DAILY PRACTICE PROBLEM

OF
PHYSICAL CHEMISTRY
FOR NEET

BY
JITENDRA HIRWANI

THERMODYNAMICS

ETOOSINDIA
INDIA’S NO. 1 ONLINE COACHING

Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar,
Kota, Rajasthan – 324005 Mob. : 9214233303
ETOOSINDIA J.H. SIR
INDIA’S NO. 1 ONLINE COACHING

DPP-1
1. Tea placed in thermos flask is an example of
(1) Open system (2) Close system (3) Isolated system (4) It can’t act as system
Ans. (3)
2. Gaseous system is placed with pressure P1, volume V1 and temperature T1, it has undergone thermodynamic changes
where temperature is remaining constant, it is
(1) Adiabatic process (2) Isothermal process
(3) Isobaric process (4) Isochoric process
Ans. (2)

A
3. The respective examples of extensive and intensive properties are

I
(1) Enthalpy, Entropy (2) Entropy, Enthalpy
(3) Entropy, Temperature (4) Temperature, Entropy

D
Ans. (3)
4. A thermally isolated gaseous system can exchange energy with the surroundings. The mode of energy may be
(1) Heat (2) Work

N
(3) Heat and radiation (4) Internal energy

I
Ans. (2)
5. A system absorbs 10kJ of heat and does 4 kJ of work. The internal energy of the system

S
(1) Decreases by 6 kJ (2) Increases by 6 kJ
(3) Decreases by 14kJ (4) Increase by 14 kJ
Ans. (2)
6.

Ans.
7.
(3)

O O
In a reaction, all reactant and products are liquid, then
(1) H > E (2) H < E (3) H = E (4) Can’t predicted

Regarding the internal energy of the molecule, which of the following statement is correct ?

T
(1) Its absolute value can be successfully calculated
(2) Its absolute value cannot be determined

E
(3) It is the sum of vibrational and rotational energies
(4) Both (1) & (2)
Ans. (2)
8. The specific heat of a gas is found to be 0.075 calories at constant volume and its formula wt. is 40. The atomicity of
the gas would be
(1) One (2) two (3) Three (4) Four
Ans. (1)
9. In a flask colourless N2O4 is in equilibrium with brown coloured NO2. At equilibrium when the flask is heated at 100°C,
the brown colour deepens and on cooling it becomes less coloured. The change in enthalpy, H for formation of NO2
is
(1) negative (2) Positive (3) Zero (4) Undefined
Ans. (2)
10. For the system S(s) + O2(g) SO2(g) :–
(1) H = E (2) H > E (3) E > H (4) H = 0
Ans. (1)

Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar, Page # 2
Kota, Rajasthan – 324005 Mob. : 9214233303
 ETOOSINDIA J.H. SIR
INDIA’S NO. 1 ONLINE COACHING

1
11. For the reaction CO (g) + O (g) CO2 (g)
2 2

Which one of the statement is correct at constant T and P ?

(1) H = E (2) H < E
(3) H > E (4) H is Independent of physical state of reactants
Ans. (2)
12. For which change H E :-

(1) H2(g) + I2(g)  2HI(g) (2) HCl () + NaOH () NaCl (s) + H2O ()
(3) C(s) + O2(g) CO2(g) (4) N2(g) + 3H2(g) 2NH3(g)

A
Ans. (4)

I
13. For the reaction PCl5(g)  PCl3(g) + Cl2(g)
(1) H = E (2) H > E (3) H < E (4) Can’t predicted

D
Ans. (2)
14. If ‘r’ is the work done on the system and ‘s’ is heat evolved by the system then,
(1) E = r + s (2) E = r – s (3) E = r (4) E = s

N
Ans. (2)

I
15. For the reaction
aA(s) + bB(g)  dD(s) + cC(g). Then

S
(1) H – E = (b – d) RT (2) H – E = (c – b) RT
(3) H – E = (a + b) – (c + d) RT (4) H – E = (a – d) RT
Ans. (2)
16.

O
For the given reaction, A D ; H = x . Steps involved are
A B ; H 1= x1

O
B C ; H 2= ?
C D ; H 3= x3

T
(1) H 2= x – (x1 + x3) (2) H 2= x + x1 + x3 (3) H 2= x1 – x3 – x (4) H 2= (x1 + x) – x3
Ans. (1)

E
Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar, Page # 3
Kota, Rajasthan – 324005 Mob. : 9214233303
ETOOSINDIA J.H. SIR
INDIA’S NO. 1 ONLINE COACHING

DPP - 2
1. The volume of a gas expands by 0.25 m at a constant pressure of 103N m–2. The work done is equal to
3

(1) 2.5 erg (2) 250 J (3) 250 watt (4) 250 newton
Ans. (1)
2. A cylinder contains either ethylene or propylene. 12 ml of gas required 54 ml of oxygen for complete combustion. The
gas is
(1) Ethylene (2) Propylene
(3) 1 : 1 mixture of two gases (4) 1 : 2 mixture
Ans. (2)

