Olrqfu"B Iz'U: Objective Questions

Chemical Kinetics
OBJECTIVE QUESTIONS
oLrq fu"B iz 'u ¼ OBJECTIVE QUESTIONS½
 Marked Questions may have for Revision Questions.
 fpfUgr iz ' u nks g jkus ;ks X; iz ' u gS A
Section (A) : Rate of reaction
[k.M (A) : vfHkfØ;k dk osx
d[ A ] d[B] d[C ]
A-1. xA + yB  zC. If  =  = 1.5 = then x,y and z can be :
dt dt dt
d[ A ] d[B] d[C ]
xA + yB  zC. ;fn  =  = 1.5 gS rks x,y vkSj z gks ldrs gS :
dt dt dt
(1) 1,1,1 (2) 3,2,3 (3*) 3,3,2 (4) 2,2,3
A-2. The rate of a reaction is expressed in different ways as follows ;
+ 1/2(d[C]/dt) = – 1/3 (d[D]/dt) = + 1/4 (d[A]/dt) = – (d[B]/dt) The reaction can be :
,d vfHkfØ;k dh vfHkfØ;k nj dks fofHkUu izdkj ls fuEu :i esa iznf'kZr fd;k tk ldrk gS :
+ 1/2(d[C]/dt) = – 1/3 (d[D]/dt) = + 1/4 (d[A]/dt) = – (d[B]/dt) gS] rks vfHkfØ;k gks ldrh gS :
(1) 4 A + B  2C + 3D (2*) B + 3D  4A + 2C
(3) 4A + 2B  2C + 3D (4) B + (1/2) D  4A + 3 C
A-3. Consider the chemical reaction :

N2(g) + 3H2(g)  2NH3(g)
The rate of this reaction can be expressed ;in terms of time and of concentration of N2(g), H2(g) or NH3(g).
Identify the correct relationship amongest the rate expressions.
d [N2 ] 1 d [H2 ] 1 d [NH3 ] d [N2 ] 3d [H2 ] 2d [NH3 ]
(1*) Rate = – =– = (2) Rate = – =– =
dt 3 dt 2 dt dt dt dt
d [N2 ] 1 d [H2 ] d [NH3 ] d [N2 ] d [H2 ] d [NH3 ]

(3) Rate = – =– = (4) Rate = – = =
dt 3 dt dt dt dt dt
jklk;fud vfHkfØ;k ekurs gq, %
N2(g) + 3H2(g)  2NH3(g)
bl vfHkfØ;k dh nj dks N2(g), H2(g) ;k NH3(g) dh lkUnzrk rFkk le; ds inksa esa O;Dr fd;k tk ldrk gS fuEu esa ls
nj O;atd ds lgh lca/k dks crkb;sA
d [N2 ] 1 d [H2 ] 1 d [NH3 ] d [N2 ] 3d [H2 ] 2d [NH3 ]
(1*) nj = – =– = (2) nj = – =– =
d [N2 ] 1 d [H2 ] d [NH3 ] d [N2 ] d [H2 ] d [NH3 ]

(3) nj = – =– = (4) nj = – = =
dt 3 dt dt dt dt dt
A-4. In a reaction N2(g) + 3H2(g)  2NH3(g) the rate of appearance of NH3 is 2.5  10–4 mol L–1 sec–1. The
rate of reaction & rate of disappearance of H2 will be (in mol L–1 sec–1)
,d vfHkfØ;k N2(g) + 3H2(g)  2NH3(g) esa NH3 ds izdV gksus dh nj 2.5  10–4 mol L–1 sec–1 gSA vfHkfØ;k dh
nj rFkk H2 ds foyqIr gksus dh nj Øe'k% gksxh (mol L–1 sec–1 esa)
(1) 3.75  10–4 , 1.25  10–4 (2) 1.25  10–4, 2.5  10–4
(3*) 1.25  10–4, 3.75  10–4 (4) 5.0  10–4, 3.75  10–4
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MAINCHK -1
Chemical Kinetics
 d [B]
A-5. 3A  2B, rate of reaction is equal to :
dt
 d [B]
3A  2B vfHkfØ;k dh nj cjkcj gS &
dt
3 d [ A] 2 d [ A] 1 d [ A] d [ A]
(1) – (2*) – (3) – (4) +2
2 dt 3 dt 3 dt dt
A-6. ln the reaction; A + 2B  3C + D, which of the following expression does not describe changes in the
concentration of various species as a function of time :
vfHkfØ;k A + 2B  3C + D esa dkSulk O;atd fofHkUu ?kVdksa dh lkUnzrk esa le; ds lkFk ifjorZu dks of.kZr ugh djrk
gS %
(1) {d [C] / dt} = – {3d [A] / dt} (2) {3d [D] / dt} = {d [C] / dt}
(3) {3d [B] / dt} = – {2d [C] / dt} (4*) {2d [B] / dt} = – {d [A] / dt}
A-7. In the following reaction : xA  yB

 d[ A ]   d[B ] 
log   dt  = log  dt  + log 2
   
where –ve sign indicates rate of disappearance of the reactant. Thus, x : y is :
fuEu vfHkfØ;k ds fy, : xA  yB
 d[ A ]   d[B ] 
log   dt  = log  dt  + log 2
   
;gk¡ ij _.kkRed fpUg vfHkdkjd dh foyqIr gksus dh nj dks iznf'kZr djrk gS] vr% x : y gS :
(1) 1 : 2 (2*) 2 : 1 (3) 3 : 1 (4) 3 : 10
A-8. A graph of volume of hydrogen released vs time for the reaction between zinc and dil.HCl is given in below fig.
On the basis of this mark the correct option.
V3  V2
(1*) Average rate upto 40 seconds is
40
V3  V2
(2) Average rate upto 40 seconds is
40  30
V3
40
V3  V1
40  20
ftad rFkk ruq HCl ds e/; vfHkfØ;k ds fy, eqDr gkbMªkstu ds vk;ru o le; ds e/; fuEu xzkQ fn;k x;k gSA bl vk/
kkj ij lgh dFku dk p;u dhft,A
V3  V2
(1*) 40 lSd.M rd vkSlr nj gSA
40
V3  V2
(2) 40 lSd.M rd vkSlr nj gSA
40  30
V3
40
V3  V1
40  20
MAINCHK -2
Chemical Kinetics
A-9. Which of the following statements is correct?
(1*) The rate of a reaction decreases with passage of time as the concentration of reactants dereases.
(2) The rate of a reaction is same at any time during the reaction.
(3) The rate of a reaction is independent of temperature change.
(4) The rate of a reaction decreases with increase in concentration of reactant(s).
fuEu esa ls dkSulk dFku lgh gS \
(1) vfHkdkjdksa dh lkUnzrk tSls&tSls ?kVrh gS le; ds lkFk vfHkfØ;k dh nj Hkh ?kVrh gSA
(2) vfHkfØ;k ds nkSjku fdlh Hkh le; ij vfHkfØ;k dh nj leku gksxhA
(3) vfHkfØ;k dh nj rki ifjorZu ij fuHkZj ugh djrh gSA
(4) vfHkfØ;k dh nj vfHkdkjdksa dh lkUnzrk esa o`f} ds lkFk ?kVrh gSA
A-10. Which of the following expressions is correct for the rate of reaction given below ?
fuEu vfHkfØ;k ds fy, dkSulk nj O;tad lgh gS ?
5Br–(aq) + BrO3– (aq) + 6H+ (aq)  3Br2(aq) + 3H2O(l)
 [Br  ]  [H ]  [Br  ] 6  [H ]

(1) =5 (2) =
t t t 5 t
 [Br  ] 5  [H ]  [Br  ]  [H ]

(3*) = (4) =6
t 6 t t t
Section (B) : Rate law

[k.M (B) : nj fu;e
B-1. aA + bB  Product, dx/dt = k [A]a [B]b . If conc of A is doubled, rate is four times. If conc. of B is made
four times, rate is doubled. What is relation between rate of disappearance of A and that of B ?
(1) {– d [A] / dt} = {– d [B] / dtK (2*) – {d [A] / dt} = – 4 {d [B] / dt}
(3) – 4 {d [A] / dt) = {– d [B]/ dt} (4) None of these
aA + bB  mRikn] vfHkfØ;k esa dx/dt = k [A]a [B]b gSA ;fn A dh lkUnzrk dks nqxquh dj nh tk, rks vfHkfØ;k dh
nj pkj xquk gks tkrh gS vkSj ;fn B dh lkUnzrk dks pkj xquh dj nh tk, rks vfHkfØ;k dh nj nqxquh gks tkrh gS rks A o
B ds foyqIr gksus dh njksa ds e/; D;k laca/k gksxk ?
(1) {– d [A] / dt} = {– d [B] / dt} (2*) – {d [A] / dt} = – 4 {d [B] / dt}
(3) – 4 {d [A] / dt) = {– d [B]/ dt} (4) mijksDr esa ls dksbZ ughaA
B-2. For a reaction pA + qB  products, the rate law expression is r = k[A]1 [B]m , then :
(1) (p+1) < (1+ m) (2) (p + q) > (1 + m)
(3*) (p + q) may or may not be equal to (1+ m) (4) (p + q) = (1 + m)
,d vfHkfØ;k pA + qB  mRikn, ds fy, vfHkfØ;k ds nj fu;e dks r = k[A]1 [B]m O;atd }kjk iznf'kZr fd;k tkrk gS
rks:
(1) (p+1) < (1+ m) (2) (p + q) > (1 + m)
(3*) (p + q), (1+ m) ds cjkcj gks ldrk gS ;k ugha gks ldrk gSA (4) (p + q) = (1 + m)
B-3. For the reaction H2 + Br2  2 HBr overall order is found to be 3/2. The rate of reaction can be expressed as:
(1) [H2][Br2]1/2 (2) [H2]1/2 [Br2] (3) [H2]3/2 [Br2]0 (4*) All of these
vfHkfØ;k H2 + Br2  2 HBr ds fy, iw.kZ vfHkfØ;k dh dksfV 3/2 ikbZ x;h gS rks vfHkfØ;k dk osx dks iznf'kZr fd;k tk ldrk gS %
(1) [H2][Br2]1/2 (2) [H2]1/2 [Br2] (3) [H2]3/2 [Br2]0 (4*) mijksDr lHkh
MAINCHK -3
Chemical Kinetics
d [ A ]
B-4. The rate of certain hypothetical reaction A + B + C  products is given by r = = K [A]1/2[B]1/3[C]1/4
dt
The order of the reaction :
d [ A ]
dkYifud vfHkfØ;k A + B + C  mRikn ds fy, nj fuEu izdkj nh tkrh gS r = = K [A]1/2[B]1/3[C]1/4 vfHkfØ;k
dt
dh dksfV gS %
1 13
(1) 1 (2) (3) 2 (4*)
2 12
B-5. 2A  B + C it would be a zero order reaction when :

(1) The rate of reaction is proportional to square of conc. of A
(2*) The rate of reaction remains same at any conc. of A
(3) The rate remains unchanged at any conc. of B and C
(4) The rate of reaction doubles if conc. of B is increased to double
2A  B + C ;g 'kqU; dksfV vfHkfØ;k gksxh %
(1) tc vfHkfØ;k dh nj A dh lkUnzrk ds oxZ ds lekuqikrh gSA
(2*) tc vfHkfØ;k dh nj A dh lHkh lkUnzrk ds fy, leku gksA
(3) tc vfHkfØ;k dh nj B rFkk C dh fdlh Hkh lkUnzrk ds fy, vifjofrZr jgrh gSA
(4) tc vfHkfØ;k dh nj nqxuh gks tkrh gS ;fn B dh lkUnzrk c<+kdj nqxuh dj nh tkrh gSA
B-6. The rate equation for the reaction 2A + B  C is found to be : rate k[A][B]. The correct statement in relation
to this reaction is that the
(1) Rate of formation of C is twice the rate of disappearance of A.
(2) Half life is a constant
(3) Unit of k must be s–1
(4*) Value of k is independent of the initial concentration of A and B
vfHkfØ;k 2A + B  C ds fy, nj lehdj.k nj k[A][B] gSA bl vfHkfØ;k ds fy, lgh dFku D;k gS %
(1) C ds fuekZ.k dh nj] A ds foyqIr gksus dh nj dh nqxuh gSA .
(2) v)Zvk;q ,d fLFkjakd gSA
(3) k dh bdkbZ s–1 gksuh pkfg,A
(4*) k dk eku A o B dh izkjfHkd lkUnzrkvksa ij fuHkZj ugha djrk gSA
B-7. For the reaction, 2NO(g) + 2H2(g)  N2(g) + 2H2O(g) the rate expression can be written in the following
ways:
{dt [N2] / dt} = k1 [NO][H2] ; {d[H2O] / dt) = k[NO][H2] ; {– d[NO] / dt} = k1 [NO] [H2] ; {–d[H2] / dt} = k1 [NO][H2]
The relationship between k, k1 , k1 and k1. is :
(1) k = k1 = k1 = k1 (2*) k = 2k1 = k1 = k1 (3) k = 2k1 = k1 = k1 (4) k = k1 = k1 = 2 k1
vfHkfØ;k 2 NO(g) + 2H2 (g)  N2(g) + 2H2O(g) ds fy, vfHkfØ;k ds nj O;atd dks fuEu izdkj ls fy[kk tk ldrk gS:
{dt [N2] / dt} = k1 [NO][H2] ; {d[H2O] / dt) = k[NO][H2] ; {– d[NO] / dt} = k1 [NO] [H2] ; {–d[H2] / dt} = k1 [NO][H2]
vr% k, k1 , k1 vkSj k1. ds e/; laca/k gS :
(1) k = k1 = k1 = k1 (2*) k = 2k1 = k1 = k1 (3) k = 2k1 = k1 = k1 (4) k = k1 = k1 = 2 k1
B-8. If a reaction gets completed in finite time then its order can be :
(1) 3 (2) 2 (3) 1 (4*) Zero
;fn vfHkfØ;k lhfer vof/k esa iw.kZ gks tkrh gS rks mldk Øe gks ldrk gS
(1) 3 (2) 2 (3) 1 (4*) 'kwU;
B-9. For the reaction A + B  Products, it is found that the order of A is 2 and of B is 3 in the rate expression.
When concentration of both is doubled the rate will increase by a factor of :
vfHkfØ;k A + B  mRikn ds fy, nj fu;e esa ;g ik;k x;k fd A dh dksfV 2 vkSj B dh 3 gS tc nksuksa lkUnzrk nqxuh
dj nh tkrh gS rks nj fdruh xquh gks tk;sxh
(1) 10 (2) 6 (3*) 32 (4) 16
MAINCHK -4
Chemical Kinetics
B-10. For a reaction A + B  products, the rate of the reaction was doubled when the concentration of. A was
doubled, the rate was again doubled when the conc. of A & B were doubled, the order of the reaction with
respect to A & B are :
,d vfHkfØ;k A + B  mRikn ds fy, vfHkfØ;k dh nj nqxuh gks tkrh gS tc A dh lkUnzrk nqxuh dj nh tkrh gSA nj
iqu% nqxuh gks tkrh gS tc A o B dh lkUnzrk,a nqxuh dj nh tkrh gSaA vfHkfØ;k dh A o B ds lkis{k dksfV gS %
(1) 1,1 (2) 2,0 (3*) 1,0 (4) 0,1
Section (C) : The integrated rate laws

