygsIVk-1, 3-MkbZu-6-vkbu
9. How many of following IUPAC names of given strutures are correct.
fuEu esa ls fdrus IUPAC lajpuk ds uke lgh gSaA
(1) 3,4-Diethyl-2,5-dimethyloctane
3,4-MkbZ,fFky-2,5-MkbZesfFkyvkWDVsu
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DPPs BOOKLET-1 VIKAAS (JA) | CHEMISTRY
(2) 5-Ethyl-1-methyl-2-propylcyclohexane
5-,fFky-1-esfFky-2-izksfiylkbDyksgsDlsu
Br
Cl Br
(3) 1,2,4-Tribromo-3,5,6-trichlorocyclohexane
Br Cl
Cl
1,2,4-VªkbZczkseks-3,5,6-VªkbZDyksjkslkbDyksgsDlsu
Cl Br
| |
(4) CH3—C—CH2—C—CH3 4-Bromo-2-chloro-4-methyl-2-nitrohexane
| |
NO2 Et
4-czkseks-2-Dyksjks-4-esfFky-2-ukbVªksgsDlsu
Ans. 3 (1 , 3 , 4)
(A) (P) 2
CH3
(B) H3C – CH – CH2 – C = CH3 (Q) 5
(C) (R) 4
(D) (S) 3
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DPPs BOOKLET-1 VIKAAS (JA) | CHEMISTRY
(ii) Conjugated diene : when the two double bonds are separated by one single bonds, the diene is called
as conjugated diene.
(iii) foyfxr MkbbZu % tc nks f}cU/k ,d ls vf/kd ,dy cU/kksa }kjk i`Fkd gksrs gS] ,sls MkbbZu foyfxr MkbZu dgykrs gSA
CH2=CH–CH2–CH=CH2 CH2=CH–CH2–CH2–CH=CH2
1,4-isUVkMkbZu 1,5-gsDlkMkbZu
Memorize this theory as soon as you get the DPP. Revize it regularly and master this concept by practice.
(iii). Which of the following compound does not have isolated diene
fuEu esa ls dkSulk ;kSfxd foyfxr MkbbZu ugha gSA
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O/I-CHEMISTRY
(C*) (D)
dk IUPAC uke gS %
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DPPs BOOKLET-1 VIKAAS (JA) | CHEMISTRY
5. The correct IUPAC name of the the compound is :
7. Which of the following has incorrect IUPAC numbering. fuEu esa ls fdldk xyr IUPAC Øekadu gSA
(A*) (B)
(C) (D)
(A) 3-ejdsIVks-5-,ehuks csUthu dkcksZflfyd vEy (B*) 3-,ehuks-5-ejdsIVks csUthu dkcksZflfyd vEy
(C) 5- ,ehuks-3-ejdsIVks csUthu dkcksZflfyd vEy (D) 5-ejdsIVks-3-,ehuks csUthu dkcksZflfyd vEy
13. How many carbon atoms are present in parent chain (main chain) of the following compound ?
fuEu ;kSfxd dh tud Ja`[kyk ¼eq[; J`a[kyk½ esa fdrus dkcZu ijek.kq mifLFkr gS \
Ans. 06
Sol.
y
x
OH
Ans. 4
15. In the given compound how many carbon atoms present in the parent chain.
fuEufyf[kr ;kSfxd dh iSr`d Jaq[kyk esa fdrus dkcZu ijek.kq mifLFkr gS\
COOH
Ans. 7
CH2 — Br
2-chloro-1-phenylpropane Bromophenylmethane
Rule – 3 : If more than one benzene ring attached to same carbon atom then it is consider as side chain.
