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Rapid Crash Course: Single Correct
Rapid Crash Course: Single Correct
MPP-1
Single correct :
Q.2 Four isomeric alcohols are possible for molecular formula C4H10O.
OH OH OH
OH
(a) (b) (c) (d)
Which of the following statement is true for given compounds?
(A) Correct boiling point order is a >b>c>d (B) Boiling point of b > a
(C) Boiling point of c > a (D) Solubility of c > d.
(A)
C
< C (B) <
O H O H
OCH3 O–CH3
(C) H 3C C N CH 3 > H 3C C N CH 3 (D) <
1
Comprehension :
Paragraph for question nos. 4 to 6
CHO CHO CHO CHO
H OH H OH H OH HO H
H OH H OH HO H HO H
H OH HO CH2OH HO H H CH 2OH
CH2OH H CH2OH OH
O2 N NO2
e c
H2 N COOH
NO2
f b
CH3 – HN SO3H
a
HO
NH–C–CH3
g
O
Q.7 How many moles of NaHCO3 will consume on reaction with 1 mole of this compound?
(A) 2 (B) 3 (C) 4 (D) 1
2
O
Q.10 Tautomers of the compound CH3—C is / are
O
OH O
CH3–C CH3–C
(A) (B)
O OH
O OH
(C) CH3—C (D) CH2=C
HO O
COOH COOH
H OH H OH
(A) & are diastereomer
H OH
H OH
COOH
COOH
H H H CHO
(B) C=C=C & C=C=C are enantiomer
CH3 CH3
Br H H Br
(D) & are identical compound.
H Br Br H
CH3 CH3
(A)
+ aq. AgNO3 (B)
+ 2K
3
Q.13 Which of the following is / are aromatic species.
COOH OH
H OH H CH3
(B) H2 N H H2 N H (Q) Diastereomer
CH3 COOH
4
Subjective :
Cl
Q.16 Cl
2 number of theoritically possible dichloro derivatives
h
Q.17 How many total isomers are possible from C3H6O and also find out the number of optically active
isomers?
Br
Br
Q.18 How many stereoisomers are possible for ?
Br Br
OH OH
O 2N NO2
SO3H
CH3CH2OH
NO2 NO2
COOH OH SO3H
O
COOH
OH
O2 N NO2
C CH NH2
NO2 OH
(a) Number of compounds which are aromatic (x).
(b) Number of compounds which can evolve H2 gas on reaction with Na metal (y).
#(c) Number of compounds which can evolve CO2 gas on reaction with NaHCO3 (z).
[If answer is x,y & z respectively, then fill 0xyz in OMR sheet]
5
ANSWER AND SOLUTION
Single correct :
Q.1 (D)
(a)
Hf OH (b)
C(1)
O COOH e > b > a > f > d > c
SO3H Resonance
Q.3 (C)
Q.4 (D)
Q.5 (C)
Q.6 (C)
Q.7 (A)
Sol. Those acids which are stronger than H2CO3 will react with NaHCO3.
Q.8 (B)
Sol. Aliphatic bases are stronger than aromatic bases. Greater the availability of lone pair greater the basic
strength.
O
CH2
O
Sol. (A) due to intramolecular H-bonding in Gauche form
Repulsion
CH3 CH3
CH3
(B)
CH3
(Anti) (Gauche)
(C) Stability of eclipsed form is less than staggered at room temperature.
6
Cl Cl
Cl
(D)
Cl
=0 0
On heating rate of interconversion from anti-Gauche increases therefore µ increases.
Q.10 (A, B, C, D)
O
Sol. All are tautomeric structures of CH3—C
O
Q.11 (C)
COOH
H OH
Sol. (A) The fisher projection of the newmann projection is
HO H , so both are diastereomers.
COOH
(B) Interchange at only one gemiral carbon will result enantiomers in chiral allenes.
(C) They are not isomers
(D) Both have COS so both are identical.
Q.12 (A, B, D)
Ph Ph
Sol. (A) + aq. AgNO3 Aromatic
Ph Ph
(B)
+ 2K Aromatic
OH
(C) + HBr Antiaromatic
OH
OH
(D) HBF4 Aromatic
7
Q.13 (A, B, C)
Sol. D is non aromatic due to tub shaped structure.
Subjective :
Q.16 9
Cl Cl Cl
Cl
Sol. (1) (3) [2 op-active + 1 meso]
Cl
Cl
Q.17 11, 2
CH3 CH3 OH CH 3 C CH 2
H CH 2 CH CH 2
Sol. (i) C=C (ii) C=C (iii) | (iv) |
H H OH OH
H OH
(v) CH 3 CH 2 C H (vi) CH 3 C CH 3 (vii) CH2 = CH – OCH3
|| ||
O O
Q.18 8
Sol. This symmetrical so the total number of stereoisomers is 23 = 8.
Q.19 5
Sol. Those molecules whose conjugate base are less basic than NaOH are soluble in NaOH.
Q.20 0684
Sol. x = 6 y=8 z=4