[k.M (C) : lekdfyr nj fu;e
C-1. The rate constant of reaction 2 A + B  C is 2.57 × 10–5 It mole–1 sec–1 after 10 sec. 2.65 × 10–5 It. mole–
1 sec–1 after 20 sec. and 2.55 × 10–5 It. mole–1 sec–1 after 30 sec. The order of the reaction is:
vfHkfØ;k 2 A + B  C ds fy, vfHkfØ;k osx fu;rkad dk eku 10 lSd.M i'pkr~ 2.57 × 10–5 Lt.mole–1 sec–1
vkSj 20 lSd.M i'pkr 2.65 × 10–5 Lt. mole–1 sec–1 rFkk 30 lSd.M i'pkr~ 2.55 × 10–5 Lt. mole–1 sec–1 gS rks
vfHkfØ;k dh dksfV D;k gksxh :
(1) 0 (2) 1 (3*) 2 (4) 3
C-2. For a first order reaction, the plot of ‘t’ against log C gives a straight line with slope equal to :
,d izFke dksfV dh vfHkfØ;k esa ‘t’ dk log C ds fo:) xzkQ ,d lh/kh js[kk ds :i esa izkIr gksrk gS rks xzkQ dk <ky fuEu
ds cjkcj gksxkA
(1) (k / 2.303) (2*) (– k / 2.303) (3) (ln k / 2.303) (4) – k.
C-3. In a first order reaction the amount of reactant decayed in three half lives (let a be is initial amount) would be:
izFke oxZ vfHkfØ;k esa vfHkdkjd ds izkjfEHkd ek=kk (A) dh fdruh ek=kk rhu v)Z vk;q esa {k; (decay) gks tk;sxh %
(1*) 7a / 8 (2) a / 8 (3) a / 6 (4) 5a / 6
C-4. Graph between concentration of the product and time of the reaction A  B is of the type Hence
graph between – d[A]/dt and time will be of the type :

(–d[A]/dt)
(1) (2) (3*) (4)
Time
X I
vfHkfØ;k A  B esa mRiknksa dh lkUnzrkvksa vkSj le; ds e/; xzkQ fuEu izdkj ls izkIr gksrk gS vr% – d[A]/dtt
l e;
vkSj le; ds e/; xzkQ fdl izdkj dk gksxk :
(–d[A]/dt) (–d[A]/dt) (–d[A]/dt) (–d[A]/dt)
(1) (2) (3*) (4)
l e; l e; l e; l e;
C-5. The reaction N2O5 (in CCl4)  2NO2 + 1/2O2(g) is first order in N2O5 with rate constant 6.2  10–4 S–1. What
is the value of rate of reaction when [N2O5] = 1.25 mole L–1
vfHkfØ;k N2O5 (CCl4 esa)  2NO2 + 1/2O2(g) izFke dksfV dh gS rFkk nj fu;rkad 6.2  10–4 S–1 gSaA vfHkfØ;k dh nj
dk eku D;k gS tc [N2O5] = 1.25 mole L–1 gSA
(1*) 7.75  10–4 mol L–1 S–1 (2) 6.35  10–3 mol L–1 S–1
–5
(3) 5.15  10 mol L S –1 –1 (4) 3,85  10–4 mol L–1 S–1
MAINCHK -5
Chemical Kinetics
C-6. K for a zero order reaction is 2 10–2 mol L–1 sec–1 . If the concentration of the reactant after 25 sec is 0.5 M,
the initial concentration must have been.
K, 2  10–2 mol L–1 sec–1 gSA ;fn fØ;kdkjd dh lkUnzrk 25 sec i'pkr~ 0.5 M gS rks izkjfEHkd lkUnzrk gksuh pkfg,
(1) 0.5 M (2) 1.25 M (3) 12.5 M (4*) 1.0 M
C-7. Plot of log(a–x) vs time t is straight line. This indicates that the reaction is of
(1) Second order (2*) First order (3) Zero order (4) Third order
log(a–x) vkSj le; t ds e/; xzkQ lh/kh js[kk gSA ;g crkrk gS fd vfHkfØ;k gS %
(1) f}rh; dksfV dh (2*) izFke dksfV dh (3) 'kqU; dksfV dh (4) r`rh; dksfV dh
C-8. In a certain reaction, 10% of the reactant decomposes in one hour, 20 % in two hours, 30% in three hours
and so on the dimensions of the rate constant is :
(1) hour–1 (2*) mole litre–1 sec–1 (3) litre mole–1 sec–1 (4) mole sec–1
fdlh vfHkfØ;k esa ,d ?k.Vs esa vfHkdkjd dk 10%] nks ?k.Vs esa 20 % rFkk rhu ?k.Vs esa 30% fo;kstu gksrk gS rFkk bl
izdkj blh fn'kk esa fo;kstu pyrk jgrk gS rks vfHkfØ;k osx fLFkjkad dh foek D;k gksxh :
(1) ?k.Vs–1 (2*) eksy yhVj–1 lSd.M–1 (3) yhVj–1 eksy–1 lSd.M–1 (4) eksy lSd.M–1
C-9. If a first order reaction is completed to the extent of 75% and 50% in time intervals, t1 and t2, what is the
ratio, t1 : t2 ?
,d izFke dksfV dh vfHkfØ;k esa le; vUrjky t1 vkSj t2 ij vfHkfØ;k Øe'k% 75% vkSj 50% iw.kZ gks tkrh gS rks t1 : t2
dk vuqikr gksxk ?
ln (3 / 4)
(1) ln 2 (2) (3*) 2 (4) 1/2
ln 2
ln 2
C-10. The rate constant for a reaction is min–1. What will be the order of reaction and time taken to change
10
concentration from 1 M to 0.25 M.
(1) one, 10 min (2) zero, 10 min (3*) one, 20 min (4) two, 20 min
ln 2
,d vfHkfØ;k ds fy, nj fu;rkad 10 min–1 gSA vfHkfØ;k dh dksfV rFkk 1 M ls 0.25 M lkUnzrk ifjorZu esa yxk le;
le; gksxk %
(1) ,d, 10 min (2) 'kwU;, 10 min (3*) ,d, 20 min (4) nks, 20 min
C-11. In the case of zero order reaction, the ratio of time required for 75% completion to 50% completion is :
(1) ln 2 (2) 2 (3*) 1.5 (4) None
'kwU; dksfV dh vfHkfØ;k ds fy, 75% iw.kZ gksus rFkk 50% iw.kZ gksus esa yxus okys le; dk vuqikr gS :
(1) ln 2 (2) 2 (3*) 1.5 (4) None dksbZ ugha
C-12. In a I order reaction A  products, the concentration of the reactant decrases to 6.25% of its initial value
in 80 minutes. What is (i) the rate constant and (ii) the rate of the reaction, 100 minutes after the start, if the
initial concentration is 0.2 mole/litre?
(1) 2.17 × 102 min1, 3.47 × 104 mol.litre1 min1
(2*) 3.465 × 102 min1, 2.166 × 104 mol.litre1 min1
(3) 3.465 × 103 min1, 2.17 × 103 mol.litre1 min1
(4) 2.166 × 103 min1, 2.667 × 104 mol.litre1 min1
,d izFke dksfV dh vfHkfØ;k A  mRikn] gS blesa] vfHkdkjd dh lkUnzrk dks viuh izkjfEHkd lkUnzrk ls 6.25% ?kVkus
esa 80 feuV yxrs gS (i) vfHkfØ;k osx fu;rkad vkSj (ii) ;fn vfHkfØ;k izkjEHk gksus ij mldh lkUnzrk 0.2 eksy@yhVj yh
x;h rks vfHkfØ;k 'kq: gksus ds 100 feuV i'pkr~ vfHkfØ;k dk osx D;k gksxkA
(1) 2.17 × 102 feuV1, 3.47 × 104 eksy yhVj1 feuV1
(2*) 3.465 × 102 feuV1, 2.166 × 104 eksy yhVj1 feuV1
MAINCHK -6
Chemical Kinetics
Section (D) : Methods to determine the rate law
[k.M (D) : osx fu;e dks fu/kkZfjr djus dh fof/k;k¡
D-1. The data for the reaction A + B  C is
Exp. [A]0 [B]0 initial rate
1 0.012 0.035 0.10
2 0.024 0.035 0.80
3 0.012 0.070 0.10
4 0.024 0.070 0.80
(1) r = k [B]3 (2*) r = k [A]3 (3) r = k [A] [B]4 (4) r = k [A]2 [B]2 .
A + B  C vfHkfØ;k ds fy, fuEu vkdM+s fn, x, gSa
iz;ksx [A]0 [B]0 izkjfEHkd nj
1 0.012 0.035 0.10
2 0.024 0.035 0.80
3 0.012 0.070 0.10
4 0.024 0.070 0.80
(1) r = k [B]3 (2*) r = k [A]3 (3) r = k [A] [B]4 (4) r = k [A]2 [B]2 .
dx
D-2. A + B  Product, =k [A]a [B]b
dt
 dx 
If  dt  = k, then order is :
 
(1) 4 (2) 2 (3) 1 (4*) 0
dx
A + B  mRikn, =k [A]a [B]b
dt
 dx 
;fn   = k gS rks vfHkfØ;k dh dksfV gS :
 dt 
(1) 4 (2) 2 (3) 1 (4*) 0
 dx   dx 
D-3. A  Product and  dt  = k[A]2 . If log  dt  is plotted against log [A],then graph is of the type :
   
(1) (2) (3*) (4)
 dx   dx 
vfHkfØ;k A  mRikn] vkSj   = k[A]2 gSA ;fn log  dt  dks log [A] ds fo:) xzkQ vkjsf[kr fd;k tk, rks xzkQ dk
 dt 
izdkj gksxk \
(1) (2) (3*) (4)
MAINCHK -7
Chemical Kinetics
d [A ]
D-4. For the reaction A  Products, – = k and at different time interval, [A] values are :
dt
Time 0 5 min 10 min 15 min

[A] 20 mol 18 mol 16 mol 14 mol
At 20 minute, rate will be :
(1) 12 mol /min (2) 10 mol/min (3) 8 mol/min (4*) 0.4 mol/min
d [A ]
vfHkfØ;k A  mRiknks esa, – dt
= k rFkk fofHkUu le;karjkyksa ij [A] dk eku gS :
l e; 0 5 feuV 10 feuV 15 feuV

[A] 20 eks
y 18 eks
y 16 eks
y 14 eks
y
20 feuV ij vfHkfØ;k dk osx gksxk :
(1) 12 eksy/feuV (2) 10 eksy/feuV (3) 8 eksy/feuV (4*) 0.4 eksy/feuV
D-5. The rate law for a reaction A + B  product is rate = K[A]1[B]2. Then which one of the following statement
is false :
(1) If [B] is held constant while [A] is doubled, the reaction will proceed twice as fast
(2*) If [A] is held constant while [B] is reduced to one quater, the rate will be halved
(3) If [A] and [B] are both doubled, the reaction will proceed 8 times as fast
(4) This is a third order reaction
vfHkfØ;k A + B  mRIkkn ds fy, nj fu;e fuEu gSA
nj = K[A]1[B]2] fuEu esa ls dkSulk dFku xyr gSA
(1) ;fn [B] dks fu;r j[kk tk, tcfd [A] nqxquk dj nsa rks vfHkfØ;k nqxquh xfr ls gksxhA
(2*) ;fn [A] dks fu;r j[kk tk, tcfd [B] dks ,d pkSFkkbZ dj nsa rks nj vk/kh gksxhA
(3) ;fn [A] vkSj [B] nksuksa nqxqus dj fn;s tk,a rks vfHkfØ;k 8 xquk rst gksxhA
(4) ;g ,d r`rh; dksfV dh vfHkfØ;k gSA
D-6. The conversion of vinyl allyl ether to pent-4-enol follows a certain kinetics.
The following plot is obtained for such a reaction.
The order for the reaction is

(1) zero (2) –1 (3*) 1 (4) 2
–1
log(a–x)
okbfuy ,fyy bZFkj (vinyl allyl ether) dk isUV–4–bZukWy ,d fuf'pr Øe dk –2

–3
vuqlj.k djrk gSA bl izdkj dh vfHkfØ;k ds fy, fuEu vkjs[k izkIr gksrs gSA –4
–5
–6
vfHkfØ;k dh dksfV gS %
0 2 4 6 8 10
(1) 'kwU; (2) –1 (3*) 1 (4) 2 l e; ¼
feuV½
D-7. The reaction A(s)  2 B(g) + C(g) is first order. The pressure after 20 min. and after very long time are 150
mm Hg and 225 mm Hg. The value of rate constant and pressure after 40 min. are :
(1) 0.05 In 1.5 min–1 ,200 mm (2) 0.5 ln 2 min–1 ,300 mm
–1
(3) 0.05 In 3 min , 300 mm (4*) 0.05 In 3 min–1 , 200 mm
A(s)  2 B(g) + C(g) vfHkfØ;k izFke dksfV dh vfHkfØ;k gSA 20 feuV ckn vkSj dkQh yEcs le; i'pkr~ nkc Øe'k% 150
mm Hg vkSj 225 mm Hg gS vr% 40 feuV ds ckn vfHkfØ;k dk osx fu;rkad vkSj nkc gksxsa \
(1) 0.05 In 1.5 min–1 ,200 mm (2) 0.5 ln 2 min–1 ,300 mm
–1
(3) 0.05 In 3 min , 300 mm (4*) 0.05 In 3 min–1 , 200 mm
MAINCHK -8
Chemical Kinetics
Section (E) : Methods to monitor the progress of the reaction
[k.M (E) : vfHkfØ;k dh izxfr izsf{kr djus dh fof/k;k¡
E-1. Consider the reaction 2A(g)  3B(g) + C(g). Starting with pure A initially, the total pressure doubled in
3 hrs. The order of the reaction might possibly be
(1*) zero (2) first
(3) second (4) unpredictable from this data
ekuk fd vfHkfØ;k 2A(g)  3B(g) + C(g) dks izkjEHk esa 'kq) A ls izkjEHk fd;k tkrk gS, 3 ?k.Vs esa dqy nkc nqxquk gks
tkrk gS rks vfHkfØ;k dh dksfV gks ldrh gS
(1*) 'kwU; dksfV (2) izFke dksfV
(3) f}rh; dksfV (4) fn, x, vkdM+ks ds vk/kkj ij Kkr ugh fd;k tk ldrk
E-2. At 373 K, a gaseous reaction A  2B + C is found to be of first order. Starting with pure A, the total pressure
at the end of 10 min. was 176 mm and after a long time when A was completely dissociated, it was 270 mm.
The pressure of A at the end of 10 minutes was :
373 K rki ij ,d xSlh; vfHkfØ;k A  2B + C izFke dksfV dh ik;h x;hA tc vfHkfØ;k 'kq) A ls izkjEHk dh x;h FkhA
rks dqy nkc 10 feuV ds ckn 176 mm ik;k x;k Fkk vkSj ,d yEcs le; i'pkr~ tc A iw.kZ:i ls fo;ksftr gks tkrk gS
rks nkc 270 gks x;k FkkA 10 feuV ds ckn A dk nkc D;k gksxkA
(1) 94 mm (2*) 47 mm (3) 43 mm (4) 90 mm
E-3. Let there be as first-order reaction of the type, A  B + C. Let us assume that only A is geseous. We are
required to calculate the value of rate constant based on the following data.
Time 0 T 
Partial pressure of A P0 Pt –
Calculate the expression of rate constant.
1  P0  1  Pt 
 1  2P0 
 1  Pt 

(1*) k = ln  P  (2) k = ln (3) k = ln (4) k = ln
t  t  t  P0 
 t  Pt 
 t  2P0 

ekuk fd A  B + C ,d çFke dksfV çdkj vfHkfØ;k gSa] ge ekurs gSa fd rhuksa çtkfr xSlh; gSaA gesa fuEu vkWdMks ij
vk/kkfjr nj fu;rkad dk eku ifjdfyr djuk vko';d gSaA
nj fu;arkd dk O;tad Kkr dhft,A