i.e.,
CH2
CH2 — Br
2–Dyksjks–1-Qsfuyizksisu czkseksQsfuyesFksu
fu;e-3 : ;fn ,d gh dkcZu ls ,d ls vf/kd csathu oy; tqM+h gqbZ gks rks csathu dks ik'oZ J`a[kyk ekuk tkrk gSA
CH2
mnk-,
Br
Br
(A*) 2,3-Dibromo-1-phenyl pentane (B) 3,4-Dibromo-5-phenyl pentane
(C) 2,3-Dibromophenyl benzene (D) 3,4-Dibromophenyl benzene
fuEu ;kSfxd dk lgh IUPAC uke gS %
Br
Br
(A*) 2,3-Mkbczkseks-1-Qsfuy isUVsu (B) 3,4-Mkbczkseks-5-Qsfuy isUVsu
(C) 2,3-Mkbczkseks Qsfuy csathu (D) 3,4-MkbczkseksQsfuy csathu
(A) Ethenyl benzene (B) Ethylbenzene (C*) Phenylethene (D) Ethene benzene
fuEu ;kSfxd dk lgh IUPAC uke gS %
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DPPs BOOKLET-1 VIKAAS (JA) | CHEMISTRY
(iii). Correct IUPAC name of the following compound is :
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DPPs BOOKLET-1 VIKAAS (JA) | CHEMISTRY
O/I-CHEMISTRY
Cl Cl
COOH
SO3H
(C*) 4-formyl-2-sulphobenzoic acid
O
HO
(D*) 2-bromo-6-chlorophenol
Br Cl
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DPPs BOOKLET-1 VIKAAS (JA) | CHEMISTRY
fuEu esa ls dkSulk@dkSuls IUPAC uke lgh gS@gSa \
Cl Cl
COOH
SO3H
(C*) 4-QkWfeZy-2-lYQkscsUtkWbd vEy
O
HO
(D*) 2-czkseks-6-DyksjksfQuksy
Br Cl
3 2 1
CH2 – CH2 – CH2 – Br
(B*) 1-Bromo-3-phenylpropane
CH = CH – Cl
(D*) 1-methoxy-2-nitrobenzene
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DPPs BOOKLET-1 VIKAAS (JA) | CHEMISTRY
3 2 1
CH2 – CH2 – CH2 – Br
CH = CH – Cl
(D*) 1- esFkkWDlh-2-ukbVªkscsUthu
(C) 5-Ethyl-1-methylcyclohex-1-ene
(D*) 4-Methyl-3-oxopentan-2-ol
(C) 5-,fFky-1-esfFkylkbDyksgsDl-1-bZu
(D*) 4-esfFky-3-vkWDlksisUVsu-2-vkWy
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DPPs BOOKLET-1 VIKAAS (JA) | CHEMISTRY
7. Which of the following is/are incorrect IUPAC name ?
(A*) 3-Methylenebutanamide (B*) Ethenylcyclohexane
(C*) 1,2,5-tribromo-3,4,6-trichlorocyclohexane (D) Tricyclopropyl methane
fUkEu esa ls dkSulk@dkSuls IUPAC uke lgh ugha gS \
(A*) 3-esfFkyhuC;wVsusekbM (B*) ,fFkuhylkbDyksgsDlsu
(C*) 1,2,5-VªkbZczkseks-3,4,6-VªkbZDyksjkslkbDyksgsDlsu (D) VªkbZlkbDyksizksfiyesFksu
O
3 2
Sol. (A) CH3—CH—CH2—C—NH2 (B)
1 Cyclohexyl ethene
CH2
4 lkbDyksgsfDly ,Fkhu
3-Methyl but-3-enamide
3-esfFkyC;wV-3-busekbM
Br
2
Cl Br
3 2 1 3 1
8. In how many of the following compound secondary suffix name is used as carboxylic acid ?
fuEu fdrus ;kSfxd esa f}fr;d vuqyXu ds :i esa dkcksZDflfyd vEy uke iz;qDr gqvk gSa \
COOH COOH
OCOCH3 OH
(A) CH3–COOH (B) (C) (D) (E)
Ans. 4
CHO O–CHO
| |
OH
9.
| || NH–CHO
OHC O OH
How many aldehyde (–CHO) groups present in the given compound?
fn;s x;s mijksDr ;kSfxd esa fdrus ,fYMgkbM (–CHO) lewg mifLFkr gksrs gSa\
Ans. 2
Column-I Column-II
Compound IUPAC Name
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DPPs BOOKLET-1 VIKAAS (JA) | CHEMISTRY
A bicyclic compound is named by attaching the prefix bicyclo to the name of hydrocarbon corresponding to the
total number of carbon atoms in two rings.
