4 EC SMAW Msds 5-08
4 EC SMAW Msds 5-08
SECTION I (IDENTIFICATION)
PRODUCT CLASSIFICATION: Covered Electrode for Shielded Metal Arc Welding (SMAW)
WARNING: This product contains or produces a chemical known to the State of California to cause birth defects (or other reproductive harm) and cancer.
(California Health & Safety Code 25249.5 et seq.)
When the electrode is consumed, fume and gas decomposition products generated are different in percent and form from the ingredients listed in Section II.
Fume and decomposition products, not the ingredients in the electrode, are important. Decomposition products include those originating from the
volatilization, reaction, or oxidation of materials in Section II, plus those from the base metal and coating, etc., as noted above. These components are
virtually always present as complex oxides and not as metals (Characterization of Arc Welding Fume: American Welding Society). Reasonably expected
fume constituents of the fume could include: complex oxides of iron, manganese, and potassium. Chromium and nickel oxides may also be present. The table
below lists reasonably expected fumes that may be generated:
MSDS: EUTECTIC 4 Page 2 of 3
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CAS Exposure Limit (mg/m )
SUBSTANCE NUMBER OSHA PEL ACGIH-TLV
Iron Oxide 1309-37-1 10 (as Fe) 5 (as Fe)
Nitric Oxide 10102-43-9 30 31
Chromium (VI) not listed 0.005 0.05 (as Cr VI)
Nickel Oxide # 1313-99-1 1 (as Ni) 0.2 (as Ni)
Manganese fume # 7439-96-5 5 0.2 (NIC 0.03)
EFFECTS OF OVEREXPOSURE - Electric arc welding may create one or more of the following health hazards:
SHORT TERM (ACUTE) OVEREXPOSURE to welding fumes may result in discomfort such as metal fume fever, dizziness, nausea, or dryness or
irritation of nose, throat, or eyes. PRIMARY ROUTE OF ENTRY is the respiratory system. IRON, IRON OXIDE, MANGANESE - Remove from
overexposure and apply artificial respiration if needed. CHROMIUM- Inhalation of chromium can cause irritation of nasal membranes and skin.
FLUORIDES - Fluoride compounds produced may cause eye and skin burns, and pulmonary edema bronchitis. Exposure to extremely high levels of
fluorides can cause abdominal pain, diarrhea, muscular weakness, and convulsions. In extreme cases it can cause loss of consciousness and death. NICKEL,
NICKEL OXIDE - May cause metallic taste, nausea, tightness in chest, fever, and allergic reactions.
LONG TERM (CHRONIC) OVEREXPOSURE may lead to siderosis (iron deposits in lungs) and is believed by some investigators to affect pulmonary
functions. PRIMARY ROUTE OF ENTRY is the respiratory system. IRON, IRON OXIDE - Long term overexposure to iron fumes can cause deposits
of iron in the lungs (siderosis). Lungs will clear in time when exposure to iron and its compounds cease. MANGANESE - Long term exposure may lead to
"Manganism.” Central nervous system is affected and symptoms include muscular weakness, impaired speech, impaired movement, and tremors. Exposed
workers should get quarterly medical examinations for manganism. Bronchitis and some lung fibrosis have been reported. FLUORIDES - Overexposure to
fluorides can cause serious bone erosion, excessive calcification of the bone and calcification of the ribs, pelvis and spinal column. May cause skin rash.
NICKEL, NICKEL OXIDE - Long term overexposure to nickel products may cause lung fibrosis or pneumoconiosis. Overexposure to HEXAVALENT
CHROMIUM (CrVI) is reported to cause lung cancer in humans.
ARC RAYS can injure eyes and burn skin. SKIN CANCER HAS BEEN REPORTED.
ELECTRIC SHOCK can kill! IN CASE OF ELECTRICAL SHOCK: turn off power and follow recommended treatment. Call a physician.
See Section VII for precautions.
EMERGENCY & FIRST AID PROCEDURES: Call for medical aid. Employ first aid techniques recommended by The American Red Cross.