1  P0  1  Pt 
 1  2P0 
 1  Pt 

(1*) k = ln  P  (2) k = ln (3) k = ln (4) k = ln
t  t  t  P0 
 t  Pt 
 t  2P0 

E-4. Which integrated equation is correct for the following Ist order reaction started with only A(g) in a closed rigid
vessel.
A (g)  B (g) + C (g) + D (g)
Pi = initial pressure ; Pt = total pressure at time t
fuEu izFke dksfV dh vfHkfØ;k ds fy, dkSulh lekdfyr lehdj.k lgh gS] ;fn izkjEHk esa dsoy A(g) gh cUn n`<+ ik=k (closed
rigid vessel) esa yh tkrh gSA
A (g)  B (g) + C (g) + D (g)
Pi = izkjfEHkd nkc ( Pt = le; t ij dqy nkc
MAINCHK -9
Chemical Kinetics
2.303  Pi  2.303  Pt 
(1) K = log10  P  (2) K = log10  P 
t  t t  i
2.303  2Pi  2.303  3Pi 

(3*) K = log10  3P – P  (4) K = log10  2P – 3P 
t  i t t  i t
E-5. The decompostion NH3 gas on a heated tungsten surface gave the following results :
Initial pressure (mm) 65 105 y 185
Half-life (sec) 290 x 670 820
Calculate approximately the values of x and y.
(1) x = 410 sec (2*) x = 467 sec (3) x = 490 sec (4) x = 430 sec
Å"eh; VaxLVu lrg ij NH3 xSl ds fo?kVu fuEu ifj.kke nsrs gSaA
izkjfEHkd nkc (mm) 65 105 y 185
v)Z&vk;q ¼lSd.M½ 290 x 670 820
x rFkk y dk yxHkx eku ifjdfyr dhft,A
(1) x = 410 lSd.M (2*) x = 467 lSd.M (3) x = 490 lSd.M (4) x = 430 lSd.M
E-6. In the reaction NH4NO2 (aq.)  N2 (g) + 2 H2O (l) the volume of N2 after 20 min and after a long time is 40 ml
and 70 ml respectively. The value of rate constant is :
vfHkfØ;k NH4NO2 (aq.)  N2 (g) + 2 H2O (l) esa N2 dk vk;ru 20 min ckn vkSj dkQh yEcs le; ckn vk;ru Øe'k%
40 ml vkSj 70 ml gS rks vfHkfØ;k ds osx fu;rkad dk eku gksxk
(1) (1/20) In (7/4) min–1 (2*) (2.303 /1200) log (7/3) sec–1
(3) (1/20) log (7/3) min–1 (4) (2.303 / 20) log (11/7) min–1
E-7. If no catalyst (H+) is present in acid hydrolysis of ester then rate constant K is :
;fn ,LVj ds vEyh; ty vi?kVu esa ;fn dksbZ mRizsjd (H+) mifLFkr ugha gS rks nj fu;rkad K gksxk
2 .303 V0 2 .303 V
(1) log (2*) log
t ( Vt  V ) t ( V  Vt )
2 . 303 V 2 .303 V
(3) log 0 (4) log
t Vt t ( Vt  V )
Section (F) : Effect of Temperature

[k.M (F) : rki dk izHkko
F-1. Rate of which reactions increases with temperature :
(1*) of any (2) of exothermic reactions
(3) of endothermic (4) of none.
fdu vfHkfØ;kvksa ds fy, vfHkfØ;k dh nj rkieku c<kus ij c<+rh gS :
(1*) fdlh Hkh vfHkfØ;k esa (2) Å"ek {ksih vfHkfØ;k esa
(3) Å"ek 'kks"kh vfHkfØ;k esa (4) fdlh ds fy, ugha
F-2. For a zero order reaction. Which of the following statement is false :
(1*) the rate is independent of the temperature of the reaction.
(2) the rate is independent of the concentration of the reactants.
(3) the half life depends as the concentration of the reactants.
(4) the rate constant has the unit mole It–1 sec–1.
'kwU; dksfV dh vfHkfØ;k ds fy, fuEu esa ls dkSulk dFku vlR; gSA
(1*) vfHkfØ;k ds rkieku ls vfHkfØ;k dk osx Lora=k (independent) gksrk gSA
(2) vfHkdkjd dh lkanzrk ls vfHkfØ;k dh nj Lora=k gksrh gSA
(3) vfHkdkjd dh lkanzrk ij vfHkfØ;k dk v)Zvk;qdky fuHkZj djrk gSA
(4) vfHkfØ;k nj fu;rkad dh bZdkbZ mole Lt–1 sec–1 gSA
MAINCHK - 10
Chemical Kinetics
F-3. The rate constant, the activation energy and the frequency factor of a chemical reaction at 25°C are
3.0 × 10–4 s–1, 104.4 KJ mol–1 and 6.0 × 1014 s–1 respectively. The value of the rate constant as T   is :
(1) 2.0 × 1018 s–1 (2*) 6.0 × 1014 s–1 (3)  (4) 3.6 × 1030 s–1
,d vfHkfØ;k ds fy, 25°C rki ij vfHkfØ;k nj fu;rkad] lfØ;.k ÅtkZ vkSj vko`fr dkjd Øe'k% 3.0 × 10–4 s–1, 104.4
KJ mol–1 vkSj 6.0 × 1014 s–1 gSA T   rd ds fy, vfHkfØ;k osx fu;rkad dk eku gksxk \
(1) 2.0 × 1018 s–1 (2*) 6.0 × 1014 s–1 (3) vUur (4) 3.6 × 1030 s–1
F-4. According to collision theory of reaction rates –

(1) Every collision between reactant leads to chemical reaction
(2) Rate of reaction is proportional to velocity of molecules
(3) All reactions which occur in gaseous phase are zero order reaction
(4*) Rate of reaction is directly proportional to collision frequency.
vfHkfØ;k dh nj ds fy, VDdj fl}kUr ds vuqlkj
(1) fØ;kdkjdksa ds e/; lHkh VDdj jklk;fud vfHkfØ;k djrs gSaA
(2) vfHkfØ;k dh nj v.kqvksa ds osx ds lekuqikrh gksrh gSA
(3) lHkh vfHkfØ;k,¡ tks fd xSlh; izkoLFkk esa gksrh gS 'kwU; dksfV dh vfHkfØ;k,¡ gksrh gSA
(4*) vfHkfØ;k dh nj VDdj vko`fr ds lh/ks lekuqikrh gksrh gSA
F-5. The minimum energy for molecules to enter into chemical reaction is called.
(1) Kinetic energy (2) Potential energy (3*) Threshold energy (4) Activation energy
jklk;fud vfHkfØ;k ds fy, v.kqvksa ds fy, U;qure ÅtkZ dgykrh gS
(1) xfrt ÅtkZ (2) fLFkfrt ÅtkZ (3*) nsgyh ÅtkZ (4) lfØ;.k ÅtkZ
F-6. The activation energy for the forward reaction X  Y is 60 KJ mol–1 and H is –20 KJ mol–1. The activation
energy for the backard reaction Y  X is :
(1*) 80 KJ mol–1 (2) 40 KJ mol–1 (3) 60 KJ mol–1 (4) 20 KJ mol–1
vxz vfHkfØ;k X  Y ds fy, lfØ;.k ÅtkZ 60 KJ mol–1 gS vkSj H is –20 KJ mol–1 gSA rc izrhi vfHkfØ;k Y  X
ds fy, ÅtkZ gS
(1*) 80 KJ mol–1 (2) 40 KJ mol–1 (3) 60 KJ mol–1 (4) 20 KJ mol–1
F-7. For producing the effective collisions, the colloiding molecules must posses :
(1) A certain minimum amount of energy (2) Energy equal to or greater than threshold energy
(3) Proper orientation (4*) Threshold energy as well as proper orientation of collision.
izHkkoh VDdj ds fy,] Vdjkus okys v.kqvksa esa gksuk vko';d gS
(1) ,d fufpr U;wure ÅtkZ (2) nsgyh ÅtkZ ds cjkcj ;k T;knk ÅtkZ
(3) lgh vfHkfoU;kl (4*) nsgyh ÅtkZ lkFk gh lkFk VDdj dk lgh vfHkfoU;kl
F-8. For the first order reaction, X(s)  X(g)

the monitoring is done by observing the volume :
time t 
volume Vt V
The rate constant is given by :
1  V  1  V  1  V  Vt  1  V  Vt 
(1) ln  V 
 (2*) ln  V  V 
 (3) ln  V 
 (4) ln  V  V 
t  t  t   t  t    t   t 
MAINCHK - 11
Chemical Kinetics
izFke dksfV dh vfHkfØ;k, X(s)  X(g)
ds fy, lapkyu vk;ru voyksdu }kjk fd;k x;k %
l e; t 
v k; r u Vt V
osx fu;rkad gS %
1  V  1  V  1  V  Vt  1  V  Vt 
(1) ln  V 
 (2*) ln  V  V 
 (3) ln  V 
 (4) ln  V  V 
t  t  t   t  t    t   t 
F-9. The first order rate constant k is related to temp. as log k = 15.0 – (106 /T) Which of the following pair of value
is correct ?
(1*) A = 1015 and E = 1.9 × 104 KJ (2) A = 10–15 and E = 40 KJ
15
(3) A = 10 and E = 40 KJ (4) A = 10–15 and E = 1.9 × 104 KJ.
izFke dksfV dh vfHkfØ;k dk nj fu;rkad k rkieku ls fuEu izdkj log k = 15.0 – (106 /T) ls lacaf/kr gS rks dkSu ls ekuksa
dk ;qXe lgh gS ?
(1*) A = 1015 rFkk E = 1.9 × 104 KJ (2) A = 10–15 rFkk E = 40 KJ
(3) A = 1015 rFkk E = 40 KJ (4) A = 10–15 rFkk E = 1.9 × 104 KJ.
F-10. For a given reaction, energy of activation for forward reaction (Eaf) is 80kJ.mol1. H = 40kJ.mol1 for the
reaction. A catalyst lowers Eaf to 20 kJ.mol1. The ratio of energy of activation for reverse reaction before and
after addition of catalyst is :
(1) 1.0 (2) 0.5 (3) 1.2 (4*)2.0
,d nh xbZ vfHkfØ;k esa vxz vfHkfØ;k ds fy, lfØ;.k ÅtkZ (Eaf) 80 fdyks twy eksy1 gSA vfHkfØ;k ds fy, H = 40
fdyks twy eksy1 gS ,d mRizsjd lfØ;rk ÅtkZ Eaf dks 20 fdyks twy eksy1 rd de dj nsrk gS izrhi vfHkfØ;k ds fy,
mRizsjd ds igys rFkk mRizsjd dks feykus ds ckn lfØ;.k ÅtkZ dk vuqikr Kkr djksA
(1) 1.0 (2) 0.5 (3) 1.2 (4*)2.0
Section (G) : Mechanism of reactions

Hkkx (G) : vfHkfØ;k dh fØ;kfo/kh
G-1. For the reaction H2 (g) + Br2 (g)  2HBr (g) the experiment data suggested that r = k[H2][Br2]1/2
The molecularity and order of the reaction are respectively :
(1) 2, 3/ 2 (2) 3/2 , 3/2 (3*) Not defined, 3/2 (4) 1,1/2
vfHkfØ;k H2 (g) + Br2 (g)  2HBr (g) ds fy, izk;ksfxd vkdM+s r = k[H2][Br2]1/2
fn, x, gS vfHkfØ;k ds fy, Øe'k% v.kqla[;rk vkSj vfHkfØ;k dh dksfV Kkr djks \
(1) 2, 3/ 2 (2) 3/2 , 3/2 (3*) iznf'kZr ugha fd;k tk ldrk, 3/2 (4) 1,1/2
G-2. The reaction of hydrogen, and iodine monochloride is represented by the equation :
H2(g) + 2Cl(g) 2HCl(g) + 2(g)
This reaction is first–order in H2(g) and also first–order in Cl(g). Which of these proposed mechanism
can be consistent with the given information about this reaction ?
Mechanism  : H2(g) + 2Cl(g) 2HCl(g) + 2(g)
Slow
Mechanism  : H2(g) + Cl(g)   HCl(g) + H(g)
fast
HI(g) + Cl(g)   HCl(g) + I2(g)
(1)  only (2*)  only (3) both  and  (4) neither  nor 
MAINCHK - 12
Chemical Kinetics
gkbMªkstu vkSj vk;ksMhu eksuks DyksjkbZM ds e/; fØ;k dks fuEu vfHkfØ;k }kjk iznf'kZr fd;k tkrk gSA
H2(g) + 2Cl(g) 2HCl(g) + 2(g)
;g vfHkfØ;k H2(g) ds fy, izFke dksfV vkSj Cl(g) ds fy, Hkh izFke dksfV dh vfHkfØ;k gSA fuEu esa ls dkSulh
fØ;kfo/kh mijksDr rF; ds vk/kkj ij nh tk ldrh gS
fØ;kfo/kh  : H2(g) + 2Cl(g) 2HCl(g) + 2(g)
fØ;kfo/kh  : H2(g) + Cl(g) /khek
 HCl(g) + H(g)
r
HI(g) + Cl(g) hoz HCl(g) + I2(g)
(1) dsoy  (2*) dsoy  (3)  vkSj nksuksa gh (4) u rks  vkSj uk gh 
G-3. The slowest step of a particualr reaction is found to be

1/2X2 + Y2  XY2. The order of the reaction is
fdlh fuf'pr vfHkfØ;k dk /khek in fuEu gS
1/2X2 + Y2  XY2
vfHkfØ;k dh dksfV gS
(1) 2 (2) 3 (3) 3.5 (4*) 1.5
G-4. For an elementary process 2X + Y  Z + W, the molecularity is :
(1) 2 (2) 1 (3*) 3 (4) Unpredictable
,d izk:ihd izØe 2X + Y  Z + W, ds fy, v.kqla[;drk gS %
(1) 2 (2) 1 (3*) 3 (4) Kkr ugha dj ldrs gSaA
G-5. For the reaction 2NO + Cl2  2NOCl the following mechanism has been proposed
NO + Cl2 NOCl2 (fast)
NOCl2 + NO  2NOCl (slow) the rate low for the reaction is :
(1*) Rate = K[NO]2[Cl2] (2) Rate = K[NO][Cl2]2 (3) Rate = K[NOCl2] (4) Rate = K[NOCl]2
vfHkfØ;k 2NO + Cl2  2NOCl ds fy, fuEu fØ;kfof/k nh tkrh gSA
NO + Cl2 NOCl2 (rhoz)
NOCl2 + NO  2NOCl (/khek) vfHkfØ;k ds fy, nj fu;e gS %
(1*) nj = K[NO]2[Cl2] (2) nj = K[NO][Cl2]2 (3) nj = K[NOCl2] (4) nj = K[NOCl]2
Section (H) : Complications in first order reactions

[k.M (H) : izFke dksfV dh vfHkfØ;kvksa esa tfVyrk,¡
H-1. The substance undergoes first order decomposition. The decomposition follows two parallel first order reactions
as :
K1 = 1.26 × 10–4 sec–1 and K2 = 3.8 × 10–5 sec–1
The percentage distribution of B and C

(1) 80% B and 20% C (2*) 76.83% B and 23.17%C
(3) 90% B and 10% C (4) 60% B and 40% C
,d inkFkZ izFke dksfV dh fo;kstu vfHkfØ;k nsrk gSA ;g fo;kstu nks lekUrj izFke dksfV dh vfHkfØ;k }kjk gksrk gSA
K1 = 1.26 × 10–4 sec–1 rFkk K2 = 3.8 × 10–5 sec–1
B vkSj C dh izfr'krrk gksxhA

