EOR Notes
EOR Notes
Oil recovery
-primary
-secondary
-tertiary(EOR,IOR)
Primary
Result from the use of natural energy present in a
reservoir as the main source of energy for the
displacement of oil to producing wells.
-solution gas drive, gas cap drive, natural water drive
fluid and rock expansion, gravity drainage.
Secondary
Result from the augmentation of natural energy through
injection of water or gas to displaced oil toward
producing well
-gas injection is either into a gas cap for pressure
maintenance and gas cap expansion or into the oil column
to displace oil immiscibly according to relative
permeability and volumetric sweepout consideration.
-Gas processes based on other mechanisms, such as oil
swelling, oil viscosity reduction, or favorable phase
behavior, are considered EOR processes.
Tertiary
-Result from the injection of gases or liquid chemicals
and the use of thermal energy.
-The use of gas is considered as EOR process if the
recovery efficiency significantly depend on a mechanism
other than immiscible frontal displacement characterized
by high interfacial tension.
-EOR processes involve the injection of a fluid or fluids
of some type into a reservoir.
The size of the fluid slugs that are injected and their unit costs
-the nature of flow in porous media and rock/fluid interactions lead to the
diminished effectiveness of injected fluid slugs.
-Highy toxic or corrosive fluids, or fluids that are not readily injected, are not very
amenable to use in EOR processes.
The availability of an EOR fluid
-If an EOR process is applied in a major reservoir, the fluid requirements for that
single reservoir can be quite large.
- And if that process is widely accepted for application across the country or the
world, the volume requirements can become an important limiting factor for its
application.
Mobility control
A solution of partially hydrolyzed polyacrylamide
polymer in brine is injected to displace oil (and associated
water) toward production wells. Polymer solutions are
designed to develop a favorable mobility ratio between
the injected polymer solution and the oil/water bank being
displaced ahead of the polymer. The purpose is to develop
a more uniform volumetric sweep of the reservoir, both
vertically and areally
CO2 dynamic miscible process
Through multiple contacts between the CO2 and oil phase, intermediate- and
higher-molecular-weight hydrocarbons are extracted into the CO2 rich phase.
Under proper conditions, this CO2-rich phase will reach a composition that
is miscible with the original reservoir oil.
Miscible
MME- the minimum enrichment at which the limiting tie line pass through injected
gas phase composition
MMP
the porous medium in tubing is filled with crude oil from a reservoir to be
consider for immiscible displacement
the system is brought to test temperature
the back pressure regulator is set at desire displacement pressure
the displacing fluid is injected at constant rate
the pressure drop across the system should be set and measured
the hydrocarbon recovery at displacing fluid breakthrough, recovery at the
time of injection for a specified number of PV and ultimate hydrocarbon
recovery are recorded
recoveries as a function of displacement pressure are plotted
the MMP is assume to be the pressure at the break in the curve
MME
MMP measurement
Type of polymer
Polyacrylamide
Polysaccharide
Polyacrylamide
Characteristic
Polymer stability
Oxidative attack
Temperature
Bacterial attack
Polymer degradation also results from bacterial attack. Biopolymers are
susceptible to biological attack resulting in the loss of solution viscosity
from the destruction of the carbohydrate backbone
For this reason, the polymer broth usually contains a bactericide, such as
formaldehyde, to control bacterial growth.
This effect is consider because bacteria could be transported appreciable
distances through porous rock
Polymer rentention
Sources of retention:
Adsorption on the surface of the porous material and mechanical entrapment
in pores that are small relative to the size of the polymer molecule in
solution.
hydrodynamic retention- Occur when flow rates are suddenly increased after
polymer has been injected at a constant rate until a steady state condition has
been attained-i.e., until the effluent concentration has reached the injected
concentration.
Inacessible PV
Polymer molecules are larger than water molecules and are large relative to
some pores in a porous rock.
Because of this, polymers do not flow through all the pore space contacted
by the brine. The fraction of the pore space not contacted by the polymer
solution is called the inaccessible PV.
The ratio of the brine mobility before contact with polymer, λw to the brine
mobility after all mobile polymer has been displaced from the pore space λwp.
Frr = residual resistance factor for the porous matrix after Contact with a particular
polymer solution,
kwp = permeability of the porous matrix to brine after contact with polymer
solution
kw = initial brine permeability. The permeability to brine after the mobile polymer
has been displaced
kwp, is assumed to be the same as the permeability of the porous medium to the
flow of polymer, kp
The resistance factor, Fr is the ratio of the brine mobility in the porous medium
before polymer contact to the polymer mobility in the same porous medium
and is defined by
POLYMER GEL
Applications:
To reduce water cut in production well
Control profile in injectors
Partially hydrolyzed polyacrylamide
In the pure state the polymer is electrically neutral, seeming to prevent any cross
linking through ionic bond. By reaction with base these polymer acquire negative
charge because some of the amide group is converted to carboxyl group
Cross linkers
The polymer molecule are bound together into a gel structure through of a
crosslinking chemical agent such Cr(III) or Al(III). They can be extracted from
chromium acetate or aluminum citrate because they are not exist in the nature.