Numbering starts from bridge head to larger ring and then back to smaller ring.
The bracketed number show the number of carbon atoms (except bridge head position carbon atoms) in each
bridge and they cited in decreasing order.
Ex.
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DPPs BOOKLET-1 VIKAAS (JA) | CHEMISTRY
lsrq cfU/kr
fLFkfr
,d ckblkbDyks ;kSfxd dk ukedj.k nks oy; esa mifLFkr dqy dkcZu ijek.kqvksa ls lEcfU/kr gkbMªksdkcZu ds uke ls iwoZ
ckblkbDyks yxkdj fd;k tkrk gSA
lsrq cfU/kr esa ukedj.k igys cM+h oy; esa djrs gSa vkSj mlds ckn NksVh oy; esa dks"Bd izR;sd lsrq esa dkcZu ijek.kqvksa dh
la[;k ¼lsrqcaf/kr dkcZu ijek.kq ds vykok½ dks ?kVrs Øe esa n'kkZrk gSA
mnkgj.k %
1
2
2 1 10
7
6 lsrq cfU/kr 3 9
3 5 C-ijek.kq 8
4 6
4 5 7
ckblkbDyks [2.2.1]gsIVsu ckblkbDyks[4.4.0]Msdsu
1 5
2 O 6 7
6 4
7 8
5 3 3
1
4 2 9
1,7,7-VªkbesfFkyckblkbDyks[2.2.1]gsIVsu-2-vkWu 7-esfFkyckblkbDyks[4.3.0]ukWusu
Memorize this theory as soon as you get the DPP. Revize it regularly and master this concept by practice.
(A) Bicyclo [3.2.1] octan-2-oic acid (B) Bicyclo [3.2.1] octan-1-carboxylic acid
(C*) Bicyclo [3.2.1] octan-8-carboxylic acid (D) None of these
(A) ckblkbDyks [3.2.1] vkWDVsu-2-vkWbd vEy (B) ckblkbDyks [3.2.1] vkWDVsu-1-dkcksZfDlfyd vEy
(C*) ckblkbDyks [3.2.1] vkWDVsu-8-dkcksZfDlfyd vEy (D) buesa ls dksbZ ughaA
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O/I-CHEMISTRY
EST INFORM AT IO
DPP
DAILY PRACTICE PROBLEMS
6. Which of the following is salicylic acid? fuEu esa ls dkSulk lsfyflfyd vEy gS\
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7. Which of the following is not cresol. fuEu esa ls dkSulk fØlkWy ugh gS\
OH
(C) Phenol
COOH
(D*) Isophthalic acid
COOH
fuEu ;kSfxdks ds xyr uke dk p;u dhft,A
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OH
O2N NO2
(C) QhukWy
COOH
(D*) vkblksFkSfyd vEy
COOH
Sol. In benzyl derivative, any functional group is attached to an sp 3 hybridized C-atom next to benzene ring.
csfUty O;qRiUu esa fØ;kRed lewg csathu oy; ls vxys sp3 ladfjr C–ijek.kq ls tqM+k gksrk gSA
13. What is the possible number of isomers of the aromatic compounds of molecular formula C 7H7Cl.
,sjkseSfVd ;kSfxd v.kqlw=k C7H7Cl ds lHkh lEHkkfor leko;oh fyf[k;sA
Ans. 04
Sol.
14. Number of structurally isomeric carbonyl compounds possible with molecular formula C5H10O ........:
v.kqlw=k C5H10O ds lEHko lajpukRed leko;oh dkcksZfuy ;kSfxdksa dh la[;k gSa %
Ans. 07
Sol. (1) CH3–CH2–CH2–CH2–CHO (2) (3)
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(7)
15. How many dichlorodiphenyl with molecular formula C12H8Cl2 of each benzene ring containing only one
(–Cl) group are possible
v.kqlw=k C12H8Cl2 MkbZDyksjks MkbZQsfuy ;kSfxd ftlesa ,d (–Cl) lewg ,d csathu oy; ij mifLFkr gks] mlds
fdrus fLFkfr leko;oh lEHko gSaA
Ans. 6
Cl Cl Cl Cl Cl
Sol. Cl
Cl Cl Cl
Cl Cl Cl
Small ring
The prefix spiro is followed by brackets containing the number of carbon atoms in ascending order, in each
ring attached to common carbon atom and ending with the name of hydrocarbon corresponding to the total
number of carbon atoms in two rings.