A
3. An athlete takes 100 g of glucose of energy equivalent to 1560 kJ. How much amount of energy is uptaken by 1 g

I
molecule of glucose ?
(1) 15.6 kJ (2) 2808 kJ (3) 1560 kJ (4) 28.08 kJ
Ans. (2)

D
4. C6H12 (l) + 9O2(g)  6H2O (l) + 6CO2 (g) ;
H298 = – 936.9 kcal. Thus

N
(1) –936.9 = E – (2 × 10–3 × 298 × 3) kcal (2) +936.9 = E + (2 × 10–3 × 298 × 3) kcal

I
(3) –936.9 = E – (2 × 10–3 × 298 × 2) kcal (4) –936.9 = E + (2 × 10–3 × 298 × 2) kcal
Ans. (1)
5. The heat change during the reaction 24g C and 128g S following the change C+S2CS2 ; H=22K cal

S
(1) 22 K cal (2) 11 K cal (3) 44 K cal (4) 32 K cal
Ans. (3)

O
6.
I

O
II

P III

T
IV
V

E
The plots between P and V which represent adiabatic and isothermal process respectively :
(1) I, IV (2) II, III (3) III, II (4) IV, I
Ans. (3)
7. Five moles of a gas is put through a series of changes as shown graphicallay in a cyclic process the A  B,
B  C and C  A respectively are
(1) Isochoric, Isobaric, Isothermal A B

(2) Isobaric, Isochoric, Isothermal

Volume

(3) Isothermal, Isobaric, Isochoric C

(4) Isochoric, Isothermal, Isobaric
Temperature
Ans. (1)
8. An electric heater of resistance 6 ohm is run for 10 minutes on a 120 volt line. The work done in this period of time is
(1) 7.2 × 103J (2) 14.4 × 105J (3) 43.2 × 104 J (4) 28.8 × 104J
Ans. (2)

Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar, Page # 4
Kota, Rajasthan – 324005 Mob. : 9214233303
 ETOOSINDIA J.H. SIR
INDIA’S NO. 1 ONLINE COACHING

9. In a closed insulated container, a liquid is stirred with a paddle to increase its temperature. In this process, which of
the following is true

(1) E  W  Q  0 (2) E  0, Q  W  0 (3) E  W  0, Q  0 (4) E  Q  0, W  0

Ans. (3)
10. A vessel contains 100 litres of a liquid X. Heat is supplied to the liquid in such a fashion that, Heat given = change in
enthalpy. The volume of the liquid increases by 2 litres. If the external pressure is one atm, and 202.6 Joules of heat were
supplied then, [U - total internal energy]
(1) U = 0 , H = 0 (2) U = + 202. 6J , H = + 202.6 J
(3) U = – 202.6J, H = – 202.6J (4) U = 0, H = + 202.6J
Ans. (4)
11. The correct figure representing isothermal and adiabatic expansions of an ideal gas from a particular initial state is

P P P P

I A
D
isothermal
(1) isothermal (2) adiabatic (3) isothermal (4) adiabatic
adiabatic isothermal adiabatic
V V V V

Ans.
12
(1)

I N
Consider the cyclic process R  S  R as shown in the Fig. You are told that one of the path is adiabatic and

S
the other one isothermal. Which one of the following is(are) true?

O
P
0
S
V

Ans.
13.
(4)

TO
(1) Process R  S is isothermal
(3) Process R  S is adiabatic
(2) Process S  R is adiabatic
(4) Such a graph is not possible

50 L of a certain liquid is confined in a piston system at the external pressure 100 atm. This pressure is suddenly

E
released and liquid is expanded against the constant atmospheric pressure, volume of the liquid increases by 1 L and
the final pressure on the liquid is 10 atm. Find the workdone.
(1) 1L.atm (2) 5 L.atm (3) 500 L.atm (4) 50 L.atm
Ans. (1)
14. Select the correct set of statement/s :
. Work done by the surrounding in case of infinite stage expansion is more than single stage expansion
. Irreversible work is always greater than reversible work. (with sign)
. On an ideal gas in case of single stage expansion and compression system as well as surrounding are restored
back to their original states
V. If gas is in thermodynamic equilibrium is taken from state A to state B, by four successive single stage
expansions. Then we can plot 4 points on the P-V indicator diagram.
(1)  (2) , , , V (3) , V (4) , , V
Ans. (1)

Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar, Page # 5
Kota, Rajasthan – 324005 Mob. : 9214233303
 ETOOSINDIA J.H. SIR
INDIA’S NO. 1 ONLINE COACHING

15. A sample of liquid in a thermally insulated container (a calorimeter) is stirred for 2 hr. by a mechanical linkage to a motor
in the surrounding, for this process :
(1) w < 0; q = 0; U = 0 (2) w > 0; q > 0; U > 0 (3) w < 0; q > 0; U = 0 (4) w > 0; q = 0; U > 0
Ans. (4)
16. Match the entries of column I with appropriate entries of column II and choose the correct option out of the four
options (1), (2), (3) and (4).
Column I Column II
(X) Isothermal (p) T = 0
(Y) Isobaric (q) V = 0
(Z) Adiabatic (r) P = 0

