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Fiitjee: JEE (Advanced), 2013
Fiitjee: JEE (Advanced), 2013
From Long Term Classroom Programs and Medium / Short Classroom Program 4 in Top 10, 10 in Top 20, 43 in Top 100, CONCEPT RECAPITULATION TEST
(Set – VI)
Paper 2
75 in Top 200, 159 in Top 500 Ranks & 3542 t o t a l s e l e c t i o n s i n I I T - J E E 2 0 1 2
Y o u a r e n o t a l l o we d t o l e a v e t h e E x a m i n a t i o n H a l l b e f o r e t h e e n d o f
the test.
INSTRUCTIONS
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part is further divided into three sections: Section-A, Section-B & Section–C.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers
on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with black pen for each character of your
Enrolment No. and write your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Three Parts.
(i) Section-A (01 – 08) contains 8 multiple choice questions which have only one correct answer.
Each question carries +3 marks for correct answer and – 1 mark for wrong answer.
Section-A (09 – 12) contains 4 multiple choice questions which have more than one correct
answer. Each question carries +4 marks for correct answer. There is no negative marking.
(ii) Section-B (01 – 02) contains 2 Matrix Match Type questions containing statements given in 2
columns. Statements in the first column have to be matched with statements in the second
column. Each question carries +8 marks for all correct answer. For each correct row +2 marks
will be awarded. There may be one or more than one correct choice. No marks will be given for
any wrong match in any question. There is no negative marking.
(iii) Section-C (01 – 06) contains 6 Numerical based questions with single digit integer as answer,
ranging from 0 to 9 and each question carries +4 marks for correct answer. There is no negative
marking.
Enrolment No.
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2
Useful Data
PHYSICS
Acceleration due to gravity g = 10 m/s2
CHEMISTRY
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Physics PART – I
SECTION – A
Single Correct Choice Type
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.
Rough work
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Gaussian
surface
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R/4
R/2
earth
P0 A C
V
V0 2V0
7. If nuclei of a radioactive element is produced at constant rate α and they decays with decay
constant λ. At t = 0, number of nuclei is zero than the number of nuclei at time t is
α α
(A) (1 − e −λt ) (B) α − e−λt
λ λ
α −λt
(C) e (D) α(1 − e −λt ) .
λ
Rough work
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8. For a certain plane reflecting surface, the unit vector along the incident ray is î and that along the
î 3
outward normal of the surface is − − ĵ . The unit vector along the reflected ray will be
2 2
î 3 î 3
(A) + ĵ (B) − ĵ
2 2 2 2
3ˆ ˆ 3 ˆ 1ˆ
(C) − i+j (D) − i− j
2 2 2
9. If B and E denote induction of magnetic field and magnetic energy density at the midpoint of
along solenoid carrying a current I, then which of the following graphs is/are correct?
(A) B (B) E
I I
(C) E (D) E
B B
Rough work
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(A) At any instant voltage across R increases at that instant magnitude of potential difference
across inductor and capacitor simultaneously increases or decreases
(B) Reading of all other voltmeters are also equal to 100 V
(C) When S1 and S2 both closed reading of V4 remains 100 V
(D) When S1 closed and S2 is opened reading of V4 decreases
(C) the waves reaching on the screen at C from S1 will lead the waves reaching from S2
(D) the waves reaching C from S1 will lag from the waves reaching from S2
Rough work
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SECTION - B
Matrix – Match Type
This section contains 2 questions. Each question contains statements given p q r s t
in two columns, which have to be matched. The statements in Column I are
A p q r s t
labelled A, B, C and D, while the statements in Column II are labelled p, q, r,
s and t. Any given statement in Column I can have correct matching with B p q r s t
ONE OR MORE statement(s) in Column II. The appropriate bubbles
corresponding to the answers to these questions have to be darkened as C p q r s t
illustrated in the following example:
If the correct matches are A – p, s and t; B – q and r; C – p and q; and D – s D p q r s t
and t; then the correct darkening of bubbles will look like the following:
1. In LCR series circuit suppose ωr is the resonance frequency, then match the following table.
Column – I Column – II
(A) If ω > ωr (p) current will lead the voltage
(B) If ω = ωr (q) voltage will lead the current
(C) If ω = 2ωr (r) XL = 2XC
(D) If ω < ωr (s) Current and voltage are in phase
(t) none of these
(D) Friction force on P when both block is coming (s) At extreme position
towards the equilibrium position from right.
(exclude the equilibrium position)
(t) none of these
Rough work
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SECTION –C
Integer Answer Type
This section contains 6 questions. The answer to each question is a single digit integer, ranging from 0
to 9 (both inclusive).
1. A point charge –Q is placed at the centre of a uniformly charged ring of charge Q. Electric field at
1
a point on the axis of ring at a distance x (x >>R) varies as Eα find n.
xn
θ
C D
2. A ray of light traveling in glass (µ = 3/2) is incident on a Water O r
A
horizontal glass air surface at the critical angle θC. If a thin B
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R
4. A perfectly reflecting solid sphere of radius r is P Q
kept in the path of a parallel beam of light of
large aperture. If the beam carries an intensity
I, The force exerted by the beam on the sphere
O Z
πr 2kI θ
is . Find the value of k.