(1) 80% B vkSj 20% C (2*) 76.83% B vkSj 23.17%C
(3) 90% B vkSj 10% C (4) 60% B vkSj 40% C
MAINCHK - 13
Chemical Kinetics
PART - I : OBJECTIVE QUESTIONS

Hkkx -I: oLrqfu"B iz'u ¼OBJECTIVE QUESTIONS½
1. A drop of solution (volume 0.05 mL) contains 3.0 × 10–6 moles of H+. If the rate contant of disappearance of
H+ is 1.0 × 107 mole litre–1 sec–1. How long would it take for H+ in drop to disappear :
(1) 6 × 10–8 sec (2) 6 × 10–7 sec (3*) 6 × 10–9 sec (4) 6 × 10–10 sec
–6 + +
foy;u dh ,d cw¡n (vk;ru 0.05 mL) esa 3.0 × 10 eksy H vk;u gSA ;fn H vk;u ds foyqIr gksus ds fy, osx fu;rkad
1.0 × 107 mole litre–1 sec–1 gS rks H+ dh cw¡n ds fy, foyqIr gksus esa yxk le; gksxk :
(1) 6 × 10–8 sec (2) 6 × 10–7 sec (3*) 6 × 10–9 sec (4) 6 × 10–10 sec
2.  / Cu
–N2Cl  –Cl + N2 Half-life is independent of concentration of reactant. After 10 minutes
 
volume of N2 gas is 10 L and after complete reaction it is 50 L. Hence rate constant is:
(1) (2.303 /10) log 5 min–1 (2*) (2.303 /10) log 1.25 min–1
(3) (2.303 /10) log 2 min–1 (4) (2.303 /10) log 4 min–1
 / Cu
–N2Cl  –Cl + N2 dk v)Zvk;qdky vfHkdkjd dh lkUnzrk ij fuHkZj ugha ¼Lora=k½ djrk
vfHkfØ;k  
gS 10 feuV i'pkr~ N2 xSl dk vk;ru 10 L vkSj vfHkfØ;k lekIr gksus ij ;g 50 L gks tkrk gS vr% vfHkfØ;k dk osx
fu;rkad ¼fLFkjkad½ gksxkA
(1) (2.303 /10) log 5 min–1 (2*) (2.303 /10) log 1.25 min–1
(3) (2.303 /10) log 2 min–1 (4) (2.303 /10) log 4 min–1
3. If concentration of reactants is increased by a factor x then the rate constant k becomes :
;fn fØ;kdkjdksa dh lkUnzrk x ls c<+k nh tk, rks nj fu;rkad k gks tk,xk :
k k
(1) In (2) (3) k + x (4*) k
x x
4. The rate constant for a reaction is 10.8  10–5 mol L–1 S–1 The reaction obeys :
(1) First order (2*) Zero order (3) Second order (4) All are wrong
–5 –1 –1
,d vfHkfØ;k ds fy, nj fu;rkad 10.8  10 mol L S gS vfHkfØ;k ikyu djrh gS %
(1) izFke dksfV dk (2*) 'kwU; dksfV dk (3) f}rh; dksfV dk (4) lHkh xyr gSA
5. For the irreversible process, A + B  products, the rate is first–order w.r.t. A and second–order w.r.t. B.If
1.0 mol each of A and B introduced into a 1.0 L vessel, and the initial rate was 1.0 × 10–2 mol L–1 s–1 , rate
when half reactants have been turned into products is :
,d vuqRØe.kh; izfØ;k A + B  mRiknksa, ds fy, vfHkfØ;k dh dksfV A ds lkis{k izFke dksfV dh vfHkfØ;k gS vkSj B
ds lkis{k f}rh; dksfV dh gS ;fn A vkSj B izR;sd ds 1.0 eksy] 1.0 yhVj dh ufydk esa Mkys tkrs gSa vkSj izkjfEHkd nj
1.0 × 10–2 mol L–1 s–1 FkhA tc vk/ks vfHkdkjd mRikn esa ifjofrZr gks tkrs gS rks osx D;k gksxk
(1*) 1.25 × 10–3 mol L–1 s–1 (2) 1.0 × 10–2 mol L–1 s–1
(3) 2.50 × 10–3 mol L–1 s–1 (4) 2.0 × 10–2 mol L–1 s–1
6. A certain zero order reaction has k = 0.025 M s–1 for the disappearance of A. What will be the concentration
of A after 15 seconds if the initial concentration is 0.50 M ?
fdlh 'kwU; dksfV dh vfHkfØ;k A ds foyqIr gksus ds fy, k = 0.025 M s–1 gS ;fn izkjfEHkd lkUnzrk 0.50 M gS rks 15 lSd.M
i'pkr~ A dh lkUnzrk D;k gksxhA
(1) 0.50 M (2) 0.375 M (3*) 0.125 M (4) 0.060 M
MAINCHK - 14
Chemical Kinetics
7. The rate law for the single step reaction 2A + B  2C, is given by
(1) Rate = K [A][B] (2*) Rate = K [A]2[B] (3) Rate = K [2A][B] (4) Rate = K[A]2[B]0
,d inh; vfHkfØ;k 2A + B  2C ds fy, nj fu;e fn;k tk ldrk gSA
(1) nj = K [A][B] (2*) nj = K [A]2[B] (3) nj = K [2A][B] (4) nj = K[A]2[B]0
8. A graph plotted between log t50% vs. log concentration is a straight line. What conclusion can you draw from
this graph.
(1) n = 1 ; t1/2  a (2) n = 2, t1/2  1/a

(3*) n = 1 ; t1/2 = (0.693 / k) (4) None of these
log t50% vkSj log lkUnzrk ds e/; xzkQ [khapus ij ,d lh/kh js[kk izkIr gksrh gS rks xzkQ ls vki D;k fu"d"kZ fudkyrs gS \
(1) n = 1 ; t1/2  a (2) n = 2, t1/2  1/a

(3*) n = 1 ; t1/2 = (0.693 / k) (4) buesa ls dksbZ ugh
9. In a first order reaction the concentration of the reactant is decreased from 1.0 M to 0.25 M in 20 min. The
rate constant of the reaction would be –
,d izFke dksfV dh vfHkfØ;k esa 20 min esa fØ;kdkjd dh lkUnzrk esa 1.0 M ls 0.25 M rd dh deh gksrh gSA vfHkfØ;k
dk nj fu;rkad gksxkA
(1) 10 min–1 (2) 6.931 min–1 (3) 0.6931 min–`1 (4*) 0.06931 min–1
10. What will be the order of reaction and rate constant for a chemical change having log t50% vs log concentration
of (A) curves as :
,d jklk;fud ifjorZu esa log t50% vkSj log (A dh lkUnzrk) ds e/; fuEu xzkQ izkIr gksrk gS rks vfHkfØ;k dksfV vkSj vfHkfØ;k
dk osx fu;rkad D;k gksxk :
(1*) 0, 1/2 (2) 1, 1 (3) 2, 2 (4) 3, 1

11. In the first order reaction 75% of the reactant disappeared in 1.388 hrs. Calculate the rate constant of the
reaction :
(1) 1 s–1 (2*) 2.8  10–4 s–1 (3) 17.2  10–3 s–1 (4) 1.8  10–3 s–1
izFke dksfV dh vfHkfØ;k eas 75% fØ;kdkjd 1.388 hrs. esa foyqIr gksrk gSA vfHkfØ;k dk nj fu;rkad Kkr dhft,A
(1) 1 s–1 (2*) 2.8  10–4 s–1 (3) 17.2  10–3 s–1 (4) 1.8  10–3 s–1
12. The kinetic data for the given reaction A(g) + 2B(g) 
 C(g) is provided in the following table for three
experiments at 300 K.
Ex. No. [A/M] [B/M] [Initial rate (M sec–1)]

1 0.01 0.01 6.930 × 10–6
2 0.02 0.01 1.386 ×10–5
3 0.02 0.02 1.386 ×10–5
MAINCHK - 15
Chemical Kinetics
In another experiment starting with intitial concentration of 0.5 and 1 M respectively for A and B at 300 K. Find
the rate of reaction after 50 minutes from start of experiment (in m/sec)?
(1) 6.93 × 10–4 (2) 0.25 × 10–7 (3*) 4.33 × 10–5 (4) 3.46 × 10–9
nhxbZ vfHkfØ;k A(g) + 2B(g)  C(g) ds fy, 300 K ij rhu iz;ksx ds fy, fuEu lkj.kh esa xfrdh vkdaMs fuEu lkj.kh
vuqlkj fn, x;s gS
i z;ksx Øeka
d [A/M] [B/M] [i z
kj a
fHkd nj (M sec–1)]
1 0.01 0.01 6.930 × 10–6
2 0.02 0.01 1.386 ×10–5
3 0.02 0.02 1.386 ×10–5
,d vU; iz;ksx 300 K ij A rFkk B dh izkjfEHkd lkUnzrk Øe'k% 0.5 rFkk 1 M ls vkjEHk djrs gq, 50 feuV i'pkr vfHkfØ;k
dh nj (m/sec esa) Kkr dhft, ?
(1) 6.93 × 10–4 (2) 0.25 × 10–7 (3*) 4.33 × 10–5 (4) 3.46 × 10–9
13. For a hypothetical elementary reaction.
K1 1
where =
K2 2
Initially only 2 moles of A are present. The total number of moles of A, B and C at the end of 75% of reaction
are:
,d dkYifud izk:ihd vfHkfØ;k ds fy,
K1 1
tgkW K =
2 2
izkjEHk esa A ds 2 eksy mifLFkr gS 75% vfHkfØ;k dh lekIrh ij A, B rFkk C ds eksyks dh la[;k gS %
(1) 2 (2) 3 (3) 4 (4*) 3.5
14. Formation of NO2F from NO2 and F2 as per the reaction 2NO2(g) + F2(g)  2NO2F(g) is a second order
reaction, first order with respect to NO2 and first order with respect to F2. If NO2 and F2 are present in a
closed vessel in ratio 2 :1 maintained at a constant temperature with an initial total pressure of 3 atm, what
will be the total pressure in the vessel after the reaction is complete?
(1) 1atm (2*) 2 atm (3) 2.5 atm (4) 3 atm
NO2 rFkk F2 ls NO2F dk cuuk fuEu vfHkfØ;k ds }kjk 2NO2(g) + F2(g)  2NO2F(g) gS] ;g ,d f}rh; dksfV
vfHkfØ;k gSA NO2 ds lkis{k izFke dksfV rFkk F2 ds lkis{k izFke dksfV vfHkfØ;k gSA ;fn NO2 rFkk F2 ,d cUn tkj esa fu;r
rki ij izkjfEHkd dqy nkc 3 ok;qe.My ds lkFk 2 :1 vuqikr esa mifLFkr gksrs gS rks vfHkfØ;k iw.kZ gksus ds ckn ik=k ds vUnj
dqy nkc D;k gksxkA
(1) 1ok;qe.Myh; (2*) 2 ok;qe.Myh; (3) 2.5 ok;qe.Myh; (4) 3 ok;qe.Myh;
15. Catalyst increases the rate of reaction because :

(1) it decreases H (2) it increases H
(3*) it decreases activation energy (4) it increases activation energy
mRizsjd vfHkfØ;k dk osx c<+k nsrk gS D;ksafd %
(1) ;g H dks ?kVkrk gSA (2) ;g H dks c<+krk gSA
(3*) ;g mRizsj.k ÅtkZ ?kVkrk gSA (4) ;g mRizsj.k ÅtkZ c<+krk gSA
MAINCHK - 16
Chemical Kinetics
16. The rate constant K1 of a reaction is found to be double that of rate constant K2 of another reaction. The
relationship between corresponding activation energies of the two reactions at same temperature (E1 and E2)
can be represented as :
(1) E1 > E2 (2) E1 < E2 (3) E1 = E2 (4*) None of these
,d vfHkfØ;k dk osx fu;rkad K1 ,d vU; vfHkfØ;k ds osx fu;rkad K2 dh rqyuk esa nksxquk ik;k x;kA rc leku rki ij
nksuks vfHkfØ;kvksa ls lEcfU/kr lafØ;.k ÅtkZvksa esa lEcU/k dks fuEu izdkj iznf'kZr fd;k tk ldrk gS %
(E1 rFkk E2)
(1) E1 > E2 (2) E1 < E2 (3) E1 = E2 (4*) buesa ls dksbZ ugha
17. When a graph between log K and 1/T is drawn a straight line is obtained. The point at which line cuts y -axis
and x -axis respectively correspond to the temp :
tc ,d xzkQ log K vkSj 1/T ds e/; vkjsf[kr fd;k tkrk gS rks ,d lh/kh js[kk izkIr gksrh gS og fcUnq ftl ij js[kk y v{k
o x v{k ij dkVrh gSA ls lEcfU/kr rki D;k gksxk \
(1) 0, Ea / 2.303 R log A (2*) , Ea / (R ln A)
(3) 0, log A (4) None of these.buesa ls dksbZ ugha
18. For a reaction A  B, Ea = 10 kJ mol–1 , H = 5 kJ mol–1 . Thus, potential energy profile for this reaction is :
(1) (2*)
(3) (4)
vfHkfØ;k A  B ds fy,] Ea = 10 kJ mol–1, H = 5 kJ mol–1 . bl izdkj bl vfHkfØ;k ds fy, fLFkfrt ÅtkZ vkjs[k gSA
(1) (2*)
(3) (4)
MAINCHK - 17
Chemical Kinetics
19. For a reaction following nth order kinetics, the half life (t1/2) would depend upon the initial concentration (1) as:
(1*) t1/2  a1n (2) t1/2  an1 (3) t1/2  an (4) t1/2  an
th
,d vfHkfØ;k tks n dk vuqlj.k djrh gS] mlds fy, v)Z vk;q (t1/2) izkjfEHkd lkUnzrk (1) ij bl izdkj fuHkZj djrh gS:
(1*) t1/2  a1n (2) t1/2  an1 (3) t1/2  an (4) t1/2  an
20. The Ea of a reaction in presence of a catalyst is 4.15 kJ mol–1 and in absence of a catalyst is 8.3 kJ mol–1.
1
What is slope of the plot of lnk vs in the absence of catalyst
T
mRizsjd dh mifLFkfr esa vfHkfØ;k ds Ea dk eku 4.15 kJ mol–1 rFkk mRizsjd dh vuqifLFkfr esa 8.3 kJ mol–1 gSA mRizsjd
1
dh vuqifLFkfr esa lnk vs ds vkjs[k dk <ky D;k gksxk \
T
(1) + 1 (2) –1 (3) + 1000 (4*) –1000
21. For the decomposition of H the following logarithmic plot is shown : [R = 1.98 cal/mol-K]
1
0
logk
–1
–2
–3
1.2 1.3 1.4 1.5 1.6
3
10 /T
The activation energy of the reaction is about

H ds fo;kstu ds fy;s fuEu y?kqxq.kd vkjs[k fn;k gS [R = 1.98 cal/mol-K]
1
0
logk
–1
–2
–3
1.2 1.3 1.4 1.5 1.6
3
10 /T
vfHkfØ;k dh lfØ;.k ÅtkZ gksxh %

(1*) 45600 cal (2) 13500 cal (3) 24600 cal (4) 32300 cal
22. Trimolecular reactions are uncommon because
(1*) the probability of three molecules colliding at an instant is very low.
(2) the probability of three molecules colliding at an instant is high.
(3) the probability of three molecules colliding at an instant is zero.
(4) the probability of many molecules colliding at an instant is high.
f=kvkf.od vfHkfØ;k vlkekU; gSa D;ksafd
(1*) vpkud rhu v.kqvksa ds Vdjkus dh izkf;drk cgqr de gksrh gSA
(2) vpkud rhu v.kqvksa ds Vdjkus dh izkf;drk mPp gksrh gSA
(3) vpkud rhu v.kqvksa ds Vdjkus dh izkf;drk 'kwU; gksrh gSA
(4) vpkud vf/kd v.kqvksa ds Vdjkus dh izkf;drk mPp gksrh gSA
MAINCHK - 18
Chemical Kinetics
23. A hypothetical reaction X2 + Y2  2XY follows the mechanism given below..
X2 X + X [Fast]
X + Y2  XY + Y [Slow]
X + Y  XY [Fast]
The order of overall reaction is
,d dkYifud vfHkfØ;k X2 + Y2  2XY fuEu fØ;kfof/k dk vuqlj.k djrh gSA