Br
5 3
6
4
2
7 1
8
Et
5-Bromo-1-ethylspiro[3.4]octane
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Br O
1 5 3
5 4 6 4 1 7 6 4
4 3
2 5 5
6
3 3 HO 8
7 2
7 8 2 8
Et
1
6 7 9 10 1 2 Me
Likbjks[2.5]vkWDVsu 5-czkseks-1-,fFkyLikbjks[3.4]vkWDVsu Likbjks[2.4]gsIVsu-4-vkWu 2-esfFkyLikbjks[4.5]Mssdsu-8-vkWy
Memorize this theory as soon as you get the DPP. Revize it regularly and master this concept by practice.
(i). The structure of spiro[3.3]heptane is : Likbjks[3.3]gsIVsu dh lajpuk gS :
(A) (B) (C) (D*)
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(A*) (B*)
(C*) (D*)
fuEu esa ls dkSulk laEcU/k dks"Bd esa fn;k x;k lgh gSaA
(A*) CH3–CN rFkk CH3NC (fØ;kRed leko;oh)
(B*) CH3–O–N=O rFkk CH3 – N O (fØ;kRed leko;oh)
||
O
(C*) CH3–CH2–CH2–CHO rFkk H3C CH CH3 (J`a[kyk leko;oh)
|
CHO
(D*) rFkk (fØ;kRed leko;oh)
(fØ;kRed leko;oh)
3. Which of the following alkene can give 3-methylpentane on hydrogenation.
(A*) 3-methylpent-1-ene (B*) 3-methylpent-2-ene
(C) 2-methylpent-1-ene (D*) 2-ethylbut-1-ene
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fuEu esa ls dkSulh ,Ydhu gkbMªkstuhdj.k ij 3-esfFkyisUVsu ns ldrh gSA
(A*) 3-esfFkyisUV-1-bZu (B*) 3-esfFkyisUV-2-bZu (C) 2-esfFkyisUV-1-bZu (D*) 2-,sfFkyC;wV-1-bZu
O O
4. H–C–OC2 H5 and CH 3–C–CH2–OH
Which is/are true about above two structure – (RVP Sir) (IUPAC & Structural Isomers)
(A*) Degree of unsaturation is (1) (B*) Both are functional isomers
(C) Both are metamers (D*) Both have same molecular formula
O O
H–C–OC2 H5 rFkk CH 3–C–CH2–OH
mijksDr nksuksa lajpuk ds lUnHkZ es lgh dFku gS@gSa &
(A*) vlar`Irk dh dksfV (1) gS (B*) nksuksa fØ;kRed leko;oh gS
(C) nksuksa e/;ko;oh gS (D*) nksuksa ds v.kqlw=k leku gSa
O O
Sol. H–C–OC2 H5 and CH 3–C–CH2–OH not a metamers to each other.
O O
H–C–OC2 H5 rFkk CH 3–C–CH2–OH ,d nwljs ds e/;ko;oh ugh gSA
O O O O
5. CH3 –C–O–C CH3 and CH 3–CH2 –C–O–C
Which is/are incorrect about given structure (RVP Sir) (IUPAC & Structural Isomers)
(A*) Both are functional isomers (B*) The degree of unsaturation is 2
(C) Both have same molecular formula (D) Both are metamers to each other
O O O O
CH3 –C–O–C CH3 rFkk CH 3–CH2 –C–O–C
fuEu lajpuk ds fy, dkSulk@dkSulsa dFku lgh gS@gSa &
(A*) nksuksa fØ;kRed leko;oh gSA (B*) vlar‘`Irrk dh dksfV 2 gSA
(C) nksuksa ds v.kqlw=k leku gSa (D) nksuksa e/;ko;oh gSa
Sol. Both having same functional group so they are not functional isomers the degree of unsaturation is 3.