A
(W) Isochoric (s) q = 0

Ans.
(1) X–p, Y–q, Z-r, W-x
(2)
(2) X–p, Y–r, Z-s, W-q (3) X–s, Y–p, Z-r, W-q

D I
(4) X–s, Y–p, Z-q, W-r

I N
O S
TO
E
Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar, Page # 6
Kota, Rajasthan – 324005 Mob. : 9214233303
ETOOSINDIA J.H. SIR
INDIA’S NO. 1 ONLINE COACHING

DPP - 3
1. For stretched rubber, Entropy
(1) Increases (2) First increases then decreases
(3) Decreases (4) First decreases then increases
Ans. (3)
2. The least random state of H2O is
(1) Ice (2) Liquid water
(3) Steam (4) Randomness is same in all
Ans. (1)

A
3. What is the increase in entropy when 11.2 L of O2 are mixed with 11.2 L of H2 at STP ?

I
(1) 0.576 J/K (2) 5.76 J/K (3) 7.56 J/K (4) 2.76 J/K
Ans. (2)
4. The standard free energy change G° is related to K (equilibrium constant) as

Ans.
(1) G° = –2.303 RT logK
(3) G° = RT logK
(1)
D
(2) G° = 2.303 RT logK
(4) G° = – RT logK

N
I
5. When two gases are mixed the entropy :–
(1) Remains constant (2) Decreases (3) Increases (4) Becomes zero

S
Ans. (3)
6. The ent halpy of vapor izati on for wa ter is 186.5 KJ mol–1, the entropy of its vaporization will be-
(1) 0.5 KJK–1 mol–1 (2) 1.0 KJK–1 mole–1 (3) 1.5 KJ K–1 mole–1 (4) 2.0 KJK–1 mole–1

O
Ans. (1)
7. In a spontaneous irreversible process the total entropy of the system and surroundings
(1) Remains constant (2) Increases (3) Decreases (4) Zero
Ans.
8.

Ans.
(2)

O
What is the sign of G for the process of ice melting at 283 K ?

T
(1) G > 0
(3)
(2) G = 0 (3) G < 0 (4) None of these

E
9. For an endothermic reaction to be spontaneous
(1) G = 0 (2) G > 0 (3) G < 0 (4) G may be +ve or -ve
Ans. (3)
10. At 27°C the reaction,
C6H6(l) + 15/2 O2(g)  6CO2(g) + 3H2O(l)
Proceeds spontaneously because the magnitude of
(1) H = TS (2) H > TS (3) H < TS (4) H > 0 and TS < 0
Ans. (2)
11. Mixing of non-reacting gases is generally accompanied by
(1) Decrease in entropy (2) Increase in entropy
(3) Change in enthalpy (4) Change in free energy
Ans. (2)

Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar, Page # 7
Kota, Rajasthan – 324005 Mob. : 9214233303
 ETOOSINDIA J.H. SIR
INDIA’S NO. 1 ONLINE COACHING

12. Two mole of an ideal gas is expanded irreversibly and isothermally at 37ºC until its volume is doubled and 3.41 kJ heat
is absorbed from surrounding. Stotal (system + surrounding) is :
(1) –0.52 J/K (2) 0.52 J/K (3) 22.52 J/K (4) 0
Ans. (2)

3
13. If G = – 177 K cal for (1) 2 Fe(s) + O (g)  Fe2O3 (s)
2 2

and G = – 19 K cal for (2) 4 Fe2O3 (s) + Fe(s)  3 Fe3O4 (s)

What is the Gibbs free energy of formation of Fe3O4(s) ?

(1) + 229.6 kcal/mol (2) – 242.3 kcal/mol (3) – 727 kcal/mol (4) – 229.6 kcal/mol

A
Ans. (2)
14.

Ans.
Which one of the following has S0 greater than zero

(1) CaO (s) + CO2(g)

(3) NaNO3(s)
(3)
CaCO 3 (s)

Na+ (aq) + NO3– (aq)

(2) NaCl (aq)

D
(4) N2 (g) + 3H2 (g)
NaCl (s)

2NH3 (g) I
N
15. What is the change in entropy when 2.5 mole of water is heated from 27ºC to 87ºC ? Assume that the heat capacity is

I
constant. (Cp,m (H2O) = 4.2 J/g-K ln (1.2) = 0.18)
(1) 16.6 J/K (2) 9 J/K (3) 34.02 J/K (4) 1.89 J/K

S
Ans. (3)
16. Consider the Gºƒ and Hºƒ (kJ/mol) for the following oxides. Which oxide can be most easily decomposed to form the
metal and oxygen gas ?

O
(1) ZnO (Gº = –318.4, Hº = –348.3) (2) Cu2O (Gº = –146.0, Hº = –168.8)
(3) HgO (Gº = –58.5, Hº = –90.8) (4) PbO (Gº = –187.9, Hº = –217.3)

O
Ans. (3)

E T

Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar, Page # 8
Kota, Rajasthan – 324005 Mob. : 9214233303