X2 X + X [rhoz in]
X + Y2  XY + Y [/khek in]
X + Y  XY [rhoz in]

rc lEiw.kZ vfHkfØ;k fd dksfV gSA
(1) 2 (2) 1 (3*) 1.5 (4) Zero 'kwU;
24. Radioactivity is affected by :
(1) temperature (2) Pressure (3) electric and magnetic field (4*) none of these
jsfM;kslfØ;rk fdlls çHkkfor gks ldrh gS %
(1) rki (2) nkc (3) fo|qr rFkk pqEcdh; {ks=k (4*) buesa ls dksbZ ugha
25. Half life period of 10 gm radioactive element is 20 days. Then half life period of 100 gm of this element is :
(1*) 20 days (2) 200 days (3) 100 days (4) 10 days
10 gm jsfM;kslfØ; rRo dh v)Z&vk;q 20 fnu gS] rks bl rRo ds 100 gm dh v)Z&vk;q gksxh %
(1*) 20 fnu (2) 200 fnu (3) 100 fnu (4) 10 fnu
26. A radioactive element has a half life of one day. After three days the amount of the element left will be :
(1) 1/2 of the original amount (2) 1/4 of the original amount
(3*) 1/8 of the original amount (4) 1/16 of the original amount
,d jsfZM;ks,fDVo rÙo dh v)Z&vk;q ,d fnu gSA rhu fnu ds i'pkr~ ml rRo dh 'ks"k ek=kk ewy ek=kk dh gksxh
(1) 1/2 (2) 1/4 (3*) 1/8 (4) 1/16
27. The activity per ml of a solution of radioactive substance is x. How much water be added to 200 ml of this
solution so that the acitivity falls to x/20 per ml after 4 half-lives ?
jsfM;ks ,fDVo inkFkZ ds foy;u dh çfr feyh lafØ;rk x gSaA 200 feyh bl foy;u esa fdruk ty dks feyk;s fd 4 v)Z vk;q
i'pkr~ lfØ;rk fxjdj x/20 çfr feyh jg tk,A
(1) 100 ml (2) 150 ml (3) 80 ml (4*) 50 ml.
PART - II : ASSERTION / REASONING

Hkkx - II : vfHkdFku@rdZ (ASSERTION/REASONING)
DIRECTIONS :
Each question has 5 choices (1), (2), (3), (4) and (5) out of which ONLY ONE is correct.
(1) Assertion is True, Reason is True; Reason is a correct explanation for Assertion.
(2) Assertion is True, Reason is True; Reason is NOT a correct explanation for Assertion.
(3) Assertion is True, Reason is False.
(4) Assertion is False, Reason is True.
(5) Both Statements are False.
funs Z ' k% izR;sd iz'u ds 5 fodYi gS A (1), (2), (3), (4) rFkk (5) gS ] ftuesa ls flQZ ,d lgh gS A
(1) vfHkdFku vkSj rdZ nksuksa lgh gSa vkSj rdZ] vfHkdFku dk lgh Li"Vhdj.k gSA
(2) vfHkdFku vkSj rdZ nksuksa lgh gSa vkSj rdZ] vfHkdFku dk lgh Li"Vhdj.k ugha gSA
(3) vfHkdFku lgh gS] rdZ xyr gSA
(4) vfHkdFku xyr gS] rdZ lgh gSA
(5) vfHkdFku o rdZ nksuksa xyr gSaA
MAINCHK - 19
Chemical Kinetics
1. Assertion : The rate of reaction whether exotherimic or endothermic, increase with temperature.
Reason : The rate reaction = K [reactant]n and K increases with temperature.
vfHkdFku : vfHkfØ;k dh nj pkgs og Å"ek{ksih gksa vFkok Å"ek'kks"kh rkieku ds lkFk o`f) gksrh gSA
rdZ : nj vfHkfØ;k = K [vfHkdkjd]n rFkk rkieku esa o`f) ds lkFk K esa o`f) gksrh gSA
Ans (1)
2. Assertion : A catalyst always lower the energy of activation.
Reason : The catalyst-reactant interaction forms activated adsorbed complex and adsorption is always
exothermic.
vfHkdFku : ,d mRizsjd ges'kk lfØ;.k dh ÅtkZ dks de djrk gSA
rdZ : mRizsjd&vfHkdkjd vUrj fØ;k lfØ;.k vf/k'kksf"kr ladqy cukrk gS rFkk vf/k'kks"k.k ges'kk Å"ek{ksih gksrk gSA
Ans (1)
3. Assertion : The catalyst does not affect the heat of reaction.
Reason : It increases the rate of reaction.
vfHkdFku : mRizsjd] vfHkfØ;k dh Å"ek dks izHkkfor ugha djrk gSA
rdZ : ;g vfHkfØ;k dh nj c<+krk gSA
Ans (2)
4. Assertion : The elementary reaction is single step reaction and does not possess mechanism.
Reason : An elementary reaction has order of reaction and molecularity same.
vfHkdFku : izkFkfed vfHkfØ;k,a ,dy pj.k dh vfHkfØ;k gS rFkk fØ;kfof/k ugha crkrh gSA
rdZ : ,d izkFkfed vfHkfØ;k dh dksfV o vkf.odrk leku j[krh gSA
Ans (1)
5. Assertion : For the reaction 2O3 3O2 ,the rate = K[O3]2 [O2]–1
Reason : The reaction has –ve order for O2.
vfHkdFku : vfHkfØ;k 2O3 3O2 , ds fy,] nj = K[O3]2 [O2]–1
rdZ : O2 ds fy, vfHkfØ;k –ve dksfV j[krh gSA
Ans (2)
6. Assertion : Order of reaction can never be fractional for an elementary reaction.
Reason : An elementary reaction takes place by one step mechanism.
vfHkdFku : ,d izkFkfed vfHkfØ;k ds fy, vfHkfØ;k dh dksfV dHkh Hkh fHkUukad ugha gks ldrh gSA
rdZ : ,dinh; fØ;k fof/k }kjk ,d izkFkfed vfHkfØ;k dks fy;k tkrk gSA
Ans (1)
7. Assertion : Every collision between molecules does not lead to a chemical reaction.
Reason : Only those molecules reacts during collisions which acquire threshold energy level.
vfHkdFkuu : v.kqvksa ds chp izR;sd VDdj ,d jklk;fud vfHkfØ;k dks iznf'kZr ugha djrh gSA
rdZ : VDdj ds nkSjku dsoy og v.kq VDdj djrs gSa tks nsgyh ÅtkZ Lrj j[krs gSaA
Ans (1)
PART - I : JEE (MAIN) / AIEEE PROBLEMS (PREVIOUS YEARS)
Hkkx - I : JEE (MAIN) / AIEEE ds iz'u ¼fiNys o"kksZ½

1. A reaction involving two different reactants can never be : [AIEEE- 2005, 3/225]
(1*) unimolecular reaction (2) first order reaction
(3) second order reaction (4) bimolecular reaction
MAINCHK - 20
Chemical Kinetics
,d vfHkfØ;k ftleas nks fofHkUu vfHkdkjd Hkkx ysrs gS ugha gks ldrhA [AIEEE- 2005, 3/225]
(1*) ,d vkf.od vfHkfØ;k (2) izFke dksfV vfHkfØ;k (3) f}rh; dksfV vfHkfØ;k (4) f}vkf.od vfHkfØ;k
2. A reaction was found to be second order with respect to the concentration of carbon monoxide. If the
concentration of carbon monoxide is doubled, with everything else kept the same, the rate of reaction will be
[AIEEE- 2006, 3/165]
(1) remain unchanged (2) tripled
(3*) increased by a factor of 4 (4) doubled
dkcZu eksuksvkWDlkbM dh lkUnzrk ds lkis{k ,d vfHkfØ;k f}rh; dksfV dh ik;h x;hA ;fn vU; lHkh dks ogh j[kk tk, vkSj
dkcZu eksuksvkWDlkbM dh lkUnzrk nqxquh dj nh tk,] rks vfHkfØ;k dh nj % [AIEEE- 2006, 3/165]
(1) vifjofrZr jgrh gSA (2) frxquh gks tkrh gSA
(3*) pkj xquk c<+ tkrh gSA (4) nqxquh gks tkrh gSA
3. The following mechanism has been proposed for the reaction of NO with Br2 to form NOBr.
NO (g) + Br2 (g) NOBr2 (g) ; NOBr2 (g) + NO (g)  2NOBr (g) (slow step)
If the second step is the rate determining step, the order of the reaction with respect to NO(g) is
[AIEEE- 2007, 3/120]
NO dh Br2 ds lkFk vfHkfØ;k ls mRikn NOBr cukus dh vfHkfØ;k fUkEu nh xbZ gS
NO (g) + Br2 (g) NOBr2 (g) ; NOBr2 (g) + NO (g)  2NOBr (g) (/khek in)
;fn f}rh; in vfHkfØ;k fu/kkZj.k in gS rc NO (g) ds lUnHkZ esa vfHkfØ;k fdl dksfV dh gksxhA[AIEEE- 2007, 3/120]
(1) 1 (2) 0 (3) 3 (4*) 2
4. The energies of activation for forward and reverse reactions for A2 + B2 2AB are 180 kJ mol–1 and 200
–1
kJ mol respectively. The presence of a catalyst lowers the activation energy of both (forward and reverse)
reactions by 100 kJ mol–1. The enthalpy change of the reaction (A2 + B2 2AB) in the presence of catalyst
will be (in kJ mol–1). [AIEEE- 2007, 3/120]
,d vfHkfØ;k A2 + B2 2AB ds fy, vxz o foijhr vfHkfØ;k ds fy, lfØ;.k ÅtkZ Øe'k% 180 fdyks twy@eksy
rFkk 200 fdyks twy@eksy gSA ,d mRizsjd dh mifLFkfr nksuksa] (vxz o foijhr) vfHkfØ;kvksa dh lfØ;.k ÅtkZ dks 100
fdykstwy@eksy de dj nsrh gSA mRizsjd dh mifLFkfr esa vfHkfØ;k (A2 + B2 2AB) dh ,UFkSYih ifjorZu gksxh
(fdykstwy@eksy es)a [AIEEE- 2007, 3/120]
(1) 280 (2*) 20 (3) 300 (4) 120
5. A radioactive element gets spilled over the floor of a room. Its half-life period is 30days. If the initial activity is
ten times the permissible value, after how many days will it be safe to enter the room :
[AIEEE- 2007, 3/120]
(1) 10 days (2*) 100 days (3) 1000 days (4) 300 days
,d jsfM;ks/kehZ inkFkZ dejs ds Q'kZ ij QSy x;k] bldh v)Z&vk;q dky 30 fnu gSA ;fn bldk izkjfEHkd lfØ;rk mi;qDr
eku dh nl xquh gS rks fdrus fnu ckn dejs esa tkuk lqjf{kr gksxk % [AIEEE- 2007, 3/120]
(1) 10 fnu (2*) 100 fnu (3) 1000 fnu (4) 300 fnu
1
6. For a reaction A  2B, rate of disappearance of 'A' related to the rate of appearance of 'B' by the
2
expression. [AIEEE- 2008, 3/105]
1
vfHkfØ;k A  2B ds fy,] ‘A’’ ds foyksiu dh nj vkSj ‘B’ ds izdVu dh nj ls lEcU/k dks fuEu esa ls fdl O;atd
2
}kjk O;Dr fd;k tkrk gSA [AIEEE- 2008, 3/105]
d [ A ] 1 d [B] d [ A ] d [B] d[A] d [B] d [ A ] 1 d [B]
(1*)   (2)   (3)  4 (4)  
dt 4 dt dt dt dt dt dt 2 dt
MAINCHK - 21
Chemical Kinetics
7.  The half life period of a first order chemical reaction is 6.93 minutes. Time required for the completion of 99%
of the chemical reaction will be (log 2 = 0.301) : [AIEEE - 2009, 8/144]
(1) 23.03 minutes (2*) 46.06 minutes (3) 460.6 minutes (4) 230.3 minutes
,d izFke dksfV dh jlk;fud vfHkfØ;k dh v)Z vk;q 6.93 feuV gSA vfHkfØ;k dks 99% iw.kZ gksus esa yxk gqvk le; gksxk
(log 2 = 0.301) : [AIEEE - 2009, 8/144]
(1) 23.03 feuV (2*) 46.06 feuV (3) 460.6 feuV (4) 230.3 feuV
8. The time for half life period of a certain reaction A  Products is 1 hour. When the initial concentration
of the reactant ‘A’, is 2.0 mol L–1 , how much time does it take for its concentration to come from 0.50 to 0.25
mol L–1. If it is a zero order reaction? [AIEEE - 2010, 8/144]
(1) 4 h (2) 0.5 h (3*) 0.25 h (4) 1 h
,d vfHkfØ;k A  mRikn dh v/kZ&vk;q ds fy, le; 1 ?k.Vk gSA tc vfHkdkjd ‘A’ dk izkjafHkd lkUnz.k
2.0 mol L–1 gks] rks blds lkUnz.k dks 0.50 ls 0.25 mol L–1 vkus esa fdruk le; yxsxk] ;fn ;g vfHkfØ;k 'kwU; dksfV dh
gS \ [AIEEE - 2010, 8/144]
(1) 4 ?k.Vs (2) 0.5 ?k.Vk (3*) 0.25 ?k.Vk (4) 1 ?k.Vk
9. Consider the reaction [AIEEE - 2010, 4/144]

Cl2 (aq) + H2S(aq)  S(s) + 2H+ (aq) + 2Cl– (aq)
The rate equation for this reaction is
rate = k [Cl2][H2S]
Which of these mechanisms is/are consistent with this rate equation?
A. Cl2 + H2S  H+ + Cl– + Cl+ + HS– (slow)
Cl+ + HS–  H+ + Cl– + S (fast)
B. H2S  H+ + HS– (fast equilibrium)
Cl2 + HS–  2Cl– + H+ + S (slow)
(1) B only (2) Both A and B (3) Neither A nor B (4*) A only
fuEufyf[kr vfHkfØ;k ij fopkj dhft, % [AIEEE - 2010, 4/144]

