12.04.20 Sr.N-SUPERCHAINA Jee Adv 2019 P2 GTA-10 QP..
12.04.20 Sr.N-SUPERCHAINA Jee Adv 2019 P2 GTA-10 QP..
PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
One of More Correct Options Type
Sec – I (Q.N : 1 – 8) +4 -1 8 32
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – II (Q.N : 9 – 14) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +3 0 6 18
27.30)
Matrix Matching Type
Sec – III (Q.N : 15 – 18) (Each match consist of 2 questions)
+3 -1 4 12
Total 18 62
CHEMISTRY
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
One of More Correct Options Type
Sec – I (Q.N : 19 – 26) +4 -1 8 32
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – II (Q.N : 27 – 32) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +3 0 6 18
127.30)
Matrix Matching Type
Sec – III (Q.N : 33 – 36) (Each match consist of 2 questions)
+3 -1 4 12
Total 18 62
MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
One of More Correct Options Type
Sec – I (Q.N : 37 – 44) +4 -1 8 32
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – II (Q.N : 45 – 50) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +3 0 6 18
127.30)
Matrix Matching Type
Sec – III (Q.N : 51 – 54) (Each match consist of 2 questions)
+3 -1 4 12
Total 18 62
9 16
A) initial current in R3 A B) initial current in R2 A
110 110
8 7
C) initial current in R2 A D) initial current in R3 A
110 110
L1 R3 L1 R1 R1 R3
A) B) C) D) R1 R4 R2 R3
L2 R4 L2 R2 R2 R4
4. Work function of a metal X equals the ionization energy of Li 2 ion in second excited
state. Work function of another metal Y equals the ionization energy of He ion with
electron in n 4 . Now photons of energy E fall separately on both the metals such that
maximum kinetic energy of photoelectron emitted from metal X is half that of
photoelectron emitted from metal Y. Choose the correct statement (E0 = Potential
energy of electron in ground state of hydrogen atom)
A) E 3.5E0
7 E0
B) E
8
C) If E is increased, difference in maximum kinetic energies of photo electrons emitted
from X and Y increases
D) If E is increased, difference in maximum kinetic energies of photo electrons emitted
from X and Y remains constant
5. A uniform solid cylinder of mass M and radius R, rolling without sliding on a rough
horizontal plane, is pulled at its axis with a horizontal velocity of V0. By means of a
string of length 2R attached to its axis, the cylinder is dragging a thin plate of mass m =
2M lying on the plane. If the pulling force is removed and the coefficient of friction
between the cylinder and ground is sufficient enough for rolling always. (µ = 0.4, V0 =
2m/sec, R = 0.5 m, g = 10 m/sec2). Choose the CORRECT option (s) before the
cylinder comes to rest
o x
v0
R
Top View
C) During motion (before hitting) tension in the string will increase continuously.
A) The density variation and the longitudinal velocity of the particles have their
maxima and minima at the position of equilibrium of the particles
C) Greatest compression occurs at the same time and place where the velocity of the
particles is maximum and in direction of wave propagation
D) Greatest rarefraction occurs at the same time and place where the velocity of the
particles is maximum and in direction of wave propagation
10. Half life of a radioactive substance is 2.34 minute. It is produced at a constant rate of
108 nuclei per sec. How soon after (in minute), the beginning of production will its
11. A non conducting ring of radius R and mass m having uniform charge distribution q is
having a small cut of length b b R is released from rest with its plane parallel to a
uniform electric field of strength E as shown in the figure. If the maximum angular
CqEb
velocity of the ring is , then find the value of C ? (Neglect gravity)
22mR 2
13. Two narrow tunnels are dug through the earth as shown in figure. O is the centre of
earth. A particle B is released from rest from position shown and travels through the
tunnel. At the same time another particle P from A is released from rest. As the particle
P reaches the intersection of tunnels C for the first time distance travelled by B is
7 7
R . Where the value of k is..
k
SECTION-III
(MATCHING LIST TYPE)
This section contains 4 questions, each having two matching lists (List-1 & List-II). The options for the correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Matching 15 & 16.
Two point sound sources of same frequency ‘f’ amplitude 2A and 4A are situated at x =
0 and x = 20 respectively ( = wavelength of wave) on the x-axis. These sources are
vibrating in same phase. Four observers A, B, C and D are situated at
X A 4 , X B 8 , X C 12 and X D 16 respectively. The value of intensity observed
by another observer O situated exactly at midpoint of location of two sources is I 0 .
Observers A, B, C and D are tabulated in first List and in second List some quantities
36 A2 k
are given. (Given I 0 )
100
List-I gives the above four observers while List-II lists the magnitude of some quantit
List – I List – II
9
I) Observer A P)
16
49
II) Observer B Q)
144
4
III) Observer C R)
9
5
IV) Observer D S)
16
81
T)
64
10
U)
36
18. If the process is carried out on one mole of monatomic ideal gas is as shown in the TV-
1
diagram with P0V0 RT0 , the correct match is
3
SECTION – I
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -1 in all other cases.
19. Which of the following statement(s) is/are correct ?
1
A) A plot of log P vs is non linear (P=vapour pressure; T=temperature)
T
B) A plot of PV vs V is linear (P=pressure ; V=volume) for ideal gas at constant
temperature
x x
C) A plot of vs temperature for chemical adsorption is non linear ( =extent of
m m
adsorption)
D) A plot of Binding energy vs mass number is linear
20. Consider the following molecular structures
22. Which dicarboxylic acid on decarboxylation give only one organic product on gentle
heating?
H3C COOH
H3C CH3
COOH H3C COOH
A) HOOC B)
CH3 CH3
CH3
H3C CH3 H3C
HOOC COOH HOOC COOH
C) D)
23. Give the structure of nucleophile that could be used to convert the iodoethane into
CH 3.CH 2.S CH3
- + - +
H3C SK H3C SK
A) B)
- +
SK
Me
- +
C) Me D) SK
A) H 525 cal.
