Scribd Logo
Upload

Welcome to Scribd!

  • Isomerism: (Ii) (Iii) (I) (Ii) (Ill)

    Uploaded by

    Ritik Kumar Nayak
    21 views6 pages
    The document discusses various types of isomerism between pairs of compounds, including chain isomerism between pentan-1-ol and 3-methylbutan-1-ol, functional isomerism between ethanol and dimethyl ether, and position isomerism between butan-1-ol and butan-2-ol. It also discusses the number of isomers possible for an alcohol with the molecular formula C5H12O and how many would contain chiral centers and exhibit enantiomerism.

    Original Description:

    Shnsnsmks

    Original Title

    New Microsoft Word Document

    Copyright

    © © All Rights Reserved

    Available Formats

    DOCX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document
    The document discusses various types of isomerism between pairs of compounds, including chain isomerism between pentan-1-ol and 3-methylbutan-1-ol, functional isomerism between ethanol and dimethyl ether, and position isomerism between butan-1-ol and butan-2-ol. It also discusses the number of isomers possible for an alcohol with the molecular formula C5H12O and how many would contain chiral centers and exhibit enantiomerism.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as docx, pdf, or txt
    21 views6 pages

    Isomerism: (Ii) (Iii) (I) (Ii) (Ill)

    Uploaded by

    Ritik Kumar Nayak
    The document discusses various types of isomerism between pairs of compounds, including chain isomerism between pentan-1-ol and 3-methylbutan-1-ol, functional isomerism between ethanol and dimethyl ether, and position isomerism between butan-1-ol and butan-2-ol. It also discusses the number of isomers possible for an alcohol with the molecular formula C5H12O and how many would contain chiral centers and exhibit enantiomerism.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as docx, pdf, or txt
    of 6

    1. .

    What type
    of
    isomerism
    exists
    between the
    following
    pairs of
    compounds?
    (i) Pentan-1-ol and 3-Methylbutan-1-ol
    (ii} Ethanol and Dimethyl ether
    (iii} Butan-1-ol and Butan-2-ol
    (i) (ii} (ill}
    (a} Chain Functional Position
    isomerism isomerism isomerism
    (b) Functional Chain Position
    isomerism isomerism isomerism
    (c} Position Chain Functional
    isomerism isomerism isomerism
    (d} Chain Position Functional
    isomerism isomerism isomerism
    ,

    C5H 12O is a
    monohydric
    alcohol. How
    many isomers of
    this alcohol are
    possible? How
    many of these
    contain chiral
    centres as well as
    can exhibit
    enantiomerism?

    (a) 8 and 3
    (c) 4 and 2

    (b) 6 and 2
    (d) 12 and 4 ,

    2. 3-propylbutan-1-ol
    3. 2-ethylpentan -1- ol
    4. 3-methyl hydroxyhexane
    5. 2-ethyl-2-propyl ethanol
    .
    A compound
    C6H14O2 has two
    tertiary alcoholic
    groups . The IUPAC
    name of this
    compound is
    6. 2, 3-dimethyl - I, 2-butanediol
    7. 3, 3-dimethyl - I, 2-butanediol
    8. 2, 3-dimethyl - 2, 3-butanediol
    9. 2-methyl - 2, 3-pentanediol
    /

    Which of the following is phenol?


    (a) Crcsol (b) Catechol
    (c) Benzcnol (d) All of the,.
    ‘
    ,

    Classify the following as primary, secondary


    and tertiary alcohols :

    (i)
    (ii) H2C= CH—CH2OH
    (iii) CH3—CH2—CH2—OH (AI 2009

    2. Wood alcohol is
    (a) CH3OH (b) C2H5OH (c) CH3CH2CH2OH (d) (CH3)2CHOH <a>
    3. Grain alcohol is
    (a) CH3OH (b) C2H5OH (c) CH3CH2CH2OH (d) (CH3)2CHOH<b>
    4. Rubbing alcohol is
    (a) CH3OH (b) C2H5OH (c) CH3CH2CH2OH (d) (CH3)2CHOH<d>
    5. Absolute alcohol is
    (a) CH3OH (b) C2H5OH (c) CH3CH2CH2OH (d) (CH3)2CHOH<b>

    Structures of Functional Groups:


    The oxygen atom in alcohols and phenols is sp3 hybridised and
    they have tetrahedral disposition of hybrid atomic orbitals. The
    two hybrid atomic orbitals have lone pair of electrons and
    remaining two are involved in bond formation. The value of 􀂑ROH bond angle depends upon the bulk of R
    group and repulsion between lone pair of electrons on oxygen. Due to the lone pair – lone pair repulsion,
    the C-O-H
    bond angle in methanol is reduced to 108.9° from the regular tetrahedral bond angle of 109.5° .
    In phenols, the –OH group is attached to sp2
    hybridised carbon of an aromatic ring. The carbon– oxygen bond
    length (136 pm) in phenol is slightly less than that in methanol. This
    is due to (i) partial double bond character on account of the conjugation
    of unshared electron pair of oxygen with the aromatic ring (Section
    11.4.4) and (ii) sp2 hybridised state of carbon to which oxygen is
    attached.
    In ethers, the four electron pairs, i.e., the two bond pairs and two
    lone pairs of electrons on oxygen are arranged approximately in a
    tetrahedral arrangement. The bond angle is slightly greater than the
    tetrahedral angle due to the repulsive interaction between the two
    bulky (–R) groups. The C–O bond length (141 pm) is almost the same
    as in alcohols.

    Which of the following is dihydric alcohol ?


    (a) Glycerol (b) Ethylene glycol
    (c) Catechol (d) Resorcinol

    An example of a compound with functional group – O – is :


    (a) acetic acid (b) methyl alcohol
    (c) diethyl ether (d) acetone
    .
    12. How many alcohol(s) with molecular formula C4H10O are
    chiral in nature?
    (a) 1 (b) 2
    (c) 3 (d) 4 ,

    /
    /*
    127. Match the columns
    Column-I Column-II
    (A) Antifreeze used in (p) Methanol
    car engine
    (B) Solvent used in (q) Phenol
    perfumes
    (C) Starting material for (r) Ethleneglycol
    picric acid
    (D) Wood spirit (s) Ethanol
    (a) A – (s), B – (q), C – (p), D – (r)
    (b) A – (r), B – (s), C – (q), D – (p)
    (c) A – (s), B – (q), C – (r), D – (p)
    (d) A – (p), B – (r), C – (q), D – (s) .

    Assertion : The bond angle in alcohols is slightly less


    than the tetrahedral angle.
    Reason : In alcohols, the oxygen of –OH group is attached
    to sp3 hybridized carbon atom.

    138. Vinyl carbinol is


    (a) HO 􀀐CH2 􀀐CH 􀀠 CH2
    (b) CH3C(OH) 􀀠 CH2
    (c) CH3 􀀐CH 􀀠 CH 􀀐OH
    (d) CH3 􀀐C(CH2OH) 􀀠 CH2 ,

    The C-O-C angle in ether is about


    (a) 180° (b) 190°28' (c) 110° (d) IOS'

    You might also like