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Carbon & Boron DPP
Carbon & Boron DPP
(Code: ATJEE)
1. Bauxite (Al2O3.2H2O) and Aluminosilicate both are ores of aluminium. Bauxite is found on earth but
not on Mars whereas Aluminosilicate is found on earth as well as Mars. Possible reason is :
(A) No human colony on Mars. (B) No tropical rain forests on Mars.
(C) No need of bauxite on Mars (D) Closeness of earth to sun.
2. Isolation of boron in very high purity is extremely difficult because of :
(A) Strong tendency of boron to acquire electron rich atoms such as C, N or O
(B) High melting point of boron (2180ºC)
(C) Tremendous affinity of liquid Boron towards oxygen.
(D) All of these
3.
true statement is :
(A) z is least reactive non-metal (B) w is cooling
(C) y is electron deficient (D) All of these
450 K
19. B2H6 + NH3 Addition compound (X) Y + Z (g)
In the above sequence Y and Z are respectively :
(A) borazine, H2 (B) boron, H2
(C) boron nitride, H2 (D) borazine and hydrogen
20. Borazine and benzene show striking similarities in their properties. This led to a labeling of borazine
as ‘inorganic benzene’. However, in contrast to benzene, borazine readily undergoes addition
reactions. The appropriate reason for this difference is :
(A) Alternate arrangement of B and N atoms in the hexagonal ring.
(B) Due to the difference in electronegativity between boron and nitrogen, the cloud (electron density)
is more localised on the nitrogen atoms.
(C) Aromatic -clouds of electron density are delocalised over all of the ring atoms.
(D) Net dipole moment of borazine molecule is non-zero.
21. (SnCl4) stannic chloride hydrolyses in dilute solution as per given reaction
SnCl4 + 4H2O [Sn(OH)4] + 4HCl
Hydrolysis can be repressed by adding compound "A".
SnCl4 + A B
B can be :
(A) Sn(OH)4 (B) SnCl2 (C) H2SnCl6 (D) Sn(OH)Cl
22. Amphoteric oxide (X) + 3C + Cl2 Poisonous gas + anhydrous chloride (Y)
Hydrated chloride
Z
Element forming 'Y' other than 'Cl' reacts with concentrated HCl but leads to passivation with conc.
HNO3. Select the correct option.
(A) X = Z and Y on reacting with LiH forms strong oxidising agent
(B) X = Z and Y on reacting with LiH forms strong reducing agent
(C) X Z and Y is used as a catalyst in Friedel crafts reaction
(D) X Z and Y on reacting with LiH forms strong oxidising agent
23. BF3 on hydrolysis forms :
(A) H3BO3 (B) HBF4 (C) both (A) and (B) (D) none of these
24. Preparation of organosilicones from SiCl4 involves substitution in first step :
SiCl4 + xRMgCl (R)x SiCl4–x + xMgCl2
Values of 'x' to obtain chain terminating & chain multiplication parts of chain silicone produced are
respectively:
(A) 1 & 2 (B) 2 & 1 (C) 2 & 3 (D) 3 & 2
25. To get the silicone R3Si–(OSiR2)n–SiR3 having 4Si–O–Si linkage, the unit taken is
(A) 4 unit of R2SiCl2 and 2 unit of R3SiCl (B) 2 unit of R2SiCl2 and 2 unit of R3SiCl
(C) 3 unit of R2SiCl2 and 2 unit of R3SiCl (D) 3 unit of R3SiCl and 2 unit R2SiCl2
26. Boric acid is polymeric due to :
(A) its acidic nature (B) the presence of hydrogen bonds
(C) its monobasic nature (D) its geometry
Ashwani Tyagi Sir 3 Code: ATJEE
CHEMISTRY TEST
27. Silicon reacts with hot solution of NaOH forming :
(A) Si(OH)4 (B) Si(OH)2 (C) SiO2 (D) Na2SiO3
28. Consider the following conversions :
100C Red heat
S1 : H3BO3 HBO2 B2O3
END OF PAPER