INHALATION: Remove to fresh air. If breathing is difficult, administer oxygen. If not breathing, begin artificial respiration.
If no detectable pulse, begin Cardiopulmonary Resuscitation. (CPR). Call for medical aid.
SKIN: Wash affected area with soap and water. If rash develops, see a physician.
EYES: Flush with a large amount of fresh water for at least 15 minutes. Get medical attention.
INGESTION: Seek medical attention.
CARCINOGENICITY
CHROMIUM - Chromium VI is listed as being carcinogenic to humans on IARC and NTP lists, and is listed by NIOSH as being a potential occupational
carcinogen (with no further categorization).
NICKEL - is listed as being carcinogenic to humans on IARC and NTP lists, and is listed by NIOSH as being a potential occupational carcinogen (with no
further categorization).
SILICON DIOXIDE - is listed as being carcinogenic to humans on IARC and NTP lists, and is listed by NIOSH as being a potential occupational
carcinogen (with no further categorization).
TITANIUM DIOXIDE is listed as being unclassifiable as to Carcinogenicity in humans by IARC and is listed by NIOSH as being a potential occupational
carcinogen (with no further categorization).
WELDING FUMES (not otherwise specified) are considered to be carcinogenic defined with no further categorization by NIOSH and IARC.
MSDS: EUTECTIC 4 Page 3 of 3
SECTION VII (PRECAUTION FOR SAFE HANDLING AND USE/APPLICABLE CONTROL MEASURES)
Read and understand the manufacturer's instructions and precautionary label on this product.
See American National Standard Z49.1, Safety in Welding and Cutting, published by the "American Welding Society," 550 N.W. LeJeune Road, Miami, FL
33126 and OSHA Publication 2206 (29CFR 1910), U.S. Government Printing Office, Superintendent of Documents, P.O. Box 371954, Pittsburgh, PA
15250-7954 for more detail on the following:
Ventilation: Use enough ventilation, local exhaust at the arc, or both, to keep the fumes and gases below the TLV's in the workers breathing
zone and the general area. Train the welder to keep his head out of the fumes. Monitor fume levels and do not exceed permissible exposure limits or values.
Respiratory Protection: Use respirable fume respirator or air supplied respirator when welding in a confined space or where local exhaust or ventilation
does not keep exposure below the TLV's.
Eye Protection: Wear a helmet or face shield with a filter lens of shade 12 or darker. Provide screens and flash goggles to shield others.
Protective Clothing: Wear head, hand, and body protection which help to prevent injury from radiation, sparks, and electrical shock. See ANSI Z49.1. At a
minimum, this includes welders’ gloves and a protective face shield and may include arm protectors, aprons, hats, shoulder protection, as well as dark
substantial clothing. Train the welder not to touch live electrical parts and to insulate himself (or herself) from work and ground, especially if clothing and
gloves are wet.
Waste: Dispose of any grinding dust and waste residues in accordance with EPA or local regulations. Plastic containers and cardboard packaging can be
recycled.
Storage: Keep material sealed and dry before use. Keep remaining product sealed and dry.
SUPPLEMENTAL INFORMATION
IARC: International Agency for the Research on Cancer
ACGIH: American Conference of Governmental Industrial Hygienists
NIOSH: National Institute for Occupational Safety and Health
NTP: National Toxicology Program
PEL: Permissible Exposure Limit
OSHA: U.S. Occupational Safety and Health Administration
TLV: Threshold Limit Value
CAS: Chemical Abstracts Service Registry Number
Exposure limits are subject to change. Contact ACGIH, OSHA, NIOSH, and IARC for current values.
The information in this MSDS was obtained from sources we believe are reliable. However, this information is provided without any representation or
warranty, expressed or implied, regarding accuracy or correctness. The conditions or methods of handling, storage, use, and disposal of the product are
beyond our control and may be beyond our knowledge. For this and other reasons we do not assume responsibility and expressly disclaim liability of loss,
damage, or expense arising from it or any way connected with the handling, storage, use, or disposal of the product.