nksuksa esa leku fØ;kRed lewg ds dkj.k fØ;kRed leko;oh ugha gS rFkk vlar‘`Irrk dh nj 3 gSA
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fuEu esa ls dkSulk laca/k lgh gS %
8. How many monochloro structural isomers will produce when 3-Methylpentane, reacts with chlorine in
presence of sunlight ?
tc 3-esfFkyisUVsu dh vfHkfØ;k lw;Z ds izdk'k dh mifLFkfr esa Dyksjhu ds lkFk dh tkrh gS rks fdrus eksuksDyksjks
lajpuk leko;oh izkIr gksrs gSa\
Ans. 04
Sol.
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9. Number of different products in the given ozonolysis reaction will be :
nh x;h vkstksuhdj.k vfHkfØ;k ls izkIr fHkUu mRiknksa dh laa[;k gksxh%
O3
Products mRikn
Zn / H2O
Ans. 02
O3
Sol.
+ CH2 = O
Zn / H2O
4 moles 6 moles
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O/I-CHEMISTRY
EST INFORM AT IO
DPP
DAILY PRACTICE PROBLEMS
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5. Which of the following give positive test with neutral FeCl3
(A) Leucine (B*) Tyrosine (C) Asparagine (D) Serine
fuEu esa ls dkSu mnklhu FeCl3 ds lkFk èkukRed ijh{k.k nsrk gSA
(A) Y;wflu (B*) Vk;jksflu (C) ,sLIkkftZu (D) lsfju
I II III
(A) I & II only (B) II & III only (C) I and III only (D*) All
fuEu es ls dkSulk ;kSfxd vkstksuhvi?kVu ij leku mRikn nsrk gSA
I II III
(A) I o II dsoy (B) II o III dsoy (C) I o III dsoy (D*) lHkh
csUthu LFkk;h gS] blfy;s bldk vkstksuh vi?kVu ugh gks ldrk
Cl2 / h
X 2 C8H16
3 monochloro structural product (3
H / Ni
9. eksuks Dyksjks lajpukRed mRikn½
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Structure of X will be :
X dh lajpuk gksxhA
11. How many ketones with molecular formula C5H10O is possible (structural isomers only).
C5H10O v.kqlw=k ds fdrus dhVksu ¼dsoy lajpukRed leko;oh½ lEHko gS &
(A) 2 (B*) 3 (C) 4 (D) 6
Cl2 / h
12. 'm' monochloro products
Cl2 / h
'n' dichloro products
Cl2 / h
'n' MkbDyksjks mRikn
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13. How many compounds will give positive iodoform test but negative Tollen’s test ?
fuEu esa fdrus ;kSfxd /kukRed vk;ksMksQkWeZ ijh{k.k rFkk _.kkRed VkWysu vfHkdeZd ijh{k.k nsrs gS \
(a) CH3CHO (b) (c)
Ans. 3
Sol. (3) b, c, e
14. Consider all possible isomeric amines of molecular weight = 73. How many of them give isocyanide
with CHCl3 and KOH
v.kqHkkj 87 ds lHkh lEHko leko;oh ,ehu ij fopkj dhft,A buesa ls fdrus f}rh;d ,ehu gS \
Ans. 4
15. In how many of the following compound. –OH group directly attached on the benzene ring ?
(1) Glycol (2) Glycerol (3) o-cresol (4) p-cresol
(5) Phenol (6) aniline (7) anisol (8) resorcinol
(9) catechol (10) Hydroquinone
fuEu esa ls fdrus ;kSfxdkas esa –OH lewg csathu oy; ls lh/ks tqM+k gS ?