Cl2 (aq) + H2S(aq)  S(s) + 2H+ (aq) + 2Cl– (aq)
bl vfHkfØ;k ds fy, nj lehdj.k gS
nj = k [Cl2][H2S]
fuEufyf[kr fØ;kfof/k;ksa esa ls dkSulh nj lehdj.k ds vuq:i gS@gSa \
A. Cl2 + H2S  H+ + Cl– + Cl+ + HS– (/kheh)
Cl+ + HS–  H+ + Cl– + S (rhoz)
B. H2S  H+ + HS– (rhoz lkE;)
Cl2 + HS–  2Cl– + H+ + S (/kheh)
(1) dsoy B (2) A vkSj B nksuksa (3) u rks A vkSj u gh B (4*) dsoy A
10. The rate of a chemical reaction doubles for every 10ºC rise of temperature. If the temperature is raised by
50ºC, the rate of the reaction increases by about : [AIEEE - 2011, 4/120]
(1) 10 times (2) 24 times (3*) 32 times (4) 64 times
izR;sd 10ºC rki o`f) ds fy;s jklk;fud vfHkfØ;k dh nj nksxquh gks tkrh gS] ;fn rki c<+kdj 50ºC dj fn;k tkrk gS
rks vfHkfØ;k dh nj yxHkx c<+ tk;sxh % [AIEEE - 2011, 4/120]
(1) 10 xquk }kjk (2) 24 xquk }kjk (3*) 32 xquk }kjk (4) 64 xquk }kjk
MAINCHK - 22
Chemical Kinetics
11. A reactant (A) forms two products :
k1
A 
 B, Activation Energy Ea1
k2
A  C, Activation Energy Ea2
If Ea2 = 2 Ea1, then k1 and k2 are related as : [AIEEE - 2011, 4/120]
,d vfHkdkjd (A) nks mRikn nsrk gS %
k1
A 
 B, lafØ;.k ÅtkZ Ea1
k2
A  C, lafØ;.k ÅtkZ Ea2
;fn Ea2 = 2 Ea1, rc k1 rFkk k2 vkil esa bl izdkj lEcfU/kr gSa %

(1) k 2  k 1eEa1 / RT (2) k 2  k1eEa 2 / RT (3*) k1  Ak 2 eEa1 / RT (4) k1  2k 2 eEa 2 / RT
12. For a first order reaction (A)  products the concentration of A changes from 0.1 M to 0.025 M in 40 minutes.
The rate of reaction when the concentration of A is 0.01 M is : [AIEEE - 2012, 4/120]
izFke dksfV vfHkfØ;k] (A)  mRikn ds fy,] A dh lkUærk 40 feuV esa 0.1 M ls cnydj 0.025 M gks tkrh gSA tc A
dh lkUærk 0.01 M gks rks vfHkfØ;k dh nj gksxh : [AIEEE - 2012, 4/120]
(1) 1.73 × 10–5 M/min (2*) 3.47 × 10–4 M/min (3) 3.47 × 10–5 M/min (4) 1.73 × 10–4 M/min
13. The rate of a reaction doubles when its temperature changes from 300 K to 310 K. Activation energy of such
a reaction will be : (R = 8.314 JK–1 mol–1 and log 2 = 0.301) [JEE(Main) - 2013, 4/120]
,d vfHkfØ;k dh nj nks xquh gks tkrh gS tc bldk rki 300 K ls 310 K gks tkrk gSA ,slh vfHkfØ;k dh lfØ;.k ÅtkZ
gksxh % (R = 8.314 JK–1 mol–1 rFkk log 2 = 0.301)
(1*) 53.6 kJ mol–1 (2) 48.6 kJ mol–1 (3) 58.5 kJ mol–1 (4) 60.5 kJ mol–1
14. For the non-stoichiometre reaction 2A + B  C + D, the following kinetic data were obtained in three
separate experiments, all at 298 K.
Initial Concentration Initial Concentration Initial rate of formation of C

( A) (B) (mol L ¯S¯)
0.1 M 0.1 M 1.2  10 –3
0.1 M 0.2 M 1.2  10 –3
0.2 M 0.1 M 2.4  10 –3
The rate law for the formation of C is : [JEE(Main) - 2014, 4/120]

dc dc dc dc
(1) = k[A] [B] (2) = k[A]2[B] (3) = k[A] [B]2 (4*) = k[A]
dt dt dt dt
jlk;fudrk fjDr vfHkfØ;k esa rhu i`Fkd iz;ksxksa esa 298 K ij fuEu xfrd vkadM+s izkIr fd;s x;s %
i zkj fEHkd l ka nz.k C cuusdhi zkj fEHkd nj

nz.k i zkj fEHkd l ka
( A) (B) ( eks
y L ¯S¯)
0.1 M 0.1 M 1.2  10 –3
0.1 M 0.2 M 1.2  10 –3
0.2 M 0.1 M 2.4  10 – 3
vfHkfØ;k ds fy, C cuus dk nj fu;e gksxk% [JEE(Main) - 2014, 4/120]

dc dc dc dc
(1) = k[A] [B] (2) = k[A]2[B] (3) = k[A] [B]2 (4*) = k[A]
dt dt dt dt
MAINCHK - 23
Chemical Kinetics
15. Higher order (>3) reactions are rare due to : [JEE(Main) - 2015, 4/120]
(1*) low probability of simultaneous collision of all the reacting species
(2) increase in entropy and activation energy as more molecules are involved
(3) shifting of equilibrium towards reactants due to elastic collisions
(4) loss of active species on collision
mPp dksfV vfHkfØ;k (>3) nqyZHk gS D;ksafd % [JEE(Main) - 2015, 4/120]
(1) izfrfØ;k esa lHkh iztkfr;ksa ds ,d lkFk VDdj dh laHkkouk de gksrh gSA
(2) vf/kd v.kqvksa ds 'kkfey gksus ls ,aVªkih vkSj lafØ;rk ÅtkZ esa o`f) gksrh gSA
(3) ykspnkj Vdjko ds dkj.k vfHkdkjdksa dh fn'kk esa lkE; dk LFkkukarj.k gksrk gSA
(4) Vdjko ls lfØ; Lih'kht dk {k; gksrk gSA
16. The reaction 2N2O5(g)  4NO2(g) + O2(g) follows first order kinetics. The pressure of a vessel containing only
N2O5 was found to increase from 50 mm Hg to 87.5 mm Hg in 30 min. The pressure exerted by the gases
after 60 min. will be (Assume temperature remains constant) : [JEE(Main)-2015_Online, 4/120]
vfHkfØ;k 2N2O5(g)  4NO2(g) + O2(g) çFke dksfV xfrdh dk ikyu djrk gSA dsoy N2O5 ;qDr ek=k dk nkc 30 feuV
esa 50 mm Hg ls 87.5 mm Hg rd c<+ x;kA 60 feuV i’’'pkr~ xSl }kjk Mkyk x;k nkc gksxk ¼ekuk vk;ru fu;r jgrk
gS ½ [JEE(Main)-2015_Online, 4/120]
(1) 125 mm Hg (2*) 106.25 mm Hg (3) 116.25 mm Hg (4) 150 mm Hg
17. A + 2B  C, the rate equation for this reaction is given as [JEE(Main)-2015_Online, 4/120]
Rate = K[A][B].
If the concentration of A is kept the same but that of B is doubled what will happen to the rate itself ?
(1) halved (2) the same (3*) doubled (4) quadrupled
A + 2B  C, bl vfHkfØ;k ds fy, nj lehdj.k uhps fn xbZ gS %
nj = K[A][B].
;fn A dh lkUnzrk leku j[kh tk;s ysfdu B dh lkUnzrk nksxquh dh tk;s rks bldh nj ij D;k çHkko iM+sxk\
(1) vk/kh (2) leku (3*) nksxquh (4) pkj xquk
18. For the equilibrium, A(g) B(g), H is –40 kJ/mol. If the ratio of the activation energies of the forward (Ef)
2
and reverse (Eb) reactions is then : [JEE(Main)-2015_Online, 4/120]
3
(1*) Ef = 80 kJ/mol; Eb = 120 kJ/mol (2) Ef = 60 kJ/mol; Eb = 100 kJ/mol
(3) Ef = 30 kJ/mol; Eb = 70 kJ/mol (4) Ef = 70 kJ/mol; Eb = 30 kJ/mol
lkE;] A(g) B(g) ds fy, H = –40 kJ/mol gSA ;fn vxz (Ef) rFkk i'p~ (Eb) vfHkfØ;kvksa dh lafØ;.k ÅtkZvksa dk
2
vuqikr 3 gSA rc :
(1*) Ef = 80 kJ/mol; Eb = 120 kJ/mol (2) Ef = 60 kJ/mol; Eb = 100 kJ/mol
(3) Ef = 30 kJ/mol; Eb = 70 kJ/mol (4) Ef = 70 kJ/mol; Eb = 30 kJ/mol
19. Decomposition of H2O2 follows a first order reaction. In fifty minutes the concentration of H2O2 decreases from
0.5 to 0.125 M in one such decomposition. When the concentration of H2O2 reaches 0.05 M, the rate of
formation of O2 will be : [JEE(Main)-2016, 4/120]
H2O2 dk fo?kVu ,d izFke dksfV dh vfHkfØ;k gSA ipkl feuV esa bl izdkj ds fo?kVu esa H2O2 dh lkUnzrk ?kVdj 0.5
ls 0.125 M gks tkrh gSA tc H2O2 dh lkUnzrk 0.05 M igq¡prh gS] rks O2 ds cuus dh nj gksxh%
(1*) 6.93  10–4 mol min–1 (2) 2.66 L min–1at STP (STP ij)
(3) 1.34  10–2 mol min–1 (4) 6.93  10–2 mol min–1
MAINCHK - 24
Chemical Kinetics
20. The reaction of ozone with oxygen atoms in the presence of chlorine atoms can occur by a two step
process show below: [JEE(Main)-2016_Online, 4/120]
 
O3(g) + Cl (g)  O2(g) + ClO (g) ...(i)
9 –1 –1
ki = 5.2 × 10 L mol s
ClO(g) + O(g)  O2(g) + Cl(g) ...(ii)
10 –1 –1
kii = 2.6 × 10 L mol s
The closest rate constant for the overall reaction O3(g) + O(g)  2O2(g) is:
Dyksjhu ijek.kqvksa dh mifLFkfr esa vkWDlhtu ijek.kqvksa ds lkFk vkstksu dh vfHkfØ;k fuEu nks inksa esa gksrh gS %
O3(g) + Cl(g)  O2(g) + ClO(g) ...(i)
ki = 5.2 × 109 L mol–1 s–1
ClO(g) + O(g)  O2(g) + Cl(g) ...(ii)
kii = 2.6 × 1010 L mol–1 s–1
lEiw.kZ vfHkfØ;k O3(g) + O(g)  2O2(g) ds fy, fudVre nj fu;rkad gS % [JEE(Main)-2016_Online, 4/120]
(1) 1.4 × 1020 L mol–1 s–1 (2*) 5.2 × 109 L mol–1 s–1
(3) 3.1 × 1010 L mol–1 s–1 (4) 2.6 × 1010 L mol–1 s–1
21. The rate law for the reaction below is given by the expression k [A][B]
A + B  Product
If the concentration of B is increased from 0.1 to 0.3 mole, keeping the value of A at 0.1 mole, the rate
constant will be : [JEE(Main)-2016_Online, 4/120]
fuEu vfHkfØ;k ds fy, O;atd k [A][B] }kjk fn;k tkrk gSA
A + B  mRikn
0.1 eksy ij A dk eku j[krs gq, ;fn B dh lkUnzrk dks 0.1 ls 0.3 eksy rd c<+k;k tkrk gS rks nj fu;rkad gksxk %
[JEE(Main)-2016_Online, 4/120]
(1) 9 k (2) 3 k (3) k/3 (4*) k
PART - II : JEE (ADVANCED) / IIT-JEE PROBLEMS (PREVIOUS YEARS)

Hkkx - II : JEE (ADVANCED) / IIT-JEE ds iz'u ¼fiNys o"kksZ½
* Marked Questions may have more than one correct option.
* fpfUgr iz ' u ,d ls vf/kd lgh fodYi okys iz ' u gS -
1. The rate constant for the reaction,2N2O5  4NO2+ O2, is 3 ×10–5 s–1. If the rate is 2.4 × 10–5 mol L–1 s–1, then
the concentration of N2O5 (in mol L–1) is : [JEE-2000, 1/35]
vfHkfØ;k, 2N2O5  4NO2 + O2 ds fy, nj fu;rkad 3 × 10–5 s–1 gSA ;fn nj 2.4 × 10–5 mol L–1 s–1 gks rks
N2O5 dh lkUnzrk (mol L–1 esa) fuEu gS % [JEE-2000, 1/35]
(A) 1.4 (B) 1.2 (C) 0.04 (D*) 0.8
2. If '' is the intensity of absorbed light and 'C' is the concentration of AB for the photochemical process,
AB + hv  AB * , the rate of formation of AB * is directly proportional to [JEE-2001, 1/35]
;fn '' vo'kksf"kr izdk'k dh rhozrk rFkk AB dh lkUnzrk 'C' gks rks fuEu izdk'kjklk;fud izØe AB + hv  AB * , esa AB * ds
mRiknu dh nj fdlds lekuqikrh gksxh \ [JEE-2001, 1/35]
2
(A) C (B*)  (C)  (D) C.
3. Consider the chemical reaction, N2(g) + 3H2(g)  2NH3(g)

The rate of this reaction can be expressed in terms of time derivatives of conc. of N2(g) , H2(g) or NH3(g).
Identify the correct relationship amongst rate expressions : [JEE-2002, 3/90]
MAINCHK - 25
Chemical Kinetics
d [N2 ] 1 d [H2 ] 1 d [NH3 ] d [N2 ] d [H2 ] d [NH3 ]
(A*) Rate =    (B) Rate =  3 2
d [N2 ] 1 d [H2 ] 1 d [NH3 ] d [N2 ] d [H2 ] d [NH3 ]

(C) Rate =   (D) Rate =   
ekuk dksbZ jklk;fud vfHkfØ;k fuEu gS % N2(g) + 3H2(g)  2NH3(g)
bl vfHkfØ;k dh nj ds fy, N2(g), H2(g) ;k NH3(g) dh lkUnzrk dks le; ds inksa esa vfHkO;Dr fd;k x;k gSA vr% nj
O;atd ds fy, dkSulk lgh laca/k gSa % [JEE-2002, 3/90]
d [N2 ] 1 d [H2 ] 1 d [NH3 ] d [N2 ] d [H2 ] d [NH3 ]
(A*) nj =    (B) nj =  3 2
d [N2 ] 1 d [H2 ] 1 d [NH3 ] d [N2 ] d [H2 ] d [NH3 ]