When metal ions such as Cr3+, Fe3+, Al3+, and Zr4+ are added to a
partially hydrolyzed polyacrylamide solution, a reaction occurs between the
carboxyl group and the metal ion.
Polyacrylamide molecules are flexible coils in dilute solutions and are
isolated from each other when the polymer concentration is less than C - the
critical overlap concentration.
If a further reaction occurs between the initial metal ion-carboxyl complex
and another carboxyl group on the same polymer chain, intra-molecular
crosslinks form.
Due to additional metal ion complexes reacting with the polymer chain, the
average molecular weight of the metal ion-polymer complex, termed a pre-
gel aggregate, increases slightly.
When the polymer concentration exceeds C, intermolecular crosslinks can
occur between two or more polymer molecules, and the molecular weight of
each complex increases in proportion to the extent of crosslinking.
Continued intermolecular crosslinking may lead to the formation of an
infinite network of crosslinks between polymer-metal ion complexes,
leading to the formation of a gel and the immobilization of the solution.
CHEMICAL FLOODING
SURFACTANT
Surfactants may be classified according to the ionic nature of the head group:
Anionic
Cationic
Nonionic
Zwitterionic
Cationics are usually not used because they adsorb strongly on reservoir rocks.
Problem: Crude oil and petroleum sulfonates have been used for low salinity
applications
The characteristics and structure of petroleum sulfonates suitable for EOR
applications depend on:
If the solvent is water, the micelles form with the tail portion directed inward and
the head (polar) portion outward. Water would be the continuous phase
Alkaline agent
Sodium hydroxide
Ammonium hydroxide
Sodium orthosilicate
Sodium carbonate
Ammonium carbonate
The hydroxide ion must react with a petroleum acid from the crude oil to form a
surfactant
Some of the petroleum acid in the crude oil partitions into the aqueous phase
surfactants
macromolecules
finely divided solids.
Foam structure
LAMELLA: region that encompasses the thin film, the two interfaces on either
side of the thin film, and part of the junction to other lamellae
• gravity drainage
• capillary suction
• surface elasticity
• viscosity (bulk and surface)
• electric double-layer repulsion
• dispersion force attraction
• steric repulsion
Gravity drainage
This liquid will drain by flowing downward through the interior of the lamellae.
Capillary suction
At the Plateau borders the gas-liquid interface is quite curved, and this curve
generates a low pressure region in the Plateau area (as shown by the Young-
Laplace Equation). Because the interface is flat along the thin-film region, a higher
pressure resides here. This pressure difference forces liquid to flow toward the
Plateau borders and causes thinning of the films and motion in the foam.
Surface elasticity
Viscosity
The bulk viscosity will most influence the thinning of thick films, and the surface
viscosity will be dominant during the thinning of thin films. Stability would vary
according to the effect of temperature on the viscosity
Because the interfaces on each side of the thin-film are equivalent, any interfacial
charge will be equally carried on each side of the film. If a foam film is stabilized
by ionic surfactants, then their presence at the interfaces will induce a repulsive
force that opposes the thinning process. The magnitude of the force will depend on
the charge density and the film thickness. Having a charged interface influences
the distribution of nearby ions in a polar medium. Ions of opposite charge
(counterions) are attracted to the surface, while those of like charge (coions) are
repelled. An electric double layer, which is diffuse because of mixing caused by
thermal motion, is thus formed.
Dispersion force attraction
Neutral molecules exert forces of attraction on each other that are caused by
electrical interactions between three types of dipolar configurations. The attraction
results from the orientation of dipoles that may be
Disjoining pressure
When the two interfaces that bind a foam lamella are electrically charged, the
interacting diffuse double layers exert a hydrostatic pressure that acts to keep the
interfaces apart. The disjoining pressure represents the net pressure difference
between the gas phase (bubbles) and the bulk liquid from which the lamellae
extend , and is the total of electrical, dispersion, and steric forces (per unit area)
that operate across the lamellae
Foam generation
Snap off
The snap off mechanism occur at low capillary pressure when a film or a collar of
water accumulate in the throat. The collar swells and bridge the throat blocking gas
flow and leading to creation of new lamella
Lamella Division
The oil drop first enters one of the film surfaces and forms a lens.
On further thinning of the film the lens enters the opposite film surface and
an oil bridge is formed.
The bridge is unstable because the capillary forces dewet the film from the
bridge and the film ruptures.
The arrows in the film indicate the direction of capillary forces.
Oil emulsion
When the pseudoemulsion film is stable, the oil drop enhance the foam stability;
when the film is unstable, the oil act as antifoam
Leave behind
Two gas menisci invade adjacent liquid-filled pore-bodies (Figure 7a). A lens is
left behind as the two menisci converge downstream. As long as the capillary
pressure of the medium is not too high, and the pressure gradient is not too large, a
stationary stable lens emerges (Figure 7b).