2c
6. A point charge q is placed at the centre of hollow conducting sphere of inner radius R and outer
radius 2R. Work done required to slowly remove the point charge from centre to infinity (through a
1 Q2
small orifice) is find n.
n 4πε 0 R
Rough work
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Chemistry PART – II
SECTION – A
This section contains 8 multiple choice questions numbered 1 to 8. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE is correct.
1. Nylon – 6, 10 is obtained by
(A) condensation of adipic acid &hexamethylenediammine.
(B) condensation of ethylene glycol and Phthalic acid
(C) condensation of melamine and formaldehyde
(D) hexamethylenediammine and sebacic acid [HOOC-(CH2)8-COOH]
2. The vapour pressures of two pure liquids ‘A’ and ‘B’ that form an ideal solution are 100 and 500
torr respectively at temperature ‘T’. This liquid solution of A and B is composed of 1 mole of ‘A’
and 1 mole of B. What will be the pressure when given of mixture has been vaporized?
(A) 800 torr (B) 500 torr
(C) 300 torr (D) 400 torr
4. When 1 g oxalic acid is burnt in a bomb calorimeter whose heat capacity is 8.75 kJ/K the
temperature increases by 0.312 K. The enthalpy of combustion of oxalic acid at 27oC is
(A) – 240.7 kJ/mol (B) – 245.7 kJ/mol
(C) – 246.95 kJ/mol (D) – 180 kJ/mol
5. 10 mole of an ideal gas is heated at constant pressure of one atmosphere from 27oC to 127oC if
CV.m= 20 + 10-2 T. Jk-1 mol-1 then, ∆H for the process is [T is temperature in Kelvin, assuming Cv
does not changes with temperature]
(A) 3000 J (B) 3350 J
(C) 3700 J (D) 30350 J
Rough work
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Fe+2
(A) (B)
+
Na
(C) (D)
HCl ( gas )
H CH3
→' X '
OH
(A) O (B) O
HO Me
H
H O O OH
(C) Both (A) and (B) is equal amounts (D) O O
Cl
8. An aqueous solution containingPb++, Cu++, Hg++, Ca++, Bi+++, Co+++, Mn++, Ni++, Zn++cation subject
to precipitated as sulphide by passing H2S gas which one is true regarding
(A) all cations are precipitated in high concentration of HCl acid.
(B) Pb++, Cu++, Hg++, Cd++, Bi+++will not be precipitated in high concentration of HCl acid.
(C) all cations are precipitated in the solution made basic by sodium hydroxide.
(D) only Co3+, Mn++, Ni++, Zn++ will be precipitated in the basic buffer of NH4OH and NH4Cl.
Rough work
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This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out which ONE OR MORE is/are correct.
Rough work
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SECTION-B
(Matrix Type)
This section contains 2 questions. Each question contains statements given p q r s t
in two columns, which have to be matched. The statements in Column I are
A p q r s t
labelled A, B, C and D, while the statements in Column II are labelled p, q, r,
s and t. Any given statement in Column I can have correct matching with B p q r s t
ONE OR MORE statement(s) in Column II. The appropriate bubbles
corresponding to the answers to these questions have to be darkened as C p q r s t
illustrated in the following example:
D p q r s t
If the correct matches are A – p, s and t; B – q and r; C – p and q; and D – s
and t; then the correct darkening of bubbles will look like the following:
Ph
(B) CH3 O (q) Enantiomers
H CH3
H D
NaOI
→
CH3
(C) CH3 O O (r) Single optically active compound
H C CH2 C OH
∆
H D →
CH3
(D) COOH (s) No reaction
O
Rough work
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SECTION –C
Integer Answer Type
This section contains 6 questions. The answer to each question is a single digit integer, ranging from 0
to 9 (both inclusive).
1. In an atom two electrons move around the nucleus in circular orbit of radii R and 4R. The ratio of
the time taken by them to complete one revolution is 1: x , where x is
2. SrTiO3 has a cubic unit cell in which Ti is present at cube centre and O at each face centre and
Sr at each corner if co-ordination number of Sr is 2x. Find x.
3. A metal has a density of 4.54 g/cc and an edge length of 412.6 pm. (Molecular weight of metal =
48 g mol–1). Find the rank of unit cell.
4. The compound AX4 is tetrahedral. What is the number of ∠XAX formed in the compound.
5. A compound of iron and chlorine (FeClx) is soluble in water. An excess of silver nitrates was
added to precipitate the chloride ion as silver chloride. If a 134.8 mg of the compound gave 304.8
mg of AgCl. What is the value of x?