(C) nj =   (D) nj =   d
4. Given X  product (Taking 1st order reaction)

conc. (mol/lit) 0.01 0.0025
time (min) 0 40
Initial rate of reaction is in mol //min. [JEE-2004, 3/84]
fn;k gS , X  mRikn (izFke dksfV dh vfHkfØ;k ekurs gq,)
lkaUnzrk (mol/lit) 0.01 0.0025
le; (feuV) 0 40
vfHkfØ;k dh izkjafHkd nj mol //min eas gksxhA [JEE-2004, 3/84]
(A*) 3.43 × 10–4 (B) 1.73 × 10–4 (C) 3.43 × 10–5 (D) 1.73 × 10–5
5. Consider a reaction aG + bH  Products. When concentration of both the reactants G and H is doubled, the
rate increases by eight times. However, when concentration of G is doubled keeping the concentration of H
fixed, the rate is doubled. The overall order of the reaction is : [JEE-2007, 3/81]
ekuk fd aG + bH  mRikn ,d vfHkfØ;k gSA bl vfHkfØ;k esa G vkSj H nksuksa vfHkdkjdksa dk lkUnzrk nqxquk djus ij
vfHkfØ;k dk nj vkB xquk c<+rh gSA fdUrq H dk lkUnzrk fLFkj j[k dj flQZ G dh lkUnzrk nqxquh djus ij vfHkfØ;k dh
nj nqxquh gksrh gSA bl vfHkfØ;k dh laiw.kZ dksfV gS& [JEE-2007, 3/81]
(A) 0 (B) 1 (C) 2 (D*) 3
6. For a first order reaction A  P, the temperature (T) dependent rate constant (k) was found to follow the
1
equation log k = – (2000) + 6.0. The pre-exponential factor A and the activation energy Ea, respectively,,
T
are : [JEE-2009, 3/80]
6 –1 –1 –1 –1
(A) 1.0 × 10 s and 9.2 kJ mol (B) 6.0 s and 16.6 kJ mol
(C) 1.0 × 106 s–1 and 16.6 kJ mol–1 (D*) 1.0 × 106 s–1 and 38.3 kJ mol–1
1
izFke dksfV vfHkfØ;k A  P, ds fy, osx fLFkjkad (k) dh rki (T) ij fuHkZjrk dks lehdj.k log k = – (2000) + 6.0
T
ds vuqlkj ik;k x;k gSA iwoZ pj?kkrkadh xq.kkd (pre-exponential factor) A ,oa lfØ;.k ÅtkZ (activation energy) Ea
Øe'k% gS % [JEE-2009, 3/80]
6 –1 –1 –1 –1
(A) 1.0 × 10 s vkSj 9.2 kJ mol (B) 6.0 s vkSj 16.6 kJ mol
6 –1 –1
(C) 1.0 × 10 s vkSj 16.6 kJ mol (D*) 1.0 × 106 s–1 vkSj 38.3 kJ mol–1
MAINCHK - 26
Chemical Kinetics
7. Plots showing the variation of the rate constant (k) with temperature (T) are given below. The plot that follows
Arrhenius equation is : [JEE-2010, 3/163]
osx fLFkjkad (k) dk rkieku (T) ds lkFk fopj.k n'kkZrs gq;s vkys[k uhps fn;s x;s gSaA vkjsZfu;l lehdj.k dk vuqdj.k djus
okyk vkys[k gS % [JEE-2010, 3/163]
(A*) (B) (C) (D)
8. In the reaction, P + Q  R + S

the time taken for 75% reaction of P is twice the time taken for 50% reaction of P. The concentration of Q
varies with reaction time as shown in the figure. The overall order of the reaction is :
[JEE(Advanced) 2013, 2/120]
(A) 2 (B) 3 (C) 0 (D) 1

fuEu vfHkfØ;k] P + Q  R + S
esa P dh 75% vfHkfØ;k dk le; P dh 50% vfHkfØ;k esa fy, x, le; dh rqyuk esa nksxquk gSA Q dh fofHkUu lkUnzrk]
vfHkfØ;k le; vuqlkj fp=k esa n'kkZbZ xbZ gSA bl vfHkfØ;k dh leLr dksfV gSA [JEE(Advanced) 2013, 2/120]
(A) 2 (B) 3 (C) 0 (D*) 1

9. For the elementary reaction M  N, the rate of disappearance of M increases by a factor of 8 upon doubling
the concentration of M. The order of the reaction with respect to M is : [JEE(Advanced) 2014, 3/120]
ljy vfHkfØ;k M  N ds fy,] M dh lkUnzrk nks xquh djus ij M dh foyksiu nj (rate of disappearance) 8 xquk c<+
tkrh gSA M ds lkis{k vfHkfØ;k dh dksfV (order of the reaction) gSA [JEE(Advanced) 2014, 3/120]
(A) 4 (B*) 3 (C) 2 (D) 1
10. The % yield of ammonia as a function of time in the reaction : [JEE(Advanced) 2015, 3/120]
N2(g) + 3H2(g) 2NH3(g), H  0
at (P, T1) is given below.
vfHkfØ;k N2(g) + 3H2(g) 2NH3(g), H  0
esa veksfu;k ds mRikn (% yield) dh le; (time) ij fuHkZjrk (P, T1) ij uhps n'kkZ;h x;h gS
MAINCHK - 27
Chemical Kinetics
% yield
T1
time
If this reaction is conducted at (P, T2), with T2 > T1, the % yield of ammonia as a function of time is repre-
sented by
;fn ;g vfHkfØ;k (P, T2), ij dh tk; tgk¡ T2 > T1] veksfu;k ds % mRikn dh le; ij fuHkZjrk iznf'kZr djrk gSA
T2
% yield
% yield
T1
T1
T2
(A) (B*)
time time
T2
% yield
% yield
T1
T2 T1
(C) (D)
time time
MAINCHK - 28
Chemical Kinetics
Max. Marks : 120 Max. Time : 1 Hr.
Important Instructions
egÙoiw.kZ funsZ'k %
1. The test is of 1 hour duration.
ijh{kk dh vof/k 1 ?kaVs gSA
2. The Test Booklet consists of 30 questions. The maximum marks are 120.
bl ijh{kk iqfLrdk esa 30 iz'u gSA vf/kdre vad 120 gSA
3. Each question is allotted 4 (four) marks for correct response.
lHkh iz'uksa ds vad leku gSA izR;sd iz'u ds lgh mÙkj ds fy, 4 ¼pkj½ vad fu/kkZfjr fd;s x;s gSA
4. Candidates will be awarded marks as stated above in Instructions No. 3 for correct response of each question.
¼ (one fourth) marks will be deducted for indicating incorrect response of each question. No deduction from the
total score will be made if no response is indicated for an item in the answer sheet.
vH;kfFkZ;ksa dks izR;sd lgh mÙkj ds fy, mijksDr funsZ'ku la[;k 3 ds funsZ'kkuqlkj ekDlZ fn;s tk,axsA izR;sd iz'u ds xyr mÙkj
ds fy;s ¼ oka Hkkx fy;k tk;sxkA ;fn mÙkj iqfLrdk esa fdlh iz'u dk mÙkj ugha fn;k x;k gks rks dqy izkIrkad ls dksbZ dVkSrh
ugha fd tk;sxhA
5. There is only one correct response for each question. Filling up more than one response in any question will be
treated as wrong response and marks for wrong response will be deducted accordingly as per instructions 4
above.
çR;sd iz'u dk dsoy ,d gh lgh mÙkj gSA ,d ls vf/kd mÙkj nsus ij mls xyr mÙkj ekuk tk;sxk vkSj mijksDr funsZ'k 4 ds
vuqlkj vad dkV fy;s tk;saxsA
1. The reaction A(g) + 2B(g)  C(g) is an elementary reaction. In an experiment involving this reaction, the
initial partial pressures of A and B are PA = 0.40 atm and PB = 1.0 atm respectively. When pressure of
C becomes 0.3 atm in the reaction the rate of the reaction relative to the initial rate is :
1 1 1
(1) (2) (3*) (4) none of these
12 50 25
vfHkfØ;k A(g) + 2B(g)  C(g) ,d ljy ¼,dy in½ vfHkfØ;k gSaA ftls ,d ç;ksx esa ç;qDr fd;k tkrk gSSA A rFkk B dk
çkjfEHkd nkc Øe'k% PA = 0.40 ok;qe.Myh; rFkk PB = 1.0 ok;qe.Myh; gSA tc PC = 0.3 ok;qe.Myh; gks tkrk gS] rks
çkjfEHkd nj ds lkis{k vfHkfØ;k dh nj gksxh \
1 1 1
(1) (2) (3*) (4) mijksDr esa ls dksbZ ugha
12 50 25
2. The rate law for the dimerisation of NO2 is

d [NO 2 ]
– = k [NO2]2
dt
which of the following changes will change the value of the specific rate constant , k :
(1) Doubling the total pressure on the system (2*) Doubling the temperature
(3) Both of (1) and (2) (4) None of the above
NO2 ds f}ydhdj.k ds fy, osx fu;e gS
d [NO 2 ]
– = k [NO2]2
dt
fuEu esa ls dkSulk ifjorZu fof'k"V nj fu;rkad k ds eku dks ifjofrZr dj ldrk gS %
(1) ra=k ij dqy nkc nqxquk djus ij (2*) rki dks nqxquk djus ij
(3) (1) rFkk (2) nksuksa gh (4) mijksDr esa ls dksbZ ugha
MAINCHK - 46
Chemical Kinetics
3. Which of the following statement is incorrect ?
(1) unit of rate of disapperarance is Ms–1 (2) Unit of rate of reaction is Ms–1
(3) Unit of rate constant k is depend on order (4*) Unit of k for first order reaction is Ms–1
fuEu esa ls dkSulk dFku xyr gS ?
(1) foyqIrrk dh nj dh bdkbZ Ms–1 gksrh gSA (2) vfHkfØ;k dh nj dh bdkbZ Ms–1 gksrh gSA
(3) nj fu;rkad k, dh bdkbZ dksfV ij fuHkZj djrh gSA (4*) izFke dksfV vfHkfØ;k ds fy, k dh bdkbZ Ms–1 gksrh gSA
4. Which of the following relation is correct for kf and kb in an equilibrium process that contains equal moles of
reactants and products.
(1) kf = kb (2) kf > kb (3) kf < kb (4*) we cannot prodict
vfHkdkjd rFkk mRikn ds leku eksy ;qDr ,d lkE; izØe esa kf rFkk kb ds fy;s lgh lEcU/k fuEu esa ls gS \
(1) kf = kb (2) kf > kb (3) kf < kb (4*) Kkr ugh fd;k tk ldrkA
5. 5. Let there be a first order reaction, A  B + C. Let us assume all there are gases. We are
required to calculate the value of rate constant based on the following data
Time 0 t 
Total pressure P0 Pt –
Calculate the expression of rate constant.
1  2P0 – Pt 
 1  P0 
 t  P0 
 1  Pt 

(1) k = ln (2*) k = ln  2P – P (3) k = ln  (4) k = ln  2P – P
t  P0 
 t  0 t

 1  2P0 – Pt

 t  0 t


ekuk fd A  B + C çFke dksVh dh vfHkfØ;k gSaA vc ;g ekurs gS fd rhuksa çtkfr xSlh; gSa] gesa fuEu vkWdMksa ij
vk/kkfjr nj fu;rkad dk eku ifjdfyr djuk vko';d gSaA
nj fu;arkd dk O;tad Kkr dhft,A
1  2P0 – Pt 
 1  P0 
 t  P0 
 1  Pt 

(1) k = ln (2*) k = ln  2P – P (3) k = ln  (4) k = ln  2P – P
t  P0 
 t  0 t

 1  2P0 – Pt

 t  0 t


6. Which of the following statement is incorrect ?

(1*) A second order reaction must be a biomolecular elementary reaction
(2) A bimolecular elementary reaction must be a second order reaction
(3) Zero order reaction must be a complex reaction
(4) First order reaction may be complex or elementary reaction
fuEu esa ls dkSulk dFku xyr gS \
(1*) ,d f}rh; dksfV vfHkfØ;k ,d tSo v.kqd izk:fid vfHkfØ;k gksxhA
(2) ,d f}v.kqd izk:fid vfHkfØ;k ,d f}rh; dksfV vfHkfØ;k gksxhA
(3) 'kqU; dksfV vfHkfØ;k ,d ladqy vfHkfØ;k gksxhA
(4) izFke dksfV vfHkfØ;k ladqy ;k izk:fid vfHkfØ;k gks ldrh gSA
MAINCHK - 47
Chemical Kinetics
7. A2 + B2  2AB; Rate of reaction = k[A]a [B]b
Initial [A2] Initial [Br2] R.O.R. (r) Ms–1
0.2 0.2 0.04

0.1 0.4 0.04
0.2 0.4 0.08
Order of reaction with respect to A2 and B2 are respectively :

(1*) a = 1, b = 1 (2) a = 2, b = 0 (3) a = 2, b = 1 (4) None of these
a b
A2 + B2  2AB; vfHkfØ;k dh nj = k[A] [B]
[A2] izkjfEHkd [Br2] izkjfEHkd vfHkfØ;k dh nj (r) Ms–1

0.2 0.2 0.04
0.1 0.4 0.04

0.2 0.4 0.08
A2 ,oa B2 dh dksfV Øe'k% gS%

(1*) a = 1, b = 1 (2) a = 2, b = 0 (3) a = 2, b = 1 (4) buesa ls dksbZ ugha
8. For a reaction A(s) + B(s)  C(s) is rate = k[A]1/2 [B]2. What changes in rate if intial concentration of A and
B increase by factor 4 and 2 respectively.
(1) 4 (2) 6 (3*) 8 (4) None of these
vfHkfØ;k A(s) + B(s)  C(s) ds fy;s nj = k[A]1/2 [B]2 gSA ;fn A rFkk B dh izkjfEHkd lkUnzrk dks Øe'k% 4 rFkk 2 xquk
c<+k fn;k tk, rks nj esa D;k ifjorZu gksxk \
(1) 4 (2) 6 (3*) 8 (4) buesa ls dksbZ ugh
9. Reaction A  B follows second order kinetics. Doubling the concetration of A will increase the rate of
formation of B a factor of :
vfHkfØ;k A  B] f}rh; dksfV xfrdh dk ikyu djrh gSA A dh lkUnzrk dks nksxquk djus ij B dh fuekZ.k dh nj esa o`f}
gksxh \
(1) 1/4 (2) 1/2 (3) 2 (4*) 4
10. The forward rate constant for the elementary reversible gaseous reaction
C2H6 2CH3 is 1.57 × 10–3 s–1 at 100 K
What is the rate constant for the backward reaction at this temperature if 10–4 mole of CH3 and 10 moles
of C2H6 are present in a 10 litre vessel at equilibrium.
100 K ij izk:fid mRØe.kh; xSlh; vfHkfØ;k C2H6 2CH3 ] ds fy;s vxz vfHkfØ;k nj fu;rkad 1.57 × 10–3 s–1 gSA
–4
;fn lkE; ij 10 yhVj ds ik=k esa CH3 ds 10 eksy rFkk C2H6 ds 10 eksy mifLFkr gks rks blh rki ij i'p vfHkfØ;k
ds fy, nj fu;rkad D;k gS \
(1) 1.57 × 109 L mol—1 s–1 (2) 1.57 × 1010 L mol—1 s–1
(3) 1.57 × 1011 L mol—1 s–1 (4*) 1.57 × 107 L mol—1 s–1
11. Rate constant k is 2.303 min–1 for a particular reaction. The initial concentration of the reaction is 1 mole/litre
then rate of reaction after 1 minutes is :
fdlh ,d vfHkfØ;k ds fy, nj fu;rkad nj k dk eku 2.303 min–1 gSA vfHkfØ;k dh çkjfEHkd lkUnzrk 1 mole/litre gks rks
1 fefuV i'pkr~ vfHkfØ;k dh nj gksxh&
MAINCHK - 48
Chemical Kinetics
(1) 2.303 M min–1 (2*) 0.2303 M min–1 (3) 0.1 M min–1 (4) none of these buesa ls dksbZ ugha
12. For an elementary reaction 2A + B  A2B if the volume of vessel is quickly reduced to half of it’s original
volume then rate of reaction will -
(1) unchange (2) increase four times
(3*) increase eight times (4) decrease eright time
,d çk:fid vfHkfØ;k 2A + B  A2B ds fy, ;fn ik=k ds vk;ru dks 'kh?kzrk ls okLrfod vk;ru dk vk/kk dj fn;k
tk, rks vfHkfØ;k dh nj &
(1) vifjofrZr jgsxh (2) pkj xquk c<+sxh
(3*) vkWB xquk c<+sxh (4) vkWB xquk ?kVsxh
13. For a first order reaction A B + 2C + 3D (A is optically inactive and B, C and D are dextrorotary), the optical
rotation at time t and  are rt and r respectively, the expression for rate constant is
izFke dksfV vfHkfØ;k ds fy, A B + 2C + 3D (A izdk'kh; fuf"Ø; rFkk B, C rFkk D nf{k.kkorZ ?kw.kZu j[krs gS), izdk'kh;
?kw.kZu le; t rFkk  ij Øe'k% rt rFkk r gSA rks nj fu;rkad dk O;atd Kkr djksA
1 rt 1 r 1 r  rt
(1) K = ln (2*) k = ln (3) k = ln
t r  rt t r  rt t rt (4) none of these buesa ls dksbZ ugha
14. In the presence of acid, the initial concentration, of cane-sugar was reduced from 0.2 M to 0.1 M in 5 hr and
to 0.05 M in 10 hr. The reaction must be of
(1) Zero order (2*) First order (3) Second order (4) Fractional order
vEy dh mifLFkfr esa bZ{kq&'kdZjk dh izkjfEHkd lkUnzrk 0.2 M ls 5 ?k.Vksa esa 0.1 M rFkk 10 ?k.Vksa esa 0.05 M rd ?kV tkrh
gSA vfHkfØ;k gksxh&
(1) 'kwU; dksfV (2*) izFke dksfV (3) f}rh; dksfV (4) fHkUukRed dksfV
15. For an exothermic chemical process occurring in two steps as follows