Bacteria
Fungi
Archaea
Protists
Plankton
Planarian
Aneroabic microbe: is any microorganism that does not require oxygen for
growth
Nutrient: is a chemical that a microorganism needs to live and grow which must
be taken in from its environment such as nitrates, molasses, phosphate
Metabolites: are the product of a set of chemical reaction that happen in living
microorganism to maintain live.
The gases are form in-situ due to fermentation of carbon sources such as glucose
by usually anaerobic bacteria. This gases dissolve the crude oil and than reduce its
viscosity. The gases also increase the pressure of the reservoir.
Production of biomass
When microorganism metabolize the nutrient they need for survival, they produce
organic biomass as a by product. This biomass accumulate between the oil and the
rock surface of the well, physically displacing the oil and making it easier to
recover from the well.
Selective plugging
Production of biosurfactant
Production of biopolymer
Bacteria reduce the permeability of highly permeable zone or of the water channel
that form in heterogeneous reservoir. Thus the unswept formations are invaded by
the water and sweep efficiency increase
Production of acid dissolve the rock matrix or carbonates thus increasing the pore
size and permeability.
MEOR process
wellbore clean up
well stimulation
enhanced water floods
Classification of MEOR
Surface MEOR :
biosurfactant (rhamnolipid)
biopolymer(xantan gum)
enzyme
Underground MEOR:
microorganism
nutrients
other additive
Underground MEOR
Limitation of MEOR
Parameter requirement
Lithology
Porosity and permeability 10-30% , above 75md
Temperature Less than 75°C
Salinity Less than 10% W/V
pH Between 4 and 9
API gravity Greater than 18°
1. Under proper condition of pH and ionic strength, clay and rock posses
charge on their surface that act to absorb bacteria and inhibit their migration
through the porous media
2. Bacteria have length of 0.5-10µm and width of 0.5-2 µm. pore size of less
than 0.5 µm will place severe restriction to the movement of them.
Permeability of 75-100md are thought to be lower limit for effective
microbial transport
3. Geothermal gradient are commonly 1-2°F/100ft. it is found that greater than
90% of the reservoir in all state have temperature of less than 185-210°F (85-
99°C using 1000ft as the limiting depth
4. Increasing salinity absorb water from the microbes and negatively effect its
growth
5. Microorganism grow optimally between a pH of 4 and 9
6. Crude oils with API gravity of less than 18 are generally consider as heavy.
Because the heavier the crude the more difficult it is to recover using
chemical means due to unfavorable mobility ratios between brine and oil
Displacement fundamental
Surface tension and IFT
Surface tension: The force acting in the plane of the surface per unit length of the
surface.
Consider the two immiscible, fluids, air (or gas) and water (or oil), as shown
schematically in Figure 2-2. A liquid molecule, which is remote from the interface,
is surrounded by other liquid molecules, thus having a resulting net attractive
force on the molecule of zero. A molecule at the interface, however, has a force
acting on it from the air (gas) molecules lying immediately above the interface
and from liquid molecules lying below the interface. Resulting forces are
unbalanced and give rise to surface tension.
Assuming the radius of the capillary tube is r, the total upward force Fup, which
holds the liquid up, is equal to the force per unit length of surface times the total
length of surface,
The upward force is counteracted by the weight of the water, which is equivalent
to a downward force of mass times acceleration
Phase trapping
Pressure in the oil phase would exceed the pressure in the water phase by the value
of Pc, but there would be no net pressure change across the drop.
If rb < ra, then PA >PB and a pressure drop exists in the direction from Point A to B.
If θa > θb and cos θa < cos θb pressure drop exists in the direction from Point A to B.
IFT and contact angles are different at the two interfaces because the fluid systems
are different. Again, if σgo cos θb > σgw cos θa a pressure drop exists from Point A to
B when this system is static.
Capillary number
The dimensionless group, or variations of the group, are called the capillary
number. In this text, the capillary number is defined as in Eq. 2.30, but without the
cos θ term. Therefore
If Darcy's law is introduced into Eq: 2.31 and Darcy velocity is used,
Nca could be increased to more than about 10-5 in a flood, then the magnitude of
residual oil would decrease.
•Micellar/surfactant polymer
flooding
•Alkaline flooding
•Alkali-surfactant flooding
•Alkali-surfactant-polymer flooding
•Polymer flooding
Alkali-surfactant-polymer flooding
In the Alkaline Surfactant Polymer (ASP) process, a
very low concentration of the surfactant is used to
achieve ultra low interfacial tension between the
trapped oil and the injection fluid/formation water.
The alkali then reacts with the acidic components in
the crude oil to form additional surfactant in-situ,
thus, continuously providing ultra low interfacial
tension and freeing the trapped oil
In the ASP Process, polymer is used to increase the
viscosity of the injection fluid, to minimize
channeling, and provide mobility control.
Polymer flooding