6. A compound ‘A’ ( C5 H 9 Br ) doesn’t react with Br2 water, but forms ‘B’ ( C5 H8 ) on treatment with
NaOH / C2 H 5OH , which reacts with Br2 water. Ozonolysis of ‘B’ forms ‘C’,( C5 H 8O2 which
O
contains a chiral carbon having both –CHO and & group). Number of geometrical isomers
− C−
possible in A is
Rough work
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SECTION – A
This section contains 8 multiple choice questions numbered 1 to 8. Each question has 4 choices (A),
(B), (C) and (D), out of which ONLY ONE is correct.
n ∞
1 2012
1. Let f(r) = ∑ r , if the value of
j= 2 j
∑ f (r ) = 2013
r =2
then the value of n is
3. If 36 people are to be seated around a square table 9 each side then the probability that a
p
particular child always sit between its parents on the same side of table is where p and q are
q
co–prime to each other then p + q is
(A) 766 (B) 796
(C) 765 (D) 795
4. A function f(x) is given as f(x) = ||x2 – 10x + 21| – p|. Then the set of values of P such that f(x) has
exactly 6 points of non derivability is
(A) p ∈ (4, ∞) (B) p ∈ [0, 4]
(C) p ∈ (–4, 4) (D) p ∈ (0, 4)
Rough work
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∞
5. If α and β are the roots of the quadratic equation 4x2 + 2x – 1 = 0 then the value of ( αr + βr ) ∑
r =1
is
(A) 2 (B) 3
(C) 0 (D) 6
6. Let A polynomial f(x) = x4 + x3 + x2 + x1 + 1 is given. Then the remainder when f(x5) is divided by
f(x) is
(A) 2 (B) 3
(C) a monic polynomial of degree 2 (D) 5
7. If α be the set of integral values of c for which the equation cos 2x + c sin x = 2c – 7 has solutions
then find the number of distinct symmetric matrices of order 3 × 3 whose trace is 18 and entries
are from the set α.
(A) 100 (B) 125
(C) 150 (D) 180
∫ xAn ( a + b x + c x + dx + ..........) dx where a, b, c, d ………. all are the factors of 1000 taken
x
8. If P =
−2
in any order then the value of P is
(A) 8 An 1000 (B) 1000 An 8
(C) 8 An 10 (D) 10 An 8
This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE or MORE are correct.
9. Which of the following functions are continuous at x = 0 if for all of them f(0) = 1
sin ( tan2 x ) 90 sin ( xº )
(A) f(x) = (B) f(x) =
( e sin x − 1) x 2 (
x + π 2 − π2 − x π 2 )
15
sin π − x sin−1 πx
7 [cos x ]
(C) f(x) = (D) f ( x ) = x
22
tan x
7
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sin2 x 1
10. If f(x) be a cubic polynomial and lim = then f(1) can be equal to
x →0 f(x) 3
(A) 0 (B) 3
(C) 31 (D) 331
α2 4 6 2β2 −1 0 γ 2 1
4
2
1 α 1 if
11. Three matrices are given as A = 9 β 7 , B = 2 γ − 2γ 1 , C=
2 0 β
1 2 2γ 2 1 9 2α − 1
Tr(A) = Tr(B) – 2 and α, β, γ ∈ R then det(c) can be
(A) –1 (B) 2
(C) 5 (D) 0
12. Locus of the point of intersection of two perpendicular tangents to an ellipse is x2 + y2 = 25. Then
the equation of tangents to such ellipse at its point of intersection with the line y = x can be
(length of semi major and semi minor axis of the ellipse are integers)
(A) 16x + 9y = 60 (B) 16x + 9y + 60 = 0
(C) 9x + 16y = 60 (D) 9x + 16y + 60 = 0
SECTION – B
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2. Given that (x − 2)2 + (y − 2)2 = 1. Match the following column–I with column–II.
Column–I Column–II
(A) Maximum value of x + y is (p) 4+ 2
(B) Maximum value of x − y is 9+4 2
(q)
2
(C) Maximum value of xy is 4+ 7
(r)
3
x (s) 2
(D) Maximum value of is
y
(t) 3
SECTION – C
This section contains 6 questions. The answer to each question is a single digit integer, ranging from 0
to 9 (both inclusive).
1. If the two points (0, 0) and (1, 1) does not lie on the same side of the line
a2x + 2b(a + b + c)y + 4 = 0 ∀ a, b ∈ R then find the maximum value of c __________.
2. A curve is given by f(x) = 25 − x 2 . A line passing through the point (–6, –2) intersects the curve
at exactly two points and the slope of such line is lying in [a, b) then the value of [a + b] (where [.]
denotes the greatest integer function) is __________.
4. Let Sk be the area bounded by the curve y = x2(1 – x)k and the lines x = 0, y = 0 and x = 1. If
n
p
lim
n→∞
∑S
k =1
k is equal to
q
and p, q ∈ N then find the least value of p + q __________.
5. If the quadratic equation ax2 + bx + c = 0 has equal roots where a, b, c denotes the lengths of the
sides opposite to vertex A, B, and C of the ∆ABC respectively then find the number of integers in
sin A sinC
the range of + ______
sinC sin A
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