(i) A + B  X (slow) (ii) X  AB (fast)
the process of reaction can be best describe by :
,d Å"ek{ksih jklkfud izØe fuEukuqlkj nks inksa esa gksrh gSA
(i) A + B  X (/khek) (ii) X  AB (rhoz)
vfHkfØ;k izØe dk lcls lgh fu:i.k fuEu esa ls gS %
(1) (2) (3*) (4)
16. The temperature coefficient of a reaction is :

(1) The rate constant
(2) The rate of constant at a fixed temperature
(3) The ratio of rate constant at two temperature
(4*) The ratio of rate constant differing by 10ºC preferably k308/k298
,d vfHkfØ;k dk rki xq.kkad gS&
(1) nj fu;rkad
(2) ,d fuf'pr rki ij nj fu;rkad
(3) nks rki ij nj fu;rkad dk vuqikr
(4*)10ºC rki vUrj ls vfHkfØ;k osx ;k nj fu;rkadks dk vuqikr k308/k298
MAINCHK - 49
Chemical Kinetics
17. The reaction A(g) + 2B(g)  C(g) + D(g) is an elementary process. In an experment, the initial partial
pressure of A and B are PA = 0.60 and PB = 0.80 atm. When PC = 0.2 atm, the rate of reaction relative to the
initial rate is :
vfHkfØ;k A(g) + 2B(g)  C(g) + D(g)] ,d izkjfEHkd izØe gSA ,d iz;ksx esa A rFkk B ds izkjfEHkd vkaf'kd nkc Øe'k%
PA= 0.60 rFkk PB = 0.80 atm gSA tc PC = 0.2 atm gks rks vfHkfØ;k dh nj] izkjfEHkd nj dh gksrh gSA
(1) 1/48 (2*) 1/24 (3) 9/16 (4) 1/6
18. In the following reaction, how is the rate of appearance of the underlined product related to rate of disappearance
of the underlined reactant :
BrO3– (aq) + 5 Br– (aq) + 6 H+ (aq)  3 Br2 () + 3 H2O ()
fuEu vfHkfØ;k esa js[kkafdr mRikn ds cuus dh nj js[kkafdr vfHkdkjd ds foyqIr gksus dh nj ls fdl izdkj lacaf/kr gS %
BrO3– (aq) + 5 Br– (aq) + 6 H+ (aq)  3 Br2 () + 3 H2O ()
d [Br2 ] 5 d [Br – ] d [Br2 ] d [Br – ]

(1) =– (2) =–
dt 3 dt dt dt
d [Br2 ] d [Br – ] d [Br2 ] 3 d [Br – ]

(3) =– (4*) =–
dt dt dt 5 dt
19. 3 A  B + C
It would be a zero order reaction when :
(1) the rate of reaction is proportional to square of concentration of A
(2*) the rate of reaction remains same at any concentration of A
(3) the rate remains unchanged at any concentration of B and C
(4) the rate of reaction doubles if concentration of B is increased to double
3 A  B + C
;g 'kwU; dksfV dh vfHkfØ;k gksxh tc %
(1) vfHkfØ;k dh nj A dh lkanzrk ds oxZ ds lekuqikrh gksrh gSA
(2*) A dh fdlh Hkh lkanzrk ij vfHkfØ;k dh nj fu;r jgrh gSA
(3) B rFkk C dh fdlh Hkh lkanzrk ij vfHkfØ;k dh nj vifjofrZr jgrh gSA
(4) ;fn B dh lknzrk dks nqxquk dj fn;k tk, rks vfHkfØ;k dh nj nqxquh gks tk;sxhA
20. At room temperature, the reaction between NO and O2 to give NO2 is fast, while that between CO and O2 is
slow. It is due to :
(1) CO is smaller in size that of NO
(2) CO is poisonous
(3*) The activation energy for the reaction, 2NO + O2  2NO2 is less then 2CO + O2  2CO2.
(4) None of the above
dejs ds rki ij NO rFkk O2 ds e/; vfHkfØ;k djkus ij rhoz NO2 izkIr gksrk gSA tcfd CO rFkk O2 ds e/; /kheh gksrh
gSA ;g bl dkj.k gksrk gS
(1) CO dk NO dh rqyuk esa vkdkj NksVk gksrk gSA
(2) CO tgjhyh gS
(3*) bl vfHkfØ;k ds fy, 2NO + O2  2NO2 dh lfØ;.k ÅtkZ 2CO + O2  2CO2 ls de gksrh gSA
(4) mijksDr esa ls dksbZ ugha
21. The time of decay for a nuclear reaction is given by t = 4t1/2. The relation between the mean life (T) and time
of decay (t) is given by :
,d ukfHkfd; vfHkfØ;k ds fy, {k; le; t = 4t1/2 ls fn;k tkrk gSA ek/; vk;q (T) rFkk {k; ds le; (t) ds e/; lEcU/k]
fn;k tkrk gS&
1
(1) 2 T ln 2 (2*) 4 T ln 2 (3) 2T4 ln 2 (4) ln 2
T2
MAINCHK - 50
Chemical Kinetics
22. Atoms 7XA, 8YB and 9Z17 are such that 8Y is an isobar of 7X and atom 9Z17 is isotone of 8Y. Mass no. of X and no.
of neutrons in Y are respectively :
7
XA, 8YB rFkk 9Z17 ijek.kq bl izdkj gS fd 8Y, 7X dk ,d leHkkfjd gS rFkk ijek.kq 9Z17 , 8Y dk leU;wVªkö Wfud gSA X dh nzO;eku
la[;k rFkk Y esa u;wVªkWu Øe'k% gS %
(1) 8, 8 (2) 17, 7 (3) 9, 8 (4*) 16, 8
23. The mechanism of the reaction
2NO + O 2  2NO 2 is
k1
NO + NO N2O 2 (fast) ;
k –1
2k
N2O 2 + O 2   N2O 2 (slow) ;
The rate constant of the reaction is :
vfHkfØ;k 2NO + O2  2NO2 dh fØ;kfo/kh fuEu gS&
k1
NO + NO N2O 2 (rhoz) ;
k –1
k2
N2O 2 + O 2   N2O 2 (/kheh) ;
vfHkfØ;k dk nj fu;rkad fuEu esa ls gS :
 k1 
(1) k2 (2) k2k1(k–1) (3) k2k1 (4*) k2  k 
 1 
24. t 1/2 = constant confirms the first order of the reaction as one a2 t 1/2 = constant confirms that the reaction
is of :
(1) Zero order (2) First order (3) Second order (4*) Third order
t 1/2 = fu;rkad] izFke dksfV vfHkfØ;k dks n'kkZrk gS blh izdkj a2 t 1/2 = fu;krkad dkSulh dksfV dh vfHkfØ;k n'kkZrk gS
(1) 'kwU; dksfV (2) izFke dksfV (3) f}rh; dksfV (4*) Rk`rh; dksfV
25. For which of the following reactions, the units of rate constant and rate of reaction are same ?
(1) First order reaction (2) Second order reaction
(3) Third order reaction (4*) Zero order reaction
fuEUk esa ls dkSulh vfHkfØ;k ds fy, nj fu;rkad dh bdkbZ rFkk vfHkfØ;k dh nj leku gksrh gS \
(1) izFke dksfV vfHkfØ;k (2) f}rh; dksfV vfHkfØ;k
(3) r`rh; dksfV vfHkfØ;k (4*) 'kwU;
26. The half-life period of a second order reaction is :
(1) Proportional to the initial concentration of reactants
(2) Independent of the initial concentration of reactants
(3*) Inversely proportional to the initial concentration of reactants
(4) Inversely proportional to the square of initial concentration of reactants
,d f}rh; dksfV vfHkfØ;k dk v)Zvk;q dky :
(1) vfHkdkjdksa dh izkjfEHkd lkUnzrk ds lekuqikrh gksrk gSA
(2) vfHkdkjdksa dh izkjfEHkd lkUnzrk ij fuHkZj ugh djrk gSA
(3*) vfHkdkjdksa dh izkjfEHkd lkUnzrk ds O;qRØekuqikrh gksrk gSA
(4) vfHkdkjdksa dh izkjfEHkd lkUnzrk ds oxZ ds O;qRØekuqikrh gksrk gSA
27. If the initial concentration of reactants in certain reaction is double, the half-life period of the reaction
doubles, the order of a reaction is :
(1*) Zero (2) First (3) Second (4) Third
,d fuf'pr vfHkfØ;k esa vfHkdkjdksa dh izkjfEHkd lkUnzrk dks nqxquk djus ij v)Zvk;q dky nqxquk gks tkrk gks rks vfHkfØ;k
dh dksfV gS %
(1*) 'kwU; (2) izFke (3) f}rh; (4) r`rh;
MAINCHK - 51
Chemical Kinetics
28. Ac227 has a half-life of 22 years. The decays folows two parallel paths
What are the decay constants () for Th and Fr respectively ?

(1) 0.03087, 0.00063 (2*) 0.00063, 0.03087 (3) 0.02, 0.98 (4) None of these
Ac227 dh v)Zvk;q 22 o"kZ gSA bldk {k; fuEu nks lkekUrj iFkksa }kjk n'kkZ;k x;k gSa
Th rFkk Fr ds fy, {k; fu;rkad () Øe'k% gS

(1) 0.03087, 0.00063 (2*) 0.00063, 0.03087 (3) 0.02, 0.98 (4) bueas ls dksbZ ugh
29. There are two radio nuclei A and B. A is a -emitter and B is -emitter, their disintegration constant are
in the ratio of 1 : 2. What should be the number of atoms of two at time t = 0, so that probability of
getting of  and -particles are same at time t = 0
A rFkk B nks jsfM;ks ukfHkd gSA A ,d -mRltZd rFkk B ,d - mRltZd gSa budk fo;kstu fu;rkad vuqikr 1 : 2 gSA
t = 0 ij buds ijek.kqvksa dh la[;k dk vuqikr D;k gksuk pkfg, fd t = 0 ij  rFkk -d.kksa dks izkIr djus dh izkf;drk
leku gks \
(1*) 2 : 1 (2) 4 : 1 (3) 1 : 2 (4) 1 : 4
30. 84
Po218 (t 1/2 = 183 sec) decay to 82Pb(t 1/2 = 161 sec) by -emission, while Pb214 is a -emitter. In an
experiment starting with 1 mole of pure Po 218, how much time would be required for the number of
nuclei of 82Pb214 to reach maximum ?
84
Po218 (t 1/2 = 183 sec) dk-mRltZu }kjk 82Pb (t 1/2 = 161 sec) esa {k; gksrk gS tcfd Pb214 ,d -mRltZd gSA ,d
iz;ksx esa 'kq) Po218 ds 1 eksy ls vkjEHk djus ij 82Pb214 ds ukfHkdksa dh vf/kdre la[;k rd igqWpus ds fy, fdrus le;
dh vko';drk gksxh \
(1) 147.5 (2*) 247.5 (3) 182 (4) 304
Practice Test (IIT-JEE (Main Pattern))

OBJECTIVE RESPONSE SHEET (ORS)
Que. 1 2 3 4 5 6 7 8 9 10
Ans.
Que. 11 12 13 14 15 16 17 18 19 20
Ans.
Que. 21 22 23 24 25 26 27 28 29 30
Ans.
MAINCHK - 52

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Chemical Kinetics

(3) 4A + 2B  2C + 3D (4) B + (1/2) D  4A + 3 C

A-3. Consider the chemical reaction :

d [N2 ] 1 d [H2 ] d [NH3 ] d [N2 ] d [H2 ] d [NH3 ]

d [N2 ] 1 d [H2 ] d [NH3 ] d [N2 ] d [H2 ] d [NH3 ]

A-7. In the following reaction : xA  yB

 [Br  ]  [H ]  [Br  ] 6  [H ]

 [Br  ] 5  [H ]  [Br  ]  [H ]

Section (B) : Rate law

B-5. 2A  B + C it would be a zero order reaction when :

Section (C) : The integrated rate laws

graph between – d[A]/dt and time will be of the type :

(1) (2) (3*) (4)

(1) (2) (3*) (4)

Time 0 5 min 10 min 15 min

l e; 0 5 feuV 10 feuV 15 feuV

The order for the reaction is

okbfuy ,fyy bZFkj (vinyl allyl ether) dk isUV–4–bZukWy ,d fuf'pr Øe dk –2

Calculate the expression of rate constant.

nj fu;arkd dk O;tad Kkr dhft,A

2.303  2Pi  2.303  3Pi 

Section (F) : Effect of Temperature

F-4. According to collision theory of reaction rates –

F-8. For the first order reaction, X(s)  X(g)

Section (G) : Mechanism of reactions

G-3. The slowest step of a particualr reaction is found to be

Section (H) : Complications in first order reactions

K1 = 1.26 × 10–4 sec–1 and K2 = 3.8 × 10–5 sec–1

The percentage distribution of B and C

K1 = 1.26 × 10–4 sec–1 rFkk K2 = 3.8 × 10–5 sec–1

B vkSj C dh izfr'krrk gksxhA

PART - I : OBJECTIVE QUESTIONS

(1) n = 1 ; t1/2  a (2) n = 2, t1/2  1/a

(1) n = 1 ; t1/2  a (2) n = 2, t1/2  1/a

(1*) 0, 1/2 (2) 1, 1 (3) 2, 2 (4) 3, 1

Ex. No. [A/M] [B/M] [Initial rate (M sec–1)]

15. Catalyst increases the rate of reaction because :

The activation energy of the reaction is about

vfHkfØ;k dh lfØ;.k ÅtkZ gksxh %

,d dkYifud vfHkfØ;k X2 + Y2  2XY fuEu fØ;kfof/k dk vuqlj.k djrh gSA

X + Y2  XY + Y [/khek in]

X + Y  XY [rhoz in]

PART - II : ASSERTION / REASONING

PART - I : JEE (MAIN) / AIEEE PROBLEMS (PREVIOUS YEARS)

Hkkx - I : JEE (MAIN) / AIEEE ds iz'u ¼fiNys o"kksZ½

9. Consider the reaction [AIEEE - 2010, 4/144]

fuEufyf[kr vfHkfØ;k ij fopkj dhft, % [AIEEE - 2010, 4/144]

;fn Ea2 = 2 Ea1, rc k1 rFkk k2 vkil esa bl izdkj lEcfU/kr gSa %

Initial Concentration Initial Concentration Initial rate of formation of C

The rate law for the formation of C is : [JEE(Main) - 2014, 4/120]

i zkj fEHkd l ka nz.k C cuusdhi zkj fEHkd nj

vfHkfØ;k ds fy, C cuus dk nj fu;e gksxk% [JEE(Main) - 2014, 4/120]

PART - II : JEE (ADVANCED) / IIT-JEE PROBLEMS (PREVIOUS YEARS)

3. Consider the chemical reaction, N2(g) + 3H2(g)  2NH3(g)

d [N2 ] 1 d [H2 ] 1 d [NH3 ] d [N2 ] d [H2 ] d [NH3 ]

d [N2 ] 1 d [H2 ] 1 d [NH3 ] d [N2 ] d [H2 ] d [NH3 ]

4. Given X  product (Taking 1st order reaction)

(A*) (B) (C) (D)