Scribd Logo
Upload

Welcome to Scribd!

  • Ion Exchange For

    Uploaded by

    GULSHAN MADHUR
    67 views3 pages
    The document discusses the fundamental requirements and common properties of ion exchange resins. Ion exchange resins must be sufficiently cross-linked to have low solubility while still allowing ion diffusion. They must also be chemically stable and contain accessible ion exchange groups. Common properties include being insoluble in water and organic solvents while possessing exchangeable counter ions. Cation exchange resins contain negatively charged groups that attract positive ions, while anion exchange resins contain positively charged groups that attract negative ions. Examples of common cation and anion exchange resins are provided.

    Original Description:

    Ion Exchange Chromatography Presentation

    Original Title

    ion exchange for ppt

    Copyright

    © © All Rights Reserved

    Available Formats

    DOCX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document
    The document discusses the fundamental requirements and common properties of ion exchange resins. Ion exchange resins must be sufficiently cross-linked to have low solubility while still allowing ion diffusion. They must also be chemically stable and contain accessible ion exchange groups. Common properties include being insoluble in water and organic solvents while possessing exchangeable counter ions. Cation exchange resins contain negatively charged groups that attract positive ions, while anion exchange resins contain positively charged groups that attract negative ions. Examples of common cation and anion exchange resins are provided.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as docx, pdf, or txt
    67 views3 pages

    Ion Exchange For

    Uploaded by

    GULSHAN MADHUR
    The document discusses the fundamental requirements and common properties of ion exchange resins. Ion exchange resins must be sufficiently cross-linked to have low solubility while still allowing ion diffusion. They must also be chemically stable and contain accessible ion exchange groups. Common properties include being insoluble in water and organic solvents while possessing exchangeable counter ions. Cation exchange resins contain negatively charged groups that attract positive ions, while anion exchange resins contain positively charged groups that attract negative ions. Examples of common cation and anion exchange resins are provided.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as docx, pdf, or txt
    of 3

    (3rd slide)

    Fundamental Requirements Of A Resin

    A useful resin must be sufficiently hydrophillic to permit diffusion of ions through the structure at a finite
    and usable rate.

    It must be sufficiently cross linked to have only a negligible solubility.

    It must be chemically stable and must contain sufficient number of accessible ion exchangers groups.

    Reversibility and no permanent change in structure .

    When swollen it must be denser than water.

    (4th slide)

    COMMON PROPERTIES OF ION ECHANGERS

    Ion Exchangers are complex , porous and polymeric in nature.

    It is almost insoluble in water and organic solvents like benzene, ether.

    They possess active or counter ions that are easily exchangeable reversibly with other ions in
    surrounding solution without any change in material.

    Granular resins swell in water to give a gel structure. Swelling is directly proportional to the percentage
    of cross linking. Highly cross linked resins are brittle, harder, complex and porous.

    Divinyl benzene prevents resin from swelling indefinitely.

    (5th slide)

    TYPES OF ION EXCHANGERS

    Currently most of the common ion exchange products are built on the styrene divinyl backbone because
    of their stability.

    These polymers carry an electric charge that is exactly balanced by the charges on the counter ions.

    These active ions are cations in cation exchanger and anions in anion exchanger.

    Thus an anion exchanger contains polymeric cations and active anions while cation exchanger consists of
    polymeric anions and active cations.

    (6th slide)

    CATION ECHANGERS

    Active ions (counter ions) are cations.

    Consists negatively charged groups and attract positive charged groups.


    The functional group in cation exchange resins are usually acids. So it is called as acidic ion exchangers.

    They are usually high molecular weight cross linked polymers having sulphonic , carboxylic , phenolic
    groups etc with equal amounts of cations.

    In cation exchangers hydrogen ions are mobile and are exchangeable with other cations and the anions
    remain attracted to resin.

    Cation exchange is good for removing metal ions from an aqueous solution.

    When a salt solution is passed through cation exchanger , the H+ ions enter the solution and the cations
    of the salt get attached to the resin.

    Resin + M+ --> Resin-M+ + H+

    Strong cation exchange resins consists of SO2H group and weak cation exchange resins consists of groups
    like COOH , OH , SH-

    (7th slide)

    Cation Exchange Resins

    Trade name Functional Group Framework Material

    Amberlite IR-120 -SO 3H Styrene/divinylbenzene

    Dowex -SO 3H Styrene/divinylbenzene

    Zerolit -SO3H Styrene/divinylbenzene

    SE Cellulose -C 2H4 , -SO3H Cellulose

    Amberlite IRC-50 -COOH Methacrylic Acid

    CM -CH 2COOH Cellulose,Fibrous

    (8th slide)

    Anion Exchange Resins

    Active ions (Counter ions) are anions

    The functional groups added to the resin is similar to cation resin but are basic instead of acidic.

    Consists positively charged groups and attract negatively charged groups. Also called basic ion
    exchangers.

    They are usually resins consisting amine or quarternary ammonium groups as integral part and equal
    amount of Ce, OH , SO43- ions, which are mobile and exchangeable.

    (9th slide)
    Anion Exchange Resins

    Quarternary ammonium a strong base

    CH2N(CH3)3 + OH + B- ----> Res-CH2N(CH3)3Cl + OH-

    Polyalky amine a weak base

    NH(-R) + OH + B --> Res-NH(-R)2B + OH-

    (10th slide)

    Trade Name Functional Group Framework Material

    Amberlite IRA-400 -CH2N(CH 3)3 Styrenedivinylbenzene

    Zerolit FF-1P -CH2N(CH 3)3 Styrenedivinylbenzene

    You might also like