The document discusses organic compounds containing nitrogen. It provides 14 multiple choice questions related to the properties, reactions, and synthesis of various nitrogen-containing organic compounds. The questions cover topics like diazonium salt stability, solubility of amines, the products of aniline reactions, Gabriel phthalimide synthesis, relative basicity of amines, and mechanisms of amide reactions.
The document discusses organic compounds containing nitrogen. It provides 14 multiple choice questions related to the properties, reactions, and synthesis of various nitrogen-containing organic compounds. The questions cover topics like diazonium salt stability, solubility of amines, the products of aniline reactions, Gabriel phthalimide synthesis, relative basicity of amines, and mechanisms of amide reactions.
The document discusses organic compounds containing nitrogen. It provides 14 multiple choice questions related to the properties, reactions, and synthesis of various nitrogen-containing organic compounds. The questions cover topics like diazonium salt stability, solubility of amines, the products of aniline reactions, Gabriel phthalimide synthesis, relative basicity of amines, and mechanisms of amide reactions.
with aniline yields yellow dye. The name of the yellow dye is a) p-hydroxyazobenzene The final product is b) p-aminoazobenzene c) p-nitroazobenzene d) o-nitroazobenzene (2018) 8. Gabriel phthalimide synthesis is used in the preparation of primary amines from phthalimide, which of the following reagent is not used during the process? (2017) a) NaOH b) HCl c) KOH d) Alkyl Halides 2. Hinsberg’s reagent is (2020) 9. The correct order of increasing basic nature a) (CH3CO)2O/pyridine for the bases NH3, CH3NH2 and (CH3)2NH in b) C6H5SO2Cl aqueous solutions c) C6H5SO2NH2 a) CH3NH2 < NH3 < (CH3)2NH d) CH3COCl / pyridine b) CH3NH2 < (CH3)2NH < NH3 3. Which of the following is lest soluble in c) (CH3)2NH < NH3 < CH3NH2 water at 298 K? d) NH3 < CH3NH2 < (CH3)2NH (2017) a) CH3NH2 b) (CH3)3N c) (CH3)2NH d) C6H5NH2 (2019) 10. In the following sequence of reactions: 4. If aniline is treated with 1 : 1 mixture of conc. 𝑅𝑒𝑑𝑢𝑐𝑡𝑖𝑜𝑛 𝐻𝑁𝑂2 HNO3 and conc. H2SO4, p-nitroaniline and A → B → CH3CH2OH the m-nitroaniline are formed nearly in equal compound A is amounts. This is due to a) Propane nitrile b) Ethane nitrile a) m-directing property of – NH3 group c) Nitromethane d) Methyl isocyanate b) Protonation of – NH2 which causes (2016) deactivation of benzene ring 11. An organic compound A on reduction with c) m – and p – directing property of – NH2 Trichloro methane and caustic potash forms group C. The compound ‘C’ on catalytic reduction d) isomerization of some p-nitroaniline into gives N-methyl benzenamine, the compound m-nitroaniline (2019) ‘A’ is 5. Which of the following will be the most a) nitrobenzene b) nitromethane stable diazonium salt (R𝑁2+ X-)? c) methanamine d) benzenamine a) CH3𝑁2+ X- b) C6H5𝑁2+ X- (2016) c) CH3CH2𝑁2+ X- d) C6H5CH2𝑁2+ X- 12. One of the following amides will not undergo (2018) Hoffmann bromamide reaction: 6. Which of the following is more basic than a) CH3CONHCH3 b) CH3CH2CONH2 aniline? c) CH3CONH2 d) C6H5CONH2 a) Diphenylamine b) Triphenylamine (2015) c) p-Nitroaniline d) Benzylamine 13. In the sequence of following reactions: Organic Compounds Containing Nitrogen (Average Marks:2.5) For: KCET 2021
The starting compound ‘P’ is
a) m-nitrotoluene b) p-nitrotoluene c) o-nitrotoluene d) o-bromotoluene (2015) 14. In the given set of reactions: 𝑎𝑙𝑐.𝐴𝑔𝐶𝑁 ℎ𝑒𝑎𝑡 𝐿𝑖𝐴𝑙𝐻4 2-Bromopropane → X→ Y The IUPAC name of product Y is a) N-isopropylmethanamine b) N-methylpropan-2-amine c) N-methylpropanamine d) butan-2-amine (2015)