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SANKALP_ST-02

SHEET ST-2
1. Determine the average oxidation no. of following elements given in bold letters :
(a) H2S2O8 (b) K4Fe(CN)6 (c) OsO4
(d) HNC (e) Fe0.94O (f) Fe3O4
(g) NH2.NH2 (h) FeSO4.(NH4)2SO4.6H2O (i) NOClO4
(j) Na2[Fe(CN)5NO] (k) [Fe(NO)(H2O)5]SO4 (l) Na2S4O6
(m) (CH3)2SO (n) Na2S2
2. Determine the oxidation number of the following elements given in bold letters :
(a) Ba2XeO6 (b) C3O2 (c) V(BrO2)2
(d) Cs4Na(HV10O28) (e) K[Co(C2O4)2.(NH3)2] (f) [Ni(CN)4]2–
3. Find the oxidation number of bold lettered atoms :
(a) Mn in K2MnO4, K2MnO3, Mn3O4, MnSO4, K3MnF6, MnO2
(b) C in CH4, C2H6, C3H8, C2H4, C2H2, H2C2O4, CO2
(c) S in Na2S2O3, S4, S8, Na2S2O7
(d) N in NH3, NH2OH, NaN3, NH4NO2
(e) Cl in Cl2, HOCl, Cl2O, ClO2, KClO3, Cl2O7
4. Determine the oxidation number of bold lettered atoms in the following :
(a) 8 KClO3 + 24 HCl 8 KCl + 12 H2O + 9Cl2 + 6ClO2
(b) 3I2 + 6NaOH NaIO3 + 5NaI + 3H2O
5. Find the oxidation number of bold lettered atoms :
(a) SnS3–2 (b) S2O3–2 (c) S2O7–2 (d) NH4+
(e) ClO2– (f) P2O7–4 (g) O2–2 (h) C2O4–2
–2 –
(i) Cr2O7 (j) MnO4 (k) Be3N2 (l) Na3Fe(CN)5NO
+3
(m) KCrO3.Cl (n) F2H2 (o) Co(NH3)6 (p) CuH
(q) O2F2
6. Oxidation number of iodine varies from-
(A) –1 to +1 (B) –1 to +7 (C) +3 to +5 (D) –1 to +5

7. 2 + K K3 in the above reaction –


(A) Only oxidation takes place (B) Only reduction takes place
(C) Both the above (D) None of the above
8. In the reaction 4P + 3KOH + 3H 2O  3KH2PO 2 + PH3
(A) P undergoes reduction only
(B) P undergoes oxidation only
(C) P undergoes both oxidation and reduction
(D) neither undergoes oxidation nor reduction
9. Which of the following reactions involves oxidation and reduction-
(A) NaBr + HCl  NaCl + HBr (B) HBr + AgNO 3  AgBr +HNO 3
(C) H2 + Br2  2HBr (D) Na2O + H2SO 4  Na2SO 4 + H2O
10. Which of the following reactions does not involve either oxidation or reduction ?
2+ + +2 –2 –2
(A) VO  V2O 3 (B) Na  Na (C) Zn  Zn (D) CrO 4  Cr2O 7

11. What is the equivalent weight of nitrogen in the process NO 3  N2 ?

NO 3  N2 ?
(A) 14 (B) 4 (C) 2.8 (D) 7
SANKALP_ST-02

12. In the half reaction 2ClO 3  Cl 2
(A) 5 electrons are gained (B) 5 electrons are liberated
(C) 10 electrons are gained (D) 10 electrons are liberated

17. Phosphorous has the oxidation state of +3 in –


(A) Phosphorus acid (H 3PO 3) (B) Ortho phosphoric acid (H3PO 4)
(C) Meta phosphoric acid (HPO 3) (D) Pyro phosphoric acid (H 4P2O 7)
18. Which statement is wrong-
(A) Oxidation number of oxygen is +1 in peroxides
(B) Oxidation number of oxygen is +2 in oxygen difluoride
1
(C) Oxidation number of oxygen is  in superoxides
2
(D) Oxidation number of oxygen is –2 in most of is compound
19. The oxidation number and covalency of sulphur in the sulphur molecule (S 8) are respectively-
(A) 0 and 2 (B) +6 and 8 (C) 0 and 8 (D) +6 and 2

ANSWER KEY
1 (a) (+6) (b) (+2) (c) (+8) (d) (+2)
(e) (0) (f) (+8/3) (g) (–2) (h) (+2)
(i) (+7) (j) (+2) (k) (+1) (l) (+5/2)
(m) (0) (n) (–1)
2 (a) (+8) (b) (+4/3) (c) (+2) (d) (+5)
(e) (+3) (f) (+2)
3 (a) [+6, +4, +8/3, +2, +3, +4] (b) [–4, –3, –8/3, –2, –1, +3, +4]
(d) [+2, 0, 0, +6] (e) [–3, –1, –1/3, –3, +3]
(f) [0, +1, +1, +4, +5, +7]
4 (a) [+5, –1, 0, +4] (b) [0, +5, –1]
5 (a) (+4) (b) (+2) (c) (+6) (d) (–3)
(e) (+3) (f) (+5) (g) (–1) (h) (+3)
(i) (+6) (j) (+7) (k) (+2) (l) (+1)
(m) (+6) (n) (–1) (o) (+3) (p) (–1)
(q) (+1)
6. B
7. C
8. C
9. C
10. D
11. C
12. C
17. A
18. A
19. A

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