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CHEMISTRY

Bohr’s Model
TARGET
DPP - 6
01. Radius of Bohr’s orbit of hydrogen atom is:
(a) 0.24 Å (b) 0.48 Å (c) 0.53 Å (d) 1.06 Å

02. Bohr theory is not applicable for:


(a) He+ (b) Li2+ (c) Be+ (d) H

03. What is the energy associated with 3rd energy shell of hydrogen atom?
(a) -2.18 × 10-18J (b) -0.342 × 10-19J (c) -0.726 × 10-18J (d) -2.42 × 10-19J

04. According to the Bohr Theory, which of the following transitions in the hydrogen atom will
give rise to the least energetic photon?
(a) n = 6 to n = 5 (b) n = 5 to n = 3 (c) n = 6 to n = 1 (d) n = 5 to n = 4

05. According to Bohr’s theory angular momentum of an electron in 6th orbit is:
h h h 2.5h
(a) 2.5 (b) 6 (c) 3 (d)
� � � 2�

06. If r1 is the radius of the first orbit of hydrogen atom, then the radii of second, third and
fourth orbits in term of r1 are:
(a) r12, r13, r14 (b) 4r1, 9r1, 16r1 (c) 8r1, 27r1, 64r1 (d) 2r1, 6r1, 8r1

07. Electronic energy is negative because:


(a) Electron has negative charge
(b) Energy is zero near the nucleus and decreases as the distance from nucleus increases
(c) Energy is zero at infinite distance from the nucleus and decreases as the electron comes
towards nucleus
(d) These are interelectronic repulsions

08. An electron jumps from lower orbit to higher orbit when:


(a) Energy is released (b) Energy is absorbed
(c) No change in energy (d) It radiates energy

09. The ionization energy of the electron in the lowest orbit of hydroen atom is 13.6 eV. The
energies required in eV to remove electron from three lowest orbits of hydrogen atom are:
(a) 13.6, 6.8, 8.4 (b) 13.6, 10.2, 3.4 (c) 13.6, 27.2, 40.8 (d) 13.6, 3.4, 1.51

10. En = -313.6/n2 kcal/mole. If the value of E = -34.84 kcal/mole, to which value does ‘n’
correspond?
(a) 4 (b) 3 (c) 2 (d) 1

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11. Zeeman effect refers to the:
(a) Splitting of the spectral lines in a magnetic field
(b) Splitting up of the spectral lines in an electrostatic field
(c) Emission of electrons from metals when light falls on it
(d) Random scattering of �-particles by gold foil

12. The number of waves in the third orbit of H atom is:


(a) 1 (b) 2 (c) 4 (d) 3

13. In a hydrogen atom, if the energy of electron in the ground state is -x eV., then that in the 2nd
excited state of He+ is:
4 9
(a) -x eV (b) � x eV (c) �2x eV (d) � x eV
9 4

14. The correct order of energy difference between adjacent energy levels in H atom:
(a) E2 - E1 > E3 - E2 > E4 - E3 (b) E2 - E1 > E4 - E3 > E3 - E2
(c) E4 - E3 > E3 - E2 > E2 - E1 (d) E3 - E2 > E4 - E3 > E2 - E1

15. The time taken by the electron in one complete revolution in the nth Bohr’s orbit of the
hydrogen atom is:
(a) Inversely proportional to n2 (b) Directly proportional to n3
h n
(c) Directly proportional to (d) Inversely proportional to
2� h

� Z2 �
16. Based on equation, E � �2.178 � 10 �18 J � 2 � certain conclusions are written. Which of them
�n �
is not correct?
(a) Larger the value of n, the larger is the orbit radius
(b) Equation can be used to calculate the change in energy when the electron changes orbit
(c) For n = 1, the electron has a more negative energy than it does for n = 6 which means that
the electron is more loosely bound in the smallest allowed orbit
(d) The negative sign in equation simply means that the energy of electron bound to the
nucleus is lower than it would be if the electrons were at the infinite distance from the nucleus

17. The energy of second Bohr orbit of the hydrogen atom is -328kJ mol-1; hence the energy of
fourth Bohr orbit would be:
(a) -41kJ mol-1 (b) -1312kJ mol-1 (c) -164kJ mol-1 (d) -82kJ mol-1

18. The radius of hydrogen atom in the ground state is 0.53 Å. The radius of Li2+ ion (atomic
number = 3) in a similar state is:
(a) 0.53 Å (b) 1.06Å (c) 0.17Å (d) 0.265Å
19. In a Bohr’s model of an atom, when an electron jumps from n = 1 to n = 3, how much energy
will be emitted or absorbed?
(a) 2.389 × 10-12 ergs (b) 0.239 × 10-10 ergs
(c) 2.15 × 10-11 ergs (d) 0.1936 × 10-10 ergs

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20. The Bohr orbit radius for the hydrogen atom (n = 1) is approximately 0.530Å. The radius for
the first excited state (n = 2) orbit is (in Å)
(a) 4.77 (b) 1.06 (c) 0.13 (d) 2.12

21. The ratio of the energy required to remove an electron from the first three Bohr’s orbits of
hydrogen is:
(a) 3 : 2 : 1 (b) 9 : 4 : 1 (c) 36 : 9 : 4 (d) 1 : 4 : 9

22. The energy of electron in first Bohr’s orbit of H-atom is -13.6 eV. What will be its potential
energy in n = 4th orbit:
(a) -13.6eV (b) -3.4eV (c) -0.85eV (d) -1.70eV

23. The value of Bohr radius of hydrogen atom is:


(a) 0.529 × 10-7cm (b) 0.529 × 10-8cm (c) 0.529 × 10-9cm (d) 0.529 × 10-10cm

24. The ratio of radii of 3rd and 2nd Bohr’s orbit of hydrogen atom is:
(a) 3 : 2 (b) 4 : 9 (c) 9 : 4 (d) 9 : 1

ANSWER-KEY
01. C 02. C 03. D 04. A 05. C 06. B 07. C

08. B 09. D 10. B 11. A 12. D 13. B 14. A

15. B 16. C 17. D 18. C 19. D 20. D 21. C

22. D 23. B 24. C

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