(1) Xyk;dkWy (2) fXyljkWy (3) o-fØlkWy (4) p-fØlkWy
(5) fQukWy (6) ,fuyhu (7) ,fulkWy (8) jslksflZukWy
(9) dSVsdkWy (10) gkbMªksfDouksu
Ans. 6
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(A*) vk;ksMksQkWeZ ijh{k.k (B*) VkWysu ijh{k.k (C) Qsgfyax ijh{k.k (D*) 2,4-DNP ijh{k.k
3. The test that can be used to distinguish between 1-propanol and 2-propanol :
(A*) Lucas test (B*) Iodoform test (C*) Victor mayer test (D) Carbyl amine test
fuEu esa ls fdl ijh{k.k }kjk 1-izksisukWy rFkk 2-izksisukWy ds e/; foHksnu fd;k tk ldrk gS %
(A*) Y;wdkWl ijh{k.k (B*) vk;ksMksQkWeZ ijh{k.k (C*) foDVj&es;j ijh{k.k (D) dkfcZy&,ehu ijh{k.k
Sol. Carbyl amine test is used to distinguish amines.
,ehuksa ds e/; foHksnu djus ds fy, dkfcZy&,ehu ijh{k.k dk mi;ksx fd;k tkrk gSA
4. Test to differentiate between (CH3OH) and (Ph-OH) is/are :
(A*) Victor mayer test (B*) Neutral FeCl3 (C*) Br2/H2O (D) Na metal
fdl ijh{k.k }kjk (CH3OH) rFkk (Ph-OH) ds e/; foHksnu fd;k tk ldrk gS@gSa&
(A*) foDVj&es;j ijh{k.k (B*) mnklhu FeCl3 (C*) Br2/H2O (D) Na /kkrq
5. What is/are the structure of a compound (C3H2D2) which decolourise bromine water.
fuEu esa ls dkSulh lajpuk ;kSfxd (C3H2D2) dh gS tks czksehu ty dks jaxghu djrh gSA
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6. Which of the following compound will give positive test with NaHCO 3?
fuEu es ls dkSuls ;kSfxd NaHCO3 ds lkFk dkSulk ;kSfxd /kukRed ijh{k.k nsrk gS ?
(A*) Br2 water test (B*) 2, 4-DNP test (C*) Neutral FeCl3 (D) Tollen’s test
(A*) Br2 ty ijh{k.k (B*) 2, 4-DNP ijh{k.k (C*) mnklhu FeCl3 (D) VkWysu ijh{k.k
Sol. Terminal alkyne and –CH=O group gives +ve test with tollens reagent.
vUrLrFk ,YdkbZu rFkk –CH=O lewg VkWysu vfHkdeZd ds lkFk /kukRed ifj{k.k nsrs gSaA
8. Which of the following will give positive iodoform test.
fuEu esa ls dkSu /kukRed vk;MksQkeZ ijh{k.k nsrs gSA
(A) (B*) (C*) (D*)
9. Compound giving offensive smell on heating with chloroform and alkali
,d ;kSfxd tks DyksjksQkWeZ rFkk {kkj ds lkFk xeZ djus ij rhoz vlguh; xa/k ;qDr ;kSfxd nsrk gS] ;kSfxd gSA
Sol. Aniline and 1° amine on heating with chloroform and alkali gives offensive smell.
Sol. ,fuyhu ,oa 1° ,ehu DyksjksQkeZ rFkk {kkj ds lkFk xeZ djus ij rhoz vlguh; xa/k ;qDr ;kSfxd nsrs gSA
10. Match the given compounds in Column-I with their appropriate descriptions given in Column-II.
Column-I Column-II
CH3 — CH — CH3
(A) | (p) It evolve CO2 gas with NaHCO3
OH
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dkWye -I esa fn;s x;s ;kSfxdksa dks dkWye-II ds mfpr fooj.k ls lqesfyr dhft;sA
dkWye-I dkWye-II
CH3 — CH — CH3
(A) | (p) NaHCO3 ds lkFk CO2 xSl fu"dkflr djrk gSA
OH
(D) csUthu dk vipf;r vkstksuhdj.k mRikn (s) ;g VkWysu ijh{k.k nsrk gSA
(t) ;g 2,4 DNP ijh{k.k nsrk gSA
Ans. (A) q,r (B) q,t (C) p (D) s , t
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