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Vibrant Academy: (India) Private Limited
Vibrant Academy: (India) Private Limited
Class Test-L
(India) Private Limited Target IIT ADVANCE-2021
(XII-MEGA) TIME : 60 MIN.
Single Choice Questions : [+3, –1][15 × 3 = 45]
ATTENTION: FILL BUBBLES IN OMR SHEET ACCORDING TO THE QUESTION NUMBERS SHOWN IN PAPER
NO2
(1) NaOH
2.
(A)
( 2) H3O
I
Br
Product (A) is
4. Which of the following compound is capable to show geometrical, optical and conformational isomerism ?
Br
H
(A) C == C == C == C (B) H2C = CH – CH – CH3
Cl Cl OH
(C) CH3 – CH = CH – CH2 – CH2 – OH (D) H2C = CH – CH2 – OH
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x H
5. value of x is
6. Mark the correct increasing order of reactivity of the following compounds with HBr/HCl.
NO2 Cl
(a) (b) (c)
(A) a < b < c (B) b < a < c (C) b < c < a (D) c < b < a
NO2 Cl CH3
7.
(a) (b) (c) (d)
Br CH2Cl
(C) NC CH2CN (D)
CN
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9. Increasing order of rate of reaction with HNO3/H2SO4 is :
O O O
O O O O O O
O O O
(A) (iii) < (ii) < (i) (B) (ii) < (iii) < (i) (C) (i) < (iii) < (ii) (D) (i) < (ii) < (iii)
O
CH2 – C AlCl3
10. O
CH2 – CH – C
O
O O
CO2H
(A) (B)
CO2H
O O
CO2H
(C) (D)
CO2H
| CH3
CH3
Me
H3O+
12. O A+B
18
Et
A and B will be
Me Me
18
(A) + , OH (B) + , OH
Et Et
Me
18
(C) OH , OH (D) No reaction
Et
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Comprehension (Q.13 to Q.15)
O O
(1) KMnO4 (1) CO2,NaOH CH3–C–O–C–CH3
(A) (B) (C) (D)
(2) NaOH / CaO / H (2) H Analgesic
Br2
Tri-bromo product
H2O
OH
OH OH OCH3
CH3
(A) (B) (C) (D)
CH3
CH3
OH OH
OH OH
CHO COOH
(A) (B) (C) (D)
CHO COOH
O O O O
C–OCH3 O–C–CH3 O–C–CH3 C–OCH3
COOH CHO COOH COOCH3
(A) (B) (C) (D)
O O
|| ||
(A) CH3 – C – NH2 (B) Ph – C – NH – Br
O O
|| ||
(C) Ph – C – NH – CH3 (D) CH3 – C – NH – Ph
NH2 CH3
(A) (B) NH2 (C) CH3 – CH2 – N – CH3 (D) CH3 – NH – CH3
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O OH
HO (1) CH3MgBr
(X)
18. H HCl (2) HCl, H2O
O
Possible final products are
OH
OH O OH
(A) O (B) (C) (D)
OH OH OH
OH
20. Which of following on acid catalyzed hydrolysis give positive Iodoform test.
O
(A) O (B)
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Class Test-L
1. D 2. B 3. D 4. A 5. B 6. C 7. D
8. A 9. D 10. B 11. B 12. B 13. B 14. B
15. C 16. CD 17. AB 18. AC 19. BD 20. ABCD
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