373
B) S 5ln 2ln 10
298
C) E 375cal
D) G of the process cannot be calculated using given information.
26. SO2 can reduce
A) H 2S / to S B) Cr2O72 / H to Cr 3
C) MnO4 / H to Mn2 D) Acidified IO3 aq to I 2
SECTION – II
(Numerical Value Answer Type )
This section contains 6 questions. The answer to each question is a Numerical values comprising of
positive or negative decimal numbers (place value ranging from Thousands Place to Hundredths place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme : +3 for correct answer, 0 in all other cases.
27.
VL VL
If we remove the wall in between the two container then change in entropy of mixing
is____________ J mol 1
K 1 (Given: R 8.3J K 1 mol1 , ln2 = 0.7)
O H
OH OH
CH3 O
CH3 OCH 3
,
H , H2C O ,
H
29. Two flasks A and B have equal volume of 100 K and 300 K and have pressure of 8 atm
& 1 atm respectively. The flask A contains H 2 gas & B contains CH 4 gas. The
30. How many of the following have only four hybrid orbitals on the central atom of its
molecules?
2
XeO3 , I 3 , XeF2 , H 2O, PCl5 , NiCl4 , Ni CO 4 , Ni CN 4 , SO42 , NH 4
2
H3C CH3
H2C CH3
SECTION-III
(MATCHING LIST TYPE)
This section contains 4 questions, each having two matching lists (List-1 & List-II). The options for the correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
33 & 34.
Answer the following questions by matching the thermodynamic process given under
column-I with the expression given under column-II.
Column – I Column – II
A) Freezing of water at 273K and 1 atm 1) q0
Column – I Column – II
-
High conc. C 2H5O
1) O 2N CH2 CH CH3
C2H5OD,
O 2N CH CH CH3
P) Rearrangement
Br
C2H5OH
2) H3CO CH CH2 CH3
H3CO CH CH CH3
Q) E1
Br
-
High conc. C 2H5O
3) O 2N CH2 CH CH3
C2H5OD,
O 2N CD CH CH3
R) E 2
Br
C2H5OH
4) H3CO CHD CH CH3
H3CO CH CD CH3 S) E1CB
Br
A) 1- Q B) 3 - S C) 2 - P D) 4 - S
A) 1 - R B) 2 - Q C) 3 - S D) 4 - R
4 4
A) S > 1 B) S < 1 C) S D) S
3 3
A) b 2 ac B) c 2 bd C) ad bc D) ab cd
40. Let Z , Z 2 , Z3 be complex numbers such that (i) Z1 Z 2 Z3 1 , (ii) Z1 Z 2 Z3 0
A) 1 B) 2 C) 3 D) 4
41. Let Z1 , Z 2 , ....... Z n be complex numbers of same modulus. Then necessarily true
statements are
n n Zj n n n n Zj
A) Re 0 Zk 0 B) Z k 0 Re Z 0
j 1 k 1 Z k
k 1 k 1 j 1 k 1 k
A)
c tan m 2 2 B)
c m 2 cot 2 tan
n m2 2 n m2 2
C)
c m 2 tan 2 2 cot 2 D)
c m2 2 for
n m 2 2
n m 2 2 4
SECTION – II
(Numerical Value Answer Type )
This section contains 6 questions. Each question is numerical value. For each question, enter the correct numerical
value (in decimal notation, truncated/rounded-off to second decimal place.
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30).
Marking scheme: +3 for correct answer , 0 if not attempted and 0 in all other cases.
1 1 1
45. The least value of x satisfying x is
[ x] [2 x] 3
c) x 1 divides ax 2 bx c
are given by 2 2 . Then =
48. Let cot 2 x cot 3x tan 2 x tan 7 x tan 5 x dx a ln (tan 2 x) b ln (sin 3x) c ln (sec 5 x)
d ln(cos 7 x) C where a, b, c, d Q and C is the constant of integration. If a b c d
m
can be expressed as in the lowest form, then m n equals
n
49. Given a right triangle ABC which is right angled at A with b c . If ha , wa and ma are
lengths of altitude, internal bisector and median from the vertex A respectively, then
ma ha
find the value of lim .
b c wa ha
If the area bounded by the curves f ( x) cos 1 cos x , g ( x) cos 1 cos x for x [0, ] is
2
50.
a 3 b 2 c , then a 5b c equals
SECTION-III
(MATCHING LIST TYPE)
This section contains 4 questions, each having two matching lists (List-1 & List-II). The options for the correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
51 & 52.
. Answer the following by appropriately matching the lists based on the information
given in the paragraph.
Let the circles C1 : x 2 y 2 9 and C2 : x 32 y 4 2 16 , intersect at the points X and
Y. Suppose that another circle C3 : x h 2 y k 2 r 2 satisfies and following
conditions:
i) centre of C3 is collinear with the centres of C1 and C2
ii) C1 and C2 both lies inside C3 , and
iii) C3 touches C1 at M and C2 at N.
Let the line through X and Y intersect C3 at Z and W, and let a common tangent of C1
and C3 be a tangent to the parabola x 2 8 y .
There are some expressions given in the List-I whose values are given in List-II below.
SR.IIT_N-SC/ N-C Page. No. 20
List – I List – II
I) 2h k P) 6
Length of ZW
II) Length of XY
Q) 6
21
IV) S)
5
T) 2 6
10
U)
3
I)
If the feet of perpendiculars from A and
B to the plane are P and Q P)
b a . n
n
respectively then the length of PQ is
II)
Reflection of A a in plane has
Q)
b a n
position vector n
1
T) a 2 d a . n n
n